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JPH07157415A - Hair cosmetic - Google Patents

Hair cosmetic

Info

Publication number
JPH07157415A
JPH07157415A JP33926893A JP33926893A JPH07157415A JP H07157415 A JPH07157415 A JP H07157415A JP 33926893 A JP33926893 A JP 33926893A JP 33926893 A JP33926893 A JP 33926893A JP H07157415 A JPH07157415 A JP H07157415A
Authority
JP
Japan
Prior art keywords
hair
dandruff
acid
hair cosmetic
cosmetic composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP33926893A
Other languages
Japanese (ja)
Inventor
Katsuo Hashimoto
克夫 橋本
Hiroshi Sasaki
啓 佐々木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Priority to JP33926893A priority Critical patent/JPH07157415A/en
Publication of JPH07157415A publication Critical patent/JPH07157415A/en
Pending legal-status Critical Current

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  • Cosmetics (AREA)

Abstract

PURPOSE:To obtain a hair cosmetic having remarkably improved dandruff- preventing effect and effective even at a remarkably decreased concentration of a dandruff-preventing agent. CONSTITUTION:This hair cosmetic contains (A) one or more kinds of substances selected from lactic acid, pyrrolidonecarboxylic acid and their salts (e.g. K, Na, Li, Ca or Mg salt) and (B) one or more kinds of dandruff-preventing agents such as zinc pyrithione, triclosan, trichlorocarbanilide, dipotassium glycyrrhizinate, allantoin, sulfur, isopropylphenol and salicylic acid. The amount of the component is preferably 0.001-5.0wt.%, especially 0.005-1.0wt.% for A and preferably 0.0001-5.0wt.%, especially 0.0005-1.0wt.% for B. The cosmetic is applied to the hair and scalp in the form of shampoo, hair rinse, hair liquid, hair tonic, hair cream, hair spray, scalp tonic, etc.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は頭髪化粧料に関し、更に
詳しくはヘアシャンプー、ヘアリンス、ヘアートリート
メント、ヘアリキッド、ヘアークリーム、ヘアスプレ
ー、ヘアトニック等のふけ防止用頭髪化粧料に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair cosmetic composition, and more particularly to a hair cosmetic composition for preventing dandruff such as hair shampoo, hair rinse, hair treatment, hair liquid, hair cream, hair spray, and hair tonic.

【0002】[0002]

【従来の技術および課題】一般に、ふけは皮脂腺の分泌
物、汗腺の分泌物、表皮層の剥離物からなり、通常は皮
脂腺等の分泌昂進により発生するが、皮膚に細菌等が感
染すると、ふけの発生は病的に助長される。このため、
従来から抗菌剤・殺菌剤を添加した頭髪化粧料がふけ防
止のために使用されてきた。例えば、従来からジンクピ
リチオン、トリクロサン等の抗菌剤がふけ防止用薬剤と
して用いられてきたが、これらのふけ防止効果は未だ満
足できるものではなかった。また、これらの抗菌剤の中
には効果を発揮させるために使用量が多くなり安全性、
安定性に問題があるものもあった。
2. Description of the Related Art In general, dandruff is composed of secretions of sebaceous glands, secretions of sweat glands, and exfoliated substances of the epidermis. Usually, dandruff is caused by increased secretion of sebaceous glands. The occurrence of is pathologically promoted. For this reason,
Hair cosmetics containing antibacterial agents and bactericides have been conventionally used to prevent dandruff. For example, antibacterial agents such as zinc pyrithione and triclosan have been conventionally used as antidandruff agents, but the antidandruff effects are not yet satisfactory. In addition, some of these antibacterial agents are used in large amounts in order to exert their effects, and thus safety,
Some had problems with stability.

【0003】[0003]

【課題を解決するための手段】本発明者等は、前記技術
的課題を達成すべく鋭意研究を重ねた結果、乳酸及びピ
ロリドンカルボン酸とこれらの塩類の中から選ばれる一
種もしくは二種以上とふけ防止用薬剤の一種もしくは二
種以上とを頭髪化粧料に含有させるとふけ防止効果が飛
躍的に向上し、ふけ防止用薬剤の濃度を大幅に低減させ
ることが可能となるという事実を見出し、この新知見に
基づいて本発明を完成するに至った。
Means for Solving the Problems The inventors of the present invention have conducted extensive studies to achieve the above technical problems, and as a result, selected one or more kinds selected from lactic acid and pyrrolidonecarboxylic acid and salts thereof. The fact that inclusion of one or more anti-dandruff agents in hair cosmetics dramatically improves the anti-dandruff effect and makes it possible to significantly reduce the concentration of the anti-dandruff agent, The present invention has been completed based on this new finding.

