JP7613303B2 - 炭化珪素半導体装置の製造方法 - Google Patents
炭化珪素半導体装置の製造方法 Download PDFInfo
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- 239000004065 semiconductor Substances 0.000 title claims description 102
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims description 50
- 229910010271 silicon carbide Inorganic materials 0.000 title claims description 50
- 238000004519 manufacturing process Methods 0.000 title claims description 30
- 238000000034 method Methods 0.000 title claims description 27
- 239000010410 layer Substances 0.000 claims description 95
- 229910052751 metal Inorganic materials 0.000 claims description 69
- 239000002184 metal Substances 0.000 claims description 69
- 239000000758 substrate Substances 0.000 claims description 65
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 23
- 230000004888 barrier function Effects 0.000 claims description 23
- 229910052760 oxygen Inorganic materials 0.000 claims description 23
- 239000001301 oxygen Substances 0.000 claims description 23
- 229910021332 silicide Inorganic materials 0.000 claims description 21
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 21
- 239000011229 interlayer Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 19
- 239000012535 impurity Substances 0.000 claims description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 17
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 13
- 229920005591 polysilicon Polymers 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 239000002344 surface layer Substances 0.000 claims description 5
- 238000000059 patterning Methods 0.000 claims description 3
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- 239000010408 film Substances 0.000 description 127
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 238000005229 chemical vapour deposition Methods 0.000 description 5
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 238000005530 etching Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- PEUPIGGLJVUNEU-UHFFFAOYSA-N nickel silicon Chemical compound [Si].[Ni] PEUPIGGLJVUNEU-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000005380 borophosphosilicate glass Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000001039 wet etching Methods 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical compound [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 description 1
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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- H10D30/0281—Manufacture or treatment of FETs having insulated gates [IGFET] of double-diffused metal oxide semiconductor [DMOS] FETs of lateral DMOS [LDMOS] FETs
- H10D30/0289—Manufacture or treatment of FETs having insulated gates [IGFET] of double-diffused metal oxide semiconductor [DMOS] FETs of lateral DMOS [LDMOS] FETs using recessing of the gate electrodes, e.g. to form trench gate electrodes
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- H10D30/66—Vertical DMOS [VDMOS] FETs
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- H10D62/83—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge
- H10D62/832—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge being Group IV materials comprising two or more elements, e.g. SiGe
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- H10D12/461—Vertical IGBTs having non-planar surfaces, e.g. having trenches, recesses or pillars in the surfaces of the emitter, base or collector regions
- H10D12/481—Vertical IGBTs having non-planar surfaces, e.g. having trenches, recesses or pillars in the surfaces of the emitter, base or collector regions having gate structures on slanted surfaces, on vertical surfaces, or in grooves, e.g. trench gate IGBTs
