JPH086847B2 - Composite pipe and manufacturing method thereof - Google Patents
Composite pipe and manufacturing method thereofInfo
- Publication number
- JPH086847B2 JPH086847B2 JP1298509A JP29850989A JPH086847B2 JP H086847 B2 JPH086847 B2 JP H086847B2 JP 1298509 A JP1298509 A JP 1298509A JP 29850989 A JP29850989 A JP 29850989A JP H086847 B2 JPH086847 B2 JP H086847B2
- Authority
- JP
- Japan
- Prior art keywords
- layer
- thermoplastic resin
- pipe
- tube
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002131 composite material Substances 0.000 title claims description 99
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000000835 fiber Substances 0.000 claims description 123
- 229920005992 thermoplastic resin Polymers 0.000 claims description 79
- 230000003014 reinforcing effect Effects 0.000 claims description 66
- 238000004804 winding Methods 0.000 claims description 10
- 238000010030 laminating Methods 0.000 claims description 4
- 229920005989 resin Polymers 0.000 description 26
- 239000011347 resin Substances 0.000 description 26
- 238000010438 heat treatment Methods 0.000 description 19
- 239000003365 glass fiber Substances 0.000 description 15
- 238000001816 cooling Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000011162 core material Substances 0.000 description 9
- 239000004801 Chlorinated PVC Substances 0.000 description 7
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229920001187 thermosetting polymer Polymers 0.000 description 5
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 4
- 229920006026 co-polymeric resin Polymers 0.000 description 4
- 239000002657 fibrous material Substances 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000012783 reinforcing fiber Substances 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 230000008602 contraction Effects 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- 229920006337 unsaturated polyester resin Polymers 0.000 description 3
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/12—Rigid pipes of plastics with or without reinforcement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/15—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
- B29C48/154—Coating solid articles, i.e. non-hollow articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/30—Extrusion nozzles or dies
- B29C48/32—Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D23/00—Producing tubular articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/36—Bending and joining, e.g. for making hollow articles
- B29C53/38—Bending and joining, e.g. for making hollow articles by bending sheets or strips at right angles to the longitudinal axis of the article being formed and joining the edges
- B29C53/48—Bending and joining, e.g. for making hollow articles by bending sheets or strips at right angles to the longitudinal axis of the article being formed and joining the edges for articles of indefinite length, i.e. bending a strip progressively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/56—Winding and joining, e.g. winding spirally
- B29C53/58—Winding and joining, e.g. winding spirally helically
- B29C53/60—Winding and joining, e.g. winding spirally helically using internal forming surfaces, e.g. mandrels
- B29C53/68—Winding and joining, e.g. winding spirally helically using internal forming surfaces, e.g. mandrels with rotatable winding feed member
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D23/00—Producing tubular articles
- B29D23/001—Pipes; Pipe joints
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Description
【発明の詳細な説明】 (産業上の利用分野) 本発明は、強化層が複数層積層された複合管およびそ
の製造方法に関する。Description: TECHNICAL FIELD The present invention relates to a composite pipe in which a plurality of reinforcing layers are laminated and a method for manufacturing the same.
(従来の技術) 従来から、樹脂製管は、金属製管と比較して軽量であ
って錆びない等の優れた特性を有しており広く用いられ
ている。しかし、この樹脂製管は、耐圧性および耐衝撃
性において金属製管に劣っている。そこで、これらの樹
脂製管に耐圧性および耐衝撃性をもたせたものとして、
熱可塑性樹脂管の外周に連続繊維で強化された樹脂の強
化層を設けた複合管が提案されている。例えば、特公昭
62−773号公報、特開昭57−100030号公報および特開昭5
9−48120号公報には、熱可塑性樹脂管の外周に、連続繊
維が管の長手方向に配置された熱硬化性樹脂の強化層を
設けた複合管および連続繊維が管の略周方向に巻回配置
された熱硬化性樹脂の強化層を設けた複合管が開示され
ている。これらの複合管は、耐圧性および耐衝撃性に優
れるばかりでなく、連続繊維が管の長手方向にも配置さ
れているので管の熱伸縮が小さく、配管ラインにおける
管の熱伸縮によるトラブルが少ないという利点を有して
いる。(Prior Art) Conventionally, resin pipes have been widely used because they have excellent characteristics such as being lighter in weight and not rusting as compared with metal pipes. However, this resin pipe is inferior to the metal pipe in pressure resistance and impact resistance. Therefore, assuming that these resin pipes have pressure resistance and impact resistance,
A composite pipe in which a reinforced layer of a resin reinforced with continuous fibers is provided on the outer circumference of a thermoplastic resin pipe has been proposed. For example,
62-773, Japanese Patent Laid-Open No. 57-30030 and Japanese Patent Laid-Open No. 5-30
In JP-A-48120, a composite pipe provided with a reinforcing layer of a thermosetting resin in which continuous fibers are arranged in the longitudinal direction of the pipe is provided on the outer periphery of a thermoplastic resin pipe, and continuous fibers are wound in a substantially circumferential direction of the pipe. Disclosed is a composite tube provided with a reinforced layer of thermosetting resin arranged in turns. These composite pipes are not only excellent in pressure resistance and impact resistance, but also because continuous fibers are arranged in the longitudinal direction of the pipe, thermal expansion and contraction of the pipe is small, and there are few problems due to thermal expansion and contraction of the pipe in the piping line. It has the advantage of
(発明が解決しようとする課題) しかし、上記従来の複合管は、強化層が熱硬化性樹脂
であるため、内層の熱可塑性樹脂管と強化層との接着力
が弱く、複合管に温水を流した場合あるいは高温下で使
用した場合、内層の熱可塑性樹脂管と強化層との線膨張
率の差により、熱可塑性樹脂管と強化層との界面に剥離
が発生し易いという問題点があった。(Problems to be solved by the invention) However, in the above-described conventional composite pipe, since the reinforcing layer is a thermosetting resin, the adhesive force between the thermoplastic resin pipe of the inner layer and the reinforcing layer is weak, and hot water is applied to the composite pipe. When flowed or used at high temperature, there is a problem that peeling easily occurs at the interface between the thermoplastic resin tube and the reinforcing layer due to the difference in linear expansion coefficient between the thermoplastic resin tube of the inner layer and the reinforcing layer. It was
本発明は、上記問題点を解決するためなされたもので
あり、その目的とするところは、耐圧性および耐衝撃性
に優れ、かつ、温水を流した場合あるいは高温下で使用
した場合にも、内層の熱可塑性樹脂管と強化層との界面
が剥離し難い複合管およびその製造方法を提供しようと
するものである。The present invention has been made to solve the above problems, and its purpose is to have excellent pressure resistance and impact resistance, and also when running hot water or when used at high temperature, An object of the present invention is to provide a composite pipe in which the interface between the thermoplastic resin pipe of the inner layer and the reinforcing layer does not easily peel off, and a method for producing the same.
