JPH07101884A - Prpearation containing water-soluble hemicellulose - Google Patents

Abstract

PURPOSE:To obtain a preparation capable of stably providing desirable flavor, color tone, taste, etc., to foods, medicines, cosmetics, pet foods, quasi-drugs, etc., for a long period. CONSTITUTION:This preparation is prepared by using a water-soluble hemicellulose as an emulsifier or a powdered substrate and using an organic acid.

Description

Detailed Description of the Invention

[0001]

FIELD OF THE INVENTION The present invention relates to a formulation containing water-soluble hemicellulose and a surfactant. The preparation of the present invention refers to an emulsified preparation and a powdered preparation, and is used for imparting a desirable flavor, color tone, flavor and the like to foods, pharmaceuticals, cosmetics, pet foods, quasi drugs and the like for a long period of time.

[0002]

2. Description of the Related Art Conventional emulsified preparations are prepared by emulsifying an oily substance such as essential oils, oil-soluble pigments, animal and vegetable oils and fats with a natural vegetable gum such as gum arabic or a nonionic surfactant. Things were being used. In addition, a powder formulation is prepared by mixing a formulation composition such as fats and oils or lipophilic or water-soluble flavors and pigments with natural gums such as gum arabic, dextrin and modified starch, emulsifying or dispersing them, and then spray-drying. Are known. In this case, natural gum arabic is widely used as an emulsifying agent or a powdering base material in the field of formulation because of its excellent emulsifying property, but natural gum substances are not suitable for production or production depending on the natural environment such as weather and temperature. The quality is not constant, there are problems such as high prices and variations in quality, and the film properties when powdered are not sufficiently stable.The flavor, color and flavor during spray drying and storage Was a problem. In addition, dextrin and modified starch are inferior to gum arabic in emulsifying property and film forming property, and when a nonionic surfactant is used, they are easily affected by pH and cancer-containing components of foods and drinks and pharmaceuticals used. There was a characteristic called. In recent years, water-soluble hemicellulose has been investigated as a substitute for the above substances, but this is also not sufficiently stable in terms of emulsifying property and film forming property.

[0003]

As described above, in the preparation, not only the emulsifying property in the manufacturing process but also the stability of the clathrate and the strength of the film are required. However, the present situation is not necessarily satisfactory, and the creation of a further improved formulation has been a problem in the art.

[0004]

[Means for Solving the Problems] In order to improve these drawbacks, the present inventors have earnestly studied a method of remarkably enhancing the emulsion stability and film strength of water-soluble hemicellulose, and as a result, the water-soluble hemicellulose was emulsified or When manufacturing a formulation used as a powdered base, by appropriately adding an organic acid, the emulsifying power and film strength of the water-soluble hemicellulose are significantly enhanced, and the heat resistance and retention of the perfume ingredients and the release delay of the perfume ingredients are delayed. We obtained the knowledge that a highly effective preparation can be provided. The present invention uses a water-soluble hemicellulose as an emulsifying agent or a powdering base during the production of a preparation, and
By adding an appropriate amount of organic acid, the emulsifiability and emulsion stability at the time of production are excellent, the stability of the clathrate after pulverization and the strength of the base film are enhanced, and the aroma that is stable for a long time in foods, etc. ,
It is intended to provide a preparation capable of imparting color tone, flavor and the like.

Examples of the oily substance used in the present invention include essential oils of citrus fruits such as orange, lime, lemon and grapefruit, essential oils of spices such as peppermint oil and perilla oil, oleoresin such as pepper, cinnamon and ginger, and jasmine. , Absolute such as rose, and oily flavoring agents such as synthetic perfume compounds, oily perfume compositions and any mixtures thereof, β-
Oil-soluble natural pigments such as carotene, paprika pigment, annatto pigment, and chlorophyll, and further fat-soluble vitamins such as liver oil, vitamin A, vitamin D, vitamin B2 butyrate, natural vitamin E mixture, soybean oil, rapeseed oil, corn oil , Animal and vegetable oils such as olive oil, palm oil, safflower oil, sunflower oil, rice oil, beef tallow, lard, fish oil,
Natural unsaturated fatty acids such as DHA, EPA, γ-linolenic acid, processed edible oils and fats such as sucrose diacetate hexaisobutyrate, medium chain saturated fatty acid triglyceride of C6 to C12, and any mixture of these edible oily materials. It can be illustrated. As a water-soluble substance,
Extracts such as coffee, herbs, matcha, black tea, guarana, bonito, shrimp, crab, sea urchin, scallop, etc.
Examples of essences such as strawberry, melon, banana, pineapple, apple, milk, cheese, butter, water-soluble pigments such as cochineal, safflower, beet, turmeric, other synthetic flavors, synthetic colorants, and any mixture thereof can do.

