JPS5934626A - Method for formation of semiconductor film - Google Patents
Method for formation of semiconductor filmInfo
- Publication number
- JPS5934626A JPS5934626A JP57143995A JP14399582A JPS5934626A JP S5934626 A JPS5934626 A JP S5934626A JP 57143995 A JP57143995 A JP 57143995A JP 14399582 A JP14399582 A JP 14399582A JP S5934626 A JPS5934626 A JP S5934626A
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- JP
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- Prior art keywords
- layer
- film
- single crystal
- electron beam
- semiconductor layer
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02367—Substrates
- H01L21/02433—Crystal orientation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02367—Substrates
- H01L21/0237—Materials
- H01L21/02373—Group 14 semiconducting materials
- H01L21/02381—Silicon, silicon germanium, germanium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02436—Intermediate layers between substrates and deposited layers
- H01L21/02439—Materials
- H01L21/02488—Insulating materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02524—Group 14 semiconducting materials
- H01L21/02532—Silicon, silicon germanium, germanium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02538—Group 13/15 materials
- H01L21/02543—Phosphides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02538—Group 13/15 materials
- H01L21/02546—Arsenides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02538—Group 13/15 materials
- H01L21/02549—Antimonides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02587—Structure
- H01L21/0259—Microstructure
- H01L21/02595—Microstructure polycrystalline
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02656—Special treatments
- H01L21/02664—Aftertreatments
- H01L21/02667—Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth
- H01L21/02689—Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth using particle beams
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02656—Special treatments
- H01L21/02664—Aftertreatments
- H01L21/02667—Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth
- H01L21/02691—Scanning of a beam
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- Microelectronics & Electronic Packaging (AREA)
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- Recrystallisation Techniques (AREA)
Abstract
Description
【発明の詳細な説明】
〔発明の属する技術分野〕
本発明は、半導体膜形成方法に係り、lP♀に粗大結晶
粒多結晶あるいは単結晶半導体膜を形成する方法に関す
る。DETAILED DESCRIPTION OF THE INVENTION [Technical field to which the invention pertains] The present invention relates to a method for forming a semiconductor film, and more particularly, to a method for forming a coarse-grained polycrystalline or single-crystalline semiconductor film in lP♀.
周知の如く、半導体基板(以下代表的にシリコン基板を
用いる)上に素子を形成する半導体装置においては、酸
化、拡散、イオン注入、写真蝕刻など公知の技術を用い
て、シリコン基板上に平面大粒の多結晶廿たは単結晶半
導体層(以下代表的にシリコン層を用いる)を形成する
方法が提案されている。例えば、シリコン基板をSiO
2またはSiN等の絶縁力・、1でおおってその上に多
結晶シリコン層を被着し、これを連続ビームのレーザー
光まだは電子線により照射アニールすることにより単結
晶シリコン層となし、該層中に素子を形成することによ
り、接層半導体装置を製造しようというものである。し
かし従来の方法では、直径で20μH1程度の粗大粒多
結晶シリコンにしがならず単結晶シリコン層をイ4する
ことはきわめてむずがしい。また実現した単結晶中には
多数の転位、双晶、積層欠陥等が含剪れ、シリコン層の
結晶性はきわめて悪いものであった。まだそのシリコン
層の表面−ば、かなり大きな凹凸ができ、そのため核層
中に素子を作る際にはリソグラフィー上多くの難点゛が
ビーム4を照射して、上記開孔部において下地単結晶シ
リコン基板との接触部を種結晶としてエピタキシャル成
長させ、引き続き横方向へ結晶成長させるというもので
ある。この方法の特徴は基板と同一面方位の単結晶領域
を希望する場所に作り得る点にあり、この技術をくりか
えしてゆけば三次元半縛体装置は可能であると考えられ
る。As is well known, in semiconductor devices in which elements are formed on a semiconductor substrate (hereinafter a silicon substrate is typically used), large planar grains are formed on a silicon substrate using known techniques such as oxidation, diffusion, ion implantation, and photolithography. A method of forming a polycrystalline semiconductor layer or a single crystalline semiconductor layer (hereinafter, a silicon layer is typically used) has been proposed. For example, a silicon substrate is made of SiO
A polycrystalline silicon layer is deposited on top of the polycrystalline silicon layer covered with an insulating material such as 2 or SiN, and then irradiated and annealed with a continuous beam of laser light or an electron beam to form a single crystal silicon layer. The idea is to manufacture a contact layer semiconductor device by forming elements in the layers. However, with the conventional method, it is extremely difficult to cut a single crystal silicon layer without forming coarse grained polycrystalline silicon with a diameter of about 20 μH1. Furthermore, the single crystal that was realized contained many dislocations, twins, stacking faults, etc., and the crystallinity of the silicon layer was extremely poor. The surface of the silicon layer still has quite large irregularities, which causes many difficulties in lithography when forming devices in the core layer. This method uses the contact area as a seed crystal to grow epitaxially, and subsequently grows the crystal in the lateral direction. The feature of this method is that it is possible to create a single crystal region with the same plane orientation as the substrate in a desired location, and it is thought that if this technique is repeated, it will be possible to create a three-dimensional semi-bound device.