【0004】すなわち、本発明は、乳酸及びピロリドン
カルボン酸とこれらの塩類の中から選ばれる一種もしく
は二種以上とふけ防止用薬剤の一種もしくは二種以上と
を含有する頭髪化粧料である。
That is, the present invention is a hair cosmetic containing one or more selected from lactic acid and pyrrolidonecarboxylic acid and salts thereof, and one or more antidandruff agents.

【0005】以下本発明の構成について詳述する。本発
明の頭髪化粧料に用いられる乳酸及びピロリドンカルボ
ン酸とこれらの塩類は、化粧料の分野において用いられ
ているものであればいずれでも良い。本発明の頭髪化粧
料に用いられる乳酸及びピロリドンカルボン酸とこれら
の塩類の具体例としては、例えば、乳酸、ピロリドンカ
ルボン酸等の非塩類、乳酸カリウム、乳酸ナトリウム、
乳酸リチウム、乳酸カルシウム、乳酸マグネシウム、ピ
ロリドンカルボン酸カリウム、ピロリドンカルボン酸ナ
トリウム、ピロリドンカルボン酸リチウム、ピロリドン
カルボン酸カルシウム、ピロリドンカルボン酸マグネシ
ウム等の塩類が挙げられ、本発明においては、これらの
中から任意の一種もしくは二種以上を選びだして用いる
ことができる。本発明の頭髪化粧料においては、これら
の中でも特に乳酸塩、ピロリドンカルボン酸塩等の塩類
の方が好ましい。本発明の頭髪化粧料に用いられる乳酸
及びピロリドンカルボン酸とこれらの塩類の含有量は、
合計量で頭髪化粧料全量中、0.001〜5.0重量%
が好ましく、0.005〜1.0重量%が特に好まし
い。含有量が0.001重量%未満の場合、ふけ防止効
果の飛躍的な向上効果は見られず、5.0重量%を越え
る量を含有させたとしても、配合量に見合ったさらなる
効果の向上は期待できない。
The structure of the present invention will be described in detail below. The lactic acid, pyrrolidonecarboxylic acid and salts thereof used in the hair cosmetic composition of the present invention may be any as long as they are used in the field of cosmetics. Specific examples of lactic acid and pyrrolidonecarboxylic acid and salts thereof used in the hair cosmetic composition of the present invention include, for example, lactic acid, non-salts such as pyrrolidonecarboxylic acid, potassium lactate, sodium lactate,
Lithium lactate, calcium lactate, magnesium lactate, potassium pyrrolidonecarboxylate, sodium pyrrolidonecarboxylate, lithium pyrrolidonecarboxylate, calcium pyrrolidonecarboxylate, magnesium pyrrolidonecarboxylate, and the like salts, and in the present invention, any of these is used. One kind or two or more kinds can be selected and used. In the hair cosmetic composition of the present invention, among these, salts such as lactate and pyrrolidonecarboxylate are preferred. The content of lactic acid and pyrrolidonecarboxylic acid and salts thereof used in the hair cosmetic composition of the present invention is
0.001-5.0% by weight of the total amount of hair cosmetics
Is preferred, and 0.005-1.0% by weight is particularly preferred. If the content is less than 0.001% by weight, no dramatic improvement in dandruff prevention effect is observed, and even if the content exceeds 5.0% by weight, further improvement in proportion to the blended amount is achieved. Can't expect.

