JP6444300B2 - Liquid treatment composition for textile products - Google Patents

Description

  The present invention relates to a liquid treatment composition for textiles, and in particular to a liquid treatment composition for textiles suitable for use in textiles such as clothing. More specifically, the present invention relates to a liquid treatment composition for textiles that is excellent in an effect of suppressing a change in fragrance tone and an effect of improving a remaining scent.

In recent years, there is an increasing need for products having a strong fragrance, and the technology for improving the remaining fragrance of a fragrance by a treating agent for textile products is still being improved.
For example, as a method for leaving a large amount of perfume in the washing bath on the treated cloth and improving the residual perfume property of the perfume, a technique of blending a large amount of perfume having a high ClogP in the perfume formulation in the fiber treatment agent is known ( (Patent No. 3102893). However, the fragrance of the fiber product after drying becomes monotonous only by using a fragrance having a high ClogP, and cannot meet the needs of consumers. In addition, there are few kinds of fragrances with high ClogP, and they are often expensive, which is disadvantageous economically.
On the other hand, a fragrance having a low ClogP is less likely to remain on the treated cloth than a fragrance having a high ClogP. Therefore, particularly when using a fragrance having a low ClogP, the originally designed fragrance tends to change. In this regard, Japanese Patent Application Laid-Open No. 2009-144306 discloses a technique that can impart a low ClogP fragrance to a fabric, but it is necessary to synthesize a specific polymer and use it together with the low ClogP fragrance, and the process is complicated. is there. In addition, this technique is not a technique intended to suppress the change in the scent. As mentioned above, it is the fragrance with a low ClogP that is highly concerned about the change in fragrance, but in textile processing agents, the problem of fragrance change exists for the entire fragrance including the fragrance with a high ClogP. It is.

  Japanese Patent Application Laid-Open No. 2011-127260 discloses a fiber product treating agent composition containing a specific silicate compound. However, according to Japanese Patent Application Laid-Open No. 2011-127260, it is necessary to mix a perfume silicate compound having a log P of 1 or more and less than 15, and a perfume silicate compound having a log P of 15 or more and less than 50. Therefore, the process for making a fragrance | flavor component into a silicate ester compound is required, and a process is complicated. In addition, as described above, there is still a problem of fragrance change in the fragrance.

  Therefore, an object of this invention is to provide the liquid processing agent composition for textiles excellent in the fragrance tone change inhibitory effect and the residual fragrance improvement effect.

  In the liquid treatment composition for textiles, the present inventors blended a specific glucan called a highly branched cyclic dextrin with a fragrance, so that the fragrance, particularly even a fragrance having a low ClogP, is treated on the treated cloth. It was found that a large amount of fragrance can be left, the change in fragrance tone can be suppressed and the remaining fragrance can be improved.

  The present invention has been completed based on such novel findings.

The present invention
(A) perfume composition,
(B) a glucan having an inner branched cyclic structure portion and an outer branched structure portion and having a polymerization degree in the range of 50 to 10,000, wherein the inner branched cyclic structure portion is α-1,4-glucoside A glucan which is a cyclic structure part formed by a bond and an α-1,6-glucoside bond, and the outer branched structure part is an acyclic structure part bonded to the inner branched cyclic structure part, and (C) Provided is a liquid treatment composition for textiles, which comprises a cationic surfactant.

  In one embodiment of the present invention, the component (A) contains a fragrance component having a ClogP value of 5 or less or a fragrance component having a cyclic structure in the structure.

  In one embodiment of the present invention, the component (C) is an amine compound having 1 to 3 hydrocarbon groups having 10 to 26 carbon atoms, which may be separated by an ester group or an amide group, a salt thereof, or a salt thereof Selected from quaternized products.

  In the liquid treating agent composition for textile products of the present invention, the fragrance is a fragrance having a low ClogP by blending the fragrance as the component (A) and the highly branched cyclic dextrin as the component (B). In addition, a large amount can be left on the treated cloth, and the change in the fragrance can be suppressed and the remaining fragrance can be improved.

[Component (A)]
(A) component contained in the liquid processing agent composition for textiles of this invention is a fragrance | flavor composition.
The fragrance composition used in the present invention is a fragrance composition containing at least one fragrance component generally used in a textile product treating agent composition, for example, a textile product finish composition or a softener composition. is there.
Specific examples of the perfume component are not particularly limited and may be appropriately selected depending on the purpose. For example, aldehydes, phenols, alcohols, ethers, esters, hydrocarbons, ketones, lactones , Musks, fragrances having a terpene skeleton, natural fragrances, animal fragrances, and the like.
The aldehydes are not particularly limited and may be appropriately selected depending on the intended purpose. For example, undecylenaldehyde, lauryl aldehyde, aldehyde C-12MNA, miracaldehyde, α-amylcinnamic aldehyde, cyclamenaldehyde, citral Citronellal, ethyl vanillin, heliotropin, anisaldehyde, α-hexylcinnamic aldehyde, octanal, ligustral, lyial, rilal, tripral, vanillin, helional and the like.
There is no restriction | limiting in particular as said phenols, According to the objective, it can select suitably, For example, eugenol, isoeugenol, etc. are mentioned.
The alcohol is not particularly limited and may be appropriately selected depending on the intended purpose.For example, bacdanol, citronellol, dihydromyrcenol, dihydrolinalool, geraniol, linalool, nerol, sandalol, santarex, Examples include terpineol, tetrahydrolinalol, and phenylethyl alcohol.

There is no restriction | limiting in particular as said ether, According to the objective, it can select suitably, For example, cedula bar, glycalva, methyl eugenol, methyl isoeugenol etc. are mentioned.
The esters are not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include cis-3-hexenyl acetate, cis-3-hexenyl propionate, cis-3-hexenyl salicylate, p-cresate. Dil acetate, pt-butyl cyclohexyl acetate, amyl acetate, methyl dihydrojasmonate, amyl salicylate, benzyl salicylate, benzyl benzoate, benzyl acetate, cedryl acetate, citronellyl acetate, decahydro-β-naphthyl acetate, dimethylbenzyl Carvinyl acetate, Ericapropionate, ethyl acetoacetate, Erica acetate, geranyl acetate, geranyl formate, hedion, linalyl acetate, β-phenylethyl acetate Hexyl salicylate, styryl acetate, terpinyl acetate, tiviberyl acetate, ot-butylcyclohexyl acetate, manzanate, allyl heptanoate, and the like.
There is no restriction | limiting in particular as said hydrocarbon, According to the objective, it can select suitably, For example, d-limonene, (alpha) -pinene, (beta) -pinene, myrcene etc. are mentioned.
The ketones are not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include α-ionone, β-ionone, methyl-β-naphthyl ketone, α-damascon, β-damascon, and δ-damascon. Cis-jasmon, methylionone, allylionone, cashmerelan, dihydrojasmon, iso-Esuper, belt fix, isolone diforanone, coabon, rosephenone, raspberry ketone, dynascon and the like.
The lactone is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include γ-decalactone, γ-undecalactone, γ-nonalactone, γ-dodecalactone, coumarin, and ambroxan. It is done.

There is no restriction | limiting in particular as said musk, According to the objective, it can select suitably, For example, cyclopentadecanolide, ethylene brush rate, galaxolide, musk ketone, tonalid, nitromusk etc. are mentioned.
The fragrance having the terpene skeleton is not particularly limited and may be appropriately selected depending on the intended purpose.For example, geraniol (gelaniol), nerol, linalool, citral, citronellol, menthol, mint, citronellal, myrcene, pinene, Examples include limonene, terpineol, carvone, yonon, camphor, and borneol.
The natural perfume is not particularly limited and may be appropriately selected depending on the intended purpose. For example, orange oil, lemon oil, lime oil, petitgren oil, yuzu oil, neroli oil, bergamot oil, lavender oil, lavandin oil , Abies oil, anise oil, bay oil, bored rose oil, ylang ylang oil, citronella oil, geranium oil, peppermint oil, peppermint oil, spearmint oil, eucalyptus oil, lemongrass oil, patchouli oil, jasmine oil, rose oil, cedar oil , Essential oils such as vetiver oil, galvanum oil, oak moss oil, pine oil, camphor oil, sandalwood oil, mellow oil, turpentine oil, clove oil, clove leaf oil, cassia oil, nutmeg oil, cananga oil, thyme oil, etc. .
There is no restriction | limiting in particular as said animal fragrance | flavor, According to the objective, it can select suitably, For example, a scent, a ghost cat scent, a sea scent incense, a dragon scent etc. are mentioned.

In the liquid treatment composition for textiles of the present invention, it is preferable to use a fragrance composition containing a fragrance component having a ClogP value of 5 or less as the component (A). For example, the perfume component may be contained in an amount of 10% by mass or more, more preferably 30% by mass or more, still more preferably 50% by mass or more, and particularly preferably 70% by mass or more based on the total mass of the perfume composition.
Moreover, in the liquid processing agent composition for textiles of the present invention, it is preferable to use a fragrance composition containing a fragrance component having a cyclic structure in the structure as the component (A). For example, the perfume component may be contained in an amount of 10% by mass or more, more preferably 20% by mass or more, still more preferably 35% by mass or more, and particularly preferably 60% by mass or more based on the total mass of the perfume composition.
More preferably, in the liquid treatment composition for textiles of the present invention, a fragrance composition having a ClogP value of 5 or less and containing a fragrance component having a cyclic structure is used. More preferably, in the liquid treatment composition for textiles of the present invention, a fragrance composition having a ClogP value of 5 or less and a fragrance component having a cyclic structure of 20% by mass or more, particularly preferably a ClogP value is A perfume composition containing 40% by mass or more of a perfume component having a cyclic structure of 5 or less is used.
The cyclic structure referred to here may be, for example, a hydrocarbon ring structure or a heterocyclic structure, which may be monocyclic or polycyclic, and may be a condensed polycyclic structure, a bridged ring structure, a spiro structure, or the like. It may be a ring structure, a saturated ring structure or an unsaturated ring structure. Examples of the hetero atom contained in the heterocycle include O, S, N, and P.
Specific examples of the cyclic structure include monocyclic compounds such as benzene and condensed ring compounds such as naphthalene. Further, the element forming the cyclic structure may be a carbocyclic compound or a heterocyclic compound. The ring size may be a 5-membered ring compound such as cyclopentane or furan, a 6-membered ring compound such as cyclohexane or benzene, or the like.

