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JPH05317891A - Filter device - Google Patents

Filter device

Info

Publication number
JPH05317891A
JPH05317891A JP4156250A JP15625092A JPH05317891A JP H05317891 A JPH05317891 A JP H05317891A JP 4156250 A JP4156250 A JP 4156250A JP 15625092 A JP15625092 A JP 15625092A JP H05317891 A JPH05317891 A JP H05317891A
Authority
JP
Japan
Prior art keywords
raw water
layer
cod
chromaticity
filter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4156250A
Other languages
Japanese (ja)
Inventor
Atsushi Watanabe
敦 渡辺
Junji Hagiwara
純二 萩原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kurita Water Industries Ltd
Original Assignee
Kurita Water Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kurita Water Industries Ltd filed Critical Kurita Water Industries Ltd
Priority to JP4156250A priority Critical patent/JPH05317891A/en
Publication of JPH05317891A publication Critical patent/JPH05317891A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Filtration Of Liquid (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

PURPOSE:To remove the SS and org. matter, such as BOD and COD, chromaticity and smell in raw water by having a filter medium layer on an upstream side of a raw water passing direction and a catalyst layer on a downstream side and injecting a oxidizing agent in the middle of the two layers. CONSTITUTION:The SS components in the raw water are captured and removed in a filter tank 3 when the secondarily treated water of sewage is supplied as the raw water by a supply pipe 7 into a treating tank 1 and is passed therein in upward current. Microorgansims are generated according to the operation and stuck on the surfaces of the filter media, thereby forming biomembranes. The removal of the soluble BOD components, the removal of ammonia by oxidation, etc., are executed and simultaneously, the capacity to stick the SS components is improved. The raw water is mixed with an oxidizing agent injected in an injection pipe 6 at the time of passing the upper part of the filter medium layer 3. The oxidizing decomposition is activated at the time when the water flows upward in the catalyst layer 4. The COD and chromaticity are removed by the generated O2. As a result, the SS, the org. matter, such as BOD and COD, chromaticity and smells, in the raw water are removed in the one filter tank 3.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、濾過装置、特に下水
の高度処理に適した濾過装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a filtration device, particularly to a filtration device suitable for advanced treatment of sewage.

【0002】[0002]

【従来の技術】従来から槽の底部に支持層を設け、その
上に濾層を設けた上向流、又は下向流濾過装置は公知で
ある。
2. Description of the Related Art Conventionally, an upflow or downflow filtration device in which a support layer is provided at the bottom of a tank and a filter layer is provided thereon is known.

【0003】[0003]

【発明が解決しようとする課題】この濾過装置によって
下水の高度処理を行うと、水中のCOD、BOD等の有
機物中、SS性成分に由来するものは除去することがで
きた(COD除去率は10%程度)。又、濾層を構成す
る濾材の表面に微生物膜が付着するので、これによって
水中の溶解性成分も一部除去されることがある。しか
し、従来の濾過装置は水中の濁質の除去を主目的とする
ため、CODの除去率は低く、色度、臭気は殆ど除去す
ることができない。
When advanced treatment of sewage was carried out by this filtration device, it was possible to remove organic substances such as COD and BOD in water, which were derived from SS-like components (COD removal rate was 10%). Further, since a microbial film adheres to the surface of the filter medium that constitutes the filter layer, this may partially remove soluble components in water. However, since the conventional filtration device has a main purpose of removing suspended solids in water, it has a low COD removal rate and can hardly remove chromaticity and odor.

【0004】[0004]

【課題を解決するための手段】本発明は、COD等の有
機物除去能力を向上すると共に、色度、臭気をも除去可
能な濾過装置を得ることを目的に開発されたもので、濾
過用充填層中に原水を通水する濾過装置において、原水
通水方向に対して上流側に濾材層、下流側に触媒層を有
し、濾材層と触媒層の中間に酸化剤を注入するようにし
たことを特徴とする。
The present invention was developed for the purpose of obtaining a filter device capable of removing organic substances such as COD and also removing chromaticity and odor. In a filtration device for passing raw water through the bed, a filter medium layer is provided on the upstream side and a catalyst layer is provided on the downstream side with respect to the raw water flow direction, and an oxidizing agent is injected between the filter medium layer and the catalyst layer. It is characterized by

【0005】[0005]

