JPH0726150B2 - Manufacturing method of tempered high-strength steel sheet with excellent weldability and brittle fracture propagation stopping properties - Google Patents
Manufacturing method of tempered high-strength steel sheet with excellent weldability and brittle fracture propagation stopping propertiesInfo
- Publication number
- JPH0726150B2 JPH0726150B2 JP1210431A JP21043189A JPH0726150B2 JP H0726150 B2 JPH0726150 B2 JP H0726150B2 JP 1210431 A JP1210431 A JP 1210431A JP 21043189 A JP21043189 A JP 21043189A JP H0726150 B2 JPH0726150 B2 JP H0726150B2
- Authority
- JP
- Japan
- Prior art keywords
- temperature
- brittle fracture
- fracture propagation
- steel sheet
- propagation stopping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Heat Treatment Of Steel (AREA)
Description
【発明の詳細な説明】 [産業上の利用分野] 本発明は溶接性・脆性破壊伝播停止特性の優れた調質高
張力鋼板の製造方法に関し、さらに詳しくは、タンク、
橋梁、ペンストック等に使用される引張強さ60kgf/mm2
以上の溶接性・脆性破壊伝播停止特性の優れた調質高張
力鋼板の製造方法に関するものである。TECHNICAL FIELD The present invention relates to a method for producing a tempered high-strength steel sheet having excellent weldability and brittle fracture propagation stopping characteristics, and more specifically, a tank,
Tensile strength 60kgf / mm 2 used for bridges, penstocks, etc.
The present invention relates to a method for producing a heat-treated high-strength steel sheet having excellent weldability and brittle fracture propagation stopping characteristics.
[従来技術] 従来より、タンク、橋梁、ペンストック等には引張強さ
60〜80kgf/mm2クラスの調質高張力鋼板が使用されてき
ている。[Prior art] Conventionally, tensile strength has been applied to tanks, bridges, penstocks, etc.
60~80kgf / mm 2 class of tempered high tensile steel plates have been used.
これらの鋼板は、高い強度を確保するために、Mn、Ni、
Cr、Mo等の合金元素を多く含有さているため、また、溶
接低温割れを防止するためには、100℃程度の温度の予
熱を必要とし、溶接性は充分ではなかった。These steel sheets have Mn, Ni, and
Since it contains a large amount of alloying elements such as Cr and Mo, and in order to prevent welding cold cracking, preheating at a temperature of about 100 ° C was required, and weldability was not sufficient.
従って、耐溶接割れ性に最も悪影響をおよぼすC含有量
を従来鋼より大幅に低くし、このC含有量低減による強
度低下を微量のBの焼入れ性向上効果を活用することに
よって補なった溶接性の優れた調質高張力鋼板が開発さ
れ、既に広範囲に使用されている。Therefore, the C content, which has the most adverse effect on the weld crack resistance, is significantly lower than that of the conventional steel, and the strength decrease due to the reduction of the C content is compensated by utilizing the effect of improving the hardenability of a small amount of B. An excellent tempered high-strength steel sheet has been developed and is already in wide use.
しかしながら、調質高張力鋼板においてC含有量を低減
すると、原因は未だ充分に明確ではないが、脆性破壊伝
播停止特性がC含有量の多い従来鋼に比べて良好でない
という問題がある。However, when the C content is reduced in the heat-treated high-strength steel sheet, the cause is not yet clear, but there is a problem that the brittle fracture propagation stopping property is not good as compared with the conventional steel having a large C content.
この脆性破壊伝播停止特性を改善するためには、靭性を
顕著に改善するNiを含有させることが有効ではあるが、
Pcm=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15
+V/10+5Bの増大により溶接性が劣化すると共に、さら
に、コストアップになるという問題があり、好ましくな
い。In order to improve this brittle fracture propagation stopping property, it is effective to contain Ni that significantly improves toughness,
Pcm = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15
There is a problem that weldability deteriorates due to an increase of + V / 10 + 5B and further increases in cost, which is not preferable.
この従来の技術的問題から、鋼の含有成分および成分割
合の調整ではなく、製造条件を適正化することにより、
脆性破壊伝播停止特性を改善するための技術が開発され
た(特公昭62−001456号公報および特公昭63−058906号
公報参照)。From this conventional technical problem, by adjusting the manufacturing conditions rather than adjusting the contained components and component ratios of steel,
Techniques for improving the brittle fracture propagation stopping property have been developed (see Japanese Patent Publication Nos. 62-001456 and 63-058906).
しかして、特公昭63−058906号公報の発明は、制御圧延
後の直接焼入れにより、組織をフェライトと微細な分散
マルテンサイトの混合組織とすることによって、フェラ
イトの高い塑性変形能と、混合組織の高い加工硬化性能
を利用することにより、破壊を停止させるという技術で
あるが、この技術はフェライトを生成させるので60kgf/
mm2以上の強度を確保することが困難であるという問題
がある。Thus, the invention of Japanese Patent Publication No. 63-058906 discloses that the structure is a mixed structure of ferrite and fine dispersed martensite by direct quenching after controlled rolling, whereby a high plastic deformability of ferrite and a mixed structure of ferrite are obtained. It is a technology that stops fracture by utilizing high work hardening performance, but since this technology produces ferrite, 60 kgf /
There is a problem that it is difficult to secure a strength of mm 2 or more.
また、特公昭63−058906号公報の発明は、制御圧延後の
直接焼入れにより、表層部組織の伸長したマルテンサイ
ト組織とすることによって、板厚方向各位置における良
好な靭性を確保し、脆性破壊伝播停止特性を改善すると
いう技術であるが、この技術は制御圧延の厳密な制御が
不可決であり、低温における圧下が過大であると板厚中
心部が焼入れ不足になり、上部ベイナイトの生成により
靭性が劣化し、逆に低温における圧下が過小であると表
層部が伸長した組織とならず、表層部の靭性が劣化する
という問題があった。Further, the invention of Japanese Patent Publication No. 63-058906 discloses that by direct quenching after controlled rolling, a martensite structure in which the surface layer structure is elongated is obtained, thereby ensuring good toughness at each position in the plate thickness direction and brittle fracture. This is a technique to improve the propagation stop property, but this technique cannot control the strict control of controlled rolling.If the reduction is excessive at low temperature, the central part of the plate thickness will be insufficiently quenched and the upper bainite will be generated. The toughness deteriorates. On the contrary, if the reduction at low temperature is too small, the surface layer portion does not have an elongated structure, and the toughness of the surface layer portion deteriorates.
[発明が解決しようとする課題] 本発明は上記に説明した従来の溶接性および脆性破壊伝
播停止特性を改善した鋼の製造法における種々の問題点
に鑑みなされたもので、即ち、本発明者は低C系鋼の引
張強さ60〜80kgf/mm2クラスの調質高張力鋼板の脆性破
壊伝播停止特性を改善するために、鋭意研究を行い、検
討を重ねた結果、脆性破壊伝播停止特性が劣化する原因
として、低C含有量であるためオーステナイト粒が粗大
となり、焼入れ時の冷却速度が速い表層部は粗粒マルテ
ンサイト組織となって、靭性が劣化することを知見し
た。[Problems to be Solved by the Invention] The present invention has been made in view of various problems in the above-described conventional method for producing a steel having improved weldability and brittle fracture propagation stopping characteristics, that is, the present inventor. Is a brittle fracture propagation arresting property after conducting extensive research and improvement in order to improve the brittle fracture propagation arresting property of the tempered high-strength steel sheet with a tensile strength of 60 to 80 kgf / mm 2 class of low C steel. It was found that as a cause of deterioration, the austenite grains become coarse due to the low C content, and the surface layer portion having a high cooling rate during quenching becomes a coarse grain martensite structure and the toughness deteriorates.
