JP2878720B2 - Flame retardant gold and silver thread - Google Patents
Flame retardant gold and silver threadInfo
- Publication number
- JP2878720B2 JP2878720B2 JP20423889A JP20423889A JP2878720B2 JP 2878720 B2 JP2878720 B2 JP 2878720B2 JP 20423889 A JP20423889 A JP 20423889A JP 20423889 A JP20423889 A JP 20423889A JP 2878720 B2 JP2878720 B2 JP 2878720B2
- Authority
- JP
- Japan
- Prior art keywords
- flame
- retardant
- gold
- resin
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 56
- 239000003063 flame retardant Substances 0.000 title claims description 56
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims description 13
- 229910052737 gold Inorganic materials 0.000 title claims description 13
- 239000010931 gold Substances 0.000 title claims description 13
- 241000218202 Coptis Species 0.000 title description 3
- 244000062175 Fittonia argyroneura Species 0.000 title description 3
- 229920005989 resin Polymers 0.000 claims description 59
- 239000011347 resin Substances 0.000 claims description 59
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 24
- 229910052782 aluminium Inorganic materials 0.000 claims description 24
- 238000000576 coating method Methods 0.000 claims description 20
- 239000011888 foil Substances 0.000 claims description 20
- 239000000853 adhesive Substances 0.000 claims description 18
- 230000001070 adhesive effect Effects 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 17
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 11
- 229910052709 silver Inorganic materials 0.000 claims description 11
- 239000004332 silver Substances 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- PQTCMBYFWMFIGM-UHFFFAOYSA-N gold silver Chemical compound [Ag].[Au] PQTCMBYFWMFIGM-UHFFFAOYSA-N 0.000 description 22
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- -1 polyethylene Polymers 0.000 description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000007756 gravure coating Methods 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000000474 nursing effect Effects 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 description 1
- LAXBNTIAOJWAOP-UHFFFAOYSA-N 2-chlorobiphenyl Chemical compound ClC1=CC=CC=C1C1=CC=CC=C1 LAXBNTIAOJWAOP-UHFFFAOYSA-N 0.000 description 1
- ANHAEBWRQNIPEV-UHFFFAOYSA-N 2-chloroethyl dihydrogen phosphate Chemical compound OP(O)(=O)OCCCl ANHAEBWRQNIPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- YEJHJDVXDVNJMA-UHFFFAOYSA-N C(C)(=O)OC=C.C(=O)(C=C)C=CCl Chemical compound C(C)(=O)OC=C.C(=O)(C=C)C=CCl YEJHJDVXDVNJMA-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004693 Polybenzimidazole Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000006269 biphenyl-2-yl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C1=C(*)C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- DLMVDBDHOIWEJZ-UHFFFAOYSA-N isocyanatooxyimino(oxo)methane Chemical compound O=C=NON=C=O DLMVDBDHOIWEJZ-UHFFFAOYSA-N 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 239000001048 orange dye Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Description
【発明の詳細な説明】 ［技術分野］ 本発明は難燃金銀糸に関する。更に詳しくは個人用を
はじめ、旅館、ホテル、公会堂、ホール、映画館、病
院、老人ホームなどの公共的施設でのカーテン、カーペ
ット、寝具、衣服等に使用しても金銀糸自体が容易に燃
焼しない難燃金銀糸に関する。Description: TECHNICAL FIELD The present invention relates to a flame-retardant gold-silver yarn. More specifically, the gold and silver yarn itself burns easily even when used for curtains, carpets, bedding, clothes, etc. in public facilities such as inns, hotels, public halls, halls, movie theaters, hospitals, nursing homes, etc. Not about flame retardant gold and silver yarn.
［従来の技術］ 従来から、金銀糸としては、ポリエステルフイルムの
両面にアルミニウム蒸着層、上塗樹脂層を順次形成して
なる積層フイルムを細幅に裁断してなるものが知られて
いる。[Prior Art] Hitherto, as a gold / silver thread, a thread obtained by cutting a laminated film, which is formed by sequentially forming an aluminum vapor-deposited layer and an overcoat resin layer on both sides of a polyester film, into narrow widths, has been known.
