JPS582275B2 - デンカイホウホウ オヨビ デンカイソウ - Google Patents
デンカイホウホウ オヨビ デンカイソウInfo
- Publication number
- JPS582275B2 JPS582275B2 JP48116402A JP11640273A JPS582275B2 JP S582275 B2 JPS582275 B2 JP S582275B2 JP 48116402 A JP48116402 A JP 48116402A JP 11640273 A JP11640273 A JP 11640273A JP S582275 B2 JPS582275 B2 JP S582275B2
- Authority
- JP
- Japan
- Prior art keywords
- anode
- chlorine
- mercury
- membrane
- anolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 101
- 229910052753 mercury Inorganic materials 0.000 claims description 99
- 239000012528 membrane Substances 0.000 claims description 95
- 239000000460 chlorine Substances 0.000 claims description 88
- 229910052801 chlorine Inorganic materials 0.000 claims description 88
- 238000000034 method Methods 0.000 claims description 62
- 229910052751 metal Inorganic materials 0.000 claims description 53
- 239000002184 metal Substances 0.000 claims description 53
- 239000002131 composite material Substances 0.000 claims description 47
- 239000000243 solution Substances 0.000 claims description 35
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 31
- 229910002804 graphite Inorganic materials 0.000 claims description 31
- 239000010439 graphite Substances 0.000 claims description 31
- 229920005597 polymer membrane Polymers 0.000 claims description 26
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 16
- 239000011734 sodium Substances 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 13
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims description 13
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 7
- 229920002313 fluoropolymer Polymers 0.000 claims description 6
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 5
- 229910001414 potassium ion Inorganic materials 0.000 claims description 5
- 229910001415 sodium ion Inorganic materials 0.000 claims description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 114
- 210000004027 cell Anatomy 0.000 description 108
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 61
- 239000012267 brine Substances 0.000 description 60
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 60
- 239000003518 caustics Substances 0.000 description 57
- 239000001257 hydrogen Substances 0.000 description 52
- 229910052739 hydrogen Inorganic materials 0.000 description 52
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 51
- 235000002639 sodium chloride Nutrition 0.000 description 43
- 239000007788 liquid Substances 0.000 description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 41
- 229910001868 water Inorganic materials 0.000 description 38
- 238000005868 electrolysis reaction Methods 0.000 description 31
- 239000004020 conductor Substances 0.000 description 29
- 150000003839 salts Chemical class 0.000 description 29
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 24
- 235000011121 sodium hydroxide Nutrition 0.000 description 21
- 239000003792 electrolyte Substances 0.000 description 19
- 229920000642 polymer Polymers 0.000 description 19
- 239000000463 material Substances 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 17
- 239000007789 gas Substances 0.000 description 16
- -1 hydroxyl ions Chemical class 0.000 description 13
- 239000011780 sodium chloride Substances 0.000 description 13
- 239000012530 fluid Substances 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- 229910052783 alkali metal Inorganic materials 0.000 description 11
- 150000001340 alkali metals Chemical class 0.000 description 11
- 229910001413 alkali metal ion Inorganic materials 0.000 description 10