従って、本発明者は低C系鋼の含有成分および成分割合
で、表層部が靭性の良好な細粒のマルテンサイト+下部
ベイナイトの混合組織とするための技術を検討した結
果、熱処理方法を従来の再加熱焼入れ・焼戻しを行なう
ことから、熱間圧延後の直接焼入れ・焼戻しを行ない、
その前段階である加熱・圧延条件の適切な制御を行なう
ことが有効であることを見出し、そして、その適切な条
件を定量化することにより溶接性・脆性破壊伝播停止特
性の優れた調質高張力鋼板の製造方法を開発したのであ
る。Therefore, the present inventor has studied a technique for forming a mixed structure of fine grain martensite + lower bainite having a good toughness in the surface layer with the components and the component ratio of the low C steel, and as a result, the heat treatment method has been conventionally used. Since reheating quenching and tempering are performed, direct quenching and tempering after hot rolling are performed.
We have found that it is effective to perform appropriate control of heating / rolling conditions, which is the previous stage, and by quantifying the appropriate conditions, we can improve the weldability and brittle fracture propagation stop properties with excellent heat treatment. We have developed a method for manufacturing tensile steel sheets.
[課題を解決するための手段] 本発明に係る溶接性・脆性破壊伝播停止特性の優れた調
質高張力鋼板の製造方法は、 (1)C 0.04〜1.10wt%、Si 0.01〜0.50wt%、Mn 0.4
〜1.5wt%、 Cr 0.05〜1.0wt%、Mo 0.05〜1.0wt%、V 0.01〜0.1wt
%、 B 0.0005〜0.005wt%、Al 0.01〜0.1wt%を含有し、か
つ、 Pcm=C+Si/30+Mn/20+Cu/20+Ni/60 +Cr/20+Mo/15+V/10+5B≦0.22wt% を満足し、残部Feおよび不可避不純物からなる鋼を、加
熱温度≦1250℃、全圧下率≧75%、さらに、仕上温度T
F(℃)が下記式 0.063(0.333TF+70.4C−300)2 +0.10TF−151C−229≦−130 (1) (Cはwt%の炭素量) を満足する条件で熱間圧延を終了した後、オーステナイ
ト域の温度から直接焼入れを行い、その後、Ac1点未満
の温度で焼戻しを行うことを特徴とする溶接性・脆性破
壊伝播停止特性の優れた調質高張力鋼板の製造方法を第
1の発明とし、 (2)C 0.04〜1.10wt%、Si 0.01〜0.50wt%、Mn 0.4
〜1.5wt%、 Cr 0.05〜1.0wt%、Mo 0.05〜1.0wt%、V 0.01〜0.1wt
%、 B 0.0005〜0.005wt%、Al 0.01〜0.1wt%、Nb 0.005〜
0.1wt% を含有し、かつ、 Pcm=C+Si/30+Mn/20+Cu/20+Ni/60 +Cr/20+Mo/15+V/10+5B≦0.22wt% を満足し、残部Feおよび不可避不純物からなる鋼を、12
50℃以下の温度で、かつ、Nbの炭窒化物が完全に固溶す
る温度の加熱温度、全圧下率≧75%、さらに、仕上温度
TF(℃)が下記式 0.063(0.333TF+70.4C−300)2 +0.067TF−151C−203≦−130 (2) (Cはwt%の炭素量) を満足する条件で熱間圧延を終了した後、オーステナイ
ト域の温度から直接焼入れを行い、その後、Ac1点未満
の温度で焼戻しを行うことを特徴とする溶接性・脆性破
壊伝播停止特性の優れた調質高張力鋼板の製造方法を第
2の発明とし、 (3)C 0.04〜1.10wt%、Si 0.01〜0.50wt%、Mn 0.4
〜1.5wt%、 Cr 0.05〜1.0wt%、Mo 0.05〜1.0wt%、V 0.01〜0.1wt
%、 B 0.0005〜0.005wt%、Al 0.01〜0.1wt% を含有し、さらに、 Cu 0.05〜0.50wt%、Ni 0.05〜1.5wt%、Ti 0.005〜0.0
3wt%、 Ca 0.001〜0.005wt% の内から選んだ1種または2種以上 を含有し、かつ、 Pcm=C+Si/30+Mn/20+Cu/20+Ni/60 +Cr/20+Mo/15+V/10+5B≦0.22wt% を満足し、残部Feおよび不可避不純物からなる鋼を、加
熱温度≦1250℃、全圧下率≧75%、さらに、仕上温度T
F(℃)が下記式 0.063(0.333TF+70.4C−300)2 +0.10TF−151C−229≦−130 (1) (Cはwt%の炭素量) を満足する条件で熱間圧延を終了した後、オーステナイ
ト域の温度から直接焼入れを行い、その後、Ac1点未満
の温度で焼戻しを行うことを特徴とする溶接性・脆性破
壊伝播停止特性の優れた調質高張力鋼板の製造方法を第
3の発明とし、 (4)C 0.04〜1.10wt%、Si 0.01〜0.50wt%、Mn 0.4
〜1.5wt%、 Cr 0.05〜1.0wt%、Mo 0.05〜1.0wt%、V 0.01〜0.1wt
%、 B 0.0005〜0.005wt%、Al 0.01〜0.1wt%、Nb 0.005〜
0.1wt% を含有し、さらに、 Cu 0.05〜0.50wt%、Ni 0.05〜1.5wt%、Ti 0.005〜0.0
3wt%、 Ca 0.001〜0.005wt% の内から選んだ1種または2種以上 を含有し、かつ、 Pcm=C+Si/30+Mn/20+Cu/20+Ni/60 +Cr/20+Mo/15+V/10+5B≦0.22wt% を満足し、残部Feおよび不可避不純物からなる鋼を、12
50℃以下の温度で、かつ、Nbの炭窒化物が完全に固溶す
る温度の加熱温度、全圧下率≧75%、さらに、仕上温度
TF(℃)が下記式 0.063(0.333TF+70.4C−300)2 +0.067TF−151C−203≦−130 (2) (Cはwt%の炭素量) を満足する条件で熱間圧延を終了した後、オーステナイ
ト域の温度から直接焼入れを行い、その後、Ac1点未満
の温度で焼戻しを行うことを特徴とする溶接性・脆性破
壊伝播停止特性の優れた調質高張力鋼板の製造方法を第
4の発明とする4つの発明よりなるものである。[Means for Solving the Problems] The method for producing a tempered high-strength steel sheet having excellent weldability and brittle fracture propagation stopping characteristics according to the present invention is (1) C 0.04 to 1.10 wt%, Si 0.01 to 0.50 wt% , Mn 0.4
~ 1.5wt%, Cr 0.05 ~ 1.0wt%, Mo 0.05 ~ 1.0wt%, V 0.01 ~ 0.1wt
%, B 0.0005 to 0.005 wt%, Al 0.01 to 0.1 wt%, and Pcm = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B ≦ 0.22wt%, and the balance Fe and Steel consisting of unavoidable impurities, heating temperature ≤ 1250 ℃, total rolling reduction ≥ 75%, and finishing temperature T
Hot rolling was completed under the condition that F (° C) satisfies the following formula 0.063 (0.333TF + 70.4C-300) 2 + 0.10TF-151C-229 ≦ -130 (1) (C is the carbon amount in wt%) After that, direct quenching is performed from the temperature of the austenite region, and then tempering is performed at a temperature of less than the Ac 1 point. (2) C 0.04 to 1.10 wt%, Si 0.01 to 0.50 wt%, Mn 0.4
~ 1.5wt%, Cr 0.05 ~ 1.0wt%, Mo 0.05 ~ 1.0wt%, V 0.01 ~ 0.1wt
%, B 0.0005 to 0.005 wt%, Al 0.01 to 0.1 wt%, Nb 0.005 to
A steel containing 0.1 wt% and satisfying Pcm = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B ≦ 0.22wt% with the balance Fe and unavoidable impurities
