JPH0892046A - Hair cosmetic - Google Patents
Hair cosmeticInfo
- Publication number
- JPH0892046A JPH0892046A JP25616994A JP25616994A JPH0892046A JP H0892046 A JPH0892046 A JP H0892046A JP 25616994 A JP25616994 A JP 25616994A JP 25616994 A JP25616994 A JP 25616994A JP H0892046 A JPH0892046 A JP H0892046A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- hair
- ester
- monomer
- acrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 12
- 239000000178 monomer Substances 0.000 claims abstract description 43
- 239000011347 resin Substances 0.000 claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 150000002148 esters Chemical class 0.000 claims abstract description 16
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 12
- -1 aliphatic alcohol ester Chemical class 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 10
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 5
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 4
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 4
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 4
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 5
- 239000003380 propellant Substances 0.000 claims description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 238000013329 compounding Methods 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 239000000443 aerosol Substances 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 150000003926 acrylamides Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 150000001721 carbon Chemical group 0.000 claims 1
- 239000011550 stock solution Substances 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 20
- 239000004925 Acrylic resin Substances 0.000 abstract description 3
- 229920000178 Acrylic resin Polymers 0.000 abstract description 3
- 229920001577 copolymer Polymers 0.000 abstract description 3
- 239000002932 luster Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
- 239000003915 liquefied petroleum gas Substances 0.000 description 14
- 235000019441 ethanol Nutrition 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- UYZQWKKNVBJVOF-UHFFFAOYSA-N 1-decoxytetradecane Chemical compound CCCCCCCCCCCCCCOCCCCCCCCCC UYZQWKKNVBJVOF-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000008266 hair spray Substances 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 2
- KCAMXZBMXVIIQN-UHFFFAOYSA-N octan-3-yl 2-methylprop-2-enoate Chemical compound CCCCCC(CC)OC(=O)C(C)=C KCAMXZBMXVIIQN-UHFFFAOYSA-N 0.000 description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 2
- PXDJXZJSCPSGGI-UHFFFAOYSA-N palmityl palmitate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- XZHNPVKXBNDGJD-UHFFFAOYSA-N tetradecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCOC(=O)C=C XZHNPVKXBNDGJD-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- IOAOAKDONABGPZ-UHFFFAOYSA-N 2-amino-2-ethylpropane-1,3-diol Chemical compound CCC(N)(CO)CO IOAOAKDONABGPZ-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- SFPNZPQIIAJXGL-UHFFFAOYSA-N 2-ethoxyethyl 2-methylprop-2-enoate Chemical compound CCOCCOC(=O)C(C)=C SFPNZPQIIAJXGL-UHFFFAOYSA-N 0.000 description 1
- FWWXYLGCHHIKNY-UHFFFAOYSA-N 2-ethoxyethyl prop-2-enoate Chemical compound CCOCCOC(=O)C=C FWWXYLGCHHIKNY-UHFFFAOYSA-N 0.000 description 1
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 description 1
- GVTFIGQDTWPFTA-UHFFFAOYSA-N 4-bromo-2-chloro-1-isothiocyanatobenzene Chemical compound ClC1=CC(Br)=CC=C1N=C=S GVTFIGQDTWPFTA-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 1
- BOUIEBMBWBCUPB-UHFFFAOYSA-N decyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCC BOUIEBMBWBCUPB-UHFFFAOYSA-N 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- DWMMZQMXUWUJME-UHFFFAOYSA-N hexadecyl octanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCC DWMMZQMXUWUJME-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical group CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- ZKGRELFDBYFQAZ-UHFFFAOYSA-N octadecyl decanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCC ZKGRELFDBYFQAZ-UHFFFAOYSA-N 0.000 description 1
- QWPNJOHZHSJFIY-UHFFFAOYSA-N octyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCC QWPNJOHZHSJFIY-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- PVJXQWMBHUOOCK-UHFFFAOYSA-N tetradecyl decanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCC PVJXQWMBHUOOCK-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、毛髪に対し、まぶしい
ほどに魅惑的な光沢を付与しながら、かつ優れたセット
保持力を有する毛髪化粧料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair cosmetic composition which imparts a dazzlingly fascinating luster to hair and has an excellent set holding power.
【０００２】[0002]
【従来の技術および発明が解決しようとする課題】従
来、毛髪化粧料には毛髪を固定する目的で、ポリビニル
ピロリドン系ポリマー、酸性ポリビニルエーテル系ポリ
マー、酸性アクリル系ポリマー、カチオン性ポリマー等
の樹脂が配合されており、近年ではアクリル樹脂アルカ
ノールアミンよりなる液化石油ガス（ＬＰＧ）に対する
溶解性のよい整髪用樹脂も開発されている（特開平３−
２０６０２３号公報、特開平３−２０３０２４号公
報）。また、毛髪に光沢を与える目的で、炭化水素油、
油脂、多価アルコール、常温液体のシリコーンオイル、
エステル類等の油分が配合されており、最近、このよう
な機能へのニーズは非常に高いものとなっている。しか
しながら、高い毛髪固定力を持つ成分に光沢を与えよう
と油分を添加すると、それによって（無添加のものに比
べて）セット性が低減してしまうといった問題点があっ
た。2. Description of the Related Art Conventionally, resins such as polyvinylpyrrolidone type polymers, acidic polyvinyl ether type polymers, acidic acrylic type polymers and cationic polymers have been used in hair cosmetics for the purpose of fixing hair. In recent years, a hair styling resin which is blended and has good solubility in liquefied petroleum gas (LPG) made of an acrylic resin alkanolamine has been developed (JP-A-3-
No. 206023, JP-A-3-203024). Also, for the purpose of giving gloss to the hair, hydrocarbon oil,
Oils and fats, polyhydric alcohols, normal temperature liquid silicone oil,
Since oils such as esters are blended, the needs for such a function have recently become extremely high. However, when an oil component is added in order to give gloss to a component having a high hair fixing power, there is a problem that the setting property is reduced (compared to the one without addition).