［発明が解決しようとする問題点］ しかしながら、上記従来の金銀糸はつぎのごとき欠点
を有する。[Problems to be Solved by the Invention] However, the conventional gold and silver yarns have the following disadvantages.
つまりポリエステルフイルムにアルミニウム蒸着層お
よび上塗樹脂層が形成された積層フイルムを細幅に裁断
してなるものであるから、容易に燃焼するので、個人用
をはじめ、旅館、ホテル、公会堂、ホール、映画館、病
院、老人ホームなどの公共的施設でのカーテン、カーペ
ット、寝具、衣服等に使用した場合に一旦、火災等が発
生すると従来の金銀糸を使用したカーテン、カーペッ
ト、寝具、衣服等が延焼を助長するという防炎上極めて
重大な問題点を有するものであった。In other words, a laminated film in which an aluminum vapor-deposited layer and an overcoat resin layer are formed on a polyester film is cut into narrow widths, so that it can be easily burned, including personal use, inns, hotels, public halls, halls, and movies. Once used for curtains, carpets, bedding, clothes, etc. in public facilities such as halls, hospitals, nursing homes, etc., once a fire etc. occurs, conventional curtains using gold and silver thread, carpets, bedding, clothes, etc. will spread. Has a very serious problem in terms of flame prevention.
本発明は上記従来の問題点に鑑み、容易に燃焼しな
い、安心してカーテン、カーペット、寝具、衣服等に使
用できる難燃金銀糸を提供することにある。SUMMARY OF THE INVENTION The present invention has been made in consideration of the above-described conventional problems, and has as its object to provide a flame-retardant gold / silver yarn that does not easily burn and can be used with ease in curtains, carpets, bedding, clothes, and the like.
［問題点を解決するための手段］ 本発明は、アルミニウム箔の片面に難燃性樹脂塗膜を
設けてなるフイルム状物が二枚、前記アルミニウム箔を
内側にして引っ張り強度の大きい樹脂フイルムの両面に
難燃性樹脂接着剤を介して積層された構成の積層フイル
ムを細幅に裁断したことを特徴とする難燃金銀糸に関す
る。[Means for Solving the Problems] The present invention relates to a resin film having a large tensile strength with two pieces of a film formed by providing a flame-retardant resin coating film on one side of an aluminum foil, with the aluminum foil inside. The present invention relates to a flame-retardant gold-silver yarn obtained by cutting a laminated film having a structure laminated on both sides via a flame-retardant resin adhesive into narrow widths.
［作用］ 本発明に用いるアルミニウム箔は、従来例における金
銀糸のアルミニウム蒸着層が単位重量あたりの表面積が
極端に大きく極めて燃焼しやすいのに比べて燃焼するこ
とがない。また高価な連続式真空蒸着装置も必要としな
いので多品種少量生産にも応じやすいなどの効果もあ
る。[Function] The aluminum foil used in the present invention does not burn as compared with the conventional example in which the aluminum vapor-deposited layer of gold-silver thread has an extremely large surface area per unit weight and is extremely easy to burn. Further, since an expensive continuous vacuum evaporation apparatus is not required, there is an effect that it is easy to cope with high-mix low-volume production.
本発明に用いる難燃性樹脂塗膜は、前記従来例におけ
る金銀糸の上塗樹脂層がハイソリッドラッカーや繊維素
系等の通常可燃性の樹脂塗膜で有るため前記アルミニウ
ム蒸着層との相乗効果で一層金銀糸を燃えやすいものと
していたが、本発明の難燃金銀糸は燃焼することがな
い。The flame-retardant resin film used in the present invention has a synergistic effect with the aluminum vapor-deposited layer because the overcoating resin layer of the gold and silver yarn in the conventional example is a normally flammable resin film such as a high solid lacquer or a fibrous material. Although the gold and silver yarns are made more flammable, the flame-retardant gold and silver yarns of the present invention do not burn.
