JPH02201424A - Manufacturing method of liquid crystal display device - Google Patents
Manufacturing method of liquid crystal display deviceInfo
- Publication number
- JPH02201424A JPH02201424A JP2151089A JP2151089A JPH02201424A JP H02201424 A JPH02201424 A JP H02201424A JP 2151089 A JP2151089 A JP 2151089A JP 2151089 A JP2151089 A JP 2151089A JP H02201424 A JPH02201424 A JP H02201424A
- Authority
- JP
- Japan
- Prior art keywords
- liquid crystal
- crystal display
- display device
- substrate
- gap
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004973 liquid crystal related substance Substances 0.000 title claims abstract description 55
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- 239000000758 substrate Substances 0.000 claims abstract description 47
- 125000006850 spacer group Chemical group 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 26
- 239000000853 adhesive Substances 0.000 claims abstract description 22
- 230000001070 adhesive effect Effects 0.000 claims abstract description 20
- 239000004642 Polyimide Substances 0.000 abstract description 6
- 229920001721 polyimide Polymers 0.000 abstract description 6
- 238000000576 coating method Methods 0.000 abstract description 5
- 210000002858 crystal cell Anatomy 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- 238000004528 spin coating Methods 0.000 abstract 2
- 239000010408 film Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 5
- 239000011521 glass Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000000565 sealant Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000009125 cardiac resynchronization therapy Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1339—Gaskets; Spacers; Sealing of cells
- G02F1/13394—Gaskets; Spacers; Sealing of cells spacers regularly patterned on the cell subtrate, e.g. walls, pillars
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Liquid Crystal (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は大面積で高精細な液晶表示装置の製造方法に関
する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for manufacturing a large-area, high-definition liquid crystal display device.
［従来の技術］
近年、液晶表示装置の技術開発に多大な努力が注がれ、
ＣＲＴに匹敵するような画面サイズ、解像度、画質の液
晶表示装置が実現できるようになった。しかし、この液
晶表示装置が工業的に効率よく生産されるためには、ま
だいくつかの課題が残されている。そのひとつとしてギ
ャップ制御の課題がある。液晶表示装置のギャップむら
は表示品質に大きな影響を及ぼす。たとえばＴＮ型など
の場合、ギャップが不均一になるとリタデーシミンの効
果によって画面の一部が変色したり、書き込み電圧のシ
フトによって階調が取れなくなる。[Prior Art] In recent years, great efforts have been made in the technological development of liquid crystal display devices.
It has become possible to realize liquid crystal display devices with screen size, resolution, and image quality comparable to CRTs. However, there are still some issues to be solved before this liquid crystal display device can be produced industrially and efficiently. One of these is the issue of gap control. Gap unevenness in liquid crystal display devices has a large effect on display quality. For example, in the case of a TN type, if the gap becomes non-uniform, a portion of the screen may become discolored due to the effect of retardation, or the gradation cannot be obtained due to a shift in the writing voltage.
この効果はＳＴＮ型などのようにツイスト角度が大きい
液晶表示装置はど顕著になる。また画面サイズが大きい
ほどギャップの均一化が難しく、高精細になるほどギャ
ップむらによるコントラストの低下が著しくなる。This effect becomes more noticeable in liquid crystal display devices with a large twist angle, such as the STN type. Furthermore, the larger the screen size, the more difficult it is to make the gaps uniform, and the higher the resolution, the more significant the reduction in contrast due to uneven gaps becomes.
ところで従来の液晶表示装置のギャップ制御技術は、第
３図に示すように、２枚の平面基板の中間にグラスファ
イバやミクロパールからなるスペーサを散布し、平面基
板の周辺をスペーサの混入したシール剤で接着固定する
ことにより、液晶層の厚みをコントロールしていた。By the way, conventional gap control technology for liquid crystal display devices, as shown in Figure 3, involves scattering spacers made of glass fiber or micro pearls between two flat substrates, and sealing the periphery of the flat substrates with the spacers mixed in. The thickness of the liquid crystal layer was controlled by adhesively fixing it with an adhesive.
［発明が解決しようとする課Ｍ］
しかし、前述の従来技術の場合、次に列記するような重
要な課題を有している。すなわち、（１）平面基板の周
辺部のみにシール剤を形成して接着するため、平面基板
の熱膨張率の相違によって平面基板の中央部でギャップ
の膨らみが生じ、液晶を封入した後において、周辺部と
中央部でギャップのむらを生じる。[Problem M to be Solved by the Invention] However, the above-mentioned prior art has important problems as listed below. In other words, (1) since a sealant is formed and bonded only to the periphery of the flat substrate, a gap bulges in the center of the flat substrate due to the difference in the coefficient of thermal expansion of the flat substrate, and after the liquid crystal is sealed, Gap unevenness occurs between the periphery and the center.
