JP7522662B2 - 新規の作物栄養および強化組成物 - Google Patents
新規の作物栄養および強化組成物 Download PDFInfo
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- JP7522662B2 JP7522662B2 JP2020563540A JP2020563540A JP7522662B2 JP 7522662 B2 JP7522662 B2 JP 7522662B2 JP 2020563540 A JP2020563540 A JP 2020563540A JP 2020563540 A JP2020563540 A JP 2020563540A JP 7522662 B2 JP7522662 B2 JP 7522662B2
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- manganese
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- 239000000203 mixture Substances 0.000 title claims description 682
- 235000016709 nutrition Nutrition 0.000 title claims description 153
- 230000035764 nutrition Effects 0.000 title claims description 150
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 188
- -1 manganese fluorosilicate Chemical compound 0.000 claims description 170
- 239000011572 manganese Substances 0.000 claims description 117
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 116
- 150000002696 manganese Chemical class 0.000 claims description 93
- 239000006194 liquid suspension Substances 0.000 claims description 87
- 229910052748 manganese Inorganic materials 0.000 claims description 86
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 84
- 235000002639 sodium chloride Nutrition 0.000 claims description 73
- 239000003795 chemical substances by application Substances 0.000 claims description 69
- 239000002245 particle Substances 0.000 claims description 68
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 67
- 150000003839 salts Chemical class 0.000 claims description 65
- 239000003337 fertilizer Substances 0.000 claims description 56
- 238000000034 method Methods 0.000 claims description 52
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 46
- 239000002689 soil Substances 0.000 claims description 36
- 239000004480 active ingredient Substances 0.000 claims description 27
- 239000002270 dispersing agent Substances 0.000 claims description 27
- 235000015097 nutrients Nutrition 0.000 claims description 26
- 239000008187 granular material Substances 0.000 claims description 25
- 239000011785 micronutrient Substances 0.000 claims description 24
- 235000013369 micronutrients Nutrition 0.000 claims description 24
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 21
- 235000002867 manganese chloride Nutrition 0.000 claims description 21
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 20
- 239000011230 binding agent Substances 0.000 claims description 20
- 239000011565 manganese chloride Substances 0.000 claims description 20
- 239000004094 surface-active agent Substances 0.000 claims description 19
- 239000006260 foam Substances 0.000 claims description 16
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 claims description 16
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 15
- 239000000872 buffer Substances 0.000 claims description 13
- 239000000969 carrier Substances 0.000 claims description 13
- 229940099607 manganese chloride Drugs 0.000 claims description 13
- 230000007480 spreading Effects 0.000 claims description 13
- 238000003892 spreading Methods 0.000 claims description 13
- 235000007079 manganese sulphate Nutrition 0.000 claims description 12
- 239000003755 preservative agent Substances 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 239000000080 wetting agent Substances 0.000 claims description 12
- 239000007884 disintegrant Substances 0.000 claims description 11
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 claims description 11
- 229940099596 manganese sulfate Drugs 0.000 claims description 11