【実施例】図示の実施例において、1は処理槽、2は充
填層であり、充填層は下層に砂による濾材層3、上層に
触媒層4を有するほか、最下層に支持層5を有する。そ
して、濾材層3と触媒層4との中間に酸化剤の注入管6
が設けてある。支持層5の層高は500mm程度、濾材
層3の層高は300mm程度、触媒層4の層高は100
0mm程度であり、これらの層高は処理すべき原水の水
質、濾過速度に応じて適切に定める。又、触媒層4を構
成する触媒は、機材がゼオライトで、Ni、Co、Fe
等の金属を坦持し、濾材層3を構成する濾過砂と区分で
きる逆洗性状を有するものを用いる。尚、注入管6で濾
材層3と触媒層4との中間に供給する酸化剤はNaOC
l、NaClO2 、H2 O等である。
In the illustrated embodiment, 1 is a processing tank, 2 is a packed bed, and the packed bed has a sand filter medium layer 3 in the lower layer, a catalyst layer 4 in the upper layer, and a support layer 5 in the lowermost layer. .. An oxidizing agent injection pipe 6 is provided between the filter medium layer 3 and the catalyst layer 4.
Is provided. The support layer 5 has a layer height of about 500 mm, the filter medium layer 3 has a layer height of about 300 mm, and the catalyst layer 4 has a layer height of 100 mm.
It is about 0 mm, and the height of these layers is appropriately determined according to the water quality of the raw water to be treated and the filtration rate. In addition, the catalyst constituting the catalyst layer 4 is made of zeolite, Ni, Co, Fe
A metal having a backwash property capable of carrying a metal such as the above and being distinguishable from the filter sand constituting the filter medium layer 3 is used. The oxidizing agent supplied to the middle of the filter layer 3 and the catalyst layer 4 through the injection pipe 6 is NaOC.
1, NaClO 2 , H 2 O and the like.

【0006】下水の二次処理水を原水として供給管7で
処理槽に供給し、上向流で通水すると、原水中のSS成
分は濾材層3で捕捉、除去される。又、運転に伴い微生
物が発生し、濾材の表面に付着して生物膜となることに
より溶解性のBOD成分の除去、アンモニアの酸化除去
等が生じる。又、同時にSS除去性能も向上する。これ
は生物膜の付着によりSS成分の付着能力が向上したも
のと予想される。
When the secondary treated water of the sewage is supplied as raw water to the treatment tank through the supply pipe 7 and is passed through in an upward flow, the SS component in the raw water is captured and removed by the filter medium layer 3. In addition, microorganisms are generated during the operation and adhere to the surface of the filter medium to form a biofilm, so that soluble BOD components are removed and ammonia is removed by oxidation. At the same time, the SS removal performance is also improved. It is expected that this is because the attachment ability of the SS component was improved by the attachment of the biofilm.

【0007】濾材層3を上に通過する際、原水は注入管
6で注入される酸化剤と混合し、触媒層4中を上向流す
るときに触媒で酸化分解を活性化され、発生したO2
COD、色度が除去される。尚、本実施例では上向流濾
過装置を説明したが、下向流濾過装置でも良く、この場
合は濾材層が上層、触媒層が下層になる。
When passing through the filter medium layer 3 upward, the raw water is mixed with the oxidant injected in the injection pipe 6, and when it flows upward in the catalyst layer 4, the oxidative decomposition is activated by the catalyst and generated. CO 2 and chromaticity are removed by O 2 . Although an upflow filtration device has been described in this embodiment, a downflow filtration device may be used. In this case, the filter medium layer is the upper layer and the catalyst layer is the lower layer.

【0008】或る下水処理場の二次処理水を図1の濾過
装置で処理した実験結果を次に示す。直径25mmのカ
ラムに、Niを坦持したゼオライト触媒層を200m
m、濾材層を130mm、支持層を25mm充填し、通
水量17.5ml/分にて通水した。酸化剤には次亜塩
酸ソーダを使用し、その添加量は10mg/立とした。 水質分析結果 原 水 本発明濾過装置 砂のみの濾過装置 SS (mg/立) 9.5 1.0 0.9 色度 (度) 21 4.3 20 COD(mg/立) 8.2 5.5 7.1 以上で明らかなように、SSの除去率は砂のみの濾過装
置と殆ど同じであるが、CODの除去率は良好で、特に
色度は、砂のみの濾過装置は殆ど除去できないのに対
し、本発明の装置では飛躍的な除去率を示した。
The experimental results of treating the secondary treated water of a certain sewage treatment plant with the filtration device of FIG. 1 are shown below. Ni-supported zeolite catalyst layer is 200 m in a 25 mm diameter column.
m, the filter medium layer was filled with 130 mm and the support layer was filled with 25 mm, and water was passed at a water flow rate of 17.5 ml / min. Sodium hypochlorite was used as the oxidizing agent, and the addition amount was 10 mg / stand. Water quality analysis results Raw water Filtration device of the present invention Filtration device for sand only SS (mg / vertical) 9.5 1.0 0.9 Chromaticity (degree) 21 4.3 20 COD (mg / vertical) 8.2 5. 5 7.1 As is clear from the above, the removal rate of SS is almost the same as that of the sand-only filter, but the COD removal rate is good, and especially the chromaticity cannot be removed by the sand-only filter. On the other hand, the device of the present invention showed a dramatic removal rate.

