JPH11322574A - Skin cosmetic - Google Patents
Skin cosmeticInfo
- Publication number
- JPH11322574A JPH11322574A JP6876599A JP6876599A JPH11322574A JP H11322574 A JPH11322574 A JP H11322574A JP 6876599 A JP6876599 A JP 6876599A JP 6876599 A JP6876599 A JP 6876599A JP H11322574 A JPH11322574 A JP H11322574A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- skin
- oil
- sodium
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 23
- MUPFEKGTMRGPLJ-RMMQSMQOSA-N Raffinose Natural products O(C[C@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O[C@@]2(CO)[C@H](O)[C@@H](O)[C@@H](CO)O2)O1)[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 MUPFEKGTMRGPLJ-RMMQSMQOSA-N 0.000 claims abstract description 15
- MUPFEKGTMRGPLJ-UHFFFAOYSA-N UNPD196149 Natural products OC1C(O)C(CO)OC1(CO)OC1C(O)C(O)C(O)C(COC2C(C(O)C(O)C(CO)O2)O)O1 MUPFEKGTMRGPLJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 claims abstract description 15
- 239000000194 fatty acid Substances 0.000 abstract description 48
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 47
- 229930195729 fatty acid Natural products 0.000 abstract description 47
- 150000004665 fatty acids Chemical class 0.000 abstract description 35
- 229920001296 polysiloxane Polymers 0.000 abstract description 25
- 239000003921 oil Substances 0.000 abstract description 13
- 235000019198 oils Nutrition 0.000 abstract description 12
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 abstract description 6
- 239000004615 ingredient Substances 0.000 abstract description 5
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- 239000003906 humectant Substances 0.000 abstract description 4
- 241001465754 Metazoa Species 0.000 abstract description 3
- 235000012000 cholesterol Nutrition 0.000 abstract description 3
- 150000002148 esters Chemical class 0.000 abstract description 3
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- 238000000576 coating method Methods 0.000 abstract description 2
- 239000003925 fat Substances 0.000 abstract description 2
- 229930195733 hydrocarbon Natural products 0.000 abstract description 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 2
- 239000002562 thickening agent Substances 0.000 abstract description 2
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- 235000015112 vegetable and seed oil Nutrition 0.000 abstract description 2
- 235000019871 vegetable fat Nutrition 0.000 abstract description 2
- 239000008158 vegetable oil Substances 0.000 abstract description 2
- 230000002087 whitening effect Effects 0.000 abstract description 2
- 239000003242 anti bacterial agent Substances 0.000 abstract 1
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- -1 etc.) Substances 0.000 description 57
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- 239000000203 mixture Substances 0.000 description 18
- 239000002253 acid Substances 0.000 description 16
- 238000011156 evaluation Methods 0.000 description 15
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 14
- 239000011734 sodium Substances 0.000 description 14
- 229910052708 sodium Inorganic materials 0.000 description 14
- 229940083542 sodium Drugs 0.000 description 14
- 239000004166 Lanolin Substances 0.000 description 13
- 235000019388 lanolin Nutrition 0.000 description 13
- 229940039717 lanolin Drugs 0.000 description 13
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 239000002202 Polyethylene glycol Substances 0.000 description 11
- 229920001223 polyethylene glycol Polymers 0.000 description 11
- 239000011591 potassium Substances 0.000 description 11
- 229910052700 potassium Inorganic materials 0.000 description 11
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 10
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 10
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 10
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 10
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 10
- 239000006210 lotion Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000009472 formulation Methods 0.000 description 9
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- 239000003346 palm kernel oil Substances 0.000 description 7
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- 244000060011 Cocos nucifera Species 0.000 description 5
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 5
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- 239000000600 sorbitol Substances 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 4
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 4
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 4
- 102000008186 Collagen Human genes 0.000 description 4
- 108010035532 Collagen Proteins 0.000 description 4
- 239000004472 Lysine Substances 0.000 description 4
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
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- 239000004359 castor oil Substances 0.000 description 4
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- 229920001436 collagen Polymers 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 4
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- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 235000004400 serine Nutrition 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960001790 sodium citrate Drugs 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940045845 sodium myristate Drugs 0.000 description 1
- 229950005425 sodium myristyl sulfate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 1
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 1
- ISONEALTCIBOKV-UHFFFAOYSA-M sodium;3-[methyl(tetradecanoyl)amino]propanoate Chemical compound [Na+].CCCCCCCCCCCCCC(=O)N(C)CCC([O-])=O ISONEALTCIBOKV-UHFFFAOYSA-M 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- RUTSRVMUIGMTHJ-UHFFFAOYSA-M sodium;tetradec-1-ene-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCC=CS([O-])(=O)=O RUTSRVMUIGMTHJ-UHFFFAOYSA-M 0.000 description 1
- AYFACLKQYVTXNS-UHFFFAOYSA-M sodium;tetradecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCS([O-])(=O)=O AYFACLKQYVTXNS-UHFFFAOYSA-M 0.000 description 1
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 1
- UPUIQOIQVMNQAP-UHFFFAOYSA-M sodium;tetradecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCOS([O-])(=O)=O UPUIQOIQVMNQAP-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000000021 stimulant Substances 0.000 description 1
- 235000021012 strawberries Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 235000008521 threonine Nutrition 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KVSKGMLNBAPGKH-UHFFFAOYSA-N tribromosalicylanilide Chemical compound OC1=C(Br)C=C(Br)C=C1C(=O)NC1=CC=C(Br)C=C1 KVSKGMLNBAPGKH-UHFFFAOYSA-N 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 description 1
- 150000004043 trisaccharides Chemical class 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 210000003954 umbilical cord Anatomy 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 229940045136 urea Drugs 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Substances 0.000 description 1
- 150000003698 vitamin B derivatives Chemical class 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000012138 yeast extract Substances 0.000 description 1
- 239000009538 yokuinin Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
- LTBBHPKPFHCPTL-UHFFFAOYSA-L zinc;carbonotrithioate Chemical compound [Zn+2].[S-]C([S-])=S LTBBHPKPFHCPTL-UHFFFAOYSA-L 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は皮膚化粧料に係わ
り、さらに詳しくは、乾燥時の保湿性が高く、かつ優れ
た使用感を提供し、しかも安全性の高い皮膚化粧料に関
する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a skin cosmetic, and more particularly, to a skin cosmetic which has a high moisturizing property when dry, provides an excellent feeling in use, and is highly safe.
【0002】[0002]
【従来の技術】皮膚化粧料の保湿剤として、従来グリセ
リン、ソルビトール、マルチトール、アミノ酸、ピロリ
ドンカルボン酸などが用いられてきた。これらは確かに
水分を保持する力は大きいが、それは主として高湿度時
に、多量の水分を吸収する機能を持つが、冬場などの乾
燥時には、必ずしも保湿能力が高いとは言えなかった。2. Description of the Related Art Glycerin, sorbitol, maltitol, amino acids, pyrrolidone carboxylic acid and the like have hitherto been used as humectants for skin cosmetics. Although these have a great ability to retain moisture, they have a function of absorbing a large amount of moisture mainly at high humidity, but they cannot always be said to have high moisture retention during drying in winter and the like.
【0003】[0003]
【発明が解決しようとする課題】本発明は、塗布時にべ
たつきが無くサッパリ感があり、のびが良く、肌のなめ
らかさを与え、化粧崩れしにくい化粧料を提供すること
を課題とする。また、乾燥時の保湿能力が十分で、かつ
高湿時には余分な水分を吸収してべたついたりしない化
粧料を提供することを課題とする。SUMMARY OF THE INVENTION An object of the present invention is to provide a cosmetic composition which has no stickiness at the time of application, has a refreshing feeling, has good spreadability, gives skin smoothness, and does not easily lose its makeup. It is another object of the present invention to provide a cosmetic composition that has sufficient moisture retention during drying and that absorbs excess moisture and does not stick during high humidity.
【0004】さらに、加工時や流通期間中、熱や光、酸
などで劣化したり、着色したりせず、つまり物理的、化
学的に安定な化粧料を提供することを課題とする。ま
た、皮膚に直接接触するものであるから、言うまでもな
く、安全なものである化粧料を提供することを課題とす
る。It is another object of the present invention to provide a physically and chemically stable cosmetic which is not degraded or colored by heat, light or acid during processing or distribution. Another object of the present invention is to provide a cosmetic that is safe because it comes into direct contact with the skin.
【0005】[0005]
【課題を解決するための手段】本発明者は上記課題を解
決するために鋭意研究を重ねた結果、皮膚化粧料にラフ
ィノースを用いると、相対湿度が低い乾燥時にも皮膚に
適度の潤いを与え、さらっとした良好な感触を与える皮
膚化粧料を得ることができることを見いだし、本発明を
完成した。Means for Solving the Problems The present inventors have conducted intensive studies to solve the above-mentioned problems, and as a result, it has been found that when raffinose is used as a skin cosmetic, the skin can be moisturized even when the relative humidity is low and dry. The present inventors have found that it is possible to obtain a skin cosmetic which gives a smooth and good feel, and has completed the present invention.