- 239000011702 manganese sulphate Substances 0.000 claims description 11
- 239000011656 manganese carbonate Substances 0.000 claims description 10
- 235000006748 manganese carbonate Nutrition 0.000 claims description 10
- 229940093474 manganese carbonate Drugs 0.000 claims description 10
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims description 10
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 claims description 10
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- RJYMRRJVDRJMJW-UHFFFAOYSA-L dibromomanganese Chemical compound Br[Mn]Br RJYMRRJVDRJMJW-UHFFFAOYSA-L 0.000 claims description 9
- 238000003801 milling Methods 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 9
- OAVRWNUUOUXDFH-UHFFFAOYSA-H 2-hydroxypropane-1,2,3-tricarboxylate;manganese(2+) Chemical compound [Mn+2].[Mn+2].[Mn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O OAVRWNUUOUXDFH-UHFFFAOYSA-H 0.000 claims description 8
- QGBLCIBATKETJC-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;manganese(2+) Chemical compound [Mn+2].O1B([O-])OB2OB([O-])OB1O2 QGBLCIBATKETJC-UHFFFAOYSA-N 0.000 claims description 8
- JLUGKDWGQPNDGX-UHFFFAOYSA-L azanium;manganese(2+);phosphate Chemical compound [NH4+].[Mn+2].[O-]P([O-])([O-])=O JLUGKDWGQPNDGX-UHFFFAOYSA-L 0.000 claims description 8
- WMOSTDJFFWYKNF-UHFFFAOYSA-L hydrogen carbonate;manganese(2+) Chemical compound [Mn+2].OC([O-])=O.OC([O-])=O WMOSTDJFFWYKNF-UHFFFAOYSA-L 0.000 claims description 8
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 claims description 8
- 229940071125 manganese acetate Drugs 0.000 claims description 8
- 239000011564 manganese citrate Substances 0.000 claims description 8
- 235000014872 manganese citrate Nutrition 0.000 claims description 8
- 229940097206 manganese citrate Drugs 0.000 claims description 8
- 239000011683 manganese gluconate Substances 0.000 claims description 8
- 235000014012 manganese gluconate Nutrition 0.000 claims description 8
- 229940072543 manganese gluconate Drugs 0.000 claims description 8
- OXHQNTSSPHKCPB-IYEMJOQQSA-L manganese(2+);(2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Mn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OXHQNTSSPHKCPB-IYEMJOQQSA-L 0.000 claims description 8
- RGVLTEMOWXGQOS-UHFFFAOYSA-L manganese(2+);oxalate Chemical compound [Mn+2].[O-]C(=O)C([O-])=O RGVLTEMOWXGQOS-UHFFFAOYSA-L 0.000 claims description 8
- QWYFOIJABGVEFP-UHFFFAOYSA-L manganese(ii) iodide Chemical compound [Mn+2].[I-].[I-] QWYFOIJABGVEFP-UHFFFAOYSA-L 0.000 claims description 8
- 239000003002 pH adjusting agent Substances 0.000 claims description 8
- 230000003472 neutralizing effect Effects 0.000 claims description 7
- 239000006096 absorbing agent Substances 0.000 claims description 6
- 230000000149 penetrating effect Effects 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 230000002335 preservative effect Effects 0.000 claims description 6
- 239000001692 EU approved anti-caking agent Substances 0.000 claims description 5
- 238000000149 argon plasma sintering Methods 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 239000003085 diluting agent Substances 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 238000007710 freezing Methods 0.000 claims description 4
- 230000008014 freezing Effects 0.000 claims description 4
- 230000036541 health Effects 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 239000013522 chelant Substances 0.000 claims description 3
- 230000000994 depressogenic effect Effects 0.000 claims description 3
