JPS5929194A - Heat-sensitive recording paper - Google Patents
Heat-sensitive recording paperInfo
- Publication number
- JPS5929194A JPS5929194A JP57138338A JP13833882A JPS5929194A JP S5929194 A JPS5929194 A JP S5929194A JP 57138338 A JP57138338 A JP 57138338A JP 13833882 A JP13833882 A JP 13833882A JP S5929194 A JPS5929194 A JP S5929194A
- Authority
- JP
- Japan
- Prior art keywords
- recording paper
- heat
- color
- pref
- sensitive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/423—Intermediate, backcoat, or covering layers characterised by non-macromolecular compounds, e.g. waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は感熱記録紙に関し、特に各種薬品、油による記
録像の消色及び地のカブリ’ｃ防止した感熱記録紙に関
するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a thermal recording paper, and more particularly to a thermal recording paper which prevents decoloring of recorded images and fogging of the background due to various chemicals and oils.
感熱記録紙とは、熱エネルギーによる物質の物理的、化
学的変化を利用して画像を得るもので非當に多くのプロ
セスが研究されている。Thermosensitive recording paper is a paper that obtains images by utilizing physical and chemical changes in substances caused by thermal energy, and an extremely large number of processes are being studied.
最近、感熱記録紙が一次発色であること、功、像ユニ稈
が不要であること等の特長を生かし、ファクシミリ用の
アウトプット、コンピュータ用のアウトプット、配録紙
として用いられるようになっている。これらは、染料タ
イプと呼ばれるもので、特公昭η３−グ／６−θ号、特
公昭１．／−ｊ−／弘０３り号、特開昭３５−．２７．
２Ｊ３号等に開示されている。Recently, thermal recording paper has come to be used for facsimile output, computer output, and recording paper, taking advantage of its features such as primary color development and no need for an image culm. There is. These are called dye types, such as Tokuko Sho η3-g/6-θ, Tokko Sho 1. /-j-/Hiro 03rd issue, JP-A-1973-. 27.
2J3, etc.
一般に感熱記録紙を記録用紙として用いた場合記録装置
が軽量、小型化できる利点があり、近来急速に利用され
るようになってきた。一方、感熱記録紙の欠点として、
各種薬品または、油等が付着した場合記録像が消色した
り、カブリが生ずることが挙げられる。これらの欠点は
実用−］ン重犬な問題であり、改良が望チれている。In general, when thermosensitive recording paper is used as recording paper, it has the advantage that recording apparatuses can be made lighter and smaller, and its use has been rapidly increasing in recent years. On the other hand, as a disadvantage of thermal recording paper,
If various chemicals or oils are attached, the recorded image may be discolored or fog may occur. These drawbacks are serious problems in practical use, and improvements are desired.
実開昭５ｔ−ｉ、ｚｓＪｓａ号では、感熱発色層上に水
溶性高分子化合物の被饅層を設は可塑剤の浸透を防止し
可塑剤に対する耐消色性を向Ｊ−することが提案されて
いる。In Utility Model Application Publication No. 5t-i and zsJsa, it was proposed that a layer of a water-soluble polymer compound to be absorbed by a water-soluble polymer compound should be provided on the heat-sensitive coloring layer to prevent the penetration of plasticizers and improve the discoloration resistance against plasticizers. ing.
凍た特開昭ｊ［−／ｌｌ−１，７９ｕ号では水溶性高分
子化合物を更に疎水性高分子化合物及び／又ｅ」、面１
水化剤を含有した被偵層を設置ｔｊ可塑剤に対する耐消
色性に町に耐水性金（；Ｊ与させることが提案されてい
る。しかしこれらの方法では各種薬品捷たは油智に対−
１＃−る耐性が不十分である。In Frozen JP-A-J [-/ll-1, 79u, a water-soluble polymer compound is further added to a hydrophobic polymer compound and/or a hydrophobic polymer compound and/or e'', surface 1.
It has been proposed to install a coating layer containing a water softening agent to provide water resistance to plasticizers. −
1# - resistance is insufficient.