Heating temperature at a temperature of 50 ° C or less and at a temperature at which Nb carbonitride is completely dissolved, total rolling reduction ≧ 75%, and finishing temperature TF (° C) is 0.063 (0.333TF + 70.4C- 300) 2 + 0.067TF-151C-203 ≤-130 (2) (C is the carbon content of wt%) After the hot rolling is finished, quenching is performed directly from the temperature in the austenite region, and then, The second invention is a method for producing a tempered high-strength steel sheet having excellent weldability and brittle fracture propagation stopping characteristics, which is characterized by performing tempering at a temperature below the Ac 1 point, and (3) C 0.04 to 1.10 wt% , Si 0.01 to 0.50 wt%, Mn 0.4
~ 1.5wt%, Cr 0.05 ~ 1.0wt%, Mo 0.05 ~ 1.0wt%, V 0.01 ~ 0.1wt
%, B 0.0005 to 0.005 wt%, Al 0.01 to 0.1 wt%, Cu 0.05 to 0.50 wt%, Ni 0.05 to 1.5 wt%, Ti 0.005 to 0.0
Contains 1 or 2 or more selected from 3 wt% and Ca 0.001 to 0.005 wt%, and satisfies Pcm = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B ≦ 0.22wt% Then, the steel consisting of the balance Fe and unavoidable impurities is heated at a temperature of ≤1250 ° C, a total reduction of ≥75%, and a finishing temperature T
Hot rolling was completed under the condition that F (° C) satisfies the following formula 0.063 (0.333TF + 70.4C-300) 2 + 0.10TF-151C-229 ≦ -130 (1) (C is the carbon amount in wt%) After that, direct quenching is performed from the temperature of the austenite region, and then tempering is performed at a temperature of less than the Ac 1 point. (4) C 0.04 to 1.10 wt%, Si 0.01 to 0.50 wt%, Mn 0.4
~ 1.5wt%, Cr 0.05 ~ 1.0wt%, Mo 0.05 ~ 1.0wt%, V 0.01 ~ 0.1wt
%, B 0.0005 to 0.005 wt%, Al 0.01 to 0.1 wt%, Nb 0.005 to
0.1 wt%, Cu 0.05 to 0.50 wt%, Ni 0.05 to 1.5 wt%, Ti 0.005 to 0.0
Contains 1 or 2 or more selected from 3 wt% and Ca 0.001 to 0.005 wt%, and satisfies Pcm = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B ≦ 0.22wt% Steel containing the balance Fe and unavoidable impurities
Heating temperature at a temperature of 50 ° C or less and at a temperature at which Nb carbonitride is completely dissolved, total rolling reduction ≧ 75%, and finishing temperature TF (° C) is 0.063 (0.333TF + 70.4C- 300) 2 + 0.067TF-151C-203 ≤-130 (2) (C is the carbon content of wt%) After the hot rolling is finished, quenching is performed directly from the temperature in the austenite region, and then, A fourth aspect of the present invention is a method for producing a tempered high-strength steel sheet having excellent weldability and brittle fracture propagation stopping characteristics, which is characterized by performing tempering at a temperature of less than Ac 1 point.
本発明に係る溶接性・脆性破壊伝播停止特性の優れた調
質高張力鋼板の製造方法について、以下詳細に説明す
る。The method for producing a tempered high-strength steel sheet having excellent weldability and brittle fracture propagation stopping properties according to the present invention will be described in detail below.
先ず、本発明に係る溶接性・脆性破壊伝播停止特性の優
れた調質高張力鋼板の製造方法において使用する鋼の含
有成分および成分割合について説明する。First, the contained components and component ratios of steel used in the method for producing a tempered high-strength steel sheet having excellent weldability and brittle fracture propagation stopping properties according to the present invention will be described.
Cは高張力鋼板としての強度を確保するために必要な元
素であり、含有量が0.04wt%未満では引張強さ60kgf/mm
2以上を確保することは困難であり、また、0.10wt%を
越えて含有させると耐溶接割れ性を害するようになる。
よって、C含有量は0.04〜0.10wt%とする。C is an element necessary to secure the strength as a high-strength steel plate. If the content is less than 0.04 wt%, the tensile strength is 60 kgf / mm.
It is difficult to secure 2 or more, and if it exceeds 0.10 wt%, the weld crack resistance will be impaired.
Therefore, the C content is 0.04 to 0.10 wt%.
Siは脱酸に有効な元素であり、含有量が0.01wt%未満で
はこの効果は少なく、また、0.50wt%を越えて過剰に含
有させると溶接性および靭性を劣化させる。よって、Si
含有量は0.01〜0.50wt%とする。Si is an element effective for deoxidation, and if the content is less than 0.01 wt%, this effect is small, and if it exceeds 0.50 wt% excessively, weldability and toughness are deteriorated. Therefore, Si
The content is 0.01 to 0.50 wt%.
Mnは焼入れ性を向上させ、板厚内部の強度を確保するた
めに必要な元素であり、含有量が0.4wt%未満ではこの
ような効果が充分に確保できず、また、1.5wt%を越え
て過剰に含有させると溶接性および靭性を劣化させる。
よつて、Mn含有量は0.4〜1.5wt%とする。Mn is an element necessary for improving the hardenability and ensuring the strength inside the plate thickness. If the content is less than 0.4 wt%, such effects cannot be sufficiently secured, and if it exceeds 1.5 wt%. If it is contained excessively, the weldability and toughness deteriorate.
Therefore, the Mn content is 0.4 to 1.5 wt%.
Crは焼入れ性を向上させるのに有効な元素であり、含有
量が0.05wt%未満ではこの効果は充分に発揮することは
できず、また、1.0wt%を越えて過多に含有させると溶
接性を害するようになる。よって、Cr含有量は0.05〜1.
0wt%とする。Cr is an element effective in improving the hardenability, and if the content is less than 0.05 wt%, this effect cannot be fully exerted, and if it exceeds 1.0 wt%, the weldability is increased. Will hurt you. Therefore, the Cr content is 0.05 to 1.
