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JP6399937B2 - Combustible waste treatment equipment - Google Patents

Combustible waste treatment equipment Download PDF

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Publication number
JP6399937B2
JP6399937B2 JP2015007462A JP2015007462A JP6399937B2 JP 6399937 B2 JP6399937 B2 JP 6399937B2 JP 2015007462 A JP2015007462 A JP 2015007462A JP 2015007462 A JP2015007462 A JP 2015007462A JP 6399937 B2 JP6399937 B2 JP 6399937B2
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cement
combustion
combustible
gas
combustible waste
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JP2016132588A (en
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淳一 寺崎
淳一 寺崎
上野 直樹
直樹 上野
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Taiheiyo Cement Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • Y02P40/125Fuels from renewable energy sources, e.g. waste or biomass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/40Valorisation of by-products of wastewater, sewage or sludge processing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Treatment Of Sludge (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Description

本発明は、可燃性廃棄物をセメント焼成装置で有効利用しながら処理する技術に関する。   The present invention relates to a technique for processing combustible waste while effectively using it in a cement baking apparatus.

セメント工場では、廃プラスチック、BOF、ASR、RPF、RDF、木屑、廃タイヤ、FRP等の様々な可燃性廃棄物をセメント焼成装置に投入してセメント原料、燃料として有効利用しながら処理している。   In cement factories, various combustible wastes such as waste plastics, BOF, ASR, RPF, RDF, wood chips, waste tires, and FRP are put into cement firing equipment and processed while effectively using them as cement raw materials and fuels. .

例えば、特許文献1には、FRPを破砕して燃料の一部としてセメント焼成装置に投入したり、この破砕片を廃タイヤと共に燃料の一部として投入し、該破砕片中に含まれる無機繊維及び/又は無機充填材をセメント原料の一部に用いる技術が開示されている。   For example, Patent Document 1 discloses that the FRP is crushed and put into a cement firing apparatus as a part of the fuel, or the crushed piece is put together with the waste tire as part of the fuel, and the inorganic fiber contained in the crushed piece And / or the technique which uses an inorganic filler for a part of cement raw material is disclosed.

また、特許文献2には、使用済みFRPを50mm以下の破砕品、3mm以下の粗砕品、90μm以下の微粉砕品とし、各々セメント焼成工程のプレヒータの導入口、仮焼炉の燃料供給装置、ロータリーキルンのバーナから供給して熱源として有効利用する技術が開示されている。   Patent Document 2 discloses that the used FRP is a crushed product of 50 mm or less, a crushed product of 3 mm or less, and a finely pulverized product of 90 μm or less, each of a preheater inlet for a cement firing process, and a fuel supply device for a calciner , A technique for supplying from a burner of a rotary kiln and effectively using it as a heat source is disclosed.

特開平7−10618号公報Japanese Patent Laid-Open No. 7-10618 特開平6−8247号公報Japanese Patent Laid-Open No. 6-8247

しかし、可燃性廃棄物をセメント焼成装置に投入して燃焼性を向上させ、かつセメント品質や装置の運転に悪影響を及ぼさないようにするために、粒径を小さくする前処理を行うとその分処理コストが増加する。特に、熱硬化性・熱可塑性樹脂や繊維強化プラスチック(FRP)、カーボンファイバー等は粉砕が困難であるため、前処理(粉砕)コストが高騰する。また、熱量を有しているが前処理にコストが嵩む光ファイバーや太陽電池等、セメント焼成装置の運転に支障を来す有機性汚泥や都市ごみ、バイオマス燃料等セメント焼成装置で有効利用することができなかった。   However, in order to improve the flammability by introducing combustible waste into the cement baking equipment and to prevent adverse effects on the cement quality and the operation of the equipment, pretreatment to reduce the particle size will be performed accordingly. Processing costs increase. In particular, thermosetting / thermoplastic resin, fiber reinforced plastic (FRP), carbon fiber, and the like are difficult to pulverize, so that the pretreatment (pulverization) cost increases. Also, it can be used effectively in cement burning equipment such as organic sludge, municipal waste, biomass fuel, etc., which has trouble in the operation of cement burning equipment, such as optical fiber and solar cells that have heat quantity but are expensive in pretreatment could not.

