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JPH06264175A - Steel sheet excellent in dent resistance, surface distortion resistance, and workability and its production - Google Patents

Steel sheet excellent in dent resistance, surface distortion resistance, and workability and its production

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Publication number
JPH06264175A
JPH06264175A JP7287593A JP7287593A JPH06264175A JP H06264175 A JPH06264175 A JP H06264175A JP 7287593 A JP7287593 A JP 7287593A JP 7287593 A JP7287593 A JP 7287593A JP H06264175 A JPH06264175 A JP H06264175A
Authority
JP
Japan
Prior art keywords
less
steel
layer
steel sheet
workability
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP7287593A
Other languages
Japanese (ja)
Inventor
Nobuhiko Matsuzu
伸彦 松津
Hirohide Asano
裕秀 浅野
Makoto Tefun
誠 手墳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP7287593A priority Critical patent/JPH06264175A/en
Publication of JPH06264175A publication Critical patent/JPH06264175A/en
Withdrawn legal-status Critical Current

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  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

(57)【要約】 【目的】 本発明は主にプレス加工される自動車部品等
に使用される耐デント性と耐面ひずみ性および加工性に
優れた鋼板とその製造方法を提供する。 【構成】 Ti、Nbの内1種以上を含有し、さらに
C、Si、Mn、P、S、Al、N量を規制した2種の
溶鋼A、BがA、B、Aの順で複層構造をなし、かつ表
層側から連続して凝固し、1〜10%の遷移層を有する
鋳片あるいは鋼塊を素材として、Ar3 −50℃以上で
熱延し、その後冷延し、再結晶温度以上で焼鈍すること
により、強度30kgf/mm2 以上で耐デント性と耐
面ひずみ性および加工性に優れたクラッド鋼板を得る。
尚、内層にBを所定量添加しても良い。
(57) [Summary] [Object] The present invention provides a steel sheet having excellent dent resistance, surface strain resistance, and workability, which is mainly used for automobile parts to be pressed, and a manufacturing method thereof. [Structure] Two kinds of molten steels A and B containing at least one of Ti and Nb and further regulated the amounts of C, Si, Mn, P, S, Al and N are mixed in the order of A, B and A. A slab or steel ingot having a layered structure and continuously solidifying from the surface side and having a transition layer of 1 to 10% is used as a material, hot rolled at Ar 3 -50 ° C or higher, then cold rolled, and re-rolled. By annealing at a crystallization temperature or higher, a clad steel plate having a strength of 30 kgf / mm 2 or higher and excellent in dent resistance, surface strain resistance and workability is obtained.
A predetermined amount of B may be added to the inner layer.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、主としてプレス加工さ
れる自動車部品等を対象とし、30kgf/mm2 以上
の引張強度を有し、耐デント性と耐面歪性及び加工性に
優れた鋼板とその製造方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is mainly applied to press-processed automobile parts, etc., and has a tensile strength of 30 kgf / mm 2 or more, and is excellent in dent resistance, surface strain resistance and workability. And its manufacturing method.

【0002】[0002]

【従来の技術】近年、自動車の軽量化や安全性向上の観
点から、鋼板の高強度化が要求されている。特に自動車
外板パネル類では耐デント性が要求されることから、外
板パネル用鋼板の高強度化の要請が強い。しかし、高強
度化は成形性の低下を伴い、特に外板の高強度化におい
ては降伏強度の上昇による面歪の発生という問題が生ず
る。このような問題点を克服するため、加工時は比較的
低降伏強度であるが、塗装焼き付け後に降伏強度が上昇
する、いわゆるBH鋼板が開発されてきた。例えば、極
低炭素鋼にTi、Nb等を添加し、固溶C量を制限した
り(特開昭59−38337号、特開昭59−3182
7号公報)、NとS量を調整し、析出物の生成を制御す
る方法(特開昭61−26757号、特開昭62−78
22号公報)等が知られているが、これらの鋼板では耐
面歪性には優れるが、耐デント性は十分ではない。耐デ
ント性を確保すべく高強度BH鋼板が開発されてきた
が、成形性が厳しい部材への適用が困難であったり、面
歪の発生により適用が限られているのが実情である。
2. Description of the Related Art In recent years, steel sheets have been required to have high strength from the viewpoint of weight reduction and safety improvement of automobiles. In particular, since automobile outer panel panels are required to have dent resistance, there is a strong demand for higher strength steel sheets for outer panel. However, the increase in strength is accompanied by a decrease in formability, and particularly in the case of increasing the strength of the outer plate, there arises a problem that surface strain occurs due to an increase in yield strength. In order to overcome such problems, so-called BH steel sheets have been developed, which have a relatively low yield strength during processing, but increase the yield strength after coating baking. For example, Ti, Nb, etc. may be added to ultra-low carbon steel to limit the amount of solute C (Japanese Patent Laid-Open No. 59-38337 and Japanese Patent Laid-Open No. 59-3182).
No. 7), a method of controlling the formation of precipitates by adjusting the amounts of N and S (JP-A 61-26757 and JP-A 62-78).
No. 22) is known, but these steel sheets are excellent in surface strain resistance, but insufficient in dent resistance. Although high-strength BH steel sheets have been developed to secure dent resistance, it is difficult to apply them to members having severe formability, or the application is limited due to occurrence of surface strain.

【0003】本発明は表層(両面)を高強度とし、内層
を軟質とした、いわゆる鋳込みクラッド鋼板にて耐デン
ト性の確保と耐面歪性・加工性確保という課題を解決す
るものである。
The present invention solves the problems of ensuring dent resistance and surface strain resistance / workability with a so-called cast clad steel plate having a surface layer (both sides) having high strength and an inner layer having softness.

【0004】クラッド鋼板にて耐デント性の確保と耐面
歪性・加工性確保の両立を試みたものとして特開平3−
133630号公報記載の技術があるが、鋳造方法につ
いては検討されていない。クラッド鋼の圧延においては
異種成分鋼の境界で割れや剥離が生じる場合がある。
又、製造後のユーザーでの加工時にやはり異種成分鋼の
境界で割れや剥離が生じる場合がある。鋼板の安定製造
と加工性の安定化のためには適切な鋳造方法が必要であ
る。
Japanese Unexamined Patent Publication No. HEI 3-Claims has attempted to secure both dent resistance and surface distortion resistance / workability with a clad steel plate.
There is a technique described in Japanese Patent No. 133630, but a casting method has not been studied. During rolling of clad steel, cracks and peeling may occur at the boundaries of dissimilar steels.
In addition, cracking or peeling may occur at the boundary between dissimilar steels during processing by the user after manufacturing. Appropriate casting method is necessary for stable production of steel sheet and stabilization of workability.

【0005】[0005]

【発明が解決しようとする課題】本発明は、表層の高強
度鋼と内層の軟質鋼からなり、遷移層を有する鋳込みク
ラッド鋼板にて、通常の鋼板では達成困難である耐デン
ト性と耐面歪性・加工性を両立させた鋼板とその製造方
法の提供にある。
DISCLOSURE OF THE INVENTION The present invention is a cast clad steel sheet comprising a high-strength steel for the surface layer and a soft steel for the inner layer and having a transition layer, which is difficult to achieve with ordinary steel sheets. The purpose of the present invention is to provide a steel sheet having both strainability and workability, and a manufacturing method thereof.

【0006】[0006]

【課題を解決するための手段】本発明はこのような課題
に対して、特定の表層及び内層の成分とし、鋳込みによ
って所定の遷移層を有するクラッド鋳片もしくはクラッ
ド鋼塊を素材として、熱間及び冷間圧延し、これに特定
の焼鈍を施すことで解決しようとするもので、その趣旨
とするところは、以下の通りである。
In order to solve the above problems, the present invention uses, as a raw material, a clad slab or a clad steel ingot which has a specific surface layer and an inner layer component and has a predetermined transition layer by casting. The present invention aims to solve the problem by cold rolling and subjecting it to specific annealing, and the gist thereof is as follows.