本発明の目的は、各種薬品才たは油等に対して十分な剛
性を有−する感熱記録紙を提供することである。An object of the present invention is to provide a heat-sensitive recording paper that has sufficient rigidity against various chemicals, oils, and the like.
上記の本発明の目的は、ｔ１丁無色の電子供力性染料と
、核染料と接触して呈色するＭ機酸とを発色成分として
含有する感熱発色層の上にポリヒドロキシ化合物とフッ
素糸界面活性ハ１ｊを含有する被偵層を設けたことを特
徴と′Ｔる感熱記録紙により達成さ〕１、た。The object of the present invention is to coat a polyhydroxy compound and a fluorine thread on a heat-sensitive coloring layer containing as coloring components a colorless electrodynamic dye and a M organic acid that develops color when it comes into contact with a nuclear dye. This was achieved with a thermosensitive recording paper characterized by providing a recording layer containing a surface active compound.
本発明の被覆層中に用いられるフッ素系界面活性剤、！
＝ １ノ［ｔマ、＋１１ハーフルメ和アルキル燐酸ｘ
ｙ。The fluorosurfactant used in the coating layer of the present invention!
= 1 no [t ma, +11 half full alkyl phosphoric acid x
y.
デル、＋２）バーフルオロアルギルスルホンＡｌｌ、（
３１パ一フルオロアルキルカルホン酸Ｊｍ、（ｌパーフ
ル：Ａロアルギルエブ用／ンｊキシド伺カ（Ｊ物、（！
”ｉ、ｌ／ｌ−フルオロアルキルトリメチルアンモニウ
ム塩などが挙げられる、
本発明に用いられる（１）〜（５）のフッ素系ｆｆ面活
性剤の中好ましいものを−ａ式で示ｒと、−すれぞれ一
般式［ＩＪ〜しＶ」で表ゎさｉ＋、る。del, +2) barfluoroargylsulfone All, (
(!)
Among the fluorine-based FF surfactants (1) to (5) used in the present invention, preferred ones are represented by the formula -a, including ``i, l/l-fluoroalkyltrimethylammonium salts, and the like. Each is represented by the general formula [IJ~shiV].
但し、Ｆ−Ｆｔｔ２一般式の、Ｉもｆは炭素数、７〜．
７！３の・ξ−フルオロアルキル基、１（・け水素せ７
こは炭素数／〜乙のアルキル基、Ｘは水嵩、Ｎａ、に、
またはＮＨ４、’Ｉ” Ｏ，’ Ｎ ａ−１またハ１〈
を”ＩＳ＜ ワーｊ式中、ｎθ、２〜／Ｑの整数′ぐあ
る
Ｒ、（−（ＧＨｚ）ｎ −８Ｏ３Ｙ ＣＩ
Ｉ 、Ｊ式中、ｎ ｉ’Ｊ’、 Ｏｆだ／〜／Ｑの整数
である１も
式中、ＩＩは／〜１０の整数である
１１゜
式中、ＩＩはＪ−コθの整数である
Ｉｔ、１ｓＯ２−Ｎ−（１２）、Ｎ（（Ｊ１３）３１
［Ｖ）１を
式中、１１はλ〜１０の整数である。However, in the general formula F-Ftt2, I and f are carbon numbers, 7 to .
7!3's ・ξ-fluoroalkyl group, 1(・sulfuride 7
This is the number of carbon atoms / ~ B alkyl group, X is the water volume, Na,
Or NH4, 'I'' O, ' Na-1 or Ha1〈
IS
In the I, J formula, n i'J', Of/1, which is an integer of /~/Q, is also in the formula, II is an integer of /~10, 11° In the formula, II is an integer of J-coθ It, 1sO2-N-(12), N((J13)31
[V) In the formula 1, 11 is an integer from λ to 10.