【0006】本発明の頭髪化粧料に用いられるふけ防止
用薬剤としては、例えば、ジンクピリチオン、トリクロ
サン、トリクロロカルバニリド、グリチルリチン酸ジカ
リウム、グリチルリチン酸モノアンモニウム、β−グリ
チルレチン酸、アラントイン、イオウ、ビオサルファー
・フリッド、イソプロピルメチルフェノール、サリチル
酸等が挙げられる。本発明の頭髪化粧料においては、こ
れらの中から一種もしくは二種以上を任意に選び用いる
ことができる。 本発明の頭髪化粧料に用いられるふけ
防止用薬剤の含有量は、頭髪化粧料全量中0.0001
〜5.0重量%が好ましく、更に好ましくは0.000
5〜1.0重量%である。含有量が0.0001重量%
未満の場合は、飛躍的なふけ防止効果は認められず、
5.0重量%を越えて配合すると、安全性、安定性に問
題が生じることもあるため好ましくない。
Examples of the antidandruff agent used in the hair cosmetic composition of the present invention include zinc pyrithione, triclosan, trichlorocarbanilide, dipotassium glycyrrhizinate, monoammonium glycyrrhizinate, β-glycyrrhetinic acid, allantoin, sulfur and biosulfur. -Frid, isopropylmethylphenol, salicylic acid and the like can be mentioned. In the hair cosmetic composition of the present invention, one kind or two or more kinds can be arbitrarily selected and used from these. The content of the antidandruff agent used in the hair cosmetic composition of the present invention is 0.0001 based on the total amount of the hair cosmetic composition.
To 5.0% by weight is preferable, and 0.000 is more preferable.
It is 5 to 1.0% by weight. Content is 0.0001% by weight
If it is less than, no dramatic antidandruff effect is observed,
If it is blended in an amount of more than 5.0% by weight, it may cause problems in safety and stability, which is not preferable.

【0007】尚、本発明の頭髪化粧料には、前記した必
須成分の他に、必要に応じて、一般に頭髪化粧料に常用
されている各種添加剤、例えば界面活性剤、防腐剤、酸
化防止剤、保湿剤、香料、油分、キレート剤、着色料、
清涼剤、染料、紫外線吸収剤等が加えられる。これら
は、本発明の効果を損なわない質的、量的条件下で使用
されなければならないことは当然である。
In addition to the above-mentioned essential components, the hair cosmetic composition of the present invention may optionally contain various additives commonly used in hair cosmetic compositions, such as surfactants, preservatives and antioxidants. Agents, moisturizers, fragrances, oils, chelating agents, colorants,
Cooling agents, dyes, UV absorbers, etc. are added. It goes without saying that these must be used under qualitative and quantitative conditions that do not impair the effects of the present invention.

【0008】本発明の頭髪化粧料とは、頭髪ないし頭皮
に使用するものを示し、より具体的には、例えば、シャ
ンプー、ヘアリンス、ヘアリキッド、ヘアートニック、
頭髪用クリーム、ヘアースプレー、スカルプトニック等
の頭髪化粧料にも用いることができる。
The hair cosmetic composition of the present invention is used for hair or scalp, and more specifically, for example, shampoo, hair rinse, hair liquid, hairnic,
It can also be used in hair cosmetics such as hair cream, hair spray, and sculptonic.

【0009】[0009]

【実施例】次に、本発明を実施例により更に詳細に説明
するが、本発明はこれにより限定されるものではない。
配合量は全て重量%である。
EXAMPLES Next, the present invention will be described in more detail by way of examples, which should not be construed as limiting the invention.
All compounding amounts are weight%.

【0010】表1〜9に記載の実施例1〜25及び比較
例1〜18のヘアートニックを常法により製造し、ふけ
防止効果を測定し、結果を記載した。
The hair nicks of Examples 1 to 25 and Comparative Examples 1 to 18 shown in Tables 1 to 9 were produced by a conventional method, the antidandruff effect was measured, and the results are shown.