  In the liquid treatment composition for textile products of the present invention, as a fragrance component in the component (A) that is preferably used, specifically, ISOE Super (ClogP4.7, with a cyclic structure), ethyl vanillin ( ClogP1.8, with cyclic structure), γ-undecalactone (ClogP3.8, with cyclic structure), eugenol (ClogP2.4, with cyclic structure), β Damascon (ClogP4.7, with cyclic structure), Helional (ClogP1.4, with a cyclic structure), benzyl salicylate (ClogP4.2, with a cyclic structure), cachemelan (ClogP4.0, with a cyclic structure), coumarin (ClogP1.4, with a cyclic structure), dimethyl Benzylcarbinyl acetate (ClogP1.9, with a cyclic structure), terpineol (ClogP2.6, with a cyclic structure), damasenone (ClogP4.3, with a cyclic structure), tripral (ClogP2.4, with a cyclic structure) , Phenylethyl alcohol (ClogP1.2, cyclic structure ), Hexylcinnamic aldehyde (ClogP4.9, with cyclic structure), β-nonone (ClogP3.8, with cyclic structure), Hedion (ClogP2.4, with cyclic structure), belt fix (ClogP5, cyclic) Structure), methylionone (ClogP4.2, with cyclic structure), limonene (ClogP4.4, with cyclic structure), lilar (ClogP2.2, with cyclic structure), riyal (ClogP3.9, with cyclic structure) However, the fragrance component used in the present invention is not limited to this. More preferred are iso-Esuper, ethyl vanillin, γ-undecalactone, eugenol, β-damascone, helional, and benzyl salicylate. More preferred are eugenol, β damascone, helional, and benzyl salicylate.

The ClogP value is a value representing a 1-octanol / water partition coefficient P representing a ratio of equilibrium concentrations in 1-octanol and in water in the form of logarithmic logP with respect to the base 10 for a chemical substance. The ClogP value can be determined by decomposing the chemical structure of a compound into its constituents by the f-value method (hydrophobic fragment constant method) and integrating the hydrophobic fragment constants and f values possessed by each fragment (for example, Clog 3 Reference Manual Daylight Software 4.34, Albert Leo, David Weininger, Version 1, March 1994).
In general, since the fragrance is more hydrophobic as the ClogP value is larger, the fragrance composition containing more fragrance components having a smaller ClogP value is more hydrophilic than the fragrance composition containing more fragrance components having a larger ClogP value. You can say that.
In the liquid processing agent composition for textiles according to the present invention, a fragrance component having a ClogP value of 1.0 or more and 8.0 or less is used with respect to the total mass of the fragrance composition from the viewpoint of a fresh fragrance and a preference. 30% by mass or more, more preferably 45% by mass or more, further preferably 50% by mass or more, particularly preferably 80% by mass or more, and still more preferably 90% by mass or more.

In the fragrance composition used in the present invention, a solvent generally used for a textile product treating agent composition, for example, a textile product finishing composition or a softener composition, may be blended. Examples of the fragrance solvent include acetin (triacetin), MMB acetate (3-methoxy-3-methylbutyl acetate), sucrose diacetate hexaisobutyrate, ethylene glycol dibutyrate, hexylene glycol, dibutyl sebacate, deltil extra ( Isopropyl myristate), methyl carbitol (diethylene glycol monomethyl ether), carbitol (diethylene glycol monoethyl ether), TEG (triethylene glycol), benzyl benzoate (BB), propylene glycol, diethyl phthalate, tripropylene glycol, aborin ( Dimethyl phthalate), deltyl prime (isopropyl palmitate), dipropylene glycol (DPG), farnesene, dioctyl adipate Tributyrin (glyceryl tributanoate), hydrolite-5 (1,2-pentanediol), propylene glycol diacetate, cetyl acetate (hexadecyl acetate), ethyl abiate, avaline (methyl abietate), citroflex A-2 (Acetyl triethyl citrate), citroflex A-4 (tributyl acetyl citrate), citroflex no. 2 (triethyl citrate), Citroflex No. 4 (tributyl citrate), Durafix (methyl dihydroabietate), MITD (isotridecyl myristate), polylimonene (limonene polymer), 1,3-butylene glycol and the like.
Although these solvents are mix | blended, for example in 0.1-30 mass% in a fragrance | flavor composition, Preferably 1-20 mass% is mix | blended.

  In the liquid treatment agent composition for textiles of the present invention, the amount of component (A) is not particularly limited, but when used as a softener composition, it is preferably 0.01 to 5 mass with respect to the total mass of the entire composition. %, More preferably 0.1 to 5% by mass, and still more preferably 0.5 to 3% by mass. When used as a spray type fiber treating agent composition, it is preferably 0.001 to 1% by mass, more preferably 0.005 to 1% by mass, and still more preferably 0.01 to 0.5% by mass, based on the total mass of the entire composition. When the blending amount of the component (A) is less than 0.001% by mass, the aroma is weak, and it is difficult to understand the effect of suppressing the change in fragrance and the effect of improving the remaining scent. When the blending amount of the component (A) is more than 5% by mass, the storage stability at high temperature may be lowered.

[Component (B)]
The component (B) contained in the liquid treating agent composition for textiles of the present invention is a glucan having an inner branched cyclic structure portion and an outer branched structure portion and having a polymerization degree in the range of 50 to 10,000, The inner branched cyclic structure portion is a cyclic structure portion formed by an α-1,4-glucoside bond and an α-1,6-glucoside bond, and the outer branched structure portion is the inner branched cyclic structure. It is a glucan, which is an acyclic structure moiety attached to the moiety. Such a glucan is also called highly branched cyclic dextrin or cluster dextrin, and the component (B) is also referred to as “highly branched cyclic dextrin” in this specification.
The highly branched cyclic dextrin contained in the liquid treatment composition for textiles of the present invention has a molecular weight of about 30,000 to 1,000,000, has one cyclic structure in the molecule, and a large number of glucans in the cyclic portion. It mainly contains dextrin having a weight average degree of polymerization of about 2500 with chains attached.
The highly branched cyclic dextrin of the highly branched cyclic dextrin contained in the liquid product composition for textiles of the present invention is composed of about 10 to 100 glucoses. The outer branched structure portion consisting of the branched glucan chain is bound.

For example, the degree of polymerization of the highly branched cyclic dextrin contained in the liquid treatment composition for textiles of the present invention is in the range of 50 to 5000.
For example, the polymerization degree of the inner branched cyclic structure portion of the highly branched cyclic dextrin contained in the liquid treating agent composition for textiles of the present invention is in the range of 10-100.
For example, the degree of polymerization of the outer branched structure portion of the highly branched cyclic dextrin contained in the liquid treatment composition for textile products of the present invention is 40 or more.
For example, the polymerization degree of each unit chain of the outer branched structure portion of the highly branched cyclic dextrin contained in the liquid treatment composition for textiles of the present invention is 10 to 20 on average.

The highly branched cyclic dextrin contained in the liquid treatment composition for textiles of the present invention is produced, for example, by using starch as a raw material and acting on an enzyme called a branching enzyme. The starch, which is a raw material, is composed of amylose in which glucose is linearly bound by α-1,4-glucoside bonds and amylopectin having a structure branched in a complex manner by α-1,6-glucoside bonds. It is a macromolecule with many connected structures. Branching enzyme, an enzyme used, is a glucan chain transferase widely distributed in animals, plants, and microorganisms. It acts on the seam portion of the cluster structure of amylopectin and catalyzes the reaction of cyclizing it.
More specifically, the highly branched cyclic dextrin contained in the liquid treatment composition for textiles of the present invention has an inner branched cyclic structure portion and an outer branched structure portion described in JP-A-8-134104. Is a glucan in the range of 50 to 10,000. In the present specification, the highly branched cyclic dextrin can be understood in consideration of the description in JP-A-8-134104.

The highly branched cyclic dextrin contained in the liquid treating agent composition for textiles of the present invention has a specific structure as described above and has a high degree of polymerization (molecular weight), and α-cyclodextrin (n = 6). ), Β-cyclodextrin (n = 7), γ-cyclodextrin (n = 8), etc., which are different from general cyclodextrins in which 6 to 8 glucoses are bound.
As a specific example of the highly branched cyclic dextrin contained in the liquid treating agent composition for textiles of the present invention, “Cluster Dextrin” (registered trademark) of Glico Nutrition Foods Co., Ltd. may be mentioned.
In addition, instead of highly cyclic branched dextrin, 6-8 glucoses such as α-cyclodextrin (n = 6), β-cyclodextrin (n = 7), γ-cyclodextrin (n = 8) are generally bonded. Even if a typical cyclodextrin is blended in a liquid treatment composition for textiles, excellent fragrance change suppressing effect and residual fragrance improvement effect equivalent to the liquid treatment composition for textiles of the present invention cannot be obtained. .

