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JPH038555A - Method for butt-joining steel - Google Patents

Method for butt-joining steel

Info

Publication number
JPH038555A
JPH038555A JP14388089A JP14388089A JPH038555A JP H038555 A JPH038555 A JP H038555A JP 14388089 A JP14388089 A JP 14388089A JP 14388089 A JP14388089 A JP 14388089A JP H038555 A JPH038555 A JP H038555A
Authority
JP
Japan
Prior art keywords
layer
insert
butt
powder
bonding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP14388089A
Other languages
Japanese (ja)
Inventor
Fumio Kashimoto
文雄 樫本
Yuichi Komizo
裕一 小溝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP14388089A priority Critical patent/JPH038555A/en
Publication of JPH038555A publication Critical patent/JPH038555A/en
Pending legal-status Critical Current

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  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、鋼管の突合せ接合に適した鋼の突合せ接合法
に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method for butt joining steel suitable for butt joining steel pipes.

〔従来の技術〕[Conventional technology]

従来より配管用炭素鋼鋼管の周溶接には、手溶接が用い
られている。しかし、手溶接では、溶接工の技量が継手
性能を大きく左右する。そのため、溶接欠陥の手直し及
び施工時間が溶接工によって大きく異なる。また、手溶
接で大径管の周溶接を行なう場合には、管径が大きくな
るにつれて肉厚も増加し、それにより溶接パス数も増加
するので、施工時間が著しく長くなる。そのため、最近
では鋼管の端面間に箔状のインサート材を介装して端面
を相互に突合せ、その突合せ部を加熱することによりイ
ンサート材を溶融させて端面を相互に接合する液相拡散
接合法も用いられている。
Conventionally, manual welding has been used for circumferential welding of carbon steel pipes for piping. However, in manual welding, the welder's skill greatly influences joint performance. Therefore, the time required to repair and perform welding defects varies greatly depending on the welder. Furthermore, when manually welding the circumference of a large-diameter pipe, the wall thickness increases as the pipe diameter increases, and the number of welding passes increases accordingly, resulting in a significantly longer construction time. For this reason, liquid phase diffusion bonding has recently been developed, in which a foil-like insert material is interposed between the end faces of steel pipes, the end faces are abutted against each other, and the abutted portion is heated to melt the insert material and join the end faces together. is also used.

〔発明が解決しようとする課題] しかし、液相拡散接合法で鋼管を突合せ接合する場合に
は、端面形状に合せて箔状のインサート材を切り抜(必
要がある。更に、切り抜いたインサート材をスポット溶
接等で端面に固定することも必要になる。従って、作業
工数が増加し、現場施工では、期待する程の施工性改善
は達成されておらず、逆にインサート材の管理上の問題
等を生じている。また、液相拡散接合法では、被接合面
の粗さも接合強度に影響するが、現場施工では満足の行
く粗さを確保することが難しい。
[Problems to be Solved by the Invention] However, when butt-joining steel pipes using the liquid phase diffusion welding method, it is necessary to cut out the foil-shaped insert material to match the end face shape. It is also necessary to fix it to the end face by spot welding etc. Therefore, the number of work hours increases, and the expected improvement in workability has not been achieved in on-site construction, and on the contrary, it has caused problems in the management of insert materials. In addition, in the liquid phase diffusion bonding method, the roughness of the surfaces to be bonded also affects the bonding strength, but it is difficult to ensure a satisfactory roughness in on-site construction.

更に、箔状のインサート材には市販品、試作品ともに最
大100鵬の幅制限があり、100mmを超える外径の
鋼管を接合する場合にはインサート材が切り継ぎの状態
になり、カッティング、セツティングが一層難しくなる
と共に、全面で均一な接合強度を得るのが困難になる。
Furthermore, there is a maximum width limit of 100 mm for both commercially available and prototype foil insert materials, and when joining steel pipes with an outer diameter exceeding 100 mm, the insert material becomes a cut and joint, making it difficult to cut and set. This makes bonding more difficult and it becomes difficult to obtain uniform bonding strength over the entire surface.

