JPH08329958A - Spiral type non-aqueous electrolyte battery and method for winding spiral electrode body - Google Patents
Spiral type non-aqueous electrolyte battery and method for winding spiral electrode bodyInfo
- Publication number
- JPH08329958A JPH08329958A JP20414195A JP20414195A JPH08329958A JP H08329958 A JPH08329958 A JP H08329958A JP 20414195 A JP20414195 A JP 20414195A JP 20414195 A JP20414195 A JP 20414195A JP H08329958 A JPH08329958 A JP H08329958A
- Authority
- JP
- Japan
- Prior art keywords
- core
- spiral
- winding
- negative electrode
- electrode body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y02E60/12—
Landscapes
- Primary Cells (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、金属製の負極缶内
に渦巻状電極体を配設したスパイラル形非水電解液電池
およびその渦巻状電極体の巻回方法に関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a spiral type non-aqueous electrolyte battery in which a spirally wound electrode body is arranged in a metal negative electrode can and a method for winding the spirally wound electrode body.
【0002】[0002]
【従来の技術】この種のリチウム電池などのスパイラル
形非水電解液電池の構造としては、金属製の負極缶内
に、正極板と負極板とをセパレータを介して重ね合わせ
巻回してなる渦巻状電極体を配設し、この巻回の中央に
形成される孔に挿着される中空筒部をその片面に有し、
且つ、渦巻状電極体の中心空隙部に冠着される突片をそ
の周縁部に有してなる絶縁部材を配した構成が従来公知
である(実公平4−21249号公報)。2. Description of the Related Art A spiral type non-aqueous electrolyte battery such as a lithium battery of this type has a spiral structure in which a positive electrode plate and a negative electrode plate are superposed and wound in a metal negative electrode can via a separator. A cylindrical electrode body is disposed, and a hollow cylindrical portion that is inserted into a hole formed in the center of the winding is attached to one side of the cylindrical electrode body,
In addition, there has been conventionally known a structure in which an insulating member having a projecting piece capped in a central void portion of a spirally-wound electrode body is arranged at a peripheral portion thereof (Japanese Utility Model Publication No. 4-212249).
【0003】上記渦巻状電極体の巻回方法としては二つ
に大別され、その一つは、例えば負極板の両側面をセパ
レータで被覆し、その被覆体の端部を巻回機の回転軸に
形成した溝部内に挿入したのち、これを約1回転させ、
つぎにこれに正極板を添えて一緒に巻回する(特公昭4
1−7133号公報)。もう一つは、上記セパレータの
延出端部を巻回機の回転軸に形成した縦割溝内に挿入し
て挟持し、約1回転させて該セパレータの延出部を巻回
後、つぎにこれに正極板を添えて一緒に巻回し、こうし
て巻回終了後はその巻回体を回転軸から取除く(特開昭
62−147661号公報)。The method of winding the spirally wound electrode body is roughly classified into two, one of which is, for example, coating both side surfaces of the negative electrode plate with separators, and rotating the winding machine at the ends of the cover body. After inserting it into the groove formed on the shaft, rotate it about 1 turn,
Next, add a positive electrode plate to this and wind it together.
1-7133). The other is to insert the extended end of the separator into a vertical groove formed in the rotary shaft of the winding machine and sandwich it, and after rotating the extended part of the separator about 1 turn, Then, the positive electrode plate is attached to this and wound together, and after the winding is completed, the wound body is removed from the rotary shaft (JP-A-62-147661).
【0004】この他、前記渦巻状電極体の中心空隙部に
ガス抜き孔を設けた棒状絶縁体を配設することによっ
て、該電極体の体積増加による内部短絡を防止するとと
もに、通常、電解液注入後に挿入される前記棒状絶縁体
により電解液の溢出を防止する提案(実開平1−155
262号公報)がなされている。尚、この公報には、巻
回体を製作する時に巻取棒となる巻取芯を絶縁体により
構成し、所定回数巻取った後に上記巻取芯とされた絶縁
体と巻回体とを一緒に切断し、その後に外装缶に収納
し、ガスケットを介してかしめ取付けされた蓋体により
密閉してもよいとの記載がなされている。In addition, by disposing a rod-shaped insulator provided with a gas vent hole in the central cavity of the spiral electrode body, an internal short circuit due to an increase in the volume of the electrode body is prevented, and the electrolytic solution is usually used. Proposal to prevent the electrolyte from overflowing by the rod-shaped insulator inserted after the injection (Actual Kaihei 1-155)
No. 262). In this publication, a winding core that serves as a winding rod when a winding body is manufactured is made of an insulating material, and after winding a predetermined number of times, the winding core is made into the insulating material and the winding material. It is described that they may be cut together and then housed in an outer can and sealed by a lid attached by caulking via a gasket.
【0005】[0005]
【発明が解決しようとする課題】上記回転軸の溝部内に
挿入された電極板は略直角に折り曲げられるため、該電
極板部分が崩れるおそれがある。また、上記回転軸の縦
割溝内に挿入されたセパレータ延出部は、渦巻状電極体
の中心空隙部にノの字状に残るため、渦巻状電極体の中
心部にスポット溶接用の電極を挿入して金属製の負極缶
と負極リード板とを接続させる際には、上記ノの字状の
セパレータ部分を中心空隙部内面に沿わせるように人手
によって修正を施さねばならなかった。更に、従来技術
では、負極缶に渦巻状電極体を挿入するにせよ、引き続
いて行われる群押えの挿入、スポット溶接用電極棒の挿
入、更には電解液の注入にしても、センター位置決め基
準が不安定乃至は取りずらかったため、スパイラル型非
水電解液電池の高速自動組立てを達成するうえで大きな
障害となっていた。Since the electrode plate inserted into the groove of the rotary shaft is bent at a substantially right angle, the electrode plate portion may be collapsed. Further, since the separator extension portion inserted in the vertical groove of the rotary shaft remains in a square shape in the central void portion of the spiral electrode body, an electrode for spot welding is formed in the center portion of the spiral electrode body. When inserting and connecting the metal negative electrode can and the negative electrode lead plate, it had to be manually corrected so that the square-shaped separator portion was aligned with the inner surface of the central cavity. Furthermore, in the prior art, even if the spirally wound electrode body is inserted into the negative electrode can, the center positioning reference is maintained even when the group presser is inserted subsequently, the spot welding electrode rod is inserted, and further, the electrolytic solution is injected. Since it was unstable or difficult to remove, it was a major obstacle in achieving high-speed automatic assembly of the spiral type non-aqueous electrolyte battery.