【0006】すなわち本発明は、ラフィノースを含有す
ることを特徴とする皮膚化粧料に関するものである。本
発明でいうところのラフィノースとは、O−α−Gal
actopyranosyl−(1→6)−α−D−g
lucopyranosiyl−β−D−fructo
furanosideのことであり、いわゆる三糖類で
ある。結晶の形態としては、無水物または数個の結晶水
をもつものである。例えばビートの糖液から、クロマト
分離装置を用いて分離することにより得られたもので、
オリゴ糖として食用にも用いられる安全性の高いもので
ある。That is, the present invention relates to a skin cosmetic comprising raffinose. Raffinose in the present invention is O-α-Gal
actpyranosyl- (1 → 6) -α-Dg
lucopyranosiyl-β-D-fructo
Furanoside is a so-called trisaccharide. The morphology of the crystals is anhydrous or one having several waters of crystallization. For example, it is obtained by separating from sugar solution of beet using a chromatographic separator,
It is highly safe to use as an oligosaccharide for food.
【0007】本発明に用いるラフィノースの配合量は
0.1〜35%程度、好ましくは0.1〜20重量%、
更に好ましくは1〜10重量%である。なお、10%程
度配合しても、ボデイー感はでるが、ガム類.カラギー
ナン等の天然多糖類のように不必要な粘度上昇は起きな
い。0.1重量%未満では本発明の効果が十分に発揮さ
れず、一方、35重量%をこえて配合しても配合量の増
加に見合う効果の増大が期待できない。なお、ここでい
う重量%はラフィノース純分の値であり、他の成分や乾
燥減量を除いたものである。The amount of raffinose used in the present invention is about 0.1 to 35%, preferably 0.1 to 20% by weight.
More preferably, it is 1 to 10% by weight. Even if it is blended at about 10%, a body feeling is obtained, but gums. Unnecessary viscosity increase does not occur unlike natural polysaccharides such as carrageenan. If the amount is less than 0.1% by weight, the effect of the present invention is not sufficiently exerted. On the other hand, if the amount is more than 35% by weight, an increase in the effect corresponding to the increase in the amount cannot be expected. Here, the weight% is a value of the pure raffinose, and excludes other components and loss on drying.
【0008】本発明の皮膚化粧料とは、外皮に適用され
る全ての化粧品、洗浄剤を含み、その形態も水溶液系、
可溶化系(例えば化粧水など)、乳化系(例えば乳液、
クリームなど)、粉末系、油液系、ゲル系、軟膏系、水
−油2層系、水−油−粉末3層系等幅広い形態をとりう
る。本発明の皮膚化粧料には、必須成分のラフィノース
の他、通常、皮膚化粧料に用いられる他の成分も適宜、
添加しうる。例えば、炭酸カルシウム、タルク、マイ
カ、ラウロイルリジン、二酸化チタン、二酸化亜鉛等の
粉末成分;ホホバ油、マカデミアナッツ油、アボガド
油、月見草油、ミンク油、ナタネ油、ヒマシ油、ヒマワ
リ油、トーモロコシ油、カカオ油、ヤシ油、コメヌカ
油、オリーブ油、アーモンド油、ごま油、サフラワー
油、大豆油、椿油、パーシック油、ヒマシ油、ミンク
油、綿実油、モクロウ、パーム油、パーム核油、卵黄
油、ラノリン、スクワレン等の天然動植物油脂類、合成
トリグリセライド;[0008] The skin cosmetics of the present invention include all cosmetics and cleaning agents applied to the outer skin, and may be in the form of an aqueous solution,
Solubilizing system (for example, lotion), emulsifying system (for example, emulsion,
Cream, etc.), powder type, oil liquid type, gel type, ointment type, water-oil two-layer system, water-oil-powder three-layer system, and the like. In the skin cosmetic of the present invention, in addition to the essential component raffinose, other components usually used in skin cosmetics are also appropriately used.
May be added. For example, powder components such as calcium carbonate, talc, mica, lauroyl lysine, titanium dioxide, and zinc dioxide; jojoba oil, macadamia nut oil, avocado oil, evening primrose oil, mink oil, rapeseed oil, castor oil, sunflower oil, corn oil, cacao oil Oil, palm oil, rice bran oil, olive oil, almond oil, sesame oil, safflower oil, soybean oil, camellia oil, persic oil, castor oil, mink oil, cottonseed oil, mocro, palm oil, palm kernel oil, egg yolk oil, lanolin, squalene Natural animal and vegetable oils and fats, such as synthetic triglycerides;
【0009】スクワラン、流動パラフィン、ワセリン、
セレシン、マイクロクリスタリンワックス、イソパラフ
ィン等の炭化水素類;カルナバウロウ、パラフィンワッ
クス、鯨ロウ、ミツロウ、キヤンデリラワックス、ラノ
リン等のワックス類、セタノール、ステアリルアルコー
ル、ラウリルアルコール、セトステアリルアルコール、
オレイルアルコール、ベヘニルアルコール、ラノリンア
ルコール、水添ラノリンアルコール、ヘキシルデカノー
ル、オクチルドデカノール等の高級アルコール類、ラウ
リン酸、ミリスチン酸、パルミチン酸、ステアリン酸、
ベヘニン酸、イソステアリン酸、オレイン酸、リノレン
酸、リノール酸、オキシステアリン酸、ウンデシレン
酸、ラノリン脂肪酸、硬質ラノリン脂肪酸、軟質ラノリ
ン脂肪酸等の高級脂肪酸類;コレステリル−オクチルド
デシル−ベヘニル等のコレステロールおよびその誘導
体;Squalane, liquid paraffin, vaseline,
Hydrocarbons such as ceresin, microcrystalline wax, and isoparaffin; waxes such as carnauba wax, paraffin wax, spermaceti, beeswax, candelilla wax, lanolin, cetanol, stearyl alcohol, lauryl alcohol, cetostearyl alcohol;
Higher alcohols such as oleyl alcohol, behenyl alcohol, lanolin alcohol, hydrogenated lanolin alcohol, hexyldecanol, octyldodecanol, lauric acid, myristic acid, palmitic acid, stearic acid,
Higher fatty acids such as behenic acid, isostearic acid, oleic acid, linolenic acid, linoleic acid, oxystearic acid, undecylenic acid, lanolin fatty acid, hard lanolin fatty acid and soft lanolin fatty acid; cholesterol such as cholesteryl-octyldodecyl-behenyl and derivatives thereof. ;
【0010】イソプロピルミリスチン酸、イソプロピル
パルミチン酸、イソプロピルステアリン酸、2エチルヘ
キサン酸グリセロール、ブチルステアリン酸等のエステ
ル類;ジエチレングリコールモノプロピルエーテル、ポ
リオキシエチレンポリオキシプロピレンペンタエリトリ
トールエーテル、ポリオキシプロピレンブチルエーテ
ル、リノール酸エチル等の極性オイル、その他アミノ変
性シリコーン、エポキシ変性シリコーン、カルボキシル
変性シリコーン、カルビノール変性シリコーン、メタク
リル変性シリコーン、メルカプト変性シリコーン、フェ
ノール変性シリコーン、片末端反応性シリコーン、異種
官能基変性シリコーン、ポリエーテル変性シリコーン、
メチルスチリル変性シリコーン、アルキル変性シリコー
ン、高級脂肪酸エステル変性シリコーン、親水性特殊変
性シリコーン、高級アルコキシ変性シリコーン、高級脂
肪酸含有シリコーン、フッ素変性シリコーン等、より具
体的にはシリコン樹脂、メチルフェニルポリシロキサ
ン、メチルポリシロキサン、オクタメチルシクロテトラ
シロキサン、デカメチルシクロペンタシロキサン、ドデ
カメチルシクロヘキサンシロキサン、メチルシクロポリ
シロキサン、オクタメチルトリシロキサン、デカメチル
テトラシロキサン、ポリオキシエチレン・メチルポリシ
ロキサン共重合体、ポリオキシプロピレン・メチルポリ
シロキサン共重合体、ポリ(オキシエチレン・オキシプ
ロピレン)メチルポリシロキサン共重合体、メチルハイ
ドロジェンポリシロキサン、テトラヒドロテトラメチル
シクロテトラシロキサン、ステアロキシメチルポリシロ
キサン、セトキシメチルポリシロキサン、メチルポリシ
ロキサンエマルション、高重合メチルポリシロキサン
(1)および(2)、トリメチルシロキシケイ酸、架橋
型メチルポリシロキサン、架橋型メチルフェニルポリシ
ロキサン、架橋型メチルフェニルポリシロキサン(2)
等の各種誘導体を含むシリコーン類;Esters such as isopropyl myristic acid, isopropyl palmitic acid, isopropyl stearic acid, glycerol 2-ethylhexanoate and butyl stearic acid; diethylene glycol monopropyl ether, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxypropylene butyl ether, linole Polar oils such as ethyl acid, other amino-modified silicones, epoxy-modified silicones, carboxyl-modified silicones, carbinol-modified silicones, methacryl-modified silicones, mercapto-modified silicones, phenol-modified silicones, one-terminal reactive silicones, heterofunctional group-modified silicones, and poly Ether-modified silicone,