（２）前記の中央部の膨らみ部分のスペーサが、封入時
の液晶の流動力によって押し流され、部分的にスペーサ
の密度が変化し、その結果、ギャップのむらが生じる。(2) The spacer in the bulge at the center is swept away by the fluidity of the liquid crystal during sealing, and the density of the spacer partially changes, resulting in uneven gaps.
（３）平面基板の面積を大きくして、大画面の液晶表示
装置を形成する場合、通常存在する平面基板の表面のう
ねりによってギャップのむらが生じる。(3) When the area of a flat substrate is increased to form a large-screen liquid crystal display device, unevenness in the gap occurs due to the undulations of the surface of the flat substrate that normally exist.
などである。etc.
そこで本発明はこのような従来技術の問題点を解決する
ためのもので、その目的とするところ・は、大面積の液
晶表示装置においてもギャップの均一性が保たれ、それ
によって表示品質がよく、生産性に優れた液晶表示装置
の製造方法を提供するところにある。The present invention is intended to solve these problems in the prior art, and its purpose is to maintain gap uniformity even in large-area liquid crystal display devices, thereby improving display quality. Another object of the present invention is to provide a method for manufacturing a liquid crystal display device with excellent productivity.
［課題を解決するための手段］
本発明の液晶表示装置の製造方法は、対向した第一平面
基板および第二平面基板、前記第一平面基板の表面に形
成され、前記２枚の平面基板の内面を平行に保持するス
ペーサ、該スペーサおよび前記第二平面基板を接着固定
する接着体、および前記２枚の平面基板の中間に封入さ
れた液晶を少なくとも構成要素とする液晶表示装置の製
造方法において、前記スペーサを第一平面基板の表面に
形成する工程と、前記第一平面基板を配向処理する工程
と、前記接着体を前記スペーサの先頭部に形成する工程
とを含むことを特徴とする液晶表示装置の製造方法。[Means for Solving the Problems] A method for manufacturing a liquid crystal display device of the present invention includes a first planar substrate and a second planar substrate facing each other; In a method for manufacturing a liquid crystal display device whose components include at least a spacer that holds the inner surfaces parallel to each other, an adhesive that adhesively fixes the spacer and the second flat substrate, and a liquid crystal sealed between the two flat substrates. , a liquid crystal comprising the steps of forming the spacer on the surface of the first planar substrate, aligning the first planar substrate, and forming the adhesive at the top of the spacer. A method for manufacturing a display device.
［実施例］ 本発明を実施例に従い、さらに詳述する。[Example] The present invention will be explained in more detail based on examples.
第１図は本発明により製造された単純マトリクス型液晶
表示装置の断面概略図である。この液晶表示装置の構造
は、透明ガラスからなる第一平面基板１０１、その表面
に形成されたＩＴＯＩ膜からなるストライプ状の横電極
１０２、第一平面基板１０１の露出した表面と横電極１
０２の表面に形成された液晶配向Ｊｌｉ１０３、および
液晶配向膜の表面に形成されたスペーサ１０４からなる
下基板と、透明ガラスよりなる第二平面基板１０５、そ
の表面に形成されたＩＴＯ薄膜よりなるストライプ状の
縦電極１０６、およびこれらの表面に形成された液晶配
向１！１０７よりなる上基板とをはりあわせ、これらの
周辺部に形成されたシール剤およびスペーサ１０４の先
頭部に形成された接着体１０９で接着固定し、液晶セル
の中に液晶１０８を封入した構造である。FIG. 1 is a schematic cross-sectional view of a simple matrix type liquid crystal display device manufactured according to the present invention. The structure of this liquid crystal display device includes a first flat substrate 101 made of transparent glass, striped horizontal electrodes 102 made of an ITOI film formed on the surface of the first flat substrate 101, and horizontal electrodes 102 formed on the exposed surface of the first flat substrate 101.
A lower substrate consisting of a liquid crystal alignment Jli 103 formed on the surface of 02 and a spacer 104 formed on the surface of the liquid crystal alignment film, a second flat substrate 105 made of transparent glass, and a stripe made of an ITO thin film formed on the surface thereof. A vertical electrode 106 having a shape of 1! and an upper substrate formed on the surfaces of these with liquid crystal orientation 1! It has a structure in which the liquid crystal 108 is fixed with adhesive and fixed in the liquid crystal cell.