In the liquid treatment agent composition for textiles of the present invention, the amount of component (B) is not particularly limited, but when used as a softener composition, it is preferably 0.01 to the total mass of the entire composition. It is 10 mass%, More preferably, it is 0.03-5 mass%, More preferably, it is 0.05-3 mass%. When the blending amount of the component (B) is more than 0.01% by mass, an excellent effect of suppressing change in fragrance tone and an effect of improving the remaining scent can be exhibited. When the blending amount of the component (B) is more than 10% by mass, the effect of suppressing the change in fragrance tone and the effect of improving the residual fragrance property are not particularly improved, the stability at high temperature storage is deteriorated, or the liquid viscosity of the composition is high. Therefore, handling properties may be reduced. In the case of a spray type fiber treatment agent, the blending amount of the component (B) is preferably 0.01 to 5% by mass, more preferably 0.03 to 3% by mass, and still more preferably based on the total mass of the entire composition. Is 0.05-1 mass%. When the blending amount of the component (B) is more than 0.01% by mass, an excellent effect of suppressing change in fragrance tone and an effect of improving the remaining scent can be exhibited. When the blending amount of the component (B) is more than 10% by mass, the stability at high temperature storage may be deteriorated, and the liquid viscosity of the composition may be increased and the handling property may be deteriorated.
In the liquid treatment composition for textiles of the present invention, the mass ratio of the component (A) / (B) is not particularly limited, but when used as a softener composition, both when used as a spray-type fiber treatment composition. The ratio is preferably 1/100 to 20, more preferably 1/10 to 5, and still more preferably 1/5 to 1.

The reason why the fragrance, especially the fragrance with a low ClogP value, feels different when comparing the odor of the liquid treatment composition for textile products and the treated cloth, is not necessarily clear, but the following reasons Can be considered.
In the case of a softener composition, when producing a composition, a fragrance component having a low ClogP value (hydrophilic fragrance component) is difficult to be incorporated into a vesicle formed by a cationic surfactant and is likely to exist in the bulk. Conceivable. Therefore, the fragrance component having a low ClogP value flows out into the rinsing liquid when softened in the washing process, and is difficult to be adsorbed on the cloth. Therefore, since the fragrance | flavor component with a low ClogP value exists on a process cloth and it reduces from the ratio in a softening agent composition, an incense tone changes and it is felt.
In the case of a spray type fiber treatment agent composition, it is considered that a fragrance component having a low ClogP value is not easily taken into the micelle formed by the cationic surfactant and is likely to exist in the bulk when the composition is produced. Accordingly, when sprayed on the cloth, the fragrance having a low ClogP value is easily volatilized because it is put on the cloth in a state where it is not taken into the micelle. Therefore, since the fragrance | flavor component with a low ClogP value will exist on the process cloth in a ratio less than the ratio in a spray type fiber processing agent composition, an incense tone will change and it will be felt.

As described above, in the case of a softener composition or a spray-type fiber treatment composition, a fragrance component having a low ClogP value is difficult to be incorporated into the cationic surfactant and easily exists in the bulk. Difficult to place.
In the liquid treatment composition for textiles of the present invention, a highly branched cyclic dextrin is blended, and the highly branched cyclic dextrin dissolved in the bulk takes a helical structure, whereby a fragrance is included in the helical structure. It is thought that the inclusion body adsorbs on the cloth. Since the highly branched cyclic dextrin does not maintain a helical structure on the fiber, the perfume component is gradually released from the clathrate adsorbed on the cloth. Therefore, it is thought that the fragrance of the fragrance | flavor component with a low ClogP value can fully be felt, and a fragrance | flavor change is suppressed.
Moreover, when a fragrance | flavor component has a cyclic structure, it is thought that it is easy to interact with highly branched cyclic dextrin, and it is thought that an effect increases more for that.

[Component (C)]
(C) component contained in the liquid processing agent composition for textiles of this invention is a cationic surfactant. For example, the cationic surfactant used as the component (C) in the present invention is a hydrocarbon group having 10 to 26 carbon atoms (hereinafter referred to as “long chain hydrocarbon group”) which may be separated by an ester group or an amide group. May be at least one compound selected from the group consisting of 1 to 3 amine compounds in the molecule, salts thereof and quaternized products thereof. Among them, a tertiary amine acid salt or a quaternized product thereof having at least one hydrocarbon group having 10 to 26 carbon atoms which may be separated by an ester group or an amide group in the molecule is preferable.
When using the liquid processing agent composition for textiles of the present invention as a softener composition, the component (C) is a hydrocarbon group having 10 to 26 carbon atoms which may be separated by an ester group or an amide group. It is preferably at least one compound selected from the group consisting of 1 to 3 amine compounds in the molecule, salts thereof and quaternized products thereof. In particular, the carbon number of the long chain hydrocarbon group is 10 to 26, preferably 17 to 26, and more preferably 19 to 24. When the carbon number of the long-chain hydrocarbon group is 10 or more, the flexibility is good, and when it is 26 or less, the handling property is good.
When the liquid treatment agent composition for textiles of the present invention is used as a spray-type fiber treatment agent composition, the component (C) is a hydrocarbon group having 10 to 14 carbon atoms which may be separated by an ester group or an amide group. An amine compound having two in the molecule, a salt thereof and a quaternized product thereof, and an amine compound having one hydrocarbon group having 10 to 18 carbon atoms which may be separated by an ester group or an amide group in the molecule, At least one compound selected from the group consisting of salts and quaternized products thereof is preferred. Especially, the amine compound which has two C10-14 hydrocarbon groups which may be divided | segmented by the ester group or the amide group in a molecule | numerator, its salt, and its quaternization thing are especially preferable.

The long chain hydrocarbon group may be saturated or unsaturated. When the long chain hydrocarbon group is unsaturated, the position of the double bond may be anywhere, but when there is one double bond, the position of the double bond is the long chain carbonization. The center of the hydrogen group is preferably distributed around the median.
The long chain hydrocarbon group may be a chain hydrocarbon group or a hydrocarbon group containing a ring in the structure, and is preferably a chain hydrocarbon group. The chain hydrocarbon group may be linear or branched. As the chain hydrocarbon group, an alkyl group or an alkenyl group is preferable, and an alkyl group is more preferable.
The long chain hydrocarbon group may be separated by an ester group (—COO—) or an amide group (—NHCO—). That is, the long-chain hydrocarbon group has at least one kind of splitting group selected from the group consisting of an ester group and an amide group in the carbon chain, and the carbon chain is split by the splitting group. May be. Having the splitting group is preferable from the viewpoint of improving biodegradability.

When it has this dividing group, the number of the dividing groups which one long-chain hydrocarbon group has may be one, or may be two or more. That is, the long chain hydrocarbon group may be divided at one place by a dividing group, or may be divided at two or more places. When having two or more splitting groups, each splitting group may be the same or different.
In addition, when it has a splitting group in a carbon chain, the carbon atom which a splitting group shall count to carbon number of a long-chain hydrocarbon group.
The long-chain hydrocarbon group is usually an unhydrogenated fatty acid derived from beef tallow, which is used industrially, a fatty acid obtained by hydrogenation or partial hydrogenation of an unsaturated part, palm-derived palm oil, oil palm-derived It is introduced by using a hydrogenated fatty acid or fatty acid ester, or a fatty acid or fatty acid ester obtained by hydrogenation or partial hydrogenation of an unsaturated portion.

［式中、Ｒ¹〜Ｒ³はそれぞれ独立に、炭素数１０〜２６の炭化水素基、−ＣＨ₂ＣＨ（Ｙ）ＯＣＯＲ⁴（Ｙは水素原子又はＣＨ₃であり、Ｒ⁴は炭素数７〜２１の炭化水素基である。）、−（ＣＨ₂）_nＮＨＣＯＲ⁵（ｎは２又は３であり、Ｒ⁵は炭素数７〜２１の炭化水素基である。）、水素原子、炭素数１〜４のアルキル基、−ＣＨ₂ＣＨ（Ｙ）ＯＨ、又は−（ＣＨ₂）_nＮＨ₂であり、Ｒ¹〜Ｒ³のうちの少なくとも１つは、炭素数１０〜２６の炭化水素基、−ＣＨ₂ＣＨ（Ｙ）ＯＣＯＲ⁴、又は−（ＣＨ₂）_nＮＨＣＯＲ⁵である。］As the amine compound in the component (C) contained in the liquid treatment composition for textiles of the present invention, a secondary amine compound or a tertiary amine compound is preferable, and a tertiary amine compound is more preferable.
More specifically, examples of the amine compound in the component (C) include compounds represented by the following general formula (C1).

[Wherein, R ^{1 to} R ³ are each independently a hydrocarbon group having 10 to 26 carbon atoms, —CH ₂ CH (Y) OCOR ⁴ (Y is a hydrogen atom or CH ₃ , and R ⁴ is 7 carbon atoms. to 21 is a hydrocarbon _{group), -.. (CH 2} ) n NHCOR 5 (n is 2 or 3, R ⁵ is a hydrocarbon group having 7 to 21 carbon atoms), a hydrogen atom, the number of carbon atoms 1 to 4 alkyl group, —CH ₂ CH (Y) OH, or — (CH ₂ ) _n NH ₂ , and at least one of R ^{1 to} R ³ is a hydrocarbon group having 10 to 26 carbon atoms. , —CH ₂ CH (Y) OCOR ⁴ , or — (CH ₂ ) _n NHCOR ⁵ . ]

Wherein the carbon number of the hydrocarbon group having 10 to 26 carbon atoms in R ¹ to R ³ is preferably 17 to 26, 19 to 24 is more preferable. The hydrocarbon group may be saturated or unsaturated. The hydrocarbon group is preferably an alkyl group or an alkenyl group.
In —CH ₂ CH (Y) OCOR ⁴ , Y is a hydrogen atom or CH ₃ , and a hydrogen atom is particularly preferable.
R ⁴ is a hydrocarbon group having 7 to 21 carbon atoms, preferably 15 to 19 carbon atoms. When R ⁴ is more present in the formula may be R ⁴ of said plurality of mutually identical, may be different.
Hydrocarbon group R ⁴ is a residue obtained by removing a carboxy group from a fatty acid having 8 to 22 carbon atoms (R ⁴ COOH) (fatty acid residues), R ⁴ Nomoto become fatty (R ⁴ COOH) is Saturated fatty acids or unsaturated fatty acids may be used, and straight-chain fatty acids or branched fatty acids may be used. Of these, saturated or unsaturated linear fatty acids are preferred. In order to impart good water absorption to the soft-treated garment, the saturated / unsaturated ratio (mass ratio) of the fatty acid serving as R ⁴ is preferably 90/10 to 0/100, and 80/20 to 0 / 100 is more preferable.
When R ⁴ is an unsaturated fatty acid residue, a cis isomer and a trans isomer are present, and the mass ratio of the cis isomer / trans isomer is preferably 40/60 to 100/0, and 70/30 to 90/10. Particularly preferred.