【０００３】[0003]
【課題を解決するための手段】本発明者らは、このよう
な問題点を克服すべく、鋭意研究を行った。その結果、
特定のアクリル樹脂アルカノールアミン液と特定のエス
テルとを組み合わせれば、セット性に優れ、かつ良好な
光沢をも有する毛髪化粧料が得られることを見い出し、
この知見に基づいて本発明を完成するに至った。[Means for Solving the Problems] The inventors of the present invention have conducted diligent research in order to overcome such problems. as a result,
It was found that by combining a specific acrylic resin alkanolamine solution and a specific ester, a hair cosmetic composition having excellent settability and also having good gloss can be obtained.
The present invention has been completed based on this finding.
【０００４】すなわち、本発明は次の成分（Ａ）と、成
分（Ｂ）とを配合することを特徴とする毛髪化粧料であ
る。That is, the present invention is a hair cosmetic characterized by containing the following component (A) and component (B).
【０００５】（Ａ）次の重合性単量体ａ〜ｄを共重合
し、水溶性有機塩基性物質で中和してなる整髪用樹脂。 ａ．アクリル酸、メタクリル酸およびイタコン酸からな
る群より選ばれた少なくとも１種の単量体 ６．０〜３
５．０重量％ ｂ．アクリル酸及び／又はメタクリル酸の炭素数１０〜
１８の脂肪族アルコールのエステルからなる少なくとも
１種の単量体 １５．０〜５０．０重量％ ｃ．アクリル酸及び／又はメタクリル酸の炭素数４〜８
の脂肪族アルコールのエステルからなる少なくとも１種
の単量体 １５．０〜５０．０重量％ ｄ．その他のビニル系単量体 １５．０〜５０．０重量
％(A) A hair styling resin obtained by copolymerizing the following polymerizable monomers a to d and neutralizing it with a water-soluble organic basic substance. a. At least one monomer selected from the group consisting of acrylic acid, methacrylic acid and itaconic acid 6.0-3
5.0% by weight b. 10 to 10 carbon atoms of acrylic acid and / or methacrylic acid
At least one monomer consisting of an ester of 18 aliphatic alcohols 15.0 to 50.0% by weight c. Acrylic acid and / or methacrylic acid having 4 to 8 carbon atoms
At least one monomer consisting of ester of aliphatic alcohol of 15.0 to 50.0% by weight d. Other vinyl monomers 15.0-50.0% by weight
【０００６】（Ｂ）一般式（Ｉ）：(B) General formula (I):
【０００７】[0007]
【化４】R1−CO−O−R2 …（Ｉ）Embedded image R 1 —CO—O—R 2 (I)
【０００８】（Ｒ1、Ｒ2は炭素数が６〜１８の直鎖ある
いは分岐の炭化水素基を表す。）で表されるエステルの
１種または２種以上。(R 1 and R 2 represent a linear or branched hydrocarbon group having 6 to 18 carbon atoms), and one or more kinds of the ester.
【０００９】また、本発明においては成分（Ａ）の単量
体として、さらに次のｅ成分を加えたものが含まれる。Further, in the present invention, as the monomer of the component (A), a monomer to which the following e component is further added is included.
【００１０】ｅ．一般式（II）：E. General formula (II):
【００１１】[0011]
【化５】 [Chemical 5]
【００１２】（式中、Ｒ3およびＲ4は水素原子またはメ
チル基、Ｒ5は炭素原子数が１〜８のアルキル基または
Ｃ（ＣＨ3）2ＣＨＣＯＣＨ3である。）で表されるＮ−
アルキル置換アクリルアミドから選ばれた少なくとも１
種の単量体 ５．０〜５０．０重量％(Wherein R 3 and R 4 are a hydrogen atom or a methyl group, R 5 is an alkyl group having 1 to 8 carbon atoms or C (CH 3 ) 2 CHCOCH 3 ). −
At least 1 selected from alkyl-substituted acrylamide
Seed monomer 5.0 to 50.0% by weight
【００１３】本発明で使用する成分（Ａ）の整髪用樹脂
において、前記単量体ａは樹脂の親水性や洗髪性に関与
し、その使用量は６．０〜３５．０重量％、好ましくは
１０．０〜３０．０重量％である。前記使用量が６．０
重量％未満の時、得られるフィルムは水に難溶で洗髪性
が不良となり、一方、それが３５．０重量％を超える
と、吸湿量が多くなり、粘着性が顕著となる。単量体ａ
としては、アクリル酸、メタクリル酸およびイタコン酸
からなる群より選ばれた不飽和カルボン酸単量体を単独
または併用で使用することができる。In the hair styling resin of the component (A) used in the present invention, the monomer a is involved in the hydrophilicity and hair washability of the resin, and the amount thereof is 6.0 to 35.0% by weight, preferably Is 10.0 to 30.0% by weight. The amount used is 6.0
If it is less than 5% by weight, the resulting film is poorly soluble in water and the hair washing property is poor, while if it exceeds 35.0% by weight, the amount of moisture absorption increases and the tackiness becomes remarkable. Monomer a
The unsaturated carboxylic acid monomer selected from the group consisting of acrylic acid, methacrylic acid and itaconic acid can be used alone or in combination.
