JP7547392B2 - 冷間圧延マルテンサイト鋼及びその冷間圧延マルテンサイト鋼の製造方法 - Google Patents
冷間圧延マルテンサイト鋼及びその冷間圧延マルテンサイト鋼の製造方法 Download PDFInfo
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- JP7547392B2 JP7547392B2 JP2021573436A JP2021573436A JP7547392B2 JP 7547392 B2 JP7547392 B2 JP 7547392B2 JP 2021573436 A JP2021573436 A JP 2021573436A JP 2021573436 A JP2021573436 A JP 2021573436A JP 7547392 B2 JP7547392 B2 JP 7547392B2
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- 229910000831 Steel Inorganic materials 0.000 title claims description 99
- 239000010959 steel Substances 0.000 title claims description 99
- 229910000734 martensite Inorganic materials 0.000 title claims description 41
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000001816 cooling Methods 0.000 claims description 30
- 238000010438 heat treatment Methods 0.000 claims description 20
- 239000010960 cold rolled steel Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 19
- 229910000859 α-Fe Inorganic materials 0.000 claims description 13
- 239000011572 manganese Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910001563 bainite Inorganic materials 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 239000011651 chromium Substances 0.000 claims description 7
- 238000005098 hot rolling Methods 0.000 claims description 7
- 238000005496 tempering Methods 0.000 claims description 6
- 230000001186 cumulative effect Effects 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- 229910001566 austenite Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 238000003303 reheating Methods 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 3
- 238000005097 cold rolling Methods 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 239000011265 semifinished product Substances 0.000 claims 3
- 229910052742 iron Inorganic materials 0.000 claims 1
- 230000000717 retained effect Effects 0.000 claims 1
- 238000004804 winding Methods 0.000 claims 1
- 238000000137 annealing Methods 0.000 description 13
- 229910052710 silicon Inorganic materials 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- 230000009466 transformation Effects 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 230000002411 adverse Effects 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000010955 niobium Substances 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000009749 continuous casting Methods 0.000 description 4
- 229910052758 niobium Inorganic materials 0.000 description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 230000000979 retarding effect Effects 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- -1 Titanium forms titanium nitrides Chemical class 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000002939 deleterious effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910001562 pearlite Inorganic materials 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910001567 cementite Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000004881 precipitation hardening Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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- C—CHEMISTRY; METALLURGY
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
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- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
- C21D1/22—Martempering
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
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- C21D8/0226—Hot rolling
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0273—Final recrystallisation annealing
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- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