本発明は、こうした施工上の問題を解決した高能率な液
相拡散接合による綱の突合せ接合法を提供することを目
的とする。
An object of the present invention is to provide a high-efficiency method for butt-joining ropes by liquid-phase diffusion welding that solves these construction problems.

〔課題を解決するための手段〕[Means to solve the problem]

本発明の突合せ接合法は、鋼の突合せ接合法において、
被接合面の少なくとも一方に、重量%でCr:10〜2
0%、Si:4〜10%、B:1〜5%を含み、残部実
質的にNiからなるわ)末を用いて層厚75〜200μ
mのインサートaを形成し、次いで、前記被接合面を相
互に突合せ、突合せ部を不活性雰囲気中で前記インサー
ト層の融点を超える温度に60秒以上加熱すると共に、
突合せ部に0.5 kg f / mm”以上の加圧力
を加えることを特徴としてなる。
The butt joining method of the present invention is a steel butt joining method that includes:
Cr: 10 to 2 in weight% on at least one of the surfaces to be joined
0%, Si: 4 to 10%, B: 1 to 5%, and the remainder substantially consists of Ni) to a layer thickness of 75 to 200 μm.
m of inserts a are formed, then the surfaces to be joined are abutted against each other, and the abutted portions are heated in an inert atmosphere to a temperature exceeding the melting point of the insert layer for 60 seconds or more,
It is characterized by applying a pressing force of 0.5 kgf/mm" or more to the abutting portion.

従来のこの種接合法で施工性を悪化させている第1の要
因は、箔状のインサート材にあるが、本発明の接合法で
は、粉末を使用して被接合面にインサート層を直接形成
するので、箔状のインサート材を使用した場合のカンテ
ィング、セツティング、切り継ぎ等に起因する問題は全
て解決される。
The first factor that deteriorates workability in conventional joining methods of this type is the foil-like insert material, but in the joining method of the present invention, the insert layer is directly formed on the surfaces to be joined using powder. Therefore, all problems caused by canting, setting, cutting, etc. when using foil insert materials are solved.

また、第2の施工性悪化要因である端面粗さについては
、インサート層形成の粉末としてSi、Bを添加したN
i基粉末を使用している。Si、Bは融点降下元素で、
接合部の加熱温度低下に寄与するのみならず、母材に拡
散しやすい元素であるために接合層の脆化を阻止する。
Regarding the end surface roughness, which is the second factor that deteriorates workability, N
i-based powder is used. Si and B are elements that lower the melting point,
Not only does it contribute to lowering the heating temperature of the joint, but since it is an element that easily diffuses into the base material, it prevents the joint layer from becoming brittle.

特にNi基中のBは母材中に拡散しながら母材と共晶反
応を生じるので、被接合面の表面粗さに対する許容範囲
が拡大し、施工性が一層改善される。
In particular, since B in the Ni group causes a eutectic reaction with the base material while diffusing into the base material, the tolerance range for the surface roughness of the surfaces to be joined is expanded, and workability is further improved.

〔作  用] 以下に、本発明の接合法における条件限定理由を説明す
る。なお、%は特にことわりのない限り重量%を示して
いる。
[Function] The reasons for limiting the conditions in the joining method of the present invention will be explained below. Note that % indicates weight % unless otherwise specified.

インサート層形成に用いる粉末にNi基粉末を使用する
のは、後述するのように主に被接合面の粗さに対する条
件緩和を閲るためである。
The reason why Ni-based powder is used as the powder used to form the insert layer is mainly to ease the conditions for the roughness of the surfaces to be joined, as will be described later.

Ni基粉末にSi、Bを添加するのは、これらの元素が
インサート層の融点低下に寄与し、且つ接合時に母材に
拡散しやすいためである。Si<4%、B<1%では融
点降下作用が不足し、Si>10%、B>5%では接合
層に残存して脆化を生しさせるので、Siは4〜10%
、Bは1〜5%とした。3124%、821%の粉末の
融点は1150’C以下である。
The reason for adding Si and B to the Ni-based powder is that these elements contribute to lowering the melting point of the insert layer and are likely to diffuse into the base material during bonding. If Si < 4% and B < 1%, the melting point lowering effect will be insufficient, and if Si > 10% and B > 5%, it will remain in the bonding layer and cause embrittlement, so Si should be 4 to 10%.
, B was 1 to 5%. The melting points of 3124% and 821% powders are 1150'C or less.