0 wt%
Moは焼入れ性を高くし、焼戻し軟化抵抗を増加させる元
素であり、含有量が0.05wt%未満ではこの効果は充分で
はなく、また、1.0wt%を越えて過剰に含有させると溶
接性を阻害し、かつ、高価となる。よって、Mo含有量は
0.05〜1.0wt%とする。Mo is an element that enhances the hardenability and increases the temper softening resistance. If the content is less than 0.05 wt%, this effect is not sufficient, and if it exceeds 1.0 wt%, the weldability is impaired. And expensive. Therefore, the Mo content is
0.05 to 1.0 wt%
Vは少量含有させることにより焼入れ性を増加し、焼戻
し軟化抵抗を高くする元素であり、含有量が0.01wt%未
満ではこのような効果は充分ではなく、また、0.1wt%
を越えて含有させると靭性が劣化する。よって、V含有
量は0.01〜0.1wt%とする。V is an element that increases the hardenability and increases the resistance to temper softening when it is contained in a small amount. If the content is less than 0.01 wt%, such an effect is not sufficient, and 0.1 wt%
If it is contained in excess of 10%, the toughness deteriorates. Therefore, the V content is 0.01 to 0.1 wt%.
Bは微量含有させることにより、焼入れ性を著しく高く
する元素であり、含有量が0.0005wt%未満では充分な効
果は得られず、また、0.005wt%を越えて過多に含有さ
せると焼入れ性向上効果は飽和し、かつ、B化合物の析
出により靭性が劣化する。よって、B含有量は、0.0005
〜0.005wt%とする。B is an element that significantly enhances the hardenability by containing a trace amount. If the content is less than 0.0005 wt%, a sufficient effect cannot be obtained, and if it exceeds 0.005 wt%, the hardenability is improved. The effect is saturated, and the toughness deteriorates due to the precipitation of the B compound. Therefore, the B content is 0.0005.
~ 0.005 wt%
Alは脱酸元素であり、また、Bの焼入れ性効果を確保す
るために、NをAlNとして固定する効果を有する元素で
あり、含有量が0.01wt%未満ではこのような効果は少な
く、また、0.1wt%を越えて含有させると靭性を劣化さ
せる。よって、Al含有量は0.01〜0.1wt%とする。Al is a deoxidizing element, and is an element having an effect of fixing N as AlN in order to secure the hardenability effect of B. If the content is less than 0.01 wt%, such an effect is small, and , If the content exceeds 0.1 wt%, the toughness deteriorates. Therefore, the Al content is 0.01 to 0.1 wt%.
Nbは圧延中の再結晶抑制効果を通じて、オーステナイト
粒の微細化および展伸化に有効な元素であり、含有量が
0.005wt%未満ではこのような効果は少なく、また、0.1
wt%を越える過剰な含有は靭性を劣化させる。よつて、
Nb含有量は0.005〜0.1wt%とする。Nb is an element effective for refining and spreading of austenite grains through the effect of suppressing recrystallization during rolling.
If it is less than 0.005 wt%, such effect is small, and if it is 0.1
Excessive content exceeding wt% deteriorates toughness. Yotsutte
The Nb content is 0.005-0.1 wt%.
なお、上記に説明した含有成分以外に、強度レベルおよ
び板厚に応じて焼入れ性向上元素として有効なCu、Niお
よびNの固定元素のTiさらに介在物の形態制御元素であ
るCaの内から選んだ1種または2種以上を含有させるこ
とができる。In addition to the components described above, Cu, Ni, a fixed element of Ni and N, which is effective as a hardenability-improving element depending on the strength level and plate thickness, and Ca, which is a morphology controlling element of inclusions, are selected. It is possible to contain one kind or two or more kinds.
Cuは固溶強化、析出強化により強度上昇に有効な元素で
あり、含有量が0.05wt%未満ではこのような効果を充分
に発揮することはできず、また、0.50wt%を越えて過剰
に含有させると熱間加工性が劣化し、表面割れを生じ易
くなる。よって、Cu含有量は0.05〜0.50wt%とする。Cu is an element effective in increasing strength by solid solution strengthening and precipitation strengthening, and if the content is less than 0.05 wt%, such effects cannot be sufficiently exhibited, and if it exceeds 0.50 wt%, it becomes excessive. If contained, hot workability deteriorates, and surface cracks are likely to occur. Therefore, the Cu content is 0.05 to 0.50 wt%.
Niは焼入れ性を向上させ、かつ、母材の靭性を向上させ
る元素であり、含有量が0.05wt%未満ではこのような効
果は充分ではなく、また、1.5wt%を越えて過多に含有
させるとスケール疵を発生し易くなり、さらに、コスト
の上昇をもたらす。よって、Ni含有量は0.05〜1.5wt%
とする。Ni is an element that improves hardenability and toughness of the base metal, and if the content is less than 0.05 wt%, such an effect is not sufficient, and if it exceeds 1.5 wt%, it is excessively contained. And scale flaws are more likely to occur, further increasing the cost. Therefore, the Ni content is 0.05 to 1.5 wt%
And
Tiは炭窒化物形成元素であり、Bの焼入れ性を向上させ
る効果を安定化するために、NをTiNとして固定するの
に有効な元素であり、含有量が0.005wt%未満ではこの
ような効果は充分ではなく、また、0.03wt%を越えて過
多に含有させると靭性の劣化をもたらす。よって、Ti含
有量は0.005〜0.03wt%とする。Ti is a carbonitride forming element, and is an element effective for fixing N as TiN in order to stabilize the effect of improving the hardenability of B. When the content is less than 0.005 wt%, The effect is not sufficient, and if it is contained in excess of 0.03 wt%, the toughness deteriorates. Therefore, the Ti content is 0.005 to 0.03 wt%.
Caは非金属介在物の球状化作用を有し、異方性の低減に
有効な元素であり、含有量が0.001wt%未満ではこのよ
うな効果は充分ではなく、また、0.005wt%を越えて過
多に含有させると非金属介在物が増加して靭性を劣化す
る。よって、Ca含有量は0.001〜0.005wt%とする。Ca has a spheroidizing effect on non-metallic inclusions and is an element effective in reducing anisotropy. If the content is less than 0.001 wt%, such an effect is not sufficient, and if it exceeds 0.005 wt%. If added too much, non-metallic inclusions increase and the toughness deteriorates. Therefore, the Ca content is 0.001 to 0.005 wt%.
次に、本発明に係る溶接性・脆性破壊伝播停止特性の優
れた調質高張力鋼板の製造方法の製造条件について説明
する。Next, the manufacturing conditions of the method for manufacturing a tempered high-strength steel sheet having excellent weldability and brittle fracture propagation stopping properties according to the present invention will be described.
上記に説明した含有成分および成分割合の鋼のNbを含有
しない場合に、1250℃以下の温度に加熱するのは、この
温度より高い温度ではオーステナイト粒が異常に成長
し、充分な圧下を加えてもオーステナイト粒は微細化せ
ず、靭性が不良となるからである。When the steel does not contain Nb of the components and component ratios described above, it is heated to a temperature of 1250 ° C or lower because austenite grains grow abnormally at a temperature higher than this temperature, and sufficient reduction is applied. This is because the austenite grains do not become fine and the toughness becomes poor.