【0007】(1)2種の成分系A、Bの鋼がA、B、
Aの順で複層構造を成している鋼板において、表層に位
置する鋼Aの成分が質量割合で C :0.05〜0.2% Si:3.0%以下 Mn:0.5〜3% P :0.1%以下 S :0.02%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.02〜0.2% Nb:0.01〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、内層に位置する鋼Bの成分が質量割合で C :0.01%以下 Si:0.5%以下 Mn:0.5%以下 P :0.1%以下 S :0.03%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.006〜0.2% Nb:0.003〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、A層とB層との境界部に鋼板板厚の1〜1
0%の厚さの遷移層を有することを特徴とする耐デント
性と耐面歪性及び加工性に優れた冷延鋼板である。
(1) Steels of two kinds of component systems A and B are A, B,
In a steel sheet having a multilayer structure in the order of A, the components of the steel A located in the surface layer are C: 0.05 to 0.2% Si: 3.0% or less Mn: 0.5 to 3% P: 0.1% or less S: 0.02% or less Al: 0.1% or less N: 0.01% or less and Ti: 0.02 to 0.2% Nb: 0.01 to 0.1 %, Containing at least one of Fe and unavoidable impurities, and the composition of steel B located in the inner layer being C: 0.01% or less Si: 0.5% or less Mn: 0.5 % Or less P: 0.1% or less S: 0.03% or less Al: 0.1% or less N: 0.01% or less and Ti: 0.006 to 0.2% Nb: 0.003 to 0.1 % Of at least 1%, and the balance is Fe and unavoidable impurities, and the steel plate thickness is 1 to 1 at the boundary between the A layer and the B layer.
A cold-rolled steel sheet excellent in dent resistance, surface strain resistance, and workability, which is characterized by having a transition layer having a thickness of 0%.

【0008】(2)2種の成分系A、Bの鋼がA、B、
Aの順で複層構造を成している鋼板において、表層に位
置する鋼Aの成分が質量割合で C :0.05〜0.2% Si:3.0%以下 Mn:0.5〜3% P :0.1%以下 S :0.02%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.02〜0.2% Nb:0.01〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、内層に位置する鋼Bの成分が質量割合で C :0.01%以下 Si:0.5%以下 Mn:0.5%以下 P :0.1%以下 S :0.03%以下 Al:0.1%以下 N :0.01%以下 B :0.0001〜0.002% かつ Ti:0.006〜0.2% Nb:0.003〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、A層とB層との境界部に鋼板板厚の1〜1
0%の厚さの遷移層を有することを特徴とする耐デント
性と耐面歪性及び加工性に優れた冷延鋼板である。
(2) Two types of component systems A and B steels are A, B,
In a steel sheet having a multilayer structure in the order of A, the components of the steel A located in the surface layer are C: 0.05 to 0.2% Si: 3.0% or less Mn: 0.5 to 3% P: 0.1% or less S: 0.02% or less Al: 0.1% or less N: 0.01% or less and Ti: 0.02 to 0.2% Nb: 0.01 to 0.1 %, Containing at least one of Fe and unavoidable impurities, and the composition of steel B located in the inner layer being C: 0.01% or less Si: 0.5% or less Mn: 0.5 % Or less P: 0.1% or less S: 0.03% or less Al: 0.1% or less N: 0.01% or less B: 0.0001 to 0.002% and Ti: 0.006 to 0.2 % Nb: 0.003 to 0.1% of at least one of them, and the balance Fe and unavoidable impurities, and the boundary between the A layer and the B layer. Parts to the steel plate thickness 1 to 1
A cold-rolled steel sheet excellent in dent resistance, surface strain resistance, and workability, which is characterized by having a transition layer having a thickness of 0%.

【0009】(3)上記(1)項に記載の鋼板の片面若
しくは両面に電気めっきを施した耐デント性と耐面歪性
及び加工性に優れた電気めっき鋼板である。
(3) An electroplated steel sheet excellent in dent resistance, surface strain resistance and workability obtained by electroplating one or both surfaces of the steel sheet described in (1) above.

【0010】(4)上記(2)項に記載の鋼板の片面若
しくは両面に電気めっきを施した耐デント性と耐面歪性
及び加工性に優れた電気めっき鋼板である。
(4) An electroplated steel sheet excellent in dent resistance, surface strain resistance, and workability obtained by electroplating one or both surfaces of the steel sheet described in (2) above.

【0011】(5)2種の成分系A、Bの鋼がA、B、
Aの順で複層構造を成している鋼板の製造において、表
層に位置する鋼Aの成分が質量割合で C :0.05〜0.2% Si:3.0%以下 Mn:0.5〜3% P :0.1%以下 S :0.02%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.02〜0.2% Nb:0.01〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、内層に位置する鋼Bの成分が質量割合で C :0.01%以下 Si:0.5%以下 Mn:0.5%以下 P :0.1%以下 S :0.03%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.006〜0.2% Nb:0.003〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、これらの溶鋼において、まずAの鋼が表側
から凝固を開始し、これが凝固を終了する部位におい
て、引き続いてBの鋼が凝固を開始して、結果形成され
たA、B両層が成分分析の点から巨視的に分離されてお
り、かつA層とB層との境界部において鋳片厚の1〜1
0%の厚さの遷移層を形成させた鋳片あるいは鋼塊を素
材として、熱間圧延するに際し、再加熱する場合は11
80℃以上に加熱した後に圧延し、再加熱しない場合は
1050℃以上で圧延を開始し、Ar3 −50℃以上で
熱延を終了し、酸洗、冷延後、再結晶温度以上で焼鈍す
ることを特徴とする耐デント性と耐面歪性及び加工性に
優れた鋼板の製造方法である。
(5) Steels of two kinds of composition systems A and B are A, B,
In the production of a steel sheet having a multilayer structure in the order of A, the components of the steel A located in the surface layer are C: 0.05 to 0.2% Si: 3.0% or less by mass ratio Mn: 0. 5 to 3% P: 0.1% or less S: 0.02% or less Al: 0.1% or less N: 0.01% or less and Ti: 0.02 to 0.2% Nb: 0.01 to 0 The content of steel B contained in the inner layer is 1% or more, and the balance is Fe and unavoidable impurities. The components of steel B located in the inner layer are C: 0.01% or less Si: 0.5% or less Mn: 0. 0.5% or less P: 0.1% or less S: 0.03% or less Al: 0.1% or less N: 0.01% or less and Ti: 0.006 to 0.2% Nb: 0.003 to 0 1% of 1% or more, and the balance Fe and unavoidable impurities. Among these molten steels, the steel of A is first from the front side. At the point where solidification is started and this ends solidification, the steel of B subsequently begins to solidify, and the two layers A and B formed as a result are macroscopically separated from the point of component analysis, and A 1 to 1 of the slab thickness at the boundary between the B layer and the B layer
When using a slab or steel ingot having a 0% thick transition layer formed as a raw material, it is 11 when reheating during hot rolling.
Roll after heating to 80 ° C or higher, and if not reheated, start rolling at 1050 ° C or higher, finish hot rolling at Ar 3 -50 ° C or higher, and after pickling, cold rolling, anneal at recrystallization temperature or higher. Is a method for producing a steel sheet having excellent dent resistance, surface strain resistance, and workability.