Examples of the water-soluble hemicellulose that can be used in the present invention include oil seeds (usually oils and fats such as soybean, palm, palm, corn, cottonseed, and shells excluding protein).
Alternatively, water-soluble dietary fiber made from plants such as cereals (rice, wheat and other normal starch-excluded starch), that is, arabinoxylan, arabinogalactan and other polysaccharides, or any mixture thereof may be used. it can. Such water-soluble hemicellulose is contained in the formulation in an amount of 0.1 to 98% by weight, preferably 5 to 50% by weight.

Organic acids usable in the present invention include citric acid, trisodium citrate, gluconic acid, succinic acid,
Sodium succinate, disodium succinate, sodium acetate, DL-tartaric acid, L-tartaric acid, DL-sodium tartrate, sodium L-tartrate, sodium lactate, calcium lactate, DL-malic acid, DL-sodium malate, fumaric acid Monosodium and any mixture thereof and the like. Such an organic acid is contained in the formulation in an amount of 0.01 to 10% by weight, preferably 0.05 to 5% by weight. As the emulsification method used in the present invention,
A colloid mill, a homomixer, a high-pressure homogenizer, an ultrasonic emulsifier, etc. may be used, and a powdering method may be any type of spray drying method. Hereinafter, the effects of the present invention will be described more specifically with reference to examples.

[0008]

【Example】

Example 1 3 g of β-carotene, 0.1 g of natural vitamin E and 8.5 g of medium chain saturated fatty acid triglyceride were dissolved to obtain a uniform oily material mixture. Separately, a solution obtained by dissolving 20 g of soybean hemicellulose and 0.3 g of DL-sodium malate in 69 g of water was added, and the whole amount of the above-mentioned oily material mixture was added and pre-stirred to disperse and then emulsified with a homogenizer,
A colorant emulsion (invention product No. 1) was obtained.

Example 2 85 g of soybean hemicellulose and 0.1 g of trisodium citrate were dissolved in 200 g of ion-exchanged water, and 20 g of coffee oil was added and mixed while maintaining the temperature at 50 ° C. This solution was emulsified with a high pressure homogenizer, and the emulsion was spray-dried to obtain 100 g of coffee flavor powder (Product No. 2 of the present invention).

Example 3 200 g of ion-exchanged water, 70 g of corn hemicellulose, 40 g of sucrose, and 0.1 g of sodium L-tartrate.
Is dissolved and 15 g of oil containing 12 g of menthol is added and mixed while maintaining at 50 ° C. This solution was emulsified with a high-pressure homogenizer and the emulsion was spray-dried to obtain 100 g of menthol flavor powder (Product No. 3 of the present invention).

Control Example 1 The same procedure as in Example 1 was carried out except that DL-sodium malate was not used and the weight shortage was supplemented with soybean hemicellulose.
o. 1) was obtained.

Control Example 2 A colorant emulsion (control product No. 2) was obtained under the same conditions as in Example 1 except that gum arabic was used instead of soybean hemicellulose in Example 1.

Control Example 3 Under the same conditions as in Example 2, except that gum arabic was used in place of soybean hemicellulose in Example 2, 100 g of mint flavor powder (control product No. 3) was obtained.

Control Example 4 100 g of mint flavor powder (control product No. 4) was obtained under the same conditions as in Example 2 except that modified starch was used in place of soybean hemicellulose.

Control Example 5 A mint oil emulsion (control product No. 5) was obtained under the same conditions as in Example 2 except that dextrin was used instead of soybean hemicellulose in Example 2.

Control Example 6 100 g of mint flavor powder (control product No. 6) was used under the same conditions as in Example 2 except that trisodium citrate was not used and the weight shortage was supplemented with soybean hemicellulose. Obtained.

Control Example 7 100 g of menthol flavor powder (control product No. 7) was obtained under the same conditions as in Example 3 except that gum arabic was used instead of corn hemicellulose.

Control Example 8 100 g of menthol flavor powder was prepared under the same conditions as in Example 3, except that L-sodium tartrate was not used in Example 3 and the weight shortage was supplemented with corn hemicellulose.
(Control product No. 8) was obtained.