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- H10D64/511—Gate electrodes for field-effect devices for FETs for IGFETs
- H10D64/517—Gate electrodes for field-effect devices for FETs for IGFETs characterised by the conducting layers
- H10D64/519—Gate electrodes for field-effect devices for FETs for IGFETs characterised by the conducting layers characterised by their top-view geometrical layouts
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- H10D64/693—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator the insulator comprising nitrogen, e.g. nitrides, oxynitrides or nitrogen-doped materials
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Description
第1実施形態について、図面を参照しつつ説明する。本実施形態では、SiC半導体装置として、トレンチゲート構造の反転型のMOSFETが形成されたものを例に挙げて説明する。まず、SiC半導体装置の構成について説明する。
第2実施形態について説明する。本実施形態は、第1実施形態に対し、バリアメタル膜を形成したものである。その他に関しては、第1実施形態と同様であるため、ここでは説明を省略する。
本開示は、実施形態に準拠して記述されたが、本開示は当該実施形態や構造に限定されるものではないと理解される。本開示は、様々な変形例や均等範囲内の変形をも包含する。加えて、様々な組み合わせや形態、さらには、それらに一要素のみ、それ以上、あるいはそれ以下、を含む他の組み合わせや形態をも、本開示の範疇や思想範囲に入るものである。
10a 一面
11 基板
12 ドリフト層
13 ベース層
14 ソース領域(不純物領域)
15 ゲート絶縁膜
18 ゲート電極
19 接続配線
20 層間絶縁膜
22 ソース電極
23 ゲート配線
24 金属シリサイド膜
31 金属層
31a 未反応金属層
Claims (3)
- ゲート電極(18)と接続される接続配線(19)を備える炭化珪素半導体装置の製造方法であって、
第1導電型または第2導電型とされた基板(11)と、前記基板上に形成された第1導電型のドリフト層(12)と、前記ドリフト層上に形成された第2導電型のベース層(13)と、前記ベース層の表層部に形成された第1導電型の不純物領域(14)と、を有し、前記ベース層のうちの前記ドリフト層と前記不純物領域との間にゲート絶縁膜(17)が形成されると共に前記ゲート絶縁膜上に前記ゲート電極が形成され、前記ベース層側の面を一面(10a)として前記一面上に、前記ゲート電極と接続されると共にポリシリコンで構成される前記接続配線が形成され、炭化珪素で構成された半導体基板(10)を用意することと、
前記ベース層、前記不純物領域、前記ゲート電極、および前記接続配線が覆われるように層間絶縁膜(20)を形成することと、
前記層間絶縁膜を含む部分に対し、前記ベース層および前記不純物領域を露出させる第1コンタクトホール(21a)を形成すると共に、前記接続配線を露出させる第2コンタクトホール(21b)を形成することと、
熱酸化を行い、前記接続配線のうちの前記第2コンタクトホールから露出する部分に酸化膜(30)を形成することと、
前記半導体基板のうちの前記第1コンタクトホールから露出する部分に金属層(31)を形成することと、
加熱処理を行い、前記金属層と前記半導体基板とを反応させて金属シリサイド膜(24)を形成することと、
前記金属層のうちの前記金属シリサイド膜となった部分と異なる部分の未反応金属層(31a)を除去することと、
前記第1コンタクトホールを通じて前記ベース層および前記不純物領域と電気的に接続される電極(22)を形成すると共に、前記第2コンタクトホールを通じて前記接続配線と電気的に接続され、前記酸化膜の酸素を還元可能な材料で構成された部分を有するゲート配線(23)を形成することと、を行い、
前記ゲート配線を形成することの途中、または前記ゲート配線を形成した後には、前記ゲート配線に関する加熱処理を行い、前記接続配線上に形成されている前記酸化膜の酸素を前記ゲート配線内に還元させて当該酸化膜を除去することを行い、
前記半導体基板を用意することでは、前記ゲート電極を形成することの後、前記半導体基板のうちの前記ゲート絶縁膜との界面におけるダングリングボンドを窒素で終端させることを行い、
前記酸化膜を形成することでは、10nm以下の前記酸化膜を形成する炭化珪素半導体装置の製造方法。 - 前記ゲート配線を形成した後、前記ゲート配線に関する加熱処理として、前記ゲート配線の膜質を安定化させる加熱処理を行い、
前記酸化膜を除去することは、前記ゲート配線の膜質を安定化させる加熱処理を行っている際に行う請求項1に記載の半導体装置の製造方法。 - 前記ゲート配線を形成することでは、主配線層(41)を形成することと、前記主配線層を形成することの前に、前記酸化膜の酸素を還元可能な材料であって、前記主配線層より拡散し難い材料であるバリアメタル層(40)を形成することと、前記バリアメタル層および前記主配線層をパターニングして前記ゲート配線を形成することと、を行い、
前記バリアメタル層を形成することの後であって前記主配線層を形成することの前に、前記ゲート配線に関する加熱処理として、前記バリアメタル層と前記接続配線とを反応させて金属シリサイド膜(26)を形成する加熱処理を行い、
前記酸化膜を除去することは、当該金属シリサイド膜を形成する加熱処理を行っている際に行う請求項1に記載の半導体装置の製造方法。
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JP2021112146A JP7613303B2 (ja) | 2021-07-06 | 2021-07-06 | 炭化珪素半導体装置の製造方法 |
US17/851,702 US20230009078A1 (en) | 2021-07-06 | 2022-06-28 | Method of manufacturing silicon carbide semiconductor device |
CN202210786074.7A CN115588617A (zh) | 2021-07-06 | 2022-07-04 | 制造碳化硅半导体器件的方法 |
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JP2010062402A (ja) | 2008-09-05 | 2010-03-18 | Mitsubishi Electric Corp | 半導体装置の製造方法 |
JP2020150242A (ja) | 2019-03-15 | 2020-09-17 | 株式会社東芝 | 半導体装置 |
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JP4825688B2 (ja) * | 2002-09-11 | 2011-11-30 | 株式会社東芝 | 半導体装置の製造方法 |
WO2010131571A1 (ja) * | 2009-05-11 | 2010-11-18 | 住友電気工業株式会社 | 半導体装置 |
JP6750590B2 (ja) * | 2017-09-27 | 2020-09-02 | 株式会社デンソー | 炭化珪素半導体装置 |
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JP2010062402A (ja) | 2008-09-05 | 2010-03-18 | Mitsubishi Electric Corp | 半導体装置の製造方法 |
JP2020150242A (ja) | 2019-03-15 | 2020-09-17 | 株式会社東芝 | 半導体装置 |
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