JPH0369623A - Flame-retardant tinsel yarn - Google Patents
Flame-retardant tinsel yarnInfo
- Publication number
- JPH0369623A JPH0369623A JP20423889A JP20423889A JPH0369623A JP H0369623 A JPH0369623 A JP H0369623A JP 20423889 A JP20423889 A JP 20423889A JP 20423889 A JP20423889 A JP 20423889A JP H0369623 A JPH0369623 A JP H0369623A
- Authority
- JP
- Japan
- Prior art keywords
- flame
- retardant
- film
- aluminum foil
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 56
- 239000003063 flame retardant Substances 0.000 title claims description 56
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 24
- 239000011888 foil Substances 0.000 claims abstract description 22
- 239000000853 adhesive Substances 0.000 claims abstract description 20
- 230000001070 adhesive effect Effects 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims description 52
- 239000011347 resin Substances 0.000 claims description 52
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 31
- 229910052737 gold Inorganic materials 0.000 claims description 31
- 239000010931 gold Substances 0.000 claims description 31
- 244000062175 Fittonia argyroneura Species 0.000 claims description 29
- 241000218202 Coptis Species 0.000 claims description 28
- 238000000576 coating method Methods 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 16
- 238000005520 cutting process Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- -1 polyethylene terephthalate Polymers 0.000 abstract description 7
- 239000000654 additive Substances 0.000 abstract description 5
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003960 organic solvent Substances 0.000 abstract description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract description 4
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 3
- 239000004925 Acrylic resin Substances 0.000 abstract description 2
- 229920000178 Acrylic resin Polymers 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract description 2
- 230000009970 fire resistant effect Effects 0.000 abstract 5
- 238000010030 laminating Methods 0.000 abstract 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000007756 gravure coating Methods 0.000 description 2
- 230000000474 nursing effect Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 description 1
- LAXBNTIAOJWAOP-UHFFFAOYSA-N 2-chlorobiphenyl Chemical compound ClC1=CC=CC=C1C1=CC=CC=C1 LAXBNTIAOJWAOP-UHFFFAOYSA-N 0.000 description 1
- ANHAEBWRQNIPEV-UHFFFAOYSA-N 2-chloroethyl dihydrogen phosphate Chemical compound OP(O)(=O)OCCCl ANHAEBWRQNIPEV-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004693 Polybenzimidazole Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- DLMVDBDHOIWEJZ-UHFFFAOYSA-N isocyanatooxyimino(oxo)methane Chemical compound O=C=NON=C=O DLMVDBDHOIWEJZ-UHFFFAOYSA-N 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 239000001048 orange dye Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
Description
【発明の詳細な説明】
［技術分野］
本発明は難燃金銀糸に関する。更に詳しくは個人用をは
じめ、旅館、ホテル、公会堂、ホール、映画館、病院、
老人ホームなどの公共的施設でのカーテン、カーペット
、寝具、衣服等に使用しても金銀糸自体が容易に燃焼し
ない難燃金銀糸に関する。DETAILED DESCRIPTION OF THE INVENTION [Technical Field] The present invention relates to flame-retardant gold and silver threads. For more details, including personal use, inns, hotels, public halls, halls, movie theaters, hospitals,
This invention relates to flame-retardant gold and silver threads that do not easily burn when used for curtains, carpets, bedding, clothing, etc. in public facilities such as nursing homes.
［従来の技術］
従来から、金銀糸としては、ポリエステルフィルムの両
面にアルミニウム蒸着層、上塗樹脂層を順次形成してな
る積層フィルムを細幅に裁断してなるものが知られてい
る。[Prior Art] Conventionally, it has been known that gold and silver threads are made by cutting a laminated film formed by sequentially forming an aluminum vapor-deposited layer and an overcoat resin layer on both sides of a polyester film into narrow widths.
［発明が解決しようとする問題点］
しかしながら、上記従来の金銀糸はつぎのごとき欠点を
宥する。[Problems to be Solved by the Invention] However, the above-mentioned conventional gold and silver threads overcome the following drawbacks.