【0006】そこでこの発明では、高速自動組立てを可
能とする新規なスパイラル型非水電解液電池の構造なら
びにその渦巻状電極体の巻回方法を提供することを目的
としている。Therefore, an object of the present invention is to provide a structure of a novel spiral type non-aqueous electrolyte battery which enables high-speed automatic assembly and a winding method of the spiral electrode body.
【0007】[0007]
【課題を解決するための手段】上記の目的を達成するた
め、本発明になるスパイラル型非水電解液電池は、金属
製の負極缶内に、長手方向全長に亘って縦切欠部を形成
した断面C形をなす合成樹脂製又はステンレス鋼製のコ
アと、そのコアを巻芯として負極板と正極板とがセパレ
ータを介して積層状に巻回されてなる渦巻状電極体と、
該負極缶内底面と該渦巻状電極体の下面とを隔絶する絶
縁部材とを配設してなるものである。In order to achieve the above object, a spiral non-aqueous electrolyte battery according to the present invention has a vertical notch formed in a metal negative electrode can over the entire length in the longitudinal direction. A synthetic resin or stainless steel core having a C-shaped cross section, and a spirally wound electrode body formed by winding a negative electrode plate and a positive electrode plate around the core in a laminated manner with a separator interposed therebetween.
An insulating member that separates the bottom surface of the negative electrode can from the lower surface of the spiral electrode body is provided.
【0008】上記コアに貫通孔を形設してもよい。A through hole may be formed in the core.
【0009】上記した絶縁部材は、環状円板部の片側に
上記コアの内側に嵌着可能な筒部を一体的に形成した鍔
付短筒成型品、または上記コアの下端外周部に嵌着させ
ることができる環状円板、あるいは上記コアの下端部
に、該コアの軸芯に対し鈍角状に一体形成された鍔状板
のいずれでもよい。The above-mentioned insulating member is a flanged short cylinder molded product integrally formed with a tubular portion which can be fitted inside the core on one side of an annular disc portion, or is fitted to the outer peripheral portion of the lower end of the core. It may be an annular disc that can be used, or a brim-shaped plate integrally formed at the lower end of the core with an obtuse angle with respect to the axis of the core.
【0010】また、金属製の負極缶と、その負極缶内に
収納され、長手方向全長に亘って縦切欠部を形成した断
面C形をなす合成樹脂製又はステンレス鋼製のコアを巻
芯として負極板と正極板とがセパレータを介して積層状
に巻回されてなる渦巻状電極体と、その負極缶の内底面
と渦巻状電極体の底面との間に配設され、切欠部を有す
る環状の絶縁部材とからなるスパイラル型非水電解液電
池であって、上記渦巻状電極体の負極板に接続された負
極リード板に絶縁テープを貼設し、この絶縁テープで上
記絶縁部材の切欠部を塞ぐようにしたものである。Further, a metal negative electrode can and a core made of synthetic resin or stainless steel having a C-shaped cross section, which is housed in the negative electrode can and formed with a vertical cutout along the entire length in the longitudinal direction, are used as cores. A spirally wound electrode body in which a negative electrode plate and a positive electrode plate are wound in a laminated manner via a separator, and is disposed between the inner bottom surface of the negative electrode can and the bottom surface of the spirally wound electrode body, and has a cutout portion. A spiral type non-aqueous electrolyte battery comprising an annular insulating member, wherein an insulating tape is attached to a negative electrode lead plate connected to the negative electrode plate of the spirally wound electrode body, and a cutout of the insulating member is formed with this insulating tape. It is designed to close the part.
【0011】更に、金属製の負極缶と、その負極缶内に
収納され、長手方向全長に亘って縦切欠部を形成した断
面C形をなす合成樹脂製又はステンレス鋼製のコアを巻
芯として負極板と正極板とがセパレータを介して積層状
に巻回されてなる渦巻状電極体と、その負極缶の内底面
と渦巻状電極体の底面との間に配設され、上記コアに一
体形成された環状の絶縁部材とからなるスパイラル型非
水電解液電池であって、上記絶縁部材に、上記コアの縦
切欠部と繋がる薄肉部を設け、この薄肉部に放射方向の
切込みを入れたものである。Further, a metal negative electrode can and a core made of synthetic resin or stainless steel having a C-shaped cross section, which is housed in the negative electrode can and has a vertical notch formed over the entire length in the longitudinal direction, are used as cores. A spiral electrode body in which a negative electrode plate and a positive electrode plate are wound in a laminated manner with a separator interposed therebetween, and is disposed between the inner bottom surface of the negative electrode can and the bottom surface of the spiral electrode body, and integrated with the core. A spiral non-aqueous electrolyte battery comprising a formed annular insulating member, wherein the insulating member is provided with a thin portion connected to the vertical cutout portion of the core, and a radial notch is formed in this thin portion. It is a thing.
【0012】本発明になるスパイラル型電極体の巻回方
法は、長手方向全長に亘って縦切欠部を形成した断面C
形をなす合成樹脂製又はステンレス鋼製のコアを巻回機
の例えばキー付回転軸に挿入し、そのコアの縦切欠部と
巻回機の回転軸のキーとを係合係止させ、このコアの外
表面に負極板または正極板のうちいずれか一方の電極板
の両側面を被覆したセパレータの延出端部を固着する。
または、長手方向全長に亘って縦切欠部を形成した断面
C形をなす合成樹脂製又はステンレス鋼製のコアを巻回
機の例えばキー付回転軸の外側から押し込んで嵌め合わ
せ、該コアの縦切欠部と巻回機の回転軸のキーとを係合
係止させると共に、負極板または正極板のうちいずれか
一方の電極板の両側面を被覆したセパレータの延出端部
を該コアと該回転軸の間で挟持させる。その後は、いず
れも、該セパレータ延出部を巻回してから、つぎに他の
電極板を添えて一緒に巻回し、巻回作業終了後は上記回
転軸からコアを含む巻回体を取り外す。The spiral electrode body winding method according to the present invention has a cross-section C in which a vertical notch is formed over the entire length in the longitudinal direction.
A synthetic resin or stainless steel core having a shape is inserted into, for example, a rotary shaft with a key of a winding machine, and a vertical cutout portion of the core is engaged and locked with a key of the rotary shaft of the winding machine. The extending end portion of the separator that covers both side surfaces of either the negative electrode plate or the positive electrode plate is fixed to the outer surface of the core.