第２図（ａ）〜（ｄ）は、第１図に示した液晶表示装置
の下基板の製造方法のうち、主な製造工程後おける下基
板の概略断面図を順次示したものである。第２図にした
がい、本発明の液晶表示装置の製造方法を説明する。同
図（ａ）は第一平面基板２０１の表面に横電極２０２を
形成したのちの概略断面図である。横電極２０２は、第
一平面基板の表面にＩＴＯｆｌｌＫをスパッタ法で堆積
したのち、フォトエツチング法で形成する。同図（ｂ）
は、前記の横電極形成工、程の後に液晶配向膜２０３を
形成したのちの概略断面図である。液晶配向膜は液体状
の配向膜原料をスピンコード法で塗布したのち、所定の
温度、時間キュアを行なって形成する。配向膜原料には
、例えば日本合成ゴム社製のＪＩＢ−２９などがある。FIGS. 2(a) to 2(d) sequentially show schematic cross-sectional views of the lower substrate after the main manufacturing steps in the method for manufacturing the lower substrate of the liquid crystal display device shown in FIG. A method for manufacturing a liquid crystal display device according to the present invention will be explained with reference to FIG. FIG. 3A is a schematic cross-sectional view after forming horizontal electrodes 202 on the surface of a first flat substrate 201. The horizontal electrodes 202 are formed by depositing ITOflK on the surface of the first planar substrate by sputtering, and then by photoetching. Same figure (b)
This is a schematic cross-sectional view after forming a liquid crystal alignment film 203 after the horizontal electrode forming step described above. The liquid crystal alignment film is formed by applying a liquid alignment film raw material by a spin code method and then curing it at a predetermined temperature and time. Examples of alignment film raw materials include JIB-29 manufactured by Japan Synthetic Rubber Co., Ltd.
同図（Ｃ）は、前記の液晶配向膜形成工程に続くスペー
サ２０４の形成工程と、その後のラビング工程の後の概
略断面図である。スペーサ２０４の形成工程は次のよう
である。まず、液晶配向ＪＩ２０３の表面にスピンコー
ド法で感光性ポリイミド（例えば宇部興産層ＰＩ−４１
０）を塗布する。つぎに、スペーサとして残す部分のみ
を、所定の条件で露光、現像し形成する。そして最後に
、所定の条件でポリイミドのキュアをおこない完成する
。スペーサの形成する位置は表示に支障を与えない画面
内の部位が好ましく、例えば隣接する横電極間の隙間お
よび隣接する縦電極間の隙間の交点などが適する。FIG. 3(C) is a schematic cross-sectional view after the step of forming the spacer 204 following the step of forming the liquid crystal alignment film and the subsequent rubbing step. The process of forming the spacer 204 is as follows. First, a photosensitive polyimide (for example, Ube Industries layer PI-41
0). Next, only the portion to be left as a spacer is formed by exposure and development under predetermined conditions. Finally, the polyimide is cured under predetermined conditions to complete the process. The spacer is preferably formed at a location within the screen that does not interfere with display, such as at the intersection of the gap between adjacent horizontal electrodes and the gap between adjacent vertical electrodes.
スペーサの材質はポリイミドに限らず、レジストやその
他の有機材料あるいはガラスなどの無機絶縁材料等が使
用できる。なおポリイミド等のように液晶配向膜あるい
は基板材料に対して密着性に憬れ、機械的強度のある材
料がより好ましい。ラビング工程は、回転ラビング法な
どによって液晶配向１Ｉ２０３の表面を配向処理する工
程である。The material of the spacer is not limited to polyimide, and resists, other organic materials, or inorganic insulating materials such as glass can be used. Note that a material such as polyimide that has good adhesion to the liquid crystal alignment film or substrate material and has mechanical strength is more preferable. The rubbing process is a process of aligning the surface of the liquid crystal alignment 1I 203 by a rotational rubbing method or the like.
液晶配向膜の表面にスペーサなど突起が存在する場合に
は回転ラビング法が適するが、そのほかの例えば、こす
りラビング法や斜方蒸着法でもよい。When a projection such as a spacer is present on the surface of the liquid crystal alignment film, a rotary rubbing method is suitable, but other methods such as a rubbing method or an oblique evaporation method may also be used.
