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JPH01148762A - Method for joining metal body to ceramic and joined body - Google Patents

Method for joining metal body to ceramic and joined body

Info

Publication number
JPH01148762A
JPH01148762A JP30834687A JP30834687A JPH01148762A JP H01148762 A JPH01148762 A JP H01148762A JP 30834687 A JP30834687 A JP 30834687A JP 30834687 A JP30834687 A JP 30834687A JP H01148762 A JPH01148762 A JP H01148762A
Authority
JP
Japan
Prior art keywords
ceramic substrate
metal body
paste
ceramic
metallization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP30834687A
Other languages
Japanese (ja)
Other versions
JP2771810B2 (en
Inventor
Shuji Yamazaki
修司 山崎
Shoichi Koyama
小山 昌一
Yoshio Koyama
小沼 良雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shinko Electric Industries Co Ltd
Original Assignee
Shinko Electric Industries Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinko Electric Industries Co Ltd filed Critical Shinko Electric Industries Co Ltd
Priority to JP62308346A priority Critical patent/JP2771810B2/en
Publication of JPH01148762A publication Critical patent/JPH01148762A/en
Application granted granted Critical
Publication of JP2771810B2 publication Critical patent/JP2771810B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/02Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
    • C04B37/023Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
    • C04B37/026Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used consisting of metals or metal salts
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/12Metallic interlayers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32Ceramic
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/40Metallic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Ceramic Products (AREA)

Abstract

PURPOSE:To easily join a metal body to a ceramic substrate with high joining strength by directly joining the metal body to the ceramic substrate with metallizing paste. CONSTITUTION:A ceramic substrate coated with metallizing paste and a metal body coated with metallizing paste are integrated by sintering in a state in which at least one of the metallizing pastes is kept in the unfired state and in contact with the other metallized part or metallizing paste.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明はセラミックに金属体を接合する方法およびこの
接合方法によって得られるセラミックと金属体との接合
体に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for joining a metal body to a ceramic, and a joined body of a ceramic and a metal body obtained by this joining method.

(従来の技術) セラミック基板にモリブデン、鉄−ニッケル合金、鉄−
ニッケルーコバルト合金等の金属線を接合する場合は、
一般にセラミック基板をメタライズし、メタライズ面に
ニッケルめっきを施してからろう材を介して金属線をろ
う付けするようにされている。
(Conventional technology) Molybdenum, iron-nickel alloy, iron-
When joining metal wires such as nickel-cobalt alloy,
Generally, a ceramic substrate is metallized, the metallized surface is plated with nickel, and then metal wires are brazed with a brazing filler metal.

この他の接合方法としては、セラミック基板に厚膜印刷
を行い、この上に金めつきを施すとともに、あらかじめ
金属線に金めつきを施し、この金属線を数百度の温度で
セラミック基板に熱圧着して接合する方法がある。
Another bonding method is to print a thick film on a ceramic substrate, apply gold plating on top of this, and then apply gold plating to a metal wire in advance, and then heat the metal wire to the ceramic substrate at a temperature of several hundred degrees. There is a method of joining by crimping.

(発明が解決しようとする問題点) しかしながら、上述したろう付けによる方法でも金属線
の接合強度は十分ではなく、また、余熱圧着の方法でも
十分な接合強度が得られないという問題点がある。また
、高温で使用する場合にあっては、前記ろう付げによる
方法ではろう材により1000℃程度が限度であり、ま
た、余熱圧着の方法では500℃以上では使用できなく
なる等の使用上の制限があり、大発熱量の部品には十分
な保証ができない。
(Problems to be Solved by the Invention) However, there is a problem in that even the brazing method described above does not provide sufficient bonding strength of metal wires, and even the preheat pressure bonding method does not provide sufficient bonding strength. In addition, when using at high temperatures, the brazing method described above has a limit of about 1000°C due to the brazing material, and the preheat compression method cannot be used at temperatures above 500°C. Therefore, we cannot provide sufficient guarantees for parts that generate a large amount of heat.