(課題を解決するための手段) 本発明における複合管は、内層の熱可塑性樹脂管、連
続繊維が長手方向に配置された熱可塑性樹脂から形成さ
れた強化層、および連続繊維が管の略周方向に巻回配置
された熱可塑性樹脂から形成された強化層が互いに融着
一体化されてなることを特徴とする。(Means for Solving the Problems) The composite pipe of the present invention includes a thermoplastic resin pipe as an inner layer, a reinforcing layer formed from a thermoplastic resin in which continuous fibers are arranged in a longitudinal direction, and continuous fibers substantially around the pipe. It is characterized in that the reinforcing layers formed from a thermoplastic resin wound in the direction are fused and integrated with each other.
また、上記構成の複合管の製造方法は、多数の連続す
るフィラメントよりなる連続繊維に熱可塑性樹脂が保持
されてなるシート状繊維複合体から前記連続繊維が長手
方向に配置された管状体を成形する工程と、該管状体の
内面に熱可塑性樹脂を溶融状態で押出積層して形成した
内層の熱可塑性樹脂管とこの外周の上記連続繊維が長手
方向に配置された強化層からなる2層管を成形する工程
及び該2層管の外周に、多数の連続するフィラメントよ
りなる連続繊維に熱可塑性樹脂が保持されてなる繊維複
合体を巻回融着する工程を包含してなることを特徴とす
る。Further, the method for producing the composite tube having the above-mentioned configuration is a tubular body in which the continuous fibers are arranged in the longitudinal direction from a sheet-shaped fiber composite in which a thermoplastic resin is held in continuous fibers composed of a large number of continuous filaments. And a two-layer pipe comprising a thermoplastic resin pipe as an inner layer formed by extruding and laminating a thermoplastic resin on the inner surface of the tubular body in a molten state, and a reinforcing layer in which the continuous fibers of the outer periphery are arranged in the longitudinal direction. And a step of winding and fusing a fiber composite in which a thermoplastic resin is held in continuous fibers made of a large number of continuous filaments around the outer periphery of the two-layer tube. To do.
本発明において、内層の熱可塑性樹脂管に用いる熱可
塑性樹脂は、管状に押出成形可能なものであれば特に限
定されず、管の使用目的に適した熱可塑性樹脂があげら
れる。例えば、ポリ塩化ビニル、塩素化ポリ塩化ビニ
ル、ポリエチレン、ポリプロピレン、ポリスチレン、ポ
リアミド、ポリカーボネート、ポリフェニレンサルファ
イド、ポリスルホン、ポリエーテルエーテルケトン等が
挙げられる。これら熱可塑性樹脂は単独あるいは複数の
混合物として用いられてもよい。また、熱安定剤、可塑
剤、滑剤、酸化防止剤、紫外線吸収剤、顔料、無機充填
材、強化繊維等の添加剤、充填材、加工助剤、改質剤等
が加えられてもよい。In the present invention, the thermoplastic resin used for the thermoplastic resin tube of the inner layer is not particularly limited as long as it can be extruded into a tubular shape, and examples thereof include a thermoplastic resin suitable for the purpose of use of the tube. Examples thereof include polyvinyl chloride, chlorinated polyvinyl chloride, polyethylene, polypropylene, polystyrene, polyamide, polycarbonate, polyphenylene sulfide, polysulfone, and polyether ether ketone. These thermoplastic resins may be used alone or as a mixture of two or more. Further, additives such as heat stabilizers, plasticizers, lubricants, antioxidants, ultraviolet absorbers, pigments, inorganic fillers, reinforcing fibers, fillers, processing aids, modifiers and the like may be added.
第1の強化層と第2の強化層を構成する連続繊維に予
め保持される熱可塑性樹脂は、内層の熱可塑性樹脂と同
一である必要は特になく、融着性の良い熱可塑性樹脂で
あればよい。The thermoplastic resin previously held by the continuous fibers constituting the first reinforcing layer and the second reinforcing layer does not need to be the same as the thermoplastic resin of the inner layer, and may be a thermoplastic resin having a good fusion property. Good.
第2の強化層の熱可塑性樹脂を、内層の熱可塑性樹脂
に対する融着性よりも隣接した第1の強化層に対して良
い融着性の熱可塑性樹脂とすると、層間の接着性が高
く、信頼性に優れた複合管が得られる。ここで述べる融
着性とは、双方の樹脂を溶融状態になるまで加熱したう
えで圧着し、冷却後融着した界面が容易に破断しないこ
とをいう。When the thermoplastic resin of the second reinforcing layer is a thermoplastic resin having a better adhesiveness to the adjacent first reinforcing layer than the adhesiveness to the thermoplastic resin of the inner layer, the adhesiveness between the layers is high, A composite tube with excellent reliability can be obtained. The term "fusing property" as used herein means that both resins are heated to a molten state and then pressure-bonded, and after cooling, the fused interface is not easily broken.
強化層は、連続繊維が少なくとも長手方向に配置され
た補強繊維と熱可塑性樹脂からなる第1の強化層、およ
び連続繊維が少なくとも管の略周方向に巻回配置された
補強繊維と熱可塑性樹脂からなる第2の強化層が互いに
融着一体化されてなっている。第1の強化層および第2
の強化層ともに、それぞれが別の方向に配置された連続
繊維又は有限長の繊維からなるクロスおよび織物を加え
て構成してもよい。The reinforcing layer is a first reinforcing layer composed of a reinforcing fiber in which continuous fibers are arranged at least in the longitudinal direction and a thermoplastic resin, and a reinforcing fiber and a thermoplastic resin in which continuous fibers are arranged at least approximately in the circumferential direction of the pipe. A second reinforcing layer consisting of: First reinforcement layer and second
Both the reinforcing layer and the reinforced layer may be formed by adding a cloth and a woven fabric, each of which is a continuous fiber or a finite length fiber arranged in different directions.
管の長手方向に配置される連続繊維および管の略周方
向に巻回配置される連続繊維は、直径1〜数十μmの連
続フィラメントよりなるロービング状又はストランド状
のものが用いられる。この繊維としては、ガラス繊維、
炭素繊維、金属繊維、アラミド繊維、ビニロン等の合成
若しくは天然の有機繊維等樹脂の補強繊維として使用可
能な連続繊維の全てが好適に使用される。As the continuous fiber arranged in the longitudinal direction of the tube and the continuous fiber wound in the substantially circumferential direction of the tube, a roving-like or strand-like one made of continuous filaments having a diameter of 1 to several tens of μm is used. As this fiber, glass fiber,
All of the continuous fibers that can be used as reinforcing fibers for resins such as synthetic or natural organic fibers such as carbon fibers, metal fibers, aramid fibers, and vinylon are preferably used.