本発明に用いらｈるフッ素系界面活性剤ｔ、！、水にダ
Ｊする溶解１隻が７以上であるものが被情層を形成する
上“Ｔ：ρｆ−ましい。Fluorine surfactant used in the present invention! , those who have 7 or more melts in water form the favored class.
本発明に用いられるフッ素系宜面活性剤のうち、各種薬
品、油等に対する耐性の点で・？−フル７１０アＩＩヤ
ル堝酸エステルが好ましい。Among the fluorine-based surfactants used in the present invention, which ones have the following characteristics in terms of resistance to various chemicals, oils, etc.? -Full 710A II carbonic acid ester is preferred.
本発明に用いられるパーフルオロアルキル燐酸丁りヌル
の−Ａ体例を例示する。し刀・しこノＬＫのみ本発明の
被覆層中に用いられるポリヒドロキシ化合物Ｃ」水酸基
をイーする水溶性高分子であシ、具体例としてはポリビ
ニルアルコール、メチル士ルロース、ヒトｒｆｆキシエ
チルセルロース、ヒドロキシツロビルセルロース、カル
ボ虎ジメチルセルロース、デンプン デンプンｈ−シ導
体などが挙げられる。An example of -A isomer of perfluoroalkyl phosphoric acid dinull used in the present invention is illustrated. The polyhydroxy compound C used in the coating layer of the present invention only for Shito/Shikono LK is a water-soluble polymer containing hydroxyl groups, specific examples include polyvinyl alcohol, methyl sululose, human RFF xyethyl cellulose, Examples include hydroxytulobil cellulose, carbo-dimethyl cellulose, starch h-h-cy conductor, and the like.
本３１チ明に用いられるポリ上１０ギシ化合物としでは
７１サリヒ′ニルアルコーノ１が次子−ましい。牛九ｒ
（クン化瓜が９０−１−ルチ以」二であり、がっ重合瓜
が１０００以−Ｌのポリヒ、−ルアルコールが好ましい
。Among the polyhydric compounds used in the present invention, 71 salinylalcono-1 is the second most preferred. Cow Niner
(Polyhyperalcohols having a weight of 90-1 or more and a weight of 1,000 or more for polymerized melon are preferred.
本発明のフッ素糸を゛ｒ面活性剤の使用に＆Ｊ、 ｄ’
リヒト’ ｏキシｆｔ、イ１物／θＯＪ代−６１部に
対して／〜？θ重ｈ；部、好まし、くは３〜．２０沌ｆ
ｔ；： Ｒｌｉである。The fluorine thread of the present invention is used as a surfactant &J, d'
Licht' oxyft, I1 thing/θOJ price -61 parts/~? θ weight h; parts, preferably 3 to . 20 chaos f
t;: Rli.
本発明の１１ｙ〜層中ｉＣはさらに材製に応じ、ポルマ
リン、グリ刊キリ゛−ル、メラミン樹脂、尿素な・１１
ｊ１１、ポリアミド樹脂、ポリアミドーエビク「コルヒ
ドリン樹脂などの配水化剤まＺｃｌｔまポウｈ（、ホウ
砂などのグル化剤を／Ｉ１１え−Ｃも良い。The 11y to iC in the layer of the present invention can be further modified depending on the material, such as 11y, polymeric resin, melamine resin, urea, etc.
J11, polyamide resin, polyamide resin, water distributing agent such as colhydrin resin, or gluing agent such as borax may also be used.
本梶明Ｑユ前自己のポリヒト【ゴギン化合′吻とフッ素
系界面活性剤’Ｌ ？’； ４１ ’ｊ’る被覆層塗液
を・哄幣し、以下で述べる感熱発色層上に塗布、り１′
／、燥し目的とする被覆層とＩる。Akira Honkaji Q Yu's own polyhuman [Goggin compound's proboscis and fluorine surfactant'L? '; 41 Sprinkle the coating layer coating liquid and apply it on the heat-sensitive coloring layer described below.
/, dried to form the desired coating layer.
次に本発明の感熱゛発色層についこ説明する。Next, the heat-sensitive coloring layer of the present invention will be explained in detail.
