JPH0347675B2 - - Google Patents
Info
- Publication number
- JPH0347675B2 JPH0347675B2 JP56031673A JP3167381A JPH0347675B2 JP H0347675 B2 JPH0347675 B2 JP H0347675B2 JP 56031673 A JP56031673 A JP 56031673A JP 3167381 A JP3167381 A JP 3167381A JP H0347675 B2 JPH0347675 B2 JP H0347675B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- putty
- swellable
- parts
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 15
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 9
- -1 polyethylene Polymers 0.000 claims description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 8
- 239000003208 petroleum Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 229920005862 polyol Polymers 0.000 claims description 5
- 150000003077 polyols Chemical class 0.000 claims description 5
- 239000003085 diluting agent Substances 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 244000043261 Hevea brasiliensis Species 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920003052 natural elastomer Polymers 0.000 claims description 3
- 229920001194 natural rubber Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000012815 thermoplastic material Substances 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000010692 aromatic oil Substances 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 229920001228 polyisocyanate Polymers 0.000 claims description 2
- 239000005056 polyisocyanate Substances 0.000 claims description 2
- 229920003051 synthetic elastomer Polymers 0.000 claims description 2
- 239000005061 synthetic rubber Substances 0.000 claims description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 31
- 239000000203 mixture Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 16
- 229910052751 metal Inorganic materials 0.000 description 15
- 239000002184 metal Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 11
- 238000011056 performance test Methods 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000000843 powder Substances 0.000 description 5
- 229920001169 thermoplastic Polymers 0.000 description 5
- 239000004416 thermosoftening plastic Substances 0.000 description 5
- 239000010426 asphalt Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 125000006353 oxyethylene group Chemical group 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 239000003566 sealing material Substances 0.000 description 4
- 230000008961 swelling Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229920005549 butyl rubber Polymers 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009415 formwork Methods 0.000 description 2
- 229920003049 isoprene rubber Polymers 0.000 description 2
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 239000005077 polysulfide Substances 0.000 description 2
- 229920001021 polysulfide Polymers 0.000 description 2
- 150000008117 polysulfides Polymers 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007841 coal based oil Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Sealing Material Composition (AREA)
Description
本発明は熱可塑性物質と水膨潤性物質とを混合