同図（ｄ）は、前記のラビング工程に続く接着体２０５
の形成後の概略断面図である。接着体２゜５は、ロール
コート法により接着剤をスペーサの先頭部にのみ形成し
たものである。接着体２０５の厚み寸法はスペーサの高
さ寸法より小さくし、接着体の形成時あるいは上基板が
はりあわされたときに上基板あるいは下基板の表示部に
接着体が広がらないことが重要である。ロールコート法
による接着体の形成では、ロールに塗布される接着剤の
厚み寸法をスペーサの高さ寸法より小さくすれば、前述
の条件を満たす接着体の形成が可能となる。但し、ロー
ルの直径が小さい場合には、接着体が第一平面基板の表
示部に接触し形成される恐れがあるため、スペーサの間
隔とロールの直径を考慮する必要がある。ロールコート
法以外では、スキージ法などが適する。The same figure (d) shows the adhesive body 205 following the above-mentioned rubbing process.
FIG. 2 is a schematic cross-sectional view after formation. Adhesive body 2.5 is one in which adhesive is applied only to the top of the spacer by roll coating. It is important that the thickness of the adhesive 205 is smaller than the height of the spacer so that the adhesive does not spread to the display area of the upper or lower substrate when the adhesive is formed or when the upper substrate is attached. . In forming an adhesive body by the roll coating method, it is possible to form an adhesive body that satisfies the above-mentioned conditions by making the thickness of the adhesive applied to the roll smaller than the height of the spacer. However, if the diameter of the roll is small, there is a risk that the adhesive will come into contact with the display portion of the first flat substrate, so it is necessary to consider the spacer spacing and the diameter of the roll. Other than the roll coating method, a squeegee method is suitable.
第１図に示した液晶表示装置は、第二図（ａ）〜（ｄ）
に沿って製造された下基板と上基板をはりあわせたのち
、その液晶セル内に液晶を封入して完成される。The liquid crystal display device shown in FIG. 1 is shown in FIGS.
After bonding together the lower and upper substrates manufactured along the lines, liquid crystal is sealed in the liquid crystal cell to complete the process.
このようにして製造された液晶表示装置は、表示面積が
対角１フインチ、ＳＴＮ型において、ギャップのむらは
５．８μｍ±０．１μｍでありコントラスト１： １５
以上と良好であった。これは各スペーサの部分において
、上基板と下基板がスペーサの高さで決まるギャップを
保持したまま接着固定されるため、液晶セルのいたると
ころでギャップが均一になっていることを反映するもの
である。The liquid crystal display device manufactured in this manner has a display area of 1 inch diagonally, an STN type, a gap unevenness of 5.8 μm±0.1 μm, and a contrast of 1:15.
The results were good. This reflects the fact that at each spacer, the upper and lower substrates are adhesively fixed while maintaining the gap determined by the height of the spacer, so the gap is uniform throughout the liquid crystal cell. .
なお本実施例では単純マトリクス型液晶表示装置の製造
方法について述べたが、本発明はアクティブ型液晶表示
装置にも適用されるものである。In this embodiment, a method for manufacturing a simple matrix type liquid crystal display device has been described, but the present invention is also applicable to an active type liquid crystal display device.
［発明の効果］
本発明の液晶表示装置の製造方法には次に列記する発明
の効果を有する。[Effects of the Invention] The method for manufacturing a liquid crystal display device of the present invention has the effects of the invention listed below.
（１）大面積の平面基板を用いた液晶表示装置において
も、均一なギャップが得られるため、安価な原料基板を
使って高品質な液晶表示装置が得られる。(1) Since a uniform gap can be obtained even in a liquid crystal display device using a large-area flat substrate, a high-quality liquid crystal display device can be obtained using an inexpensive raw material substrate.
（２）ラビング等の表面処理の工程とは独立した工程で
接着体が形成できるため、配向特性あるいは信頼性など
を低下させない製造方法である。(2) Since the adhesive body can be formed in a step independent of the surface treatment step such as rubbing, this manufacturing method does not reduce alignment characteristics or reliability.