Alternatively, a synthetic resin or stainless steel core having a C-shaped cross section with a longitudinal cutout formed over the entire length in the longitudinal direction is pushed in from the outside of, for example, a rotary shaft with a key of a winding machine to fit the core into the longitudinal direction of the core. The cutout portion and the key of the rotating shaft of the winding machine are engaged and locked, and the extending end portion of the separator that covers both side surfaces of one of the negative electrode plate and the positive electrode plate is provided with the core and the core. Hold it between the rotating shafts. After that, in each case, the separator extending portion is wound, then the other electrode plate is attached and wound together, and after the winding work is completed, the wound body including the core is removed from the rotating shaft.
【0013】コアの外側に渦巻状電極体を巻回形成する
回転力は、巻回機の回転軸に設けた例えばキーと、コア
の長手方向全長に亘って形成した縦切欠部との係合係止
で確実に得られる。このコアは、渦巻状電極体の負極缶
内への挿入、群押えの挿入、スポット溶接用電極棒の挿
入、更には電解液注入管の挿入等が連続するスパイラル
型非水電解液電池の高速自動組立て工程で、確実なセン
ター位置決め基準として利用することができる。The rotating force for forming the spirally wound electrode body on the outer side of the core is obtained by engaging a key provided on the rotating shaft of the winding machine with a vertical notch formed over the entire length of the core in the longitudinal direction. Securely obtained by locking. This core is a high-speed spiral type non-aqueous electrolyte battery in which the spiral electrode body is inserted into the negative electrode can, the group presser is inserted, the spot welding electrode rod is inserted, and further the electrolyte injection pipe is inserted. It can be used as a reliable center positioning reference in the automatic assembly process.
【0014】負極缶内底面と該渦巻状電極体の下面とを
隔絶する絶縁部材がコアと別体構成であると、コアの外
側に渦巻状電極体を巻回形成するときに何の障害もない
状態で行え、巻回後にコアと絶縁部材とを嵌着して一体
化できる。また、絶縁部材に相当する鍔状板をコアの下
端部に該コアの軸芯に対し鈍角状をなして一体形成した
構成であると、巻回体が鍔状板に当たらないように逃が
しているため、円滑に最後まで巻回でき、巻回後のコア
と絶縁部材との一体化は不要である。If the insulating member that separates the inner bottom surface of the negative electrode can from the lower surface of the spirally wound electrode body is formed separately from the core, there is no obstacle when the spirally wound electrode body is formed outside the core. It can be performed in the absence of the core, and the core and the insulating member can be fitted and integrated after winding. Further, in the structure in which the collar-shaped plate corresponding to the insulating member is integrally formed at the lower end of the core with an obtuse angle with respect to the axis of the core, the winding body escapes so as not to hit the collar-shaped plate. Therefore, the winding can be smoothly performed to the end, and it is not necessary to integrate the wound core with the insulating member.
【0015】コアに貫通孔があると、電解液注入の際、
コアの中心部より浸入しようとする電解液が、この貫通
孔を通過して渦巻状電極体に浸透していくことができ
る。If the core has a through hole, when the electrolyte is injected,
The electrolytic solution, which is about to enter from the central portion of the core, can pass through the through hole and permeate into the spiral electrode body.
【0016】[0016]
【発明の実施の形態】以下、この発明をスパイラル形リ
チウム電池に適用した実施形態について説明する。BEST MODE FOR CARRYING OUT THE INVENTION Embodiments in which the present invention is applied to a spiral lithium battery will be described below.
【0017】図1において、金属製の負極缶1内には、
長手方向全長に亘って縦切欠部8を形成した断面C形を
なす合成樹脂製又はステンレス鋼製のコア9が巻芯とな
って、このコア9の外側に渦巻状電極体2が配設されて
いる。この渦巻状電極体2が、リチウムからなる負極板
3と、二酸化マンガンを活物質とする正極板4とがポリ
プロピレン不織布製のセパレータ5を交互に介して重合
された巻回体である点、および負極缶1の内底面と渦巻
状電極体2の下面との間に配設された絶縁部材7によっ
て両者を隔絶している点では従来と変わりない。図示の
絶縁部材7は、環状円板部7aの片側に上記コア9の内
側に嵌着することができる筒部7bを一体的に形成した
鍔付短筒成型品であり、平らな環状円板部7aで負極リ
ード板6を負極缶1の内底面に押し付けている。尚、図
中、11は正極リード板10と電気的に連結されている
正極端子、12は群押え、13は巻回された渦巻状電極
体2がばらけないように貼着した群固定テープである。In FIG. 1, in the negative electrode can 1 made of metal,
A core 9 made of synthetic resin or stainless steel and having a C-shaped cross section with a longitudinal cutout 8 formed along the entire length in the longitudinal direction serves as a winding core, and the spiral electrode body 2 is arranged outside the core 9. ing. The spiral electrode body 2 is a wound body in which a negative electrode plate 3 made of lithium and a positive electrode plate 4 having manganese dioxide as an active material are polymerized by alternately interposing a separator 5 made of polypropylene nonwoven fabric, and It is the same as the conventional one in that the insulating member 7 disposed between the inner bottom surface of the negative electrode can 1 and the lower surface of the spirally wound electrode body 2 isolates the both. The insulating member 7 shown in the figure is a flanged short cylinder molded product integrally formed with a tubular portion 7b which can be fitted inside the core 9 on one side of the annular disc portion 7a, and is a flat annular disc. The negative electrode lead plate 6 is pressed against the inner bottom surface of the negative electrode can 1 at the portion 7a. In the figure, 11 is a positive electrode terminal electrically connected to the positive electrode lead plate 10, 12 is a group retainer, and 13 is a group fixing tape adhered so that the wound spirally wound electrode body 2 does not come apart. Is.
【0018】上記した長手方向全長に亘る縦切欠部8を
形成したコア9を反りのない成形品として得るには、図
6に示したように、縦切欠部8の端面内側に肉盛り部1
4,14を形成してバランスをとるとよい。絶縁部材7
は、図1の鍔付短筒成型品のほか、図2に示すように、
コア9の下端部が嵌着可能な孔15を穿設した環状円板
7cでもよい。このようにコア9と絶縁部材7とを分け
るときには両者の嵌着工程を必要とするが、コア9の外
側に渦巻状電極体2を巻回形成する際に何の障害物もな
い状態で巻回できることになる。これに反し、コア9の
一端に直角に鍔状板を一体形成したとすると、上記した
コア9と絶縁部材7の嵌着工程は省略できても、セパレ
ータ5を最初にコア9に固定する際余程厳密に行わない
と、巻回途中で巻回物が段々鍔状板側に寄って巻回不能
になり兼ねない。In order to obtain the above-described core 9 having the vertical notch 8 formed over the entire length in the longitudinal direction as a warp-free molded product, as shown in FIG. 6, the built-up portion 1 is formed inside the end face of the vertical notch 8.