- BNBLBRISEAQIHU-UHFFFAOYSA-N disodium dioxido(dioxo)manganese Chemical compound [Na+].[Na+].[O-][Mn]([O-])(=O)=O BNBLBRISEAQIHU-UHFFFAOYSA-N 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 235000021073 macronutrients Nutrition 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- CADICXFYUNYKGD-UHFFFAOYSA-N sulfanylidenemanganese Chemical compound [Mn]=S CADICXFYUNYKGD-UHFFFAOYSA-N 0.000 claims description 3
- PCDVXBKFEVKXMQ-TYYBGVCCSA-L (e)-but-2-enedioate;manganese(2+) Chemical compound [Mn+2].[O-]C(=O)\C=C\C([O-])=O PCDVXBKFEVKXMQ-TYYBGVCCSA-L 0.000 claims description 2
- 229910021569 Manganese fluoride Inorganic materials 0.000 claims description 2
- 229910001289 Manganese-zinc ferrite Inorganic materials 0.000 claims description 2
- GNRRVTTWUWEUPP-UHFFFAOYSA-L O.O.O.O.Cl(=O)(=O)[O-].[Mn+2].Cl(=O)(=O)[O-] Chemical compound O.O.O.O.Cl(=O)(=O)[O-].[Mn+2].Cl(=O)(=O)[O-] GNRRVTTWUWEUPP-UHFFFAOYSA-L 0.000 claims description 2
- GKYPBYNKDZIVED-UHFFFAOYSA-N [Mn+2].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O Chemical compound [Mn+2].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O GKYPBYNKDZIVED-UHFFFAOYSA-N 0.000 claims description 2
- JIYIUPFAJUGHNL-UHFFFAOYSA-N [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Mn++].[Mn++].[Mn++].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Zn++].[Zn++] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Mn++].[Mn++].[Mn++].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[Zn++].[Zn++] JIYIUPFAJUGHNL-UHFFFAOYSA-N 0.000 claims description 2
- 239000012190 activator Substances 0.000 claims description 2
- RRZKHZBOZDIQJG-UHFFFAOYSA-N azane;manganese Chemical compound N.[Mn] RRZKHZBOZDIQJG-UHFFFAOYSA-N 0.000 claims description 2
- KDAKOPXAEMJUSU-UHFFFAOYSA-N bis(selanylidene)manganese Chemical compound [Se]=[Mn]=[Se] KDAKOPXAEMJUSU-UHFFFAOYSA-N 0.000 claims description 2
- 239000006172 buffering agent Substances 0.000 claims description 2
- UNRVMLDKEXPNDG-UHFFFAOYSA-N butanedioic acid;manganese Chemical compound [Mn].OC(=O)CCC(O)=O UNRVMLDKEXPNDG-UHFFFAOYSA-N 0.000 claims description 2
- 239000002577 cryoprotective agent Substances 0.000 claims description 2
- PHGMGTWRSNXLDV-UHFFFAOYSA-N diethyl furan-2,5-dicarboxylate Chemical compound CCOC(=O)C1=CC=C(C(=O)OCC)O1 PHGMGTWRSNXLDV-UHFFFAOYSA-N 0.000 claims description 2
- CTNMMTCXUUFYAP-UHFFFAOYSA-L difluoromanganese Chemical compound F[Mn]F CTNMMTCXUUFYAP-UHFFFAOYSA-L 0.000 claims description 2
- QFEOTYVTTQCYAZ-UHFFFAOYSA-N dimanganese decacarbonyl Chemical group [Mn].[Mn].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] QFEOTYVTTQCYAZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000003623 enhancer Substances 0.000 claims description 2
- 230000000749 insecticidal effect Effects 0.000 claims description 2
- UMUKXUYHMLVFLM-UHFFFAOYSA-N manganese(ii) selenide Chemical compound [Mn+2].[Se-2] UMUKXUYHMLVFLM-UHFFFAOYSA-N 0.000 claims description 2
- VMINMXIEZOMBRH-UHFFFAOYSA-N manganese(ii) telluride Chemical compound [Te]=[Mn] VMINMXIEZOMBRH-UHFFFAOYSA-N 0.000 claims description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000006254 rheological additive Substances 0.000 claims description 2
- 239000003516 soil conditioner Substances 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- DSKJXGYAJJHDOE-UHFFFAOYSA-N methylideneurea Chemical compound NC(=O)N=C DSKJXGYAJJHDOE-UHFFFAOYSA-N 0.000 claims 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims 2
- 229960001763 zinc sulfate Drugs 0.000 claims 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims 2
- 238000011282 treatment Methods 0.000 description 105