【0011】(ふけ防止効果測定方法)比較的ふけの多
い22〜50歳の男性パネラー75名により実使用テス
トを以下の方法にて行った。尚、各試料につき5名のパ
ネラーによる実使用テストを行った。試験開始前にコン
トロール期間として、一ヵ月間、1日に一度、薬剤無添
加のシャンプーで洗髪及び薬剤無添加のヘアトニックに
よる整髪を行い、1週間に2回のペースで累積したふけ
を採取し、採取したふけ中の蛋白質を測定した。次に、
続けて試験期間として、実施例及び比較例のヘアートニ
ックを用いて、コントロール期間と同様に一ヵ月間、1
日に一度、シャンプーでの洗髪及びヘアートニックによ
る整髪及び累積したふけの採取、蛋白質の測定を行っ
た。パネラー1人ごとのコントロール期間のふけ中の蛋
白質量の平均と試験期間のふけ中の蛋白質量の平均とを
比較した場合の減少率を求め、パネラーの平均を求めて
ふけ防止効果を測定した。尚、評価基準は以下に従っ
た。 ふけ中の蛋白質量の減少率が50%以上 ・・・A ふけ中の蛋白質量の減少率が40%以上50%未満・・・B ふけ中の蛋白質量の減少率が20%以上40%未満・・・C ふけ中の蛋白質量の減少率が20%未満 ・・・D
(Measurement Method for Antidandruff Effect) An actual use test was conducted by the following method by 75 male panelists aged 22 to 50 who have a relatively large amount of dandruff. An actual use test was conducted by 5 panelists for each sample. Before the start of the test, as a control period, hair was shampooed with shampoo without addition of chemicals once a day for one month, and hair styling with hair tonic without addition of chemicals was performed, and accumulated dandruff was collected twice a week. The protein in the collected dandruff was measured. next,
Subsequently, as the test period, using the articonics of Examples and Comparative Examples, for one month as in the control period, 1
Once a day, shampoo was used for hair washing, hair styling by hair nick, collection of accumulated dandruff, and protein measurement. The reduction rate was calculated when the average amount of protein in the dandruff during the control period and the average amount of protein in the dandruff during the test period were calculated for each panelist, and the average of the panelists was calculated to measure the antidandruff effect. The evaluation criteria were as follows. Reduction rate of protein content in dandruff is 50% or more ・ ・ ・ A Reduction rate of protein content in dandruff is 40% or more and less than 50% ・ ・ ・ B Reduction rate of protein content in dandruff is 20% or more and less than 40%・ ・ ・ C Reduction rate of protein content in dandruff is less than 20% ・ ・ ・ D

【0012】[0012]

【表1】 [Table 1]

【0013】[0013]

【表2】 [Table 2]

【0014】[0014]

【表3】 [Table 3]

【0015】[0015]

【表4】 [Table 4]

【0016】[0016]

【表5】 [Table 5]

【0017】[0017]

【表6】 [Table 6]

【0018】[0018]

【表7】 [Table 7]

【0019】[0019]

【表8】 [Table 8]

【0020】[0020]

【表9】 [Table 9]

【0021】表1〜9の結果からもわかるとおり、乳酸
及びピロリドンカルボン酸とこれらの塩類の中から選ば
れた一種もしくは二種以上と、ふけ防止用薬剤の一種も
しくは二種以上とを併用したものは優れたふけ防止効果
を示した。
As can be seen from the results of Tables 1 to 9, lactic acid and pyrrolidonecarboxylic acid and one or more selected from these salts were used in combination with one or more antidandruff agents. The product showed an excellent antidandruff effect.

【0022】 実施例7 ヘアシャンプー (1)ラウロイルメチルタウリンナトリウム 10.0 (2)ラウリン酸ジエタノールアミド 8.0 (3)エチレングリコール脂肪酸エステル 1.5 (4)乳酸ナトリウム 0.1 (5)トリクロロカルバニリド 0.1 (6)香料 0.3 (7)精製水 残余 常法により上記ふけ防止用ヘアシャンプーを製造した。
上記のふけ防止用ヘアシャンプーはふけ防止効果に優れ
たものであった。
Example 7 Hair Shampoo (1) Sodium lauroylmethyl taurine 10.0 (2) Diethanolamide lauric acid 8.0 (3) Ethylene glycol fatty acid ester 1.5 (4) Sodium lactate 0.1 (5) Trichloro Carbanilide 0.1 (6) Fragrance 0.3 (7) Purified water Residue The hair shampoo for dandruff prevention was produced by a conventional method.
The hair shampoo for preventing dandruff had excellent anti-dandruff effect.

【0023】 実施例8 ヘアシャンプー (1)ポリオキシエチレン(E.O.平均3モル付加) ラウリル硫酸ナトリウム 10.0 (2)ラウリン酸ジエタノールアミド 4.0 (3)エチレングリコール脂肪酸エステル 1.5 (4)乳酸ナトリウム 0.1 (5)トリクロサン 0.1 (6)香料 0.1 (7)精製水 残余 常法により上記ふけ防止用ヘアシャンプーを製造した。
上記のふけ防止用ヘアーシャンプーは、ふけ防止効果に
優れていた。
Example 8 Hair Shampoo (1) Polyoxyethylene (EO average 3 mol addition) Sodium lauryl sulfate 10.0 (2) Lauric acid diethanolamide 4.0 (3) Ethylene glycol fatty acid ester 1.5 (4) Sodium lactate 0.1 (5) Triclosan 0.1 (6) Fragrance 0.1 (7) Purified water Residue The hair shampoo for dandruff prevention was produced by a conventional method.
The hair shampoo for preventing dandruff was excellent in the effect of preventing dandruff.