It is good to form and balance 4,14. Insulation member 7
In addition to the collared short cylinder molded product of Fig. 1, as shown in Fig. 2,
It may be an annular disc 7c having a hole 15 into which the lower end of the core 9 can be fitted. As described above, when the core 9 and the insulating member 7 are separated from each other, a fitting process is required, but when the spirally wound electrode body 2 is wound around the core 9, the winding is performed without any obstacles. You can turn it. Contrary to this, if a collar-shaped plate is integrally formed at one end of the core 9 at a right angle, even if the above-described step of fitting the core 9 and the insulating member 7 can be omitted, when the separator 5 is first fixed to the core 9. If it is not done so strictly, the wound product may gradually become closer to the flange plate side during the winding, and the winding may become impossible.
【0019】かかる不都合を回避するには、図3に示し
た他の実施形態のように、コア9の下端部に、該コア9
の軸芯に対し鈍角状をなすように鍔状板7dを一体形成
することによって、セパレータ5が鍔状板7dに当たっ
て巻回不能としないための逃げを作ることである。In order to avoid such inconvenience, as in the other embodiment shown in FIG. 3, the core 9 is provided at the lower end of the core 9.
By integrally forming the collar-shaped plate 7d so as to form an obtuse angle with respect to the axis of the separator, a clearance is provided so that the separator 5 does not hit the collar-shaped plate 7d and cannot be wound.
【0020】上記したコア9を含む渦巻状電極体2を巻
回形成する方法について述べれば、以下の二つがある。
その一つは、コア9の材質はセパレータ5と融着可能な
ものとなし、図4に示すように、長手方向全長に亘って
縦切欠部8を形成した断面C形をなす合成樹脂製又はス
テンレス鋼製のコア9を巻回機(図示せず)のキー17
付回転軸16に挿入して、コア9の縦切欠部8と巻回機
の回転軸16のキー17とを係合係止させる。そのコア
9の外表面に、負極板3または正極板4のうちいずれか
一方の電極板の両側面を被覆したセパレータ5の延出端
部を超音波融着等の接着手段によって直接固着(符号1
8は融着箇所を示す)後、約1回転させて該セパレータ
延出部を巻回してから、つぎにこれに他の電極板を添え
て一緒に巻回を開始し、巻回作業終了後は回転軸16か
らコア9を含む巻回体である渦巻状電極体2を取り外
す。この場合、回転軸16のキー17の外表面を、図6
の二点鎖線の如く、コア9外表面と略同一円上にある円
弧で構成すると、得られた渦巻状電極体2に歪んだ箇所
を生じさせない。The method of forming the spiral electrode body 2 including the core 9 by winding will be described below.
One of them is that the material of the core 9 is such that it can be fused with the separator 5, and as shown in FIG. 4, it is made of a synthetic resin having a C-shaped cross section in which a vertical notch 8 is formed over the entire length in the longitudinal direction. A key 17 of a winding machine (not shown) for the core 9 made of stainless steel.
It is inserted into the attached rotary shaft 16, and the vertical cutout portion 8 of the core 9 and the key 17 of the rotary shaft 16 of the winding machine are engaged and locked. On the outer surface of the core 9, the extended end portion of the separator 5 which covers both side surfaces of one of the negative electrode plate 3 and the positive electrode plate 4 is directly fixed by an adhesive means such as ultrasonic fusion (reference numeral). 1
8 indicates a fusion-bonded portion), and then the separator extending portion is wound about one rotation, and then another electrode plate is attached to this to start winding together, and after the winding work is completed. Removes the spiral electrode body 2 which is a wound body including the core 9 from the rotating shaft 16. In this case, the outer surface of the key 17 of the rotary shaft 16 is
As shown by the two-dot chain line, if it is constituted by an arc that is substantially on the same circle as the outer surface of the core 9, the obtained spiral electrode body 2 will not have a distorted portion.
【0021】もう一つの巻回方法は、図5に示したよう
に、コア9の長手方向全長に亘って穿設されている縦切
欠部8の幅を適当な値(一例を挙げると、巻回機の回転
軸16の径が3.4mmなら、コア9の縦切欠部8の幅は
2mm程度)とし、矢印で示したように、回転軸16の外
側からコア9を押し込んで回転軸16に抱かせる。その
際、コア9の縦切欠部8を巻回機回転軸16の例えばキ
ー17に係合係止させると同時に、上記セパレータ5の
延出端部をコア9と巻回機の回転軸16との間で挟持さ
せて固定してしまう。挟持後に巻回を開始し、巻回作業
終了後は回転軸16からコア9を含む巻回体である渦巻
状電極体2を取り外すことは、前記した挿入方式の場合
と同様である。As another winding method, as shown in FIG. 5, the width of the vertical notch 8 formed along the entire length of the core 9 in the longitudinal direction is set to an appropriate value (for example, winding). If the diameter of the rotary shaft 16 of the rotating machine is 3.4 mm, the width of the vertical cutout 8 of the core 9 is about 2 mm), and the core 9 is pushed in from the outside of the rotary shaft 16 as indicated by the arrow. Let me hold you. At this time, the vertical notch 8 of the core 9 is engaged and locked with, for example, the key 17 of the winding shaft 16 of the winding machine, and at the same time, the extended end of the separator 5 is connected to the core 9 and the rotating shaft 16 of the winding machine. It will be pinched and fixed between them. Winding is started after the pinching, and after the winding work is completed, the spiral electrode body 2, which is a wound body including the core 9, is removed from the rotary shaft 16 in the same manner as in the insertion method described above.
【0022】図3のコア9と鍔状板7dとを一体形成し
たものを、この巻回方法に使用するときには、回転軸1
6の外側からコア9を押し込め得るように、鍔状板7d
にはコア9の縦切欠部8と繋がる切欠部19を形成しな
ければならないが、図6に示したように、この切欠部1
9をハの字状とすると、回転軸16の外側からコア9を
押し込む際の拡開がし易くなる。この際、図11に示す
ように、負極リード板6に絶縁テープ22を貼設し、こ
の絶縁テープ22で絶縁部材7の切欠部19を塞ぐこと
により、電池組立後において渦巻状電極体2と負極缶1
とが接触して内部短絡を生じる事態の発生を未然に防止
できる。又、コア9のクランプ力のみでの係合係止でも
良い。更に、図12に示すように、絶縁部材7に薄肉部
20を設け、その中央に放射方向の切込み21を入れて
おけば、回転軸16の外側からコア9を押し込めること
ができると同時に、負極リード板6に絶縁テープ22を
貼設して絶縁しなくても内部短絡を防止することが可能
となる。When the core 9 shown in FIG. 3 and the collar plate 7d are integrally formed, the rotary shaft 1 is used when this winding method is used.