して得られる水膨潤性パテに関するものであり、
特に、パテを注入後、間〓を生じても、水膨潤効
果でその隙間をシールし、“水漏れ”を止めると
いう止水性に優れるパテを提供するものである。
従来パテとしては乾性油を主成分とした油性
系、ポリサルフアイド系、シリコン系、或るいは
ウレタン系などがあるが、特に土木、建築関係で
の使用に於て、本来の主目的である“水漏れをと
める”という効果では完全なる止水性を有するパ
テは未だ見い出されていない。
かような“漏水”を防止するために近年水膨潤
系目地材が種々提案されているが、これらは定型
品がほとんどであり、使用に際しては、予め目地
部に貼り付けておくとか、目地部の寸法精度が高
くないと使用できないといつた問題点もあり、未
だパテ状の水膨潤性目地材は報告されていない。
本発明は上記問題点を改良した新規水膨潤性パ
テに関するものである。
即ち本発明は、必須成分として、熱可塑性物質
100重量部に対して、水膨潤性ウレタン樹脂10〜
500重量部、希釈剤10〜400重量部とを含有するこ
とを特徴とする水膨潤性パテを提供するものであ
る。
本発明に言う水膨潤性パテは必須成分として
（）熱可塑性物質と（）水膨潤性物質とを含
有するものであり、熱可塑性物質（）100部
（重量基準、以下同じ）に対し水膨潤性物質（）
10〜500部を配合する事が必要である。パテ材と
するには注入できるような粘性に調整することが
必要であり、熱可塑性物質（）100部に対し、
10〜400部の範囲で本発明のもう一つの必須成分
である希釈剤を添加する事が必要である。
本発明に言う熱可塑性物質（）としては、ポ
リエチレン、ポリプロピレン、ポリキシリレン、
ポリ酢酸ビニル、ポリアクリレート、ポリメタク
リレート、ポリ塩化ビニリ、ポリ塩化ビニリデ
ン、ナイロン等の熱可塑性合成樹脂、石油樹脂、
クマロン−インデン樹脂、未加硫の天然ゴム、ス
チレンブタジエンゴム（SBR）、ブタジエンゴム
（BR）、イソプレンゴム（IR）、エチレンプロピ
レンゴム（EPR）、ニトリルブタジエンゴム
（NBR）、クロロプレンゴム（CR）、ブチルゴム
（IIR）等の未加硫合成ゴム、天然アスフアルト、
ストレートアスフアルト、ブローンアスフアルト
等の歴青物等が用いられる。
本発明に言う水膨潤性物質（）としては、ポ
リオールと有機ポリイソシアネートとの反応より
得られる水膨潤性ウレタン樹脂が好ましく、ポリ
オール成分が分子中にエチレンオキサイド基を10
％以上含有するポリエーテルポリオールであり、
水道水に10日間浸漬した時の重量増加率が10％以
上である水膨潤性ウレタン樹脂が特に好ましい。
また、その他に、ポリビニルアルコール、アクリ
ル樹脂等の膨潤性物質を少量併用することが可能
である。
本発明に言う希釈剤とはパテ材としての作業性
を調整するために添加するもので、25℃で液状を
呈する物質なら全て使用可能であり、例えば石油
系或るいは石炭系の油、動植物油類、DOP、
DBPの如き可塑剤、トルエン、キシレン、ベン
ゼンの如き溶剤などが挙げられる。
又、上記の成分以外に必要に応じてウレタン樹
脂やゴム等に用いられる充填剤や顔料なども適度
に添加できる。
本発明の水膨潤性パテは、漏水防止効果が非常
に優れ、また目地にパテを施工した後の表面加工
性、作業性が良好であつて、広範な用途に用いら
れうるものである。
次に本発明の実施例を示す。尚、例中の性能テ
ストは次の方法により行なつた。
(1) 水膨潤率…水道水に７日間浸漬後の重量増加
率を測定した。
(2) 漏水試験…第１図に示した漏水試験機の隙間
部に２〜３mmの間隙を生じるようにパテ３を注
入し、７日間水中に浸漬しパテわ完全に水膨潤
させた後、２の方向から0.5Kgｆ／cm3の水圧を
かけ漏水の有無を調べた。
(3) 耐候性試験…１ケ月屋外に暴露し、表面にク
ラツクの発生の有無を調べた。
構造例
以下の実施例で用いる水膨潤性ウレタン樹脂は
次の方法により製造した。
即ちプロピレングリコールにプロピレンオキサ
イドとエチレンオキサイドを付加させた平均分子
量4500、エチレンオキサイド基75％のポリエーテ
ル1.3モルとブタジオール0.6モルとジフエニルメ
タンジイソシアネート2.0モルとを反応させて水
膨潤性ウレタン樹脂を製造した（ポリオール中の
エチレンオキサイド基74％、水膨潤率352％）。
実施例 １
下記に示す配合組成を20cmオープンロールで混
練りし、水膨潤性パテ−を製造した。
水膨潤性パテ−
ポリプロピレン（平均分子量80000） 100重量部
水膨潤性ウレタン樹脂 60
炭酸カルシウム 120
石油系芳香族油 80
このパテについて性能テストを行つた。結果を
表−１に示す。
実施例 ２
下記に示す配合組成を20cmオープンロールで混
練りし、水膨潤性パテ−を製造した。
水膨潤性パテ−
ポリ塩化ビニル（平均分子量110000） 100重量部
水膨潤性ウレタン樹脂 90
タルク 150
DOP 150
このパテについて性能テストを行つた。結果を
表−１に示す。
実施例 ３
下記に示す配合組成を20cmオープンロールで混
練りし、水膨潤性パテ−を製造した。
水膨潤性パテ−
ポリエチレン（平均分子量20000） 100重量部
水膨潤性ウレタン樹脂 130
カーボンブラツク 20
ヒマシ油 90
このパテについて性能テストを行つた。結果を
表−１に示す。
実施例 ４
下記に示す配合組成を20cmオープンロールで混
練りし、水膨潤性パテ−を製造した。
水膨潤性パテ−
EPR 100重量部
水膨潤性ウレタン樹脂 50
石油系オイル 75
炭酸カルシウム 95
このパテについて性能テストを行つた。結果を
表−１に示す。
実施例 ５
下記に示す配合組成を20cmオープンロールで混
練りし水膨潤性パテ−を製造した。
水膨潤性パテ−
IIR 100重量部
水膨潤性ウレタン樹脂 45
塩素化パラフイン 65
カーボンブラツク 15
タルク 60
このパテについて性能テストを行つた。結果を
表−１に示す。
実施例 ６
下記に示す配合組成を20cmオープンロールで混
練りし水膨潤性パテ−を製造した。
水膨潤性パテ−
クマロン−インデン樹脂 100重量部
水膨潤性ウレタン樹脂 130
炭酸カルシウム 20
DBP 65
このパテについて性能テストを行つた。結果を
表−１に示す。
実施例 ７
下記に示す配合組成を20cmオープンロールで混
練りし、水膨潤性パテ−を製造した。
ストレートアスフアルト 100重量部
水膨潤性ウレタン樹脂 70
フエノール 20
このパテについて性能テストを行つた。結果を
表−１に示す。
比較例 １、２
市販品のポリサルフアイド系パテ（比較例１）、
乾性油系パテ（比較例２）を入手し、性能テスト
を行つた。結果を表−１に示す。
The present invention relates to a water-swellable putty obtained by mixing a thermoplastic substance and a water-swellable substance,