また、上述したろう付けによる接合方法では、メタライ
ズ面と金属線にあらかじめめっき処理を施す必要があり
、余熱圧着の方法でもあらかじめセラミックと金属線と
に金めつきを施す必要があって、工程が複雑になるとい
う問題点があり、また、ニッケルめっきを施した場合に
は僅かに磁性を帯びるため高周波特性が劣化するという
問題点がある。また、金属線がモリブデン線の場合はモ
リブデンに金めつきを施すことが難しいという問題点も
ある。
In addition, the above-mentioned joining method by brazing requires plating on the metallized surface and the metal wire in advance, and the preheat pressure bonding method also requires gold plating on the ceramic and the metal wire in advance, which slows down the process. There is a problem in that it becomes complicated, and there is also a problem in that when nickel plating is applied, it becomes slightly magnetic, resulting in deterioration of high frequency characteristics. Furthermore, when the metal wire is a molybdenum wire, there is also the problem that it is difficult to apply gold plating to the molybdenum.

そこで、本発明は上記問題点を解消すべくなされたもの
であり、その目的とするところは、セラミック基板に容
易に金属体を接合することができる接合方法と、この金
属体の接合方法によって得られるセラミックと金属体と
の接合体を提供するにある6 (問題点を解決するための手段) 本発明は上記目的を達成するため次の構成をそなえる。
Therefore, the present invention has been made to solve the above-mentioned problems, and its purpose is to provide a joining method that can easily join a metal body to a ceramic substrate, and to provide benefits obtained by this method of joining the metal body. (Means for solving the problems) The present invention has the following configuration in order to achieve the above object.

すなわち、 セラミック基板と金属体とがメタライズ部により直接一
体化されていることを特徴とし、また、メタライズペー
ストが塗布されたセラミック基板と、メタライズペース
トが塗布された金属体とを、上記両メタライズペースト
の少なくとも一方を未焼成のペーストの状態のままで他
方側のメタライズ部またはメタライズペーストに接触さ
せた状態で焼結して一体化させることを特徴とする。
That is, the ceramic substrate and the metal body are directly integrated by the metallized portion, and the ceramic substrate coated with the metallize paste and the metal body coated with the metallize paste are bonded to each other by the above-mentioned metallization paste. The present invention is characterized in that at least one of the metallized parts or the metallized paste is sintered in an unfired paste state and brought into contact with the other metallized part or metallized paste so as to be integrated.

(作用) 次に作用について述べる。(effect) Next, we will discuss the effect.

セラミック基板と金属体とはめっき面あるいはろう材を
介することなくメタライズ部によって直接一体化して接
合される。金属体とセラミック基板とはメタライズペー
ストの焼結により強固に接合される。
The ceramic substrate and the metal body are directly integrated and joined by the metallized portion without using a plating surface or a brazing material. The metal body and the ceramic substrate are firmly joined by sintering the metallized paste.

(実施例) 以下本発明の好適な実施例を詳細に説明する。(Example) Preferred embodiments of the present invention will be described in detail below.

〔第1実施例〕 第1実施例はべりリアセラミック基板にモリブデン線を
接合したものである。
[First Example] In the first example, a molybdenum wire is bonded to a Berria ceramic substrate.

この実施例では、まず、ベリリアセラミック基板上に、
モリブデン粉末95重量%、酸化マグネシウム2.5重
量%、酸化ケイ素2.5重量%を含有するメタライズペ
ーストを塗布し、1200℃〜1500℃の還元性雰囲
気中で焼成して前記ベリリアセラミック基板上にメタラ
イズ層を形成する。
In this example, first, on a beryllia ceramic substrate,
A metallizing paste containing 95% by weight of molybdenum powder, 2.5% by weight of magnesium oxide, and 2.5% by weight of silicon oxide was applied and fired in a reducing atmosphere at 1200°C to 1500°C to form a coating on the beryllia ceramic substrate. Form a metallized layer on.