Specific examples of fatty acids used as R ⁴ include stearic acid, palmitic acid, myristic acid, lauric acid, oleic acid, elaidic acid, linoleic acid, partially hydrogenated palm oil fatty acid (iodine value 10 to 60), partial Examples include hydrogenated beef tallow fatty acid (iodine value of 10 to 60). Among them, a fatty acid prepared by combining two or more selected from stearic acid, palmitic acid, myristic acid, oleic acid, elaidic acid, and linoleic acid in predetermined amounts to satisfy the following conditions (a) to (c) It is preferable to use a composition.
(A) The ratio (mass ratio) of saturated fatty acid / unsaturated fatty acid is 90/10 to 0/100, more preferably 80/20 to 0/100.
(B) The ratio (mass ratio) of cis isomer / trans isomer is 40/60 to 100/0, more preferably 70/30 to 90/10.
(C) The fatty acid having 18 carbon atoms is 60 mass% or more, preferably 80 mass% or more, the fatty acid having 20 carbon atoms is less than 2 mass%, and the fatty acid having 21 to 22 carbon atoms is less than 1 mass%. .

In — (CH ₂ ) _n NHCOR ⁵ , n is 2 or 3, and 3 is particularly preferable.
R ⁵ is a hydrocarbon group having 7 to 21 carbon atoms, preferably 15 to 19 carbon atoms. When R ⁵ is more present in the formula may be R ⁵ of said plurality of mutually identical, may be different.
Examples of R ⁵ include the same as R ⁴ .
At least one of R ^{1 to} R ³ is a long-chain hydrocarbon group (that is, a hydrocarbon group having 10 to 26 carbon atoms, —CH ₂ CH (Y) OCOR ⁴ , or — (CH ₂ ) _n NHCOR ⁵ ). It is preferable that two are long-chain hydrocarbon groups.
When one or two of R ^{1 to} R ³ are long-chain hydrocarbon groups, the remaining two or one is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, —CH ₂ CH (Y) OH or — (CH ₂ ) _n NH ₂ , preferably an alkyl group having 1 to 4 carbon atoms, —CH ₂ CH (Y) OH, or — (CH ₂ ) _n NH ₂ . Among these, as a C1-C4 alkyl group, a methyl group or an ethyl group is preferable, and a methyl group is especially preferable. Y in —CH ₂ CH (Y) OH is the same as Y in —CH ₂ CH (Y) OCOR ⁴ . _{N in} — (CH ₂ ) _n NH ₂ is the same as n in — (CH ₂ ) _n NHCOR ⁵ .

［式中、Ｒ⁷及びＲ⁸はそれぞれ独立に、炭素数１０〜２６の炭化水素基である。Ｒ⁹及びＲ¹⁰はそれぞれ独立に、炭素数７〜２１の炭化水素基である。］Preferable examples of the compound represented by the general formula (C1) include compounds represented by the following general formulas (C1-1) to (C1-8).

[Wherein, R ⁷ and R ⁸ are each independently a hydrocarbon group having 10 to 26 carbon atoms. R ⁹ and R ¹⁰ are each independently a hydrocarbon group having 7 to 21 carbon atoms. ]

Examples of the hydrocarbon group for R ⁷ and R ⁸ include the same hydrocarbon groups as those having 10 to 26 carbon atoms for R ^{1 to} R ³ .
Examples of the hydrocarbon group having 7 to 21 carbon atoms in R ⁹ and R ¹⁰ include those similar to the hydrocarbon group having 7 to 21 carbon atoms in R ⁴ . When R ⁹ is more present in the formula, R ⁹ of the plurality of may be the same as each other, it may be different.
The salt of an amine compound is obtained by neutralizing an amine compound with an acid. The acid used for neutralization of the amine compound may be an organic acid or an inorganic acid, and examples thereof include hydrochloric acid, sulfuric acid, and methyl sulfuric acid. Neutralization of the amine compound can be performed by a known method.
A quaternized product of an amine compound is obtained by reacting the amine compound with a quaternizing agent. Examples of the quaternizing agent used for the quaternization of the amine compound include alkyl halides such as methyl chloride and dialkyl sulfates such as dimethyl sulfate. When these quaternizing agents are reacted with an amine compound, the alkyl group of the quaternizing agent is introduced into the nitrogen atom of the amine compound, and a salt of a quaternary ammonium ion and a halogen ion or a monoalkyl sulfate ion is formed. . The alkyl group introduced by the quaternizing agent is preferably an alkyl group having 1 to 4 carbon atoms, more preferably a methyl group or an ethyl group, and particularly preferably a methyl group. The quaternization of the amine compound can be performed by a known method.

The component (C) contained in the liquid treating agent composition for textiles of the present invention includes at least one selected from the group consisting of the compound represented by the general formula (C1), a salt thereof, and a quaternized product thereof. Preferably, at least one selected from the group consisting of the general formulas (C1-1) to (C1-8), a salt thereof, and a quaternized product thereof is more preferable, (C1-4) to (C1-6), More preferred is at least one selected from the group consisting of a salt and a quaternized product thereof.
As the compound represented by the formula (C1), a salt thereof, and a quaternized product thereof, a commercially available product may be used, or a product produced by a known method may be used.
For example, a compound represented by the general formula (C1-2) (hereinafter “compound (C1-2)”) and a compound represented by the general formula (C1-3) (hereinafter “compound (C1-3)”) are: The fatty acid composition, or a fatty acid methyl ester composition obtained by replacing the fatty acid in the fatty acid composition with a methyl ester of the fatty acid, and methyldiethanolamine can be synthesized. At that time, from the viewpoint of improving flexibility, the abundance ratio represented by “compound (C1-2) / compound (C1-3)” is synthesized such that the mass ratio is 99/1 to 50/50. It is preferable to do.
Furthermore, when the quaternized product is used, it is more preferable to use dimethyl sulfate as a quaternizing agent. At that time, from the viewpoint of flexibility, the abundance ratio represented by “a quaternized compound (C1-2) / a quaternized compound (C1-3)” is 99/1 to 50/50 in mass ratio. It is preferable to synthesize.

Compound represented by general formula (C1-4) (hereinafter “compound (C1-4)”), compound represented by general formula (C1-5) (hereinafter “compound (C1-5)”), general formula The compound represented by (C1-6) (hereinafter “compound (C1-6)”) can be synthesized by a condensation reaction of the fatty acid composition or fatty acid methyl ester composition and triethanolamine. In that case, the content ratio of each component to the total mass of the compounds (C1-4), (C1-5), and (C1-6) is 1 to 60 masses of the compound (C1-4) from the viewpoint of flexibility. %, The compound (C1-5) is preferably 5 to 98% by mass, the compound (C1-6) is preferably 0.1 to 40% by mass, the compound (C1-4) is 30 to 60% by mass, the compound ( More preferably, C1-5) is 10 to 55% by mass, and compound (C1-6) is 5 to 35% by mass.
In addition, when using the quaternized product, it is more preferable to use dimethyl sulfate as a quaternizing agent in that the quaternization reaction proceeds sufficiently. The abundance ratio of each of the quaternized compounds (C1-4), (C1-5) and (C1-6) is a mass ratio from the viewpoint of flexibility, and the quaternized compound (C1-4) is 1 to 4. 60% by mass, the quaternized compound (C1-5) is preferably 5 to 98% by mass, and the quaternized compound (C1-6) is preferably 0.1 to 40% by mass. ) Is 30 to 60% by mass, the quaternized compound (C1-5) is 10 to 55% by mass, and the quaternized compound (C1-6) is 5 to 35% by mass. preferable. In addition, when the compounds (C1-4), (C1-5), and (C1-6) are quaternized, esteramine that has not been quaternized generally remains after the quaternization reaction. At that time, the ratio of “quaternized product / non-quaternized ester amine” is preferably in the range of a mass ratio of 70/30 to 99/1.

  The compound represented by the general formula (C1-7) (hereinafter “compound (C1-7)”) and the compound represented by the general formula (C1-8) (hereinafter “compound (C1-8)”) are as described above. From the adduct of fatty acid composition, N-methylethanolamine and acrylonitrile, JOrg. Chem. , 26, 3409 (1960), by a condensation reaction with N- (2-hydroxyethyl) -N-methyl-1,3-propylenediamine synthesized by a known method. In that case, it is preferable to synthesize | combine so that the abundance ratio represented by "compound (C1-7) / compound (C1-8)" may be 99 / 1-50 / 50 by mass ratio. When the quaternized product is used, it is preferable to use methyl chloride as a quaternizing agent, which is expressed as “a quaternized compound (C1-7) / a quaternized compound (C1-8)”. It is preferable to synthesize the abundance ratio such that the mass ratio is 99/1 to 50/50.