In particular, the purpose of the present invention is to provide a putty with excellent water-stopping properties that, even if a gap occurs after the putty is injected, the water swelling effect seals the gap and stops "water leakage." Conventional putty types include oil-based putty based on drying oil, polysulfide-based, silicone-based, and urethane-based putty. In terms of the effect of "stopping leaks," no putty has yet been found that has complete water-stopping properties. Various water-swelling joint materials have been proposed in recent years to prevent such "water leakage," but most of these are standard products, and when used, they must be pasted on the joints in advance or There is also the problem that it cannot be used unless the dimensional accuracy is high, and no putty-like water-swellable joint material has been reported yet. The present invention relates to a new water-swellable putty that has improved the above-mentioned problems. That is, the present invention uses a thermoplastic material as an essential component.
10 to 100 parts by weight of water-swellable urethane resin
The present invention provides a water-swellable putty characterized by containing 500 parts by weight and 10 to 400 parts by weight of a diluent. The water-swellable putty referred to in the present invention contains () a thermoplastic substance and () a water-swellable substance as essential components, and the water-swellable putty per 100 parts (by weight, the same applies hereinafter) of the thermoplastic substance (). sexual substance ()
It is necessary to mix 10 to 500 parts. To make a putty material, it is necessary to adjust the viscosity so that it can be injected, and for 100 parts of thermoplastic material (),
It is necessary to add a diluent, which is another essential component of the present invention, in a range of 10 to 400 parts. The thermoplastic substances mentioned in the present invention include polyethylene, polypropylene, polyxylylene,
Polyvinyl acetate, polyacrylate, polymethacrylate, polyvinychloride, polyvinylidene chloride, thermoplastic synthetic resins such as nylon, petroleum resins,
Coumarone-indene resin, unvulcanized natural rubber, styrene-butadiene rubber (SBR), butadiene rubber (BR), isoprene rubber (IR), ethylene propylene rubber (EPR), nitrile-butadiene rubber (NBR), chloroprene rubber (CR) , unvulcanized synthetic rubber such as butyl rubber (IIR), natural asphalt,
Bituminous materials such as straight asphalt and blown asphalt are used. As the water-swellable substance (2) according to the present invention, a water-swellable urethane resin obtained by the reaction of a polyol and an organic polyisocyanate is preferable, and the polyol component has 10 ethylene oxide groups in the molecule.
It is a polyether polyol containing % or more,
Particularly preferred is a water-swellable urethane resin whose weight increase rate is 10% or more when immersed in tap water for 10 days.