本’ｉＩ′ｉ門に用いられる「１７．了（ｊ（、り性染
刺は、代表的なものとじて、（１）トリアリールメタン
系、（２）ジフェニルメタン系、（３）キーリーン−フ
ン系、（４）デアジン系、（５ｊスピロピラン系化合物
なとがあＱ、具体的な例とじてに［、特開昭３３−Ｊ、
７２．３３号等に記載されているもの等があげられる。Typical dyes used in this category include (1) triarylmethane, (2) diphenylmethane, and (3) Keelin-Fun. system, (4) deazine system, (5j spiropyran system compound Natoga Q, specific examples [, JP-A-1973-J,
Examples include those described in No. 72.33.
本珀明に使用される有機ｒ’ｌＢ： ＆ しては、フェ
ノーノ１−誘導体、芳ｔｘ’ ）ｐＪ：カルボン酸誘男
１体が幻贅し７く、ｌｈにビスツー［ノール類が好せし
い。具体的にＣ」１、フェノ−／Ｌ ｆＨ自とし−Ｃ，
ｐ−オクブールノエノール、ρ−ｔ ｅ ｒ ｔ−プラ
スしフェノール、１．１− フエ：ルフ：［ノール、／
、／−ビス（１）−ヒ［ロキシフェニル）ノ１７ ノ’
：ン、２１．２−ヒス（ｐ−ヒト゛ロキシフェニル）ソ
ロノξン、／ｌ／−ヒス（ｐ−ヒドロキシフェニル）ヘ
ンタン、／、／−ヒス（ｐ−ヒドロ！Ｖシフエ、−ル）
ヘキシン、！１．２−ビス（ｐ−ヒドロキシフェニル）
ヘキシン、／、／−ヒス（ｐ−ｅ ト＋：＋ ＊シフェ
ニルンーλ−エチノし一ヘキザン、λ、コノ−ス（４Ｉ
−ヒドロキシ−３，Ｊ−ジクロし１フエニル）ノロ・ξ
ンなどがあげられる。Organic r'lB used in the present invention: & is a phenol derivative, aromatic tx') pJ: carboxylic acid derivative is a phantom, and lh is a bistwo [nols are preferred. Yes. Specifically, C'1, pheno-/L fH itself-C,
/
, /-bis(1)-hy[roxyphenyl)no17no'
:-n, 21.2-his(p-hydroxyphenyl)solonξn, /l/-his(p-hydroxyphenyl)hentane, /, /-his(p-hydro!Vsihue,-l)
Hexin! 1.2-bis(p-hydroxyphenyl)
hexane, /, /-his (p-e t+:+
-Hydroxy-3,J-dichloro-1 phenyl)
Examples include:
芳香族カルボン′ｈｐ言含ンｕ体としては、ｐ−ヒドロ
キシ安息香酸べ〕・′ジル、Ｉ’−ヒ１゛ロギシに３息
香酸エチル、［）−ヒドロキシ安偲、香酸ブチル、３．
、ｔ−ジーｔｅｒｌ−グチルーシ゛リナル７ｐ、３．ｓ
−ジーα−メカルベンジルリーリチルｒ１更及びカル十
ン酸に卦いては仁れらの９′７価金朗扇などがあげられ
る。Aromatic carbon'hp-containing u forms include p-hydroxybenzoic acid benzyl, I'-hydroxybenzoic acid, ethyl trizoate, [)-hydroxybenzoic acid, butyl fragrant, ．．
, t-terl-glucinal 7p, 3. s
-D-alpha-mecarbenzyl lyrityl r1 and cardecanoic acid include Nire et al.'s 9'7-valent Kinrousen.