Methylstyryl-modified silicone, alkyl-modified silicone, higher fatty acid ester-modified silicone, hydrophilic special modified silicone, higher alkoxy-modified silicone, higher fatty acid-containing silicone, fluorine-modified silicone, etc., more specifically, silicone resin, methylphenylpolysiloxane, methyl Polysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexanesiloxane, methylcyclopolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, polyoxyethylene / methylpolysiloxane copolymer, polyoxypropylene Methyl polysiloxane copolymer, poly (oxyethylene / oxypropylene) methyl polysiloxane copolymer, methyl hydrogen polysiloxane Sun, tetrahydrotetramethylcyclotetrasiloxane, stearoxymethylpolysiloxane, sethoxymethylpolysiloxane, methylpolysiloxane emulsion, highly polymerized methylpolysiloxanes (1) and (2), trimethylsiloxysilicic acid, cross-linked methylpolysiloxane, Crosslinked methylphenylpolysiloxane, crosslinked methylphenylpolysiloxane (2)
Silicones containing various derivatives such as;
【0011】パラアミノ安息香酸およびその誘導体、ホ
モメチル−7N−アセチルアラントイラニレート、ブチ
ルメトキシベンゾイルメタン、ヂーパラメトキシケイ皮
酸−モノ−2−エチルヘキサン酸グリセリル、オクチル
シンナメート等のパラメトキシケイ皮酸誘導体、アミル
サリシレート等のサリチル酸誘導体、2,4−ジヒドロ
キシベンゾフェノン等のベンゾフェノン誘導体、ジメト
キシベンジリデンジオキソイミダゾリンプロピオン酸エ
チルヘキシル、酢酸液状ラノリン、コガネバナ根抽出エ
キス、トリアニリノ−p−カルボエチルヘキシルオキシ
−トリアジン等の紫外線吸収剤;アルブチン、コウジ
酸、リン酸アスコルビン酸マグネシウムなどのアスコル
ビン酸およびその誘導体、グルタチオン、甘草エキス、
チョウジエキス、茶抽出物、アスタキサンチン、牛胎盤
エキス、トコフェロールおよびその誘導体、トラネキサ
ム酸およびその塩、アズレン、γ−ヒドロキシ酪酸等の
美白成分;Paramethoxycinnamic acid such as paraaminobenzoic acid and derivatives thereof, homomethyl-7N-acetylalantranylanilate, butylmethoxybenzoylmethane, glyceryl monoparamethoxycinnamate-mono-2-ethylhexanoate and octylcinnamate Acid derivatives, salicylic acid derivatives such as amyl salicylate, benzophenone derivatives such as 2,4-dihydroxybenzophenone, dimethoxybenzylidene dioxoimidazoline ethylhexyl propionate, liquid lanolin acetate, Scutellaria root extract, trianilino-p-carboethylhexyloxy-triazine and the like Ultraviolet absorbers; arbutin, kojic acid, ascorbic acid such as magnesium phosphate ascorbate and derivatives thereof, glutathione, licorice extract,
Whitening ingredients such as clove extract, tea extract, astaxanthin, beef placenta extract, tocopherol and its derivatives, tranexamic acid and its salts, azulene and γ-hydroxybutyric acid;
【0012】マルチトール、ソルビトール、グリセリ
ン、プロピレングリコール、1,3−ブチレングリコー
ル、ポリエチレングリコール、グリコール等の多価アル
コール、ピロリドンカルボン酸ソーダ、乳酸ソーダ、ク
エン酸ソーダなど有機酸およびその塩、ヒアルロン酸ソ
ーダなどヒアルロン酸およびその塩、酵母および酵母抽
出液の加水分解物、酵母培養液、乳酸菌培養液など醗酵
代謝産物、コラーゲン、エラスチン、ケラチン、セリシ
ン等の水溶性蛋白、コラーゲン加水分解物、カゼイン加
水分解物、シルク加水分解物、ポリアスパラギン酸ナト
リウム等のぺプチド類およびその塩、トレハロース、キ
シロビオース、マルトース、蔗糖、ブドウ糖、植物性粘
質多糖等の糖類・多糖類およびその誘導体、水溶性キチ
ン、キトサン、ペクチン、コンドロイチン硫酸およびそ
の塩等のグリコサミノグリカンおよびその塩、グリシ
ン、セリン、スレオニン、アラニン、アスパラギン酸、
チロシン、バリン、ロイシン、アルギニン、グルタミ
ン、プロリン酸等のアミノ酸、アミノカルボニル反応物
等の糖アミノ酸化合物、アロエ、マロニエ等の植物抽出
液、トリメチルグリシン、尿素、尿酸、アンモニア、レ
シチン、ラノリン、スクワラン、スクワレン、グルコサ
ミン、クレアチニン、DNA、RNA等の核酸関連物質
等の保湿剤;Polyhydric alcohols such as maltitol, sorbitol, glycerin, propylene glycol, 1,3-butylene glycol, polyethylene glycol and glycol, organic acids such as sodium pyrrolidone carboxylate, sodium lactate and sodium citrate and salts thereof, and hyaluronic acid Hyaluronic acid and its salts such as soda, hydrolyzate of yeast and yeast extract, fermentation metabolites such as yeast culture and lactic acid bacteria culture, water-soluble proteins such as collagen, elastin, keratin, and sericin, collagen hydrolyzate, casein hydrolyzate Hydrolysates, silk hydrolysates, peptides such as sodium polyaspartate and salts thereof, trehalose, xylobiose, maltose, sucrose, glucose, saccharides and polysaccharides such as vegetable mucopolysaccharides and derivatives thereof, water-soluble chitin, Chitosan, baek Emissions, glycosaminoglycans and salts thereof such as chondroitin sulfate and its salts, glycine, serine, threonine, alanine, aspartic acid,
Amino acids such as tyrosine, valine, leucine, arginine, glutamine and prophosphoric acid, sugar amino acid compounds such as aminocarbonyl reactants, plant extracts such as aloe and malonier, trimethylglycine, urea, uric acid, ammonia, lecithin, lanolin, squalane, Humectants such as squalene, glucosamine, creatinine, DNA and nucleic acid-related substances such as RNA;
【0013】カルボキシメチルセルロース、ヒドロキシ
エチルセルロースヒドロキシプロピルトリメチルアンモ
ニウムクロリドエーテル、エチルセルロース、ヒドロキ
シプロピルセルロース、メチルヒドロキシプロピルセル
ロース、可溶性デンプン、カルボキシメチルデンプン、
メチルデンプン、アルギン酸プロピレングリコールエス
テル、ポリビニルアルコール、ポリビニルピロリドン、
ポリビニルメチルエーテル、カルボキシビニルポリマ
ー、ポリアクリル酸、メチルセルロース、ヒドロキシエ
チルセルロース、アラビアガム、キサンタンガム、グア
ーガム、ローカストビンガム、クインスシード、カラギ
ーナン、ガラクタン、ペクチン、マンナン、デンプン、
デキストラン、サクシノグルカン、カードラン、ヒアル
ロン酸、ゼラチン、カゼイン、アルブミン、コラーゲ
ン、メトキシエチレン無水マレイン酸共重合体、両性メ
タクリル酸エステル共重合体、ポリ塩化ジメチルメチレ
ンピペリジニウム、ポリアクリル酸エステル共重合体、
ポリ酢酸ビニル、ニトロセルロース、シリコーンレジ
ン、ポリエチレングリコール脂肪酸エステル、ジステア
リン酸ポリエチレングリコール等のポリオキシエチレン
脂肪酸エステル、ポリオキシエチレンジオレイン酸メチ
ルグルコシド等のポリオキシエチレン脂肪酸エステルメ
チルグリコシド、テトラデセンスルホン酸等のα―オレ
フィンスルホン酸等の増粘剤;Carboxymethylcellulose, hydroxyethylcellulose hydroxypropyltrimethylammonium chloride ether, ethylcellulose, hydroxypropylcellulose, methylhydroxypropylcellulose, soluble starch, carboxymethylstarch,
Methyl starch, propylene glycol alginate, polyvinyl alcohol, polyvinyl pyrrolidone,
Polyvinyl methyl ether, carboxyvinyl polymer, polyacrylic acid, methylcellulose, hydroxyethylcellulose, gum arabic, xanthan gum, guar gum, locust bingham, quince seed, carrageenan, galactan, pectin, mannan, starch,
Dextran, succinoglucan, curdlan, hyaluronic acid, gelatin, casein, albumin, collagen, methoxyethylene maleic anhydride copolymer, amphoteric methacrylate copolymer, polydimethyl dimethylmethylene piperidinium, polyacrylate Polymer,
Polyoxyethylene fatty acid ester such as polyvinyl acetate, nitrocellulose, silicone resin, polyethylene glycol fatty acid ester, polyethylene glycol distearate, polyoxyethylene fatty acid ester methylglycoside such as polyoxyethylene dioleic acid methyl glucoside, tetradecene sulfonic acid, etc. Thickeners such as α-olefin sulfonic acid;
【0014】エチレンジアミン四酢酸およびその塩類、
ヒドロキシエチレンジアミン3酢酸およびその塩類、リ
ン酸、アスコルビン酸、コハク酸、グルコン酸、ポリリ
ン酸塩類、メタリン酸塩類などの金属イオン封鎖剤;エ
タノール、プロピレングリコール、1,3−ブチレグリ
コール等の有機溶剤、ブチルヒドロキシトルエン、トコ