【0009】[0009]

【発明の効果】本発明によれば、砂濾過では除去できな
い溶解性COD等の有機物が除去できる。又、生物処理
では分解できない色度が除去できる。そして、濾材層
と、触媒層とを同じ処理槽内に設けることにより、各層
を別々の槽に設ける必要がなくなり、処理装置がコンパ
クトになる。又、SS成分と、COD、色度等の除去を
同時に行える。更に、濾材層の表面に生物膜が付着する
が、この生物膜がBOD成分、アンモニアを除去する。
SS成分、アンモニア等は酸化剤を消費するため、これ
らをあらかじめ除去することにより酸化剤の利用率は向
上し、注入量も低減する。そして、酸化剤を濾材層と、
触媒層との中間に注入するので、濾材層中に生じた生物
膜の機能を阻害しない。
According to the present invention, organic substances such as soluble COD which cannot be removed by sand filtration can be removed. Also, chromaticity that cannot be decomposed by biological treatment can be removed. By providing the filter medium layer and the catalyst layer in the same processing tank, it is not necessary to provide each layer in a separate tank, and the processing apparatus becomes compact. Further, the SS component, COD, chromaticity, etc. can be removed at the same time. Further, a biofilm adheres to the surface of the filter medium layer, and this biofilm removes BOD components and ammonia.
Since SS components, ammonia, and the like consume the oxidant, by removing them in advance, the utilization rate of the oxidant is improved and the injection amount is also reduced. Then, the oxidizer is a filter medium layer,
Since it is injected in the middle of the catalyst layer, it does not impede the function of the biofilm formed in the filter medium layer.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例の濾過装置の断面図である。FIG. 1 is a cross-sectional view of a filter device according to an embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1 処理槽 2 充填層 3 濾材層 4 触媒層 5 支持層 6 酸化剤の注入管 1 Treatment Tank 2 Packing Layer 3 Filter Medium Layer 4 Catalyst Layer 5 Supporting Layer 6 Oxidizing Agent Injection Pipe

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 C02F 3/06 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display area C02F 3/06

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 濾過用充填層中に原水を通水する濾過装
置において、上記充填層が、原水通水方向に対して上流
側に濾材層、下流側に触媒層を有し、濾材層と触媒層の
中間に酸化剤を注入するようにしたことを特徴とする濾
過装置。
1. A filtration device for passing raw water through a packed bed for filtration, wherein the packed bed has a filter material layer on the upstream side and a catalyst layer on the downstream side in the raw water flow direction, A filtering device characterized in that an oxidizing agent is injected into the middle of the catalyst layer.
JP4156250A 1992-05-25 1992-05-25 Filter device Pending JPH05317891A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4156250A JPH05317891A (en) 1992-05-25 1992-05-25 Filter device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4156250A JPH05317891A (en) 1992-05-25 1992-05-25 Filter device

Publications (1)

Publication Number Publication Date
JPH05317891A true JPH05317891A (en) 1993-12-03

Family

ID=15623674

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4156250A Pending JPH05317891A (en) 1992-05-25 1992-05-25 Filter device

Country Status (1)

Country Link
JP (1) JPH05317891A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002159984A (en) * 2000-11-27 2002-06-04 Kurita Water Ind Ltd Biodegradation method of TOC component
WO2004028982A1 (en) * 2002-09-27 2004-04-08 Shanghai Gi Biotechnology Engineering Co., Ltd. A method for treating wastewater
CN114133075A (en) * 2021-12-31 2022-03-04 上海相出净流环保科技开发有限公司 Heterogeneous ozone catalytic oxidation and membrane separation integrated reactor

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002159984A (en) * 2000-11-27 2002-06-04 Kurita Water Ind Ltd Biodegradation method of TOC component
JP4608765B2 (en) * 2000-11-27 2011-01-12 栗田工業株式会社 Biodegradation method of TOC component
WO2004028982A1 (en) * 2002-09-27 2004-04-08 Shanghai Gi Biotechnology Engineering Co., Ltd. A method for treating wastewater
CN114133075A (en) * 2021-12-31 2022-03-04 上海相出净流环保科技开发有限公司 Heterogeneous ozone catalytic oxidation and membrane separation integrated reactor

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