感熱発色記録紙用塗故金製造−ノ゛る際には、−ｔ：
ＭＬのような感熱記録Ａ４（用？ｒ白色素利ケ水を６月
ｉＱ媒として分子ＦＱ ’Ｔることが材間Ｃある。この
時、ポリビニ刀・アル：７−）へ ヒト＋１■−ｔシー
Ｌチル土几ロース、テンプン訪専体等の水浴注高分イ全
便用Ｊるこ／、が好せしい。これらの分散媒を用いた感
１ゆ〜ｉＩコ録Ａ」料用発色素拐の分１４′シ方法ｆ、
ｊ１、一般に７７重ｂｉ−”−ヒントから／ ０ ：ｊ
（ｊ編パーにノド、さらに幻ましく ｔ」１１、！重…
″パーセントがらｊ取量）９−ヒントの水溶性重分イに
者、１４１〜た勺敗媒に対し、「１１（与性染料凍たは
、４１機酸を１０重″垣バーセットがらＳＯ重紹）ξ−
セント投入Ｌ７、ボールミル、ツ”ノドミル、７１−ラ
・イタ、コロイドミル等の分散機により分散をｒＪ′う
、。Production of coated gold for heat-sensitive color recording paper--t:
ML-like heat-sensitive record A4 (use?r White dye utilization water as a June iQ medium can be used as a molecular FQ'T. At this time, polyvinyl sword Al: 7-) to human +1 ■- It is preferable to use Jruco for all meals, such as t sea L chilled loin, starch soup, etc. Using these dispersion media, method f,
j1, generally from 77 double bi-”-hint/0:j
(J edition par and throat, even more fantastic t" 11,! heavy...
9-Hint's water-soluble heavy fraction, 141 to 100% of the defeating medium, 11 (donative dye frozen or 41 organic acid to 10-weight bar set) SO Heavy introduction) ξ−
Dispersion is carried out using a dispersing machine such as a cent input L7, a ball mill, a Tsunodo mill, a 71-La Ita, or a colloid mill.
１： ｉｎ３の分故薦を／１危合１２だものに、さらに
必要に応じ吸油１′１：順相、ワックス類、金属石ケン
等を加え感熱発１”’ｌ ＭＬｊ録紙用紙用塗液−１紙
、プラスデック等の支持体−１−に塗布して、１−４的
の感熱発色層を得る。1: Recommend the separation of in3 to /1 danger 12, and add oil absorption as necessary. Liquid 1 is coated on a support 1 such as paper or Plus Deck to obtain a thermosensitive coloring layer of 1 to 4.
以ド′１！施ｌ＋ｌＩ金示ｒが本光明を」、これに限ｚ
１されるもの−ｃ ＆、Ｉ、ない。More than 1! This is the only thing that will bring you enlightenment.
1 to be done-c &, I, not.
夷ノ１ｆｉｉ １やり」
３−シシゴーチルｒミノ−４−り１］ロー７− （β−
工） ；１シエ、ｆ−ル）アミノフルオラン、２０７学
／Ｑチボ′リビールアルコール（クン化度９ｇ％市合度
、ｔ ｏ ｏ ）水溶液１００ｆとともに３００ ｍｌ
ボールミル中−で−・Ａｒ−夜分赦し分散液（Ａ）を得
た１、同様にλ。Ii no 1fii 1 yari" 3-shishigochirmino-4-ri1] low 7- (β-
300 ml with 100f of aqueous solution
In a ball mill, an Ar aqueous dispersion (A) was obtained, similarly to λ.
−一ビス（ケー ヒドロギンフ′［−ニル）ツロノミン
１０ｖとス１−ノリン酸アミ１′／θ２を１０％、４４
’ ＩＪビニルアルコール水浴ａ々１ｏｏｙとともに３
００ ｍ／ボールミル中で／昼孜分散し分散液αりを得
た。-10v of bis(K-hydroginph'[-nyl)turonomine and 10% of s-1-nolinic acid amide 1'/θ2, 44
'IJ vinyl alcohol bath a1ooy with 3
00 m/in a ball mill/hitsuko to obtain a dispersion liquid.