しかし、現実には横方向に単結晶化できる長さくなり、
先に浴融、1与結晶し、第1!!lJで示すようにレト
j孔恥からはなかなかエビタ片シャルしにくい0開孔部
が溶融シフ、シかも絶縁膜2上のシリコン層3が蒸発せ
ずに横方向エビ成長するビームアニーげている要因は多
い。However, in reality, the length is long enough to form a single crystal in the lateral direction.
First, melt the bath, give one crystal, and the first! ! As shown by lJ, the opening part, which is difficult to remove from the hole, melts and shifts, and the silicon layer 3 on the insulating film 2 does not evaporate and grows laterally due to beam annealing. There are many factors.
〔多61男の目的〕
本発明はこのような点に鑑みてな−4h、たもので積層
集積回路装置を実現5をぜうる良質の単結晶又は粗大結
晶粒多結晶化79体層を得ることを1.′l的とする。[Purpose of the 61st Man] In view of the above points, the present invention realizes a multilayer integrated circuit device using a multilayer integrated circuit device. 1. 'l-like.
本発明では、形成1−1.た半導体層上にれ〜j侯を形
成12、こ伯、をストライプ状に残イjσゼるように選
択エツチング(−て長溝を設け、このiNAに沿っで電
子ビームを走査(7、前記半導体層を単結晶も(7くは
粗大結晶粒多結晶化[7ている。In the present invention, formation 1-1. Form a long groove on the semiconductor layer 12, selectively etching it so that it remains in a stripe shape, and scan the electron beam along this iNA (7, etching the semiconductor layer). The layer can also be a single crystal layer (or coarse grained polycrystalline layer).
〔発明の効シ(1〕
本発明により絶h5ル八土の>pめられた所に良質の半
導体層を形成1.で、素子の積層化を実用上十分な特性
をもたせて実D;、することを可能とすること型(7f
lo )面方位の単結晶シリコンlk板101の上に約
2μmの5IOJG’j 102を形成する。この除ン
リコンfi−101には図示しな“が既に所望″)素子
が11.4知P劇程を経て形成されている。次に第2図
(b)に示すようにSin、層102の表面にたとえば
約600OAの多結晶シリコン層103を被着する。そ
の上に0、5〜1.Ottmの”102FJ 104を
形成する。次に第2図(clに示すようK、周知の方法
にてS i02膜104の一部をストライプ状にエツチ
ング除去する。その後第2図(d)に示すように電子ビ
ーム10を上部から。[Effects of the Invention (1)] According to the present invention, a high-quality semiconductor layer is formed in a place with an absolute value of 1. In 1., it is possible to realize the stacking of elements with practically sufficient characteristics. , type (7f
5IOJG'j 102 having a thickness of about 2 μm is formed on a single crystal silicon lk plate 101 with a lo ) plane orientation. In this removed recon fi-101, a "desired" element (not shown) is formed through 11.4 steps. Next, as shown in FIG. 2(b), a polycrystalline silicon layer 103 of approximately 600 OA, for example, is deposited on the surface of the Sin layer 102. 0, 5-1 on top of that. Next, as shown in FIG. 2 (cl), a part of the Si02 film 104 is etched away in a stripe shape using a well-known method. Thereafter, as shown in FIG. electron beam 10 from above.
上記ストライプに平行に走査しながら照射して上記シリ
コン層103をアニールに再結晶化する。尚、11はビ
ーム走査方向である。The silicon layer 103 is annealed and recrystallized by irradiation while scanning parallel to the stripes. Note that 11 is the beam scanning direction.
本発明の最大の特徴は、第2図(clに示す試料構造、
第2図(dlで示す、111子ビームの特徴を充分に生
かしたアニール法にある。即ち、電子ビームのエネルギ
ーデポジションは電子の物質に対する透過能によっての
み決まっており、第2図(clの構造の試料では810
2 jQがストライプ状に開孔[7ている部分105で
はシリコン層103に大部分の電子ビームエネルギーが
デポジットされるが、それ以外の5in2膜104でお
おわれている部分ではエネルギー吸収が8i02腹中で
も起こるため、シリコン層におに!I)温度分布は第3
図に示すごとく、開孔部105で高く、それ以外でそれ
より低くなる。このよう最後に同化が起こる。従ってア
ニール後の再結晶化時の固液界面は第4図に示すごとく
になる。図に於いて、曲線の左側は同相、右側は液相で
あり、同相・液相界面付近には結晶粒界の発生が示され
ている。The greatest feature of the present invention is the sample structure shown in FIG.