また、上記に説明した含有成分および成分割合の鋼のNb
を含有する場合には、1250℃以下で、Nbの炭窒化物が完
全に固溶する温度(Nb、C、N含有量により変化する
が、Irvine等によれば[Nb(wt%)]×[C+12/14N]
≦2.26−6770/Tにより評価可能)とするのは、鋼中にNb
炭窒化物が粗大なまま残存すると、Nbによる圧延中のオ
ーステナイト再結晶抑制効果が充分に得られず、また、
靭性が不良となるからである。In addition, the Nb of the steel of the content components and component ratios described above
When Nb is contained, the temperature at which the carbonitride of Nb completely forms a solid solution at 1250 ° C or lower (changes depending on the Nb, C, and N contents, but according to Irvine et al., [Nb (wt%)] × [C + 12 / 14N]
≤2.26-6770 / T) can be evaluated as Nb in steel.
If the carbonitride remains coarse, the effect of suppressing recrystallization of austenite during rolling by Nb cannot be sufficiently obtained, and
This is because the toughness becomes poor.
全圧下率を75%以上とするのは、この圧下率未満では加
熱時の粗大なオーステナイト粒が板厚中心部で充分に微
細化されず、靭性が不良となるからである。The reason why the total rolling reduction is set to 75% or more is that if the rolling reduction is less than this, the coarse austenite grains during heating are not sufficiently refined in the central portion of the plate thickness, resulting in poor toughness.
さらに、仕上温度TF(℃)を特許請求の範囲に記載の
通りの(1)式または(2)式とした理由について説明
する。Further, the reason why the finishing temperature TF (° C.) is set to the formula (1) or the formula (2) as described in the claims will be described.
第1図は種々の圧延条件により圧延した後、直接焼入
れ、焼戻しを行なって引張強さを約68kgf/mm2にした場
合の落重試験におけるNDT温度(脆性破壊伝播停止特性
の一つの尺度)と、表面3mmのvTrs(シャルピ衝撃試験
における破面遷移温度)の関係を示す図である。第1図
において使用した鋼の含有成分および成分割合は、C 0.
07〜0.10wt%−Si 0.25wt%−Mn 1.25wt%−Cr 0.15wt
%−Mo 0.10wt%−Nb 0〜0.015wt%−V 0.037wt%−B
0.001wt%−Pcm 0.16〜0.19wt%であり、加熱温度:1200
℃、全圧下率:80%、仕上温度:1000〜840℃、焼入れ:
直接焼入れ、焼戻し:TS=68kgf/mm2を目標として温度調
整、試験片:JIS4号(5mmサブサイズ)とした。Fig. 1 shows the NDT temperature (one measure of the brittle fracture propagation stopping property) in the drop weight test when the plate was rolled under various rolling conditions and then directly quenched and tempered to a tensile strength of approximately 68 kgf / mm 2. FIG. 3 is a diagram showing a relationship between vTrs (fracture surface transition temperature in a Charpy impact test) on a surface of 3 mm. The components and ratios of the steel used in Fig. 1 are C 0.
07〜0.10wt% -Si 0.25wt% -Mn 1.25wt% -Cr 0.15wt
% -Mo 0.10wt% -Nb 0-0.015wt% -V 0.037wt% -B
0.001wt% -Pcm 0.16-0.19wt%, heating temperature: 1200
℃, total reduction: 80%, finishing temperature: 1000 ~ 840 ℃, quenching:
Direct quenching, tempering: Temperature adjustment targeting TS = 68 kgf / mm 2 , test piece: JIS No. 4 (5 mm subsize).
この第1図から、NDT温度と表面のvTrsは良好な相関関
係があり、脆性破壊伝播停止特性を改善するためには、
表面部の靭性を改善する必要があることは明らかであ
る。From FIG. 1, there is a good correlation between the NDT temperature and the surface vTrs, and in order to improve the brittle fracture propagation stopping property,
Clearly, there is a need to improve the toughness of the surface.
この靭性を支配する因子として、焼入れままの硬さ(焼
入れ組織の指標)およびオーステナイト粒径が重要であ
り、これらと靭性との関係を表面部の場合について定量
化した。その結果、表面のvTrsは焼入れままのビッカー
ス硬さHVQと、亀裂の進行方向のオーステナイト粒の平
均幅d(cm)およびC含有量(wt%)を用いて次式によ
り精度よく推定できるということがわかった(第2図参
照)。As the factors that govern this toughness, as-quenched hardness (an index of the quenched structure) and austenite grain size are important, and the relationship between these and toughness was quantified in the case of the surface portion. As a result, the surface vTrs can be accurately estimated by the following equation using the as-quenched Vickers hardness HVQ, and the average width d (cm) and C content (wt%) of the austenite grains in the crack propagation direction. Was found (see FIG. 2).
vTrs=0.063{HVQ−0.83(1120C+270)}2 −66.7logd−1/2−68(℃) (3) HVQ:焼入れままのビッカース硬さ d:亀裂進行方向のオーステナイト粒の平均幅 C:炭素含有量(wt%) この式よりvTrsに対してはC含有量毎にHVQの最適値が
存在し、その値よりも高すぎても、低すぎても靭性は劣
化し、また、dを小さくする程靭性は良好となることが
わかる。vTrs = 0.063 {HVQ-0.83 ( 1120C + 270)} 2 -66.7logd -1/2 -68 (℃) (3) HVQ: quenching remains Vickers hardness d: average width of the crack advancing direction of the austenite grains C: carbon content Amount (wt%) From this formula, for VTrs, there is an optimum value of HVQ for each C content, and if it is higher or lower than that value, toughness deteriorates, and d is reduced. It can be seen that the toughness becomes better.
次に、この式にあるHVQおよびdを支配する因子とし
て、加熱温度、圧下率、仕上温度およびC含有量を選定
し、これらとHVQ、dとの関係を定量化した。Next, the heating temperature, the rolling reduction, the finishing temperature and the C content were selected as the factors controlling HVQ and d in this equation, and the relationship between these and HVQ and d was quantified.
その結果、加熱温度が1250℃以下(Nbを含有する場合に
は、1250℃以下で、かつ、Nbの炭窒化物が完全に固溶す
る温度)であり、全圧下率75%以上である限り、HVQお
よびdは、圧延仕上温度TFのみによって定まり、次式
のように表すことができることがわかった(第3図、第
4図参照)。As a result, the heating temperature is 1250 ° C or lower (when Nb is contained, it is 1250 ° C or lower, and the temperature at which the Nb carbonitride is completely dissolved), and as long as the total rolling reduction is 75% or more. , HVQ and d are determined only by the rolling finish temperature TF, and can be expressed by the following equations (see FIGS. 3 and 4).
この第3図において、 HVQ=0.333TF+1000C−81 (4) TF:圧延仕上温度(℃) C:炭素含有量(wt%) である。In this FIG. 3, HVQ = 0.333TF + 1000C−81 (4) TF: rolling finishing temperature (° C.) C: carbon content (wt%).