- 239000004562 water dispersible granule Substances 0.000 description 84
- 235000002908 manganese Nutrition 0.000 description 78
- 239000011593 sulfur Substances 0.000 description 76
- 229910052717 sulfur Inorganic materials 0.000 description 69
- 241000196324 Embryophyta Species 0.000 description 58
- 235000010469 Glycine max Nutrition 0.000 description 36
- 244000068988 Glycine max Species 0.000 description 36
- 238000009472 formulation Methods 0.000 description 33
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 28
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- GEYXPJBPASPPLI-UHFFFAOYSA-N manganese(iii) oxide Chemical compound O=[Mn]O[Mn]=O GEYXPJBPASPPLI-UHFFFAOYSA-N 0.000 description 24
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Classifications
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- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D5/00—Fertilisers containing magnesium
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/30—Anti-agglomerating additives; Anti-solidifying additives
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/50—Surfactants; Emulsifiers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/70—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting wettability, e.g. drying agents
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
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- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/27—Dispersions, e.g. suspensions or emulsions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Soil Sciences (AREA)
- Plant Pathology (AREA)
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
次の例は本発明の組成物の基本的な方法論および多用途性を例解している。本明細書において開示されている特定のパラメータおよび範囲には変更がなされ得るということと、開示されている変数を変更するための当分野において公知のいくつもの異なるやり方があり得るということとは認識される。しかしながら、これらの調製例は単に例示的であり、本発明の範囲を限定することは意図されないということは指摘されるべきである。かつ、これらの要素の好ましい実施形態のみが、明細書および図面に記されている通り本明細書において開示されているということは理解されるが、本発明はその通りに限定されるべきではなく、後続する請求項の趣旨および範囲の点で解釈されるべきである。
例1:80部の元素状硫黄、10部の塩化マンガン、および10部のリグノスルホン酸ナトリウム(Reax100)をブレンドすることによって、塩化マンガンおよび元素状硫黄の水分散性顆粒状組成物を調製して、添加剤ミックスを得た。得られた混合物を好適なビーズミルまたは湿式粉砕装置を用いて湿式ミリングして、20ミクロン未満の平均粒子サイズを得た。それから、得られた湿式ミリングされたスラリーを170度C未満の入口温度および70℃未満の出口温度で噴霧乾燥し、次にふるい分けをして、アンダーサイズのおよびオーバーサイズの顆粒を除去し、硫黄80%および塩化マンガン10%の水分散性顆粒状組成物を得た。組成物は次の粒子サイズ分布を有した:0.9ミクロン未満のD10;4ミクロン未満のD50、および12ミクロン未満のD90。組成物の顆粒サイズは0.1~2.5mmの範囲である。
例7:1部の酸化マンガン、60部の元素状硫黄、15部のナフタレンスルホン酸縮合物、0.2部のホルムアルデヒド、1部のポリジメチルシロキサン、および22.4部のプロピレングリコールを混合することによって、液体懸濁液組成物を調製し、撹拌子を装備したベッセルにこれらの成分をフィードすることによってホモジナイゼーションして、均質な混合物を得た。得られた混合物を好適な湿式ミリング装置に通して、20ミクロン未満の粒子サイズを有する懸濁液を得た。それから、0.4部のアラビアガムを連続的なホモジナイゼーション下において追加して、液体懸濁液組成物を得た。組成物は、約1.2ミクロン未満のD10;4.2ミクロン未満のD50および10ミクロン未満のD90という粒子サイズ分布を有した。
圃場研究を実施して、大豆において、本発明の実施形態に従う水分散性顆粒および懸濁液濃縮を包含する異なる製剤によって、元素状硫黄および二酸化マンガンの異なる製剤の相乗的効果を判定した。
圃場実験方法論:
インドール県デワスの商業耕作大豆圃場において、圃場試験を実施して、収量に対する硫黄+二酸化マンガンの異なる製剤の効果を見た。
a)試験場:インドール県デワス(MP)
b)作物:大豆(品種:JS335)
c)実験季節:2018年カリフ
d)試験設計:乱塊法
e)反復:4
f)処理:6
g)区画サイズ:8m×5m=40sq.m
h)施用日:01.07.2018
i)播種日:03.07.2018
j)施用の方法:基肥
k)収穫日:08.10.2018
E=X+Y-(XY/100)
式中、
E=定められたドーズの2つの製品XおよびYの混合物による期待される%効果
X=製品Aによる観察される%効果
Y=製品Bによる観察される%効果
SF=観察される効果/期待される効果
組み合わせについて観察される収量効果のパーセンテージが期待されるパーセンテージに等しいときには、単に相加的効果が推量され得る。そして、組み合わせについて観察される収量効果のパーセンテージが期待されるパーセンテージよりも低いときには、組み合わせの拮抗的効果が推量され得る。用語「相乗的効果」は、ウィーズ(Weeds),1967年,第15巻,p.20-22に発表された「除草剤の組み合わせの相乗的および拮抗的応答の計算(Calculation of the synergistic and antagonistic responses of herbicide combinations)」と題する記事においてコルビーS.R.によって定義されている。組み合わせについて観察される収量効果のパーセンテージ(E)が期待されるパーセンテージよりも多大であるときには、組み合わせの相乗的効果が推量され得る。
大豆の葉の炭水化物含量、莢数、試験重量、収量、および油パーセンテージに対する、異なる濃度の硫黄(S)+種々のマンガン塩の異なる製剤のインパクトを判定するための圃場試験.