In addition, a small amount of a swelling substance such as polyvinyl alcohol or acrylic resin can be used in combination. The diluent mentioned in the present invention is added to adjust the workability as a putty material, and any substance that is liquid at 25°C can be used, such as petroleum-based or coal-based oil, animal or plant oil, etc. Oils, DOP,
Examples include plasticizers such as DBP, and solvents such as toluene, xylene, and benzene. In addition to the above-mentioned components, fillers and pigments used in urethane resins, rubbers, etc. can also be appropriately added, if necessary. The water-swellable putty of the present invention has an extremely excellent water leakage prevention effect, and also has good surface workability and workability after applying the putty to joints, and can be used in a wide range of applications. Next, examples of the present invention will be shown. The performance test in the example was conducted in the following manner. (1) Water swelling rate: Weight increase rate after 7 days immersion in tap water was measured. (2) Water leakage test...Putty 3 was injected into the gap of the water leakage tester shown in Figure 1 so as to create a gap of 2 to 3mm, and after being immersed in water for 7 days to allow the putty to completely swell with water, A water pressure of 0.5 Kgf/cm 3 was applied from direction 2 to check for water leakage. (3) Weather resistance test: The product was exposed outdoors for one month, and the presence or absence of cracks on the surface was examined. Structural Example The water-swellable urethane resin used in the following examples was manufactured by the following method. That is, a water-swellable urethane resin is produced by reacting 1.3 moles of polyether with an average molecular weight of 4500 and 75% ethylene oxide groups, which is obtained by adding propylene oxide and ethylene oxide to propylene glycol, 0.6 moles of butadiol, and 2.0 moles of diphenylmethane diisocyanate. (74% ethylene oxide group in polyol, water swelling rate 352%). Example 1 The composition shown below was kneaded using a 20 cm open roll to produce a water-swellable putty. Water-swellable putty Polypropylene (average molecular weight 80,000) 100 parts by weight Water-swellable urethane resin 60 Calcium carbonate 120 Petroleum-based aromatic oil 80 A performance test was conducted on this putty. The results are shown in Table-1. Example 2 The composition shown below was kneaded using a 20 cm open roll to produce a water-swellable putty. Water-swellable putty Polyvinyl chloride (average molecular weight 110,000) 100 parts by weight Water-swellable urethane resin 90 Talc 150 DOP 150 A performance test was conducted on this putty. The results are shown in Table-1. Example 3 The composition shown below was kneaded using a 20 cm open roll to produce a water-swellable putty. Water-swellable putty Polyethylene (average molecular weight 20,000) 100 parts by weight Water-swellable urethane resin 130 Carbon black 20 Castor oil 90 A performance test was conducted on this putty. The results are shown in Table-1. Example 4 The composition shown below was kneaded using a 20 cm open roll to produce a water-swellable putty. Water-swellable putty EPR 100 parts by weight Water-swellable urethane resin 50 Petroleum oil 75 Calcium carbonate 95 A performance test was conducted on this putty. The results are shown in Table-1. Example 5 A water-swellable putty was produced by kneading the composition shown below using a 20 cm open roll. Water-swellable putty IIR 100 parts by weight Water-swellable urethane resin 45 Chlorinated paraffin 65 Carbon black 15 Talc 60 Performance tests were conducted on this putty. The results are shown in Table-1. Example 6 A water-swellable putty was produced by kneading the composition shown below using a 20 cm open roll. Water-swellable putty Coumarone-indene resin 100 parts by weight Water-swellable urethane resin 130 Calcium carbonate 20 DBP 65 A performance test was conducted on this putty. The results are shown in Table-1. Example 7 The composition shown below was kneaded using a 20 cm open roll to produce a water-swellable putty. Straight asphalt 100 parts by weight Water-swellable urethane resin 70 Phenol 20 A performance test was conducted on this putty. The results are shown in Table-1. Comparative Examples 1, 2 Commercially available polysulfide putty (Comparative Example 1),
A drying oil-based putty (Comparative Example 2) was obtained and a performance test was conducted. The results are shown in Table-1.