【００１４】単量体ｂは、樹脂の親油性、柔軟性、洗髪
性に関与し、その使用量は１５．０〜５０．０重量％、
好ましくは２０．０〜４５．０重量％である。前記使用
量が１５．０重量％未満のとき、得られるフィルムは硬
く、フレーキング現象を生じ易くなる。一方、それが５
０．０重量％を超えると、得られるフィルムは非常に柔
らかくなって粘着性を示すようになり、洗髪性は不良と
なる。単量体ｂの具体例として、例えば、デシル（メ
タ）アクリレート、ラウリル（メタ）アクリレート、ミ
リスチル（メタ）アクリレート、パルミチル（メタ）ア
クリレート、ステアリル（メタ）アクリレート、オレイ
ル（メタ）アクリレート、トリデシル（メタ）アクリレ
ート等の合成アルコールの（メタ）アクリレート等を単
独または併用で使用することができる。The monomer b is involved in the lipophilicity, softness and hair washability of the resin, and its amount used is 15.0 to 50.0% by weight,
It is preferably 20.0 to 45.0% by weight. When the amount used is less than 15.0% by weight, the obtained film is hard and the flaking phenomenon easily occurs. On the other hand, it is 5
If it exceeds 0.0% by weight, the resulting film becomes very soft and becomes tacky, resulting in poor washability. Specific examples of the monomer b include, for example, decyl (meth) acrylate, lauryl (meth) acrylate, myristyl (meth) acrylate, palmityl (meth) acrylate, stearyl (meth) acrylate, oleyl (meth) acrylate, tridecyl (meth). ) A synthetic alcohol (meth) acrylate such as acrylate can be used alone or in combination.
【００１５】単量体ｃも整髪用樹脂の親油性、柔軟性、
洗髪性に関与し、その使用量は１５．０〜５０．０重量
％、好ましくは２０．０〜４５．０重量％である。前記
使用量が１５．０重量％未満のとき、液化石油ガスに対
する溶解性が不良となり、一方、それが５０．０重量％
を超えると洗髪性が不良となる。単量体ｃの具体例とし
ては、例えば、ｎ−ブチル（メタ）アクリレート、イソ
ブチル（メタ）アクリレート、ターシャリーブチル（メ
タ）アクリレート、ｎ−ヘキシル（メタ）アクリレー
ト、ｎ−オクチル（メタ）アクリレート、２−エチルヘ
キシル（メタ）アクリレート等を単独または併用で使用
することができる。前記単量体ｂと単量体ｃを比較する
と、樹脂の親油性に対する寄与および洗髪性を不良にす
る作用は前者が後者より大であるが、液化石油ガスに対
する溶解性に対する寄与も前者が後者より大である。液
化石油ガスに対する溶解性をより高めるために、単量体
ｂと単量体ｃの合計量が４１．０重量％以上であること
が好ましい。The monomer c is also the lipophilicity and flexibility of the hair styling resin.
It is involved in hair washability, and the amount used is 15.0 to 50.0% by weight, preferably 20.0 to 45.0% by weight. When the amount used is less than 15.0% by weight, the solubility in liquefied petroleum gas becomes poor, while it is 50.0% by weight.
If it exceeds, the hair washability will be poor. Specific examples of the monomer c include, for example, n-butyl (meth) acrylate, isobutyl (meth) acrylate, tertiary butyl (meth) acrylate, n-hexyl (meth) acrylate, n-octyl (meth) acrylate, 2-Ethylhexyl (meth) acrylate and the like can be used alone or in combination. Comparing the monomer b with the monomer c, the former has a greater effect on the lipophilicity of the resin and the effect of impairing the hair washability than the latter, but the latter also contributes to the solubility in liquefied petroleum gas. Is greater. In order to further improve the solubility in liquefied petroleum gas, the total amount of the monomer b and the monomer c is preferably 41.0% by weight or more.
【００１６】単量体ｄは、フィルムの硬さや液化石油ガ
スへの溶解性に関与し、その使用量は０〜２５．０重量
％であり、必要に応じて使用される。前記使用量は、所
期の効果を十分に得るためには１．０重量％以上である
ことが好ましいが、それが２５．０重量％を超えると液
化石油ガスへの溶解性が不良となる。単量体ｄの具体例
としては、メチル（メタ）アクリレート、エチル（メ
タ）アクリレート、プロピル（メタ）アクリレート、エ
トキシエチル（メタ）アクリレート、アクリロニトリ
ル、（メタ）アクリルアミド、酢酸ビニル、スチレン、
ビニルピロリドン等を単独または併用で使用することが
できる。前記単量体ｄの内、メチルアクリレート、エチ
ルアクリレート、プロピルアクリレート、エトキシエチ
ルアクリレート、アクリロニトリル、アクリルアミド、
ビニルピロリドンを使用した場合は比較的柔軟なフィル
ムが得られ、メチルメタクリレート、エチルメタクリレ
ート、プロピルメタクリレート、エトキシエチルメタク
リレート、メタクリルアミド、酢酸ビニル、スチレンを
使用した場合は前者に比べて硬く、粘着性の少ないフィ
ルムが得られる。The monomer d is involved in the hardness of the film and the solubility in liquefied petroleum gas, and the amount used is 0 to 25.0% by weight, and is used as necessary. The amount used is preferably 1.0% by weight or more in order to obtain the desired effect sufficiently, but if it exceeds 25.0% by weight, the solubility in liquefied petroleum gas becomes poor. . Specific examples of the monomer d include methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, ethoxyethyl (meth) acrylate, acrylonitrile, (meth) acrylamide, vinyl acetate, styrene,
Vinylpyrrolidone and the like can be used alone or in combination. Among the monomers d, methyl acrylate, ethyl acrylate, propyl acrylate, ethoxyethyl acrylate, acrylonitrile, acrylamide,
When vinylpyrrolidone is used, a relatively flexible film is obtained, and when methylmethacrylate, ethylmethacrylate, propylmethacrylate, ethoxyethylmethacrylate, methacrylamide, vinyl acetate, or styrene is used, it is harder and more sticky than the former. Less film is obtained.