次いで、前記ベリリアセラミック基板に接合するモリブ
デン線の下端に前記メタライズペーストを付着させ、前
記ベリリアセラミック基板上にモリブデン線を位置決め
する。
Next, the metallization paste is attached to the lower end of the molybdenum wire to be bonded to the beryllia ceramic substrate, and the molybdenum wire is positioned on the beryllia ceramic substrate.

モリブデン線に付けられたメタライズペーストが乾燥し
た後、再度1200℃〜1500℃の還元性雰囲気中で
焼成して、モリブデン線とベリリアセラミック基板とを
接合する。
After the metallization paste applied to the molybdenum wire is dried, it is fired again in a reducing atmosphere at 1200° C. to 1500° C. to bond the molybdenum wire and the beryllia ceramic substrate.

焼成完了後のモリブデン線とベリリアセラミックの接合
体は前記メタライズペーストが焼結される際に接合する
ので、従来のろう付けによる接合方法や、余熱圧着の接
合方法とくらべて接合強度を向上させることができた。
After completion of firing, the bonded body of molybdenum wire and beryllia ceramic is bonded when the metallized paste is sintered, so the bonding strength is improved compared to the conventional bonding method using brazing or preheat compression bonding. I was able to do that.

なお、上述したように続けて2度焼成を行ってモリブデ
ン線の接合を行うかわりに、ベリリアセラミック基板に
メタライズペーストを塗布した際に同時にモリブデン線
をメタライズペーストに接触させておき、1回の焼成で
ベリリアセラミック基板とモリブデン線との接合を行う
ようにすることも可能である。
In addition, instead of performing two consecutive firings to bond the molybdenum wires as described above, the molybdenum wires are brought into contact with the metallization paste at the same time when the metallization paste is applied to the beryllia ceramic substrate, and the molybdenum wires are fired once. It is also possible to bond the beryllia ceramic substrate and the molybdenum wire by firing.

なお、ベリリアセラミックにたいして、一般に使用され
ているモリブデン−マンガン系のメタライズペーストを
使用した場合はペースト中のマンガンがベリリアセラミ
ック中に拡散する性質によってメタライズ層とベリリア
セラミック基板間では十分な接合力を有しないが、前記
モリブデン粉末、酸化マグネシウム、酸化ケイ素からな
るメタライズペーストはべりリアセラミック基板とのマ
ツチングが良好であり、ベリリアセラミック基板とメタ
ライズ層間で好適な接合力を有するものである。ここで
、ベリリアセラミック基板用に好適に使用できるメタラ
イズペーストの組成は、モリブデン粉末80重量%以上
、酸化マグネシウム15重量%以下、酸化ケイ素15重
足%以下の組成のものである。なお、このメタライズペ
ーストには適宜アルミナ、酸化クロム、酸化カルシウム
を添加して用いてもよい。
Note that when a commonly used molybdenum-manganese metallization paste is used for beryllia ceramic, sufficient bonding between the metallized layer and the beryllia ceramic substrate is not achieved due to the property of manganese in the paste diffusing into the beryllia ceramic. Although the metallization paste is not strong, the metallization paste made of molybdenum powder, magnesium oxide, and silicon oxide has good matching with the Bereria ceramic substrate and has a suitable bonding force between the Bereria ceramic substrate and the metallization layer. Here, the composition of the metallizing paste that can be suitably used for the beryllia ceramic substrate is one containing 80% by weight or more of molybdenum powder, 15% by weight or less of magnesium oxide, and 15% by weight or less of silicon oxide. Note that alumina, chromium oxide, and calcium oxide may be added to this metallization paste as appropriate.

〔第2実施例〕 第2実施例はアルミナセラミック基板にモリブデンある
いは、タングステン、鉄−ニッケル合金、鉄−ニッケル
ーコバルト合金等からなる金属線を接合する例である。
[Second Embodiment] The second embodiment is an example in which a metal wire made of molybdenum, tungsten, iron-nickel alloy, iron-nickel-cobalt alloy, etc. is bonded to an alumina ceramic substrate.