本発明に用いる難燃性樹脂接着剤もまた前記難燃性樹
脂塗膜と同様に燃焼することがない。The flame-retardant resin adhesive used in the present invention also does not burn like the flame-retardant resin coating film.
本発明に用いる引っ張り強度の大きい樹脂フイルム
は、本発明は積層フイルムを細幅に裁断して得られる本
発明の難燃金銀糸に製繊性、製編性、製組紐性などの糸
としての必要物性を付与する作用がある。The resin film having a high tensile strength used in the present invention is used in the present invention as a yarn having a fineness, knitting property, braiding property, etc. in the flame-retardant gold-silver yarn of the present invention obtained by cutting a laminated film into a narrow width. Has the effect of imparting necessary physical properties.
［実施例］ つぎに図面にもとづき本発明の難燃金銀糸を説明す
る。第１図は本発明の難燃金銀糸の斜視図であり、円内
はその構成を示す概略拡大断面図である。第２図は本発
明の難燃金銀糸を他の糸条とを組み合せた撚合糸の実施
態様例を示す概略部分断面図である。図において（10）
は難燃金銀糸、（11）は難燃性樹脂塗膜、（12）はアル
ミニウム箔、（13）は難燃性樹脂接着剤、（14）は引っ
張り強度の大きい樹脂フイルム、（20）は糸条である。[Example] Next, the flame-retardant gold-silver yarn of the present invention will be described with reference to the drawings. FIG. 1 is a perspective view of the flame-retardant gold-silver yarn of the present invention, and the inside of a circle is a schematic enlarged sectional view showing the configuration. FIG. 2 is a schematic partial sectional view showing an embodiment of a twisted yarn obtained by combining the flame-retardant gold-silver yarn of the present invention with another yarn. In the figure (10)
Is a flame-retardant gold-silver thread, (11) is a flame-retardant resin coating, (12) is an aluminum foil, (13) is a flame-retardant resin adhesive, (14) is a resin film with high tensile strength, (20) is It is a thread.
難燃金銀糸（10）を構成する難燃性樹脂塗膜（11）に
用いる樹脂としては特に制限するものではないが、前記
アルミニウム箔にたいして密着性に優れていることが要
求されるほか、耐熱性と自己消火性とを兼備する必要が
ある。かかる要求を満たす樹脂としては、たとえば熱可
塑性樹脂、熱硬化性樹脂、電子線硬化性樹脂、紫外線硬
化性樹脂のいずれもが用いられ、たとえばアクリル系樹
脂、塩化ビニル−酢酸ビニル共重合体、ポリカーボネー
ト、ウレタン系樹脂、尿素系樹脂、メラミン系樹脂、尿
素−メラミン系樹脂、エポキシ系樹脂、アルキッド系樹
脂、アミノアルキッド系樹脂、ロジン変性マレイン酸樹
脂などの単独または混合物などが好ましく用いられる。The resin used for the flame-retardant resin coating film (11) constituting the flame-retardant gold-silver thread (10) is not particularly limited, but it is required that the resin has excellent adhesion to the aluminum foil, It is necessary to combine the property with self-extinguishing. As the resin satisfying such requirements, for example, any of a thermoplastic resin, a thermosetting resin, an electron beam-curable resin, and an ultraviolet-curable resin is used. For example, acrylic resin, vinyl chloride-vinyl acetate copolymer, polycarbonate , Urethane-based resins, urea-based resins, melamine-based resins, urea-melamine-based resins, epoxy-based resins, alkyd-based resins, aminoalkyd-based resins, rosin-modified maleic resins, and the like, alone or in combination.