- 239000004744 fabric Substances 0.000 description 10
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 9
- 238000010586 diagram Methods 0.000 description 9
- 230000001965 increasing effect Effects 0.000 description 9
- 229910052938 sodium sulfate Inorganic materials 0.000 description 9
- 235000011152 sodium sulphate Nutrition 0.000 description 9
- 229910000497 Amalgam Inorganic materials 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 238000006298 dechlorination reaction Methods 0.000 description 8
- 239000002002 slurry Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 239000011521 glass Substances 0.000 description 7
- 230000002706 hydrostatic effect Effects 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 7
- 238000011084 recovery Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 230000005484 gravity Effects 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- 239000012266 salt solution Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- MJGFBOZCAJSGQW-UHFFFAOYSA-N mercury sodium Chemical compound [Na].[Hg] MJGFBOZCAJSGQW-UHFFFAOYSA-N 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 230000036961 partial effect Effects 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 229910001023 sodium amalgam Inorganic materials 0.000 description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000004811 fluoropolymer Substances 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 230000001976 improved effect Effects 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- OBTWBSRJZRCYQV-UHFFFAOYSA-N sulfuryl difluoride Chemical group FS(F)(=O)=O OBTWBSRJZRCYQV-UHFFFAOYSA-N 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910006095 SO2F Inorganic materials 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910001316 Ag alloy Inorganic materials 0.000 description 1
- 206010006326 Breath odour Diseases 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical class [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 239000013529 heat transfer fluid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 210000002287 horizontal cell Anatomy 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- LWUVWAREOOAHDW-UHFFFAOYSA-N lead silver Chemical compound [Ag].[Pb] LWUVWAREOOAHDW-UHFFFAOYSA-N 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229960002523 mercuric chloride Drugs 0.000 description 1
- 150000002730 mercury Chemical class 0.000 description 1
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 1
- 229940008718 metallic mercury Drugs 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000009428 plumbing Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US298922A US3864226A (en) | 1972-10-19 | 1972-10-19 | Process for electrolyzing aqueous sodium or potassium ion solutions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS4974200A JPS4974200A (da) | 1974-07-17 |
| JPS582275B2 true JPS582275B2 (ja) | 1983-01-14 |
Family
ID=23152568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP48116402A Expired JPS582275B2 (ja) | 1972-10-19 | 1973-10-18 | デンカイホウホウ オヨビ デンカイソウ |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US3864226A (da) |
| JP (1) | JPS582275B2 (da) |
| AR (1) | AR206774A1 (da) |
| BE (1) | BE806231A (da) |
| BR (1) | BR7308030D0 (da) |
| CA (1) | CA1043735A (da) |
| CH (2) | CH606492A5 (da) |
| CS (1) | CS193024B2 (da) |
| DD (1) | DD109850A5 (da) |
| DE (1) | DE2348889C3 (da) |
| DK (1) | DK154027C (da) |
| ES (1) | ES419772A1 (da) |
| FR (1) | FR2203679B1 (da) |
| GB (1) | GB1427829A (da) |
| IE (1) | IE38350B1 (da) |