【0024】 実施例10 ヘアリンス (1)ステアリルトリメチルアンモニウムクロライド 2.0 (2)ステアリルアルコール 1.0 (3)ジプロピレングリコール 5.0 (4)ポリオキシエチレン(E.O.平均60モル付加) 硬化ヒマシ油 0.5 (5)ピロリドンカルボン酸ナトリウム 0.1 (6)グリチルリチン酸ジカリウム 0.1 (7)香料 0.3 (8)精製水 残余 常法により上記ふけ防止用ヘアーリンスを製造した。上
記のふけ防止用ヘアーリンスはふけ防止効果に優れてい
た。
Example 10 Hair rinse (1) Stearyl trimethyl ammonium chloride 2.0 (2) Stearyl alcohol 1.0 (3) Dipropylene glycol 5.0 (4) Polyoxyethylene (EO average 60 mol addition) Hardened castor oil 0.5 (5) Sodium pyrrolidonecarboxylate 0.1 (6) Dipotassium glycyrrhizinate 0.1 (7) Perfume 0.3 (8) Purified water Residue The anti-dandruff hair rinse was produced by a conventional method. . The anti-dandruff hair rinse was excellent in the anti-dandruff effect.

【0025】[0025]

【発明の効果】本発明の頭髪化粧料は、ふけ防止効果に
優れた頭髪化粧料である。
The hair cosmetic composition of the present invention is a hair cosmetic composition having an excellent antidandruff effect.

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 乳酸及びピロリドンカルボン酸とこれら
の塩類の中から選ばれる一種もしくは二種以上と、ふけ
防止用薬剤の一種もしくは二種以上とを含有することを
特徴とする頭髪化粧料。
1. A hair cosmetic comprising one or more selected from lactic acid and pyrrolidonecarboxylic acid and salts thereof, and one or more anti-dandruff agents.
【請求項2】 ふけ防止用薬剤が、ジンクピリチオン、
トリクロサン、トリクロロカルバニリド、グリチルリチ
ン酸ジカリウム、グリチルリチン酸モノアンモニウム、
β−グリチルレチン酸、アラントイン、イオウ、ビオサ
ルファー・フリッド、イソプロピルメチルフェノール、
サリチル酸の中から選ばれる一種もしくは二種以上であ
ることを特徴とする請求項1に記載の頭髪化粧料。
2. The antidandruff agent is zinc pyrithione,
Triclosan, trichlorocarbanilide, dipotassium glycyrrhizinate, monoammonium glycyrrhizinate,
β-glycyrrhetinic acid, allantoin, sulfur, biosulfur frid, isopropylmethylphenol,
The hair cosmetic composition according to claim 1, which is one kind or two or more kinds selected from salicylic acid.
【請求項3】 乳酸及びピロリドンカルボン酸の塩類
が、カリウム塩、ナトリウム塩、リチウム塩、カルシウ
ム塩、マグネシウム塩のうちのいずれかであることを特
徴とする請求項1及び2に記載の頭髪化粧料。
3. The hair makeup according to claim 1, wherein the salts of lactic acid and pyrrolidonecarboxylic acid are any of potassium salt, sodium salt, lithium salt, calcium salt and magnesium salt. Fee.
【請求項4】 乳酸及びピロリドンカルボン酸とこれら
の塩類の中から選ばれる一種もしくは二種以上の含有量
が、頭髪化粧料全量中0.001〜5.0重量%である
ことを特徴とする請求項1ないし3に記載の頭髪化粧
料。
4. The content of one or more selected from lactic acid, pyrrolidonecarboxylic acid and salts thereof is 0.001 to 5.0% by weight based on the total amount of the hair cosmetic composition. The hair cosmetic composition according to claim 1.
【請求項5】 ふけ防止用薬剤の一種もしくは二種以上
の含有量が頭髪化粧料全量中0.0001〜5.0重量
%であることを特徴とする請求項1ないし4に記載の頭
髪化粧料。
5. The hair makeup according to claim 1, wherein the content of one or more anti-dandruff agents is 0.0001 to 5.0% by weight based on the total amount of the hair cosmetic composition. Fee.
JP33926893A 1993-12-03 1993-12-03 Hair cosmetic Pending JPH07157415A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33926893A JPH07157415A (en) 1993-12-03 1993-12-03 Hair cosmetic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33926893A JPH07157415A (en) 1993-12-03 1993-12-03 Hair cosmetic