【0012】(6)2種の成分系A、Bの鋼がA、B、
Aの順で複層構造を成している鋼板の製造において、表
層に位置する鋼Aの成分が質量割合で C :0.05〜0.2% Si:3.0%以下 Mn:0.5〜3% P :0.1%以下 S :0.02%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.002〜0.2% Nb:0.003〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、内層に位置する鋼Bの成分が質量割合で C :0.01%以下 Si:0.5%以下 Mn:0.5%以下 P :0.1%以下 S :0.03%以下 Al:0.1%以下 N :0.01%以下 B :0.0001〜0.002% かつ Ti:0.006〜0.2% Nb:0.003〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、これらの溶鋼において、まずAの鋼が表側
から凝固を開始し、これが凝固を終了する部位におい
て、引き続いてBの鋼が凝固を開始して、結果形成され
たA、B両層が成分分析の点から巨視的に分離されてお
り、かつA層とB層との境界部において鋳片厚の1〜1
0%の厚さの遷移層を形成させた鋳片あるいは鋼塊を素
材として、熱間圧延するに際し、再加熱する場合は11
80℃以上に加熱した後に圧延し、再加熱しない場合は
1050℃以上で圧延を開始し、Ar3 −50℃以上で
熱延を終了し、酸洗、冷延後、再結晶温度以上で焼鈍す
ることを特徴とする耐デント性と耐面歪性及び加工性に
優れた鋼板の製造方法である。
(6) Steels of two kinds of composition systems A and B are A, B,
In the production of a steel sheet having a multilayer structure in the order of A, the components of the steel A located in the surface layer are C: 0.05 to 0.2% Si: 3.0% or less by mass ratio Mn: 0. 5-3% P: 0.1% or less S: 0.02% or less Al: 0.1% or less N: 0.01% or less and Ti: 0.002-0.2% Nb: 0.003-0 The content of steel B contained in the inner layer is 1% or more, and the balance is Fe and unavoidable impurities. The components of steel B located in the inner layer are C: 0.01% or less Si: 0.5% or less Mn: 0. 0.5% or less P: 0.1% or less S: 0.03% or less Al: 0.1% or less N: 0.01% or less B: 0.0001 to 0.002% and Ti: 0.006 to 0 0.2% Nb: 0.003 to 0.1%, containing at least one kind, and the balance Fe and unavoidable impurities. In molten steel, first, the steel of A starts to solidify from the front side, and at the point where it finishes solidification, the steel of B subsequently starts to solidify, and both layers A and B formed as a result are analyzed from the viewpoint of component analysis. It is macroscopically separated and has a slab thickness of 1 to 1 at the boundary between the A layer and the B layer.
When using a slab or steel ingot having a 0% thick transition layer formed as a raw material, it is 11 when reheating during hot rolling.
Roll after heating to 80 ° C or higher, and if not reheated, start rolling at 1050 ° C or higher, finish hot rolling at Ar 3 -50 ° C or higher, and after pickling, cold rolling, anneal at recrystallization temperature or higher. Is a method for producing a steel sheet having excellent dent resistance, surface strain resistance and workability.

【0013】(7)上記(5)項に記載の方法におい
て、得られた鋼板の片面若しくは両面に電気めっきを施
すことを特徴とする耐デント性と耐面歪性及び加工性に
優れた鋼板の製造方法である。
(7) In the method described in (5) above, a steel sheet having excellent dent resistance, surface strain resistance and workability, characterized in that one or both surfaces of the obtained steel sheet are electroplated. Is a manufacturing method.

【0014】(8)上記(6)項に記載の方法におい
て、得られた鋼板の片面若しくは両面に電気めっきを施
すことを特徴とする耐デント性と耐面歪性及び加工性に
優れた鋼板の製造方法である。
(8) In the method described in the above item (6), a steel sheet having excellent dent resistance, surface strain resistance and workability, characterized in that one or both surfaces of the obtained steel sheet are electroplated. Is a manufacturing method.

【0015】[0015]

【作用】耐デント性には表面の強度が強く影響すること
から、表層部は高度強化する必要がある。一方、内層ま
で高強度化するとプレス時に面歪が生じやすくなり、
又、加工性も劣化するため、内層は軟質にする必要があ
る。こうすることによって耐デント性と耐面歪性・加工
性を両立させることが可能となる。
[Function] Since the strength of the surface has a strong influence on the dent resistance, it is necessary to highly strengthen the surface layer portion. On the other hand, if the strength is increased to the inner layer, surface strain tends to occur during pressing,
Further, since the workability is deteriorated, the inner layer needs to be soft. This makes it possible to achieve both dent resistance and surface distortion resistance / workability.

【0016】次に本発明の各構成要件の限定理由につい
て詳述する。
Next, the reasons for limiting the respective constituents of the present invention will be described in detail.

【0017】まず、表層に位置するA鋼の化学成分の限
定理由について詳述する。
First, the reasons for limiting the chemical composition of the steel A located on the surface will be described in detail.

【0018】C:Cは強化元素の一つであり、0.2%
をこえるとスポット溶接性が劣化するため、Cの上限は
0.2%とする。更に、本発明ではTiC、Nb(C、
N)等の生成による析出強化と組織の細粒化を強化手段
として利用する。この意味から、Cは最低0.05%は
必要である。
C: C is one of the strengthening elements, and is 0.2%.
%, The spot weldability deteriorates, so the upper limit of C is made 0.2%. Furthermore, in the present invention, TiC, Nb (C,
N) or the like is used as a strengthening means by precipitation strengthening and grain refinement of the structure. From this meaning, C must be at least 0.05%.

【0019】Si:Siは強化元素であるので、表層部
の強度確保のために添加してもよいが、過大な添加は加
工性・溶接性の劣化を招くため上限を3%とする。望ま
しい上限は2%である。下限値は特に規定するところで
はなく、0.005%まで下げても構わない。
Si: Si is a strengthening element, so Si may be added to secure the strength of the surface layer portion, but an excessive addition causes deterioration of workability and weldability, so the upper limit is made 3%. A desirable upper limit is 2%. The lower limit is not particularly specified and may be lowered to 0.005%.

【0020】Mn:Siと同じくMnは強化元素であ
り、強度確保の意味合いから下限を0.5%とする。上
限は加工性・溶接性の観点から3%とする。
Mn: Mn is a strengthening element like Si, and the lower limit is 0.5% from the viewpoint of ensuring strength. The upper limit is 3% from the viewpoint of workability and weldability.

【0021】P:Pは強化元素であるので、表層部の強
度確保のために添加してもよいが、2次加工性や溶接性
を阻害するので、上限を0.1%とする。下限値は規定
するところではなく、0.001%程度まで下げても構
わない。
P: Since P is a strengthening element, it may be added to secure the strength of the surface layer portion, but it impairs secondary workability and weldability, so the upper limit is made 0.1%. The lower limit is not specified and may be lowered to about 0.001%.

【0022】S:Sは加工性・溶接性を劣化させ、熱間
割れを助長するため低いほど良く、上限を0.02%と
する。
S: S deteriorates workability and weldability and promotes hot cracking, so the lower the better, the upper limit is 0.02%.

【0023】Al:Alは、脱酸剤として用いる。Al
が多すぎるとアルミナ系介在物が増加し、鋼の加工性を
劣化させるので上限を0.1%とした。本鋼では脱酸剤
としてSiやTiを利用しても本発明の主旨には反しな
いので、Alの下限値は特に規定する必要はない。望ま
しい範囲としては0.002〜0.1%である。
Al: Al is used as a deoxidizing agent. Al
If the content is too large, alumina-based inclusions increase and the workability of the steel deteriorates, so the upper limit was made 0.1%. In the present steel, even if Si or Ti is used as a deoxidizing agent, it does not violate the gist of the present invention, so the lower limit of Al does not need to be specified. A desirable range is 0.002 to 0.1%.