管の長手方向に配置される連続繊維および管の略周方
向に巻回配置される連続繊維は、同じ種類の繊維であっ
てもよいし、異なる種類の繊維であってもよい。又、連
続繊維はそのフィラメント一本一本の間に熱可塑性樹脂
が充分に含浸し、保持した状態のものが好ましく、この
ような連続繊維が補強していることが、管の水密性、お
よび、連続繊維と熱可塑性樹脂との接着性を高める点で
好ましく、連続繊維と樹脂との接着性を高めるためにあ
らかじめフィラメント間に熱可塑性樹脂が含浸される等
の表面処理が施されたものを用いるのが好ましい。The continuous fibers arranged in the longitudinal direction of the pipe and the continuous fibers wound in the substantially circumferential direction of the pipe may be the same type of fibers or different types of fibers. Further, the continuous fiber is preferably in a state of being sufficiently impregnated with a thermoplastic resin between the filaments and held, and the fact that such continuous fiber reinforces the watertightness of the pipe and It is preferable in that it enhances the adhesiveness between the continuous fiber and the thermoplastic resin, and it is preferable that surface treatment such as impregnating the thermoplastic resin between the filaments in advance is performed to enhance the adhesiveness between the continuous fiber and the resin. It is preferably used.
第1の強化層と第2の強化層の融着一体化は、内層の
熱可塑性樹脂管の外周に形成された管の長手方向に連続
繊維が配置された熱可塑性樹脂からなる第1の強化層の
外周に、熱可塑性樹脂が保持された多数のフィラメント
からなる連続繊維を一層あるいは多層を加熱しながら巻
回するか、又は巻回した後に加熱手段により第1の強化
層と第2の強化層を形成する連続繊維が含浸した熱可塑
性樹脂を加熱し、互いを融着することにより得られる。The fusion-bonding integration of the first reinforcing layer and the second reinforcing layer is performed by the first strengthening of the thermoplastic resin in which continuous fibers are arranged in the longitudinal direction of the pipe formed on the outer circumference of the thermoplastic resin pipe of the inner layer. A continuous fiber composed of a large number of filaments holding a thermoplastic resin is wound around the outer periphery of the layer while heating one layer or multiple layers while heating, or after winding, a first reinforcing layer and a second reinforcing layer by a heating means. It is obtained by heating a thermoplastic resin impregnated with continuous fibers forming a layer and fusing each other.
本発明の複合管の長手方向に配置される第1の強化層
のシート状繊維複合体は、連続繊維のフィラメント間に
熱可塑性樹脂が含浸され保持され、加熱・加圧等により
シート状にされたものである。そして、このシート状繊
維複合体は、そのシートの長手方向と略平行に連続繊維
が配置される。シート状繊維複合体の幅は成形する強化
層を設けた2層管の外周の周長と略等しく成形され、厚
みは所望する強化層の厚みにより決められるが、通常は
0.1mm〜3mm程度のものが好適に用いられる。またシート
状繊維複合体中の繊維は、シートの長手方向と略平行に
配置された連続繊維が必要であるが、その他にこの連続
繊維と直交方向等の交叉方向に配置された有限長の繊維
から構成されるクロス状繊維材に、熱可塑性樹脂が保持
されてなる繊維複合体であってもよい。このシート状繊
維複合体中の繊維量は5〜70容量%である。5容量%未
満では充分な補強効果が得られず、70容量%を超えると
内層の熱可塑性樹脂管及び第2の強化層との融着性が低
下し充分に界面が融着しない。The sheet-shaped fiber composite of the first reinforcing layer arranged in the longitudinal direction of the composite pipe of the present invention is made to have a thermoplastic resin impregnated between filaments of continuous fibers and held, and formed into a sheet by heating and pressing. It is a thing. Then, in this sheet-shaped fiber composite, continuous fibers are arranged substantially parallel to the longitudinal direction of the sheet. The width of the sheet-shaped fiber composite is formed to be approximately equal to the outer circumference of the two-layer tube provided with the reinforcing layer to be formed, and the thickness is determined by the desired thickness of the reinforcing layer,
Those having a thickness of about 0.1 mm to 3 mm are preferably used. Further, the fibers in the sheet-shaped fiber composite need continuous fibers arranged substantially parallel to the longitudinal direction of the sheet, but in addition, fibers having a finite length arranged in a crossing direction such as a direction orthogonal to the continuous fibers. A fiber composite in which a thermoplastic resin is held by a cloth-shaped fiber material composed of The amount of fibers in this sheet-shaped fiber composite is 5 to 70% by volume. If it is less than 5% by volume, a sufficient reinforcing effect cannot be obtained, and if it exceeds 70% by volume, the fusion bonding property between the thermoplastic resin pipe of the inner layer and the second reinforcing layer is lowered and the interface is not sufficiently fused.
連続繊維を管の概略周方向に配置して第2の強化層を
形成するのに用いる繊維複合体は、連続繊維のフィラメ
ント間に熱可塑性樹脂が含浸され保持され、加熱・加圧
等によりテープ状、紐状等にされた繊維複合体であっ
て、繊維複合体の長手方向と略平行に連続繊維が配置さ
れる。この繊維複合体の幅、厚みは特に制限されない
が、紐状の繊維複合体を用いる場合には、直径0.5〜5mm
程度のものが好適に用いられ、テープ状の繊維複合体が
用いられる場合には幅10〜100mm、厚み0.1mm〜3mm程度
のものが好適に用いられる。またテープ状の繊維複合体
中の繊維は、その長手方向と略平行に配置された連続繊
維が必須であるが、その他にこの連続繊維と直交方向等
の交叉方向に配置された有限長さの繊維が含まれたもの
であってもよい。The fiber composite used for forming the second reinforcing layer by arranging the continuous fibers in the substantially circumferential direction of the tube is a tape in which a thermoplastic resin is impregnated and held between filaments of the continuous fibers, and the tape is formed by heating and pressing. In the fiber composite in the shape of a strip, a string, etc., continuous fibers are arranged substantially parallel to the longitudinal direction of the fiber composite. The width and thickness of this fiber composite are not particularly limited, but when a string-shaped fiber composite is used, the diameter is 0.5 to 5 mm.
Those having a width of about 10 to 100 mm and a thickness of about 0.1 mm to 3 mm are preferably used when a tape-shaped fiber composite is used. Further, the fibers in the tape-shaped fiber composite must have continuous fibers arranged substantially parallel to the longitudinal direction thereof, but in addition, a fiber having a finite length arranged in a crossing direction such as a direction orthogonal to the continuous fibers may be used. It may contain fibers.