第4図において、 logd−1/2=−1.5TF/1000+2.26C+2.42 (5) (Nb無含有の場合) logd−1/2=TF/1000+2.26C+2.03 (5′) (Nb含有の場合) TF:圧延仕上温度(℃) C:炭素含有量(wt%) 第4図(a)はNbは含まず(上記式(5)で示す。)、
第4図(b)はNb含有量は0.015wt%(上記式(5′)
で示す。)である。In Fig. 4, logd- 1 / 2 = -1.5TF / 1000 + 2.26C + 2.42 (5) (Nb-free) logd- 1 / 2 = TF / 1000 + 2.26C + 2.03 (5 ') (Nb-containing) TF: rolling finishing temperature (° C) C: carbon content (wt%) Fig. 4 (a) does not contain Nb (shown by the above formula (5)),
In Fig. 4 (b), the Nb content is 0.015 wt% (the above formula (5 ')
Indicate. ).
C含有量の比較的に多い従来鋼と同等以上の脆性破壊伝
播停止特性を確保するためには、NDT温度を−50℃以下
とする必要があり、これを満足するためには、第1図よ
り表面のvTrsを−130℃以下とする必要があることがわ
かる。(3)式のvTrs≦−130という不等式に、(4)
(5)(5′)式を代入して整理すると、特許請求の範
囲に記載の(1)(2)式が得られる。In order to secure the brittle fracture propagation stopping property equivalent to or higher than that of the conventional steel having a relatively large C content, it is necessary to set the NDT temperature to -50 ° C or lower, and in order to satisfy this, FIG. It can be seen that it is necessary to keep the surface vTrs at -130 ° C or lower. In the inequality vTrs ≤ −130 of the equation (3),
By substituting the expressions (5) and (5 ′) for rearranging, the expressions (1) and (2) described in the claims are obtained.
以上に説明した理由により、仕上温度TFを特許請求の
範囲の(1)(2)式に規定したのである。For the reason explained above, the finishing temperature TF is defined by the formulas (1) and (2) in the claims.
また、オーステナイト域の温度から直接焼入れを行なう
のは、加熱、圧延条件の制御により得られた変形帯等の
ベイナイト変態の核を多数含んだ微粒オーステナイト組
織から、靭性の良好な微細なマルテンサイトと下部ベイ
ナイトの混合組織を表面部に生成させるためである。Further, the direct quenching from the temperature of the austenite region, heating, from the fine grained austenite structure containing a large number of bainite transformation nuclei such as the deformation zone obtained by the control of the rolling conditions, tough fine martensite and This is because the mixed structure of the lower bainite is generated on the surface portion.
そして、この直接焼入れをオーステナイト域から行なう
のは、それより低い温度から焼入れを行なうと、フェラ
イトが生成して60kgf/mm2以上の強度を確保するのが困
難となるためである。The reason why the direct quenching is performed from the austenite region is that if quenching is performed at a temperature lower than that, it is difficult to secure ferrite with a strength of 60 kgf / mm 2 or more.
さらに焼戻し温度をAc1点未満の温度とするのは、Ac1点
以上の温度では組織が部分的にオーステナイトに変態し
て、焼戻し後にフェライトおよび上部ベイナイトが生成
し、強度の著しい低下をもたらすからである。Further to the tempering temperature and the temperature of the Ac less than 1 point is transformed into tissue partially austenite at Ac 1 point or higher, ferrite and upper bainite is generated after tempering, because results in a significant decrease in strength Is.
[実 施 例] 本発明に係る溶接性・脆性破壊伝播停止特性の優れた調
質高張力鋼の製造方法の実施例を説明する。[Example] An example of a method for producing a heat-treated high-strength steel excellent in weldability and brittle fracture propagation stopping property according to the present invention will be described.
実 施 例 第1表に示す含有成分および成分割合の鋼を常法により
溶製してスラブを製造し、このスラブを第2表に示す加
熱条件、圧延条件により種々の板厚に圧延を行ない、第
2表に示す熱処理を行なった後、引張試験および衝撃試
験を行ない、さらに、斜めY型溶接割れ試験により溶接
性を評価した。Example A slab is manufactured by smelting steel having the contained components and component ratios shown in Table 1 by a conventional method, and this slab is rolled into various plate thicknesses under the heating conditions and rolling conditions shown in Table 2. After performing the heat treatment shown in Table 2, a tensile test and an impact test were performed, and the weldability was evaluated by an oblique Y-type weld cracking test.
また、落重試験或いは二重引張試験によって脆性破壊伝
播停止特性を評価した。Moreover, the brittle fracture propagation stopping property was evaluated by a drop weight test or a double tensile test.
第3表にこれらの結果を示す。Table 3 shows these results.
第3表から明らかなように、本発明に係る溶接性・脆性
破壊伝播停止特性の優れた調質高張力鋼の製造方法によ
り製造された鋼板A〜Gは、その何れもが60kgf/mm2以
上の引張強さおよび割れ防止予熱温度25℃以上の良好な
溶接性を有しているものである。As is clear from Table 3, all of the steel sheets A to G produced by the method for producing a heat-treated high-strength steel having excellent weldability and brittle fracture propagation stopping characteristics according to the present invention have 60 kgf / mm 2 It has excellent tensile strength and good weldability with a crack prevention preheating temperature of 25 ° C or higher.
さらに、落重試験におけるNDT温度−60℃以下、0℃に
おけるKca値 以上の優れた脆性破壊伝播停止特性を有している。Furthermore, Kca value at NDT temperature of -60 ℃ or less and 0 ℃ in drop weight test It has the excellent brittle fracture propagation stopping properties described above.
この本発明に係る溶接性・脆性破壊伝播停止特性の優れ
た調質高張力鋼の製造方法により製造された鋼板に対し
て、比較鋼HはPcm値が高すぎるために、溶接性が充分
ではなく、比較鋼I〜Mは圧延条件が適切でないため、
脆性破壊伝播停止特性は充分ではない。Compared with the steel sheet produced by the method for producing a heat-treated high-strength steel having excellent weldability and brittle fracture propagation stopping characteristics according to the present invention, the comparative steel H has a Pcm value that is too high, so the weldability is insufficient. Comparative steels I to M do not have appropriate rolling conditions,
The brittle fracture propagation stopping property is not sufficient.
[発明の効果] 以上説明したように、本発明に係る溶接性・脆性破壊伝
播停止特性の優れた調質高張力鋼の製造方法は上記の構
成であるから、溶接性および脆性破壊伝播停止特性の優
れた低C系の引張強さが60〜80kgf/mm2クラスの調質高
張力鋼板を効果的に製造することができるという効果を
有するものである。 [Effects of the Invention] As described above, since the method for producing a heat-treated high-strength steel excellent in weldability and brittle fracture propagation stopping characteristics according to the present invention has the above-described configuration, the weldability and brittle fracture propagation stopping characteristics are thus obtained. It has an effect that it is possible to effectively produce a heat-treated high-strength steel sheet having excellent low C tensile strength of 60 to 80 kgf / mm 2 class.
【図面の簡単な説明】 第1図は表面3mmのvTrs(℃)とNDT温度(℃)との関係
を示す図、第2図は表面の実測vTrs(℃)と計算vTrs
(℃)との関係を示す図、第3図は圧延仕上温度TF
(℃)とDQままの硬さ(HVQ)との関係を示す図、第4
図(a)(b)はNbを含有しない場合とNbを含有する場
合の圧延仕上温度TF(℃)とlogd12(cm12)との関係
を示す図である。[Brief description of drawings] Fig. 1 is a diagram showing the relationship between vTrs (° C) and NDT temperature (° C) on a surface of 3 mm, and Fig. 2 is the measured vTrs (° C) and calculated vTrs of the surface.