その厚さには制限はないが通常難燃性樹脂塗膜の厚み
は0.5〜５μｍの範囲、好ましくは0.5〜３μｍの範囲か
ら選ばれる。0.5μｍより薄いとアルミニウム箔の保護
を充分できず、金属光沢の低下が目立つなどして好まし
くない。３μｍより厚いと風合いが悪くなり経済性の点
から好ましくない。なお自己消火性を完全にするため
に、難燃添加剤を配合する。Although there is no limitation on the thickness, the thickness of the flame-retardant resin coating film is generally selected from the range of 0.5 to 5 μm, preferably the range of 0.5 to 3 μm. If the thickness is less than 0.5 μm, the aluminum foil cannot be sufficiently protected, and the metallic luster is undesirably reduced. If the thickness is more than 3 μm, the texture becomes poor, which is not preferable in terms of economy. In order to make the self-extinguishing property complete, a flame retardant additive is added.
本発明で用いる難燃添加剤として特に制限はないが、
たとえばリン酸エステル（トリクレシルホスフェート、
トリブチルホスフェート、２ビフェニルホスフェート、
ジフェニルクレシルホスフェート、ジフェニルオクチル
ホスフェート、ベータクロロエチルホスフェート、トリ
フェニルホスフェート）、塩化物（塩化パラフィン、塩
化ジフェニル）や酸化アンチモンなどが使用できる。There is no particular limitation on the flame retardant additive used in the present invention,
For example, phosphate esters (tricresyl phosphate,
Tributyl phosphate, 2 biphenyl phosphate,
Diphenylcresyl phosphate, diphenyloctyl phosphate, beta chloroethyl phosphate, triphenyl phosphate), chlorides (paraffin chloride, diphenyl chloride), antimony oxide, and the like can be used.
難燃性樹脂塗膜の形成は、前記難燃性樹脂塗膜を形成
するための樹脂の有機溶剤溶液、水溶液などをロールコ
ーティング法、グラビアコーティング法、リバースコー
ティング法、スプレイコーティング法などの通常のコー
ティング法により塗布し、乾燥（熱硬化性樹脂、電子線
硬化性樹脂、紫外線硬化性樹脂などの場合は硬化）する
ことによって行われる。尚、難燃性樹脂塗膜はそれを形
成する溶液中に通常の染料、顔料や蓄光蛍光などの特殊
染料や顔料などを適宜添加して所望の色に彩色すること
もできる。The formation of the flame-retardant resin coating film is performed by using an organic solvent solution of the resin for forming the flame-retardant resin coating film, an aqueous solution, or the like, by a roll coating method, a gravure coating method, a reverse coating method, or a spray coating method. It is performed by applying by a coating method and drying (curing in the case of a thermosetting resin, an electron beam curable resin, an ultraviolet curable resin, or the like). The flame-retardant resin coating film can be colored to a desired color by appropriately adding ordinary dyes, pigments, special dyes such as phosphorescent fluorescent light, pigments, and the like to a solution for forming the flame-retardant resin coating film.
難燃金銀糸（10）を構成するアルミニウム箔（12）の
厚さは通常４〜20μｍの範囲、好ましくは６〜８μｍの
範囲から選ばれる。アルミニウム箔の厚さが４μｍ未満
ではアルミニウム箔の価格が高く広範長尺のものの入手
が困難で好ましくない。一方20μｍを越えると剛直な金
銀糸となり風合に欠けるので一般向きでなく好ましくな
い。The thickness of the aluminum foil (12) constituting the flame-retardant gold-silver thread (10) is generally selected from the range of 4 to 20 μm, preferably the range of 6 to 8 μm. When the thickness of the aluminum foil is less than 4 μm, the price of the aluminum foil is high and it is difficult to obtain a wide and long aluminum foil, which is not preferable. On the other hand, if it exceeds 20 μm, it becomes a rigid gold-silver thread and lacks in feeling, so it is not suitable for general use and is not preferred.