フィラメント間に熱可塑性樹脂を含浸させて連続繊維
に熱可塑性樹脂を保持させる方法は、多数のフィラメン
トより構成されるロービング状もしくはストランド状の
連続繊維材を(i)粉体状熱可塑性樹脂の流動床中を通
過させる方法、(ii)粉体状熱可塑性樹脂を分散した液
体の槽中を通過させ、粉体状熱可塑性樹脂をフィラメン
ト間に含浸させ続いて溶融温度以上に加熱して繊維と樹
脂を一体化せしめるか、又は含浸させた後一旦乾燥させ
た後に溶融温度以上に加熱して繊維と樹脂を一体化せし
め、シート状、テープ状、紐状等の所望の形状に成形す
る方法が好適に採用される。また、溶融粘度が低い樹脂
の場合には、上記連続繊維材を溶融樹脂の槽中に浸漬す
る方法で含浸させることも可能である。The method of impregnating the thermoplastic resin between the filaments to retain the thermoplastic resin in the continuous fiber is as follows: (i) Flowing the powdery thermoplastic resin with a roving-like or strand-like continuous fiber material composed of a large number of filaments. A method of passing through the bed, (ii) passing through a bath of a liquid in which the powdery thermoplastic resin is dispersed, impregnating the powdery thermoplastic resin between the filaments, and subsequently heating it above the melting temperature to form fibers. A method is to integrate the resin, or impregnate it and then dry it, and then heat it to a temperature not lower than the melting temperature to integrate the fiber and resin, and form it into a desired shape such as a sheet, tape, or string. It is preferably adopted. Further, in the case of a resin having a low melt viscosity, it is possible to impregnate the continuous fiber material by a method of immersing the continuous fiber material in a bath of the molten resin.
強化層の外周に外層を設ける場合、外層に用いる熱可
塑性樹脂は、特に制限なく総ての熱可塑性樹脂が採用さ
れてよいが、境界の強化層に用いられている熱可塑性樹
脂と融着性のよい熱可塑性樹脂を用いることが、強化層
と外層とが強固に融着一体化した複合管が得られる点で
好ましい。When an outer layer is provided on the outer periphery of the reinforcing layer, the thermoplastic resin used for the outer layer may be any thermoplastic resin without particular limitation, but the thermoplastic resin used for the boundary reinforcing layer and the fusion bonding property. It is preferable to use a good thermoplastic resin in order to obtain a composite tube in which the reinforcing layer and the outer layer are firmly fused and integrated.
以下、本発明を第1図〜第4図に基づいて説明する。 Hereinafter, the present invention will be described with reference to FIGS.
第1図は、本発明にかかる複合管の一実施例の端面を
剥離した斜視図である。この図において、1は複合管で
あり、この複合管1は芯材となる内層の熱可塑性樹脂管
2の外周に管の長手方向に連続繊維が配置された第1の
強化層3と、この強化層3の外周に管の略周方向に連続
繊維が配置された第2の強化層4と、この第2の強化層
4外周に熱可塑性樹脂が被覆された外層5とから構成さ
れている。FIG. 1 is a perspective view of an embodiment of the composite pipe according to the present invention with the end surface peeled off. In this figure, 1 is a composite pipe, and this composite pipe 1 has a first reinforcing layer 3 in which continuous fibers are arranged in the longitudinal direction of the pipe on the outer circumference of a thermoplastic resin pipe 2 which is an inner layer serving as a core material. It is composed of a second reinforcing layer 4 in which continuous fibers are arranged on the outer periphery of the reinforcing layer 3 in a substantially circumferential direction of the tube, and an outer layer 5 in which the outer periphery of the second reinforcing layer 4 is coated with a thermoplastic resin. .
第2図ないし第4図は本発明にかかる複合管の製造工
程の一例を示す説明図であり、これらの図において製造
工程は、押出機11と、この押出機11の先端に取付けられ
て、軸心に配置され先方まで延びている内コア12と、こ
の内コア12の外周に環状間隙を形成するように配置され
た内金型13と、この内金型13の外周に環状の隙間14を形
成するように配置された賦形ロール15,16と、内金型13
の先方の外周に隙間14と同心状の環状の間隙が形成され
るように内コア12と同心状に配置された外金型17と、外
金型17で成形された積層管10bに繊維複合体9を巻回す
る巻回装置18を備えると共に、さらに、内金型13の近傍
に配置されてシート状繊維複合体8を加熱する加熱手段
23と、2層積層管10b及び巻回した繊維複合体9を加熱
する加熱手段24と、熱可塑性樹脂を供給する押出機19
と、この押出機19の先端に取付けられて強化層4の外周
に熱可塑性樹脂を被覆して外層5を成形する被覆金型20
と、外層が成形された4層積層の複合管1を冷却サイジ
ングする冷却装置21と、成形された複合管1を引き取る
引取機22とから構成されている。2 to 4 are explanatory views showing an example of a manufacturing process of the composite pipe according to the present invention. In these drawings, the manufacturing process is attached to the extruder 11 and the tip of the extruder 11, An inner core 12 arranged at the axial center and extending to the forward side, an inner mold 13 arranged so as to form an annular gap on the outer periphery of the inner core 12, and an annular gap 14 on the outer periphery of the inner mold 13. Shaping rolls 15 and 16 arranged so as to form the inner mold 13
The outer die 17 arranged concentrically with the inner core 12 so that an annular gap that is concentric with the gap 14 is formed on the outer periphery of the outer periphery of the outer die 17, and the fiber composite in the laminated tube 10b formed by the outer die 17. A heating device that includes a winding device 18 that winds the body 9 and that is arranged near the inner mold 13 to heat the sheet-shaped fiber composite body 8.
23, heating means 24 for heating the two-layer laminated tube 10b and the wound fiber composite 9, and an extruder 19 for supplying a thermoplastic resin.
And a coating die 20 which is attached to the tip of the extruder 19 and which coats the outer periphery of the reinforcing layer 4 with a thermoplastic resin to form the outer layer 5.
And a cooling device 21 for cooling and sizing the four-layer laminated composite pipe 1 having an outer layer formed therein, and a take-off machine 22 for taking the formed composite pipe 1 together.
次に、本発明の複合管の製造方法を説明する。 Next, a method for manufacturing the composite pipe of the present invention will be described.