そこで、本発明は、上記従来技術における問題点に鑑みてなされたものであって、燃焼特性や化学組成、物性によりセメント焼成装置で利用が困難である可燃性廃棄物を効率的に有効利用することを目的とする。   Therefore, the present invention has been made in view of the above-described problems in the prior art, and efficiently uses flammable waste that is difficult to use in a cement baking apparatus due to combustion characteristics, chemical composition, and physical properties. For the purpose.

上記目的を達成するため、本発明は、可燃性廃棄物の処理装置であって、セメント焼成装置の仮焼炉に隣接して設けられ、熱硬化性・熱可塑性樹脂や繊維強化プラスチック、カーボンファイバー、光ファイバー、太陽電池、有機性汚泥、都市ごみ、バイオマス燃料から選択される1種以上の可燃性廃棄物を前処理しないでそのまま燃焼させる燃焼炉と、該燃焼炉から排出された燃焼ガス及び可燃性ガス並びに燃焼残渣を、ダクトを介さずに直接前記仮焼炉に供給する供給装置とを備えることを特徴とする。 In order to achieve the above object , the present invention is a combustible waste treatment apparatus, which is provided adjacent to a calcining furnace of a cement firing apparatus, and is a thermosetting / thermoplastic resin, fiber reinforced plastic, or carbon fiber. A combustion furnace in which one or more combustible wastes selected from optical fibers, solar cells, organic sludge, municipal waste, and biomass fuel are burned as they are without pretreatment, and combustion gases and combustibles discharged from the combustion furnace And a supply device for supplying the gas and the combustion residue directly to the calcining furnace without using a duct .

本発明によれば、粉砕等の前処理に要するコストが高すぎるためにセメント焼成装置で有効利用できない可燃性廃棄物や、セメント焼成装置に直接供給して処理することができない可燃性廃棄物を効率よく処理することができる。また、燃焼炉から排出された燃焼ガス及び可燃性ガス並びに燃焼残渣を、ダクトを介さずに直接仮焼炉に供給するため、熱損失等を最小限に抑えながら可燃性廃棄物を処理することができる。 According to the present invention, and the flammable waste that can not be effectively utilized in the cement burning device in order cost is too high it takes to pre-treatment such as pulverization, can not be processed directly supplied to the cement burning device combustible waste Can be processed efficiently. In addition, since the combustion gas, combustible gas and combustion residue discharged from the combustion furnace are supplied directly to the calcining furnace without going through the duct, the combustible waste should be treated while minimizing heat loss. Can do.

以上のように、本発明によれば、熱硬化性・熱可塑性樹脂や繊維強化プラスチック、カーボンファイバー、光ファイバー、太陽電池、有機性汚泥、都市ごみ、バイオマス燃料等の可燃性廃棄物をセメント焼成装置で効率的に有効利用することができる。   As described above, according to the present invention, a cement baking apparatus for combustible waste such as thermosetting / thermoplastic resin, fiber reinforced plastic, carbon fiber, optical fiber, solar cell, organic sludge, municipal waste, and biomass fuel. Can be used efficiently and efficiently.

本発明に係る可燃性廃棄物の処理装置の参考例を適用したセメント焼成装置を示す全体構成図である。It is a whole block diagram which shows the cement baking apparatus to which the reference example of the processing apparatus of the combustible waste which concerns on this invention is applied. 本発明に係る可燃性廃棄物の処理装置の参考例を示す概略図である。It is the schematic which shows the reference example of the processing apparatus of the combustible waste which concerns on this invention. 本発明に係る可燃性廃棄物の処理装置の実施形態を示す概略図である。It is the schematic which shows one Embodiment of the processing apparatus of the combustible waste which concerns on this invention.