In the liquid treatment composition for textiles of the present invention, the component (C) has an action of enhancing the adsorption of the component (A) and the component (B), and is blended to impart flexibility to the treated cloth. The
In the liquid treatment agent composition for a textile product of the present invention, the amount of component (C) is not particularly limited, but is preferably 0.01 to 30% by mass with respect to the total mass of the entire composition.
When using the liquid processing agent composition for textiles of this invention as a softening agent composition, the compounding quantity of (C) component is although it does not specifically limit, Preferably it is 5-30 mass% with respect to the total mass of the whole composition. More preferably, it is 5-25 mass%, More preferably, it is 8-22 mass%. When it is 5% by mass or more, a sufficient flexibility imparting effect can be obtained. Storage stability is favorable in it being 30 mass% or less.
When using the liquid processing agent composition for textiles of this invention as a spray type fiber processing agent composition, the compounding quantity of (C) component is although it does not specifically limit, Preferably it is 0.8 with respect to the total mass of the whole composition. It is 01-10 mass%, More preferably, it is 0.03-8 mass%, More preferably, it is 0.05-5 mass%.
In the liquid treatment composition for textiles of the present invention, the mass ratio of the component (B) / (C) is not particularly limited, but when used as a softener composition, it is preferably 1/300 to 2/3. Preferably 1/25 to 2/3, more preferably 1/15 to 2/3, and when used as a spray-type fiber treatment composition, preferably 1/1000 to 1000, more preferably 1/80 to 200. More preferably, it is 1 / 10-100.

[Optional ingredients]
The liquid processing agent composition for textiles of the present invention may contain other components other than the above-mentioned components (A) to (C) as necessary, as long as the effects of the present invention are not impaired.
As this other component, a well-known component can be suitably mix | blended in the liquid processing agent composition for textiles. For example, water, water-soluble solvents, nonionic surfactants, silicones, dyes and / or pigments, preservatives, ultraviolet absorbers, antibacterial agents and the like can be contained.
The liquid treatment composition for textiles of the present invention is preferably an aqueous composition and preferably contains water.
As water, any of tap water, ion exchange water, pure water, distilled water, and the like can be used. Of these, ion-exchanged water is preferred.

The nonionic surfactant can be preferably used mainly for the purpose of improving the emulsion dispersion stability of the oil-soluble component in the emulsion when the fiber product treating agent composition of the present invention is an emulsion. In particular, when a nonionic surfactant is blended, a sufficient level of freeze / restoration stability is easily secured in terms of commercial value.
As the nonionic surfactant, for example, those derived from higher alcohols, higher amines or higher fatty acids can be used. More specifically, a polyoxyethylene alkyl ether or polyoxyethylene fatty acid alkyl having an alkyl group or alkenyl group having 10 to 22 carbon atoms and an average addition mole number of ethylene oxide of 10 to 100 mol (carbon of the alkyl). 1 to 3) ester; polyoxyethylene alkylamine having an average addition mole number of ethylene oxide of 10 to 100 mol, alkyl polyglucoside having an alkyl group or alkenyl group having 8 to 18 carbon atoms, and an average addition mole number of ethylene oxide. Examples include hydrogenated castor oil that is 10 to 100 mol. Among these, a polyoxyethylene alkyl ether having an alkyl group having 10 to 18 carbon atoms and an average added mole number of ethylene oxide of 20 to 80 mol is preferable.
Content of the nonionic surfactant in the processing agent composition for textiles of this invention can be determined according to the desired function, for example, Preferably it is 0.01-10 mass%, More preferably, it is 0.1-0.1%. It is 8 mass%, More preferably, it is 0.5-5 mass%. When the content of the nonionic surfactant is equal to or higher than the lower limit, the emulsion dispersion stability of the oil-soluble component in the emulsion and the freeze recovery stability of the emulsion are further improved. If it is below an upper limit, the raise of the viscosity of the processing agent composition for liquid fiber products can be suppressed, and it can be made favorable in terms of usability.

There is no restriction | limiting in particular in the kind of a silicone compound, According to the objective, it can select suitably. The molecular structure of the silicone compound may be linear, branched, or cross-linked. The silicone compound may be a modified silicone compound, and the modified silicone compound may be modified with one organic functional group or modified with two or more organic functional groups. It may be.
The silicone compound can be used in the state of oil, and can also be used in the state of an emulsion dispersed by any emulsifier.
Specific examples of the silicone compound include, for example, dimethyl silicone, polyether modified silicone, methylphenyl silicone, alkyl modified silicone, higher fatty acid modified silicone, methyl hydrogen silicone, fluorine modified silicone, epoxy modified silicone, carboxy modified silicone, carbinol. Examples thereof include modified silicone and amino-modified silicone.
Among these, polyether-modified silicone, amino-modified silicone, dimethyl silicone and the like are preferable from the viewpoint of versatility and deodorizing and deodorizing effect, and polyether-modified silicone and amino are particularly preferable from the viewpoint of effect and handling during production. Modified silicone is preferred.

前記一般式（Ｉ）中、Ｍ、Ｎ、ａ、及びｂは、平均重合度を表し、Ｒは、水素又はアルキル基を表す。ここで、Ｍは、１０〜１０，０００であることが好ましく、１００〜３００がより好ましい。Ｎは、１〜１，０００であることが好ましく、１〜１００がより好ましい。更に、Ｍ＞Ｎであることが好ましい。ａは、２〜１００であることが好ましく、２〜５０がより好ましい。ｂは、０〜５０であることが好ましく、０〜１０がより好ましい。Ｒは、水素又は炭素数１〜４のアルキル基であることが好ましい。Specific examples of the polyether-modified silicone include, for example, a copolymer of alkylsiloxane and polyoxyalkylene. In addition, as carbon number of the alkyl group of the said alkylsiloxane, 1-3 are preferable, and as carbon number of the alkylene group of the said polyoxyalkylene, 2-5 are preferable. Among these, the polyether-modified silicone is preferably a copolymer of dimethylsiloxane and polyoxyalkylene (polyoxyethylene, polyoxypropylene, a random or block copolymer of ethylene oxide and propylene oxide, etc.). Specific examples of such a polyether-modified silicone include, for example, a compound represented by the following general formula (I), a compound represented by the following general formula (II), and the like.

In the general formula (I), M, N, a, and b represent the average degree of polymerization, and R represents hydrogen or an alkyl group. Here, M is preferably 10 to 10,000, and more preferably 100 to 300. N is preferably 1 to 1,000, and more preferably 1 to 100. Furthermore, it is preferable that M> N. a is preferably 2 to 100, and more preferably 2 to 50. b is preferably 0 to 50, and more preferably 0 to 10. R is preferably hydrogen or an alkyl group having 1 to 4 carbon atoms.

前記一般式（ＩＩ）中、Ａ、Ｂ、ｈ、及びｉは、平均重合度であり、Ｒは、アルキル基を表し、Ｒ’は、水素又はアルキル基を表す。ここで、Ａは、５〜１０，０００であることが好ましく、Ｂは、２〜１０，０００であることが好ましい。ｈは、２〜１００であることが好ましく、ｉは、０〜５０であることが好ましい。Ｒは、炭素数１〜５のアルキル基であることが好ましい。Ｒ’は、水素又は炭素数１〜４のアルキル基であることが好ましい。
前記一般式（ＩＩ）で表される線状ポリシロキサン−ポリオキシアルキレンブロック共重合体は、反応性末端基を有するポリオキシアルキレン化合物と、該化合物の反応性末端基と反応する末端基を有するジヒドロカルビルシロキサンとを反応させることにより製造することができる。このようなポリエーテル変性シリコーンは、側鎖のポリオキシアルキレン鎖が長く、ポリシロキサン鎖の重合度が大きいものほど粘度が高くなるので、製造時の作業性改善及び水性組成物への配合を容易にするために、水溶性有機溶剤とのプレミックスの形で配合に供することが好ましい。該水溶性有機溶剤としては、例えば、エタノール、ジプロピレングリコール、ブチルカルビトール等が挙げられる。
前記ポリエーテル変性シリコーンとしては、より具体的には、例えば、東レ・ダウコーニング（株）製の、ＳＨ３７７２Ｍ、ＳＨ３７７５Ｍ、ＦＺ−２１６６、ＦＺ−２１２０、Ｌ−７２０、ＳＨ８７００、Ｌ−７００２、Ｌ−７００１、ＳＦ８４１０、ＦＺ−２１６４、ＦＺ−２２０３、ＦＺ−２２０８、信越化学工業（株）製の、ＫＦ３５２Ａ、ＫＦ６１５Ａ、Ｘ−２２−６１９１、Ｘ−２２−４５１５、ＫＦ−６０１２、ＫＦ−６００４等、モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社製のＴＳＦ４４４０、ＴＳＦ４４４１、ＴＳＦ４４４５、ＴＳＦ４４５０、ＴＳＦ４４４６、ＴＳＦ４４５２、ＴＳＦ４４６０等が挙げられる。The polyether-modified silicone represented by the general formula (I) generally has an organohydrogenpolysiloxane having a Si-H group and a carbon-carbon double bond such as polyoxyalkylene allyl ether at the terminal. It can be produced by addition reaction of polyoxyalkylene alkyl ether with a platinum catalyst. Therefore, the polyether-modified silicone may contain a slight amount of unreacted polyoxyalkylene alkyl ether or organohydrogenpolysiloxane having a Si—H group. Since the organohydrogenpolysiloxane having a Si—H group has high reactivity, the abundance in the polyether-modified silicone is preferably 30 ppm or less (as the amount of Si—H).