フェロール、フィチン酸等の酸化防止剤;安息香酸およ
びその塩、サリチル酸およびその塩、ソルビン酸および
その塩、パラオキシ安息香酸アルキルエステル(エチル
パラベン、ブチルパラベン等)およびその塩、デヒドロ
酢酸およびその塩類、パラクロルメタクレゾール、ヘキ
サクロロフェン、ホウ酸、レゾルシン、トリブロムサラ
ン、オルトフェニルフェノール、グルコン酸クロルヘキ
シジン、チラム、感光素201号、フェノキシエタノー
ル、塩化ベンザルコニウム、塩化ベンゼトニウム、ハロ
カルバン、塩化クロルヘキシジン、トリクロロカルバニ
ド、酢酸トコフェロール、ジンクピリチオン、ヒノキチ
オール、フェノール、イソプロピルメチルフェノール、
2,4,4−トリクロロ−2−ヒドロキシフェノール、
ヘキサクロロフェン等の抗菌.防腐剤;Ethylenediaminetetraacetic acid and salts thereof,
Sequestering agents such as hydroxyethylenediamine triacetic acid and salts thereof, phosphoric acid, ascorbic acid, succinic acid, gluconic acid, polyphosphates and metaphosphates; organic solvents such as ethanol, propylene glycol and 1,3-butyleglycol , Butylhydroxytoluene, tocopherol, phytic acid and the like; antioxidants; benzoic acid and its salts, salicylic acid and its salts, sorbic acid and its salts, alkyl paraoxybenzoate (ethylparaben, butylparaben, etc.) and its salts, dehydrogen Acetic acid and its salts, parachloromethcresol, hexachlorophen, boric acid, resorcinol, tribromosalan, orthophenylphenol, chlorhexidine gluconate, thiram, photosensitizer 201, phenoxyethanol, benzal chloride , Benzethonium chloride, halocarban, chlorhexidine chloride, trichlorocarbanilide Nido, tocopherol acetate, zinc pyrithione, hinokitiol, phenol, isopropyl methylphenol,
2,4,4-trichloro-2-hydroxyphenol,
Antibacterial such as hexachlorophen. Preservative;
【0015】クエン酸、リンゴ酸、酒石酸、乳酸、アジ
ピン酸、グルタミン酸、アスパラギン酸、マレイン酸等
の有機酸;ビタミンA及びその誘導体;ビタミンB6 塩
酸塩、ビタミンB6 トリパルミテート、ビタミンB6 ジ
オクタノエート、ビタミンB2及びその誘導体等のビタ
ミンB類;アスコルビン酸、アスコルビン酸硫酸エステ
ル、アスコルビン酸リン酸エステル等のビタミンC類、
αトコフェロール、βトコフェロール、γトコフェロー
ル等のビタミンE類、ビタミンD類、ビタミンH、パン
トテン酸等のビタミン類、ニコチン酸アミド、ニコチン
酸ベンジル、γ−オリザノール、アラントイン、グリチ
ルリチン酸(塩)グリチルレチン酸およびその誘導体、
ヒノキチオール、ムシジン、ビサボロール、ユーカリプ
トール、チモールイノシトール、サポニン類(キラヤサ
ポニン、アズキサポニン、ヘチマサポニン等)トラネキ
サム酸、パントテルエチルエーテル、エチニルエストラ
ジオール、セファランジン、プラセンタエキス、センブ
リエキス、セファランチン、ビタミンEおよびその誘導
体、Organic acids such as citric acid, malic acid, tartaric acid, lactic acid, adipic acid, glutamic acid, aspartic acid and maleic acid; vitamin A and its derivatives; vitamin B 6 hydrochloride, vitamin B 6 tripalmitate, vitamin B 6 Vitamin Bs such as dioctanoate, vitamin B 2 and derivatives thereof; vitamin Cs such as ascorbic acid, ascorbic acid sulfate, and ascorbic acid phosphate;
Vitamin E such as α-tocopherol, β-tocopherol, γ-tocopherol, vitamins such as vitamin D, vitamin H, pantothenic acid, nicotinamide, benzyl nicotinate, γ-oryzanol, allantoin, glycyrrhizic acid (salt) glycyrrhetinic acid and Its derivatives,
Hinokitiol, mucidin, bisabolol, eucalyptol, thymol inositol, saponins (e.g., quilayasaponin, azoxaponin, hepimasaponin) tranexamic acid, pantoterethyl ether, ethinyl estradiol, cephalandin, placenta extract, assembly extract, cepharanthin, vitamin E and Its derivatives,
【0016】ガンマ−オリザノールなどの血行促進剤、
トウガラシチンキ、ショオウキョウチンキ、カンタリス
チンキ、ニコチン酸ベンジルエステルなどの局所刺激
剤、ビタミンA類、ビタミンB群、ビタミンD群、ビタ
ミンE、パントテン酸、ビタミンHなどの各種ビタミン
やアミノ酸などの栄養剤、グリチルレチン酸、グリチル
リチン酸誘導体、アラントイン、アズレン、アミノカプ
ロン酸、ヒドロコルチゾンなどの抗炎症剤、酸化亜鉛、
硫酸亜鉛、アラントインヒドロキシアルミニウム、塩化
アルミニウム、スルホ石炭酸亜鉛、タンニン酸などの収
斂剤、メントール、カンフルなどの清涼剤、抗ヒスタミ
ン剤、高分子シリコーン、環状シリコーン等のシリコン
系物質、トコフェロール類、BHA、BHT、没食子
酸、NDGAなどの酸化防止剤等の各種薬剤;A blood circulation promoting agent such as gamma-oryzanol;
Local stimulants such as tincture tincture, tincture tincture, tincture tincture, benzyl nicotinic acid, nutrition of various vitamins such as vitamins A, vitamins B, vitamin D, vitamin E, pantothenic acid, vitamin H, and amino acids Agents, glycyrrhetinic acid, glycyrrhizic acid derivatives, allantoin, azulene, aminocaproic acid, anti-inflammatory agents such as hydrocortisone, zinc oxide,
Astringents such as zinc sulfate, allantoin hydroxyaluminum, aluminum chloride, zinc sulfocarbonate, and tannic acid; cooling agents such as menthol and camphor; antihistamines; silicone-based materials such as polymeric silicones and cyclic silicones; tocopherols, BHA, BHT; Various drugs such as gallic acid and antioxidants such as NDGA;
【0017】サッカロマイセスなどの酵母、糸状菌、バ
クテリア、牛胎盤、人胎盤、人臍帯、酵母、牛コラーゲ
ン、牛乳由来蛋白、小麦、大豆、牛血液、ブタ血液、鶏
冠、カミツレ、キュウリ、コメ、シアバター、シラカ
バ、茶、トマト、ニンニク、ハマメリス、バラ、ヘチ
マ、ホップ、モモ、アンズ、レモン、キウイ、ドクダ
ミ、トウガラシ、クララ、ギシギシ、コウホネ、セー
ジ、ノコギリ草、ゼニアオイ、センキュウ、センブリ、
タイム、トウキ、トウヒ、バーチ、スギナ、ヘチマ、マ
ロニエ、ユキノシタ、アルニカ、ユリ、ヨモギ、シャク
ヤク、アロエ、アロエベラ、オウゴン、オウバク、コウ
カ、ベニバナ、サンシン、シコン、タイソウ、チンピ、
ニンジン、ヨクイニン、ハトムギ、クチナシ、サワラ等
の動植物・微生物およびその一部から有機溶媒、アルコ
ール、多価アルコール、水、水性アルコール等で抽出ま
たは加水分解して得た天然エキス;色素;Yeast such as Saccharomyces, filamentous fungi, bacteria, bovine placenta, human placenta, human umbilical cord, yeast, bovine collagen, protein derived from milk, wheat, soybean, bovine blood, swine blood, cockscomb, chamomile, cucumber, rice, shii Avatar, birch, tea, tomato, garlic, hamamelis, rose, loofah, hop, peach, apricot, lemon, kiwi, dokudami, capsicum, clara, cedar, kohone, sage, sawtooth grass, mallow, senkyu, assembly,
Thyme, touki, spruce, birch, horsetail, luffa, marronnier, yukinoshita, arnica, lily, mugwort, peonies, aloe, aloe vera, ougon, oubak, squash, safflower, sanshin, sicon, taisou, chimpi,
Natural extracts obtained by extracting or hydrolyzing animals, plants and microorganisms, such as carrots, yokuinin, barley, gardenia, and strawberries, and parts thereof with organic solvents, alcohols, polyhydric alcohols, water, aqueous alcohols, and the like;
【0018】モノラウリン酸ソルビタン、セスキオレイ
ン酸ソルビタン、トリオレイン酸ソルビタン、モノオレ
イン酸ソルビタン、モノステアリン酸ソルビタン、トリ
ステアリン酸ソルビタン、モノイソステアリン酸ソルビ
タン等のソルビタン脂肪酸エステル、モノラウリン酸ポ
リオキシエチレンソルビタン、モノステアリン酸POE
ソルビタン、トリステアリン酸POEソルビタン、モノ
ステアリン酸POEソルビタン、モノイソステアリン酸
POEソルビタン等のポリオキシエチレンソルビタン脂
肪酸エステル、ポリエチレングリコールモノオレート、
ポリエチレングリコールモノラウリン酸、ポリエチレン
グリコールモノステアリン酸、ポリエチレングリコール
モノオレイン酸、ポリエチレングリコールジステアリン
酸、ポリエチレングリコールジオレイン酸、ポリエチレ
ングリコールジイソステアリン酸等のポリエチレングリ
コール脂肪酸エステル、POEラウリルエーテル、PO
Eセチルエーテル、POEステアリルエーテル、POE
オレイルエーテル、POEベヘニルエーテル等のポリオ
キシエチレンアルキルエーテル、Sorbitan monolaurate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monooleate, sorbitan monostearate, sorbitan tristearate, sorbitan monoisostearate, etc., polyoxyethylene sorbitan monolaurate, monosorbate Stearic acid POE