【００１７】本発明の整髪用樹脂は基本的には前述した
ａ〜ｄの重量性単量体を共重合するが、さらに次の単量
体ｅを配合することが好ましい。The hair styling resin of the present invention basically copolymerizes the aforesaid weighting monomers a to d, but it is preferable to further add the following monomer e.
【００１８】単量体ｅは、液化石油ガスへの溶解性を阻
害せずに高温および高湿下のセット力向上に寄与すると
共に、フィルムの硬さを調整するものである。その使用
量は５．０〜５０．０重量％、好ましくは１０．０〜４
５．０重量％である。前記使用量が５．０重量％未満の
とき、高温および高湿下のセットの向上がなく、一方、
それが５０．０重量％を超えると、フィルムが硬くな
り、風合いを損なうことになる。単量体ｅの具体例とし
ては、例えば、ジアセトン（メタ）アクリルアミド、
Ｎ，Ｎ−ジメチル（メタ）アクリルアミド、Ｎ−イソプ
ロピル（メタ）アクリルアミド、Ｎ−オクチル（メタ）
アクリルアミド等を単独または併用で使用することがで
きる。単量体ｅが特にジアセトンアクリルアミドの場
合、高温および高湿下において優れたセット力を持続さ
せることができる。The monomer e contributes to the improvement of the setting force under high temperature and high humidity without impairing the solubility in liquefied petroleum gas, and adjusts the hardness of the film. The amount used is 5.0 to 50.0% by weight, preferably 10.0 to 4
It is 5.0% by weight. When the amount used is less than 5.0% by weight, there is no improvement in the set under high temperature and high humidity, while
If it exceeds 50.0% by weight, the film becomes hard and the texture is impaired. Specific examples of the monomer e include, for example, diacetone (meth) acrylamide,
N, N-dimethyl (meth) acrylamide, N-isopropyl (meth) acrylamide, N-octyl (meth)
Acrylamide and the like can be used alone or in combination. Especially when the monomer e is diacetone acrylamide, an excellent setting force can be maintained under high temperature and high humidity.
【００１９】これらのａ〜ｄあるいはａ〜ｅの重合性単
量体を共重合し、得られた樹脂含有液に水溶性有機塩基
性物質を加えることにより、共重合樹脂を好ましくは５
０．０〜１００％の中和率で中和すると共に水溶性にす
る。水溶性有機塩基性物質としては、例えば、アンモニ
ア水、モルホリン、（モノ、ジまたはトリ）エタノール
アミン、（モノ、ジまたはトリ）イソプロパノールアミ
ン、アミノメチルプロパノールアミン、アミノエチルプ
ロパノールアミン、アミノメチルプロパンジオール、ア
ミノエチルプロパンジオール等を単独または併用で使用
することができる。特に有機アミンを使用すると、水を
含有しない樹脂組成物が得られるので、水を忌避するエ
アゾールの製造には好適である。前記のようにして得ら
れた樹脂組成物は、共重合体の平均分子量が５，０００
〜２００，０００程度であり、前記共重合で得られた親
油性溶媒溶液のままで、あるいは含水溶媒系として使用
することができる。成分（Ａ）の整髪用樹脂を毛髪化粧
料に配合する時の配合量は０．１〜３０．０重量％、好
ましくは１．０〜２０．０重量％である。０．１重量％
未満では目的の効果は得られず、３０．０重量％を超え
るとべたつきを生じることがある。By copolymerizing these polymerizable monomers a to d or a to e, and adding a water-soluble organic basic substance to the obtained resin-containing liquid, a copolymer resin is preferably added to
It is made neutral and water-soluble at a neutralization rate of 0.0 to 100%. Examples of the water-soluble organic basic substance include aqueous ammonia, morpholine, (mono-, di- or tri) ethanolamine, (mono-, di- or tri) isopropanolamine, aminomethylpropanolamine, aminoethylpropanolamine, aminomethylpropanediol. , Aminoethylpropanediol and the like can be used alone or in combination. In particular, when an organic amine is used, a resin composition containing no water can be obtained, which is suitable for producing an aerosol that repels water. The resin composition obtained as described above has an average molecular weight of 5,000.
It is about 200,000 and can be used as the lipophilic solvent solution obtained by the above copolymerization or as a water-containing solvent system. When the hair styling resin of the component (A) is blended with the hair cosmetic composition, the blending amount is 0.1 to 30.0% by weight, preferably 1.0 to 20.0% by weight. 0.1% by weight
If it is less than 3% by weight, the desired effect cannot be obtained, and if it exceeds 30.0% by weight, stickiness may occur.
【００２０】本発明で使用する成分（Ｂ）のエステル
は、前記一般式（Ｉ）で表されるもので、式中のＲ1、
Ｒ2は炭素数が６〜１８のものである。性状は常温で無
色〜淡黄色透明な油液である。具体的な構造を化学名で
示せば、カプロン酸ステアリル、カプリル酸パルミチ
ル、カプリン酸ミリスチル、ラウリン酸ラウリル、ミリ
スチン酸デシル、パルミチン酸オクチル、ステアリン酸
ステアリル、ミリスチン酸ミリスチル、パルミチン酸パ
ルミチル、ステアリン酸ステアリル等がある。成分
（Ｂ）のエステルの配合量は、毛髪化粧料全量中の０．
０１〜４０．０重量％、好ましくは０．１〜２５．０重
量％である。０．１重量％未満では目的の効果は得られ
ず、４０．０重量％を超えて含有させてもさらなる効果
の向上はみられないからである。The ester of the component (B) used in the present invention is represented by the above general formula (I), and R 1 in the formula,
R 2 has 6 to 18 carbon atoms. It is a colorless to pale yellow transparent oil liquid at room temperature. If the specific structure is shown by chemical name, stearyl caproate, palmityl caprylate, myristyl caprate, lauryl laurate, decyl myristate, octyl palmitate, stearyl stearate, myristyl myristate, palmityl palmitate, stearyl stearate. Etc. The compounding amount of the ester of the component (B) is 0.