In the general formula (II), A, B, h, and i are average polymerization degrees, R represents an alkyl group, and R ′ represents hydrogen or an alkyl group. Here, A is preferably 5 to 10,000, and B is preferably 2 to 10,000. h is preferably 2 to 100, and i is preferably 0 to 50. R is preferably an alkyl group having 1 to 5 carbon atoms. R ′ is preferably hydrogen or an alkyl group having 1 to 4 carbon atoms.
The linear polysiloxane-polyoxyalkylene block copolymer represented by the general formula (II) has a polyoxyalkylene compound having a reactive terminal group and a terminal group that reacts with the reactive terminal group of the compound. It can be produced by reacting with dihydrocarbylsiloxane. Such polyether-modified silicone has a longer side chain polyoxyalkylene chain, and the higher the degree of polymerization of the polysiloxane chain, the higher the viscosity. Therefore, it is easy to improve workability during production and blend into aqueous compositions. Therefore, it is preferable to use it in the form of a premix with a water-soluble organic solvent. Examples of the water-soluble organic solvent include ethanol, dipropylene glycol, butyl carbitol and the like.
More specifically, examples of the polyether-modified silicone include SH3772M, SH3775M, FZ-2166, FZ-2120, L-720, SH8700, L-7002, and L-, manufactured by Toray Dow Corning Co., Ltd. 7001, SF8410, FZ-2164, FZ-2203, FZ-2208, manufactured by Shin-Etsu Chemical Co., Ltd., KF352A, KF615A, X-22-6191, X-22-4515, KF-6012, KF-6004, etc. Examples include TSF4440, TSF4441, TSF4445, TSF4450, TSF4446, TSF4452, and TSF4460 manufactured by Momentive Performance Materials Japan GK.

式（ＩＩＩ）中、Ｒ₁、Ｒ₆は互いに同一でも、異なっていてもよく、メチル基、水酸基、水素のいずれかを表す。Ｒ₂は、−（ＣＨ₂）_n−Ａ₁、及び−（ＣＨ₂）_n−ＮＨＣＯ−（ＣＨ₂）_m−Ａ₁のいずれかを表す。Ａ₁は、−Ｎ（Ｒ₃）（Ｒ₄）、及び−Ｎ⁺（Ｒ₃）（Ｒ₄）（Ｒ₅）・Ｘ^-のいずれかを表す。Ｒ₃〜Ｒ₅は、互いに同一であってもよいし、異なっていてもよく、水素原子、炭素数１〜１２のアルキル基、フェニル基、及び−（ＣＨ₂）_n−ＮＨ₂のいずれかを表す。Ｘ^-は、フッ素イオン、塩素イオン、臭素イオン、ヨウ素イオン、硫酸メチルイオン、及び硫酸エチルイオンのうちのいずれかを表す。ｍ及びｎの値は、互いに同一であってもよいし、異なっていてもよく、０〜１２の整数を表す。ｐ及びｑの値は、ポリシロキサンの重合度を表し、互いに同一であってもよいし、異なっていてもよく、ｐは０〜２００００、好ましくは１０〜１００００、ｑは１〜５００、好ましくは１〜１００を表す。
本発明の繊維製品用処理剤組成物で用いるアミノ変性シリコーンのオイルの場合、２５℃における動粘度が５０〜２００００ｍｍ²／ｓであることが好ましく、１００〜１００００ｍｍ²／ｓであることがより好ましい。動粘度がこの範囲にあると、高い風合い付与効果が発現されるとともに、製造性が良好であり、組成物の取り扱いも容易になるため好ましい。The amino-modified silicone is a silicone oil in which an amino group is introduced into the terminal or side chain of the dimethyl silicone skeleton, and a substituent such as a hydroxyl group, an alkyl group, or a phenyl group may be substituted in addition to the amino group. Moreover, the form of oil may be sufficient, and the form of the amino modified silicone emulsion which emulsified the nonionic surfactant or the cationic surfactant as an emulsifier may be sufficient. A preferred amino-modified silicone oil or base oil in the case of an emulsion is represented by the following general formula (III).

In formula (III), R ₁ and R ₆ may be the same as or different from each other and each represents a methyl group, a hydroxyl group, or hydrogen. R ₂ represents any _one of — (CH ₂ ) _n —A ₁ and — (CH ₂ ) _n —NHCO— (CH ₂ ) _m —A ₁ . A ₁ represents any _one of —N (R ₃ ) (R ₄ ) and —N ⁺ (R ₃ ) (R ₄ ) (R ₅ ) · X ⁻ . R _{3 to} R ₅ may be the same or different from each other, and are any one of a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, a phenyl group, and — (CH ₂ ) _n —NH ₂ . Represents. X ⁻ represents any one of fluorine ion, chlorine ion, bromine ion, iodine ion, methyl sulfate ion, and ethyl sulfate ion. The values of m and n may be the same as or different from each other, and represent an integer of 0 to 12. The values of p and q represent the degree of polymerization of the polysiloxane and may be the same or different from each other. p is 0 to 20000, preferably 10 to 10000, q is 1 to 500, preferably 1-100 are represented.
For amino-modified silicone oil used in the textile treating agent composition of the present invention preferably has a kinematic viscosity at 25 ° C. is 50~20000mm ² / s, more preferably 100~10000mm ² / s . When the kinematic viscosity is in this range, a high texture imparting effect is exhibited, manufacturability is good, and the composition is easy to handle, which is preferable.

Commercially available amino-modified silicones can be used. For example, amino-modified silicone oils sold by Toray Dow Corning Co., Ltd. as SF-8417, BY16-892, BY16-890. From Shin-Etsu Chemical Co., Ltd., KF-864, KF-860, KF-8004, KF-8002, KF-8005, KF-867, KF-861, KF-880, KF-867S and the like can be mentioned.
The amino-modified silicone emulsion type is sold by Toray Dow Corning Co., Ltd. as SM8904, BY22-079, FZ-4671, FZ-4672, and sold by Shin-Etsu Chemical Co., Ltd. in the Polon series. Polon MF-14, Polon MF-29, Polon MF-14D, Polon MF-44, Polon MF-14EC, Polon MF-52, sold by Asahi Kasei Wacker Silicone Co., Ltd., WACKER FC201, WACKER FC218 Is given.
The kinematic viscosity of the dimethyl silicone is not particularly limited but is preferably 1~100,000,000mm ² / s, more preferably ^{10~10,000,000mm 2 / s, 100~1,000,000mm 2 /} s Is more preferable. Further, it may be an oil or an emulsion.

It is preferable that the liquid processing agent composition for textiles of this invention contains a water-soluble solvent in addition to water.
The water-soluble solvent is preferably one or more selected from the group consisting of lower (1 to 4 carbon atoms) alcohols, glycol ether solvents, and polyhydric alcohols. Specifically, ethanol, isopropanol, glycerin, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, hexylene glycol, polyoxyethylene phenyl ether, dipropylene glycol monomethyl ether, and water represented by the following general formula (X) It is preferable to mix | blend the solvent component chosen from an ionic solvent.
^{_{R 11 -O- (C 2 H 4}} O) y - (C 3 H 6 O) z -H ··· (X)
In the formula, R ¹¹ is an alkyl group or alkenyl group having 1 to 6 carbon atoms, preferably 2 to 4 carbon atoms. y and z are average addition mole numbers, y is 1-10, Preferably it is 2-5, z shows the number of 0-5, Preferably it is 0-2.
Among the above-mentioned water-soluble solvents, ethanol, ethylene glycol, butyl carbitol, propylene glycol, diethylene glycol monobutyl ether, and dipropylene glycol monomethyl ether are preferable.
The water-soluble solvent is preferably blended in the liquid treating agent composition for textiles of the present invention in an amount of 0 to 30% by mass, more preferably 0.01 to 25% by mass, and still more preferably 0.1 to 20% by mass. The

The dye and / or pigment can be blended for the purpose of improving the appearance of the liquid treating agent composition for textiles of the present invention. Preferably, it is one or more of red, blue, yellow or purple water-soluble dyes selected from acid dyes, direct dyes, basic dyes, reactive dyes, and mordant / acid mordant dyes.
Specific examples of the dyes that can be added are described in the Dye Handbook (edited by the Society of Synthetic Organic Chemistry, published on July 20, 1970, Maruzen Co., Ltd.).
From the viewpoint of the storage stability of the fiber composition treating agent composition of the present invention and the dyeing property to fibers, the composition has at least one functional group selected from a hydroxyl group, a sulfonic acid group, an amino group, and an amide group in the molecule. Acid dyes, direct dyes, and reactive dyes are preferable, and the blending amount thereof is preferably 1 to 50 ppm, more preferably 1 to 30 ppm, based on the entire composition.
Examples of the dye used in the liquid treatment composition for textile products of the present invention include JP-A-6-123081, JP-A-6-123082, JP-A-7-18573, JP-A-8-27669, It is also possible to use dyes described in JP-A-9-250085, JP-A-10-77576, JP-A-11-43865, JP-A-2001-181972, JP-A-2001-348784, etc. it can.

The preservative can be used mainly in the treatment composition for textiles of the present invention in order to enhance the antiseptic power and sterilizing power and maintain the antiseptic property during long-term storage.
Examples of the preservative include isothiazolone-based organic sulfur compounds, benzisothiazolone-based organic sulfur compounds, benzoic acids, 2-bromo-2-nitro-1,3-propanediol, and the like.
Examples of isothiazolone organic sulfur compounds include 5-chloro-2-methyl-4-isothiazoline-3-one, 2-n-butyl-3-isothiazolone, 2-benzyl-3-isothiazolone, 2-phenyl-3-isothiazolone. 2-methyl-4,5-dichloroisothiazolone, 5-chloro-2-methyl-3-isothiazolone, 2-methyl-4-isothiazolin-3-one, or a mixture thereof. Among them, 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one are preferable, and 5-chloro-2-methyl-4-isothiazolin-3-one and 2- A mixture of methyl-4-isothiazolin-3-one is more preferred, and a mixture of about 77% by weight of the former and about 23% by weight of the latter is particularly preferred.
Examples of benzisothiazolone-based organic sulfur compounds include 1,2-benzisothiazoline-3-one, 2-methyl-4,5-trimethylene-4-isothiazolin-3-one, and dithio-2,2-bis ( Benzmethylamide) or a mixture thereof. Among these, 1,2-benzisothiazolin-3-one is particularly preferable.
Examples of benzoic acids include benzoic acid or a salt thereof, parahydroxybenzoic acid or a salt thereof, methyl paraoxybenzoate, ethyl paraoxybenzoate, propyl paraoxybenzoate, butyl paraoxybenzoate, benzyl paraoxybenzoate, and the like.
It is preferable that the compounding quantity of antiseptic | preservative is 0.0001-1 mass% with respect to the total amount of the processing agent composition for textiles in the liquid processing agent composition for textiles of this invention. When the blending amount of the preservative is less than the lower limit, it is difficult to obtain the effect of adding the preservative, and when it exceeds the upper limit, the storage stability may be lowered.