Polyoxyethylene sorbitan fatty acid esters such as sorbitan, POE sorbitan tristearate, POE sorbitan monostearate, POE sorbitan monoisostearate, polyethylene glycol monooleate,
Polyethylene glycol fatty acid esters such as polyethylene glycol monolauric acid, polyethylene glycol monostearic acid, polyethylene glycol monooleic acid, polyethylene glycol distearic acid, polyethylene glycol dioleic acid, polyethylene glycol diisostearic acid, POE lauryl ether, PO
E-cetyl ether, POE stearyl ether, POE
Polyoxyethylene alkyl ethers such as oleyl ether and POE behenyl ether;
【0019】モノステアリン酸ジグリセリル、モノオレ
イン酸ジグリセリル、ジオレイン酸ジグリセリル、モノ
イソステアリン酸ジグリセリル、モノステアリン酸テト
ラグリセリル、トリステアリン酸テトラグリセリル、ペ
ンタステアリン酸テトラグリセリル、モノラウリン酸ヘ
キサグリセリル、モノミリスチン酸ヘキサグリセリル、
ジステアリン酸デカグリセリル、ジイソステアリン酸デ
カグリセリル等のポリグリセリン脂肪酸エステル、ポリ
グリコールジエステル、ヤシ油脂肪酸モノエタノールア
ミド、ラウロイルモノエタノールアミド、ミリストイル
モノエタノールアミド、ラウロイルジエタノールアマイ
ド、ヤシ油脂肪酸ジエタノールアマイド、ラウロイルイ
ソプロパノールアマイド、ミリストイルイソプロパノー
ルアマイド、ヤシ油脂肪酸イソプロパノールアマイド等
の脂肪酸アルカノールアマイド、マルチトールヒドロキ
シ脂肪酸エーテル、アルキル化多糖、アルキルグルコシ
ド、シュガーエステル等の糖誘導体、Diglyceryl monostearate, diglyceryl monooleate, diglyceryl dioleate, diglyceryl monoisostearate, tetraglyceryl monostearate, tetraglyceryl tristearate, tetraglyceryl pentastearate, hexaglyceryl monolaurate, monoglyceryl monolaurate Hexaglyceryl myristate,
Polyglycerol fatty acid esters such as decaglyceryl distearate and decaglyceryl diisostearate, polyglycol diester, coconut oil monoethanolamide, lauroyl monoethanolamide, myristoyl monoethanolamide, lauroyl diethanol amide, coco oil fatty acid diethanol amide, lauroyl isopropanol amide , Myristoyl isopropanol amide, fatty acid alkanol amides such as coconut oil fatty acid isopropanol amide, maltitol hydroxy fatty acid ether, alkylated polysaccharide, alkyl glucoside, sugar derivatives such as sugar ester,
【0020】ポリオキシエチレンヒマシ油、ポリオキシ
エチレン硬化ヒマシ油、モノステアリン酸プロピレング
リコール、自己乳化型モノステアリン酸プロピレングリ
コール等のプロピレングリコール脂肪酸エステル、モノ
ステアリン酸グリセリル、自己乳化型モノステアリン酸
グリセリル等のグリセリン脂肪酸エステル、モノステア
リン酸POEグリセリルなどのポリオキシエチレングリ
セリン脂肪酸エステル、ヘキサステアリン酸POEソル
ビット、テトラステアリン酸POEソルビット、テトラ
オレイン酸POEソルビット、モノラウリン酸POEソ
ルビット等のポリオキシエチレンソルビット脂肪酸エス
テル、POEオクチルフェノールエーテル、POEノニ
ルフェノールエーテル、POEクロロフェノールエーテ
ル、ポリエチレングリコール等の非イオン界面活性剤、Polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, propylene glycol fatty acid esters such as propylene glycol monostearate, propylene glycol monostearate, glyceryl monostearate, glyceryl monostearate, etc. Glycerin fatty acid esters, polyoxyethylene glycerin fatty acid esters such as POE glyceryl monostearate, POE sorbitol hexastearate, POE sorbit tetrastearate, POE sorbitol tetraoleate, polyoxyethylene sorbite fatty acid esters such as POE sorbitol monolaurate, POE octyl phenol ether, POE nonyl phenol ether, POE chlorophenol ether, polyethylene Nonionic surfactants such as recall,
【0021】ラウリルトリメチルアンモニウムクロライ
ド、セチルトリメチルアンモニウムクロライド、牛脂ア
ルキルトリメチルアンモニウムクロライド、ステアリル
トリメチルアンモニウムクロライド、ベヘニルトリメチ
ルアンモニウムクロライド、ジオクチルジメチルアンモ
ニウムクロライド、ジステアリルジメチルアンモニウム
クロライド、ヤシ油アルキルトリメチルアンモニウムブ
ロミド、ステアリルトリメチルアンモニウムブロミド等
のアルキルアンモニウム塩、ラノリン誘導第4級アンモ
ニウム塩、塩化べンザルコニウム、塩化ステアリルジメ
チルベンジルアンモニウム、ラウリルアミンオキシド、
ヤシ油アルキルアミンオキシド、ステアリン酸ジエチル
アミノエチルアミド等のカチオン界面活性剤;ラウリン
酸ナトリウム、ミリスチン酸ナトリウム、ヤシ油脂肪酸
ナトリウム、パーム核油脂肪酸ナトリウム、ラウリン酸
リジン、ミリスチン酸リジン、ヤシ油脂肪酸リジン、パ
ーム核油脂肪酸リジン、ラウリン酸アルギニン、ミリス
チン酸アルギニン、ヤシ油脂肪酸アルギニン、パーム核
油脂肪酸アルギニン、ラウリン酸カリウム、ミリスチン
酸カリウム、ヤシ油脂肪酸カリウム、パーム核油脂肪酸
カリウム、ラウリン酸トリエタノールアミン、ミリスチ
ン酸トリエタノールアミン、ヤシ油脂肪酸トリエタノー
ルアミン、パーム核油脂肪酸トリエタノールアミン、ラ
ウリン酸アンモニウム、ミリスチン酸アンモニウム、ヤ
シ油脂肪酸アンモニウム、パーム核油脂肪酸アンモニウ
ムなどの脂肪酸およびその塩、Lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, tallowalkyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, dioctyldimethylammonium chloride, distearyldimethylammonium chloride, coconut oil alkyltrimethylammonium bromide, stearyltrimethylammonium Alkylammonium salts such as bromide, lanolin-derived quaternary ammonium salts, benzalkonium chloride, stearyldimethylbenzylammonium chloride, laurylamine oxide,
Cationic surfactants such as coconut oil alkylamine oxide and diethylaminoethylamide stearate; sodium laurate, sodium myristate, sodium coconut oil, sodium palm kernel oil, lysine laurate, lysine myristate, lysine coconut oil, Palm kernel oil fatty acid lysine, arginine laurate, arginine myristate, coconut oil fatty acid arginine, palm kernel oil fatty acid arginine, potassium laurate, potassium myristate, coconut oil fatty acid potassium, potassium palm kernel oil fatty acid potassium, triethanolamine laurate, Triethanolamine myristate, triethanolamine of coconut oil fatty acid, triethanolamine of palm kernel oil, ammonium laurate, ammonium myristate, coconut oil fatty acid ammo Um, fatty acids and salts thereof such as palm kernel oil fatty ammonium,
【0022】ラウリル硫酸ナトリウム、ラウリル硫酸カ
リウム、ミリスチル硫酸ナトリウム、ミリスチル硫酸カ
リウム等のアルキル硫酸エステルおよびその塩、ラウリ
ルリン酸ナトリウム、ミリスチルリン酸ナトリウムなど
のアルキルリン酸およびその塩、ラウリル硫酸トリエタ
ノールアミンエーテル、ミリスチルリン酸トリエタノー
ルアミンエーテル、ヤシ油脂肪酸アルキル硫酸トリエタ
ノールアミンエーテルなどのアルキル硫酸トリエタノー
ルアミンエーテルおよびその塩、ラウリルスルホン酸ナ
トリウム、ミリスチルスルホン酸ナトリウム、ヤシ油ア
ルキルスルホン酸ナトリウム等のアルキルスルホン酸お
よびその塩、ラウリルリン酸ナトリウム、ミリスチルリ
ン酸ナトリウム、ヤシ油脂肪酸リン酸ナトリウムなどの
アルキルリン酸およびその塩、ドデセンスルホン酸ナト
リウム、テトラデセンスルホン酸ナトリウム、ドデセン
スルホン酸カリウム、テトラデセンスルホン酸カリウム
などのα−オレフィンスルホン酸およびその塩、Alkyl sulfates and salts thereof such as sodium lauryl sulfate, potassium lauryl sulfate, sodium myristyl sulfate and potassium myristyl sulfate; alkyl phosphoric acids and salts thereof such as sodium lauryl phosphate and sodium myristyl phosphate; triethanolamine lauryl sulfate Alkyl triethanolamine ethers such as ether, myristyl phosphate triethanolamine ether, coconut oil fatty acid alkyl sulfate triethanolamine ether and salts thereof, alkyls such as sodium lauryl sulfonate, sodium myristyl sulfonate, and coconut oil sodium alkyl sulfonate Alkyl phosphates such as sulfonic acid and its salts, sodium lauryl phosphate, sodium myristyl phosphate, and coconut oil fatty acid sodium phosphate. Beauty its salts, sodium Dodesensuruhon acid, sodium tetradecene sulfonate, potassium Dodesensuruhon acid, alpha-olefin sulfonate and salts thereof such as potassium tetradecene sulfonate,
【0023】リニアドデシルベンゼン硫酸およびその塩
などの直鎖および分岐鎖アルキルベンゼン硫酸およびそ