難燃金銀糸（10）を構成するための難燃性樹脂接着剤
（13）としては特に制限するものではないが、前記アル
ミニウム箔および引っ張り強度の大きい樹脂フイルムに
たいしても密着性に優れていることが要求されるほか、
耐熱性と自己消火性とを兼備する必要がある。かかる要
求を満たす接着剤としては、たとえばアクリル系、酢酸
ビニル系、塩化ビニル系、ポリエチレン系、スチレン−
ブタジエン系などのエマルジョン接着剤の単独またはブ
レンド物、エチレン−酢酸ビニル系、塩素化ポリプロピ
レン系、塩化ビニル−酢酸ビニル系、アクリル系、アク
リル−塩化ビニル−酢酸ビニル系、フェノール系、キシ
レン系、石油樹脂系、ユリア系、メラミン系、不飽和ポ
リエステル系、アルキド系、エポキシ系、ウレタン系、
シリコン系、フラン系などの有機溶剤型接着剤の単独ま
たはブレンド物に難燃添加剤を配合したものがあげられ
る。The flame-retardant resin adhesive (13) for constituting the flame-retardant gold-silver thread (10) is not particularly limited, but it has excellent adhesion to the aluminum foil and the resin film having high tensile strength. Is required,
It is necessary to have both heat resistance and self-extinguishing properties. Adhesives satisfying such requirements include, for example, acrylic, vinyl acetate, vinyl chloride, polyethylene, and styrene-based adhesives.
Butadiene or other emulsion adhesive alone or blended, ethylene-vinyl acetate, chlorinated polypropylene, vinyl chloride-vinyl acetate, acrylic, acryl-vinyl chloride-vinyl acetate, phenol, xylene, petroleum Resin type, urea type, melamine type, unsaturated polyester type, alkyd type, epoxy type, urethane type,
Examples thereof include those in which a flame retardant additive is blended into a single or blend of an organic solvent-based adhesive such as a silicone-based or furan-based adhesive.
難燃性樹脂接着剤（13）はこれら接着剤のエマルジョ
ンや有機溶剤溶液などをロールコーティング法、グラビ
アコーティング法、リバースコーティング法、スプレイ
コーティング法などの通常のコーティングにより塗布
し、乾燥することによって行われる。難燃性樹脂接着剤
の厚さは通常0.5〜５μｍの範囲、より好ましくは0.5〜
３μｍの範囲から選ばれる。接着剤の厚さが0.5μｍ未
満では充分な接着強度が得られず好ましくない。一方５
μｍを越えても接着強度に変りがなく、風合いも損ない
経済性の点からも好ましくない。The flame-retardant resin adhesive (13) is prepared by applying an emulsion or organic solvent solution of these adhesives by ordinary coating such as roll coating, gravure coating, reverse coating, or spray coating, and drying. Will be The thickness of the flame-retardant resin adhesive is usually in the range of 0.5 to 5 μm, more preferably 0.5 to 5 μm.
It is selected from the range of 3 μm. If the thickness of the adhesive is less than 0.5 μm, sufficient adhesive strength cannot be obtained, which is not preferable. 5
Even if the thickness exceeds μm, the adhesive strength is not changed, and the feeling is impaired.
難燃金銀糸（10）を構成するための引っ張り強度の大
きい樹脂フイルム（14）としては特に制限するものでは
ないが、たとえばポリエチレンテレフタレート、ポリア
ミド、ポリアミドイミド、ポリカーボネートなどの樹脂
フイルムがあげられる。なかでも延伸ポリエチレンテレ
フタレート樹脂フイルムが価格、強度、取り扱い性など
の点で好ましい。その厚さは通常４〜25μｍ程度であ
る。The resin film (14) having a high tensile strength for forming the flame-retardant gold-silver thread (10) is not particularly limited, and examples thereof include resin films such as polyethylene terephthalate, polyamide, polyamideimide, and polycarbonate. Among them, a stretched polyethylene terephthalate resin film is preferred in terms of price, strength, handleability, and the like. Its thickness is usually about 4 to 25 μm.
かくしてえらた積層フイルム状物はマイクロスリッタ
ーで0.15〜5mm程度の細幅に裁断して本発明の難燃金銀
糸をえる。The laminated film thus obtained is cut into a narrow width of about 0.15 to 5 mm with a microslitter to obtain the flame-retardant gold-silver thread of the present invention.