Bは更にインサート層(液相)の粘性上昇に寄与し、1
%未満では液相の粘性上昇により接合界面上のボイド、
酸化物が排出しにくく、欠陥として残存しやすくなる。
B further contributes to increasing the viscosity of the insert layer (liquid phase), and 1
If it is less than %, the viscosity of the liquid phase increases, causing voids on the bonding interface.
Oxides are difficult to discharge and tend to remain as defects.

逆に5%趙えでは粘性低下により液相が過度に排出され
、たれ落ちを招く。
On the other hand, at 5% viscosity, the liquid phase is excessively discharged due to a decrease in viscosity, resulting in dripping.

Crは、液相の粘性保持と、接合層の延性向上とに寄与
するが、10%未満ではこれらの効果が薄く、20%超
えでは接合層の脆化を促進する。
Cr contributes to maintaining the viscosity of the liquid phase and improving the ductility of the bonding layer, but if it is less than 10%, these effects are weak, and if it exceeds 20%, it promotes embrittlement of the bonding layer.

従って、Crは10〜20%とした。Therefore, Cr was set at 10 to 20%.

上記粉末は、例えば溶射、バインダー使用等によりイン
サート層に成形される。
The above powder is formed into an insert layer by thermal spraying, using a binder, etc., for example.

インサート層の層厚は、75μm未満ではインサート層
形成の段階で層中の空隙率が5%〜10%程度発生し、
しかもインサート材料の不足により接合時に界面上に十
分な液層が形成されなくなり、逆に200μm超えでは
界面上の1夜層が過多になり、粉末中のSi、Bの拡散
が不十分となって脆化が発生するので、75〜200μ
mとした。
If the thickness of the insert layer is less than 75 μm, the porosity in the layer will be approximately 5% to 10% at the stage of forming the insert layer.
Moreover, due to the lack of insert material, a sufficient liquid layer cannot be formed on the interface during bonding, and conversely, if the thickness exceeds 200 μm, there will be too much overnight layer on the interface, resulting in insufficient diffusion of Si and B in the powder. 75 to 200μ, as embrittlement occurs.
It was set as m.

インサート層は被接合面の一方に形成すればよいが、両
面に形成する場合は合計の層厚を75〜200μmとす
るのが望ましい。また、前記空隙率を低くおさえる為に
、粉末の粒径は小さい程望ましいが、通常は30μm〜
40μmの平均粒径で十分に目的は達成できる。
The insert layer may be formed on one of the surfaces to be joined, but when it is formed on both surfaces, it is desirable that the total layer thickness be 75 to 200 μm. In addition, in order to keep the porosity low, the particle size of the powder is preferably as small as possible, but it is usually 30 μm or more.
An average particle size of 40 μm is sufficient to achieve the objective.

被接合面を突合せた後の突合せ部の加熱温度は、インサ
ート層を溶融させるためにその粉末の融点を超える温度
とし、粉末の融点+50″C程度が望ましい、粉末の融
点は5ilO%、84%で1000°Cになり、Si 
:4%、81%で1150’Cになるため、望ましい加
熱温度範囲は1050〜1200℃になる。
The heating temperature of the abutting part after abutting the surfaces to be joined is set to a temperature exceeding the melting point of the powder in order to melt the insert layer, preferably about +50"C of the melting point of the powder, the melting point of the powder is 5ilO%, 84% The temperature reached 1000°C, and Si
: 4% and 81% result in 1150'C, so the desirable heating temperature range is 1050-1200°C.