の塩、リニアドデシルベンゼンスルホン酸およびその塩
などの直鎖および分岐鎖アルキルベンゼンスルホン酸お
よびその塩、ラウロイルメチルタウリンナトリウム、ミ
リストイルメチルタウリンナトリウム、ヤシ油脂肪酸ア
シルメチルタウリンナトリウム、ラウロイルメチルタウ
リンカリウム、ミリストイルメチルタウリンカリウム、
ヤシ油脂肪酸アシルメチルタウリンカリウム、ラウロイ
ルメチルタウリントリエタノールアミン、ミリストイル
メチルタウリントリエタノールアミン、ヤシ油脂肪酸ア
シルメチルタウリントリエタノールアミンなどのアシル
メチルタウリンおよびその塩、ラウロイルメチル−β−
アラニンナトリウム、ミリストイルメチル−β−アラニ
ンナトリウム、ヤシ油脂肪酸アシルメチル−β−アラニ
ンナトリウム、ラウロイルメチル−β−アラニンカリウ
ム、ミリストイルメチル−β−アラニンカリウム、ヤシ
油脂肪酸アシルメチル−β−アラニンカリウム、ラウロ
イルメチル−β−アラニントリエタノールアミン、ミリ
ストイルメチル−β−アラニントリエタノールアミン、
ヤシ油脂肪酸アシルメチル−β−アラニントリエタノー
ルアミンなどのアシルメチル−β−アラニンおよびその
塩、Linear and branched-chain alkylbenzenesulfuric acid and its salts such as linear dodecylbenzenesulfuric acid and its salts; linear and branched-chain alkylbenzenesulfonic acids and its salts such as linear dodecylbenzenesulfonic acid and its salts; lauroylmethyltaurine sodium; Myristoyl methyltaurine sodium, coconut oil fatty acid acylmethyltaurine sodium, lauroylmethyltaurine potassium, myristoylmethyltaurine potassium,
Acylmethyltaurine such as coconut oil fatty acid potassium acylmethyltaurine, lauroylmethyltaurine triethanolamine, myristoylmethyltaurine triethanolamine, coconut oil fatty acid acylmethyltaurine triethanolamine and salts thereof, lauroylmethyl-β-
Sodium alanine, sodium myristoylmethyl-β-alanine, coconut oil fatty acid acylmethyl-β-alanine, potassium lauroylmethyl-β-alanine, potassium myristoylmethyl-β-alanine, coconut fatty acid acylmethyl-β-alanine potassium, lauroylmethyl- β-alanine triethanolamine, myristoylmethyl-β-alanine triethanolamine,
Acylmethyl-β-alanine and salts thereof, such as coconut fatty acid acylmethyl-β-alanine triethanolamine;
【0024】N−ラウロイルグルタミン酸ナトリウム、
N−ミリストイルグルタミン酸ナトリウム、N−ヤシ油
脂肪酸アシルグルタミン酸ナトリウム、N−硬化牛脂脂
肪酸アシルグルタミン酸ナトリウム、N−牛脂/ヤシ油
混合脂肪酸アシルグルタミン酸ナトリウム、N−ラウロ
イルグルタミン酸カリウム、N−ミリストイルグルタミ
ン酸カリウム、N−ヤシ油脂肪酸アシルグルタミン酸カ
リウム、N−硬化牛脂脂肪酸アシルグルタミン酸カリウ
ム、N−牛脂/ヤシ油混合脂肪酸アシルグルタミン酸カ
リウム、N−ラウロイルグルタミン酸トリエタノールア
ミン、N−ミリストイルグルタミン酸トリエタノールア
ミン、N−ヤシ油脂肪酸アシルグルタミン酸トリエタノ
ールアミン、N−硬化牛脂脂肪酸アシルグルタミン酸ト
リエタノールアミン、N−牛脂/ヤシ油混合脂肪酸アシ
ルグルタミン酸トリエタノールアミン等のN−アシルグ
ルタミン酸およびその塩、Sodium N-lauroyl glutamate,
Sodium N-myristoyl glutamate, N-coconut oil fatty acid acylglutamate, N-hardened tallow fatty acid sodium acylglutamate, N-tallow / coconut oil mixed fatty acid sodium acylglutamate, N-lauroyl glutamate, potassium N-myristoyl glutamate, N- Potassium coconut fatty acid acylglutamate, potassium N-hardened tallow fatty acid acylglutamate, potassium N-fatty acid / coconut oil mixed fatty acylglutamate, N-lauroylglutamate triethanolamine, N-myristoylglutamate triethanolamine, N-coconut fatty acid acyl Glutamate triethanolamine, N-hardened tallow fatty acid acylglutamate triethanolamine, N-tallow / coconut oil mixed fatty acid acylglutamate N- acyl glutamic acid and its salts such as ethanolamine,
【0025】ラウロイルサルコシンナトリウム、ミリス
トイルサルコシン、パルミトイルサルコシン、オレオイ
ルサルコシン等のN−アシルサルコシンおよびその塩等
のN−アシルアミノ酸およびその塩、ポリオキシエチレ
ンラウリルエーテル硫酸ナトリウム、ポリオキシエチレ
ンセチルエーテル硫酸ナトリウム、ポリオキシエチレン
オレイルエーテル硫酸ナトリウム等のポリオキシエチレ
ンアルキルエーテル硫酸およびその塩、ポリオキシエチ
レンラウリルエーテルリン酸ナトリウム、ポリオキシエ
チレンセチルエーテルリン酸ナトリウム、ポリオキシエ
チレンオレイルエーテルリン酸ナトリウム等のポリオキ
シエチレンアルキルエーテルリン酸およびその塩、カル
ボキシル化ポリオキシエチレントリデシルエーテルナト
リウム塩、などのエーテルカルボン酸およびその塩、N-acyl sarcosine such as sodium lauroyl sarcosine, myristoyl sarcosine, palmitoyl sarcosine, oleoyl sarcosine and salts thereof and N-acyl amino acids and salts thereof, sodium polyoxyethylene lauryl ether sulfate, sodium polyoxyethylene cetyl ether sulfate , Polyoxyethylene alkyl ether sulfates such as sodium polyoxyethylene oleyl ether sulfate and salts thereof, polyoxyethylenes such as sodium polyoxyethylene lauryl ether phosphate, sodium polyoxyethylene cetyl ether phosphate, and sodium polyoxyethylene oleyl ether phosphate. Ethylene alkyl ether phosphoric acid and its salts, carboxylated polyoxyethylene tridecyl ether sodium salt, etc. Terukarubon acid and its salts,
【0026】ラウロイルイセチオン酸、ミリストイルイ
セチオン酸、ヤシ油脂肪酸アシルイセチオン酸等のアニ
オン界面活性剤、;ラウリルジメチルアミノ酢酸ベタイ
ン、ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ベ
タイン等の酢酸ベタイン、アルキルカルボキシメチルヒ
ドロキシエチルイミダゾリニウムベタイン、アルキルソ
ジウムカルボキシメチルカルボキシエチルイミダゾリニ
ウムベタイン等のイミダゾリニウムベタイン、ヤシ油ア
ルキルベタイン、ラウリルベタイン等のアルキルベタイ
ン、ビス(ステアリルヒドロキシエチルイミダゾリン)
クロル酢酸錯体等の両性活性剤、レシチン、ラノリン、
コレステロール、サポニン等の天然界面活性剤、アルギ
ン酸ナトリウム、澱粉誘導体、トラガントゴム等の高分
子界面活性剤;香料;精製水等を配合することができ
る。Anionic surfactants such as lauroylisethionic acid, myristoyl isethionic acid and coconut fatty acid acyl isethionic acid; betaines such as lauryldimethylaminoacetic acid betaine and coconut fatty acid amidopropyldimethylaminoacetic acid betaine; alkylcarboxymethylhydroxy; Imidazolinium betaines such as ethyl imidazolinium betaine and alkyl sodium carboxymethyl carboxyethyl imidazolinium betaine; alkyl betaines such as coconut oil alkyl betaine and lauryl betaine; and bis (stearylhydroxyethylimidazoline)
Amphoteric activators such as chloroacetic acid complexes, lecithin, lanolin,
Natural surfactants such as cholesterol and saponin, polymer surfactants such as sodium alginate, starch derivatives and tragacanth gum; fragrances; purified water and the like can be added.
【0027】[0027]
【発明の実施の形態】次に、本発明を実施例によりさら
に詳細に説明するが、本発明はこれによって何ら限定さ
れるものではない。なお配合量の数値は、化粧料に対す
る重量%によりあらわす。Now, the present invention will be described in further detail with reference to Examples. However, it should be understood that the present invention is by no means restricted by such specific Examples. In addition, the numerical value of a compounding amount is represented by the weight% with respect to cosmetics.
【0028】[0028]
【実施例1、比較例1〜7】(化粧水)表1に示す処方
の化粧水を次の方法で作成した。精製水に保湿剤を加
え、室温下で溶解する。一方流動パラフィンにエモリエ
ント剤、界面活性剤を加え室温下で溶解する。このパラ
フィン相を前述水相に添加しマイクロエマルジョンを調
整する。Example 1, Comparative Examples 1 to 7 (Lotion) A lotion having the formulation shown in Table 1 was prepared by the following method. Add humectant to purified water and dissolve at room temperature. On the other hand, an emollient and a surfactant are added to liquid paraffin and dissolved at room temperature. This paraffin phase is added to the aqueous phase to prepare a microemulsion.