先ず、内金型13の後方よりシート状繊維複合体8を連
続的に内金型13の外周と賦形ロール15,16により形成さ
れる環状の隙間14を通過させて供給し、連続繊維が管の
長手方向に配置された管状体10aを成形する(第3図な
いし第4図)。この時、加熱手段23によりシート状繊維
複合体8を加熱すると管状体10aの成形を容易にするこ
とができ、また賦形ロール15,16をシート状繊維複合体
8の軟化温度以上に加熱してもよい。First, the sheet-shaped fiber composite body 8 is continuously fed from the rear of the inner die 13 through the outer periphery of the inner die 13 and the annular gap 14 formed by the shaping rolls 15 and 16, and the continuous fiber is The tubular body 10a arranged in the longitudinal direction of the pipe is molded (FIGS. 3 to 4). At this time, the heating of the sheet-shaped fiber composite 8 by the heating means 23 can facilitate the molding of the tubular body 10a, and the shaping rolls 15 and 16 are heated to the softening temperature of the sheet-shaped fiber composite 8 or higher. May be.
続いて、上記管状体10aは内金型13及び内コア12と外
金型17とで形成されている環状の隙間に導入される。こ
こで押出機11から押出された溶融可塑化した熱可塑性樹
脂は内金型13により管状に成形され、内金型13内部で管
状体10aの内面に押出積層され、内層の熱可塑性樹脂の
外周に連続繊維が管の長手方向に配置された熱可塑性樹
脂の第1の強化層3が融着された2層管10bを成形す
る。Subsequently, the tubular body 10a is introduced into the annular gap formed by the inner die 13, the inner core 12 and the outer die 17. The melt-plasticized thermoplastic resin extruded from the extruder 11 is formed into a tubular shape by the inner mold 13, and is extruded and laminated on the inner surface of the tubular body 10a inside the inner mold 13, and the outer periphery of the thermoplastic resin of the inner layer is formed. A two-layer tube 10b is formed by fusing the first reinforcing layer 3 of a thermoplastic resin in which continuous fibers are arranged in the longitudinal direction of the tube.
続いて、2層管10bの周囲に巻回装置18を回転させて
繊維複合体9を巻回し、2層管10b及び繊維複合体9の
表面を加熱手段24により加熱して両者を融着し、連続繊
維が管の概略周方向に配置された熱可塑性樹脂の第2の
強化層4を設ける。2層管10bの表面が融着状態にある
ときに繊維複合体9を巻回することにより両者が融着し
た3層管10cが得られる。Then, the winding device 18 is rotated around the two-layer tube 10b to wind the fiber composite 9, and the surfaces of the two-layer tube 10b and the fiber composite 9 are heated by the heating means 24 to fuse the two. , A second reinforcing layer 4 of thermoplastic resin in which the continuous fibers are arranged approximately in the circumferential direction of the tube. By winding the fiber composite 9 while the surface of the two-layer tube 10b is in a fusion-bonded state, a three-layer tube 10c in which both are fused is obtained.
続いて、3層管10cの第2の強化層4の外周に、熱可
塑性樹脂を押出機19から被覆金型20をへて導入し、強化
層4の外周に外層5を設けた後、水槽等の冷却装置21に
より冷却サイジングして複合管1を製造し、引取機22に
より引き取る。Subsequently, a thermoplastic resin is introduced into the outer periphery of the second reinforcing layer 4 of the three-layer pipe 10c from the extruder 19 through the coating die 20, and the outer layer 5 is provided on the outer periphery of the reinforcing layer 4, and then the water tank. The composite pipe 1 is manufactured by cooling and sizing with a cooling device 21 such as the above, and taken up by a take-up machine 22.
なお、2層管10aの外周に繊維複合体9を巻回融着す
る際、2層管10aが変形するのを防止するために、内コ
ア12を2層管10aの内部に押出方向に突出させ、この内
コア12の外側位置で繊維複合体9を2層管10aの外周に
巻回する方法、あるいは内コア12の先端より2層管10a
の内部に冷却空気を吹き込み2層管10aの内面を冷却し
つつ繊維複合体9を巻回する方法等が採用されるように
してもよい。また、上記において、複合管は引取機で引
き取りながら、一連の製造工程を連続的に行うことによ
り連続して製造する例について示したが、2層管を予め
別の工程で製造しておき、後で第2の強化層を成形して
もよい。また、上記ににおいては、シート状繊維複合体
を加熱する例について示したが、加熱操作はなくてもよ
いし、加熱手段の設置位置も上記例に限られない。In order to prevent the two-layer tube 10a from being deformed when the fiber composite body 9 is wound and fused around the outer periphery of the two-layer tube 10a, the inner core 12 is projected into the two-layer tube 10a in the extrusion direction. Then, the fiber composite body 9 is wound around the outer circumference of the two-layer tube 10a at a position outside the inner core 12, or the two-layer tube 10a is wound from the tip of the inner core 12.
It is also possible to adopt a method in which cooling air is blown into the interior of the fiber to wind the fiber composite 9 while cooling the inner surface of the two-layer tube 10a. Further, in the above, while the composite pipe is taken by the take-off machine, an example of continuously producing by performing a series of production steps is shown, but a two-layer pipe is produced in another process in advance, The second reinforcing layer may be molded later. Further, in the above, an example of heating the sheet-shaped fiber composite has been shown, but the heating operation may be omitted, and the installation position of the heating means is not limited to the above example.
また、上記において、複合管を熱可塑性樹脂の内層か
ら外周に、順次連続繊維が管の長手方向に配置された第
1の強化層と、連続繊維が管の概略周方向に巻回配置さ
れた第2の強化層と、熱可塑性樹脂の外層とから構成さ
れた例について説明したが、複合管の強化層の配置はこ
の例に限定されないと共に、強化層の数も上記例に限定
されず、第1の強化層と第2の強化層とはそれぞれ複数
であってもよいし、また強化層の外周に熱可塑性樹脂の
外層はなくてもよい。Further, in the above, the composite pipe is arranged from the inner layer of the thermoplastic resin to the outer periphery thereof, the first reinforcing layer in which continuous fibers are sequentially arranged in the longitudinal direction of the pipe, and the continuous fibers are arranged in a substantially circumferential direction of the pipe. Although the example including the second reinforcing layer and the outer layer of the thermoplastic resin has been described, the arrangement of the reinforcing layer of the composite pipe is not limited to this example, and the number of the reinforcing layers is not limited to the above example. Each of the first reinforcing layer and the second reinforcing layer may be plural, and the outer layer of the thermoplastic resin may not be provided on the outer periphery of the reinforcing layer.