It is 01 to 40.0% by weight, preferably 0.1 to 25.0% by weight. This is because if the amount is less than 0.1% by weight, the desired effect cannot be obtained, and if the amount exceeds 40.0% by weight, no further improvement in the effect can be seen.
【００２１】本発明の剤型は任意であり、可溶化系、乳
化系、粉末分散系、油−水の２相系、油−水−粉末の３
層系など、いずれでも構わず、各種添加剤を加えてヘア
クリーム、ヘアローション、ヘアミスト（ノンガスタイ
プ）とすることができる。さらに、噴射剤と共に加圧封
入してエアゾールとすることができる。前記噴射剤とし
ては、プロパン、ブタンおよびイソブタンを主成分とす
る液化石油ガス（ＬＰＧ）、ジメチルエーテルおよび炭
酸ガス、窒素ガス等の圧縮ガス等の単独またはそれらの
混合物を使用することができる。これらのうち、特に液
化石油ガス（ＬＰＧ）が好ましい。前記成分（Ａ）と成
分（Ｂ）を含む原液と噴射剤との配合比は、原液５〜９
５重量部に対して噴射剤９５〜５重量部が好ましい。The dosage form of the present invention is optional and can be any one of solubilizing system, emulsifying system, powder dispersion system, oil-water two-phase system, and oil-water-powder.
Any type such as a layer system may be used, and various additives may be added to form a hair cream, a hair lotion, or a hair mist (non-gas type). Furthermore, it can be pressurized and enclosed together with a propellant to form an aerosol. As the propellant, liquefied petroleum gas (LPG) containing propane, butane and isobutane as main components, dimethyl ether and compressed gas such as carbon dioxide gas and nitrogen gas, or a mixture thereof can be used. Of these, liquefied petroleum gas (LPG) is particularly preferable. The mixing ratio of the undiluted solution containing the component (A) and the ingredient (B) and the propellant is 5 to 9 undiluted solution.
95 to 5 parts by weight of propellant is preferable to 5 parts by weight.
【００２２】[0022]
【実施例】以下、実施例および比較例により本発明をさ
らに詳細に説明する。本発明はこれによって限定される
ものではない。配合量は全て重量％である。EXAMPLES The present invention will be described in more detail with reference to Examples and Comparative Examples. The present invention is not limited to this. All compounding amounts are weight%.
【００２３】原料製造例１（整髪用樹脂Ａの製造） 還流冷却器、温度計、窒素置換用ガラス管、滴下ロート
および攪拌機を取り付けた１ｌ四ツ口フラスコに、ａ．
メタクリル酸２０％、ｂ．ミリスチルアクリレート３５
％、ｃ．エチルヘキシルメタクリレート３５％、ｄ．メ
チルメタクリレート１０％からなる重合性単量体２００
部、エチルアルコール１００部、重合開始剤０．５〜４
部を加え、窒素気流下、還流状態（約８０℃）で５時間
重合を行う。重合後、冷却し、５０℃にて水溶性有機塩
基性物質（アミノメチルプロパノール（ＡＭＰ））のエ
チルアルコール溶液を添加して整髪用樹脂Ａを得た。Raw Material Production Example 1 (Production of Hairdressing Resin A) A 1-liter four-necked flask equipped with a reflux condenser, a thermometer, a glass tube for nitrogen substitution, a dropping funnel and a stirrer was charged with a.
Methacrylic acid 20%, b. Myristyl acrylate 35
%, C. 35% ethylhexyl methacrylate, d. Polymerizable monomer 200 consisting of 10% methyl methacrylate
Parts, ethyl alcohol 100 parts, polymerization initiator 0.5-4
Parts are added and polymerization is carried out for 5 hours under reflux (about 80 ° C.) under a nitrogen stream. After the polymerization, the mixture was cooled, and an ethyl alcohol solution of a water-soluble organic basic substance (aminomethyl propanol (AMP)) was added at 50 ° C. to obtain a hair styling resin A.
【００２４】原料製造例２（整髪用樹脂Ｂの製造） 還流冷却器、温度計、窒素置換用ガラス管、滴下ロート
および攪拌機を取り付けた１ｌ四ツ口フラスコに、ａ．
メタクリル酸２０％、ｂ．ミリスチルアクリレート３５
％、ｃ．エチルヘキシルメタクリレート２５％、ｄ．メ
チルメタクリレート１０％、ｅ．ジメチルアクリルアミ
ド１０％からなる重合性単量体２００部、エチルアルコ
ール１００部、重合開始剤０．５〜４部を加え、窒素気
流下、還流状態（約８０℃）で５時間重合を行う。重合
後、冷却し、５０℃にて水溶性有機塩基性物質（アミノ
メチルプロパノール（ＡＭＰ））のエチルアルコール溶
液を添加して整髪用樹脂Ｂを得た。Raw Material Production Example 2 (Production of Hairdressing Resin B) A 1-liter four-necked flask equipped with a reflux condenser, a thermometer, a glass tube for nitrogen substitution, a dropping funnel and a stirrer was charged with a.