前記本発明の難燃金銀糸はそのまま平糸として使用し
てもよいが、芯糸に丸撚りするか、羽衣撚りするか、蛇
腹撚りするか、あるいは本発明の難燃金銀糸を芯にして
他の糸をタスキ撚りするなどして撚糸としてもよい。The flame-retardant gold-silver yarn of the present invention may be used as it is as a flat yarn, but may be round-twisted to a core yarn, twisted in a garment, twisted in a bellows, or formed using the flame-retardant gold-silver yarn of the present invention as a core. The yarn may be twisted by, for example, twisting the yarn.
本発明の難燃金銀糸は最外層の難燃性樹脂塗膜をはじ
めその構成のほとんどを難燃性ないしは不燃性素材で構
成したので難燃金銀糸自体が火災などによって延焼する
ことはない。Since most of the structure of the flame-retardant gold-silver yarn of the present invention, including the outermost flame-retardant resin coating film, is made of a flame-retardant or non-flammable material, the flame-retardant gold-silver yarn itself does not spread due to a fire or the like.
つぎに実施例をあげて本発明を説明する。 Next, the present invention will be described with reference to examples.
実施例１ 厚さ７μｍのアルミニウム箔の片面に二液型エポキシ
−イソシアネート樹脂50部、トリクレシルホスフェート
５部、酢酸エチル20部、メチルエチルケトン20部、シク
ロヘキサノン10部からなる燃焼性樹脂塗膜用塗料をグラ
ビア方式で塗布し、乾燥し、加熱硬化させて、厚さ１μ
ｍの難燃性樹脂塗膜を形成してアルミニウム箔の片面に
難燃性樹脂塗膜を設けてなるフイルム状物を二枚を作成
した。Example 1 A paint for a combustible resin coating comprising 50 parts of a two-part epoxy-isocyanate resin, 5 parts of tricresyl phosphate, 20 parts of ethyl acetate, 20 parts of methyl ethyl ketone and 10 parts of cyclohexanone on one side of an aluminum foil having a thickness of 7 μm. Is applied by a gravure method, dried, and cured by heating to a thickness of 1 μm.
m, and two pieces of a film having a flame-retardant resin film provided on one side of an aluminum foil were prepared.
ついで厚さ12μｍの二軸４延伸ポリエチレンテレフタ
レートフイルムの両面に二液型ポリウレタン樹脂50部、
トリクレシルホスフェート５部、メチルエチルケトン45
部からなる難燃性樹脂接着剤を用いて前記アルミニウム
箔の片面に難燃性樹脂塗膜を設けてなるフイルム状物の
アルミニウム箔側を内側にして貼り合せて積層フイルム
を作成した。Next, 50 parts of a two-component polyurethane resin were placed on both sides of a 12 μm thick biaxial 4-stretched polyethylene terephthalate film,
Tricresyl phosphate 5 parts, methyl ethyl ketone 45
The aluminum foil was laminated on one side of the aluminum foil by using a flame-retardant resin adhesive comprising one part of the aluminum foil with the aluminum foil side facing inward to form a laminated film.
えられた積層フイルムをマイクロスリッターで120切
（0.252mm幅）の細幅に裁断して銀色の本発明の難燃金
銀糸をえた。The obtained laminated film was cut into a narrow width of 120 cuts (0.252 mm width) with a micro slitter to obtain a silver flame-retardant gold-silver thread of the present invention.
実施例２ 実施例１の難燃性樹脂塗膜用塗料にオレンジ色染料を
５部添加したものを用いたほかは同様にして金色の本発
明の難燃金銀色をえた。Example 2 A gold-colored flame-retardant gold and silver of the present invention was obtained in the same manner as in Example 1, except that the paint for a flame-retardant resin coating film to which 5 parts of an orange dye was added was used.
［発明の効果］ 実施例１および実施例２でえられた難燃金銀糸を用い
てポリベンゾイミダゾール系（米国セラニーズ社製）と
共に製織した。[Effects of the Invention] The flame-retardant gold-silver yarns obtained in Examples 1 and 2 were woven together with a polybenzimidazole (Celanese, USA).