The collar-shaped plate 7d so that the core 9 can be pushed in from the outside of 6
It is necessary to form a cutout portion 19 connected to the vertical cutout portion 8 of the core 9 on the core 9, but as shown in FIG.
If the 9 is formed in a V shape, the core 9 can be easily expanded when it is pushed in from the outside of the rotary shaft 16. At this time, as shown in FIG. 11, an insulating tape 22 is attached to the negative electrode lead plate 6, and the notch 19 of the insulating member 7 is closed with this insulating tape 22 to form the spiral electrode body 2 after the battery is assembled. Negative electrode can 1
It is possible to prevent the occurrence of a situation in which the and are brought into contact with each other to cause an internal short circuit. Further, the engagement and locking may be performed only by the clamping force of the core 9. Further, as shown in FIG. 12, if a thin portion 20 is provided in the insulating member 7 and a radial notch 21 is formed in the center thereof, the core 9 can be pushed in from the outside of the rotary shaft 16 and, at the same time, the negative electrode It is possible to prevent an internal short circuit without attaching the insulating tape 22 to the lead plate 6 and insulating it.
【0023】なお、図7乃至図9に示すように、コア9
に複数個の貫通孔9aを形設することで、電解液注入の
際、コア9の内側から外側へ電解液が浸透しやすくし
て、電解液の注液時間を短縮することができる。また、
図10に示すように、絶縁部材7が一体形成されたコア
9に貫通孔9aを形設した場合も同様である。実際、貫
通孔9aを形設したコア9(図7に示すタイプ)と、形
設していないコア9とを作製し、電解液の浸透性を比較
したところ、前者は後者に比べて電解液の注液時間がほ
ぼ半分であった。As shown in FIGS. 7 to 9, the core 9
By forming a plurality of through-holes 9a in the core, it is possible to facilitate the permeation of the electrolytic solution from the inside to the outside of the core 9 during the injection of the electrolytic solution, and to shorten the injection time of the electrolytic solution. Also,
As shown in FIG. 10, the same applies to the case where the through hole 9a is formed in the core 9 integrally formed with the insulating member 7. Actually, when a core 9 having a through hole 9a formed therein (type shown in FIG. 7) and a core 9 having no through hole 9a were prepared and the permeability of the electrolytic solution was compared, the former showed a higher electrolytic solution than the latter. The liquid injection time was about half.
【0024】[0024]
【発明の効果】以上の説明から明らかなように、この発
明では、渦巻状電極体の中心に合成樹脂製又はステンレ
ス鋼製の断面C形のコアが配設されるから、渦巻状電極
体の負極缶内への挿入、群押えの挿入、スポット溶接用
電極棒の挿入、更には電解液注入管の挿入といった各工
程が連続するスパイラル型非水電解液電池の高速自動組
立てを行う際に、そのコアをしっかりしたセンター位置
決め基準として利用できる。コアの長手方向全長に亘っ
て形成した縦切欠部は、巻回機の回転軸と係合係止して
コアを回転させる機能の他に、後述する挟着方式の場合
に必要な拡開を可能とする。As is apparent from the above description, according to the present invention, the core of synthetic resin or stainless steel having a C-shaped cross section is disposed at the center of the spiral electrode body. When performing high-speed automatic assembly of a spiral type non-aqueous electrolyte battery in which each step such as insertion into the negative electrode can, insertion of a group presser, insertion of an electrode rod for spot welding, and insertion of an electrolyte injection pipe is performed, The core can be used as a solid centering reference. The vertical notch formed over the entire length in the longitudinal direction of the core has the function of engaging and locking the rotation shaft of the winding machine to rotate the core, and also provides the expansion required in the case of the pinching method described later. It is possible.
【0025】絶縁部材を鍔付短筒成型品とすると、その
筒部をコアの内側に嵌着することで、コアと絶縁部材と
の一体化が確実である。コアの下端外周部に嵌着させる
ことができる環状円板の場合は成型が容易である。ま
た、コアの下端部に、該コアの軸芯に対し鈍角状をなす
鍔状板を一体形成したものでは、巻回物が鍔状板に当っ
て巻回不能にさせないし、巻回体から離れた鍔状板を掴
んで巻回物を巻回機の回転軸から取外すことで巻回体端
面へストレスを与えなくするほか、組立後はスラスト方
向のガタ防止或いは緩衝バネ機能を期待することができ
る。If the insulating member is a brim-shaped short cylinder molded product, the core and the insulating member are surely integrated by fitting the cylindrical portion inside the core. Molding is easy in the case of an annular disc that can be fitted to the outer periphery of the lower end of the core. Further, in the one in which the flange-shaped plate forming an obtuse angle with the axis of the core is integrally formed at the lower end portion of the core, the wound product does not hit the flange-shaped plate so as not to be wound, and By removing the wound object from the rotary shaft of the winding machine by grasping the flange-shaped plate away from it, stress on the end face of the wound body can be eliminated, and after assembly, anti-backlash in the thrust direction or buffer spring function can be expected. You can
【0026】コアに貫通孔を形設すれば、電解液注入の
際、コアの中心部より浸入しようとする電解液が、この
貫通孔を通過して渦巻状電極体に浸透していくため、電
解液の注液時間を短縮することができる。また、反りの
程度が減少して寸法精度が向上する効果も生じ、生産性
の向上に寄与する。If the through hole is formed in the core, the electrolytic solution that is about to enter from the center of the core when the electrolytic solution is injected passes through the through hole and permeates into the spiral electrode body. The time for injecting the electrolyte solution can be shortened. In addition, the degree of warpage is reduced and the dimensional accuracy is improved, which contributes to improved productivity.
【0027】負極リード板に絶縁テープを貼設し、この
絶縁テープで絶縁部材の切欠部を塞ぐようにすれば、電
池組立後において渦巻状電極体と負極缶とが接触して内
部短絡を生じることはない。If an insulating tape is attached to the negative electrode lead plate and the notch of the insulating member is closed with this insulating tape, the spiral electrode body and the negative electrode can come into contact with each other after the battery is assembled, causing an internal short circuit. There is no such thing.
【0028】環状の絶縁部材に薄肉部を設け、この薄肉
部に放射方向の切込みを入れると、絶縁部材がコアに一
体形成されているにも拘らず、負極リード板を絶縁しな
くても内部短絡を防止することが可能となる。If a thin-walled portion is provided on the annular insulating member and a radial cut is made in this thin-walled portion, the inner portion is formed even if the negative electrode lead plate is not insulated even though the insulating member is integrally formed with the core. It is possible to prevent a short circuit.