An ultraviolet absorber is a chemical | medical agent with the effect which protects an ultraviolet-ray, it is a component which absorbs an ultraviolet-ray, converts into infrared rays, visible light, etc., and discharge | releases.
Examples of the ultraviolet absorber include aminobenzoic acid derivatives such as p-aminobenzoic acid, ethyl p-aminobenzoate, glyceryl p-aminobenzoate, and amyl p-dimethylaminobenzoate; ethylene glycol salicylate, dipropylene glycol salicylate , Salicylic acid derivatives such as octyl salicylate, myristyl salicylate; methyl diisopropylcinnamate, ethyl p-methoxycinnamate, isopropyl p-methoxycinnamate, p-methoxycinnamate-2-ethylhexyl, p-methoxycinnamic acid Cinnamic acid derivatives such as butyl; benzophenone derivatives such as 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and 2,2′-dihydroxy-4-methoxybenzophenone; urocanic acid, Ouro Examples include azole compounds such as ethyl kanate; 4-t-butyl-4′-methoxybenzoylmethane.

The antibacterial agent is a component having an effect of suppressing the growth of bacteria on the fiber and further suppressing the generation of an unpleasant odor derived from the degradation product of the microorganism.
Antibacterial agents include, for example, cationic bactericides such as quaternary ammonium salts (benzalkonium chloride), diclosan, triclosan, bis- (2-pyridylthio-1-oxide) zinc, polyhexamethylene biguanidine hydrochloride, Examples include 8-oxyquinoline and polylysine.
In addition to the above-mentioned compounds, as a function improver, a shrinkage inhibitor, an anti-wrinkle agent, a shape retention agent, a drape retention agent, an iron property improvement agent, an oxygen bleaching inhibitor, a whitening agent, a whitening agent, and a fabric softening Clay, antistatic agent, dye transfer inhibitor such as polyvinylpyrrolidone, polymer dispersant, stain remover, scum dispersant, 4,4-bis (2-sulfostyryl) biphenyl disodium (Cino Pearl CBS manufactured by Ciba Specialty Chemicals) X) fluorescent whitening agents, dye fixing agents, anti-fading agents such as 1,4-bis (3-aminopropyl) piperazine, stain removers, fiber surface modifiers such as cellulase, amylase, protease, lipase, keratinase, etc. Silk protein powders and surface modified products that can give silk texture and functions such as There are emulsified dispersions, specifically K-50, K-30, K-10, A-705, S-702, L-710, FP series (Idemitsu Petrochemical), hydrolyzed silk liquid (upper hair) Anti-contamination of SILKGEN G Solvel S (Ichimaru Falcos), alkylene terephthalate and / or nonionic polymer compound comprising alkylene isophthalate unit and polyoxyalkylene unit, such as FR627 manufactured by Kyoyo Chemical Industry, SRC-1 manufactured by Clariant Japan An agent or the like can be blended.

[PH of composition]
The pH of the liquid treating agent composition for textile products of the present invention is not particularly limited, but in the case of a liquid softening agent composition, it is 25 from the viewpoint of suppressing hydrolysis of the component (C) accompanying storage aging. It is preferable that pH in 1 degree is in the range of 1-6, and it is more preferable that it is in the range of 2-4.
When using the liquid processing agent composition for textiles of this invention as a spray-type fiber processing agent composition, it is preferable that pH in 25 degreeC is 5-11 from a viewpoint of improving stability of a fragrance, 7-7. 10 is more preferable.
When adjusting pH, hydrochloric acid, sulfuric acid, phosphoric acid, alkyl sulfuric acid, benzoic acid, p-toluenesulfonic acid, citric acid, malic acid, succinic acid, lactic acid, glycolic acid, hydroxyethane diphosphonic acid, phytin PH adjusting agents such as acids, short-chain amine compounds such as ethylenediaminetetraacetic acid and dimethylamine, alkali metal hydroxides such as sodium hydroxide, alkali metal carbonates and alkali metal silicates can be used.

[Viscosity of composition]
In the case of the liquid softener composition, the viscosity of the liquid treatment composition for textiles of the present invention is preferably less than 1000 mPa · s (B-type viscometer, manufactured by TOKIMEC, 25 ° C., the same applies hereinafter). . Considering the increase in viscosity due to storage aging, the viscosity immediately after production is more preferably less than 800 mPa · s, and further preferably less than 500 mPa · s. When it is in such a range, the usability such as handling property at the time of loading into the washing machine is good.
When using the liquid processing agent composition for textiles of the present invention as a spray type fiber processing agent composition, the viscosity at 25 ° C. is preferably 10 mPa · s or less from the viewpoint of handling properties, and is 5 mPa · s or less. It is more preferable that The viscosity can be adjusted by component (B), the amount of water blended, and the like.

[Production method]
The preparation method of the liquid processing agent composition for textiles of this invention is not specifically limited.
In the case of a liquid softening agent composition, it can be produced by a known method, for example, a method similar to the conventional method for producing a liquid softening agent composition using a cationic surfactant as a main agent.
For example, (A) component, (C) component, the oil phase containing nonionic surfactant, and the aqueous phase containing (B) component are mixed and emulsified under temperature conditions more than melting | fusing point of (C) component. The product can be prepared, and then, if necessary, it can be produced by adding and mixing other components to the obtained emulsion. The oil phase can be prepared by mixing the component (A), the component (C), a nonionic surfactant, and an optional component as necessary at a temperature equal to or higher than the melting point of the component (C). An aqueous phase can be prepared by mixing water, (B) component, and an arbitrary component as needed.
In the case of a spray-type fiber treatment agent composition, it is not particularly limited and can be prepared according to a conventional method. For example, it can prepare by mixing each said component with water as needed.

[Use / How to use]
Although the use of the liquid treatment agent composition for textiles of this invention is not specifically limited, It can apply to a cleaning composition, a bleaching agent composition, a liquid softening agent composition, a spray type fiber treatment agent, etc. Especially, it is preferable to apply as a liquid softening agent composition or a spray type fiber treatment agent.
The method for treating textiles such as clothing with the liquid treating composition for textiles of the present invention is not particularly limited, and conventionally known detergents, finishing agents (softeners, glues, etc.), spray fibers It can process like a processing agent etc.
The liquid treatment composition for textile products of the present invention is not particularly limited in the case of a liquid softener composition, but for example, the composition of the present invention is dissolved in rinsing water at the rinsing stage of washing. There is a method of performing treatment or dissolving the composition of the present invention in water using a container such as a tub, and further adding garments, and in this case, it is diluted to an appropriate concentration and used. In that case, the bath ratio (weight ratio of the treatment liquid to the textile product) is preferably 3 to 100 times, particularly preferably 5 to 50 times. Specifically, when performing the flexible treatment, it is preferably used in such an amount that the concentration of the component (C) is 0.01 ppm to 1000 ppm, more preferably 0.1 ppm to 300 ppm with respect to the total amount of water used. Is used in such an amount.

When the liquid treatment composition for textiles of the present invention is used as a spray-type fiber treatment composition, the method of use is not particularly limited. For example, the treatment composition can be used as a trigger spray container or a dispenser type pump. It can be carried out by placing in a spray container and spraying directly on the textile. After spraying, you may perform a drying process as needed. The fiber product is not particularly limited, and examples thereof include clothing, curtains, sofas, carpets, towels, handkerchiefs, sheets, and macula covers. The amount of the treatment composition applied to the fiber product is preferably 0.5 to 10 g, more preferably 1 to 5 g, per 100 g of the fiber product.
The spray type fiber treatment agent is preferably contained in a trigger type spray container (hereinafter referred to as trigger container). The trigger container is not particularly limited, and is generally the same as the trigger container used for the fiber treatment product used for imparting a scent or deodorizing effect to a textile product such as clothing. Can be used. As the trigger container used in the present invention, an accumulator type trigger container is preferable from the viewpoints of good spray properties and spray pattern and no occurrence of afterdraw. Further, the amount of spraying once is 0 from the viewpoint of preventing the fiber product sprayed with the treating agent composition from causing stains and giving a preferable effect without giving the hand excessive fatigue. It is preferable that it is 2-0.6g.

  EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to this. In the examples, the component blending amounts are all expressed by mass% (in terms of pure content, unless otherwise specified).

[(A) component]
Table 1: Composition of perfume composition

[Component (B)]
B-1: Cluster dextrin (registered trademark, manufactured by Glico Nutrition Foods Co., Ltd.)
The main component of Cluster Dextrin (registered trademark) has a molecular weight of about 30,000 to 1,000,000, has one cyclic structure in the molecule, and a weight average polymerization degree of 2500 having many glucan chains bonded to the cyclic portion. About dextrin. The cyclic structure portion is composed of about 16 to 100 glucoses, and many non-cyclic branched glucan chains are bonded to the cyclic structure.
B-2 (comparative example): α cyclodextrin
B-3 (comparative example): β cyclodextrin

[Component (C)]
C-1: Cationic surfactant (cationic surfactant described in Example 4 of JP-A-2003-12471)
C-2: Cationic surfactant (cationic surfactant described in Example 1 of JP-A-2002-167366)
C-3: Didecyldimethylammonium salt (trade name: ARCARD 210, Lion Akzo)

[Other optional ingredients]
D-1:
・ Primary isotridecyl alcohol ethylene oxide 60 mol adduct: 2%
・ Calcium chloride (trade name: granular calcium chloride, Tokuyama Corporation): 0.5%
-Isothiazolone solution (trade name: Caisson CG-ICP, Dow Chemical): 100 ppm ^*
D-2:
Polyoxyethylene lauryl ether ethylene oxide 8 mol adduct (trade name: New Coal 1100, Japanese emulsifier): 0.2%
・ Isothiazolone solution (trade name: Caisson CG-ICP, Dow Chemical) 100 ppm <sup>*
* The</sup> amount of isothiazolone solution is shown as it is.