つまりポリエステルフィルムにアルミニウム蒸着層およ
び上塗樹脂層が形成された積層フィルムを細幅に裁断し
てなるものであるから、容易に燃焼するので、個人用を
はじめ、旅館、ホテル、公会堂、ホール、映画館、病院
、老人ホームなどの公共的施設でのカーテン、カーペッ
ト、寝具、衣服等に使用した場合に一旦、火災等が発生
すると従来の金銀糸を使用したカーテン、カーペット、
寝具、衣服等が延焼を助長するという防災上極めて重大
な問題点を有するものてあった。In other words, it is made by cutting a laminated film consisting of a polyester film, an aluminum vapor deposited layer and a top coated resin layer into thin pieces, so it burns easily and is suitable for personal use, inns, hotels, public halls, auditoriums, movie theaters, etc. If a fire breaks out when used for curtains, carpets, bedding, clothing, etc. in public facilities such as buildings, hospitals, and nursing homes, conventional curtains, carpets, carpets, etc. using gold and silver thread will be destroyed.
Bedding, clothing, etc. had an extremely serious problem in terms of disaster prevention, as they encouraged the spread of fire.
本発明は上記従来の問題点に鑑み、容易に燃焼しない、
安心してカーテン、カーペット、寝具、衣服等に使用で
きる難燃金銀糸を提供することにある。In view of the above-mentioned conventional problems, the present invention provides a method that does not burn easily.
To provide flame-retardant gold and silver threads that can be safely used for curtains, carpets, bedding, clothing, etc.
［問題点を解決するための手段］
本発明は、アルミニウム箔の片面に難燃性樹脂塗膜を設
けてなるフィルム状物が二枚、前記アルミニウム箔を内
側にして引っ張り強度の大きい樹脂フィルムの両面に難
燃性樹脂接着剤を介して積層された構成の積層フィルム
を細幅に裁断したことを特徴とする難燃金銀糸に関する
。[Means for Solving the Problems] The present invention consists of two film-like materials each having a flame-retardant resin coating on one side of an aluminum foil, and a resin film having high tensile strength with the aluminum foil inside. The present invention relates to a flame-retardant gold and silver thread characterized by cutting a laminated film laminated on both sides with a flame-retardant resin adhesive into narrow widths.
［作 用］
本発明に用いるアルミニウム箔は、前記従来例における
金銀糸のアルミニウム蒸着層が単位重量あたりの表面積
か極端に大きく極めて燃焼しやすいのに比べて燃焼する
ことがない。また高価な連続式真空蒸着装置も必要とし
ないので多品種少量生産にも応じやすいなどの効果もあ
る。[Function] The aluminum foil used in the present invention does not burn compared to the aluminum vapor deposited layer of the gold and silver thread in the conventional example, which has an extremely large surface area per unit weight and is extremely easy to burn. In addition, it does not require expensive continuous vacuum evaporation equipment, making it easy to handle high-mix, low-volume production.
本発明に用いる難燃性樹脂塗膜は、前記従来例における
金銀系の上塗樹脂層がハイソリッドラッカーや繊維素系
等の通常可燃性の樹脂塗膜で有るため前記アルミニウム
蒸着層との相乗効果で一層金銀糸を燃えやすいものとし
ていたが１本発明の難燃金銀糸は燃焼することがない。The flame-retardant resin coating used in the present invention has a synergistic effect with the aluminum vapor deposited layer because the gold and silver-based top coat resin layer in the conventional example is a normally flammable resin coating such as high solid lacquer or cellulose. However, the flame-retardant gold and silver thread of the present invention does not burn.
本発明に用いる難燃性樹脂接着剤もまた前記難燃性樹脂
塗膜と同様に燃焼することがない。The flame-retardant resin adhesive used in the present invention also does not burn like the flame-retardant resin coating film.