この実施例でも第1実施例と同様にアルミナセラミック
基板にメタライズペーストを塗布した後1200℃〜1
500℃の還元性雰囲気中で焼成し、ついで金属線にメ
タライズペーストを付着させるとともに、焼成されたメ
タライズ層に位置決めした後再度1200℃〜1500
℃の還元性雰囲気中で焼成し、金属線をアルミナセラミ
ック基板上に接合する。
In this example, as in the first example, after applying the metallization paste to the alumina ceramic substrate,
It is fired in a reducing atmosphere at 500°C, and then the metallization paste is attached to the metal wire, and after being positioned on the fired metallized layer, it is heated again at 1200°C to 1500°C.
The metal wire is bonded onto the alumina ceramic substrate by firing in a reducing atmosphere at ℃.

ここで、アルミナセラミック基板用として以下のメタラ
イズペーストが好適に使用できる。
Here, the following metallization pastes can be suitably used for alumina ceramic substrates.

■ モリブデン粉末80重量%以上、酸化ケイ素15型
組%以下、酸化マグネジ9415重景%以下、■ モリ
ブデン粉末80重量%以上、酸化ケイ素15型組%以下
、アルミナ15重量%以下、■ モリブデン粉末80重
量%以上、酸化ケイ素15重量%以下。
■ Molybdenum powder 80% by weight or more, silicon oxide 15% or less, magneth oxide 9415 grazing% or less, ■ Molybdenum powder 80% or more, silicon oxide 15% or less, alumina 15% by weight or less, ■ Molybdenum powder 80% % by weight or more, and 15% by weight or less of silicon oxide.

この第2実施例においても、メタライズペーストの焼結
によって金属線はメタライズ層を介してアルミナセラミ
ック基板と一体に接合するから、従来のろう付は接合方
法および余熱圧着接合方法とくらべて大きな接合強度を
得ることができる。
In this second embodiment as well, the metal wire is integrally joined to the alumina ceramic substrate through the metallized layer by sintering the metallized paste, so the conventional brazing has a higher joining strength than the joining method and the preheat compression joining method. can be obtained.

また、上述した第1実施例および第2実施例かられかる
ように、本実施例の方法によればメタライズペーストを
介して金属線をそのまま接合しているので、ろう付は方
法や全熱圧着方法のときのようにめっき処理を施す必要
がなく接合操作が一層容易である。
In addition, as can be seen from the first and second embodiments described above, according to the method of this embodiment, the metal wires are directly joined via the metallization paste, so brazing is performed using the full heat compression method. Unlike the conventional method, there is no need to perform plating treatment, making the joining operation easier.

なお、上述した実施例においてはモリブデン等の金属線
を接合する例について述べたが、セラミックに接合され
る金属体は金属線に限定されるものではなく、金属の板
状体等であっても同様に接合できる。
In addition, in the above-mentioned embodiment, an example was described in which a metal wire such as molybdenum was bonded, but the metal body to be bonded to the ceramic is not limited to a metal wire, and may be a metal plate-shaped body or the like. It can be joined in the same way.

以上、本発明について好適な実施例を挙げて種々説明し
たが、本発明はこの実施例に限定されるものではなく、
発明の精神を逸脱しない範囲内で多くの改変を施し得る
のはもちろんのことである。
As mentioned above, various explanations have been given of the present invention by giving preferred examples, but the present invention is not limited to these examples.
Of course, many modifications can be made without departing from the spirit of the invention.

(発明の効果) 本発明のセラミックと金属体の接合方法ではメタライズ
ペーストを用いてセラミック基板と金属体とを直接接合
するようにしているから、ろう付は接合の場合のように
めっき処理やろう材が不必要であり、金属体をそのまま
接合することができるので、接合作業をきわめて容易に
行うことができる。
(Effect of the invention) Since the ceramic and metal body bonding method of the present invention uses a metallization paste to directly bond the ceramic substrate and the metal body, brazing can be performed by plating as in the case of bonding. Since no materials are required and the metal bodies can be joined as they are, the joining work can be performed extremely easily.