Methacrylic acid 20%, b. Myristyl acrylate 35
%, C. 25% ethylhexyl methacrylate, d. Methyl methacrylate 10%, e. 200 parts of a polymerizable monomer consisting of 10% of dimethylacrylamide, 100 parts of ethyl alcohol, and 0.5 to 4 parts of a polymerization initiator are added, and polymerization is carried out under a nitrogen stream under reflux (about 80 ° C.) for 5 hours. After the polymerization, the mixture was cooled, and an ethyl alcohol solution of a water-soluble organic basic substance (aminomethyl propanol (AMP)) was added at 50 ° C. to obtain a hair styling resin B.
【００２５】実施例１，２、比較例１〜５ 次の表１に示す配合処方によってヘアスプレーを調製し
た。表中、整髪用樹脂Ａ、整髪用樹脂Ｂは上記の各原料
製造例で製造したもので、樹脂固型分１００％に換算し
た量である。Examples 1 and 2, Comparative Examples 1 to 5 Hair sprays were prepared according to the formulations shown in Table 1 below. In the table, the hair styling resin A and the hair styling resin B are those produced by the above-mentioned respective raw material production examples, and are the amounts converted into the resin solid content of 100%.
【００２６】得られたヘアスプレーの（１）セット力、
（２）セット持続力、（３）光沢を評価した結果を併せ
て表１に示す。なお、各評価方法は以下の通りである。(1) Setting power of the obtained hair spray,
The results of evaluation of (2) set sustainability and (3) gloss are also shown in Table 1. The evaluation methods are as follows.
【００２７】（１）セット力 専門パネラー５０人に各サンプルを使用してもらい、塗
布、乾燥後のセット力が優れているか否かを官能評価し
てもらった。(1) Setting Power 50 professional panelists used each sample and sensory evaluated whether or not the setting power after coating and drying was excellent.
【００２８】（２）セット持続力 専門パネラー５０人に各サンプルを使用してもらい、通
常の日常生活６時間後のセット力が優れているか否かを
官能評価してもらった。(2) Sustainability of set 50 expert panelists used each sample and sensory-evaluated whether or not the set ability after 6 hours of ordinary daily life was excellent.
【００２９】（３）光沢 専門パネラー５０人に各サンプルを使用してもらい、塗
布、乾燥後の光沢が優れているか否かを官能評価しても
らった。(3) Gloss 50 professional panelists used each sample and sensory evaluated whether or not the gloss after coating and drying was excellent.
【００３０】上記（１）〜（３）の項目ごとに、優れて
いると感じたパネル数が１〜２０人のとき×、２１〜４
０人のとき△、４１〜４５人のとき○、４６〜５０人の
とき◎と評価した。For each of the above items (1) to (3), when the number of panels that are felt to be excellent is 1 to 20, × 21 to 4
When 0 people were evaluated as Δ, when 41 to 45 people were evaluated as ◯, and when 46 to 50 people were evaluated as ⊚.
【００３１】[0031]
【表１】 ─────────────────────────────────── 実施例 比較例 ───── ────────────── １ ２ １ ２ ３ ４ ５ ─────────────────────────────────── ブチレングリコール 2.0 2.0 2.0 2.0 2.0 2.0 2.0 ポリエチレン(100) 硬化ヒマシ油エステル 1.0 1.0 1.0 1.0 1.0 1.0 1.0 ミリスチン酸オクチル 5.0 5.0 5.0 − − − 5.0 整髪用樹脂Ａ 3.0 − − 3.0 − − − 整髪用樹脂Ｂ − 3.0 − − 3.0 − − ポリビニルピロリドン／ 酢酸ビニル共重合体 − − − − − 3.0 3.0 エタノール 34.0 34.0 37.0 39.0 39.0 39.0 34.0 イオン交換水 5.0 5.0 5.0 5.0 5.0 5.0 5.0 ＬＰＧ(4.0kg/cm2 at20℃) 50.0 50.0 50.0 50.0 50.0 50.0 50.0 香料 適量 適量 適量 適量 適量 適量 適量 ─────────────────────────────────── (1)セット力 ◎ ◎ × ◎ ◎ ○ △ (2)セット持続力 ○ ◎ × ○ ◎ ○ △ (3)光沢 ◎ ◎ ◎ △ △ △ ○ ───────────────────────────────────[Table 1] ─────────────────────────────────── Examples Comparative examples ───── ── ──────────── 1 2 1 2 3 4 5 ──────────────────────────────── ──── Butylene glycol 2.0 2.0 2.0 2.0 2.0 2.0 2.0 Polyethylene (100) hydrogenated castor oil ester 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Octyl myristate 5.0 5.0 5.0 − − − 5.0 Hairdressing resin A 3.0 − − 3.0 − − − Hairdressing Resin B − 3.0 − − 3.0 − − Polyvinylpyrrolidone / vinyl acetate copolymer − − − − − 3.0 3.0 Ethanol 34.0 34.0 37.0 39.0 39.0 39.0 34.0 Ion-exchanged water 5.0 5.0 5.0 5.0 5.0 5.0 5.0 LPG (4.0 kg / cm 2 at20 ℃) 50.0 50.0 50.0 50.0 50.0 50.0 50.0 Perfume Appropriate amount Adequate amount Adequate amount Adequate amount Adequate amount ────────────────────── ──────────── (1) Set power ◎ ◎ × ◎ ◎ ○ △ (2) Set durability ○ ◎ × ○ ◎ ○ △ (3) Gloss ◎ ◎ ◎ △ △ △ ○ ── ──────────────────────────────────
【００３２】実施例３，４、比較例６〜１０ 次の表２に示す配合処方によってヘアムースを調製し、
実施例１と同様に評価した。Examples 3 and 4, Comparative Examples 6 to 10 Hair mousses were prepared according to the formulations shown in Table 2 below.
Evaluation was performed in the same manner as in Example 1.