【表】
△僅かにクラツクあり
×クラツク発性
本発明の水膨潤性パテ性能、施工面での効果を
より明確にするために、次のテストを行つた。
＜テストの簡単な説明＞
第２図の如く、外径約12mmの違径金棒６にテス
ト用のシール材７を装着し、箱型のコンクリート
型枠５に固定し、圧縮強度300Kgｆ／cm2の生コン
クリート１０を流し込み、７日間養生後脱型し、
このコンクリートブロツクを30日間水中で養性し
た。次いでコンクリートブロツクを水柱より取出
し、鉄パイプ８より、赤インクで着色した水を用
いて３Kgｆ／cm2の水圧をかけ、漏水状態をチエツ
クした。コンクリートを乾燥させた後、破壊して
着色具合より漏水の水道を観察した。
尚、違径金棒とは、コンリロート構造物の補強
材として使われる鉄筋であり、コンクリートとの
接触面積を大きくするために、丸金棒にラセン状
及び長さ方向に刻目（溝）を入れた金棒である。
実施例 ８〜12
実施例１〜５で用いた水膨潤性パテ〜の性
能をテストした。
いずれもこの水膨潤性パテは、手で押さえるこ
とにより容易に変型、圧着が可能であり、丸めて
球状やひも状のものを作ることが出来、その時、
手に付着して手が汚れる様なことがない。又、こ
の性質は不変である。
丸いひも状に伸ばして、これを違径金棒に約巾
10mm、厚み15mmの輪になる様に圧着して装着し
た。違径金棒の溝にも完全に充填圧着しており、
施工性が非常に優れている。このものの前記止水
テストの結果は表２の通りである。
実施例８のテストには水膨潤性パテを使用
実施例９のテストには水膨潤性パテを使用
実施例10のテストには水膨潤性パテを使用
実施例11のテストには水膨潤性パテを使用
実施例12のテストには水膨潤性パテを使用
比較例 ３
＜配合＞*1
UPX−２（オキシエチレン基51.3％） 100部*2
ポリエーテル 105.1部
ナフテン酸鉛 0.3部
＊１ （UPX−２）
グリセリンにプロピレンオキサイドとエチレ
ンオキサイドをランダムに付加せしめて得られ
た分子量2500オキシエチレン基31％の３官能ポ
リエーテル30部と、プロピレングリコールにプ
ロピレンオキサイドを付加した後、エチレンオ
キサイドを付加せしめる事より得られた分子量
2000、オキシエチレン基含有量60％の２官能ポ
リエーテル70部とを混合し、トリレンジイソシ
アネートを用いて得られたNCO含量3.08％の
イソシアネート基含有プレポリマー
＊２ （ポリエーテル）
プロピレングリコールにプロピレンオキサイ
ド付加させた後エチレンオキサイドを付加せし
めた分子量2000、オキシエチレン基30％のポリ
エーテル
以上の配合で、金型に注型、硬化させ、外径39
ｍ／ｍ、内径９ｍ／ｍ、厚み15ｍ／ｍのリング状
水膨線ゴムパツキンを作製した。このものを違径
金棒に差し込んで固定したが、内径を伸長させ
て、金枠の端から中心部まで移動させるのが面倒
であり、且つゴム弾性の復元力をもつてしても、
金棒の溝は完全に埋めることが出来ず〓間が生じ
ていた。
止水テストの結果は表２の通りである。
比較例 ４
＜配合＞
熱可塑性樹脂 100重量部*3
水膨潤性粉体 180重量部
を加え、ミキシングロールでよく混練後、厚さ
1.3mmのシートに成型した。
＊３ （水膨潤性粉体）
イソブチレン−無水マレイン酸共重合体のア
ンモニア中和物（クラレ製、商品名イソバン−
110）100重量部とトリメチロールメラミン10重
量部と有機アミン塩触媒１重量部と水300重量
部とを混合し、90℃で１時間加熱反応させた。
このようにして、容易に粉枠しうる反応生成物
が得られた。この反応生成物を、ボールミルで
30分間粉枠し、100メツシユ通過区分80％を占
める粉体とした。
この粉体は、20℃の水に１時間浸漬した場
合、150倍に膨潤し、また水中に長時間浸漬し
ても溶解しなかつた。
以上のシートは、入力で変形不可能であり、又
違径金棒に密着しない。
従つて、このシートを切り、金型でプレス成型
し、内径９ｍ／ｍ、外径39ｍ／ｍ、厚さ10ｍ／ｍ
のリング状水膨張ゴムパツキングを作製し、止水
テストを行つた。結果を、表２の通りであり、施
工性、金棒の溝の充填状態は比較例３と同様であ
つた。
比較例 ５
比較例３と同じ配合の混合物を、未硬化状態で
違径金棒に塗布したが、流動性がある為、硬化前
にそれ落ちてしまい殆ど付着しなかつた。
比較例 ６
＜配合＞
比較例３のUPX−２ 100部*4
硬化剤 135部
＊４ （硬化剤）
比較例３のポリエーテル 105部
ナフテン酸鉛 0.3部
炭酸カルシウム 150部
微細シリカ（日本アエルジル製、アエルジル
200） 15部
以 上の混合物をらいかい器で混練りし、パテ
状の硬化剤を作製した。
以上の混合物は、流動性が少ないパテ状物質で
あるが、手に付着し、手で任意の形状のものを作
ることができない。従つてこのものをコーキング
ガンに入れ、違径金棒に押出し装着した。溝も完
全に埋まり装着状態は良好であつた。
しかし、硬化に時間がかかり、硬化前は容易に
変形、脱落する為、生コンクリートを流し込むこ
とができず、待ち時間が必要であつた。
又、この高粘度の２液を混合するのは大変であ
り、且つ、混合したものは硬化前に使いきらない
とゲル化し、使用できなくなる欠点を有してい
た。[Table] △Slight crack ×Crack occurrence In order to clarify the water-swellable putty performance of the present invention and its effectiveness in terms of construction, the following tests were conducted. <Brief explanation of the test> As shown in Fig. 2, a sealing material 7 for the test was attached to a metal rod 6 with an outer diameter of approximately 12 mm, which was fixed to a box-shaped concrete formwork 5, with a compressive strength of 300 kgf/cm 2 . Pour fresh concrete 10, remove the mold after curing for 7 days,