Comparative Experiment 1 Coloring agent emulsions of Example 1 and Comparative Examples 1 and 2 were prepared on the same day, and laser diffraction particle size distribution analyzer SALD-
The particle size distribution was measured using 1100 (Shimadzu Corporation). Simultaneously, 10 g of skim milk powder was dissolved in 844 g of water, and 140 g of granulated sugar, 5 g of 10% lactic acid aqueous solution, and 1 g of the colorant emulsion obtained in Example 1 and Control Example 1 and Control Example 2 were uniformly added to the solution. Mixed in. After filling the bottle, the bottle was stoppered and sterilized at 85 ° C. for 20 minutes to obtain a colored acidic milk drink.
This was left to stand at room temperature and the change with time was observed. The results are shown in Table 1.
Shown in.

[0020]

[Table 1]

Each symbol in the table has the following meaning. -R: No neck ring is observed. ± R: Neck ring is slightly recognized. + R: A clear neck ring is recognized. R: Remarkable neck ring is recognized. -P: No precipitation is observed. ± P: Slight precipitation is observed. + P: A clear precipitate is observed. P: Remarkable precipitation is recognized.

As is clear from the results shown in Table 1, the product N of the present invention
o. No. 1 is the control product No. 1 and the control product No. The emulsifying power of the water-soluble hemicellulose was much higher than that of Comparative Example No. 2. It showed a slightly higher emulsifying power than 2 (gum arabic). Moreover, when the colored acidic milk drink was allowed to stand at room temperature for about 30 days, the control product No. No precipitation occurred in No. 1, but
Acknowledged the occurrence of neck ring and lost the commercial value. Control product No. In No. 2, no neck ring was observed, but significant precipitation occurred. On the other hand, the product No. of the present invention.
In No. 1, neither coloring nor precipitation was observed, and the colored acidic milk drink was stable.

Comparative Experiment 2 The coffee flavor powders obtained in Example 2 and Comparative Examples 3 to 6 were stored at 40 ° C., and changes with time were observed. In addition, the emulsifying property when the coffee oil was emulsified was also evaluated. The results are shown in Table 2.

[0024]

[Table 2]

Each symbol in the table has the following meaning. ◎: Very good ○: Good △: Somewhat bad ×:
Poor −: Not Evaluable As is clear from the results of Table 2, the product No. of the present invention. No. 2 had good emulsifiability, the strength of the base film was excellent even after 6 months of storage, and there was no loss of flavor, while the control product No. In No. 3, the emulsifiability was slightly inferior, and the strength and flavor of the base film decreased with time. The tendency is that the reference product No. 6,
Control product No. It becomes remarkable in the order of 4. The reference product No. 5
I couldn't emulsify.

Comparative Experiment 3 The menthol flavor powders of Example 3 and Comparative Examples 7 to 8 were placed in a sealed container, stored at 40 ° C. and then opened, and the menthol content was measured by gas chromatography.

[0027]

[Table 3]

As is clear from the results of Table 3, the product N of the present invention
o. The menthol content of the sample No. 3 did not decrease even after storage for 6 months, whereas the control sample No. 3 did not. 7 and the control product No. In No. 8, the content of menthol decreased with time and the loss of clathrate was observed.

Comparative Experiment 4 The coffee powder flavor (obtained from the present invention No. 2) obtained in Example 2 and the control examples 3 and 4 were added to the chewing gum base material shown below.
Coffee powder flavor obtained in 6 (control products No. 3, 4,
6) is added, kneaded and pressure-formed, and 3 g per sheet
To obtain a coffee-flavored chewing gum. The chewing gum base composition is shown in Table 4.

[0030]

[Table 4]

The chewing gums were subjected to a sensory evaluation by 10 expert panelists. As a result, the product of the present invention showed no significant difference in flavor intensity as compared with the control example, but was remarkably excellent in persistence and persistence. It was determined that

[0032]

As is clear from the results of the examples, the preparations obtained according to the present invention have extremely good emulsification properties and emulsion stability in the manufacturing process, and even when powdered, the formulation after powderization The stability of the adherend and the strength of the film are particularly excellent, and it has a long-lasting and desirable flavor for various foods, pharmaceuticals, etc.
Since it is possible to impart color tone, flavor, etc., its industrial significance is extremely great.

Claims (2)

[Claims] 1. A formulation comprising water-soluble hemicellulose and an organic acid. 2. The water-soluble hemicellulose is a polysaccharide derived from soybean, corn or rice bran.
The described formulation.