Publications (1)

Publication Number Publication Date
JPH07157415A true JPH07157415A (en) 1995-06-20

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JP33926893A Pending JPH07157415A (en) 1993-12-03 1993-12-03 Hair cosmetic

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Cited By (13)

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US5540920A (en) * 1994-11-22 1996-07-30 Olin Corporation Synergistic biocide composition containing pyrithione plus an additive
WO1998002137A1 (en) * 1996-07-12 1998-01-22 Indústria e Comércio de Cosméticos Natura Ltda. Composition in gel form for skin oiliness balancing
US6436885B2 (en) 2000-01-20 2002-08-20 The Procter & Gamble Company Antimicrobial cleansing compositions containing 2-pyrrolidone-5-carboxylic acid
US6517849B1 (en) 1999-10-19 2003-02-11 The Procter & Gamble Company Tissue products containing antiviral agents which are mild to the skin
US6588964B1 (en) 2000-10-10 2003-07-08 The Procter & Gamble Company Fluid applicator
JP2005082506A (en) * 2003-09-05 2005-03-31 Kao Corp Isopropylmethylphenol glycoside
US7001594B1 (en) 2000-10-10 2006-02-21 The Procter & Gamble Company Scalp cosmetic compositions and corresponding methods of application to provide scalp moisturization and skin active benefits
JP2007254356A (en) * 2006-03-23 2007-10-04 Kao Corp Hair cosmetics
JP2007254355A (en) * 2006-03-23 2007-10-04 Kao Corp Hair cleaning composition
JP2008069082A (en) * 2006-09-12 2008-03-27 Mandom Corp Germicide composition and skin care preparation containing the germicide composition
JP2012176995A (en) * 2012-06-21 2012-09-13 Kao Corp Hair cosmetics
CN105616204A (en) * 2016-01-25 2016-06-01 柳州三农科技有限公司 Antidandruff and gentle shampoo
JP2017124996A (en) * 2016-01-15 2017-07-20 安井 敦司 Antibacterial and antiviral composition and lubricant comprising the same

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY115993A (en) * 1994-11-22 2003-10-31 Univ Connecticut Synergistic biocide composition containing pyrithione plus an additive
US5540920A (en) * 1994-11-22 1996-07-30 Olin Corporation Synergistic biocide composition containing pyrithione plus an additive
WO1998002137A1 (en) * 1996-07-12 1998-01-22 Indústria e Comércio de Cosméticos Natura Ltda. Composition in gel form for skin oiliness balancing
US6517849B1 (en) 1999-10-19 2003-02-11 The Procter & Gamble Company Tissue products containing antiviral agents which are mild to the skin
US6436885B2 (en) 2000-01-20 2002-08-20 The Procter & Gamble Company Antimicrobial cleansing compositions containing 2-pyrrolidone-5-carboxylic acid
US7001594B1 (en) 2000-10-10 2006-02-21 The Procter & Gamble Company Scalp cosmetic compositions and corresponding methods of application to provide scalp moisturization and skin active benefits
US6588964B1 (en) 2000-10-10 2003-07-08 The Procter & Gamble Company Fluid applicator
JP2005082506A (en) * 2003-09-05 2005-03-31 Kao Corp Isopropylmethylphenol glycoside
JP2007254356A (en) * 2006-03-23 2007-10-04 Kao Corp Hair cosmetics
JP2007254355A (en) * 2006-03-23 2007-10-04 Kao Corp Hair cleaning composition
EP1842572B1 (en) * 2006-03-23 2013-10-30 Kao Corporation Hair cleansing composition
JP2008069082A (en) * 2006-09-12 2008-03-27 Mandom Corp Germicide composition and skin care preparation containing the germicide composition
JP2012176995A (en) * 2012-06-21 2012-09-13 Kao Corp Hair cosmetics
JP2017124996A (en) * 2016-01-15 2017-07-20 安井 敦司 Antibacterial and antiviral composition and lubricant comprising the same
CN105616204A (en) * 2016-01-25 2016-06-01 柳州三农科技有限公司 Antidandruff and gentle shampoo

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