This concrete block was incubated in water for 30 days. Next, the concrete block was taken out from the water column, and a water pressure of 3 kgf/cm 2 was applied to it through iron pipe 8 using water colored with red ink to check for water leakage. After drying the concrete, it was destroyed and water leaks were observed based on the coloration. Incidentally, different diameter metal rods are reinforcing bars used as reinforcing materials for concrete-routed structures, and are round metal rods with grooves (grooves) in a spiral shape and longitudinal direction in order to increase the contact area with concrete. It is. Examples 8-12 The performance of the water-swellable putty used in Examples 1-5 was tested. In both cases, this water-swellable putty can be easily deformed and crimped by pressing it with your hands, and can be rolled into balls or strings.
There is no chance of it getting on your hands and getting them dirty. Moreover, this property remains unchanged. Stretch it into a round string and tie it around a metal rod of different diameter.
I attached it by crimping it into a ring of 10mm and 15mm thick. The grooves of metal rods with different diameters are completely filled and crimped.
It has excellent construction properties. The results of the water stop test for this product are shown in Table 2. Testing Example 8 uses water-swellable putty Testing Example 9 uses water-swelling putty Testing Example 10 uses water-swelling putty Testing Example 11 uses water-swelling putty Water-swellable putty was used for the test in Example 12 Comparative Example 3 <Formulation> *1 UPX-2 (oxyethylene group 51.3%) 100 parts *2 Polyether 105.1 parts Lead naphthenate 0.3 parts *1 (UPX -2) 30 parts of a trifunctional polyether with a molecular weight of 2500 and 31% oxyethylene groups obtained by randomly adding propylene oxide and ethylene oxide to glycerin, and propylene oxide being added to propylene glycol, followed by adding ethylene oxide. Molecular weight obtained from
2000, an isocyanate group-containing prepolymer with an NCO content of 3.08% obtained by mixing 70 parts of a bifunctional polyether with an oxyethylene group content of 60% and using tolylene diisocyanate *2 (Polyether) Propylene glycol and propylene A polyether with a molecular weight of 2000 and 30% oxyethylene groups, which has been added with ethylene oxide after oxide addition.The above composition was poured into a mold, hardened, and the outside diameter was 39.