分数前（Ａ）、分散液の）を３：コＯの庫縁比で混合し
、さらに混合液２００？に対し、ｒｏｙの炭酸力ルシウ
ノ、微粉末を添加、十分に分数させて感熱発色層塗液と
ｔ、ｆｒＯ，。A fraction (A) of the dispersion liquid was mixed at a ratio of 3:0 to 0, and then the mixed liquid was further mixed at a ratio of 200? To this, add Roy's carbonic acid fine powder, make it into a sufficient fraction, and apply it to the heat-sensitive coloring layer coating solution.
この感熱・竜色層倹液をＪＯＹ／ｍ２のｊイＰａ螢有゛
Ｊる原紙」二に固ｊヒ分″′ｃ６ｙ／ｍ２の塗布絽が得
られる。Ｌうエアー−Ｊイフで塗布し、！θ°（゛λ分
間乾燥し５．１１冬熱発色層を形成した。This heat-sensitive, dragon-colored layer solution is coated on JOY/m2 of base paper with a hard coating of JOY/m2. ,!θ°(゛λ minutes) to form a 5.11 winter thermal coloring layer.
この感熱帖色層−１，−に以下の配合力・ら成る被覆層
塗液を固型イＪで３Ｙ／ｍ２の塗布肯が得られるよう塗
布［−１５０°（ノコ分間乾燥（−゛Ｃ加情］〜を形成
し、本発す１］の感熱、ｉ１シヒ紙を得た。To this heat-sensitive paper color layer -1,-, apply a coating liquid consisting of the following compounding strength to obtain a coating rate of 3Y/m2 using a solid IJ [-150° (drying with a saw for a minute (-゛C) The heat-sensitive paper of 1] was formed and produced.
〔被慴層塗Ｙ（υＪ
６′係ポリビニルｊ” １１＝１−ル（クン化１＆ ｙ
ｇ％、ｉ％曾１ｆ４： ／ ７００ ）水溶液・・・
・・・７００重Ｍ部、７幅パー ７月、７１ＩＪノ′ノ
ＩＡ）Ｌ−燐酸エス１月・（化合物ｆｆ！Ｉ（１））
水溶液・・・・・・ ４１０車編部実り市１「
す２
実＃＋ｊ Ｉ（・ＩＪ Ｉのし被覆層塗液〕の一２チノ
髪−フルオロブールキル燐酸ニスデル水溶液の使用Ｒｆ
ｆ：／（１’重謝部にする他は実施例１と同様にして感
熱記録紙を得た。[Painted layer coating Y (υJ 6' polyvinyl
g%, i% 1f4: / 700) Aqueous solution...
...700 weight M parts, 7 width par July, 71IJNO'NOIA) L-phosphoric acid S January (compound ff! I (1))
Aqueous solution... 410 Car Edition Department Mariichi 1
2 Fruit #+j I (・IJ I Noshi Coating Layer Coating Solution) 12 Chino Hair - Use of Nisdel Fluorobourkyl Phosphate Aqueous Solution Rf
f:/(1' Thermal recording paper was obtained in the same manner as in Example 1 except that the 1'-grained portion was changed.
実施例３
実施例１の〔被）′＃層塗液〕のｇ係ポリビニルアルコ
ール（クン化度１１、重合度／ ７０ ｔ、四水溶液の
代わりにｌＩ係ヒドロキシニブルセルロース水浴液を用
いる他は実施例１と同様にして感熱記録紙を得た。Example 3 The same procedure was carried out except that a Group G polyvinyl alcohol (degree of oxidation 11, degree of polymerization/70 t, and Group II hydroxynibble cellulose water bath solution was used in place of the aqueous solution of Example 1) in the coating liquid for layer #1. A thermosensitive recording paper was obtained in the same manner as in Example 1.
比較例１
実施例においで、被覆層を設けない他は同様にし゛Ｃ比
軸用の感熱記録紙を例だ。Comparative Example 1 A thermosensitive recording paper for C ratio axis was used in the same manner as in the example except that the coating layer was not provided.
