JPS55108422A - Batch-wise esterification - Google Patents
Batch-wise esterificationInfo
- Publication number
- JPS55108422A JPS55108422A JP1630279A JP1630279A JPS55108422A JP S55108422 A JPS55108422 A JP S55108422A JP 1630279 A JP1630279 A JP 1630279A JP 1630279 A JP1630279 A JP 1630279A JP S55108422 A JPS55108422 A JP S55108422A
- Authority
- JP
- Japan
- Prior art keywords
- slurry
- batch
- feeding
- feed rate
- wise
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000032050 esterification Effects 0.000 title abstract 3
- 238000005886 esterification reaction Methods 0.000 title abstract 3
- 239000002002 slurry Substances 0.000 abstract 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
PURPOSE: To efficiently produce a high-grade polyester having excellent color in batch-wise esterification, by controlling the feed rate of a slurry consisting of terephtahlic acid and ethylene glycol so that the rate is low at the initial period and high at the latter half period.
CONSTITUTION: The batch-wise esterification comprises the steps of: continuously feeding to a reaction system charged with 30W65% of bis-β-hydroxyethyl terephthalate or lower polymers thereof, a slurry consisting of terephthalic acid and ethylene glycol at such a feed rate that the initial slurry feed rate, Fa(kg/hr), defined as a feed rate at the initial 15% period of the time required for feeding all the slurry, satisfies the inequalities, in which Sv(kg) is the total quantity, per batch, of slurry charged, and Ft(hr) is the time required for feeding all the slurry, and the time required for feeding all the slurry, Ft, is in the range of 2.0W4.5: and reacting the mixture at a pressure of 0W1.0kg/cm2 gauge and a temperature of 225W260°C.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1630279A JPS55108422A (en) | 1979-02-15 | 1979-02-15 | Batch-wise esterification |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1630279A JPS55108422A (en) | 1979-02-15 | 1979-02-15 | Batch-wise esterification |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS55108422A true JPS55108422A (en) | 1980-08-20 |
JPS6146485B2 JPS6146485B2 (en) | 1986-10-14 |
Family
ID=11912740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1630279A Granted JPS55108422A (en) | 1979-02-15 | 1979-02-15 | Batch-wise esterification |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS55108422A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5847023A (en) * | 1981-09-16 | 1983-03-18 | Toray Ind Inc | Production of polyester for blow molding |
US6815525B2 (en) | 2000-12-07 | 2004-11-09 | Eastamn Chemical Company | Component introduction into manufacturing process through recirculation |
US6906164B2 (en) | 2000-12-07 | 2005-06-14 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7074879B2 (en) | 2003-06-06 | 2006-07-11 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7135541B2 (en) | 2003-06-06 | 2006-11-14 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7332548B2 (en) | 2004-03-04 | 2008-02-19 | Eastman Chemical Company | Process for production of a polyester product from alkylene oxide and carboxylic acid |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03107804A (en) * | 1989-09-14 | 1991-05-08 | Aeg Kabel Ag | Construction and method for storing extra length of optical fiber |
-
1979
- 1979-02-15 JP JP1630279A patent/JPS55108422A/en active Granted
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5847023A (en) * | 1981-09-16 | 1983-03-18 | Toray Ind Inc | Production of polyester for blow molding |
US7211633B2 (en) | 2000-12-07 | 2007-05-01 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7446162B2 (en) | 2000-12-07 | 2008-11-04 | Eastman Chemical Company | Polyester process using a pipe reactor |
US6906164B2 (en) | 2000-12-07 | 2005-06-14 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7541423B2 (en) | 2000-12-07 | 2009-06-02 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7531618B2 (en) | 2000-12-07 | 2009-05-12 | Eastman Chemical Company | Polyester process using a pipe reactor |
US6815525B2 (en) | 2000-12-07 | 2004-11-09 | Eastamn Chemical Company | Component introduction into manufacturing process through recirculation |
US7495067B2 (en) | 2000-12-07 | 2009-02-24 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7345139B2 (en) | 2000-12-07 | 2008-03-18 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7420026B2 (en) | 2000-12-07 | 2008-09-02 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7423109B2 (en) | 2000-12-07 | 2008-09-09 | Eastman Chemical Company | Polyester process using a pipe reactor |
US6861494B2 (en) | 2000-12-07 | 2005-03-01 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7135541B2 (en) | 2003-06-06 | 2006-11-14 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7074879B2 (en) | 2003-06-06 | 2006-07-11 | Eastman Chemical Company | Polyester process using a pipe reactor |
US7332548B2 (en) | 2004-03-04 | 2008-02-19 | Eastman Chemical Company | Process for production of a polyester product from alkylene oxide and carboxylic acid |
Also Published As
Publication number | Publication date |
---|---|
JPS6146485B2 (en) | 1986-10-14 |
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