加熱温度保持時間は、短時間はど経済的であるが、融点
降下元素であるSi、Bを母材に十分に拡散させるため
6二60秒以上を必要上する。
Although a short heating temperature holding time is economical, it is necessary to hold the heating temperature for 6260 seconds or more in order to sufficiently diffuse Si and B, which are elements that lower the melting point, into the base material.

加圧力を0.5 kg f / mm”以上としたのは
、インサート層(液層)中の気孔をIP出するためであ
る。
The reason why the pressurizing force was set to 0.5 kg f/mm" or more was to extract the pores in the insert layer (liquid layer) by IP.

この意味から、加圧力は大きい方が望ましいが、加圧力
の増大は被接合材の塑性変形を生じ、接合後の外観をそ
こなうために、実際上は、1.5 kg f/ml11
2以下に制限することが望まれる。
From this point of view, it is desirable that the pressing force be large, but an increase in the pressing force causes plastic deformation of the materials to be joined, which impairs the appearance after joining, so in practice it is 1.5 kg f/ml11
It is desirable to limit the number to 2 or less.

接合雰囲気は、接合界面の酸化防止のために不活性雰囲
気とし、02量を200pp−以下とすることが望まし
い。雰囲気確保に使用するシールドガスとしては、Nz
、Ar等を挙げることができるが、経済性の点からN2
が望ましい。
The bonding atmosphere is preferably an inert atmosphere to prevent oxidation of the bonding interface, and the amount of O2 is preferably 200 pp- or less. The shielding gas used to secure the atmosphere is Nz
, Ar, etc., but from the economic point of view, N2
is desirable.

被接合面の粗さは、鏡面に近いほど良好な接合強度が得
られるが、本発明の接合法で使用するインサート層形成
用の粉末はNi基で、しかもBを含んでいるので、溶融
時に88母材中に拡散させながら母材と共晶反応を進行
させる。従って、母材が炭素鋼の場合、同等成分のFe
系粉末よりも共晶反応が促進され、その結果、表面粗さ
の許容範囲が100μmRma x程度まで拡大する。
The closer the roughness of the surfaces to be joined to the mirror surface, the better the joining strength can be obtained. However, since the powder for forming the insert layer used in the joining method of the present invention is Ni-based and also contains B, it 88 While diffusing into the base material, a eutectic reaction with the base material proceeds. Therefore, if the base material is carbon steel, Fe with the same composition
The eutectic reaction is promoted more than in the case of powder-based powders, and as a result, the allowable range of surface roughness is expanded to approximately 100 μmRmax.

〔実施例〕〔Example〕

成分組成を第1表に示す外径406.4 mm、肉厚7
.9印、長さ600In11の炭素8w4管(SGP、
100A)を管軸と直角に切断し、一方の端面にンヨソ
トブラスト後、第2表に示すわ)末を溶射して層厚75
〜200μmのインサート層を形成した。
The composition is shown in Table 1.Outer diameter: 406.4 mm, wall thickness: 7
.. 9 mark, length 600In11 carbon 8w4 tube (SGP,
100A) was cut at right angles to the tube axis, and after blasting on one end surface, the powder shown in Table 2 was sprayed to a layer thickness of 75mm.
An insert layer of ˜200 μm was formed.

他方の端面は50 μmRma x、100 μmRm
aχに仕上げた。
The other end face is 50 μmRmax, 100 μmRm
Finished in aχ.

しかる後、第1回に示すように、切断した2本の炭素鋼
鋼管1a+1bを、その切断面を相互に突合せてクラン
プ2a、2bにそれぞれ固定した。
Thereafter, as shown in the first step, the two cut carbon steel pipes 1a+1b were fixed to clamps 2a and 2b, respectively, with their cut surfaces butted against each other.

クランプ2a、2bは油圧シリンダー3a、3bヲ介シ
てトランス4に連結されている。次いで、炭素鋼鋼管1
a、lbの突合せ部外面側に半割型のコイルチャンバー
5を同心状にセットした。コイルチャンバー5は、トラ
ンス4に接続された加熱コイルとN2ガスシールド機構
とを内蔵しており、油圧シリンダー6にてトランス4に
機械的に結合されている。
The clamps 2a, 2b are connected to a transformer 4 via hydraulic cylinders 3a, 3b. Next, carbon steel pipe 1
A half-split coil chamber 5 was set concentrically on the outer surface side of the butt portion of a and lb. The coil chamber 5 contains a heating coil connected to the transformer 4 and an N2 gas shield mechanism, and is mechanically coupled to the transformer 4 by a hydraulic cylinder 6.