本発明に用いる引っ張り強度の大きい樹脂フィルムは１
本発明は積層フィルムを細幅に裁断して得られる本発明
の難燃金銀糸に製織性、製編性。The resin film with high tensile strength used in the present invention is 1
The flame-retardant gold and silver thread of the present invention, which is obtained by cutting a laminated film into narrow widths, has excellent weavability and knitting properties.
製組紐性などの糸としての必要物性を付与する作用があ
る。It has the effect of imparting necessary physical properties as a thread, such as braidability.
［実施例］ つぎに図面にもとづき本発明の難燃金銀糸を説明する。[Example] Next, the flame-retardant gold and silver thread of the present invention will be explained based on the drawings.
第１図は本発明の難燃金銀糸の斜視図であり、円内はそ
の構成を示す概略拡大断面図である。第２図は本発明の
難燃金銀糸を他の糸条とを組み合せた撚合糸の実施態様
例を示す概略部分断面図である０図において（１０）は
難燃金銀糸、（１１）は難燃性樹脂塗膜、（１２）はア
ルミニウム箔、（１３）は難燃性樹脂接着剤、（１４）
は引っ張り強度の大きい樹脂フィルム、（２０）は糸条
である。FIG. 1 is a perspective view of the flame-retardant gold and silver thread of the present invention, and the area within the circle is a schematic enlarged sectional view showing its structure. FIG. 2 is a schematic partial cross-sectional view showing an embodiment of a twisted yarn in which the flame-retardant gold and silver threads of the present invention are combined with other yarns. In FIG. is a flame-retardant resin coating, (12) is an aluminum foil, (13) is a flame-retardant resin adhesive, (14)
(20) is a resin film with high tensile strength, and (20) is a thread.
難燃金銀糸（１０）を構成する難燃性樹脂塗膜（１１）
に用いる樹脂としては特に制限するものではないが、前
記アルミニウム箔にたいして密着性に優れていることが
要求されるほか、耐熱性と自己消火性とを兼備する必要
がある。かかる要求を満たす樹脂としては、たとえば熱
可塑性樹脂、熱硬化性樹脂、電子線硬化性樹脂、紫外線
硬化性樹脂のいずれもが用いられ、たとえばアクリル系
樹脂、塩化どニルー酢酸ビニル共重合体、ポリカーボネ
ート、ウレタン系樹脂、尿素系樹脂、メラミン系樹脂、
尿素−メラミン系樹脂、エポキシ系樹脂、アルキッド系
樹脂、アミノアルキッド系樹脂、ロジン変性マレイン酸
樹脂などの単独または混合物などが好ましく用いられる
。Flame-retardant resin coating (11) constituting flame-retardant gold and silver thread (10)
The resin used for this is not particularly limited, but it is required to have excellent adhesion to the aluminum foil, as well as heat resistance and self-extinguishing properties. Examples of resins that meet these requirements include thermoplastic resins, thermosetting resins, electron beam curable resins, and ultraviolet ray curable resins, such as acrylic resins, dinylphenyl chloride-vinyl acetate copolymers, and polycarbonates. , urethane resin, urea resin, melamine resin,
Preferably used are urea-melamine resins, epoxy resins, alkyd resins, aminoalkyd resins, rosin-modified maleic acid resins, and the like alone or in mixtures.
その厚さには制限はないが通常難燃性樹脂塗膜の厚みは
０．５〜５μｓの範囲、好ましくは０．５〜３μｓの範
囲から選ばれる。０．５μｓより薄いとアルミニウム箔
の保護を充分できず、金属光沢の低下が目立つなどして
好ましくない、 ３７４ｍより厚いと風合いが悪くな
り経済性の点から好ましくない、なお自己消火性を完全
にするために、難燃添加剤を配合する。Although there is no limit to the thickness, the thickness of the flame-retardant resin coating is usually selected from the range of 0.5 to 5 μs, preferably from the range of 0.5 to 3 μs. If it is thinner than 0.5 μs, it will not be able to protect the aluminum foil sufficiently and the metallic luster will be noticeably lowered, which is undesirable. If it is thicker than 374 m, the texture will deteriorate and it is unfavorable from an economic point of view. To achieve this, flame retardant additives are added.