(作用) 本発明の複合管は、内層の熱可塑性樹脂管の外周に、
連続繊維が管の長手方向に配置された第1の強化層及び
連続繊維が管の概略周方向に配置された第2の強化層か
らなり、これらの各層の境界の熱可塑性樹脂は融着一体
化している。そのため、管の長手方向に配置された第1
の強化層の連続繊維により管の線膨張が抑制され、熱収
縮が低減され、各層の界面での剥離が発生しにくくなる
と共に、管の概略周方向に配置された第2の強化層によ
り管の耐圧性、耐衝撃性が向上する。(Function) The composite pipe of the present invention is provided with the outer periphery of the thermoplastic resin pipe of the inner layer,
The continuous fibers consist of a first reinforcing layer arranged in the longitudinal direction of the pipe and a second reinforcing layer in which the continuous fibers are arranged substantially in the circumferential direction of the pipe, and the thermoplastic resin at the boundary of each of these layers is fused and integrated. It has become. Therefore, the first, which is arranged in the longitudinal direction of the pipe,
The continuous fiber of the reinforcing layer suppresses the linear expansion of the tube, reduces the thermal contraction, and makes it difficult for peeling to occur at the interface of each layer, and the second reinforcing layer arranged substantially in the circumferential direction of the tube The pressure resistance and impact resistance are improved.
また、本発明の複合管の製造方法は、多数のフィラメ
ントよりなる連続繊維に熱可塑性樹脂が保持された繊維
複合体の連続繊維が管の長手方向に配置された管状体を
成形する工程とこの管状体の内面に熱可塑性樹脂管を溶
融状態で押出積層して2層管を成形する工程とこの2層
管の外周に多数のフィラメントよりなる連続繊維に熱可
塑性樹脂が保持された繊維複合体を巻回融着する工程か
らなるので、各層の境界において熱可塑性樹脂が融着一
体化した複合管が容易に製造される。Further, the method for producing a composite pipe of the present invention comprises a step of forming a tubular body in which continuous fibers of a fiber composite in which a thermoplastic resin is held in continuous fibers composed of a large number of filaments are arranged in the longitudinal direction of the pipe. A step of extruding and laminating a thermoplastic resin tube in a molten state on the inner surface of a tubular body to form a two-layer tube, and a fiber composite in which the thermoplastic resin is held in continuous fibers made of a number of filaments on the outer periphery of the two-layer tube Since it comprises the process of winding and fusing, the composite pipe in which the thermoplastic resin is fused and integrated at the boundary of each layer is easily manufactured.
(実施例) 本発明の実施例を図面に基づいて説明する。(Example) The Example of this invention is described based on drawing.
実施例1 1)繊維複合体の作製 第5図に示すように、直径23μmのフィラメントより
構成されるロービング状ガラス繊維(4400tex)6の10
本を、酢酸ビニル−塩化ビニル共重合樹脂を主成分とす
る粒子径が約250μmの粉体状熱可塑性樹脂組成物7
が、エアー30aにより流動化されている流動床30中を通
過させて、ガラス繊維6のフィラメント間に粉体状熱可
塑性樹脂を付着させた後、約180℃に加熱された1対の
加熱ロール31により加熱・加圧し、熱可塑性樹脂を溶融
させガラス繊維6と一体化せしめ、厚み0.6mmの繊維複
合体6aを作製した。この繊維複合体の熱可塑性樹脂とガ
ラス繊維との容積割合は、熱可塑性樹脂:ガラス繊維=
75:25であった。Example 1 1) Preparation of fiber composite As shown in FIG. 5, 10 of roving glass fiber (4400tex) 6 composed of filaments having a diameter of 23 μm was used.
A powdery thermoplastic resin composition 7 containing a vinyl acetate-vinyl chloride copolymer resin as a main component and having a particle diameter of about 250 μm.
Is passed through the fluidized bed 30 fluidized by the air 30a to adhere the powdery thermoplastic resin between the filaments of the glass fiber 6 and then heated to about 180 ° C. By heating and pressurizing with 31, the thermoplastic resin was melted and integrated with the glass fiber 6, and a fiber composite 6a having a thickness of 0.6 mm was produced. The volume ratio between the thermoplastic resin and the glass fiber of this fiber composite is as follows: thermoplastic resin: glass fiber =
It was 75:25.
上記繊維複合体6aを切断し、幅107mm、厚み0.6mmの連
続ガラス繊維が長手方向に配置されたシート状繊維複合
体8を作製した。又、上記繊維複合体6aを切断し、幅20
mm、厚み0.6mmの連続ガラス繊維が長さ方向に配置され
たテープ状の繊維複合体9を作製した。The fiber composite 6a was cut to prepare a sheet-shaped fiber composite 8 in which continuous glass fibers having a width of 107 mm and a thickness of 0.6 mm were arranged in the longitudinal direction. Also, the fiber composite 6a is cut into a width of 20
A tape-shaped fiber composite 9 was prepared in which continuous glass fibers having a thickness of 0.6 mm and a thickness of 0.6 mm were arranged in the longitudinal direction.
2)複合管の製造 上記シート状繊維複合体8及びテープ状の繊維複合体
9を用いて、第2図に示すような工程により複合管を製
造した。2) Manufacture of composite pipe Using the sheet-shaped fiber composite 8 and the tape-shaped fiber composite 9 described above, a composite pipe was manufactured by the steps shown in FIG.
シート状繊維複合体8を、加熱手段23として用いる熱
風発生機により熱風を吹きつけて加熱しつつ、賦形ロー
ル15,16により外径=約34mm、厚み0.6mmの管状体10aに
成形した。The sheet-shaped fiber composite body 8 was formed into a tubular body 10a having an outer diameter of about 34 mm and a thickness of 0.6 mm by the shaping rolls 15 and 16 while being heated by blowing hot air with a hot air generator used as the heating means 23.
続いて、上記管状体10aを内金型13(温度=約210℃)
と内コア12(温度=約210℃)と外金型17(温度=約210
℃)とで構成される環状の隙間に導入し、押出機11によ
り溶融可塑化され、内金型13により管状に成形された塩
素化ポリ塩化ビニル樹脂を、外金型17内部で管状体10a
内面に押出積層し、塩素化ポリ塩化ビニル樹脂管(厚み
約1.5mm)を内層2とした塩素化ポリ塩化ビニル樹脂管
の外周に連続ガラス繊維が管の長手方向に配置された酢
酸ビニル−塩化ビニル共重合樹脂の第1の強化層3(厚
み約0.6mm)が融着された外径=34mmの2層管10aを成形
した。Subsequently, the tubular body 10a is attached to the inner mold 13 (temperature = about 210 ° C.).
Inner core 12 (Temperature = about 210 ℃) and outer mold 17 (Temperature = about 210 ℃)
The chlorinated polyvinyl chloride resin, which has been introduced into an annular gap composed of the (3) and is melted and plasticized by the extruder 11 and formed into a tube by the inner die 13, inside the outer die 17 is a tubular body 10a.
Chlorinated polyvinyl chloride resin tube (thickness: about 1.5 mm) is laminated by extrusion on the inner surface and the inner layer 2 is a chlorinated polyvinyl chloride resin tube. Continuous glass fibers are arranged on the outer circumference of the tube. A two-layer pipe 10a having an outer diameter of 34 mm and having a first reinforcing layer 3 (having a thickness of about 0.6 mm) of vinyl copolymer resin fused thereto was formed.