【0029】つぎに本発明の巻回方法の効果について述
べると、コアに巻回機の回転軸を差し込む挿入方式で
は、コアの縦切欠部は巻回機の回転軸のキーと協働する
キー溝として比較的狭い幅でよいから、コアの外側に巻
回された巻回物の締付力によって受けるコアの縮径度合
いを小さくできるので、コアを組立時の基準とする場合
に甚だ好都合である。融着によるセパレータの伸縮に対
する影響や接着の信頼性の点で特に問題とはならない。Next, the effect of the winding method of the present invention will be described. In the insertion method in which the rotary shaft of the winding machine is inserted into the core, the vertical notch of the core is a key that cooperates with the key of the rotary shaft of the winding machine. Since the groove can have a relatively narrow width, it is possible to reduce the degree of diameter reduction of the core that is received by the tightening force of the winding material wound on the outside of the core, which is very convenient when using the core as a reference during assembly. is there. There is no particular problem in terms of the influence on the expansion and contraction of the separator due to fusion and the reliability of adhesion.
【0030】また、コアを巻回機の回転軸に被せる挟着
方式では、セパレータの延出端部をコアに固定するのが
至って簡便な挟着で済む利点がある。コアを拡径可能に
するため縦切欠部の幅はやや大き目になり、巻回物の締
付力によって受けるコアの縮径度合いもやや大となる
が、それがコアを組立時の基準にできなくするといった
ことはない。Further, in the sandwiching method of covering the rotating shaft of the winding machine with the core, the extension end of the separator is fixed to the core, which is advantageous in that the sandwiching can be simply carried out. The width of the vertical notch is slightly larger to allow the core to expand, and the degree of core reduction caused by the tightening force of the wound material is also somewhat large, but that can be used as a reference when assembling the core. There is nothing to lose.
【0031】いずれの巻回方式の場合も、巻回体である
渦巻状電極体はコアを介して回転軸と接触するから、巻
回作業終了後、コアを含む巻回体である渦巻状電極体を
回転軸から取除く際に、従来のように巻回体を竹の子状
に引きずり出す虞は全くない。In any of the winding methods, since the spirally wound electrode body, which is a wound body, contacts the rotating shaft through the core, the spirally wound electrode body, which is a wound body including the core, is wound after the winding work is completed. When removing the body from the rotating shaft, there is no possibility of dragging the wound body into a bamboo shape as in the conventional case.
【図1】(a)は本発明になるスパイラル型非水電解液
電池の第1の実施形態を示す断面図、(b)は(a)の
巻芯部の状態を示す拡大断面図である。1A is a sectional view showing a first embodiment of a spiral-type non-aqueous electrolyte battery according to the present invention, and FIG. 1B is an enlarged sectional view showing a state of a winding core portion of FIG. 1A. .
【図2】第2の実施形態の要部を示す断面図である。FIG. 2 is a sectional view showing a main part of a second embodiment.
【図3】第3の実施形態の要部を示す断面図である。FIG. 3 is a sectional view showing a main part of a third embodiment.
【図4】本発明になる渦巻状電極体の巻回方法を説明す
る斜視図である。FIG. 4 is a perspective view illustrating a winding method of the spiral electrode body according to the present invention.
【図5】本発明になる渦巻状電極体の別の巻回方法を説
明する斜視図である。FIG. 5 is a perspective view illustrating another winding method of the spiral electrode body according to the present invention.
【図6】鍔状板を設けたコアの断面図である。FIG. 6 is a cross-sectional view of a core provided with a collar plate.
【図7】貫通孔を形設したコアの一例を示す斜視図であ
る。FIG. 7 is a perspective view showing an example of a core having through holes formed therein.
【図8】貫通孔を形設したコアの別の例を示す斜視図で
ある。FIG. 8 is a perspective view showing another example of a core having a through hole formed therein.
【図9】貫通孔を形設したコアの更に別の例を示す斜視
図である。FIG. 9 is a perspective view showing still another example of a core having a through hole formed therein.
【図10】貫通孔を形設したコアの更に別の例を示す斜
視図である。FIG. 10 is a perspective view showing still another example of a core having a through hole formed therein.
【図11】コアに配設された渦巻状電極体を示す斜視図
である。FIG. 11 is a perspective view showing a spiral electrode body arranged on a core.
【図12】絶縁部材に薄肉部を設けたコアの一例を示す
斜視図である。FIG. 12 is a perspective view showing an example of a core in which a thin portion is provided on an insulating member.
1…負極缶、2…渦巻状電極体、3…負極板、4…正極
板、5…セパレータ、6…負極リード板、7…絶縁部
材、7a…環状円板部、7b…筒部、7c…環状円板、
7d…鍔状板、8…縦切欠部、9…コア、9a…貫通
孔、10…正極リード板、11…正極端子、12…群押
え、13…群固定テープ、14…肉盛り部、15…孔、
16…回転軸、17…キー、18…融着箇所、19…切
欠部、20…薄肉部、21…切込み、22…絶縁テープDESCRIPTION OF SYMBOLS 1 ... Negative electrode can, 2 ... Spiral electrode body, 3 ... Negative electrode plate, 4 ... Positive electrode plate, 5 ... Separator, 6 ... Negative electrode lead plate, 7 ... Insulating member, 7a ... Annular disk part, 7b ... Cylindrical part, 7c ... annular disc,
Reference numeral 7d ... Collar plate, 8 ... Vertical notch, 9 ... Core, 9a ... Through hole, 10 ... Positive lead plate, 11 ... Positive terminal, 12 ... Group retainer, 13 ... Group fixing tape, 14 ... Padding section, 15 ... holes,
16 ... Rotating shaft, 17 ... Key, 18 ... Fusion-bonded part, 19 ... Notch part, 20 ... Thin part, 21 ... Notch, 22 ... Insulating tape
フロントページの続き (72)発明者 村田 知也 東京都港区新橋5丁目36番11号 富士電気 化学株式会社内 (72)発明者 福原 敬司 東京都港区新橋5丁目36番11号 富士電気 化学株式会社内 (72)発明者 加藤 益生 東京都港区新橋5丁目36番11号 富士電気 化学株式会社内 (72)発明者 北方 雅一 東京都港区新橋5丁目36番11号 富士電気 化学株式会社内Front page continuation (72) Inventor Tomoya Murata 5-36-11 Shimbashi, Minato-ku, Tokyo Fuji Electric Chemical Co., Ltd. (72) Keiji Fukuhara 5-36-11 Shimbashi, Minato-ku, Tokyo Fuji Electric Chemical Co., Ltd. In-company (72) Inventor Massei Kato 5-36-1 Shimbashi, Minato-ku, Tokyo Fuji Electric Chemical Co., Ltd. (72) Inventor Masakazu Kitakata 5-36-11 Shinbashi, Minato-ku, Tokyo Fuji Electric Chemical Co., Ltd. Within
Claims (9)
に収納され、長手方向全長に亘って縦切欠部(8)を形
成した断面C形をなす合成樹脂製又はステンレス鋼製の
コア(9)を巻芯として負極板(3)と正極板(4)と
がセパレータ(5)を介して積層状に巻回されてなる渦
巻状電極体(2)と、その負極缶の内底面と渦巻状電極
体の底面との間に配設された絶縁部材(7)とからなる
ことを特徴とするスパイラル型非水電解液電池。1. A negative electrode can (1) made of metal, and a synthetic resin or stainless steel having a C-shaped cross section, which is housed in the negative electrode can and has a vertical notch (8) formed along the entire length in the longitudinal direction. Of the spirally wound electrode body (2) in which the negative electrode plate (3) and the positive electrode plate (4) are wound in a laminated manner with the core (9) of FIG. A spiral type non-aqueous electrolyte battery comprising an insulating member (7) disposed between the inner bottom surface and the bottom surface of the spiral electrode body.