比較例２
実施例におい工、僚機層を以下の被挿ｌ曽塗液で形成゛
１−る他は同様にして比軟用の感〃（記録紙金得た。Comparative Example 2 A recording paper with a soft odor was obtained in the same manner as in the example except that the odor layer and wingman layer were formed using the following coating liquid.
〔被棲層＠液」
ｔチボリヒニルアルＪ−ル（り−ン化度９ざ悌、Ｍ会度
／ ７００ ）水溶液
比較試験
実施例及び比較例で４４１られた感熱記録紙の比較実験
は次のように行なった。[Covering layer@Liquid] Tiborinyl Al J-L (Rinization degree: 9 degrees, M degree: 700) Aqueous solution comparative test The comparative experiment of the thermal recording paper carried out in 441 Examples and Comparative Examples is as follows. I went to
（１） カブリ及び発色性
主走査ｊドツト／喘、副走査６ドツ）／ｍの密度で、ｊ
ｍｓ／ドツト、５ｏｓｎＪ／ｍ２のエネルギーを記録素
子に力えて記録を行い、マクベスＩＬＩ）−ｓ／ａ型反
射ｆＩ＃度計（ビジュアルフィルター使用）によってカ
ブリ（記録前の地の濃度）及び記録後の発色体濃度（初
期濃度）を測定した１、
（２）各■１薬品、油に対する耐性ツースト発色性ツー
ストで得られ／こ発色体上に、各種薬品、油を約０．３
μｍの厚味になるように塗布し１．２ｊ ０Ｃ１几）１
乙ｊ係の雰囲気中に一２ｑ時間放置（７た後、カブリ（
地の４１及びつら包体濃度ヶ側足した。(1) Fog and color development Main scanning dots / m, sub-scanning 6 dots)/m,
Recording is performed by applying energy of ms/dot and 5osnJ/m2 to the recording element, and the fog (density of the ground before recording) and after recording are measured using a Macbeth ILI)-S/A type reflection fI# meter (using a visual filter). The concentration (initial concentration) of the chromophore was measured.1, (2) Resistance to 1 drug and oil each
Apply to a thickness of 1.2j 0C1)1
Leave it in the atmosphere for 12 hours (after 7 hours, it will fog (
41 of the land and the icicle body concentration were added.
比較試験の結果を第１岩に示す。The results of the comparative test are shown in the first rock.
」−記の９−、Ｌｌ、本発明の感熱記録紙ｔ」１、比較
用感熱記録紙に比べ、発色体の各１４Ｍ 薬品、油によ
る消色が少なく、刀・つ、カブリの点でも優〕１．てい
ることがわかる、。"-9-, Ll, Thermal recording paper of the present invention" 1. Compared to the comparative thermal recording paper, it has 14M of each coloring body. It is less likely to be discolored by chemicals and oil, and is also superior in terms of sharpness and fog. ]1. I can see that.
Claims (1)
触して呈色ノる有機酸とを発色成分として含有する感熱
発色層の上にポリヒドロキシ化合物とフッ素系界面活性
剤を含イ１する被情層を設りたことを特徴とする感熱記
録紙。 ２ 該フッ素系界面活性剤の水に対する溶解度が／以Ｆ
であることを特徴とする特許請求の範囲第１項記載の感
熱記録紙。 ３ 該フッ素系界面活性剤がパーフル調ロアルキル燐酸
エステルであることを特徴とする特許請求の範囲第１項
記載の感熱記録紙８[Claims] 1 #l#? A coating containing a polyhydroxy compound and a fluorine-containing surfactant is placed on a heat-sensitive coloring layer containing a colorless electrophoretic dye and an organic acid that develops a color when it comes into contact with the dye as a coloring component. A thermal recording paper that is characterized by having an emotional layer. 2 The solubility of the fluorosurfactant in water is / or less
The thermosensitive recording paper according to claim 1, characterized in that: 3. Thermal recording paper 8 according to claim 1, characterized in that the fluorine-based surfactant is a purpurine-like loalkyl phosphate ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57138338A JPS5929194A (en) | 1982-08-09 | 1982-08-09 | Heat-sensitive recording paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57138338A JPS5929194A (en) | 1982-08-09 | 1982-08-09 | Heat-sensitive recording paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5929194A true JPS5929194A (en) | 1984-02-16 |