続いて、上記2層管10aの外周に、テープ状の繊維複
合体9を巻回装置18を用いて、連続ガラス繊維を管の長
手方向に対して10.5°傾けて連続的に巻回し、遠赤外線
ヒーターの加熱手段24により2層管10a及びシート状繊
維複合体8を加熱し、両者を融着一体化し、2層管10a
の外周に連続ガラス繊維が管の概略周方向に配置された
酢酸ビニル−塩化ビニル共重合樹脂の厚みが約0.6mmの
第2の強化層4を設けた。Then, the tape-shaped fiber composite 9 is wound around the outer circumference of the two-layer tube 10a by using a winding device 18 to continuously wind the continuous glass fibers at an angle of 10.5 ° with respect to the longitudinal direction of the tube, and The two-layer tube 10a and the sheet-shaped fiber composite 8 are heated by the heating means 24 of the infrared heater, and the two are fused and integrated to form the two-layer tube 10a.
A second reinforcing layer 4 having a thickness of about 0.6 mm of a vinyl acetate-vinyl chloride copolymer resin, in which continuous glass fibers were arranged in a substantially circumferential direction of the tube, was provided on the outer circumference of the.
続いて、強化層4が設けられた3層の積層管10cを被
覆金型20に導入し、押出機19により溶融可塑化されたポ
リ塩化ビニル樹脂を積層管10cの強化層4の外周に押出
被覆し外層5(厚み約1mm)を設けた後、冷却装置21で
冷却サイジングを施し4層の複合管1とした。この上記
一連の工程を引取機22で引き取りつつ行い、複合管1を
連続的に製造した。Subsequently, the three-layer laminated pipe 10c provided with the reinforcing layer 4 is introduced into the coating mold 20, and the polyvinyl chloride resin melt-plasticized by the extruder 19 is extruded onto the outer periphery of the reinforcing layer 4 of the laminated pipe 10c. After coating and providing the outer layer 5 (thickness: about 1 mm), cooling sizing was performed by the cooling device 21 to obtain the four-layer composite pipe 1. The composite pipe 1 was continuously manufactured by performing the above series of steps while being taken by the take-up machine 22.
得られた複合管1は、内径が約30.8mm、外径が約37.2
mmの積層管であって、塩素化ポリ塩化ビニル樹脂管の内
層2の外周に連続ガラス繊維が管の長手方向に配置され
た酢酸ビニル−塩化ビニル共重合樹脂の第1の強化層3
が融着され、この強化層の外周に連続ガラス繊維が管の
概略周方向に配置された酢酸ビニル−塩化ビニル共重合
樹脂の第2の強化層4が融着され、さらにこの強化層4
の外周にポリ塩化ビニル樹脂管の外層5が融着されてな
る4層の複合管であった。The obtained composite pipe 1 has an inner diameter of about 30.8 mm and an outer diameter of about 37.2 mm.
mm laminated tube, the first reinforcing layer 3 of vinyl acetate-vinyl chloride copolymer resin in which continuous glass fibers are arranged on the outer periphery of the inner layer 2 of the chlorinated polyvinyl chloride resin tube in the longitudinal direction of the tube.
And a second reinforcing layer 4 of vinyl acetate-vinyl chloride copolymer resin, in which continuous glass fibers are arranged substantially in the circumferential direction of the tube, is fused to the outer periphery of the reinforcing layer.
It was a four-layer composite pipe in which the outer layer 5 of the polyvinyl chloride resin pipe was fused to the outer periphery of the composite pipe.
比較例 特開昭59−48120号公報に開示された製造方法によ
り、内径30mm、外径34mmの塩素化ポリ塩化ビニル樹脂管
の内層の外周に、連続ガラス繊維が管の長手方向に配置
された不飽和ポリエステル樹脂(熱硬化性樹脂)の強化
層(厚み約0.6mm)が設けられ、さらにこの強化層の外
周に連続ガラス繊維が管の概略周方向に配置された不飽
和ポリエステル樹脂(熱硬化性樹脂)の強化層(厚み約
0.6mm)が設けられ、更にこの強化層の外周にポリ塩化
ビニル樹脂の外層(厚み約1mm)が融着されてなる複合
管を成形した。Comparative Example According to the manufacturing method disclosed in JP-A-59-48120, continuous glass fibers were arranged in the longitudinal direction of the tube on the outer periphery of the inner layer of a chlorinated polyvinyl chloride resin tube having an inner diameter of 30 mm and an outer diameter of 34 mm. An unsaturated polyester resin (thermosetting resin) is provided with a reinforced layer (thickness of about 0.6 mm) of continuous unsaturated polyester resin (thermosetting resin), and continuous glass fibers are arranged around the outer periphery of the reinforced layer approximately in the circumferential direction of the tube. Reinforcing layer (thickness: approx.
0.6 mm) was provided, and an outer layer of polyvinyl chloride resin (thickness: about 1 mm) was fused to the outer periphery of the reinforcing layer to form a composite pipe.
(評価) 実施例1及び比較例で得られた複合管を長さ1mに切断
し、それぞれの複合管に温水(90℃)と冷水(25℃)を
15分間隔で交互に通水する冷熱繰り返し試験を行った。(Evaluation) The composite pipes obtained in Example 1 and Comparative Example were cut to a length of 1 m, and hot water (90 ° C) and cold water (25 ° C) were put into each composite pipe.
A cold-heat repeated test was conducted in which water was passed alternately at 15-minute intervals.
上記試験5000サイクル経過後の状態を観察したとこ
ろ、実施例1で得た複合管には異常は認められなかった
が、比較例で得た複合管は、内層の塩素化ポリ塩化ビニ
ル樹脂管と不飽和ポリエステル樹脂の界面で剥離が発生
していた。When the state after 5000 cycles of the above-mentioned test was observed, no abnormality was found in the composite pipe obtained in Example 1, but the composite pipe obtained in Comparative Example was the inner layer chlorinated polyvinyl chloride resin pipe. Peeling occurred at the interface of the unsaturated polyester resin.
(発明の効果) 本発明の複合管は、内層の熱可塑性樹脂の内層の外周
に、連続繊維が管の長手方向及び概略周方向に配置され
た2層の強化層が設けられていると共に融着一体化して
いるので、管の熱収縮が小さく、耐圧性、耐衝撃性に優
れている。また、温水を流した場合あるいは高温下で使
用した場合にも、複合管の各層の境界の界面での剥離が
発生しない。(Effects of the Invention) The composite pipe of the present invention is provided with two layers of reinforcing layers in which continuous fibers are arranged in the longitudinal direction and the substantially circumferential direction of the pipe on the outer periphery of the inner layer of the thermoplastic resin of the inner layer and melted. Since they are attached and integrated, the heat shrinkage of the tube is small, and the pressure resistance and impact resistance are excellent. Further, even when hot water is flowed or used at high temperature, peeling does not occur at the boundary interface between the layers of the composite pipe.