本発明で用いる難燃添加剤として特に制限はないが、た
とえばリン酸エステル（トリクレジルホスフェート、ト
リブチルホスフェート、２ビフエニルホスフエート、ジ
フェニルクレシルホスフェート、ジフェニルオクチルホ
スフェート、ベータクロロエチルホスフェート、トリフ
ェニルホスフェート）、１Ｍ化物（塩化パラフィン、塩
化ジフェニル）や酸化アンチモンなどが使用できる。The flame retardant additive used in the present invention is not particularly limited, but examples include phosphoric acid esters (tricresyl phosphate, tributyl phosphate, 2-biphenyl phosphate, diphenyl cresyl phosphate, diphenyloctyl phosphate, beta-chloroethyl phosphate, triphenyl phosphate), 1M chloride (paraffin chloride, diphenyl chloride), antimony oxide, etc. can be used.
難燃性樹脂塗膜の形成は、前記難燃性樹脂塗膜を形成す
るための樹脂の有機溶剤溶液、水溶液などをロールコー
ティング法、グラビアコーティング法、リバースコーテ
ィング法、スプレィコーティング法などの通常のコーテ
ィング法により塗布し、乾燥（熱硬化性樹脂、電子線硬
化性樹脂、紫外線硬化性樹脂などの場合は硬化）するこ
とによって行われる。尚、難燃性樹脂塗膜はそれを形成
する溶液中に通常の染料、顔料や蓄光蛍光などの特殊染
料や顔料などを適宜添加して所望の色に彩色することも
できる。The flame-retardant resin coating film is formed by applying a resin organic solvent solution, aqueous solution, etc. to form the flame-retardant resin coating film using a conventional method such as a roll coating method, gravure coating method, reverse coating method, or spray coating method. This is done by applying by a coating method and drying (curing in the case of thermosetting resin, electron beam curable resin, ultraviolet curable resin, etc.). Incidentally, the flame-retardant resin coating film can also be colored into a desired color by appropriately adding ordinary dyes, pigments, special dyes and pigments such as phosphorescent fluorescent, etc. to the solution forming the film.
難燃金銀糸（１０）を構成するアルミニウム箔（１２）
の厚さは通常４〜２０μｓの範囲、好ましくは６〜８μ
ｓの範囲から選ばれる。アルミニウム箔の厚さが４μｓ
未満ではアルミニウム箔の価格が高く広幅長尺のものの
入手が困難で好ましくない、一方２０μｓを越えると剛
直な金銀糸となり風合に欠けるので一般向きでなく好ま
しくない。Aluminum foil (12) constituting flame-retardant gold and silver thread (10)
The thickness is usually in the range of 4 to 20 μs, preferably 6 to 8 μs.
selected from the range of s. The thickness of aluminum foil is 4μs
If it is less than 20 μs, the aluminum foil becomes expensive and it is difficult to obtain a wide and long one, which is undesirable. On the other hand, if it exceeds 20 μs, it becomes a rigid gold and silver thread and lacks texture, so it is not suitable for general use and is not preferred.