a)試験場:ウッジャイン県サベール(MP)
b)作物:大豆(品種:JS335)
c)実験季節:2018年カリフ
d)試験設計:乱塊法
e)反復:3
f)処理:10
g)区画サイズ:7m×5m=35sq.m
h)R×P間隔:30cm×10cm
i)施用日:28.06.2018
j)播種日:29.06.2018
k)施用の方法:基肥
l)収穫日:11.10.2018
上の表から、本発明の実施形態に従う水分散性顆粒状形態の様々な濃度の硫黄およびマンガンによる処理T1、T2、およびT3ならびに同様に本発明の実施形態に従う懸濁液濃縮物形態の処理T7、T8、T9は、パスティルおよび無処理の植物と比較して、大豆植物の葉の可溶性炭水化物含量、穀粒収量、油含量の有意な増大を示すことが観察された。
大豆作物の50日播種において、全ての処理された区画からサンプルを取ることによって、大豆葉の炭水化物含量の観察をもまた判定した。そして、大豆葉の炭水化物含量の改善に対する硫黄(S)+二酸化マンガン(Mn)組み合わせの異なる製剤の効果を見るために、平均データをグラフ1の形態で提示している(図1)。
T1-無処理;
T2-二酸化マンガン25%顆粒@790g/エーカMn;
T3-硫黄90%WDG@2000g/エーカS;
T4-硫黄40%+二酸化マンガン25%(Mn15.9%)WDG@2000g/エーカS+790g/エーカMn;
T5-硫黄40%+25%二酸化マンガン(Mn15.9%)パスティル@2000g/エーカS+790g/エーカMn;
T6-硫黄20%+12.5%酸化マンガン(Mn7.95%)SC@2000g/エーカS+790g/エーカMn。
E=X+Y-(XY/100)
式中、
E=定められたドーズにおける2つの製品XおよびYの混合物による期待される%効果
X=処理T2の製品による観察される%効果(21.13%)
Y=処理T3の製品による観察される%効果(18.01)
ハリヤナ州カルナルの商業的耕作小麦圃場において、圃場試験を実施して、収量に対する様々な濃度の硫黄+酸化マンガンの異なる製剤の相乗的効果を研究した。
試験は乱塊法(RBD)によってラビの季節に計画し、無処理のコントロールを包含する6つの処理を4回反復した。各処理について、40sq.m(8m×5m)の区画サイズを維持した。試験は、異なる製剤によってかつ様々な濃度で単独でおよび組み合わせで施用された硫黄および酸化マンガンによって実施し、小麦作物の播種時に基肥施用として施用した。試験圃場の小麦作物は農業生産工程管理を踏襲し、栽培した。小麦PBW343品種の種子を研究に用い、30cmsの列間および10cmsの植物間の間隔で作付けした。
a)試験場:ラージャスターン州シカール
b)作物:小麦(品種:PBW343)
c)実験季節:2018~19年ラビ
d)試験設計:乱塊法
e)反復:4
f)処理:6
g)区画サイズ:8m×5m=40sq.m
h)施用日:01.11.2018
i)播種日:02.11.2018
j)施用の方法:基肥
k)収穫日:01.04.2019
試験は乱塊法(RBD)によってラビの季節に計画し、無処理のコントロールを包含する10個の処理を3回反復した。各処理について、35sq.m(7m×5m)の区画サイズを維持した。硫黄ならびに種々のマンガン塩、例えば酸化マンガン、二酸化マンガン、および硝酸マンガンの試験サンプルを、組み合わせで、異なる製剤によって、様々な濃度で、小麦作物の播種時に基肥施用として施用した。圃場試験の小麦作物は農業生産工程管理を踏襲して栽培した。小麦Kranti品種の種子を研究に用い、30cmsの列間および10cms植物間の間隔で作付けした。