[Method for preparing softener composition]
The amount of each component was adjusted as described in Tables 2 and 3 below, and a liquid softener composition was prepared by the following procedure.
The liquid softening agent composition was prepared by the following procedure using a glass container having an inner diameter of 100 mm and a height of 150 mm and a stirrer (Agitator SJ type, manufactured by Shimadzu Corporation). First, the (A) component, the (C) component, and the optional primary isotridecyl alcohol ethylene oxide 60 mol adduct were mixed and stirred to obtain an oil phase mixture. On the other hand, (B) component and the isothiazolone liquid which is an arbitrary component were dissolved in the balance purified water to obtain an aqueous phase mixture. Here, the mass of the ion-exchange water for balance is equivalent to the balance obtained by subtracting the total mass of the oil phase mixture and (B) from 980 g. Next, the oil phase mixture heated above the melting point of the component (C) is placed in a glass container and stirred, and the aqueous phase mixture heated above the melting point of the component (C) is added in two portions. And stirred. Here, the division ratio of the aqueous phase mixture was 30:70 (mass ratio), and the stirring was performed at a rotational speed of 1,000 rpm for 3 minutes after the first aqueous phase mixture addition and for 2 minutes after the second aqueous phase mixture addition. It was. Thereafter, calcium chloride as an optional component is added, and if necessary, hydrochloric acid (reagent 1 mol / L, Kanto Chemical) or sodium hydroxide (reagent 1 mol / L, Kanto Chemical) is added in an appropriate amount to adjust the pH to 2.5. In addition, ion-exchanged water was added so that the total mass was 1,000 g to obtain a target liquid softener composition.

[Preparation Method of Spray Type Fiber Treatment Agent Composition]
The blending amount of each component was adjusted as described in Tables 4 and 5 below, and a liquid softener composition was prepared by the following procedure.
Using a 500 ml beaker, ion-exchanged water in which (A) component solution and (B) component aqueous solution are mixed in ethanol, which is optional component, and (C) component and optional component are dissolved therein (Adjust the amount of ion-exchanged water so that the total amount becomes 400 g) was added under stirring conditions to obtain the desired spray type fiber treating agent composition.

[Evaluation of incense tone and residual fragrance]
1. Pretreatment method of cotton knitted fabric for evaluation
Cotton knitted fabric (100% cotton, Tanigami Shoten) cut to 10cm x 10cm with a commercial detergent "Top Platinum Clear" (manufactured by Lion Corporation) using a two-tank washing machine (Toshiba VH-30S) three times Pretreatment was performed (standard amount of detergent used, 30 times the bath ratio, 50 ° C tap water, 10 minutes of washing → 10 minutes of water rinsing twice).

2. Softener treatment in the rinsing process at the time of washing The following criteria are used by 15 panelists to determine the smell of the cotton knitted fabric after washing and drying using the softener composition prepared as described above, and the smell of the softener composition. And sensory evaluation. In terms of product value, a value of Δ or more was considered acceptable.
In addition, the fragrance of the dried cotton knitted fabric was sensory-evaluated according to the following criteria by 15 panelists using the 6-step odor intensity method. In terms of product value, a value of Δ or more was considered acceptable.
Use a two-tank washing machine (Toshiba VH-30S) for 10 minutes with a commercial detergent "Top Platinum Clear" (Lion Corporation) for 10 minutes (standard usage, standard course, bath ratio 20 times) , 25 ° C tap water), followed by 3 minutes of rinsing, softened for 3 minutes with the composition for the second time of rinsing (1.5 ml of cotton knitted fabric, 10 mL of composition, 20 times bath ratio, 25 ° C Tap water was used). Dehydration was performed for 1 minute between the washing and rinsing steps. After the treatment, it was dried for 20 hours under constant temperature and humidity conditions of 20 ° C. and 45% RH.

3. Spraying treatment by spraying The spray-type fiber treatment agent composition prepared as described above was filled in a trigger container, sprayed and dried, and the smell of the cotton knitted fabric and the smell of the spray-type fiber treatment agent composition were treated by the panel 15 Sensory evaluation was performed by a person according to the following criteria. In terms of product value, a value of Δ or more was considered acceptable.
In addition, the fragrance of the dried cotton knitted fabric was sensory-evaluated according to the following criteria by 15 panelists using the 6-step odor intensity method. In terms of product value, a value of Δ or more was considered acceptable.
As a trigger container, the contents of a commercially available clothing care product (trade name “Style Guard wrinkles and odors are refreshing spray”, manufactured by Lion Co., Ltd.) are taken out, washed thoroughly, and thoroughly dried. Prepared. Fill the trigger container with the spray-type fiber treatment agent composition and equalize the amount of 2% owf (= weight of the treatment agent composition (g) / weight of the treatment cloth (g) × 100) with respect to the evaluation cloth. Sprayed. After the treatment, it was dried for 20 hours under constant temperature and humidity conditions of 20 ° C. and 45 ° C. RH.

<Evaluation criteria>
(1) Odor of cotton knitted fabric and softener composition (inhibition effect on incense tone change)
◎ ◎ ◎: More than 14 out of 15 people evaluated that the smell of cotton knitted fabric and softener composition is the same ◎ ◎: 15 people evaluated that the smell of cotton knitted fabric and softener composition is the same 11-13 out of people ◎: 8-10 out of 15 people who evaluated that the smell of cotton knitted fabric and softener composition was the same ○: Evaluated that the smell of cotton knitted fabric and softener composition was the same 5-7 out of 15 people △: 2-4 out of 15 people evaluated that the smell of cotton knitted fabric and softener composition is the same ×: The smell of cotton knitted fabric and softener composition Less than 1 in 15 people rated it the same

(2) Aroma (effect of improving residual fragrance)
When evaluated by the 6-level odor intensity method (0: odorless, 1: very weak, 2: weak, 3: easy to detect, 4: strong, 5: intense)
◎◎◎: (Score when component (B) is included)-(Score when component (B) is not included) is 0.4 or more ◎◎: (Score when component (B) is included)-((B ) The score when the component is not included) is 0.3 or more and less than 0.4 point ◎: (The score when the component (B) is included)-(The score when the component (B) is not included) is 0.2 or more and less than 0.3 point ○ : (Score when component (B) is included)-(Score when component (B) is not included) is 0.1 or more and less than 0.2 point Δ: (Score when component (B) is included)-((B) The score when the component is not included) is 0 point or more and less than 0.1 point ×: (the score when the component (B) is included)-(the score when the component (B) is not included) is less than 0 point

^*香料組成物は有り姿での配合量を記載。Table 2: Composition of softener composition (numerical value of composition is% by mass)

^{* For the} fragrance composition, the blending amount is shown.

^*香料組成物は有り姿での配合量を記載。Table 3: Composition of softener composition (numerical value of composition is% by mass)

^{* For the} fragrance composition, the blending amount is shown.

^*香料組成物は有り姿での配合量を記載。Table 4: Composition of spray type fiber treating agent composition (numerical value of composition is mass%)

^{* For the} fragrance composition, the blending amount is shown.

^*香料組成物は有り姿での配合量を記載。Table 5: Composition of spray type fiber treating agent composition (numerical value of composition is mass%)

^{* For the} fragrance composition, the blending amount is shown.

Claims (7)

(A) Isoe super, ethyl vanillin, γ undecalactone, eugenol, β damascone, heional, cashemaran, coumarin, dimethylbenzylcarbinyl acetate, terpineol, damasenone, tripral, phenylethyl alcohol, hexylcinnamic aldehyde, β ionone, A perfume composition containing at least 50% by mass of one or more perfume ingredients having a ClogP value of 5 or less, selected from Hedion, Beltfix, Methylionone, Limonene, Lillal, and Lilyal ;
(B) a glucan having an inner branched cyclic structure portion and an outer branched structure portion and having a polymerization degree in the range of 50 to 10,000, wherein the inner branched cyclic structure portion is α-1,4-glucoside A glucan which is a cyclic structure part formed by a bond and an α-1,6-glucoside bond, and the outer branched structure part is an acyclic structure part bonded to the inner branched cyclic structure part, and (C) A liquid treatment composition for textile products, comprising a cationic surfactant. The component (C) is selected from an amine compound having 1 to 3 hydrocarbon groups having 10 to 26 carbon atoms which may be separated by an ester group or an amide group, a salt thereof or a quaternized product thereof. The liquid processing agent composition for textiles according to claim 1 .   (A) The liquid processing agent composition for textiles of Claim 1 or 2 characterized by the compounding quantity of a component being 0.01-5 mass% with respect to the gross mass of the whole composition.   The blending amount of the component (B) is 0.01 to 10% by mass with respect to the total mass of the entire composition, and the liquid for textiles according to any one of claims 1 to 3. Treatment agent composition.   The liquid treatment agent composition for textiles according to claim 1, wherein the mass ratio of component (B) / component (C) is 1/300 to 2/3.   (A) The liquid processing agent composition for textiles of Claim 1 or 2 characterized by the compounding quantity of a component being 0.001-0.5 mass% with respect to the gross mass of the whole composition. object.   The liquid processing agent composition for textiles according to any one of claims 1 to 6, wherein the mass ratio of (A) component / (B) component is 1/100 to 20.