【0029】表1の下表はベースとなる配合成分で.こ
れに表1の上表の成分をそれぞれ添加し試料を作成し
た。 (評価)表1に示す成分を含有する化粧水につき、使用
感を評価した。女性8名のパネラーの前腕に、0.3m
l塗布した後、のび、つっぱり感、べたつき、滑らかさ
の4項目につき官能評価により判定した。The lower table in Table 1 shows the base components. The components shown in the upper table of Table 1 were respectively added thereto to prepare samples. (Evaluation) The feeling of use of the lotion containing the components shown in Table 1 was evaluated. 0.3m on the forearm of eight female panelists
After coating, the four items of stretch, tightness, stickiness, and smoothness were evaluated by sensory evaluation.
【0030】評価基準は、以下の通りとした。 好ましい感触 2点 やや好ましい 1点 普通 0点 やや好ましくない −1点 好ましくない −2点 そして、5段階評価の平均を求め、評価判定を下記のよ
うに表示した。結果を表2に示す。The evaluation criteria were as follows. Preferred feel 2 points Somewhat favorable 1 point Normal 0 point Somewhat unfavorable -1 point Unfavorable -2 points The average of the five-level evaluation was obtained, and the evaluation judgment was displayed as follows. Table 2 shows the results.
【0031】 1.5以上〜 2.0 ; ◎ 0.5以上〜 1.5未満 ; ○ −0.5以上〜 0.5未満 ; △ −2.0 〜−0.5未満 ; ×1.5 or more to 2.0; ◎ 0.5 or more to less than 1.5; ○ -0.5 or more to less than 0.5; Δ -2.0 to less than -0.5; ×
【0032】[0032]
【実施例2および比較例8】(スキンクリーム)表3に
しめす処方のスキンクリームをつぎに示す方法で作っ
た。サラシミツロウ、自己乳化型モノステアリン酸グリ
セリン、スクワラン、ステアリン酸、ベヘニルアルコー
ル、メチルポリシロキサン、オクタン酸セチル、パルミ
チン酸セチル、吸着精製ラノリンを85℃にて混和す
る。これとは別に、ラフィノース、水酸化ナトリウムを
精製水の一部に溶解し、両者を混合する。乳化後、残り
の精製水を加え、75℃まで再加熱後冷却して用いる。 (評価)10名のパネルに対し、各1gを皮膚に塗布
し、10分間放置した後に皮膚のさっぱり感を評価し
た。Example 2 and Comparative Example 8 (Skin cream) A skin cream having the formulation shown in Table 3 was prepared by the following method. The beeswax, self-emulsifying glyceryl monostearate, squalane, stearic acid, behenyl alcohol, methylpolysiloxane, cetyl octanoate, cetyl palmitate, and adsorbed purified lanolin are mixed at 85 ° C. Separately, raffinose and sodium hydroxide are dissolved in a part of purified water, and both are mixed. After emulsification, the remaining purified water is added, the mixture is reheated to 75 ° C., and then cooled and used. (Evaluation) For 10 panels, 1 g of each was applied to the skin, and after leaving it for 10 minutes, the refreshing feeling of the skin was evaluated.
【0033】 実施例2の方が好ましいと評価したパネル 10名 比較例8の方が好ましいと評価したパネル 0名10 panelists evaluated that Example 2 was more preferable 0 panel panels evaluated that Comparative Example 8 was more preferable
【0034】[0034]
【実施例3および比較例9】(乳液)表4に示す処方の
乳液を次に示す方法で作成した。精製水にラフィノース
またはポリエチレングリコール1500、トリエタノー
ルアミンを加え、80℃に加温する。ステアリン酸、セ
タノール、ワセリン、スクワラン、流動パラフィンを溶
解し、これにソルビタンモノオレイン酸エステルを加え
80℃に調整する。この油相を先に調整した水相に加え
予備乳化後、ホモミキサーにて乳化、冷却して用いる。 (評価)12名のパネルに対し、1gを皮膚に塗布後、
10分間放置した後、皮膚のべたつきを評価した。Example 3 and Comparative Example 9 (Emulsion) An emulsion having the formulation shown in Table 4 was prepared by the following method. Raffinose or polyethylene glycol 1500 and triethanolamine are added to purified water, and the mixture is heated to 80 ° C. Stearic acid, cetanol, petrolatum, squalane, and liquid paraffin are dissolved, and sorbitan monooleate is added thereto, and the mixture is adjusted to 80 ° C. This oil phase is added to the previously prepared aqueous phase, pre-emulsified, then emulsified and cooled with a homomixer before use. (Evaluation) After applying 1 g to the skin for 12 panels,
After standing for 10 minutes, the stickiness of the skin was evaluated.
【0035】 実施例3が好ましいと評価したパネル 9名 比較例9が好ましいと評価したパネル 2名 同じと評価したパネル 1名9 panels evaluated as preferred in Example 3 2 panels evaluated as preferred in Comparative Example 9 1 panel evaluated as the same
【0036】[0036]
【実施例4および比較例10】(パック)表5に示す処
方のパックを次に示す方法で作成した。精製水にラフィ
ノース又はPEG400、モンモリロナイト、N−ラウ
ロイルグルタミン酸ナトリウムを加え、十分に分散させ
る。 (評価)10名のパネルに対し適量を顔面に塗布し、3
0分間放置した後に洗い流し、乾燥したタオルで水分を
軽く拭いた後に、さっぱり感を評価した。Example 4 and Comparative Example 10 (Pack) A pack having the formulation shown in Table 5 was prepared by the following method. Raffinose or PEG400, montmorillonite, and sodium N-lauroylglutamate are added to the purified water and sufficiently dispersed. (Evaluation) Apply an appropriate amount to the face of 10
After leaving it for 0 minutes, it was washed away, and after gently wiping the water with a dry towel, the refreshing feeling was evaluated.
【0037】 実施例4が好ましいと評価したパネル 9名 比較例10が好ましいと評価したパネル 1名9 panels evaluated as preferred in Example 4 1 panel evaluated as preferred in Comparative Example 10
【0038】[0038]
【実施例5および比較例11】(アフターシェービング
ローション)表6に示すアフターシェービングローショ
ンを次に示す方法で作成した。精製水にラフィノース又
はグリセロールとアラントインを加え溶解する。エタノ
ールに他の成分を加え、溶解する。これに先の水相を加
え用いる。 (評価)男性パネル15名により西洋カミソリを用いて
ひげ剃り後製剤を塗布し、10分間放置した後にサッパ
リ感を評価した。Example 5 and Comparative Example 11 (After Shaving Lotion) An after shaving lotion shown in Table 6 was prepared by the following method. Add raffinose or glycerol and allantoin to purified water and dissolve. Add other components to ethanol and dissolve. The above aqueous phase is added and used. (Evaluation) After shaving using a Western razor, the formulation was applied by 15 male panels and left for 10 minutes to evaluate the refreshing feeling.
【0039】 実施例5が好ましいと評価したパネル 11名 比較例11が好ましいと評価したパネル 2名 同じと評価したパネル 2名11 panels evaluated as preferred in Example 5 2 panels evaluated as preferred in Comparative Example 11 2 panel evaluated as the same
【0040】[0040]
【実施例6および比較例12】(ファンデーション)表
7に示すファンデーションを次に示す方法で作成した。
ベントナイトをプロピレングリコールに分散してから精
製水に加え70℃でホモミキサー処理した後、POEソ
ルビタンモノステアレート、トリエタノールアミンおよ
びラフィノースまたはグリセリンとプロピレングリコー
ルを添加し十分に攪拌する。これに十分粉砕混合したタ
ルク、二酸化チタン、ベンガラ、黄酸化鉄、黒酸化鉄を
攪拌しながら添加し、70℃でホモミキサー処理する。
次に70〜80℃で加熱溶解されたステアリン酸、イソ
ヘキサデシルアルコール、モノステアリン酸グリセリ
ン、液状ラノリン、流動パラフィンを徐々に添加し、7
0℃でホモミキサー処理する。これを室温まで攪拌しな
がら冷却して用いる。 (評価)8名のパネルにより顔面に塗布して用い8時間
後に化粧崩れを評価した。Example 6 and Comparative Example 12 (Foundation) The foundations shown in Table 7 were prepared by the following method.
After bentonite is dispersed in propylene glycol, the mixture is added to purified water and treated with a homomixer at 70 ° C., and then POE sorbitan monostearate, triethanolamine and raffinose or glycerin and propylene glycol are added, followed by sufficient stirring. Talc, titanium dioxide, red iron oxide, yellow iron oxide and black iron oxide, which have been sufficiently pulverized and mixed, are added thereto with stirring, and homomixed at 70 ° C.
Next, stearic acid, isohexadecyl alcohol, glyceryl monostearate, liquid lanolin, and liquid paraffin, which had been heated and dissolved at 70 to 80 ° C., were gradually added.
Homomixer at 0 ° C. This is cooled and used while stirring to room temperature. (Evaluation) Eight hours after the application to the face by a panel of eight people, the makeup collapse was evaluated.