A ring-shaped water-swelling rubber packing with a diameter of 9 m/m, an inner diameter of 9 m/m, and a thickness of 15 m/m was prepared. I fixed this thing by inserting it into metal rods of different diameters, but it was troublesome to extend the inner diameter and move it from the edge of the metal frame to the center, and even with the restoring force of rubber elasticity,
The groove of the metal rod could not be completely filled and a gap was created. The results of the water stop test are shown in Table 2. Comparative Example 4 <Formulation> Add 100 parts by weight of thermoplastic resin *3 and 180 parts by weight of water-swellable powder, mix well with a mixing roll, and then adjust the thickness.
It was molded into a 1.3mm sheet. *3 (Water-swellable powder) Ammonia neutralized product of isobutylene-maleic anhydride copolymer (manufactured by Kuraray, trade name: Isoban-
110) 100 parts by weight, 10 parts by weight of trimethylolmelamine, 1 part by weight of an organic amine salt catalyst, and 300 parts by weight of water were mixed and reacted by heating at 90°C for 1 hour.
In this way, a reaction product was obtained that could be easily powdered. This reaction product is processed using a ball mill.
The powder was powdered for 30 minutes, and the powder accounted for 80% of the 100-mesh passing section. This powder swelled 150 times when immersed in water at 20°C for 1 hour, and did not dissolve even when immersed in water for a long time. The above sheet cannot be deformed by input, and does not adhere tightly to metal rods of different diameters. Therefore, this sheet was cut and press-molded using a mold, with an inner diameter of 9 m/m, an outer diameter of 39 m/m, and a thickness of 10 m/m.
We created a ring-shaped water-expandable rubber packing and conducted a water stop test. The results are shown in Table 2, and the workability and filling condition of the metal rod groove were the same as in Comparative Example 3. Comparative Example 5 A mixture having the same formulation as in Comparative Example 3 was applied to metal bars of different diameters in an uncured state, but due to its fluidity, it fell off before curing and hardly adhered. Comparative Example 6 <Formulation> UPX-2 of Comparative Example 3 100 parts *4 Curing agent 135 parts*4 (Curing agent) Polyether of Comparative Example 3 105 parts Lead naphthenate 0.3 parts Calcium carbonate 150 parts Fine silica (manufactured by Nippon Aergil) , Aergil
200) A putty-like hardener was prepared by kneading 15 parts or more of the mixture in a sieve. The above mixture is a putty-like substance with low fluidity, but it sticks to the hands and cannot be shaped into a desired shape by hand. Therefore, I put this in a caulking gun and pushed it onto a metal rod with a different diameter. The groove was completely filled and the mounting condition was good. However, it takes time to harden and is easily deformed and falls off before hardening, making it impossible to pour fresh concrete and requiring a waiting period. Further, it is difficult to mix these two highly viscous liquids, and if the mixture is not used up before curing, it will gel and become unusable.