【００３３】[0033]
【表２】 ─────────────────────────────────── 実施例 比較例 ───── ────────────── ３ ４ ６ ７ ８ ９ １０ ─────────────────────────────────── プロピレングリコール 3.0 3.0 3.0 3.0 3.0 3.0 3.0 ホ゜リオキシエチレン(10)ホ゜リオキシ フ゜ロヒ゜レン(20)テ゛シルテトラテ゛シルエーテル 3.0 3.0 3.0 3.0 3.0 3.0 3.0 ホ゜リオキシエチレン(9)ラウリルエーテル 1.0 1.0 1.0 1.0 1.0 1.0 1.0 ラウリン酸パルミチル 10.0 10.0 10.0 − − − 10.0 整髪用樹脂Ａ 5.0 − − 5.0 − − − 整髪用樹脂Ｂ − 5.0 − − 5.0 − − ポリビニルアルコール／ 酢酸ビニル共重合体 − − − − − 5.0 5.0 エタノール 10.0 10.0 10.0 10.0 10.0 10.0 10.0 イオン交換水 58.0 58.0 63.0 68.0 68.0 68.0 58.0 ＬＰＧ(4.0kg/cm2 at20℃) 10.0 10.0 10.0 10.0 10.0 10.0 10.0 香料 適量 適量 適量 適量 適量 適量 適量 ─────────────────────────────────── (1)セット力 ◎ ◎ × ◎ ◎ ○ △ (2)セット持続力 ○ ◎ × ○ ◎ ○ △ (3)光沢 ◎ ◎ ◎ △ △ △ ○ ───────────────────────────────────[Table 2] ─────────────────────────────────── Examples Comparative examples ───── ── ──────────── 3 4 6 7 8 9 10 ─────────────────────────────── ──── Propylene glycol 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Polyoxyethylene (10) Polyoxypropylene (20) Decyl tetradecyl ether 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Polyoxyethylene (9) Lauryl ether 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Palmyl laurate 10.0 10.0 10.0 − − − 10.0 Hairdressing resin A 5.0 − − 5.0 − − − Hairdressing resin B − 5.0 − − 5.0 − − Polyvinyl alcohol / vinyl acetate copolymer − − − − − 5.0 5.0 Ethanol 10.0 10.0 10.0 10.0 10.0 10.0 10.0 Ion-exchanged water 58.0 58.0 63.0 68.0 68.0 68.0 58.0 LPG (4.0 kg / cm 2 at 20 ℃) 10.0 10.0 10.0 10.0 10.0 10.0 10.0 Fragrance Amount Amount Amount Amount Amount Amount Amount Amount Amount Amount Amount ─────────────────────────────── ───── (1) Set power ◎ ◎ × ◎ ◎ ○ △ (2) Set persistence ○ ◎ × ○ ◎ ○ △ (3) Gloss ◎ ◎ ◎ △ △ △ ○ ───────── ──────────────────────────
【００３４】 実施例５ ヘアリキッド ポリエチレングリコール ２．０ 重量％ ポリオキシエチレン（５） デシルテトラデシルエーテル ２．０ カプリン酸ステアリル １２．０ 整髪用樹脂Ｂ ４．０ エタノール ６０．０ イオン交換水 ２０．０ 香料 適量Example 5 Hair Liquid Polyethylene Glycol 2.0% by Weight Polyoxyethylene (5) Decyl Tetradecyl Ether 2.0 Stearyl Caprate 12.0 Hairdressing Resin B 4.0 Ethanol 60.0 Ion Exchange Water 20. 0 Perfume
【００３５】[0035]
【発明の効果】以上説明したように、本発明の毛髪化粧
料は、整髪固定力（セット力）、固定持続力（セット持
続力）に優れ、かつ、まぶしいほどに魅惑的な光沢を毛
髪に与えるものである。As described above, the hair cosmetic composition of the present invention has excellent hair-fixing power (setting power) and fixing lasting power (setting lasting power), and has a dazzlingly fascinating luster to the hair. To give.
Claims (4)
することを特徴とする毛髪化粧料。 （Ａ）次の重合性単量体ａ〜ｄを共重合し、水溶性有機
塩基性物質で中和してなる整髪用樹脂。 ａ．アクリル酸、メタクリル酸およびイタコン酸からな
る群より選ばれた少なくとも１種の単量体 ６．０〜３
５．０重量％ ｂ．アクリル酸および／またはメタクリル酸の炭素数１
０〜１８の脂肪族アルコールのエステルからなる少なく
とも１種の単量体 １５．０〜５０．０重量％ ｃ．アクリル酸および／またはメタクリル酸の炭素数４
〜８の脂肪族アルコールのエステルからなる少なくとも
１種の単量体 １５．０〜５０．０重量％ ｄ．その他のビニル系単量体 ０〜２５．０重量％ （Ｂ）一般式（Ｉ）： 【化１】R1−CO−O−R2 …（Ｉ） （Ｒ1、Ｒ2は炭素数が６〜１８の直鎖あるいは分岐の炭
化水素基を表す。）で表されるエステルの１種または２
種以上。1. A hair cosmetic composition comprising the following component (A) and component (B). (A) A hair styling resin obtained by copolymerizing the following polymerizable monomers a to d and neutralizing it with a water-soluble organic basic substance. a. At least one monomer selected from the group consisting of acrylic acid, methacrylic acid and itaconic acid 6.0-3
5.0% by weight b. 1 carbon atom of acrylic acid and / or methacrylic acid
At least one monomer consisting of an ester of an aliphatic alcohol of 0-18 15.0-50.0% by weight c. 4 carbon atoms of acrylic acid and / or methacrylic acid
To 8 at least one monomer consisting of an ester of an aliphatic alcohol 15.0 to 50.0% by weight d. Other vinyl monomers 0 to 25.0% by weight (B) General formula (I): embedded image R 1 —CO—O—R 2 (I) (R 1 and R 2 have carbon numbers 1 to 2 of an ester represented by 6 to 18 representing a linear or branched hydrocarbon group).