【0041】 実施例6が好ましいと評価したパネル 5名 比較例12が好ましいと評価したパネル 3名5 panels evaluated that Example 6 was preferable 3 panels evaluated that Comparative Example 12 was preferable
【0042】[0042]
【実施例7および比較例13】(洗顔料)表8に示す配
合にしたがって使用後の感触が改善された洗顔料を得
た。全量を混合し全量を100として,80℃で均一に
した後に冷却し固化させた。 (評価)8名のパネルにより洗顔を行い、使用後のサッ
パリ感を評価した 実施例7が好ましいと評価したパネル 6名 比較例13が好ましいと評価したパネル 1名 同じと評価したパネル 1名Example 7 and Comparative Example 13 (Facial cleansing) According to the composition shown in Table 8, a facial cleanser having an improved feel after use was obtained. The whole amount was mixed to make the total amount 100, and the mixture was made uniform at 80 ° C., then cooled and solidified. (Evaluation) Eight panel members washed their face and evaluated the refreshing feeling after use. Six panel members evaluated that Example 7 was preferable. 6 panel members who evaluated Comparative Example 13 as preferable. 1 panel.
【0043】[0043]
【実施例8および比較例14】(ゲル状洗顔料)表9に
示す配合によって使用感の改善されたゲル状洗顔料を得
た。(A)と(B)をそれぞれ加熱混合した後に合わ
せ、これに(C)を添加して冷却後充填した。 (評価)11名のパネルにより洗顔を行い使用後の皮膚
の滑らかさを評価した。Example 8 and Comparative Example 14 (Gel-like facial cleanser) A gel-like facial cleanser having an improved feeling in use was obtained by the formulation shown in Table 9. (A) and (B) were mixed after heating and mixing, respectively, and (C) was added thereto, followed by cooling and filling. (Evaluation) The face was washed with a panel of 11 persons, and the smoothness of the skin after use was evaluated.
【0044】 実施例8が好ましいと評価したパネル 8名 比較例14が好ましいと評価したパネル 3名8 panelists evaluated that Example 8 was preferable 3 panel panels evaluated that Comparative Example 14 was preferable
【0045】[0045]
【実施例9および比較例15】(スキンローション)表
10に示す配合により、使用後のしっとり感が増したス
キンローションを得た。(A)(B)をそれぞれ80℃
で加熱混合し,均一にした後に(B)に(C)を加え,
全量を合わせ,真空乳化機で乳化する。冷却後充填し
た。 (評価)8名のパネルに対し,各3gを皮膚に塗布し,
10分間放置した後に皮膚のしっとり感を評価した 実施例9が好ましいと評価したパネル 6名 比較例15が好ましいと評価したパネル 2名Example 9 and Comparative Example 15 (Skin Lotion) By the formulation shown in Table 10, a skin lotion having a moist feeling after use was obtained. (A) and (B) each at 80 ° C
After heating and mixing to make it uniform, add (C) to (B),
Combine all the ingredients and emulsify with a vacuum emulsifier. Filled after cooling. (Evaluation) 3 g of each was applied to the skin for 8 panels,
After standing for 10 minutes, the moist feeling of the skin was evaluated. Six panels evaluated that Example 9 was preferable. Two panels evaluated that Comparative Example 15 was preferable.
【0046】[0046]
【実施例10および比較例16】(クリーム)表11に
示す処方にしたがって皮膚に対する伸びの良いクリーム
を得た。(A)(B)をそれぞれ80℃で加熱混合し,
均一にした後に(B)に(C)を加え,全量を合わせ,
真空乳化機で乳化する。冷却後充填した。 (評価)12名のパネルに対し,各1gを皮膚に塗布
し,クリームの伸びを評価した 実施例10が好ましいと評価したパネル 8名 比較例16が好ましいと評価したパネル 2名 同じと評価したパネル 2名Example 10 and Comparative Example 16 (Cream) According to the formulation shown in Table 11, a cream having good stretchability on the skin was obtained. (A) and (B) are each heated and mixed at 80 ° C.
After homogenizing, add (C) to (B) and combine all
Emulsify with a vacuum emulsifier. Filled after cooling. (Evaluation) 1 g of each was applied to the skin for 12 panels, and the elongation of the cream was evaluated. 8 panels evaluated as preferred in Example 10 2 panels evaluated as preferred in Comparative Example 16 2 evaluated as the same Panel 2 people
【0047】[0047]
【実施例11および比較例17】(化粧水)表12の処
方にしたがって皮膚のしっとり感が持続する化粧水を得
た。卵黄油,架橋型メチルポリシロキサン,マイクロク
リスタリンワックス,エタノール,フェノキシエタノー
ルを測り取り80℃で加熱溶解する。残部を測り取り8
0℃で均一となるまで混合する。両者を併せ真空乳化機
で乳化させ,冷却後充填する。 (評価)15名のパネルに対し,各々約2gを皮膚に塗
布し,5分後と1時間後にしっとり感を評価した。EXAMPLE 11 AND COMPARATIVE EXAMPLE 17 (Lotion) According to the formulation shown in Table 12, a lotion having a moist feeling on the skin was obtained. Egg yolk oil, cross-linked methylpolysiloxane, microcrystalline wax, ethanol and phenoxyethanol are measured and dissolved by heating at 80 ° C. Measure the rest 8
Mix at 0 ° C. until uniform. The two are combined and emulsified by a vacuum emulsifier, cooled and filled. (Evaluation) About 2 g of each of 15 panels were applied to the skin, and after 5 minutes and 1 hour, the moist feeling was evaluated.
【0048】5分後 実施例11が好ましいと評価したパネル 10名 比較例17が好ましいと評価したパネル 5名 1時間後 実施例11が好ましいと評価したパネル 14名 比較例17が好ましいと評価したパネル 1名After 5 minutes, 10 panels evaluated that Example 11 was preferable. 5 panels evaluated that Comparative Example 17 was preferable. 5 panelists 1 hour after. 14 panels evaluated that Example 11 was preferable. Panel 1 person
【0049】[0049]
【表1】 [Table 1]
【0050】[0050]
【表2】 [Table 2]
【0051】[0051]
【表3】 [Table 3]
【0052】[0052]
【表4】 [Table 4]
【0053】[0053]
【表5】 [Table 5]
【0054】[0054]
【表6】 [Table 6]
【0055】[0055]
【表7】 [Table 7]
【0056】[0056]
【表8】 [Table 8]
【0057】[0057]
【表9】 [Table 9]
【0058】[0058]
【表10】 [Table 10]
【0059】[0059]
【表11】 [Table 11]
【0060】[0060]
【表12】 [Table 12]
【0061】[0061]
【発明の効果】本発明により、塗布時にべたつきが無く
サッパリ感があり、のびが良く、肌のなめらかさを与
え、化粧崩れしにくい皮膚化粧料を得ることが出来る。Industrial Applicability According to the present invention, it is possible to obtain a skin cosmetic which has no stickiness at the time of application, has a refreshing feeling, spreads well, gives skin smoothness, and does not easily lose its makeup.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI A61K 7/02 A61K 7/02 A 7/035 7/035 31/00 617 31/00 617J ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 6 Identification code FI A61K 7/02 A61K 7/02 A 7/035 7/035 31/00 617 31/00 617J
Claims (2)
料。1. A skin cosmetic comprising raffinose.
〜35重量%配合されてなる、請求項1に記載の皮膚化
粧料。2. Raffinose is contained in the skin cosmetic in an amount of 0.1%.
The skin cosmetic according to claim 1, which is contained in an amount of up to 35% by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6876599A JPH11322574A (en) | 1998-03-16 | 1999-03-15 | Skin cosmetic |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6587098 | 1998-03-16 | ||
JP10-65870 | 1998-03-16 | ||
JP6876599A JPH11322574A (en) | 1998-03-16 | 1999-03-15 | Skin cosmetic |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH11322574A true JPH11322574A (en) | 1999-11-24 |
Family
ID=26407031
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6876599A Pending JPH11322574A (en) | 1998-03-16 | 1999-03-15 | Skin cosmetic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH11322574A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000063223A (en) * | 1998-08-20 | 2000-02-29 | Kanebo Ltd | Cosmetic for adjusting makeup and makeup |
JP2001226215A (en) * | 1999-12-10 | 2001-08-21 | Kanebo Ltd | Cosmetic and method of producing ether derivative of raffinose |
JP2005255668A (en) * | 2005-01-07 | 2005-09-22 | Musashino Meneki Kenkyusho:Kk | Cosmetics |
JP2006045186A (en) * | 2004-07-05 | 2006-02-16 | Fancl Corp | Lamella structure regenerative agent and skin external preparation |
JP2006273813A (en) * | 2005-03-30 | 2006-10-12 | Naris Cosmetics Co Ltd | Gel-like composition |
JP2008255009A (en) * | 2007-03-30 | 2008-10-23 | Naris Cosmetics Co Ltd | Humectant powder for skin |
-
1999
- 1999-03-15 JP JP6876599A patent/JPH11322574A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000063223A (en) * | 1998-08-20 | 2000-02-29 | Kanebo Ltd | Cosmetic for adjusting makeup and makeup |
JP2001226215A (en) * | 1999-12-10 | 2001-08-21 | Kanebo Ltd | Cosmetic and method of producing ether derivative of raffinose |
JP2006045186A (en) * | 2004-07-05 | 2006-02-16 | Fancl Corp | Lamella structure regenerative agent and skin external preparation |
JP2005255668A (en) * | 2005-01-07 | 2005-09-22 | Musashino Meneki Kenkyusho:Kk | Cosmetics |
JP2006273813A (en) * | 2005-03-30 | 2006-10-12 | Naris Cosmetics Co Ltd | Gel-like composition |
JP2008255009A (en) * | 2007-03-30 | 2008-10-23 | Naris Cosmetics Co Ltd | Humectant powder for skin |
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