a)試験場:ナーシク(マハーラーシュトラ州)
b)作物:小麦(品種:Kranti)
c)実験季節:2018~19年ラビ
d)試験設計:乱塊法
e)反復:3
f)処理:10
g)区画サイズ:7m×5m=35sq.m
h)R×P間隔:30cm×10cm
h)施用日:12.11.2018
i)播種日:14.11.2018
j)施用の方法:基肥
k)収穫日:28.03.2019
圃場研究を実施して、ジャガイモにおける瘡痂病(Streptomyces・scabiesによって引き起こされる)のコントロールに対する硫黄+二酸化マンガンの異なる製剤のインパクトを研究した。
インドール県のデワスにおいて、圃場試験を実施して、ジャガイモにおける瘡痂病(Streptomyces・scabiesによって引き起こされる)のコントロールに対する硫黄+二酸化マンガンの異なる製剤の効果を評価した。試験は乱塊法(RBD)によってラビの季節に計画し、無処理のコントロールを包含する6つの処理を4回反復した。各処理について、40sq.m(8m×5m)の区画サイズを維持した。評価された化合物は、所定のドーズでの異なる製剤による硫黄および二酸化マンガン単独ならびにその組み合わせを包含し、ジャガイモ塊茎の播種時に基肥溝施用として施用された。試験圃場のジャガイモ作物は農業生産工程管理を踏襲して栽培した。ジャガイモLoker品種の種子を研究に用い、60cmsの列間および25cmsの植物間の間隔で作付けした。
a)試験場:インドール県デワス
b)作物:ジャガイモ(品種:Loker)
c)実験季節:2018年ラビ
d)試験設計:乱塊法
e)反復:4
f)処理:6
g)区画サイズ:8m×5m=40sq.m
h)播種日:10.11.2018
i)施用日:10.11.2018
j)施用の方法:溝基肥
k)収穫日:18.03.2019
試験は乱塊法(RBD)によってカリフの季節に計画し、無処理のコントロールを包含する5つの処理を4回反復した。各処理について、40sq.m(8m×5m)の区画サイズを維持した。試した組成物は、本発明の実施形態に従う組成物を包含する様々な粒子サイズ範囲の硫黄40%および25%二酸化マンガン(Mn15.8%)水分散性顆粒を包含した。所定のドーズの組成物を大豆種子の播種時に基肥施用として施用した。試験圃場の大豆作物は農業生産工程管理を踏襲して栽培した。大豆JS9041品種の種子を40cmの列間および15cmの植物間の間隔で播種に用いた。
a)試験場:マハーラーシュトラ州ナーシク
b)作物:大豆(品種:JS9041)
c)実験季節:2018年カリフ
d)試験設計:乱塊法
e)反復:4
f)処理:5
g)区画サイズ:8m×5m=40sq.m
h)移植日:08.07.2018
i)施用日:07.07.2018
j)施用の方法:基肥施用
k)収穫日:12.10.2018
圃場実験方法論:
マハーラーシュトラ州ナーシクにおいて、圃場試験を実施して、商業耕作ジャガイモの収量に対する、単独でのおよび本発明の実施形態に従う組み合わせでの活性成分の異なる用量における硫黄およびマンガンの異なる製剤の効果を見た。
a)試験場:マハーラーシュトラ州ナーシク
b)作物:ジャガイモ
c)実験季節:2018年ラビ
d)試験設計:乱塊法
e)反復:4
f)処理:6
g)区画サイズ:8m×5m=40sq.m
h)播種日:25.10.2018
i)施用日:24.10.2018
j)施用の方法:溝基肥
k)収穫日:25.01.2019
Claims (24)
- 作物栄養のための液体懸濁液組成物であって、
前記組成物が:
トータルの組成物の1重量%~60重量%の範囲の元素状硫黄と;