難燃金銀糸（ｌＯ）を構成するための難燃性樹脂接着剤
（１３）としては特に制限するものではないが、前記ア
ルミニウム箔および引っ張り強度の大きい樹脂フィルム
にたいしても密着性に優れていることが要求されるほか
、耐熱性と自己消火性とを兼備する必要がある。かかる
要求を満たす接着剤としては、たとえばアクリル系、酢
酸ビニル系、塩化ビニル系、ポリエチレン系、スチレン
−ブタジェン系などのエマルジョン接着剤の単独または
ブレンド物、エチレン−酢酸ビニル系、塩素化ポリプロ
ピレン系、塩化ビニル−酢酸ビニル系、アクリル系、ア
クリル−塩化ビニル−酢酸ビニル系、フェノール系、キ
シレン系、石油樹脂系、ユリア系、メラミン系、不飽和
ポリエステル系、アルキド系、エポキシ系、ウレタン系
、シリコン系、フラン系などの有機溶剤型接着剤の単独
またはブレンド物に難燃添加剤を配合したものがあげら
れる。The flame-retardant resin adhesive (13) for constituting the flame-retardant gold and silver thread (IO) is not particularly limited, but it should have excellent adhesion to the aluminum foil and resin film with high tensile strength. In addition to being required, it must also have heat resistance and self-extinguishing properties. Adhesives that meet these requirements include, for example, emulsion adhesives such as acrylic, vinyl acetate, vinyl chloride, polyethylene, styrene-butadiene, etc. alone or in blends, ethylene-vinyl acetate, chlorinated polypropylene, Vinyl chloride-vinyl acetate, acrylic, acrylic-vinyl chloride-vinyl acetate, phenol, xylene, petroleum resin, urea, melamine, unsaturated polyester, alkyd, epoxy, urethane, silicone Examples include organic solvent-based adhesives such as furan-based adhesives, alone or in blends, with flame retardant additives added.
難燃性樹脂接着剤（１３）はこれら！ｔｃ着剤のエマル
ジョンや有機溶剤溶液などをロールコーティング法、グ
ラビアコーティング法、リバースコーティング法、スプ
レィコーティング法などの通常のコーティングにより塗
布し、乾燥することによって行われる。難燃性樹脂接着
剤の厚さは通常０．５〜５−の範囲、より好ましくは０
．５〜３μｓの範囲から選ばれる。接着剤の厚さが０．
５μｓ未満では充分な接着強度が得られず好ましくない
。一方５μｓを越えても接着強度に変りがなく、風合い
も損ない経済性の点からも好ましくない。These are the flame-retardant resin adhesives (13)! This is done by applying an emulsion of a TC adhesive, an organic solvent solution, or the like by a conventional coating method such as a roll coating method, a gravure coating method, a reverse coating method, or a spray coating method, and then drying it. The thickness of the flame retardant resin adhesive is usually in the range of 0.5 to 5, more preferably 0.
．． It is selected from the range of 5 to 3 μs. Adhesive thickness is 0.
If it is less than 5 μs, sufficient adhesive strength cannot be obtained, which is not preferable. On the other hand, if it exceeds 5 μs, there is no change in adhesive strength, the texture is impaired, and it is not preferable from an economic point of view.
難燃金銀糸（１０）を構成するための引っ張り強度の大
きい樹脂フィルム（１４）としては特に制限するもので
はないが、たとえばポリエチレンテレフタレート、ポリ
アミド、ポリアミドイミド、ポリカーボネートなどの樹
脂フィルムがあげられる。なかでも延伸ポリエチレンテ
レフタレート樹脂フィルムが価格、強度、取り扱い性な
どの点て好ましい。その厚さは通常４〜２５μｓ程度で
ある。The resin film (14) with high tensile strength for forming the flame-retardant gold and silver thread (10) is not particularly limited, but examples thereof include resin films such as polyethylene terephthalate, polyamide, polyamideimide, and polycarbonate. Among these, a stretched polyethylene terephthalate resin film is preferred in terms of price, strength, ease of handling, and the like. Its thickness is usually about 4 to 25 μs.
かくしてえらた積層フィルム状物はマイクロスリッター
で０．１５〜５問程度の細幅に裁断して本発明の難燃金
銀糸をえる。The thus selected laminated film material is cut into narrow widths of about 0.15 to 5 pieces using a micro slitter to obtain the flame-retardant gold and silver thread of the present invention.
前記本発明の難燃金銀糸はそのまま平糸として使用して
もよいが、芯糸に丸撚りするか、羽衣撚りするか、蛇腹
撚りするか、あるいは本発明の難燃金銀糸を芯にして他
の糸をタヌキ撚りするなどして撚糸としてもよい。The flame-retardant gold and silver thread of the present invention may be used as a flat thread as it is, but it may be twisted round, feather-twisted, bellows-twisted as a core thread, or used in other ways using the flame-retardant gold and silver thread of the present invention as a core. It is also possible to make twisted thread by twisting the threads.