This is an annealing method that takes full advantage of the characteristics of the 111 electron beam, shown in Figure 2 (dl).In other words, the energy deposition of the electron beam is determined only by the ability of the electron to penetrate the material, and as shown in Figure 2 (cl). 810 for structural samples
Most of the electron beam energy is deposited in the silicon layer 103 in the part 105 where 2 jQ is opened in a striped pattern [7], but in the other part covered with the 5in2 film 104, energy absorption also occurs in the 8i02 abdomen. Because of this, the silicon layer is covered! I) Temperature distribution is the third
As shown in the figure, it is high at the opening 105 and lower at other locations. Finally, assimilation occurs. Therefore, the solid-liquid interface during recrystallization after annealing becomes as shown in FIG. In the figure, the left side of the curve is the same phase, and the right side is the liquid phase, and the occurrence of grain boundaries is shown near the same phase/liquid phase interface.
ところで、通常溶融再結晶を自然現象に甘かせて行なう
と多くの核生成が行なわれ多数の結晶粒界が見られるが
、この結晶粒界は固液界面に直交するように連続して結
晶粒成長が起こる。そのため、第4図で示すように8i
02が開口し、ていた部分301では結晶粒界がますま
す集中して多数の結晶粒ができるが、 Sin、でおお
われていた部分では粒界がだんだん分散してゆき、やが
て単結晶ができるようになる。このようにして第2図(
cl工程で形成したストライプ状開口部の周期に合′i
2せた鳴のストライプ状の非常に大きな結晶粒が成長す
る。By the way, when melt recrystallization is carried out without relying on natural phenomena, a lot of nucleation occurs and many grain boundaries are seen, but these grain boundaries are continuous crystal grains perpendicular to the solid-liquid interface. Growth occurs. Therefore, as shown in Figure 4, 8i
In the part 301 where 02 was opened, the grain boundaries became more and more concentrated and a large number of crystal grains were formed, but in the part covered with Sin, the grain boundaries gradually became dispersed, and eventually a single crystal was formed. become. In this way, Figure 2 (
It matches the period of the striped openings formed in the cl process.
Very large crystal grains in the form of two stripes grow.
このようにして電子ビームアニールによりクリ成してゆ
く。素子領域えはゲート酸化膜107を介による電極1
12〜114を形成し、て二層に積層した半導体装置を
完成する。In this way, electron beam annealing is performed to clear the structure. In the element region, the electrode 1 is formed through the gate oxide film 107.
12 to 114 are formed to complete a two-layer stacked semiconductor device.
なお、上記実施例では電子ビームによりシリコン層のア
ニールを行なったが、アニール条件としては加速圧5〜
301<Vで特に10KV以下がよくビーム電流は1〜
lOmAがよいが10Kvでは4mAが最適であった。In the above example, the silicon layer was annealed with an electron beam, but the annealing conditions were an acceleration pressure of 5 to 5.
301<V, especially 10KV or less is good, and the beam current is 1~
1OmA is good, but 4mA was optimal at 10Kv.
真空度はi o’〜10−”Torrで基板温度は40
0〜500℃、シリコン基板を静′rL的にチャッキン
グしてアニールが行なわれた。このような条件での浴接
幅は約50μmであったため、第2図(cjに示すスト
ライプ状溝のピッチの2倍のfilDを50μmとした
。またビームをX方向(ストライプと平行方向)に走査
する時の辿m”は100crrVkC。The degree of vacuum is IO' ~ 10-'' Torr and the substrate temperature is 40
Annealing was performed by statically chucking the silicon substrate at 0 to 500°C. Since the bath contact width under these conditions was approximately 50 μm, filD, which is twice the pitch of the striped grooves shown in Figure 2 (cj), was set to 50 μm. The trace m" during scanning is 100crrVkC.
X方向(ストライプと直交方向)のステ、ツブ送り距離
Pは25μmすなわちP = 1’)/’、2とした。The feed distance P in the X direction (direction perpendicular to the stripes) was 25 μm, that is, P = 1')/', 2.
本発明においては距離りまたはPの決め方も重曹で、D
C−MOS)ランジスタウバイポーラトランジスれらの
素子を積層配列することにより、従来より高集積、高速
、多機能なf+を層半導体装置を実現することが可能と
なった。In the present invention, the distance or P is determined using baking soda.
(C-MOS) Langstau Bipolar Transistor By arranging these elements in a stacked manner, it has become possible to realize an f+ layer semiconductor device that is more highly integrated, faster, and has more functions than before.