したことを特徴とする請求項1記載のスパイラル型非水
電解液電池。2. The spiral type non-aqueous electrolyte battery according to claim 1, wherein a through hole (9a) is formed in the core (9).
a)の片側に上記コア(9)の内側に嵌着することがで
きる筒部(7b)を一体的に形成した鍔付短筒成型品で
あることを特徴とする請求項1又は請求項2記載のスパ
イラル型非水電解液電池。3. The insulating member (7) comprises an annular disc portion (7).
3. A flanged short cylinder molded product integrally formed with a cylinder part (7b) which can be fitted inside the core (9) on one side of a). The spiral type non-aqueous electrolyte battery described.
の下端外周部に嵌着させることができる環状円板(7
c)であることを特徴とする請求項1又は請求項2記載
のスパイラル型非水電解液電池。4. The insulating member (7) comprises the core (9).
An annular disc (7) that can be fitted to the outer periphery of the lower end of the
The spiral non-aqueous electrolyte battery according to claim 1 or 2, which is c).
の下端部に、該コアの軸芯に対し鈍角状をなすように一
体形成された鍔状板(7d)であることを特徴とする請
求項1又は請求項2記載のスパイラル型非水電解液電
池。5. The insulating member (7) comprises the core (9).
The spiral non-aqueous electrolyte according to claim 1 or 2, characterized in that it is a flange-shaped plate (7d) integrally formed at the lower end of the core so as to form an obtuse angle with the axis of the core. battery.
に収納され、長手方向全長に亘って縦切欠部(8)を形
成した断面C形をなす合成樹脂製又はステンレス鋼製の
コア(9)を巻芯として負極板(3)と正極板(4)と
がセパレータ(5)を介して積層状に巻回されてなる渦
巻状電極体(2)と、その負極缶の内底面と渦巻状電極
体の底面との間に配設され、切欠部(19)を有する環
状の絶縁部材(7)とからなるスパイラル型非水電解液
電池であって、 上記渦巻状電極体の負極板に接続された負極リード板
(6)に絶縁テープ(22)を貼設し、この絶縁テープ
で上記絶縁部材の切欠部を塞ぐようにしたことを特徴と
するスパイラル型非水電解液電池。6. A negative electrode can (1) made of metal, and made of synthetic resin or stainless steel having a C-shaped cross section, which is housed in the negative electrode can and has a vertical notch (8) formed along the entire length in the longitudinal direction. Of the spirally wound electrode body (2) in which the negative electrode plate (3) and the positive electrode plate (4) are wound in a laminated manner with the core (9) of FIG. A spiral type non-aqueous electrolyte battery, which is arranged between an inner bottom surface and a bottom surface of a spiral electrode body and comprises an annular insulating member (7) having a notch (19), wherein the spiral electrode body Insulating tape (22) is attached to the negative electrode lead plate (6) connected to the negative electrode plate of (1), and the notch of the insulating member is closed with this insulating tape. battery.
に収納され、長手方向全長に亘って縦切欠部(8)を形
成した断面C形をなす合成樹脂製又はステンレス鋼製の
コア(9)を巻芯として負極板(3)と正極板(4)と
がセパレータ(5)を介して積層状に巻回されてなる渦
巻状電極体(2)と、その負極缶の内底面と渦巻状電極
体の底面との間に配設され、上記コアに一体形成された
環状の絶縁部材(7)とからなるスパイラル型非水電解
液電池であって、 上記絶縁部材に、上記コアの縦切欠部と繋がる薄肉部
(20)を設け、この薄肉部に放射方向の切込み(2
1)を入れたことを特徴とするスパイラル型非水電解液
電池。7. A negative electrode can (1) made of metal and a synthetic resin or stainless steel having a C-shaped cross section, which is housed in the negative electrode can and has a vertical cutout (8) formed along the entire length in the longitudinal direction. Of the spirally wound electrode body (2) in which the negative electrode plate (3) and the positive electrode plate (4) are wound in a laminated manner with the core (9) of FIG. A spiral non-aqueous electrolyte battery comprising an annular insulating member (7) disposed between an inner bottom surface and a bottom surface of a spiral electrode body and integrally formed with the core, wherein: A thin portion (20) connected to the vertical cutout portion of the core is provided, and a radial notch (2) is formed in this thin portion.
A spiral type non-aqueous electrolyte battery containing 1).
形成した断面C形をなす合成樹脂製又はステンレス鋼製
のコア(9)を巻回機のキー(17)付回転軸(16)
に挿入し、このコアの縦切欠部と巻回機の回転軸のキー
とを係合係止させ、このコアの外表面に負極板(3)ま
たは正極板(4)のうちいずれか一方の電極板の両側面
を被覆したセパレータ(5)の延出端部を固着後、該セ
パレータ延出部を巻回してから、つぎに他の電極板を添
えて一緒に巻回し、巻回作業終了後は該回転軸からコア
を含む巻回体を取り外すことを特徴とするスパイラル型
電極体の巻回方法。8. A rotary shaft with a key (17) of a winding machine, which comprises a core (9) made of synthetic resin or stainless steel and having a C-shaped cross section in which a vertical notch (8) is formed over the entire length in the longitudinal direction. 16)
The core of the winding shaft and the key of the rotary shaft of the winding machine are engaged with each other, and the outer surface of the core is provided with either the negative electrode plate (3) or the positive electrode plate (4). After fixing the extending end of the separator (5) covering both side surfaces of the electrode plate, winding the separator extending part, and then winding the electrode plate together with another electrode plate, and ending the winding operation. After that, the spirally wound electrode body is wound by removing the wound body including the core from the rotary shaft.