本発明の難燃金銀糸は最外層の難燃性樹脂塗膜をはじめ
その構成のほとんどな難燃性ないしは不燃性素材で構成
したので難燃金銀糸自体が火災などによって延焼するこ
とはない。Since the flame-retardant gold and silver thread of the present invention is made of mostly flame-retardant or non-combustible materials, including the outermost flame-retardant resin coating, the flame-retardant gold and silver thread itself will not spread in the event of a fire.
つぎに実施例をあげて本発明を説明する。Next, the present invention will be explained with reference to Examples.
実施例１
厚さ７−のアルミニウム箔の片面に二液型エポキシ−イ
ソシアネート樹脂５０部、トリクレジルホスフェート５
部、酢酸エチル２０部、メチルエチルケトン２０部、シ
クロヘキサノン１０部からなる難燃性樹脂塗膜用塗料を
グラビア方式で塗布し、乾燥し、加熱硬化させて、厚さ
ｌμｓの難燃性樹脂塗膜を形成してアルミニウム箔の片
面に難燃性樹脂塗膜を設けてなるフィルム状物を二枚を
作成した。Example 1 50 parts of two-part epoxy-isocyanate resin and 5 parts of tricresyl phosphate were applied to one side of a 7-thick aluminum foil.
A flame-retardant resin coating composition consisting of 20 parts of ethyl acetate, 20 parts of methyl ethyl ketone, and 10 parts of cyclohexanone was applied using a gravure method, dried, and cured by heating to form a flame-retardant resin coating film with a thickness of lμs. Two film-like products were prepared by forming a flame-retardant resin coating on one side of an aluminum foil.
ついで厚さ１２Ｑの二軸延伸ポリエチレンテレフタレー
トフィルムの両面に二液型ポリウレタン樹脂５０部、ト
リクレジルホスフェート ５部、メチルエチルケトン４
５部からなる難燃性樹脂接着剤を用いて前記アルミニウ
ム箔の片面に難燃性樹脂塗膜を設けてなるフィルム状物
のアルミニウム箔側を内側にして貼り合せて積層フィル
ムを作成した。Next, 50 parts of two-component polyurethane resin, 5 parts of tricresyl phosphate, and 4 parts of methyl ethyl ketone were applied to both sides of a biaxially stretched polyethylene terephthalate film having a thickness of 12Q.
Using a flame-retardant resin adhesive consisting of 5 parts, a film-like film formed by providing a flame-retardant resin coating on one side of the aluminum foil was bonded with the aluminum foil side facing inside to prepare a laminated film.
えられた積層フィルムをマイクロスリッターで１２０切
（０，２５２ｍ５幅）の細幅に裁断して銀色の本発明の
難燃金銀糸をえた。The obtained laminated film was cut into 120 pieces (width: 0.252 m5) using a micro slitter to obtain silver flame-retardant gold and silver threads of the present invention.
実施例２
実施例１の難燃性樹脂塗膜用塗料にオレンジ色染料を５
蔀添加したものを用いたほかは同様にして金色の本発明
の難燃金銀糸をえた。Example 2 Five orange dyes were added to the flame-retardant resin paint of Example 1.
A gold-colored flame-retardant gold and silver thread of the present invention was obtained in the same manner, except that the thread containing silver was used.
［発明の効果］
実施例１および実施例２でえられた難燃金銀糸を用いて
ポリベンゾイミダゾール糸（米国 セラニーズ社製）と
共に製織した。[Effects of the Invention] The flame-retardant gold and silver threads obtained in Examples 1 and 2 were woven together with polybenzimidazole threads (manufactured by Celanese, USA).
えられた織布には所望のメタリック模様が表現されてい
た。The desired metallic pattern was expressed in the resulting woven fabric.