また、本発明の複合管の製造方法は、多数のフィラメ
ントよりなる連続繊維に熱可塑性樹脂が保持された繊維
複合体の連続繊維が管の長手方向に配置された管状体を
成形する工程とこの管状体の内面に熱可塑性樹脂管を溶
融状態で押出積層して2層管を成形する工程とこの2層
管の外周に多数のフィラメントよりなる連続繊維に熱可
塑性樹脂が保持された繊維複合体を巻回融着する工程か
らなるので、上記のような複合管を容易に製造すること
ができる。Further, the method for producing a composite pipe of the present invention comprises a step of forming a tubular body in which continuous fibers of a fiber composite in which a thermoplastic resin is held in continuous fibers composed of a large number of filaments are arranged in the longitudinal direction of the pipe. A step of extruding and laminating a thermoplastic resin tube in a molten state on the inner surface of a tubular body to form a two-layer tube, and a fiber composite in which the thermoplastic resin is held in continuous fibers made of a number of filaments on the outer periphery of the two-layer tube Since it comprises the step of winding and fusing, the composite pipe as described above can be easily manufactured.
第1図は本発明にかかる複合管の一実施例の斜視図、第
2図は本発明にかかる複合管の製造方法の工程の一例を
示す説明図、第3図は2層管を成形する工程を説明する
ための断面図、第4図はシート状繊維複合体から強化層
を成形する工程を説明するための平面図、第5図は繊維
複合体を製造する工程を説明する説明図である。 1;複合管、2;内層の熱可塑性樹脂管 3;第1の強化層、4;第2の強化層 8;シート状繊維複合体 9;繊維複合体、10a;管状体 11,19;押出機、18;巻回装置 20;被覆金型 21;冷却装置、22;引取機FIG. 1 is a perspective view of an embodiment of a composite pipe according to the present invention, FIG. 2 is an explanatory view showing an example of steps of a method for producing a composite pipe according to the present invention, and FIG. 3 is for forming a two-layer pipe. Sectional drawing for explaining the process, FIG. 4 is a plan view for explaining the step of forming a reinforcing layer from the sheet-shaped fiber composite, and FIG. 5 is an explanatory view for explaining the step of manufacturing the fiber composite. is there. 1; Composite tube, 2; Inner layer thermoplastic resin tube 3; First reinforcing layer, 4; Second reinforcing layer 8; Sheet-shaped fiber composite 9; Fiber composite, 10a; Tubular body 11, 19; Extrusion Machine, 18; winding device 20; coating mold 21; cooling device, 22; take-up machine
Claims (2)
手方向に配置された熱可塑性樹脂の強化層、および連続
繊維が管の略周方向に巻回配置された熱可塑性樹脂の強
化層が互いに融着一体化されてなることを特徴とする複
合管。1. A thermoplastic resin tube as an inner layer, a thermoplastic resin reinforcing layer in which continuous fibers are arranged in a longitudinal direction of the tube, and a thermoplastic resin in which continuous fibers are wound and arranged in a substantially circumferential direction of the tube. A composite pipe in which layers are fused and integrated with each other.
る連続繊維に熱可塑性樹脂が保持されてなるシート状繊
維複合体から上記連続繊維が長手方向に配置された管状
体を成形する工程、(b)該管状体の内面に熱可塑性樹
脂を溶融状態で押出積層し2層管を成形する工程、
(c)該2層管の外周に多数の連続するフィラメントよ
りなる連続繊維に熱可塑性樹脂が保持されてなる繊維複
合体を巻回融着する工程を包含してなることを特徴とす
る複合管の製造方法。2. (a) A step of forming a tubular body in which the continuous fibers are arranged in the longitudinal direction from a sheet-shaped fiber composite in which a thermoplastic resin is held by continuous fibers composed of a large number of continuous filaments, b) a step of extruding and laminating a thermoplastic resin in a molten state on the inner surface of the tubular body to form a two-layer tube,
(C) A composite pipe including a step of winding and fusing a fiber composite in which a thermoplastic resin is held on continuous fibers composed of a large number of continuous filaments around the outer periphery of the two-layer pipe. Manufacturing method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1298509A JPH086847B2 (en) | 1989-11-16 | 1989-11-16 | Composite pipe and manufacturing method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1298509A JPH086847B2 (en) | 1989-11-16 | 1989-11-16 | Composite pipe and manufacturing method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH03157591A JPH03157591A (en) | 1991-07-05 |
JPH086847B2 true JPH086847B2 (en) | 1996-01-29 |
Family
ID=17860638
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1298509A Expired - Fee Related JPH086847B2 (en) | 1989-11-16 | 1989-11-16 | Composite pipe and manufacturing method thereof |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH086847B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021094840A1 (en) | 2019-11-15 | 2021-05-20 | Nexgen Pipes Pte. Ltd. | Pipe forming apparatus |
US20220134689A1 (en) * | 2016-06-01 | 2022-05-05 | Long Pipes Limited | Construction of tubular assemblies |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003065464A (en) * | 2001-08-24 | 2003-03-05 | Furukawa Electric Co Ltd:The | Composite pipe |
EP2667072A1 (en) * | 2012-05-21 | 2013-11-27 | MIR Arastima ve Gelistime A.S. | Thermoplastic pipe having longitudinally arranged continuous fiber reinforcement and production method thereof |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS602388U (en) * | 1984-05-04 | 1985-01-09 | 富士通株式会社 | DC/DC converter power supply |
JPS6222038A (en) * | 1985-07-23 | 1987-01-30 | Matsushita Electric Ind Co Ltd | Temperature detection device |
-
1989
- 1989-11-16 JP JP1298509A patent/JPH086847B2/en not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20220134689A1 (en) * | 2016-06-01 | 2022-05-05 | Long Pipes Limited | Construction of tubular assemblies |
US11806919B2 (en) * | 2016-06-01 | 2023-11-07 | Long Pipes Usa, Inc. | Construction of tubular assemblies |
WO2021094840A1 (en) | 2019-11-15 | 2021-05-20 | Nexgen Pipes Pte. Ltd. | Pipe forming apparatus |
EP4058273A4 (en) * | 2019-11-15 | 2023-12-27 | Nexgen Pipes Pte. Ltd. | TUBE FORMING DEVICE |
Also Published As
Publication number | Publication date |
---|---|
JPH03157591A (en) | 1991-07-05 |
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