そして、コイルチャンバー5内のN2ガスシールド機構
よりN2ガスを流出させると共に、炭素鋼鋼管1a、l
b内にN2ガスを流通させて、炭素@鋼管1a、lbの
突合せ部を内面側および外面側からガスシールドする一
方、コイルチャンバー5内の加熱コイルに通電を行って
、突合せ部を種々の温度に加熱保持した。加熱により突
合せ部が管軸方向に熱膨張して、その端面間に加圧力が
付与される。クランプ2a、2bの支持剛性を変化させ
ることにより、炭素w4綱管1a、lbに対する拘束力
を調整して、端面間に付加される加圧力の調整を行った
。加熱温度およびその保持時間は、トランス4に接続さ
れる高周波電源で調整し、雰囲気中の0□量はシールド
ガス流星で調整した。
Then, while letting N2 gas flow out from the N2 gas shield mechanism in the coil chamber 5, the carbon steel pipes 1a and 1
N2 gas is passed through the chamber 5 to gas-shield the butt part of the carbon@steel pipes 1a and lb from the inner and outer sides, while the heating coil in the coil chamber 5 is energized to heat the butt part to various temperatures. It was heated and maintained at . The abutting portion thermally expands in the tube axis direction due to heating, and a pressurizing force is applied between the end faces. By changing the support rigidity of the clamps 2a, 2b, the restraining force on the carbon w4 wire pipes 1a, lb was adjusted, and the pressing force applied between the end faces was adjusted. The heating temperature and its holding time were adjusted by a high frequency power source connected to the transformer 4, and the amount of 0□ in the atmosphere was adjusted by a shielding gas meteor.

接合後、その接合部から第2図に示す試験片を採取し、
その試験片に引張試験を施して接合温度を調査した。調
査結果を接合条件と共に第3表および第4表に示す。
After joining, a test piece shown in Figure 2 was taken from the joint,
The test piece was subjected to a tensile test to investigate the bonding temperature. The investigation results are shown in Tables 3 and 4 together with the bonding conditions.

A1−2Gは本発明例であり、いずれも被接合面の粗さ
が100μmRma xに調整されているにもかかわら
ず、40 kg f 7mm2前後の接合強度(母材破
断)を示している。
A1-2G is an example of the present invention, and both exhibit a bonding strength (base material fracture) of around 40 kg f 7 mm2, even though the roughness of the surfaces to be bonded is adjusted to 100 μmRmax.

これに対し、A27は加圧力およびインサート層の層厚
が不足しているので、接合強度が低い。
On the other hand, A27 has a low bonding strength because the pressing force and the thickness of the insert layer are insufficient.

A2Bはさらに接合雰囲気の不活性度が低いために、被
接合面粗さが50μmRmayに仕上げられているにも
かかわらず接合強度が低い。A29は層厚が不足してい
るので、加圧力を1.6 kg f /mm”に上昇さ
せても十分な接合強度は得られていない。
Furthermore, since the inertness of the bonding atmosphere in A2B is low, the bonding strength is low even though the surface roughness to be bonded is finished to 50 μmRmay. Since the layer thickness of A29 is insufficient, sufficient bonding strength cannot be obtained even if the pressing force is increased to 1.6 kgf/mm''.

A31〜44はインサートaが本発明の定める粉末組成
ではない粉末を素材としており、加圧力、層厚のいかん
にかかわらず接合強度が低い。しがも、A38〜44で
は加圧力を]、 6 kg f /閣2に上昇させても
十分な接合強度は得られていない。
In A31 to A44, the insert a is made of powder that does not have the powder composition defined by the present invention, and the bonding strength is low regardless of the pressing force or layer thickness. However, in A38-44, even if the pressing force is increased to 6 kgf/kaku2, sufficient bonding strength is not obtained.