えられた織布には所望のメタリック模様が表現されて
いた。The desired metallic pattern was expressed on the obtained woven fabric.
また他の諸物性は下記の通りであった。 Other physical properties are as follows.
耐熱性:JIS K 6328 異常なし 防炎性:JIS L 1091 A2法 （45°メッケルバーナ法） 残じん時間 0秒 残炎時間 0秒 炭化面積 10cm2以下 耐水圧:JIS L 1092 1000mm以上Heat resistance: JIS K 6328 No abnormality Flameproof: JIS L 1091 A2 method (45 ° Meckel burner method) Residual dust time 0 seconds Residual flame time 0 seconds Carbonized area 10 cm 2 or less Water pressure: JIS L 1092 1000 mm or more
第１図は本発明の難燃金銀糸の斜視図であり、円内はそ
の構成を示す概略拡大断面図である。第２図は本発明の
難燃金銀糸を他の糸条と組み合せた撚合糸の実施態様例
を示す概略部分断面図である。 （図面の符号） （10）：難燃金銀糸 （11）：難燃性樹脂塗膜 （12）：アルミニウム箔 （13）：難燃性樹脂接着剤 （14）：引っ張り強度の大きい樹脂フイルム （20）：糸条FIG. 1 is a perspective view of the flame-retardant gold-silver yarn of the present invention, and the inside of a circle is a schematic enlarged sectional view showing the configuration. FIG. 2 is a schematic partial sectional view showing an embodiment of a twisted yarn obtained by combining the flame-retardant gold-silver yarn of the present invention with another yarn. (Signs in the drawings) (10): Flame-retardant gold and silver yarn (11): Flame-retardant resin coating (12): Aluminum foil (13): Flame-retardant resin adhesive (14): Resin film with high tensile strength ( 20): Thread
Claims (1)
に、難燃添加剤を含有する樹脂からなる厚さ0.5〜５μ
ｍの難燃性樹脂塗膜を設けてなるフイルム状物が二枚、
前記アルミニウム箔を内側にして引っ張り強度の大きい
樹脂のフイルムの両面に難燃性樹脂接着剤を介して積層
された構成の積層フイルムを細幅に裁断したことを特徴
とする難燃金銀糸。An aluminum foil having a thickness of 4 to 20 μm is coated on one side with a resin containing a flame retardant additive in a thickness of 0.5 to 5 μm.
m, two film-like objects provided with a flame-retardant resin coating film,
A flame-retardant gold / silver yarn, wherein a laminated film having a structure in which the aluminum foil is on the inside and laminated on both surfaces of a resin film having high tensile strength via a flame-retardant resin adhesive is cut into a narrow width.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20423889A JP2878720B2 (en) | 1989-08-07 | 1989-08-07 | Flame retardant gold and silver thread |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20423889A JP2878720B2 (en) | 1989-08-07 | 1989-08-07 | Flame retardant gold and silver thread |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0369623A JPH0369623A (en) | 1991-03-26 |
| JP2878720B2 true JP2878720B2 (en) | 1999-04-05 |
Family
ID=16487137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20423889A Expired - Fee Related JP2878720B2 (en) | 1989-08-07 | 1989-08-07 | Flame retardant gold and silver thread |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2878720B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005281875A (en) * | 2004-03-29 | 2005-10-13 | Oike Ind Co Ltd | Tinsel |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005254247A (en) | 2004-03-09 | 2005-09-22 | Matsushita Electric Ind Co Ltd | Welding equipment |
| KR101037703B1 (en) * | 2009-06-30 | 2011-05-30 | 코오롱글로텍주식회사 | Polyurethane slit flame retardant fabric for automobile interior materials and polyurethane slit flame retardant fabric manufactured by the method |
-
1989
- 1989-08-07 JP JP20423889A patent/JP2878720B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005281875A (en) * | 2004-03-29 | 2005-10-13 | Oike Ind Co Ltd | Tinsel |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0369623A (en) | 1991-03-26 |
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