本発明による効果を用いれば、シリコン以外の半導体た
とえばゲルマニウム+ GaAs 、 GaP J h
るいはlnP 、 In5t)などの種々の半導体にお
いても充分な効果が期待できる。By using the effects of the present invention, semiconductors other than silicon, such as germanium + GaAs, GaP J h
Sufficient effects can also be expected in various semiconductors such as InP, In5t, and the like.
第1図はエネルギービーム照射によるLE8B構造の単
結晶膜の形成過程を説明する断面図、第2図(a)〜(
f)はこの発明による半纏体膜を用いて行なった二jd
MO8LsI製造工程を示す工程断面図、第3図は本発
明による電子ビームアニール時の試料の温度分布を示す
特性図、第4図は半導体膜のアニールによって溶融径再
結晶する時の固液界面を示す図である。
1・・・半導体基板、 2・・・絶縁膜、3・・・半
導体層、 4・・・エネルギービーム、101・・
・単結晶シリコン基板、 102・・・8402膜、1
03・ 多結晶シリコン層、 104 ・・S r
02膜、103′・・・再結晶化したシリコン層、10
5・・・開口部、 107・・・ゲート酸化膜、1
06・・・絶縁膜、 108・・・ゲート電極、1
09.110・・・ソース、ドレイン領域、111・・
・絶縁族% 112〜114・・・AI電極。
出願人 工業技術院長 石 坂 誠 −第1図
(仄2
(C〕
第2図
第2図
i
第2図Figure 1 is a cross-sectional view explaining the formation process of a single crystal film with an LE8B structure by energy beam irradiation, and Figures 2 (a) to (
f) was carried out using the semi-enveloped membrane according to the present invention.
FIG. 3 is a process cross-sectional view showing the MO8LsI manufacturing process, FIG. 3 is a characteristic diagram showing the temperature distribution of a sample during electron beam annealing according to the present invention, and FIG. 4 is a solid-liquid interface when the semiconductor film is annealed to recrystallize the melt diameter. FIG. DESCRIPTION OF SYMBOLS 1... Semiconductor substrate, 2... Insulating film, 3... Semiconductor layer, 4... Energy beam, 101...
・Single crystal silicon substrate, 102...8402 film, 1
03. Polycrystalline silicon layer, 104...S r
02 film, 103'... recrystallized silicon layer, 10
5... Opening portion, 107... Gate oxide film, 1
06... Insulating film, 108... Gate electrode, 1
09.110...source, drain region, 111...
- Insulating group% 112-114...AI electrode. Applicant Makoto Ishizaka, Director General of the Agency of Industrial Science and Technology - Figure 1 (2 (C)) Figure 2 Figure 2 i Figure 2
Claims (1)
程と、前記半導体層上に薄膜を形成しさらにこの薄膜を
ストライプ状に残存させるように選択エツチングして長
溝を設ける工程と、前記長溝に沿って電子ビームを走査
し前記半導体層を単結晶もしくは粗大結晶粒多結晶化さ
せる工程とから成る半導体膜形成方法。a step of depositing a polycrystalline or amorphous semiconductor layer on a substrate; a step of forming a thin film on the semiconductor layer and selectively etching the thin film so as to remain in a stripe shape to form long grooves; A method for forming a semiconductor film comprising the step of scanning an electron beam along a long groove to convert the semiconductor layer into a single crystal or coarse grain polycrystal.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57143995A JPS5934626A (en) | 1982-08-21 | 1982-08-21 | Method for formation of semiconductor film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57143995A JPS5934626A (en) | 1982-08-21 | 1982-08-21 | Method for formation of semiconductor film |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5934626A true JPS5934626A (en) | 1984-02-25 |
JPH0368532B2 JPH0368532B2 (en) | 1991-10-28 |
Family
ID=15351858
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57143995A Granted JPS5934626A (en) | 1982-08-21 | 1982-08-21 | Method for formation of semiconductor film |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5934626A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0141506A2 (en) * | 1983-09-12 | 1985-05-15 | AT&T Corp. | Method for producing a semiconductor structure |
JPS63300510A (en) * | 1987-05-30 | 1988-12-07 | Agency Of Ind Science & Technol | Laminated semiconductor device |
JP2008136406A (en) * | 2006-11-30 | 2008-06-19 | Daiwa Seiko Inc | Fishing bag |
-
1982
- 1982-08-21 JP JP57143995A patent/JPS5934626A/en active Granted
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0141506A2 (en) * | 1983-09-12 | 1985-05-15 | AT&T Corp. | Method for producing a semiconductor structure |
JPS63300510A (en) * | 1987-05-30 | 1988-12-07 | Agency Of Ind Science & Technol | Laminated semiconductor device |
JP2008136406A (en) * | 2006-11-30 | 2008-06-19 | Daiwa Seiko Inc | Fishing bag |
Also Published As
Publication number | Publication date |
---|---|
JPH0368532B2 (en) | 1991-10-28 |
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