| IL (1) | IL43321A (da) |
| IN (1) | IN141177B (da) |
| IT (1) | IT1003184B (da) |
| LU (1) | LU68632A1 (da) |
| NL (1) | NL7314449A (da) |
| NO (1) | NO138256C (da) |
| PL (1) | PL91059B1 (da) |
| SU (2) | SU797594A3 (da) |
| ZA (1) | ZA737955B (da) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59150852U (ja) * | 1983-03-30 | 1984-10-09 | 朝日スチ−ル工業株式会社 | 線格子フエンス |
| JPS60117959U (ja) * | 1984-01-20 | 1985-08-09 | 朝日スチール工業株式会社 | 格子フエンス |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS551351B2 (da) * | 1974-03-07 | 1980-01-12 | ||
| JPS526374A (en) * | 1975-07-07 | 1977-01-18 | Tokuyama Soda Co Ltd | Anode structure for electrolysis |
| JPS534796A (en) * | 1976-07-05 | 1978-01-17 | Asahi Chem Ind Co Ltd | Electrolysis of pressurized alkali halide |
| ES452238A1 (es) * | 1976-10-08 | 1977-11-01 | Diaz Nogueira Eduardo | Un procedimiento de electrolisis de salmuera por catodo de mercurio. |
| US4086393A (en) * | 1976-11-24 | 1978-04-25 | Energy Development Associates | Gas phase free liquid chlorine electrochemical systems |
| JPS55161081A (en) * | 1979-06-01 | 1980-12-15 | Asahi Glass Co Ltd | Electrolytic cell |
| JPS5693883A (en) * | 1979-12-27 | 1981-07-29 | Permelec Electrode Ltd | Electrolytic apparatus using solid polymer electrolyte diaphragm and preparation thereof |
| US4313812A (en) * | 1980-03-10 | 1982-02-02 | Olin Corporation | Membrane electrode pack cells designed for medium pressure operation |
| US4390408A (en) * | 1980-06-06 | 1983-06-28 | Olin Corporation | Membrane electrode pack cells designed for medium pressure operation |
| EP0110425A3 (en) * | 1982-12-06 | 1985-07-31 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | An electrolytic process of an aqueous alkali metal halide solution and electrolytic cell used therefor |
| US5041197A (en) * | 1987-05-05 | 1991-08-20 | Physical Sciences, Inc. | H2 /C12 fuel cells for power and HCl production - chemical cogeneration |
| JPS6450998A (en) * | 1987-08-21 | 1989-02-27 | Power Reactor & Nuclear Fuel | Electrolysis treating method of radioactive waste liquid |
| IT1230714B (it) * | 1989-02-10 | 1991-10-29 | Solvay | Procedimento di fabbricazione di un solfuro di un metallo alcalino. |
| US5118398A (en) * | 1989-12-05 | 1992-06-02 | United Technologies Corporation | Method and an apparatus for detecting ionizable substance |
| US20070087245A1 (en) * | 2005-10-14 | 2007-04-19 | Fuller Timothy J | Multilayer polyelectrolyte membranes for fuel cells |
| US20120186989A1 (en) * | 2011-01-26 | 2012-07-26 | Yuri Alexeevich Omelchenko | Process for producing chlorine with low bromine content |
| US8636893B2 (en) * | 2011-01-26 | 2014-01-28 | Superior Plus Lp | Process for producing chlorine with low bromine content |
| WO2015027190A1 (en) | 2013-08-23 | 2015-02-26 | Mirakel Technologies, Inc. | Systems, devices and methods for styling hair |
| PT3597791T (pt) * | 2018-07-20 | 2022-01-27 | Covestro Deutschland Ag | Processo para melhoria do desempenho de elétrodos de níquel |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1109311A (en) * | 1912-01-06 | 1914-09-01 | Edward A Allen | Method and means for electrolyzing saline solutions. |
| US2681320A (en) * | 1950-12-23 | 1954-06-15 | Rohm & Haas | Permselective films of cationexchange resins |
| US2742419A (en) * | 1952-03-01 | 1956-04-17 | Diamond Alkali Co | Electrolytic cell base structure |
| GB1149416A (en) * | 1967-03-16 | 1969-04-23 | Ici Ltd | Manufacture of chlorine and caustic alkali in diaphragm cells |