図1は、本発明に係る可燃性廃棄物の処理装置の参考例を適用したセメント焼成装置を示し、このセメント焼成装置1は、セメント原料Mを予熱するプレヒータ5と、予熱された原料を仮焼する仮焼炉4と、仮焼された原料を焼成するセメントキルン2と、セメントキルン2で焼成したセメントクリンカを冷却するクリンカークーラ3と、プレヒータ5の排ガスを誘引するファン8と、本発明に係る可燃性廃棄物の処理装置として、可燃性廃棄物Wを燃焼させる燃焼炉9等を備える。 FIG. 1 shows a cement firing apparatus to which a reference example of a combustible waste treatment apparatus according to the present invention is applied. This cement firing apparatus 1 preheats a cement raw material M and a preheated raw material. A calcining furnace 4 for firing, a cement kiln 2 for firing the calcined raw material, a clinker cooler 3 for cooling the cement clinker fired in the cement kiln 2, a fan 8 for attracting exhaust gas from the preheater 5, and the present invention As a combustible waste treatment apparatus, a combustion furnace 9 for burning the combustible waste W is provided.

プレヒータ5は、4段に配置されたサイクロン5a〜5dで構成され、原料シュート7から供給されたセメント原料Mを予熱する。   The preheater 5 is composed of cyclones 5 a to 5 d arranged in four stages, and preheats the cement raw material M supplied from the raw material chute 7.

仮焼炉4は、仮焼用のバーナ4aを備え、プレヒータ5の2段目サイクロン5bから供給されたセメント原料Mを仮焼する。   The calcining furnace 4 includes a burner 4a for calcining, and calcines the cement raw material M supplied from the second-stage cyclone 5b of the preheater 5.

セメントキルン2は、主バーナ2aを備え、プレヒータ5の最下段サイクロン5aから窯尻2cに供給されたセメント原料Mを焼成する。   The cement kiln 2 includes a main burner 2a, and fires the cement raw material M supplied from the lowermost cyclone 5a of the preheater 5 to the kiln bottom 2c.

クリンカークーラ3は、セメントキルン2で焼成したセメントクリンカを冷却するために設けられる。クーラ抽気ダクト3aは、クリンカクーラ3から排出された熱ガスを仮焼炉4に導入するために備えられる。   The clinker cooler 3 is provided for cooling the cement clinker fired by the cement kiln 2. The cooler bleed duct 3 a is provided for introducing the hot gas discharged from the clinker cooler 3 into the calcining furnace 4.

燃焼炉9は、可燃性廃棄物Wを燃焼させて燃焼ガス及び可燃性ガスGを生成するために備えられ、例えば、流動床型焼却炉やストーカ式焼却炉、火格子が可動式の焼却炉を用いることができる。燃焼炉9には大気Aを導入してもよいが、可燃性廃棄物Wの燃焼効率を向上させるため、酸素濃度が21%〜100%の高酸素濃度ガスを導入してもよい。燃焼ガス及び可燃性ガスGは、供給装置(不図示)を介してセメントキルン2の窯尻2cに供給される。   The combustion furnace 9 is provided for burning the combustible waste W to generate the combustion gas and the combustible gas G. For example, a fluidized bed incinerator, a stoker type incinerator, an incinerator with a movable grate Can be used. Although the atmosphere A may be introduced into the combustion furnace 9, in order to improve the combustion efficiency of the combustible waste W, a high oxygen concentration gas having an oxygen concentration of 21% to 100% may be introduced. Combustion gas and combustible gas G are supplied to kiln bottom 2c of cement kiln 2 via a supply device (not shown).

次に、上記構成を有するセメント焼成装置1の動作について図1及び図2を参照しながら説明する。   Next, operation | movement of the cement baking apparatus 1 which has the said structure is demonstrated, referring FIG.1 and FIG.2.

