JPS57145829A - Preparation of adipic acid - Google Patents
Preparation of adipic acidInfo
- Publication number
- JPS57145829A JPS57145829A JP16032481A JP16032481A JPS57145829A JP S57145829 A JPS57145829 A JP S57145829A JP 16032481 A JP16032481 A JP 16032481A JP 16032481 A JP16032481 A JP 16032481A JP S57145829 A JPS57145829 A JP S57145829A
- Authority
- JP
- Japan
- Prior art keywords
- solvent
- reaction
- liquid
- adipic acid
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prepare adipic acid in high purity and yield, without necessitating catalyst, low temperature, and high pressure, by the oxidative ring-opening reaction of cyclohexylamine with liquid nitrogen dioxide (N2O4) in a solvent at a temperature below the boiling point of N2O4.
CONSTITUTION: In the preparation of adipic acid by the oxidative ring-opening reaction of cyclohexylamine with liquid nitrogen dioxide (N2O4), the reaction is carried out in a solvent (e.g. dichloromethane, ethylene dichloride, bromoform, etc.) at a temperature below the boiling point of N2O4. The generated heat of reaction can be effectively removed by adding the starting compound dissolved in a solvent to liquid N2O4 or a solution of liquid N2O4 in a solvent; however, the reaction may be carried out by adding liquid N2O4 to the starting compound dissolved in a solvent.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16032481A JPS57145829A (en) | 1981-10-09 | 1981-10-09 | Preparation of adipic acid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16032481A JPS57145829A (en) | 1981-10-09 | 1981-10-09 | Preparation of adipic acid |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1981977A Division JPS53105416A (en) | 1976-04-09 | 1977-02-26 | Process for adipic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS57145829A true JPS57145829A (en) | 1982-09-09 |
Family
ID=15712494
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP16032481A Pending JPS57145829A (en) | 1981-10-09 | 1981-10-09 | Preparation of adipic acid |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57145829A (en) |
-
1981
- 1981-10-09 JP JP16032481A patent/JPS57145829A/en active Pending
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