また、この接合方法によれば、焼結されたメタライズ部
によってセラミックと金属体が直接接合されるから、従
来の接合方法によるものと比較して接合強度を向上させ
ることができる。また、メタライズ層によって一体化し
ているから接合個所の耐熱性が高く、高温にさらされる
部品に使用しても十分な信頼性を保証することができる
Further, according to this joining method, the ceramic and the metal body are directly joined by the sintered metallized portion, so that the joining strength can be improved compared to the conventional joining method. In addition, since they are integrated by a metallized layer, the joints have high heat resistance, and sufficient reliability can be guaranteed even when used in parts exposed to high temperatures.

Claims (1)

【特許請求の範囲】 1、セラミック基板と金属体とがメタライズ部により直
接一体化されていることを特徴とするセラミックと金属
体との接合体。 2、メタライズペーストが塗布されたセラミック基板と
、メタライズペーストが塗布された金属体とを、上記両
メタライズペーストの少なくとも一方を未焼成のペース
トの状態のままで他方側のメタライズ部またはメタライ
ズペーストに接触させた状態で焼結して一体化させるこ
とを特徴とするセラミックと金属体との接合方法。
[Claims] 1. A joined body of a ceramic and a metal body, characterized in that the ceramic substrate and the metal body are directly integrated through a metallized portion. 2. Contact the ceramic substrate coated with the metallization paste and the metal body coated with the metallization paste with the metallization part or metallization paste on the other side, with at least one of the two metallization pastes remaining in an unfired paste state. A method of joining a ceramic and a metal body, which is characterized by sintering the ceramic body and integrating the metal body.
JP62308346A 1987-12-05 1987-12-05 Method of joining ceramic and metal body and joined body Expired - Lifetime JP2771810B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62308346A JP2771810B2 (en) 1987-12-05 1987-12-05 Method of joining ceramic and metal body and joined body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62308346A JP2771810B2 (en) 1987-12-05 1987-12-05 Method of joining ceramic and metal body and joined body

Publications (2)

Publication Number Publication Date
JPH01148762A true JPH01148762A (en) 1989-06-12
JP2771810B2 JP2771810B2 (en) 1998-07-02

Family

ID=17979955

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62308346A Expired - Lifetime JP2771810B2 (en) 1987-12-05 1987-12-05 Method of joining ceramic and metal body and joined body

Country Status (1)

Country Link
JP (1) JP2771810B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116052922A (en) * 2022-12-30 2023-05-02 河北中瓷电子科技股份有限公司 A kind of electronic slurry for beryllium oxide ceramics and its preparation method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5864283A (en) * 1981-10-13 1983-04-16 トヨタ自動車株式会社 How to join ceramics and metal
JPS59223280A (en) * 1983-06-02 1984-12-15 日本特殊陶業株式会社 Method of bonding ceramic and metal
JPS6246975A (en) * 1985-08-23 1987-02-28 株式会社東芝 Method of joining ti to ceramic

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5864283A (en) * 1981-10-13 1983-04-16 トヨタ自動車株式会社 How to join ceramics and metal
JPS59223280A (en) * 1983-06-02 1984-12-15 日本特殊陶業株式会社 Method of bonding ceramic and metal
JPS6246975A (en) * 1985-08-23 1987-02-28 株式会社東芝 Method of joining ti to ceramic

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116052922A (en) * 2022-12-30 2023-05-02 河北中瓷电子科技股份有限公司 A kind of electronic slurry for beryllium oxide ceramics and its preparation method
CN116052922B (en) * 2022-12-30 2025-03-04 河北中瓷电子科技股份有限公司 Electronic slurry for beryllium oxide ceramics and preparation method thereof

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