Fig. 3 shows the relationship with (℃), and Fig. 3 shows the rolling finish temperature TF.
Diagram showing the relationship between (℃) and DQ hardness (HVQ), No. 4
Figures (a) and (b) are diagrams showing the relationship between the rolling finish temperature TF (° C) and logd 12 (cm 12 ) when Nb is not contained and when Nb is contained.
Claims (4)
n 0.4〜1.5wt%、 Cr 0.05〜1.0wt%、Mo 0.05〜1.0wt%、V 0.01〜0.1wt
%、 B 0.0005〜0.005wt%、Al 0.01〜0.1wt%を含有し、か
つ、 Pcm=C+Si/30+Mn/20+Cu/20+Ni/60 +Cr/20+Mo/15+V/10+5B≦0.22wt% を満足し、残部Feおよび不可避不純物からなる鋼を、加
熱温度≦1250℃、全圧下率≧75%、さらに、仕上温度T
F(℃)が下記式 0.063(0.333TF+70.4C−300)2 +0.10TF−151C−229≦−130 (1) (Cはwt%の炭素量) を満足する条件で熱間圧延を終了した後、オーステナイ
ト域の温度から直接焼入れを行い、その後、Ac1点未満
の温度で焼戻しを行うことを特徴とする溶接性・脆性破
壊伝播停止特性の優れた調質高張力鋼板の製造方法。1. C 0.04 to 1.10 wt%, Si 0.01 to 0.50 wt%, M
n 0.4-1.5wt%, Cr 0.05-1.0wt%, Mo 0.05-1.0wt%, V 0.01-0.1wt
%, B 0.0005 to 0.005 wt%, Al 0.01 to 0.1 wt%, and Pcm = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B ≦ 0.22wt%, and the balance Fe and Steel consisting of unavoidable impurities, heating temperature ≤ 1250 ℃, total rolling reduction ≥ 75%, and finishing temperature T
Hot rolling was completed under the condition that F (° C) satisfies the following formula 0.063 (0.333TF + 70.4C-300) 2 + 0.10TF-151C-229 ≦ -130 (1) (C is the carbon amount in wt%) Then, a method for producing a heat-treated high-strength steel sheet having excellent weldability and brittle fracture propagation stopping properties, characterized by performing direct quenching from a temperature in the austenite region and then tempering at a temperature of less than the Ac 1 point.
n 0.4〜1.5wt%、 Cr 0.05〜1.0wt%、Mo 0.05〜1.0wt%、V 0.01〜0.1wt
%、 B 0.0005〜0.005wt%、Al 0.01〜0.1wt%、Nb 0.005〜
0.1wt% を含有し、かつ、 Pcm=C+Si/30+Mn/20+Cu/20+Ni/60 +Cr/20+Mo/15+V/10+5B≦0.22wt% を満足し、残部Feおよび不可避不純物からなる鋼を、12
50℃以下の温度で、かつ、Nbの炭窒化物が完全に固溶す
る温度の加熱温度、全圧下率≧75%、さらに、仕上温度
TF(℃)が下記式 0.063(0.333TF+70.4C−300)2 +0.067TF−151C−203≦−130 (2) (Cはwt%の炭素量) を満足する条件で熱間圧延を終了した後、オーステナイ
ト域の温度から直接焼入れを行い、その後、Ac1点未満
の温度で焼戻しを行うことを特徴とする溶接性・脆性破
壊伝播停止特性の優れた調質高張力鋼板の製造方法。2. C 0.04 to 1.10 wt%, Si 0.01 to 0.50 wt%, M
n 0.4-1.5wt%, Cr 0.05-1.0wt%, Mo 0.05-1.0wt%, V 0.01-0.1wt
%, B 0.0005 to 0.005 wt%, Al 0.01 to 0.1 wt%, Nb 0.005 to
A steel containing 0.1 wt% and satisfying Pcm = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B ≦ 0.22wt% with the balance Fe and unavoidable impurities
Heating temperature at a temperature of 50 ° C or less and at a temperature at which Nb carbonitride is completely dissolved, total rolling reduction ≧ 75%, and finishing temperature TF (° C) is 0.063 (0.333TF + 70.4C- 300) 2 + 0.067TF-151C-203 ≤-130 (2) (C is the carbon content of wt%) After the hot rolling is finished, quenching is performed directly from the temperature in the austenite region, and then, A method for producing a tempered high-strength steel sheet having excellent weldability and brittle fracture propagation stopping characteristics, characterized by performing tempering at a temperature below the Ac 1 point.
n 0.4〜1.5wt%、 Cr 0.05〜1.0wt%、Mo 0.05〜1.0wt%、V 0.01〜0.1wt
%、 B 0.0005〜0.005wt%、Al 0.01〜0.1wt% を含有し、さらに、 Cu 0.05〜0.50wt%、Ni 0.05〜1.5wt%、Ti 0.005〜0.0
3wt%、 Ca 0.001〜0.005wt% の内から選んだ1種または2種以上 を含有し、かつ、 Pcm=C+Si/30+Mn/20+Cu/20+Ni/60 +Cr/20+Mo/15+V/10+5B≦0.22wt% を満足し、残部Feおよび不可避不純物からなる鋼を、加
熱温度≦1250℃、全圧下率≧75%、さらに、仕上温度T
F(℃)が下記式 0.063(0.333TF+70.4C−300)2 +0.10TF−151C−229≦−130 (1) (Cはwt%の炭素量) を満足する条件で熱間圧延を終了した後、オーステナイ
ト域の温度から直接焼入れを行い、その後、Ac1点未満
の温度で焼戻しを行うことを特徴とする溶接性・脆性破
壊伝播停止特性の優れた調質高張力鋼板の製造方法。3. C 0.04 to 1.10 wt%, Si 0.01 to 0.50 wt%, M
n 0.4-1.5wt%, Cr 0.05-1.0wt%, Mo 0.05-1.0wt%, V 0.01-0.1wt
%, B 0.0005 to 0.005 wt%, Al 0.01 to 0.1 wt%, Cu 0.05 to 0.50 wt%, Ni 0.05 to 1.5 wt%, Ti 0.005 to 0.0
Contains 1 or 2 or more selected from 3 wt% and Ca 0.001 to 0.005 wt%, and satisfies Pcm = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B ≦ 0.22wt% Then, the steel consisting of the balance Fe and unavoidable impurities is heated at a temperature of ≤1250 ° C, a total reduction of ≥75%, and a finishing temperature T
Hot rolling was completed under the condition that F (° C) satisfies the following formula 0.063 (0.333TF + 70.4C-300) 2 + 0.10TF-151C-229 ≦ -130 (1) (C is the carbon amount in wt%) Then, a method for producing a heat-treated high-strength steel sheet having excellent weldability and brittle fracture propagation stopping properties, characterized by performing direct quenching from a temperature in the austenite region and then tempering at a temperature of less than the Ac 1 point.