また他の諸物性は下記の通りてあった。Other physical properties were as follows.
耐熱性： ＪＩＳ Ｋ ６３２８
異常なし
防炎性二ＪＩＳ Ｌ １０９１ Ａ２法（４５°メツ
ケルバーナ法）
残じん時間 ０秒
残炎時間 ０秒
炭化面積 １００１以下
耐水圧二ＪＩＳ Ｌ １０９２
１０００１冨以上Heat resistance: JIS K 6328 No abnormalities Flame retardant2 JIS L 1091 A2 method (45° Metkel burner method) Residual dust time 0 seconds Afterflame time 0 seconds Carbonized area 1001 or less Water pressure resistance2 JIS L 1092 10001 or more
第１図は本発明の難燃金銀糸の斜視図であり、円内はそ
の構成を示す概略拡大断面図である。第２図は本発明の
難燃金銀糸を他の糸条と組み合せた撚合糸の実施態様例
を示す概略部分断面図である。
（図面の符号）
（１０） ：難燃金銀糸
（１１） ：難燃性樹脂塗膜
（１２）ニアルミニウム箔
（ｔ３）：難燃性樹脂接着剤
（ｉｌｌ） ：引っ張り強度の大きｂＸＭＡ脂フィルム
（２０） ：糸条FIG. 1 is a perspective view of the flame-retardant gold and silver thread of the present invention, and the area within the circle is a schematic enlarged sectional view showing its structure. FIG. 2 is a schematic partial sectional view showing an embodiment of a twisted yarn in which the flame-retardant gold and silver yarn of the present invention is combined with other yarns. (Drawing code) (10): Flame-retardant gold and silver thread (11): Flame-retardant resin coating (12) Nialuminum foil (t3): Flame-retardant resin adhesive (ill): High tensile strength bXMA resin film (20) : Yarn
Claims (1)
るフィルム状物が二枚、前記アルミニウム箔を内側にし
て引っ張り強度の大きい樹脂フィルムの両面に難燃性樹
脂接着剤を介して積層された構成の積層フィルムを細幅
に裁断したことを特徴とする難燃金銀糸。1. Two film-like materials each having a flame-retardant resin coating on one side of aluminum foil are laminated with the aluminum foil inside and a flame-retardant resin adhesive on both sides of a resin film with high tensile strength. A flame-retardant gold and silver thread made by cutting a laminated film with a thin structure into thin pieces.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20423889A JP2878720B2 (en) | 1989-08-07 | 1989-08-07 | Flame retardant gold and silver thread |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20423889A JP2878720B2 (en) | 1989-08-07 | 1989-08-07 | Flame retardant gold and silver thread |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0369623A true JPH0369623A (en) | 1991-03-26 |
| JP2878720B2 JP2878720B2 (en) | 1999-04-05 |
Family
ID=16487137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20423889A Expired - Fee Related JP2878720B2 (en) | 1989-08-07 | 1989-08-07 | Flame retardant gold and silver thread |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2878720B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7348518B2 (en) | 2004-03-09 | 2008-03-25 | Matsushita Electric Industrial Co., Ltd. | Welding apparatus |
| KR101037703B1 (en) * | 2009-06-30 | 2011-05-30 | 코오롱글로텍주식회사 | Polyurethane slit flame retardant fabric for automobile interior materials and polyurethane slit flame retardant fabric manufactured by the method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3900295B2 (en) * | 2004-03-29 | 2007-04-04 | 尾池工業株式会社 | Gold and silver thread |
-
1989
- 1989-08-07 JP JP20423889A patent/JP2878720B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7348518B2 (en) | 2004-03-09 | 2008-03-25 | Matsushita Electric Industrial Co., Ltd. | Welding apparatus |
| KR101037703B1 (en) * | 2009-06-30 | 2011-05-30 | 코오롱글로텍주식회사 | Polyurethane slit flame retardant fabric for automobile interior materials and polyurethane slit flame retardant fabric manufactured by the method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2878720B2 (en) | 1999-04-05 |
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