【0024】N:Nは加工性の観点から0.01%以下
とする。
N: N is 0.01% or less from the viewpoint of workability.

【0025】本発明では、表面の強度確保のために析出
強化元素を添加する。このために0.02%〜0.2%
のTiないし0.01〜0.1%のNbのうち1種以上
を添加する。下限値未満では析出強化が不十分である。
上限値を超える添加は加工性を劣化させ、また経済的で
ない。
In the present invention, a precipitation strengthening element is added to secure the surface strength. Because of this 0.02% to 0.2%
One or more of Ti to 0.01 to 0.1% Nb are added. If it is less than the lower limit, precipitation strengthening is insufficient.
Addition exceeding the upper limit deteriorates workability and is not economical.

【0026】尚、Ca、REM、Crの添加は本発明の
必須条件ではないが、Ca、REMは介在物の球状化、
即ち加工性への介在物の悪影響の低減に寄与し、Crは
焼鈍中のC汚れ防止に寄与するので、選択的に添加する
ことは本発明の主旨に反しない。しかし、これらの元素
の添加は製造コストの上昇を招くため、これらの元素の
合計添加量の上限は0.5%とする。
Although addition of Ca, REM and Cr is not an essential condition of the present invention, Ca and REM are spheroidized inclusions,
That is, since it contributes to the reduction of the adverse effects of inclusions on workability and Cr contributes to the prevention of C contamination during annealing, the selective addition is not against the gist of the present invention. However, the addition of these elements causes an increase in manufacturing cost, so the upper limit of the total addition amount of these elements is 0.5%.

【0027】次に内層に位置するB鋼の化学成分の限定
理由について詳述する。加工性と耐面歪性を確保するた
め、内層は基本的に軟質とする必要がある。
Next, the reasons for limiting the chemical composition of the B steel located in the inner layer will be described in detail. In order to secure workability and surface strain resistance, the inner layer must basically be soft.

【0028】C、N:C、Nは強化元素であると共に、
侵入型固溶元素でr値向上に寄与する集合組織の形成を
阻害する。従って、極力低減させる必要がある。そのた
め、0.01%を上限とする。
C, N: C and N are strengthening elements, and
It is an interstitial solid solution element and inhibits the formation of texture that contributes to the improvement of the r value. Therefore, it is necessary to reduce it as much as possible. Therefore, the upper limit is 0.01%.

【0029】Si:Siも強化元素であり、加工性を劣
化させるので上限を0.5%とする。下限は特に規定す
る必要はなく、0.005%程度まで低くても良い。
Si: Si is also a strengthening element and deteriorates workability, so the upper limit is made 0.5%. The lower limit need not be specified in particular, and may be as low as about 0.005%.

【0030】Mn:C、Siと同様に加工性を劣化させ
るので上限を0.5%とする。尚、Mnの極端な低減は
熱間割れを助長するとともに経済的でないため、Mnは
0.05%以上とすることが望ましい。
Since Mn: C and Si deteriorate workability similarly to Si, the upper limit is made 0.5%. In addition, since extreme reduction of Mn promotes hot cracking and is not economical, Mn is preferably set to 0.05% or more.

【0031】P:強化元素であるとともに、中心偏析を
助長し、溶接性を低下させる作用があるため上限を0.
1%とする。望ましくは0.06%以下とする。下限値
は特に規定するところではなく、0.001%程度まで
下げても構わない。
P: As an strengthening element, it promotes central segregation and has the effect of lowering weldability, so the upper limit is set to 0.
1% It is preferably 0.06% or less. The lower limit is not particularly specified and may be lowered to about 0.001%.

【0032】S:A系介在物を増加させ、加工性を劣化
させる。又、熱間割れを助長するので、上限を0.03
%とする。望ましくは0.02%以下とする。
S: Increases A-type inclusions and deteriorates workability. Also, since it promotes hot cracking, the upper limit is 0.03.
%. It is preferably 0.02% or less.

【0033】Al:Alは、脱酸剤として用いる。Al
が多すぎるとアルミナ系介在物が増加し、鋼の加工性を
劣化させるので上限を0.1%とした。本鋼では脱酸剤
としてSiやTiを利用しても本発明の主旨には反しな
いので、Alの下限値は特に規定する必要はない。望ま
しい範囲としては0.001〜0.1%である。
Al: Al is used as a deoxidizing agent. Al
If the content is too large, alumina-based inclusions increase and the workability of the steel deteriorates, so the upper limit was made 0.1%. In the present steel, even if Si or Ti is used as a deoxidizing agent, it does not violate the gist of the present invention, so the lower limit of Al does not need to be specified. A desirable range is 0.001 to 0.1%.

【0034】更に本鋼ではTi0.006〜0.2%、
Nb0.003〜0.1%のうち1種以上を含有させる
必要がある。
Further, in the present steel, Ti 0.006 to 0.2%,
It is necessary to contain one or more of Nb 0.003 to 0.1%.

【0035】Ti、NbはN、Cを固定し、固溶C、N
の悪影響を防止する。下限未満ではこれらの効果がな
く、上限を超える添加は不純物としての悪影響が大きく
なり、加工性が劣化する。望ましくは、数1 式とす
る。
Ti and Nb fix N and C to form solid solution C and N
Prevent the adverse effects of. If the amount is less than the lower limit, these effects are not exhibited, and if the amount exceeds the upper limit, adverse effects as impurities become large and the workability deteriorates. Desirably, the formula 1 is used.

【0036】[0036]

【数1】C(%)/12+N(%)/14≦Ti(%)
/48+Nb(%)/93+Al(%)/27
[Formula 1] C (%) / 12 + N (%) / 14 ≦ Ti (%)
/ 48 + Nb (%) / 93 + Al (%) / 27

【0037】B:2次加工性の向上のためにBを0.0
001〜0.002%添加しても良い。下限未満ではそ
の効果はなく、上限を超えると再結晶温度を上昇させ、
加工性が劣化する。
B: B is 0.0 to improve secondary workability.
You may add 001-0.002%. Below the lower limit, there is no effect, and above the upper limit, the recrystallization temperature rises,
Workability deteriorates.

【0038】本鋼はこのような表層A鋼と内層B鋼を持
つ鋳片あるいは鋼塊を素材に熱延・冷延されるが、圧延
時にA、B鋼の境界において剥離や割れが発生せず、均
一に塑性変形することが必要である。そのためには、鋳
片あるいは鋼塊を鋳造する際、遷移層を有することが必
要である。遷移層とはA層とB層の境界部に形成される
層であって、A層とB層の鋼成分が混合している領域を
いう。鋳造時に形成された遷移層は圧延・焼鈍後も保持
される。0.75mm厚の製品の遷移層付近における成
分変化を図1に例示する。遷移層では図1のように成分
が連続的に変化し、組織もこの成分変化に準じて変化す
る。
This steel is hot-rolled or cold-rolled from a slab or ingot having such surface A steel and inner layer B steel as a raw material, but peeling or cracking occurs at the boundary between the A and B steels during rolling. Instead, it is necessary to perform uniform plastic deformation. For that purpose, it is necessary to have a transition layer when casting a slab or a steel ingot. The transition layer is a layer formed at the boundary between the A layer and the B layer, and is a region where the steel components of the A layer and the B layer are mixed. The transition layer formed during casting is retained even after rolling and annealing. FIG. 1 exemplifies the change in composition near the transition layer of a 0.75 mm thick product. In the transition layer, the components continuously change as shown in FIG. 1, and the structure also changes in accordance with this component change.