トータルの組成物の0.1重量%~55重量%の範囲の濃度の少なくとも1つのマンガン塩、それらの錯体、またはそれらの混合物と;
少なくとも1つの農芸化学的に受け入れられる賦形剤と;
トータルの組成物の0.01重量%~5重量%の範囲の少なくとも1つの構造形成剤と;
を含み、
前記組成物は、硫酸亜鉛、硫酸マンガン、およびメチレン尿素反応生成物を含まず、
前記組成物が、0.1ミクロンから20ミクロンのサイズ範囲の粒子を含み、
前記農芸化学的に受け入れられる賦形剤は、界面活性剤、分散剤、濡れ剤、水混和性溶媒、保水剤、展着剤、浸透剤、固着剤、ドリフト縮減剤、紫外線吸収剤、UV線散乱剤、保存料、安定剤、緩衝剤またはpH調整剤または中和剤、凍結防止剤または凝固点降下剤、抑泡剤、および固化防止剤の1つ以上から選択され、
前記構造形成剤は、増粘剤、粘度調整剤、タッキファイヤ、懸濁助剤、レオロジー調整剤、および沈降防止剤の1つ以上から選択される、
作物栄養のための液体懸濁液組成物。 - 作物栄養のための水分散性顆粒状組成物であって、
前記組成物が:
トータルの組成物の1重量%~90重量%の範囲の元素状硫黄と;
トータルの組成物の0.1重量%~70重量%の範囲の少なくとも1つのマンガン塩、それらの錯体、またはそれらの混合物と;
トータルの組成物の1%~30%w/wの範囲の少なくとも1つの分散剤と;
を含み、
前記組成物は、硫酸亜鉛、硫酸マンガン、およびメチレン尿素反応生成物を含まず、
前記組成物の顆粒が、0.1~2.5mmの範囲であり、0.1ミクロンから20ミクロンのサイズ範囲の粒子を含む、
作物栄養のための水分散性顆粒状組成物。 - 前記マンガン塩が、少なくとも1つの水可溶性の塩および水不溶性の塩またはそれらの混合物を含む、
請求項1または2に記載の組成物。 - 前記マンガン塩が、少なくとも1つの水不溶性のマンガン塩またはそれらの混合物を含む、
請求項1または2に記載の組成物。 - 水不溶性の前記マンガン塩が、酸化マンガン;水酸化マンガン;リン酸マンガン;カルボニルマンガン;二セレン化マンガン;炭酸マンガン;モリブデン酸マンガン;セレン化マンガン;テルル化マンガン;チタン酸マンガン;窒化マンガン;シュウ酸マンガン;フェロシアン化マンガン;フッ化マンガン;ホウ酸マンガン;硫化マンガン;過酸化マンガン;フェロシアン化マンガン;マンガンブラック;パイロルーサイト;またはそれらの混合物の少なくとも1つを含む、
請求項1または2に記載の組成物。 - 前記マンガン塩が、少なくとも1つの水可溶性のマンガン塩、またはそれらの混合物を含む、
請求項1または2に記載の組成物。 - 水可溶性の前記マンガン塩が、酢酸マンガン、マンガンジアセタート、グルコン酸マンガン、臭化マンガン、塩化マンガン、ヨウ化マンガン、コハク酸マンガン、フマル酸マンガン、硝酸マンガン、二塩化マンガン、マンガン酸ナトリウム、過マンガン酸カリウム、クエン酸マンガン、重炭酸マンガン、二クロム酸マンガン、フルオロケイ酸マンガン、リン酸マンガンアンモニウム;マンガン亜鉛フェライト、塩素酸マンガン四水和物、臭化マンガン、マンガン酸ナトリウム、キレートマンガン、またはそれらの混合物の少なくとも1つを含む、
請求項1または2に記載の組成物。 - 前記組成物が、0.1mmから1.5mmのサイズ範囲のマイクロ顆粒の形態である、
請求項2に記載の水分散性顆粒状組成物。 - 前記組成物の顆粒が0.1から10ミクロンのサイズ範囲の粒子を含む、
請求項2に記載の水分散性顆粒状組成物。 - 前記マンガン塩、それらの錯体、またはそれらの混合物の1つ以上対前記元素状硫黄の重量比が1:600から55:1である、