More than seeds.
することを特徴とする毛髪化粧料。 （Ａ）次の重合性単量体ａ〜ｅを共重合し、水溶性有機
塩基性物質で中和してなる整髪用樹脂。 ａ．アクリル酸、メタクリル酸およびイタコン酸からな
る群より選ばれた少なくとも１種の単量体 ６．０〜３
５．０重量％ ｂ．アクリル酸及び／又はメタクリル酸の炭素数１０〜
１８の脂肪族アルコールのエステルからなる少なくとも
１種の単量体 １５．０〜５０．０重量％ ｃ．アクリル酸及び／又はメタクリル酸の炭素数４〜８
の脂肪族アルコールのエステルからなる少なくとも１種
の単量体 １５．０〜５０．０重量％ ｄ．その他のビニル系単量体 ０〜２５．０重量％ ｅ．一般式（II）： 【化２】 （式中、Ｒ3およびＲ4は水素原子またはメチル基、Ｒ5
は炭素原子数が１〜８のアルキル基またはＣ（ＣＨ3）2
ＣＨ2ＣＯＣＨ3である。）で表されるＮ−アルキル置換
アクリルアミドから選ばれた少なくとも１種の単量体
５．０〜５０．０重量％ （Ｂ）一般式（Ｉ）： 【化３】R1−CO−O−R2 …（Ｉ） （Ｒ1、Ｒ2は炭素数が６〜１８の直鎖あるいは分岐の炭
化水素基を表す。）で表されるエステルの１種または２
種以上。2. A hair cosmetic composition comprising the following component (A) and component (B). (A) A hair styling resin obtained by copolymerizing the following polymerizable monomers a to e and neutralizing it with a water-soluble organic basic substance. a. At least one monomer selected from the group consisting of acrylic acid, methacrylic acid and itaconic acid 6.0-3
5.0% by weight b. 10 to 10 carbon atoms of acrylic acid and / or methacrylic acid
At least one monomer consisting of an ester of 18 aliphatic alcohols 15.0 to 50.0% by weight c. Acrylic acid and / or methacrylic acid having 4 to 8 carbon atoms
At least one monomer consisting of ester of aliphatic alcohol of 15.0 to 50.0% by weight d. Other vinyl monomers 0 to 25.0% by weight e. General formula (II): (In the formula, R 3 and R 4 are a hydrogen atom or a methyl group, R 5
Is an alkyl group having 1 to 8 carbon atoms or C (CH 3 ) 2
It is CH 2 COCH 3 . ) At least one monomer selected from N-alkyl-substituted acrylamides represented by
5.0 to 50.0% by weight (B) General formula (I): embedded image R 1 —CO—O—R 2 (I) (R 1 and R 2 are direct carbon atoms having 6 to 18 carbon atoms) 1 or 2 of an ester represented by a chain or branched hydrocarbon group).
More than seeds.
重量％であり、成分（Ｂ）の配合量が０．０１〜４０．
０重量％である請求項１または２記載の毛髪化粧料。3. The compounding amount of the component (A) is 0.1 to 30.0.
% By weight, and the compounding amount of the component (B) is 0.01 to 40.
The hair cosmetic composition according to claim 1 or 2, which is 0% by weight.
温にて液状である原液５〜９５重量部と、液化ガス推進
剤９５〜５重量部からなるエアゾールタイプである請求
項１または２記載の毛髪化粧料。4. An aerosol type which comprises 5 to 95 parts by weight of a stock solution which is liquid at room temperature and contains 95 to 5 parts by weight of a liquefied gas propellant, which contains the components (A) and (B). 2. The hair cosmetic composition as described in 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25616994A JPH0892046A (en) | 1994-09-26 | 1994-09-26 | Hair cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25616994A JPH0892046A (en) | 1994-09-26 | 1994-09-26 | Hair cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0892046A true JPH0892046A (en) | 1996-04-09 |
Family
ID=17288873
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25616994A Pending JPH0892046A (en) | 1994-09-26 | 1994-09-26 | Hair cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0892046A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998000096A1 (en) * | 1996-07-02 | 1998-01-08 | L'oreal | Use of acrylic copolymers in cosmetics and compositions used |
| JP2001302445A (en) * | 2000-04-17 | 2001-10-31 | Daizo:Kk | Aerosol products |
| JP2008540461A (en) * | 2005-05-27 | 2008-11-20 | ザ プロクター アンド ギャンブル カンパニー | Moisture resistant hair styling composition containing two copolymers |
| US7481996B2 (en) | 2003-08-06 | 2009-01-27 | Kao Corporation | Aerosol cosmetic composition |
-
1994
- 1994-09-26 JP JP25616994A patent/JPH0892046A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998000096A1 (en) * | 1996-07-02 | 1998-01-08 | L'oreal | Use of acrylic copolymers in cosmetics and compositions used |
| FR2750600A1 (en) * | 1996-07-02 | 1998-01-09 | Oreal | USE IN COSMETICS OF ACRYLIC COPOLYMERS; COMPOSITIONS IMPLEMENTED |
| JP2001302445A (en) * | 2000-04-17 | 2001-10-31 | Daizo:Kk | Aerosol products |
| US7481996B2 (en) | 2003-08-06 | 2009-01-27 | Kao Corporation | Aerosol cosmetic composition |
| JP2008540461A (en) * | 2005-05-27 | 2008-11-20 | ザ プロクター アンド ギャンブル カンパニー | Moisture resistant hair styling composition containing two copolymers |
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