【0039】この遷移層は、鋳込み法にて、まずAの鋼
が表側から凝固を開始し、これが凝固を終了する部位に
おいて、引き続いてBの鋼が凝固を開始することにより
得られる。然して、遷移層を挟んだA、B層は大きく混
ざりあうことなく連続して凝固し、成分分析の点から巨
視的に分離されていることが必要である。
This transition layer is obtained by the casting method in which the steel A first starts to solidify from the front side, and the steel B subsequently starts to solidify at the portion where the solidification ends. However, it is necessary that the A and B layers sandwiching the transition layer are solidified continuously without being largely mixed and are macroscopically separated from the viewpoint of component analysis.

【0040】尚、このようなA鋼−B鋼−A鋼の構造を
もった鋼板を得る方法としては、圧延において接合する
方法、あるいは一旦凝固したB鋼の鋼片あるいは鋼板の
外側に溶融したA鋼を凝固させる方法などが知られてい
るが、これらの方法によって製造された素材においては
内層と外層が組織的に不連続である。又、鋳込み法と異
なり、これらの方法ではA層とB層との境界面が必ず酸
化雰囲気にさらされることから、この境界にはマクロ
的、あるいはミクロ的な欠陥が存在することもあり、圧
延等で強い加工を加えた場合には境界の一部に応力集中
を生じて圧延が不安定となり、剥離や割れを生じやすく
なる。
As a method of obtaining a steel sheet having such a structure of A steel-B steel-A steel, a method of joining by rolling or a method of melting once on a steel piece or steel sheet of B steel once solidified is employed. Although methods of solidifying A steel and the like are known, in the materials manufactured by these methods, the inner layer and the outer layer are structurally discontinuous. Further, unlike the casting method, since the boundary surface between the A layer and the B layer is always exposed to an oxidizing atmosphere in these methods, there are macro- or micro-defects at this boundary. If strong processing is applied by, for example, stress concentration occurs at a part of the boundary, rolling becomes unstable, and peeling or cracking easily occurs.

【0041】遷移層の厚さは鋳造厚み又は鋼板板厚の1
〜10%が望ましい。尚、遷移層は内層(B層)の両側
に形成されるが、ここでいう遷移層厚みは片側あたりの
厚みとする。
The thickness of the transition layer is 1 of the casting thickness or the steel plate thickness.
10% is preferable. The transition layer is formed on both sides of the inner layer (layer B), and the thickness of the transition layer here is the thickness per one side.

【0042】上述のように遷移層は圧延作業の安定化の
ため必要であるが、製品の加工性の安定性確保のために
も必要である。一般に薄鋼板はシャー剪断あるいはポン
チとダイスによる打ち抜きを経て加工されるが、遷移層
が薄すぎると鋼板の剪断面に板厚を分割するようなセパ
レーション状の割れ、あるいはその起点となるミクロク
ラックが発生する。この割れあるいはミクロクラックは
剪断時の変形が表層部と内層部で異なるために生ずるも
のである。これらの欠陥はそれだけでは問題にならなく
てもその後の加工における割れやネッキングの原因とな
る。
As mentioned above, the transition layer is necessary for stabilizing the rolling work, but is also necessary for ensuring the stability of the workability of the product. Generally, thin steel sheets are processed by shear shearing or punching with punches and dies, but if the transition layer is too thin, separation-like cracks that divide the plate thickness into shear planes of the steel sheet, or microcracks that become the starting points thereof, are generated. Occur. This cracking or microcrack occurs because the deformation during shearing differs between the surface layer portion and the inner layer portion. These defects cause cracks and necking in the subsequent processing even if they are not a problem by themselves.

【0043】図2はポンチとダイスにて20φの初期穴
を打ち抜いた後穴広げを行った場合の不良率(セパレー
ション状割れないし穴広げ率40%以内でのネッキング
発生率)と遷移層厚みの関係を示したものである。ここ
で素材の表層部は引張強度50〜60kgf/mm2
当で、内層は引張強度は27〜35kgf/mm2 相当
であり、表層部厚みは片側当り板厚の10〜15%であ
る。遷移層の厚さが鋼板板厚の1%未満では不良率が急
増する。一方、遷移層が1%以上あれば遷移層が変形の
干渉層となって打ち抜き時のセパレーションの発生がな
くなるため、加工不良を防ぐことができる。従って、遷
移層の厚さは鋼板板厚の1%以上とする。
FIG. 2 is a graph showing the defect rate (separation-like cracking or necking occurrence rate within 40% of hole expansion) and the transition layer thickness when punching and punching an initial hole of 20φ with a punch and a die. It shows the relationship. Here, the surface layer of the material has a tensile strength of 50 to 60 kgf / mm 2 and the inner layer has a tensile strength of 27 to 35 kgf / mm 2 , and the surface layer has a thickness of 10 to 15% per side. If the thickness of the transition layer is less than 1% of the plate thickness of the steel plate, the defective rate increases rapidly. On the other hand, if the transition layer is 1% or more, the transition layer serves as a deformation interference layer and the occurrence of separation at the time of punching is eliminated, so that defective processing can be prevented. Therefore, the thickness of the transition layer is 1% or more of the steel plate thickness.

【0044】一方、遷移層の厚さが増加すると、実質的
に内層部の厚み比率が低下するので、加工性の確保が困
難となる。このため遷移層の厚み比率は10%以下とす
る。
On the other hand, when the thickness of the transition layer is increased, the thickness ratio of the inner layer portion is substantially reduced, so that it becomes difficult to secure workability. Therefore, the thickness ratio of the transition layer is 10% or less.

【0045】また、クラッド率としては、内層/表層の
厚み比を2〜10に制御することが好ましい。ここでの
表層厚みは表裏を合わせた部分をいい、遷移層部分は除
くものとする。内層/表層の厚み比2未満では内層の割
合が少なく、全体としての加工性が不足すると共に表層
部の影響により面歪が生じやすくなる。一方、10を越
えると表層部が薄すぎて耐デント性の確保が困難とな
る。
As for the cladding rate, it is preferable to control the thickness ratio of inner layer / surface layer to 2 to 10. Here, the surface layer thickness means a portion in which the front and back sides are combined, and the transition layer portion is excluded. If the thickness ratio of the inner layer / surface layer is less than 2, the ratio of the inner layer is small, the workability as a whole is insufficient, and surface strain easily occurs due to the influence of the surface layer portion. On the other hand, when it exceeds 10, the surface layer is too thin and it becomes difficult to secure the dent resistance.

【0046】こうして製造された鋳片あるいは鋼塊は、
必要があれば分塊圧延し、その後熱延される。熱延に際
しては、加熱炉に挿入して再加熱した後に熱間圧延して
も良いし、加熱炉に挿入することなく直接熱間圧延して
も良い。本発明では表層部はTi、Nbの析出強化で強
度を確保する必要があるので、再加熱する場合は118
0℃以上に加熱した後に圧延し、再加熱しない場合は1
050℃以上で圧延を開始する必要がある。熱延での仕
上げ圧延終了温度はAr3 −50℃以上とする必要があ
る。この温度未満になると成品の加工性が劣化すると共
に、表層部の熱間でのTiC、Nb(C、N)の粗大析
出が増え、強化に不利になる。仕上げ圧延終了後の冷却
及び巻取りは通常の方法で良い。巻取温度は、TiCな
いしNb(C、N)を充分析出させるために550〜7
00℃が好ましい。
The slab or ingot produced in this way is
If necessary, it is slab-rolled and then hot-rolled. At the time of hot rolling, it may be hot-rolled after being inserted into a heating furnace and reheated, or may be directly hot-rolled without being inserted into the heating furnace. In the present invention, since it is necessary to secure the strength of the surface layer portion by precipitation strengthening of Ti and Nb, when reheating, 118
Rolled after heating to 0 ℃ or higher, and 1 if not reheated
It is necessary to start rolling at 050 ° C or higher. The finish rolling finish temperature in hot rolling needs to be Ar 3 −50 ° C. or higher. When the temperature is lower than this temperature, the workability of the product is deteriorated, and coarse precipitation of TiC and Nb (C, N) during hot working of the surface layer portion is increased, which is disadvantageous for strengthening. Cooling and winding after finishing rolling may be performed by ordinary methods. The coiling temperature is 550 to 7 in order to sufficiently precipitate TiC or Nb (C, N).
00 ° C is preferred.