| GB1199952A (en) * | 1967-05-15 | 1970-07-22 | Wolfen Filmfab Veb | Electrolysis of Alkali Metal Halide Solutions |
| US3645866A (en) * | 1969-08-26 | 1972-02-29 | Georgy Ivanovich Volkov | Method of electrolysis with a flowing mercury cathode in a chlorine cell |
| US3682797A (en) * | 1970-10-02 | 1972-08-08 | Great Lakes Carbon Corp | Stationary film mercury cell |
| US3775272A (en) * | 1972-02-25 | 1973-11-27 | Olin Corp | Mercury diaphragm chlor-alkali cell and process for decomposing alkali metal halides |
-
1972
- 1972-10-19 US US298922A patent/US3864226A/en not_active Expired - Lifetime
-
1973
- 1973-01-01 AR AR250438A patent/AR206774A1/es active
- 1973-09-25 IL IL43321A patent/IL43321A/en unknown
- 1973-09-28 DE DE2348889A patent/DE2348889C3/de not_active Expired
- 1973-10-04 IE IE1777/73A patent/IE38350B1/xx unknown
- 1973-10-12 ZA ZA00737955A patent/ZA737955B/xx unknown
- 1973-10-15 BR BR8030/73A patent/BR7308030D0/pt unknown
- 1973-10-16 IN IN2308/CAL/73A patent/IN141177B/en unknown
- 1973-10-17 CS CS737163A patent/CS193024B2/cs unknown
- 1973-10-17 LU LU68632A patent/LU68632A1/xx unknown
- 1973-10-17 SU SU731969452A patent/SU797594A3/ru active
- 1973-10-17 DD DD174181A patent/DD109850A5/xx unknown
- 1973-10-18 IT IT30270/73A patent/IT1003184B/it active
- 1973-10-18 NO NO4045/73A patent/NO138256C/no unknown
- 1973-10-18 DK DK565673A patent/DK154027C/da not_active IP Right Cessation
- 1973-10-18 FR FR7337192A patent/FR2203679B1/fr not_active Expired
- 1973-10-18 BE BE136821A patent/BE806231A/xx not_active IP Right Cessation
- 1973-10-18 ES ES419772A patent/ES419772A1/es not_active Expired
- 1973-10-18 PL PL1973165937A patent/PL91059B1/pl unknown
- 1973-10-18 JP JP48116402A patent/JPS582275B2/ja not_active Expired
- 1973-10-18 CA CA183,759A patent/CA1043735A/en not_active Expired
- 1973-10-19 CH CH1482273A patent/CH606492A5/xx not_active IP Right Cessation
- 1973-10-19 GB GB4891673A patent/GB1427829A/en not_active Expired
- 1973-10-19 NL NL7314449A patent/NL7314449A/xx active Search and Examination
-
1974
- 1974-06-28 SU SU742038381A patent/SU971110A3/ru active
-
1977
- 1977-11-07 CH CH1354077A patent/CH619741A5/de not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59150852U (ja) * | 1983-03-30 | 1984-10-09 | 朝日スチ−ル工業株式会社 | 線格子フエンス |
| JPS60117959U (ja) * | 1984-01-20 | 1985-08-09 | 朝日スチール工業株式会社 | 格子フエンス |
Also Published As
| Publication number | Publication date |
|---|---|
| NO138256C (no) | 1978-08-02 |
| IN141177B (da) | 1977-01-29 |
| CA1043735A (en) | 1978-12-05 |
| BE806231A (fr) | 1974-04-18 |
| IL43321A (en) | 1976-09-30 |
| DD109850A5 (da) | 1974-11-20 |
| CH606492A5 (da) | 1978-10-31 |
| BR7308030D0 (pt) | 1974-07-18 |
| ZA737955B (en) | 1975-11-26 |
| FR2203679A1 (da) | 1974-05-17 |
| AR206774A1 (es) | 1976-08-23 |
| IL43321A0 (en) | 1973-11-28 |
| CH619741A5 (da) | 1980-10-15 |
| US3864226A (en) | 1975-02-04 |
| DE2348889B2 (de) | 1981-07-16 |
| JPS4974200A (da) | 1974-07-17 |
| IE38350L (en) | 1974-04-19 |
| DK154027B (da) | 1988-10-03 |
| NL7314449A (da) | 1974-04-23 |
| SU797594A3 (ru) | 1981-01-15 |
| IT1003184B (it) | 1976-06-10 |
| LU68632A1 (da) | 1973-12-27 |
| AU6147673A (en) | 1975-04-17 |
| CS193024B2 (en) | 1979-09-17 |
| SU971110A3 (ru) | 1982-10-30 |
| DE2348889A1 (de) | 1974-08-01 |
| PL91059B1 (en) | 1977-02-28 |
| IE38350B1 (en) | 1978-02-15 |
| GB1427829A (en) | 1976-03-10 |
| DK154027C (da) | 1989-02-13 |
| NO138256B (no) | 1978-04-24 |
| ES419772A1 (es) | 1976-09-01 |
| DE2348889C3 (de) | 1982-05-06 |
| FR2203679B1 (da) | 1978-03-10 |
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