| JPH0443796B2 JPH0443796B2 (en) | 1992-07-17 |
Family
ID=15219573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57138338A Granted JPS5929194A (en) | 1982-08-09 | 1982-08-09 | Heat-sensitive recording paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5929194A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6111285A (en) * | 1984-06-28 | 1986-01-18 | Fuji Photo Film Co Ltd | Heat-sensitive recording paper |
| JPS6195985A (en) * | 1984-10-18 | 1986-05-14 | Mitsubishi Paper Mills Ltd | heat sensitive recording sheet |
| JPS61123586A (en) * | 1984-11-20 | 1986-06-11 | Ricoh Co Ltd | Heat sensitive recording material |
| JPH02220887A (en) * | 1989-02-23 | 1990-09-04 | Dainippon Ink & Chem Inc | Resin composition for thermal recording medium and thermal recording medium overcoat |
| JPH03504140A (en) * | 1988-12-27 | 1991-09-12 | カーギル・インコーポレーテッド | Blocked isocyanate and its manufacturing method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5385787A (en) * | 1976-12-30 | 1978-07-28 | Ciba Geigy Ag | Method of improving fluorinated surfactant |
| JPS53149880A (en) * | 1977-06-03 | 1978-12-27 | Dainippon Ink & Chem Inc | Fluorocarbon emulsion |
| JPS56126193A (en) * | 1980-03-11 | 1981-10-02 | Ricoh Co Ltd | Heat-sensitive recording material |
| JPS56146795A (en) * | 1980-04-17 | 1981-11-14 | Ricoh Co Ltd | Heat sensitive recording material |
| JPS56146794A (en) * | 1980-04-17 | 1981-11-14 | Ricoh Co Ltd | Heat sensitive recording material |
| JPS57107884A (en) * | 1980-12-25 | 1982-07-05 | Oji Paper Co Ltd | Thermal recording sheet |
-
1982
- 1982-08-09 JP JP57138338A patent/JPS5929194A/en active Granted
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5385787A (en) * | 1976-12-30 | 1978-07-28 | Ciba Geigy Ag | Method of improving fluorinated surfactant |
| JPS53149880A (en) * | 1977-06-03 | 1978-12-27 | Dainippon Ink & Chem Inc | Fluorocarbon emulsion |
| JPS56126193A (en) * | 1980-03-11 | 1981-10-02 | Ricoh Co Ltd | Heat-sensitive recording material |
| JPS56146795A (en) * | 1980-04-17 | 1981-11-14 | Ricoh Co Ltd | Heat sensitive recording material |
| JPS56146794A (en) * | 1980-04-17 | 1981-11-14 | Ricoh Co Ltd | Heat sensitive recording material |
| JPS57107884A (en) * | 1980-12-25 | 1982-07-05 | Oji Paper Co Ltd | Thermal recording sheet |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6111285A (en) * | 1984-06-28 | 1986-01-18 | Fuji Photo Film Co Ltd | Heat-sensitive recording paper |
| JPS6195985A (en) * | 1984-10-18 | 1986-05-14 | Mitsubishi Paper Mills Ltd | heat sensitive recording sheet |
| JPH0444593B2 (en) * | 1984-10-18 | 1992-07-22 | Mitsubishi Paper Mills Ltd | |
| JPS61123586A (en) * | 1984-11-20 | 1986-06-11 | Ricoh Co Ltd | Heat sensitive recording material |
| JPH03504140A (en) * | 1988-12-27 | 1991-09-12 | カーギル・インコーポレーテッド | Blocked isocyanate and its manufacturing method |
| JPH02220887A (en) * | 1989-02-23 | 1990-09-04 | Dainippon Ink & Chem Inc | Resin composition for thermal recording medium and thermal recording medium overcoat |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0443796B2 (en) | 1992-07-17 |
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