【0047】本鋼は熱延の後、酸洗され、冷延される。
冷延圧下率は内層部の加工性確保のために60〜90%
が望ましい。
After hot rolling, the steel is pickled and cold rolled.
Cold rolling reduction is 60 to 90% to secure workability of inner layer
Is desirable.

【0048】次に焼鈍を行う。ここでは再結晶と粒成長
を通して加工性を確保する。このため、焼鈍温度は再結
晶温度以上とする。焼鈍の方法は箱焼鈍でも連続焼鈍で
も良い。尚、焼鈍温度があまりにも高い場合は表層部の
析出強化効果が低下するので、焼鈍温度は箱焼鈍では8
50℃以下、連続焼鈍の場合は900℃以下が好まし
い。焼鈍後の調質圧延は通常条件、例えば調圧率0.5
〜2%で良い。
Next, annealing is performed. Here, workability is secured through recrystallization and grain growth. Therefore, the annealing temperature is set to the recrystallization temperature or higher. The annealing method may be box annealing or continuous annealing. Note that if the annealing temperature is too high, the precipitation strengthening effect of the surface layer portion decreases, so the annealing temperature is 8 for box annealing.
It is preferably 50 ° C or lower, and 900 ° C or lower in the case of continuous annealing. The temper rolling after annealing is performed under normal conditions, for example, a pressure regulation rate of 0.5.
~ 2% is good.

【0049】尚、本鋼板に耐食性を付与するため、焼鈍
後亜鉛等を電気めっきしてもよい。このめっきは片面だ
けでも、又は両面に施しても良い。
In order to impart corrosion resistance to the steel sheet, zinc or the like may be electroplated after annealing. This plating may be applied to only one side or both sides.

【0050】[0050]

【実施例】表層及び内層を表1(A〜G)に示す化学成
分に調整して、特開昭63−108947号公報に開示
された方法、即ち2本ノズルにて2種の溶鋼を注入し、
かつ鋳片の厚みを横切る方向へ磁束を付与する方法にて
連続鋳造で溶製した。いずれのスラブも表層と内層が成
分分析の点から巨視的に分離されており、かつそれぞれ
の層の境界において、鋳造厚みの1〜10%の厚みの遷
移層を形成しており、この遷移層厚みは焼鈍後も変化し
ていないことを確認した。A〜Fは本発明の成分であ
る。Gは表層のCが低く、又内層にTi、Nbが添加さ
れていない。尚、H、Iは通常の連続鋳造法にて製造し
た比較用単層スラブである。
EXAMPLES The surface layer and the inner layer were adjusted to the chemical composition shown in Table 1 (A to G) and the method disclosed in JP-A-63-108947, that is, two kinds of molten steel were injected with two nozzles. Then
Moreover, it was melted by continuous casting by a method of applying a magnetic flux in a direction crossing the thickness of the slab. In both slabs, the surface layer and the inner layer are macroscopically separated from the point of component analysis, and a transition layer having a thickness of 1 to 10% of the casting thickness is formed at the boundary of each layer. It was confirmed that the thickness did not change even after annealing. AF are the components of the present invention. G has a low C in the surface layer, and Ti and Nb are not added to the inner layer. In addition, H and I are comparative single-layer slabs manufactured by a normal continuous casting method.

【0051】[0051]

【表1】 [Table 1]

【0052】これらのスラブを熱延後、酸洗ラインにて
脱スケール処理を施した後に圧下率75〜85%で冷延
し、焼鈍した。焼鈍は連続焼鈍または箱焼鈍を行った。
連続焼鈍の場合は5〜20℃/sで昇温し、焼鈍温度で
40〜120s保持した後に急冷し、過時効を150〜
300s行った。箱焼鈍では、高温保持を8〜12時間
行った。一部については電気メッキラインを通板して亜
鉛めっきを施した。熱延・焼鈍・めっき目付量等の条件
を表2及び表3に示す。スキンパス伸び率は1〜1.5
%であった。表2及び表3には製品の引張特性・耐デン
ト性・耐面ひずみ性を併記した。
After hot rolling, these slabs were subjected to descaling treatment in an pickling line, then cold rolled at a rolling reduction of 75 to 85% and annealed. The annealing was continuous annealing or box annealing.
In the case of continuous annealing, the temperature is raised at 5 to 20 ° C./s, the annealing temperature is maintained for 40 to 120 s, and then rapidly cooled, and the overaging is performed at 150 to
It went for 300s. In box annealing, high temperature holding was performed for 8 to 12 hours. Some parts were galvanized through the electroplating line. Conditions such as hot rolling, annealing, and coating weight are shown in Tables 2 and 3. Skin pass elongation is 1 to 1.5
%Met. Tables 2 and 3 also show the tensile properties, dent resistance, and surface strain resistance of the products.

【0053】引張試験は、JIS Z2201に準じた
5号試験片を用いた。平均r値は圧延方向に対して、0
°、45°、90°の各方向のr値の面内平均(=(0
°方向r値+90°方向r値+45°方向r値×2)/
4)で表した。
For the tensile test, a No. 5 test piece according to JIS Z2201 was used. The average r value is 0 with respect to the rolling direction.
In-plane average of r values in each direction of °, 45 °, 90 ° (= (0
R value in ° direction + r value in 90 ° direction + r value in 45 ° direction x 2) /
It is represented by 4).

【0054】耐デント性の測定方法は、鋼板に対して直
径100mmの円筒平底張出し成形を行い、平底面に
2.5%の予ひずみを与えた後、半径25mmの鋼製圧
子を20kgfの負荷で押しつけて塑性変形(へこみ)
を与え、へこみ量をスパン40mmにて3点法で測定す
る方法とした。
The dent resistance was measured by subjecting a steel plate to a cylindrical flat bottom overhang forming process with a diameter of 100 mm, applying a prestrain of 2.5% to the flat bottom face, and then applying a steel indenter with a radius of 25 mm to a load of 20 kgf. Plastic deformation (dent) by pressing with
Was given, and the dent amount was measured by a three-point method with a span of 40 mm.

【0055】耐面ひずみ性は、600×600mmの鋼
板をしわ押さえ力60tonにてかまぼこ型(エンボス
付)に成形し、エンボス周辺を目視にて評価した。
The surface strain resistance was evaluated by visually forming a 600 × 600 mm steel plate into a kamaboko shape (with embossing) with a creasing force of 60 tons and visually evaluating the periphery of the embossing.

【0056】表2及び表3において、No.1、2、
4、5、6、7、8、9は本発明法にしたがって製造し
た鋼板であり、比較材に比べ加工性(伸び・r値)・耐
デント性・耐面ひずみ性が優れている。
In Tables 2 and 3, No. 1, 2,
Steel sheets 4, 5, 6, 7, 8, and 9 are manufactured according to the method of the present invention, and are excellent in workability (elongation / r value), dent resistance, and surface strain resistance as compared with the comparative material.