n 0.4〜1.5wt%、 Cr 0.05〜1.0wt%、Mo 0.05〜1.0wt%、V 0.01〜0.1wt
%、 B 0.0005〜0.005wt%、Al 0.01〜0.1wt%、Nb 0.005〜
0.1wt% を含有し、さらに、 Cu 0.05〜0.50wt%、Ni 0.05〜1.5wt%、Ti 0.005〜0.0
3wt%、 Ca 0.001〜0.005wt% の内から選んだ1種または2種以上 を含有し、かつ、 Pcm=C+Si/30+Mn/20+Cu/20+Ni/60 +Cr/20+Mo/15+V/10+5B≦0.22wt% を満足し、残部Feおよび不可避不純物からなる鋼を、12
50℃以下の温度で、かつ、Nbの炭窒化物が完全に固溶す
る温度の加熱温度、全圧下率≧75%、さらに、仕上温度
TF(℃)が下記式 0.063(0.333TF+70.4C−300)2 +0.067TF−151C−203≦−130 (2) (Cはwt%の炭素量) を満足する条件で熱間圧延を終了した後、オーステナイ
ト域の温度から直接焼入れを行い、その後、Ac1点未満
の温度で焼戻しを行うことを特徴とする溶接性・脆性破
壊伝播停止特性の優れた調質高張力鋼板の製造方法。4. C 0.04 to 1.10 wt%, Si 0.01 to 0.50 wt%, M
n 0.4-1.5wt%, Cr 0.05-1.0wt%, Mo 0.05-1.0wt%, V 0.01-0.1wt
%, B 0.0005 to 0.005 wt%, Al 0.01 to 0.1 wt%, Nb 0.005 to
0.1 wt%, Cu 0.05 to 0.50 wt%, Ni 0.05 to 1.5 wt%, Ti 0.005 to 0.0
Contains 1 or 2 or more selected from 3 wt% and Ca 0.001 to 0.005 wt%, and satisfies Pcm = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5B ≦ 0.22wt% Steel containing the balance Fe and unavoidable impurities
Heating temperature at a temperature of 50 ° C or less and at a temperature at which Nb carbonitride is completely dissolved, total rolling reduction ≧ 75%, and finishing temperature TF (° C) is 0.063 (0.333TF + 70.4C- 300) 2 + 0.067TF-151C-203 ≤-130 (2) (C is the carbon content of wt%) After the hot rolling is finished, quenching is performed directly from the temperature in the austenite region, and then, A method for producing a tempered high-strength steel sheet having excellent weldability and brittle fracture propagation stopping characteristics, characterized by performing tempering at a temperature below the Ac 1 point.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1210431A JPH0726150B2 (en) | 1989-08-15 | 1989-08-15 | Manufacturing method of tempered high-strength steel sheet with excellent weldability and brittle fracture propagation stopping properties |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1210431A JPH0726150B2 (en) | 1989-08-15 | 1989-08-15 | Manufacturing method of tempered high-strength steel sheet with excellent weldability and brittle fracture propagation stopping properties |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0375310A JPH0375310A (en) | 1991-03-29 |
JPH0726150B2 true JPH0726150B2 (en) | 1995-03-22 |
Family
ID=16589209
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1210431A Expired - Fee Related JPH0726150B2 (en) | 1989-08-15 | 1989-08-15 | Manufacturing method of tempered high-strength steel sheet with excellent weldability and brittle fracture propagation stopping properties |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0726150B2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002349564A (en) | 2001-05-31 | 2002-12-04 | Thk Co Ltd | Track rail mounting structure of linear guide device |
JP5874664B2 (en) * | 2013-03-15 | 2016-03-02 | Jfeスチール株式会社 | High strength steel plate with excellent drop weight characteristics and method for producing the same |
JP6253974B2 (en) * | 2013-12-27 | 2017-12-27 | Jfeスチール株式会社 | Thick steel plate for reactor containment vessel with excellent brittle crack propagation stopping characteristics |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0227407B2 (en) * | 1984-06-19 | 1990-06-18 | Nippon Steel Corp | YOSETSUSEINISUGURETAKOKYODOKONOSEIZOHOHO |
JPS63145711A (en) * | 1986-12-08 | 1988-06-17 | Kobe Steel Ltd | Production of high tension steel plate having excellent low temperature toughness |
-
1989
- 1989-08-15 JP JP1210431A patent/JPH0726150B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH0375310A (en) | 1991-03-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3653736B1 (en) | Hot-rolled steel strip and manufacturing method | |
US8147626B2 (en) | Method for manufacturing high strength steel plate | |
JP4379085B2 (en) | Manufacturing method of high strength and high toughness thick steel plate | |
JP5089224B2 (en) | Manufacturing method of on-line cooling type high strength steel sheet | |
JP3906779B2 (en) | Manufacturing method of low temperature steel with excellent stress corrosion cracking resistance | |
JP4264177B2 (en) | Method for producing a steel material having a coarse ferrite layer on the surface layer | |
JPH05186823A (en) | Production of cu-containing high tensile strength steel with high toughness | |
JP3546726B2 (en) | Method for producing high-strength steel plate with excellent HIC resistance | |
JP4362319B2 (en) | High strength steel plate with excellent delayed fracture resistance and method for producing the same | |
JP3602471B2 (en) | High tensile strength steel sheet excellent in weldability and method for producing the same | |
JP5672658B2 (en) | High strength steel plate for line pipes with excellent HIC resistance and weld heat affected zone toughness and method for producing the same | |
JP4926447B2 (en) | Manufacturing method of high strength steel with excellent weld crack resistance | |
JP3499705B2 (en) | 950N / mm2 class tempered high-strength steel sheet having excellent homogeneity in thickness direction and low anisotropy of toughness, and method for producing the same | |
JP3863413B2 (en) | High toughness high tension non-tempered thick steel plate and manufacturing method thereof | |
JPH0726150B2 (en) | Manufacturing method of tempered high-strength steel sheet with excellent weldability and brittle fracture propagation stopping properties | |
JP3602396B2 (en) | Low yield ratio high strength steel sheet with excellent weldability | |
JPS6167717A (en) | Manufacture of high tension steel plate having superior strength and toughness in its weld heat-affected zone | |
JPH059570A (en) | Manufacturing method of high weldability and high strength steel | |
JPH09324216A (en) | Manufacture of high strength steel or line pipe, excellent in hic resistance | |
JPH09324217A (en) | Manufacture of high strength steel for line pipe, excellent in hic resistance | |
JP3327065B2 (en) | Method for producing tempered high-strength steel sheet excellent in brittle crack propagation arrestability | |
KR100311791B1 (en) | METHOD FOR MANUFACTURING QUENCHED AND TEMPERED STEEL WITH SUPERIOR TENSILE STRENGTH OF AROUND 600MPa AND IMPROVED TOUGHNESS IN WELDED PART | |
JP2546888B2 (en) | Manufacturing method of high-strength steel sheet with excellent weldability and toughness | |
KR102747790B1 (en) | Cold-rolled steel sheet and method of manufacturing the same | |
JPH0579728B2 (en) |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080322 Year of fee payment: 13 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090322 Year of fee payment: 14 |
|
LAPS | Cancellation because of no payment of annual fees |