〔発明の効果〕〔Effect of the invention〕

本発明の突合せ接合法は、粉末を使用してインサートi
を形成するので、被接合面の形状に関係なく、被接合面
にインサート材料を容易かつ確実に固定することができ
る。しかも、優れた接合強度が保証され、かつ被接合面
粗さの許容範囲が広い。従って、配管現場等での現場施
工において、確実性、施工性に著しく優れた接合作業を
可能にする。そして、その効果は管径に関係なく享受で
き、200A以上の大径管を配管する場合等に特に大き
い作業性改善効果が得られる。
The butt joining method of the present invention uses powder to insert i
, the insert material can be easily and reliably fixed to the surfaces to be joined, regardless of the shape of the surfaces to be joined. Furthermore, excellent bonding strength is guaranteed, and the tolerance range for the roughness of the surfaces to be bonded is wide. Therefore, in on-site construction at piping sites, etc., it is possible to perform joining work with outstanding reliability and workability. The effect can be enjoyed regardless of the pipe diameter, and a particularly large workability improvement effect can be obtained when piping a large diameter pipe of 200A or more.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の接合法の一実施態(裏を示す模式図、
第2図は試験片の形状説明図である。 図中、la、lb:E管、2a、2b:クランプ、4ニ
ドランス、5;コイルチャンハ第 2 図 第 ■ 図 a Q b b
FIG. 1 is an embodiment of the joining method of the present invention (schematic diagram showing the back side,
FIG. 2 is an explanatory diagram of the shape of the test piece. In the figure, la, lb: E tube, 2a, 2b: clamp, 4 Nidransu, 5; coil handle Figure 2 Figure ■ Figure a Q b b

Claims (1)

【特許請求の範囲】[Claims] 1、鋼の突合せ接合法において、被接合面の少なくとも
一方に、重量%でCr:10〜20%、Si:4〜10
%、B:1〜5%を含み、残部実質的にNiからなる粉
末を用いて層厚75〜200μmのインサート層を形成
し、次いで、前記被接合面を相互に突合せ、突合せ部を
不活性雰囲気中で前記インサート層の融点を超える温度
に60秒以上加熱すると共に、突合せ部に0.5kgf
/mm^2以上の加圧力を加えることを特徴とする鋼の
突合せ接合法。
1. In the steel butt joining method, at least one of the surfaces to be joined has Cr: 10 to 20% and Si: 4 to 10% by weight.
%, B: 1 to 5%, and the remainder substantially consists of Ni to form an insert layer with a layer thickness of 75 to 200 μm, and then the surfaces to be joined are abutted against each other, and the abutted portion is inert. The insert layer is heated in an atmosphere to a temperature exceeding the melting point of the insert layer for 60 seconds or more, and 0.5 kgf is applied to the butt part.
A steel butt joining method characterized by applying a pressing force of /mm^2 or more.
JP14388089A 1989-06-06 1989-06-06 Method for butt-joining steel Pending JPH038555A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14388089A JPH038555A (en) 1989-06-06 1989-06-06 Method for butt-joining steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14388089A JPH038555A (en) 1989-06-06 1989-06-06 Method for butt-joining steel

Publications (1)

Publication Number Publication Date
JPH038555A true JPH038555A (en) 1991-01-16

Family

ID=15349168

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14388089A Pending JPH038555A (en) 1989-06-06 1989-06-06 Method for butt-joining steel

Country Status (1)

Country Link
JP (1) JPH038555A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007075867A (en) * 2005-09-15 2007-03-29 Fukuda Metal Foil & Powder Co Ltd Ni BRAZING FILLER METAL ALLOY

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007075867A (en) * 2005-09-15 2007-03-29 Fukuda Metal Foil & Powder Co Ltd Ni BRAZING FILLER METAL ALLOY
JP4690156B2 (en) * 2005-09-15 2011-06-01 福田金属箔粉工業株式会社 Ni brazing alloy

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