【0057】図3は横軸を引張強度として、表2及び表
3の本発明鋼の耐デント性を通常の単層板(No.1
1、12)及びその他の比較材と比べたものである。板
厚が厚いほど強度が高いほどへこみ量は少なくなるが、
本発明鋼は同一強度の単層板と比較して板厚が薄くても
へこみ量が少ない。このことは本発明により耐デント性
の観点から板厚を低減できることを意味する。
FIG. 3 shows the dent resistance of the steels of the present invention shown in Tables 2 and 3 with the tensile strength taken along the horizontal axis and the normal single layer plate (No. 1).
1, 12) and other comparative materials. The thicker the plate, the higher the strength.
The steel of the present invention has a smaller amount of dents than a single-layer plate having the same strength even if the plate thickness is thin. This means that the present invention can reduce the plate thickness from the viewpoint of dent resistance.

【0058】その他の鋼板について説明する。No.3
は加熱温度及び仕上温度の低すぎのためにr値と耐デン
ト性が本発明鋼より劣る。No.10は表層の強度が低
く、かつクラッド率が高すぎ(表層部が薄すぎ)るため
に耐デント性が劣り、かつ内層にTiないしNbが添加
されていないためにr値が低い。
Other steel plates will be described. No. Three
Is inferior in r value and dent resistance to the steel of the present invention because the heating temperature and finishing temperature are too low. No. Sample No. 10 has a low surface layer strength, a clad ratio that is too high (the surface layer portion is too thin), and is therefore inferior in dent resistance, and a low r value because Ti or Nb is not added to the inner layer.

【0059】[0059]

【表2】 [Table 2]

【0060】[0060]

【表3】 [Table 3]

【0061】上記表2及び表3において、下記の通りで
ある。 注1)クラッド率(比)=内層厚み/表裏層厚み。 注2)焼鈍様式:「連続」は連続焼鈍を、「箱」は箱焼
鈍を示す。 注3)焼鈍温度:連続焼鈍の( )内数値は過時効温
度を示す。
In Tables 2 and 3 above, they are as follows. Note 1) Cladding ratio (ratio) = inner layer thickness / front and back layer thickness. Note 2) Annealing method: “Continuous” indicates continuous annealing, and “Box” indicates box annealing. Note 3) Annealing temperature: The value in parentheses for continuous annealing indicates the overaging temperature.

【0062】[0062]

【発明の効果】本発明により、自動車部品等でますます
要求の高まっている高強度化・耐デント性と耐面歪性及
び加工性の両立が可能となる。このことは鋼板板厚の低
減による燃費軽減(天然燃料の浪費防止)や、衝突強度
の向上による安全性の向上等につながり、社会的な意義
も大きい。
EFFECTS OF THE INVENTION According to the present invention, it becomes possible to achieve both high strength, dent resistance, surface strain resistance and workability, which are increasingly required for automobile parts and the like. This leads to a reduction in fuel consumption (preventing waste of natural fuel) by reducing the thickness of the steel plate, and an improvement in safety due to an increase in collision strength, which has great social significance.

【図面の簡単な説明】[Brief description of drawings]

【図1】表層・遷移層・内層部の板厚方向の成分変化の
例を示すグラフである。
FIG. 1 is a graph showing an example of component changes in the plate thickness direction of a surface layer / transition layer / inner layer portion.

【図2】遷移層の比率と加工不良率との関係を示すグラ
フである。
FIG. 2 is a graph showing a relationship between a ratio of a transition layer and a processing defect rate.

【図3】耐デント性(へこみ量)と引張強度を示すグラ
フである。
FIG. 3 is a graph showing dent resistance (indentation amount) and tensile strength.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 C21D 9/46 Z C22C 38/14 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location C21D 9/46 Z C22C 38/14