請求項1に記載の液体懸濁液組成物。 - 前記マンガン塩、それらの錯体、またはそれらの混合物の1つ以上対前記元素状硫黄の重量比が1:50から35:1である、
請求項1に記載の液体懸濁液組成物。 - 前記マンガン塩、それらの錯体、またはそれらの混合物の1つ以上対前記元素状硫黄の重量比が1:90から70:1である、
請求項2に記載の水分散性顆粒状組成物。 - 前記組成物の粘度が10cpsから1200cpsの範囲である、
請求項1に記載の液体懸濁液組成物。 - 前記組成物の粘度が10cpsから500cpsの範囲である、
請求項1に記載の液体懸濁液組成物。 - 前記組成物の懸濁性が少なくとも30%である、
請求項1または2に記載の組成物。 - 前記組成物が、さらに、任意に、1つ以上の微量栄養素、マクロ栄養素、バイオスティミュラント、殺虫活性成分、および/または、リン肥料、カリウム肥料、もしくはそれらの混合物から選択される肥料、から選択される少なくとも1つの追加の活性成分を含む、
請求項1または2に記載の組成物。 - 微量栄養素が、トータルの組成物の0.1重量%から70重量%の範囲で存在する、
請求項1または2に記載の組成物。 - 前記組成物が、さらに、崩壊剤、濡れ剤、バインダまたはフィラーまたは担体または希釈剤、緩衝剤またはpH調整剤または中和剤、抑泡剤、ドリフト縮減剤、固化防止剤、展着剤、浸透剤、固着剤、およびそれらの混合物から選択される1つ以上の農芸化学的に受け入れられる賦形剤を含む、
請求項2に記載の水分散性顆粒状組成物。 - 前記組成物が少なくとも40%の分散性を有する、
請求項2に記載の水分散性顆粒状組成物。 - 請求項1に記載の作物栄養のための液体懸濁液組成物の調製のプロセスであって、
前記プロセスが:元素状硫黄、少なくとも1つのマンガン塩、それらの錯体、またはそれらの混合物、前記少なくとも1つの構造形成剤、および前記少なくとも1つの農芸化学的に受け入れられる賦形剤のブレンドをミリングして、0.1ミクロンから20ミクロンの粒子サイズ範囲を有するスラリーまたはウェットミックスを得ることを含む、
作物栄養のための液体懸濁液組成物の調製のプロセス。 - 請求項2に記載の作物栄養のための水分散性顆粒状組成物の調製のプロセスであって、
前記プロセスが:
a.元素状硫黄、少なくとも1つのマンガン塩、それらの錯体、またはそれらの混合物、および少なくとも1つの分散剤のブレンドをミリングして、スラリーまたはウェットミックスを得ることと;
b.前記ウェットミックスを乾燥して、0.1mmから2.5mmの範囲の顆粒サイズを有しかつ0.1ミクロンから20ミクロンのサイズ範囲の粒子を含む水分散性顆粒状組成物を得ることと、
を含む、
作物栄養のための水分散性顆粒状組成物の調製のプロセス。 - 前記ミリングするステップが、さらに、崩壊剤、濡れ剤、バインダまたはフィラーまたは担体または希釈剤、緩衝剤またはpH調整剤または中和剤、抑泡剤、ドリフト縮減剤、固化防止剤、展着剤、浸透剤、および固着剤から選択される少なくとも1つのさらなる農芸化学的に受け入れられる賦形剤を追加することを含む、請求項21に記載のプロセス。
- 方法が、植物、植物増殖材料、種子、苗、または周囲の土壌の少なくとも1つを請求項1または2に記載の組成物によって処理することを含む、植物の健康または収量を改善する方法。
- 肥料組成物、栄養素組成物、作物活性剤組成物、土壌改良剤組成物、および収量向上剤組成物の少なくとも1つとしての、請求項1または2に記載の組成物。
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