【表】
実施例 13
下記に示す配合組成を20cmオープンロールで混
練りし、水膨潤性パテを製造した。
未加硫天然ゴム 100重量部
水膨潤性ウレタン樹脂 40
DOP 50
カーボンブラツク 15
タルク 55
このパテについて実施例１〜７と同様の性能テ
ストを行つたところ、結果は次の通りであつた。
水膨潤率 60重量％
漏水試験 漏水なし
耐候性試験 ○[Table] Example 13 The composition shown below was kneaded using a 20 cm open roll to produce a water-swellable putty. Unvulcanized natural rubber 100 parts by weight Water-swellable urethane resin 40 DOP 50 Carbon black 15 Talc 55 This putty was subjected to the same performance tests as in Examples 1 to 7, and the results were as follows. Water swelling rate 60% by weight Water leakage test No-leakage weathering test ○
第１図、第２図は、本発明のパテの性能テスト
に使用した漏水試験機の略示断面図である（単位
mm）。
１：ストツパー、２：0.5Kgｆ／cm2の水圧のか
かる方向、３：〓お間部に注入したパテ、４：
鉄、５：コンクリート型枠、６：違径金棒、７：
シール材（テスト用）、８：鉄パイプ、９：軟質
ウレタンフオーム（鉄パイプと違径金棒を連結固
定する為のもの）、１０：コンクリート、１１：
３Kgｆ／cm2の水圧のかかる方向、Ａ：シール材と
コンクリート間を伝わる漏水、Ｂ：シール材と違
径金棒間を伝わる漏水。
Figures 1 and 2 are schematic cross-sectional views of a water leakage tester used in the performance test of the putty of the present invention (unit:
mm). 1: Stopper, 2: Direction of water pressure of 0.5Kgf/cm 2 , 3: Putty injected into the buttocks, 4:
Iron, 5: Concrete formwork, 6: Different diameter metal rod, 7:
Sealing material (for testing), 8: Iron pipe, 9: Soft urethane foam (for connecting and fixing iron pipe and metal rod of different diameters), 10: Concrete, 11:
Direction of water pressure of 3Kgf/ cm2 , A: Water leakage between the sealing material and concrete, B: Water leakage between the sealing material and metal bars with different diameters.
Claims (1)
レン、石油樹脂、未加硫天然ゴム、未加硫合成ゴ
ム、歴青物から選ばれる熱可塑性物質100重量部
に対して、分子中にエチレンオキサイド基を10％
以上有するポリエーテルポリオールと有機ポリイ
ソシアネートの反応により得られる水膨潤性ウレ
タン樹脂10〜500重量部、及び石油系芳香族油、
ヒマシ油、石油系オイル、塩素化パラフイン、ジ
オクチルフタレート（DOP）、ジブチルフタレー
ト（DBP）、フエノールから選ばれる希釈剤10〜
400重量部とを含有することを特徴とする水膨潤
性止水用パテ。1. As an essential component, 10% ethylene oxide group is contained in the molecule based on 100 parts by weight of a thermoplastic material selected from polyethylene, polypropylene, petroleum resin, unvulcanized natural rubber, unvulcanized synthetic rubber, and bituminous materials.
10 to 500 parts by weight of a water-swellable urethane resin obtained by the reaction of a polyether polyol having the above and an organic polyisocyanate, and a petroleum aromatic oil,
Diluent selected from castor oil, petroleum oil, chlorinated paraffin, dioctyl phthalate (DOP), dibutyl phthalate (DBP), phenol 10~
400 parts by weight of a water-swellable water-stopping putty.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3167381A JPS57145170A (en) | 1981-03-05 | 1981-03-05 | Water-swelling putty |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3167381A JPS57145170A (en) | 1981-03-05 | 1981-03-05 | Water-swelling putty |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57145170A JPS57145170A (en) | 1982-09-08 |
| JPH0347675B2 true JPH0347675B2 (en) | 1991-07-22 |
Family
ID=12337637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3167381A Granted JPS57145170A (en) | 1981-03-05 | 1981-03-05 | Water-swelling putty |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57145170A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6038733U (en) * | 1983-05-12 | 1985-03-18 | 旭電化工業株式会社 | Water stop material |
| JPH071538A (en) * | 1992-09-14 | 1995-01-06 | Asahi Denka Kogyo Kk | Composite waterproofing material |
| JPH073046A (en) * | 1992-09-14 | 1995-01-06 | Asahi Denka Kogyo Kk | Water-stopping sheet |
| JP3996009B2 (en) * | 2002-07-31 | 2007-10-24 | 東亜道路工業株式会社 | Two-part waterstop composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5196848A (en) * | 1975-02-21 | 1976-08-25 | ||
| JPS553424A (en) * | 1978-06-21 | 1980-01-11 | C I Kasei Co Ltd | Water swelling resin composition |
-
1981
- 1981-03-05 JP JP3167381A patent/JPS57145170A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5196848A (en) * | 1975-02-21 | 1976-08-25 | ||
| JPS553424A (en) * | 1978-06-21 | 1980-01-11 | C I Kasei Co Ltd | Water swelling resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57145170A (en) | 1982-09-08 |
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