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】 2種の成分系A、Bの鋼がA、B、Aの
順で複層構造を成している鋼板において、表層に位置す
る鋼Aの成分が質量割合で C :0.05〜0.2% Si:3.0%以下 Mn:0.5〜3% P :0.1%以下 S :0.02%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.02〜0.2% Nb:0.01〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、内層に位置する鋼Bの成分が質量割合で C :0.01%以下 Si:0.5%以下 Mn:0.5%以下 P :0.1%以下 S :0.03%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.006〜0.2% Nb:0.003〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、A層とB層との境界部に鋼板板厚の1〜1
0%の厚さの遷移層を有することを特徴とする耐デント
性と耐面歪性及び加工性に優れた冷延鋼板。
1. In a steel sheet in which two kinds of steels of component systems A and B have a multi-layer structure in the order of A, B and A, the component of steel A located in the surface layer is C: 0 in mass ratio. 0.05 to 0.2% Si: 3.0% or less Mn: 0.5 to 3% P: 0.1% or less S: 0.02% or less Al: 0.1% or less N: 0.01% or less And, Ti: 0.02 to 0.2%, Nb: 0.01 to 0.1%, at least one kind is contained, the balance consists of Fe and unavoidable impurities, and the components of steel B located in the inner layer are mass proportions. C: 0.01% or less Si: 0.5% or less Mn: 0.5% or less P: 0.1% or less S: 0.03% or less Al: 0.1% or less N: 0.01% or less And Ti: 0.006 to 0.2%, Nb: 0.003 to 0.1%, at least one kind, and the balance Fe and inevitable impurities. 1 to 1 of the steel plate thickness at the boundary between B and B layers
A cold-rolled steel sheet excellent in dent resistance, surface strain resistance, and workability, which has a transition layer having a thickness of 0%.
【請求項2】 2種の成分系A、Bの鋼がA、B、Aの
順で複層構造を成している鋼板において、表層に位置す
る鋼Aの成分が質量割合で C :0.05〜0.2% Si:3.0%以下 Mn:0.5〜3% P :0.1%以下 S :0.02%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.02〜0.2% Nb:0.01〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、内層に位置する鋼Bの成分が質量割合で C :0.01%以下 Si:0.5%以下 Mn:0.5%以下 P :0.1%以下 S :0.03%以下 Al:0.1%以下 N :0.01%以下 B :0.0001〜0.002% かつ Ti:0.006〜0.2% Nb:0.003〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、A層とB層との境界部に鋼板板厚の1〜1
0%の厚さの遷移層を有することを特徴とする耐デント
性と耐面歪性及び加工性に優れた冷延鋼板。
2. In a steel sheet in which two kinds of steels of component systems A and B form a multi-layer structure in the order of A, B and A, the component of steel A located in the surface layer is C: 0 in mass ratio. 0.05 to 0.2% Si: 3.0% or less Mn: 0.5 to 3% P: 0.1% or less S: 0.02% or less Al: 0.1% or less N: 0.01% or less And, Ti: 0.02 to 0.2%, Nb: 0.01 to 0.1%, at least one kind is contained, the balance consists of Fe and unavoidable impurities, and the components of steel B located in the inner layer are mass proportions. C: 0.01% or less Si: 0.5% or less Mn: 0.5% or less P: 0.1% or less S: 0.03% or less Al: 0.1% or less N: 0.01% or less B: 0.0001 to 0.002% and Ti: 0.006 to 0.2% Nb: 0.003 to 0.1%. Consists fine unavoidable impurities, 1 and 1 of the steel sheet thickness at the boundary between the A layer and the B layer
A cold-rolled steel sheet excellent in dent resistance, surface strain resistance, and workability, which has a transition layer having a thickness of 0%.
【請求項3】 請求項1に記載の鋼板の片面若しくは両
面に電気めっきを施した耐デント性と耐面歪性及び加工
性に優れた電気めっき鋼板。
3. An electroplated steel sheet excellent in dent resistance, surface strain resistance, and workability, which is obtained by electroplating one or both surfaces of the steel sheet according to claim 1.
【請求項4】 請求項2に記載の鋼板の片面若しくは両
面に電気めっきを施した耐デント性と耐面歪性及び加工
性に優れた電気めっき鋼板。
4. An electroplated steel sheet excellent in dent resistance, surface strain resistance, and workability, which is obtained by electroplating one or both surfaces of the steel sheet according to claim 2.
【請求項5】 2種の成分系A、Bの鋼がA、B、Aの
順で複層構造を成している鋼板の製造において、表層に
位置する鋼Aの成分が質量割合で C :0.05〜0.2% Si:3.0%以下 Mn:0.5〜3% P :0.1%以下 S :0.02%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.02〜0.2% Nb:0.01〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、内層に位置する鋼Bの成分が質量割合で C :0.01%以下 Si:0.5%以下 Mn:0.5%以下 P :0.1%以下 S :0.03%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.006〜0.2% Nb:0.003〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、これらの溶鋼において、まずAの鋼が表側
から凝固を開始し、これが凝固を終了する部位におい
て、引き続いてBの鋼が凝固を開始して、結果形成され
たA、B両層が成分分析の点から巨視的に分離されてお
り、かつA層とB層との境界部において鋳片厚の1〜1
0%の厚さの遷移層を形成させた鋳片あるいは鋼塊を素
材として、熱間圧延するに際し、再加熱する場合は11
80℃以上に加熱した後に圧延し、再加熱しない場合は
1050℃以上で圧延を開始し、Ar3 −50℃以上で
熱延を終了し、酸洗、冷延後、再結晶温度以上で焼鈍す
ることを特徴とする耐デント性と耐面歪性及び加工性に
優れた鋼板の製造方法。
5. In the production of a steel sheet in which steels of two kinds of component systems A and B form a multi-layer structure in the order of A, B and A, the components of steel A located on the surface layer are C by mass ratio. : 0.05-0.2% Si: 3.0% or less Mn: 0.5-3% P: 0.1% or less S: 0.02% or less Al: 0.1% or less N: 0.01 % Or less and Ti: 0.02 to 0.2% Nb: 0.01 to 0.1%, at least one of which is composed of the balance Fe and inevitable impurities, and the composition of Steel B located in the inner layer is In mass ratio C: 0.01% or less Si: 0.5% or less Mn: 0.5% or less P: 0.1% or less S: 0.03% or less Al: 0.1% or less N: 0.01 % Or less and Ti: 0.006 to 0.2%, Nb: 0.003 to 0.1%, one or more of them are contained, and the balance is Fe and inevitable impurities. In these molten steels, the steel A first starts to solidify from the front side, and the steel B subsequently starts to solidify at the point where it solidifies, and the two layers A and B formed as a result are analyzed. Is macroscopically separated from the above point, and the slab thickness is 1 to 1 at the boundary between the A layer and the B layer.
When using a slab or steel ingot having a 0% thick transition layer formed as a raw material, it is 11 when reheating during hot rolling.
Roll after heating to 80 ° C or higher, and if not reheated, start rolling at 1050 ° C or higher, finish hot rolling at Ar 3 -50 ° C or higher, and after pickling, cold rolling, anneal at recrystallization temperature or higher. A method for producing a steel sheet having excellent dent resistance, surface strain resistance, and workability.
【請求項6】 2種の成分系A、Bの鋼がA、B、Aの
順で複層構造を成している鋼板の製造において、表層に
位置する鋼Aの成分が質量割合で C :0.05〜0.2% Si:3.0%以下 Mn:0.5〜3% P :0.1%以下 S :0.02%以下 Al:0.1%以下 N :0.01%以下 かつ Ti:0.02〜0.2% Nb:0.01〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、内層に位置する鋼Bの成分が質量割合で C :0.01%以下 Si:0.5%以下 Mn:0.5%以下 P :0.1%以下 S :0.03%以下 Al:0.1%以下 N :0.01%以下 B :0.0001〜0.002% かつ Ti:0.006〜0.2% Nb:0.003〜0.1% のうち1種以上を含有し、残部Feおよび不可避的不純
物からなり、これらの溶鋼において、まずAの鋼が表側
から凝固を開始し、これが凝固を終了する部位におい
て、引き続いてBの鋼が凝固を開始して、結果形成され
たA、B両層が成分分析の点から巨視的に分離されてお
り、かつA層とB層との境界部において鋳片厚の1〜1
0%の厚さの遷移層を形成させた鋳片あるいは鋼塊を素
材として、熱間圧延するに際し、再加熱する場合は11
80℃以上に加熱した後に圧延し、再加熱しない場合は
1050℃以上で圧延を開始し、Ar3 −50℃以上で
熱延を終了し、酸洗、冷延後、再結晶温度以上で焼鈍す
ることを特徴とする耐デント性と耐面歪性及び加工性に
優れた鋼板の製造方法。
6. In the production of a steel sheet in which steels of two kinds of component systems A and B form a multilayer structure in the order of A, B and A, the components of steel A located on the surface layer are C by mass ratio. : 0.05-0.2% Si: 3.0% or less Mn: 0.5-3% P: 0.1% or less S: 0.02% or less Al: 0.1% or less N: 0.01 % Or less and Ti: 0.02 to 0.2% Nb: 0.01 to 0.1%, at least one of which is composed of the balance Fe and inevitable impurities, and the composition of Steel B located in the inner layer is In mass ratio C: 0.01% or less Si: 0.5% or less Mn: 0.5% or less P: 0.1% or less S: 0.03% or less Al: 0.1% or less N: 0.01 % Or less B: 0.0001 to 0.002% and Ti: 0.006 to 0.2% Nb: 0.003 to 0.1% One or more kinds are contained, and the balance. In these molten steels, the steel A first starts to solidify from the front side, and the steel B subsequently starts to solidify at the site where the solidification ends. , B layers are macroscopically separated from the viewpoint of component analysis, and the slab thickness is 1 to 1 at the boundary between A layer and B layer.
When using a slab or steel ingot having a 0% thick transition layer formed as a raw material, it is 11 when reheating during hot rolling.
Roll after heating to 80 ° C or higher, and if not reheated, start rolling at 1050 ° C or higher, finish hot rolling at Ar 3 -50 ° C or higher, and after pickling, cold rolling, anneal at recrystallization temperature or higher. A method for producing a steel sheet having excellent dent resistance, surface strain resistance, and workability.
【請求項7】 請求項5に記載の方法において、得られ
た鋼板の片面若しくは両面に電気めっきを施すことを特
徴とする耐デント性と耐面歪性及び加工性に優れた鋼板
の製造方法。
7. The method for producing a steel sheet excellent in dent resistance, surface strain resistance and workability according to claim 5, wherein one or both surfaces of the obtained steel sheet are electroplated. .
【請求項8】 請求項6に記載の方法において、得られ
た鋼板の片面若しくは両面に電気めっきを施すことを特
徴とする耐デント性と耐面歪性及び加工性に優れた鋼板
の製造方法。
8. The method according to claim 6, wherein the obtained steel sheet is electroplated on one side or both sides thereof, which is excellent in dent resistance, surface strain resistance and workability. .
JP7287593A 1993-03-09 1993-03-09 Steel sheet excellent in dent resistance, surface distortion resistance, and workability and its production Withdrawn JPH06264175A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7287593A JPH06264175A (en) 1993-03-09 1993-03-09 Steel sheet excellent in dent resistance, surface distortion resistance, and workability and its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7287593A JPH06264175A (en) 1993-03-09 1993-03-09 Steel sheet excellent in dent resistance, surface distortion resistance, and workability and its production

Publications (1)

Publication Number Publication Date
JPH06264175A true JPH06264175A (en) 1994-09-20

Family

ID=13501951

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7287593A Withdrawn JPH06264175A (en) 1993-03-09 1993-03-09 Steel sheet excellent in dent resistance, surface distortion resistance, and workability and its production

Country Status (1)

Country Link
JP (1) JPH06264175A (en)

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