第１図は本発明により製造された単純マトリクス型液晶
表示装置の断面概略図である。
第２図（ａ）〜（ｄ）は、第１図に示した液晶表示装置
の下基板の製造方法のうち、主な製造工程後おける下基
板の概略断面図を順次水したものである。
第３図は従来の液晶表示装置の概略図である。
１０１．２０１．３０１・・第一平面基板１０２．２０
２．３０２・・横電極
１０３．１０７．２０３．３０３．３０７・・液晶配向
膜
１０４．２０４．３０４・・スペーサ
１０５．３０５・・第二平面電極
１０６．３０６・・縦電極
１０８．３０８・・液晶
１０９．２０５−・・接着体
シール剤
以上FIG. 1 is a schematic cross-sectional view of a simple matrix type liquid crystal display device manufactured according to the present invention. FIGS. 2(a) to 2(d) are sequential schematic cross-sectional views of the lower substrate after the main manufacturing steps in the method for manufacturing the lower substrate of the liquid crystal display device shown in FIG. FIG. 3 is a schematic diagram of a conventional liquid crystal display device. 101.201.301...first planar substrate 102.20
2.302... Horizontal electrode 103.107.203.303.307... Liquid crystal alignment film 104.204.304... Spacer 105.305... Second plane electrode 106.306... Vertical electrode 108.308... Liquid crystal 109.205--Adhesive sealant or higher
Claims (1)
面基板の表面に形成され、前記２枚の平面基板の内面を
平行に保持するスペーサ、該スペーサおよび前記第二平
面基板を接着固定する接着体、および前記２枚の平面基
板の中間に封入された液晶を少なくとも構成要素とする
液晶表示装置の製造方法において、前記スペーサを第一
平面基板の表面に形成する工程と、前記第一平面基板を
配向処理する工程と、前記接着体を前記スペーサの先頭
部に形成する工程とを含むことを特徴とする液晶表示装
置の製造方法。A first planar substrate and a second planar substrate facing each other, a spacer formed on the surface of the first planar substrate and holding the inner surfaces of the two planar substrates in parallel, and adhesively fixing the spacer and the second planar substrate. A method for manufacturing a liquid crystal display device having at least an adhesive and a liquid crystal sealed between the two planar substrates, the step of forming the spacer on the surface of the first planar substrate; A method for manufacturing a liquid crystal display device, comprising the steps of: aligning a substrate; and forming the adhesive at the top of the spacer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2151089A JPH02201424A (en) | 1989-01-31 | 1989-01-31 | Manufacturing method of liquid crystal display device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2151089A JPH02201424A (en) | 1989-01-31 | 1989-01-31 | Manufacturing method of liquid crystal display device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02201424A true JPH02201424A (en) | 1990-08-09 |
Family
ID=12056970
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2151089A Pending JPH02201424A (en) | 1989-01-31 | 1989-01-31 | Manufacturing method of liquid crystal display device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02201424A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2319855B (en) * | 1996-11-28 | 2001-04-18 | Sharp Kk | Liquid crystal display element and method of manufacturing same |
| JP2006337820A (en) * | 2005-06-03 | 2006-12-14 | Lg Phillips Lcd Co Ltd | Liquid crystal display device and its manufacturing method |
| JP2006338011A (en) * | 2005-06-01 | 2006-12-14 | Samsung Electronics Co Ltd | Liquid crystal display panel and method for manufacturing the same |
| US7852448B2 (en) * | 2006-06-08 | 2010-12-14 | Sony Corporation | Liquid crystal display device |
| US7978299B2 (en) | 2007-12-10 | 2011-07-12 | Seiko Epson Corporation | Liquid crystal device and method for manufacturing the same |
-
1989
- 1989-01-31 JP JP2151089A patent/JPH02201424A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2319855B (en) * | 1996-11-28 | 2001-04-18 | Sharp Kk | Liquid crystal display element and method of manufacturing same |
| US6266121B1 (en) | 1996-11-28 | 2001-07-24 | Sharp Kabushiki Kaisha | Liquid crystal display element and method of manufacturing same |
| JP2006338011A (en) * | 2005-06-01 | 2006-12-14 | Samsung Electronics Co Ltd | Liquid crystal display panel and method for manufacturing the same |
| US8040484B2 (en) | 2005-06-01 | 2011-10-18 | Samsung Electronics Co., Ltd. | Liquid crystal display panel having a constant cell gap and method of making the same |
| JP2006337820A (en) * | 2005-06-03 | 2006-12-14 | Lg Phillips Lcd Co Ltd | Liquid crystal display device and its manufacturing method |
| KR101137900B1 (en) * | 2005-06-03 | 2012-04-24 | 엘지디스플레이 주식회사 | liquid crystal display device and method for manufacturing the same |
| US8724073B2 (en) | 2005-06-03 | 2014-05-13 | Lg Display Co., Ltd. | Method for manufacturing liquid crystal display device comprising applying adhesive solution on column spacers and sidewall |
| US7852448B2 (en) * | 2006-06-08 | 2010-12-14 | Sony Corporation | Liquid crystal display device |
| US7978299B2 (en) | 2007-12-10 | 2011-07-12 | Seiko Epson Corporation | Liquid crystal device and method for manufacturing the same |
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