形成した断面C形をなす合成樹脂製又はステンレス鋼製
のコア(9)を巻回機のキー(17)付回転軸(16)
の外側から押し込んで嵌め合わせ、このコアの縦切欠部
と巻回機の回転軸のキーとを係合係止させると共に、負
極板(3)または正極板(4)のうちいずれか一方の電
極板の両側面を被覆したセパレータ(5)の延出端部を
該コアと該回転軸の間で挟持後、上記セパレータ延出部
を巻回してから、つぎに他の電極板を添えて一緒に巻回
し、巻回作業終了後は該回転軸からコアを含む巻回体を
取り外すことを特徴とするスパイラル型電極体の巻回方
法。9. A rotary shaft with a key (17) of a winding machine, which comprises a core (9) made of synthetic resin or stainless steel and having a C-shaped cross section in which a vertical notch (8) is formed over the entire length in the longitudinal direction. 16)
Of the negative electrode plate (3) or the positive electrode plate (4) while the vertical cutout portion of the core and the key of the rotating shaft of the winding machine are engaged and locked by pushing from the outside of the After sandwiching the extending end portion of the separator (5) covering both side surfaces of the plate between the core and the rotating shaft, the separator extending portion is wound, and then another electrode plate is attached together. A spiral-type electrode body winding method comprising: winding a spirally wound electrode body, and removing a winding body including a core from the rotating shaft after the winding work is completed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20414195A JPH08329958A (en) | 1994-08-23 | 1995-08-10 | Spiral type non-aqueous electrolyte battery and method for winding spiral electrode body |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19831194 | 1994-08-23 | ||
JP7117095 | 1995-03-29 | ||
JP6-198311 | 1995-03-29 | ||
JP7-71170 | 1995-03-29 | ||
JP20414195A JPH08329958A (en) | 1994-08-23 | 1995-08-10 | Spiral type non-aqueous electrolyte battery and method for winding spiral electrode body |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH08329958A true JPH08329958A (en) | 1996-12-13 |
Family
ID=27300573
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP20414195A Pending JPH08329958A (en) | 1994-08-23 | 1995-08-10 | Spiral type non-aqueous electrolyte battery and method for winding spiral electrode body |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH08329958A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0867960A1 (en) * | 1997-03-24 | 1998-09-30 | Alcatel | Electrochemical generator with improved safety |
FR2761814A1 (en) * | 1997-03-24 | 1998-10-09 | Alsthom Cge Alcatel | Sealed battery with wound electrochemical assembly |
WO2001024206A1 (en) * | 1999-09-30 | 2001-04-05 | Asahi Glass Company, Limited | Capacitor element |
KR100502314B1 (en) * | 1998-03-30 | 2005-09-26 | 삼성에스디아이 주식회사 | battery |
JP2006310286A (en) * | 2005-04-25 | 2006-11-09 | Samsung Sdi Co Ltd | Cylindrical lithium secondary battery |
US7598001B2 (en) | 2004-06-04 | 2009-10-06 | Sanoh Industrial Co., Ltd. | Alkaline battery, current collector, electrode, and method of manufacturing electrode |
WO2011001617A1 (en) * | 2009-06-30 | 2011-01-06 | パナソニック株式会社 | Winding electrode group and battery |
WO2013163189A1 (en) * | 2012-04-26 | 2013-10-31 | Medtronic, Inc. | Electrode assemblies including insulative portions |
US8778521B2 (en) | 2012-04-26 | 2014-07-15 | Medtronic, Inc. | Mandrel for electrode assemblies |
US9130223B2 (en) | 2012-04-26 | 2015-09-08 | Medtronic, Inc. | Mandrel for electrode assemblies |
-
1995
- 1995-08-10 JP JP20414195A patent/JPH08329958A/en active Pending
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2761814A1 (en) * | 1997-03-24 | 1998-10-09 | Alsthom Cge Alcatel | Sealed battery with wound electrochemical assembly |
FR2761815A1 (en) * | 1997-03-24 | 1998-10-09 | Alsthom Cge Alcatel | ELECTROCHEMICAL GENERATOR WITH SPIRAL ELECTRODES WITH IMPROVED SAFETY IN THE EVENT OF GASEOUS RELEASE |
EP0867960A1 (en) * | 1997-03-24 | 1998-09-30 | Alcatel | Electrochemical generator with improved safety |
KR100502314B1 (en) * | 1998-03-30 | 2005-09-26 | 삼성에스디아이 주식회사 | battery |
JP4681181B2 (en) * | 1999-09-30 | 2011-05-11 | 旭硝子株式会社 | Electricity storage element |
WO2001024206A1 (en) * | 1999-09-30 | 2001-04-05 | Asahi Glass Company, Limited | Capacitor element |
US6896993B2 (en) | 1999-09-30 | 2005-05-24 | Asahi Glass Company, Limited | Electrochemical device comprising a pair of electrodes and an electrolyte |
US7598001B2 (en) | 2004-06-04 | 2009-10-06 | Sanoh Industrial Co., Ltd. | Alkaline battery, current collector, electrode, and method of manufacturing electrode |
JP2006310286A (en) * | 2005-04-25 | 2006-11-09 | Samsung Sdi Co Ltd | Cylindrical lithium secondary battery |
WO2011001617A1 (en) * | 2009-06-30 | 2011-01-06 | パナソニック株式会社 | Winding electrode group and battery |
WO2013163189A1 (en) * | 2012-04-26 | 2013-10-31 | Medtronic, Inc. | Electrode assemblies including insulative portions |
US8778521B2 (en) | 2012-04-26 | 2014-07-15 | Medtronic, Inc. | Mandrel for electrode assemblies |
US9130223B2 (en) | 2012-04-26 | 2015-09-08 | Medtronic, Inc. | Mandrel for electrode assemblies |
US9356264B2 (en) | 2012-04-26 | 2016-05-31 | Medtronic, Inc. | Electrode assemblies including a mandrel and at least one insulative portion |
US9843067B2 (en) | 2012-04-26 | 2017-12-12 | Medtronic, Inc. | Methods for electrode assemblies including at least one insulative portion |
US9954245B2 (en) | 2012-04-26 | 2018-04-24 | Medtronic, Inc. | Mandrel for electrode assemblies |
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