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- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
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- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
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- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
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- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
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- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
Description
- 1700MPa以上、好ましくは1750MPaを超える最大引張強さ、
- 1500MPa以上、好ましくは1550MPaを超える降伏強さ、
- 少なくとも22%、好ましくは25%を超える穴広げ率、
を同時に有する冷間圧延マルテンサイト鋼板を利用可能にすることにより、これらの問題を解決することにある。
Ac3=910-203[C]^(1/2)-15.2[Ni]+44.7[Si]+104[V]+31.5[Mo]+13.1[W]-30[Mn]-11[Cr]-20[Cu]+700[P]+400[Al]+120[As]+400[Ti]
式中、元素含量は冷間圧延鋼板の重量百分率で表される。
Ms=545-601.2*(1-EXP(-0.868[C]))-34.4[Mn]-13.7[Si]-9.2[Cr]-17.3[Ni]-15.4[Mo]+10.8[V]+4.7[Co]-1.4[Al]-16.3[Cu]-361[Nb]-2.44[Ti]-3448[B]
表2は、冷間圧延マルテンサイト鋼となるために必要な機械的特性を表1の鋼に付与するために、冷間圧延鋼板に実施された熱間圧延及び焼鈍のプロセスパラメータをまとめた。
前記標準に従って実施された種々の機械的試験の結果をまとめた。試験は、JIS-Z2241に従い、最大引張強さ及び降伏強さを試験する。穴広げを評価するために、穴広げと呼ばれる試験を適用する。この試験では、試料にパンチで10mmの穴を開け、変形させ、変形後に穴の直径を測定し、HER%=100*(Df-Di)/Diを計算する。
Claims (18)
- 冷間圧延マルテンサイト鋼板であって、重量パーセントで表される以下の元素、すなわち、
0.3%≦C≦0.4%、
0.5%≦Mn≦1%、
0.2%≦Si≦0.6%、
0.1%≦Cr≦1%、
0.01%≦Al≦1%、
0.01%≦Mo≦0.5%、
0.001%≦Ti≦0.1%、
0%≦S≦0.09%、
0%≦P≦0.09%、
0%≦N≦0.09%、
を含み、以下の任意元素、すなわち、
0%≦Nb≦0.1%、
0%≦V≦0.1%、
0%≦Ni≦1%、
0%≦Cu≦1%、
0%≦B≦0.05%、
0.001%≦Ca≦0.01%、
0%≦Sn≦0.1%、
0%≦Pb≦0.1%、
0%≦Sb≦0.1%、
の1種以上を含むことができ、残余の組成は鉄及び加工により生ずる不可避の不純物から構成され、前記冷間圧延マルテンサイト鋼板の微細組織は、面積百分率により、少なくとも95%のマルテンサイトと、1~5%の間の累積量のフェライト及びベイナイトと、0~2%の間の任意の量の残留オーステナイトとを含む、冷間圧延マルテンサイト鋼板。 - 前記組成が、0.3%~0.38%の炭素を含む、請求項1に記載の冷間圧延マルテンサイト鋼板。
- 前記組成が、0.3%~0.36%の炭素を含む、請求項1又は2に記載の冷間圧延マルテンサイト鋼板。
- 前記組成が、0.01%~0.5%のアルミニウムを含む、請求項1~3のいずれか一項に記載の冷間圧延マルテンサイト鋼板。
- 前記組成が、0.5%~0.9%のマンガンを含む、請求項1~4のいずれか一項に記載の冷間圧延マルテンサイト鋼板。
- 前記組成が、0.3%~0.9%のクロムを含む、請求項1~5のいずれか一項に記載の冷間圧延マルテンサイト鋼板。
- マルテンサイトの量が96%~99%の間である、請求項1~6のいずれか一項に記載の冷間圧延マルテンサイト鋼板。
- フェライト及びベイナイトの前記累積量が、1%~4%の間である、請求項1~7のいずれか一項に記載の冷間圧延マルテンサイト鋼板。
- 請求項1~8のいずれか一項に記載の冷間圧延マルテンサイト鋼板であって、1700MPa以上の最大引張強さ、及び1500MPa以上の降伏強さを有する、冷間圧延マルテンサイト鋼板。
- 以下の連続工程を含む冷間圧延マルテンサイト鋼板の製造方法。
- 請求項1~6のいずれか一項に記載の化学組成を有する半製品を提供する工程、
- 前記半製品を1000℃~1280℃の間の温度に再加熱する工程、
- オーステナイトの範囲で前記半製品を圧延し、ここで、熱間圧延仕上げ温度はAc3~Ac3+100℃の間である、熱間圧延鋼板を得る工程、
- 少なくとも20℃/秒の冷却速度で前記熱間圧延鋼板を650℃未満の巻取り温度まで冷却する工程;及び前記熱間圧延鋼板を巻取る工程、
- 前記熱間圧延鋼板を室温まで冷却する工程、
- 前記熱間圧延鋼板にスケール除去処理を施す、任意の工程、
- 前記熱間圧延鋼板を焼鈍することができる、任意の工程、
- 前記熱間圧延鋼板にスケール除去処理を施す、任意の工程、
- 35~90%の間の圧下率で前記熱間圧延鋼板を冷間圧延し、冷間圧延鋼板を得る工程、
- 次いで、前記冷間圧延鋼板を2段階加熱で加熱する工程であって、
○ 前記冷間圧延鋼板を加熱する第1段階は室温から始まり、少なくとも10℃/秒の加熱速度HR1で550~750℃の間の温度HT1まで行われ、
○ 加熱の第2段階はHT1から始まり、1℃/秒~50℃/秒の間の加熱速度HR2でAc3~Ac3+100℃の間の温度Tsoakまで行われ、それが10~500秒間保持される、2段階加熱で加熱する工程、
- 次いで、前記冷間圧延鋼板を2段階冷却で冷却する工程であって、
○ 前記冷間圧延鋼板を冷却する第1段階はTsoakから始まり、30℃/秒~150℃/秒の間の冷却速度CR1で630℃~750℃の間の温度T1まで行われ、
○ 冷却の第2段階はT1から始まり、少なくとも50℃/秒の冷却速度CR2でMs-10~20℃の間の温度T2まで行われる、2段階冷却で冷却する工程、
- 次いで、前記冷間圧延鋼板を少なくとも1℃/秒の速度で、150~300℃の間の焼き戻し温度Ttemperまで再加熱し、それが100~600秒間保持される工程、
- 次いで、少なくとも1℃/秒の冷却速度で室温まで冷却し、請求項1~6のいずれか一項に記載の冷間圧延マルテンサイト鋼板を得る工程。 - 前記巻取り温度が475℃~625℃の間である、請求項10に記載の方法。
- TsoakがAc3+10℃~Ac3+100℃の間である、請求項10又は11に記載の方法。
- CR1が30℃/秒~120℃/秒の間である、請求項10~12のいずれか一項に記載の方法。
- T1が640℃~725℃の間である、請求項10~13のいずれか一項に記載の方法。
- CR2が少なくとも100℃/秒である、請求項10~14のいずれか一項に記載の方法。
- T2がMs-50℃~20℃の間である、請求項10~15のいずれか一項に記載の方法。
- Ttemperが200℃~300℃の間である、請求項10~16のいずれか一項に記載の方法。
- 車両の構造部品を製造するための、請求項1~9のいずれか一項により得ることができる鋼板の使用。
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