セメント原料Mを原料シュート7を介して3段目サイクロン5cの出口ダクトに供給し、最上段サイクロン5d、3段目サイクロン5c及び2段目サイクロン5bにおいてセメント原料Mを予熱する。2段目サイクロン5bで予熱したセメント原料Mを仮焼炉4に供給してバーナ4aから吹き込んだ微粉炭等の燃焼熱で仮焼した後、最下段サイクロン5a及び原料シュート10を介してセメントキルン2の窯尻2cに供給する。窯尻2cに供給したセメント原料Mをセメントキルン2において主バーナ2aから吹き込んだ微粉炭等の燃焼熱で焼成し、生成したセメントクリンカをクリンカクーラ3に供給して冷却する。   The cement raw material M is supplied to the outlet duct of the third-stage cyclone 5c through the raw material chute 7, and the cement raw material M is preheated in the uppermost cyclone 5d, the third-stage cyclone 5c, and the second-stage cyclone 5b. After the cement raw material M preheated by the second-stage cyclone 5b is supplied to the calcining furnace 4 and calcined by the combustion heat of pulverized coal blown from the burner 4a, the cement kiln is passed through the lowermost cyclone 5a and the raw material chute 10. 2 to the kiln bottom 2c. The cement raw material M supplied to the kiln bottom 2c is baked by the combustion heat of pulverized coal blown from the main burner 2a in the cement kiln 2, and the generated cement clinker is supplied to the clinker cooler 3 to be cooled.

上記運転と並行して燃焼炉9に可燃性廃棄物W及び大気Aを導入し、可燃性廃棄物Wを燃焼させる。燃焼ガス及び可燃性ガスGを仮焼炉4に供給してセメント原料Mの仮焼に用い、発生した燃焼残渣Rをセメントキルン2の窯尻2cに供給し、セメント原料として用いる。可燃性廃棄物Wは、熱硬化性・熱可塑性樹脂や繊維強化プラスチック、カーボンファイバー、光ファイバー、太陽電池、有機性汚泥、都市ごみ、バイオマス燃料等であり、これらを単独で又は複数同時にそのまま燃焼炉9に供給することができる。   In parallel with the above operation, the combustible waste W and the atmosphere A are introduced into the combustion furnace 9 to burn the combustible waste W. Combustion gas and combustible gas G are supplied to the calcining furnace 4 and used for calcining the cement raw material M, and the generated combustion residue R is supplied to the kiln bottom 2c of the cement kiln 2 and used as cement raw material. Combustible waste W is thermosetting / thermoplastic resin, fiber reinforced plastic, carbon fiber, optical fiber, solar cell, organic sludge, municipal waste, biomass fuel, etc. 9 can be supplied.

次に、本発明に係る可燃性廃棄物の処理装置の実施形態について図3を参照しながら説明する。 Next, one embodiment of the treatment apparatus of the combustible waste according to the present invention while referring to Figure 3.

この可燃性廃棄物の処理装置11の燃焼炉12は、図2に示した燃焼炉9と同様、流動床型焼却炉やストーカ式焼却炉、火格子が可動式の焼却炉を用いることができ、本実施の形態では、仮焼炉4に隣接して設置される。その他の構成は図1及び図2に示したセメント焼成装置1と同様である。このような構成とすることで、燃焼炉12から排出された燃焼ガス及び可燃性ガスG及び燃焼残渣Rを供給装置やダクトを介さず直接仮焼炉4に供給することができ、熱損失等を最小限に抑えながら可燃性廃棄物Wを処理することができる。   As the combustion furnace 12 of the combustible waste treatment apparatus 11, a fluidized bed incinerator, a stoker-type incinerator, or an incinerator with a movable grate can be used as in the combustion furnace 9 shown in FIG. In this embodiment, it is installed adjacent to the calcining furnace 4. The other structure is the same as that of the cement baking apparatus 1 shown in FIG.1 and FIG.2. With such a configuration, the combustion gas, the combustible gas G, and the combustion residue R discharged from the combustion furnace 12 can be directly supplied to the calcining furnace 4 without using a supply device or a duct, and heat loss, etc. The flammable waste W can be treated while minimizing the above.

尚、上記可燃性ガスは、可燃性廃棄物Wの燃焼、熱分解により発生する一酸化炭素や揮発性有機物質のガスであり、燃焼ガスGと共に仮焼炉4、セメントキルン2、ライジングダクト6に供給することで燃焼させ、その熱量も有効に利用することができる。   The combustible gas is a gas of carbon monoxide or a volatile organic substance generated by combustion and thermal decomposition of the combustible waste W. The calcining furnace 4, the cement kiln 2, and the rising duct 6 together with the combustion gas G are used. It is made to combust by supplying to and the calorie | heat amount can also be utilized effectively.

以上のように、本実施の形態では、可燃性廃棄物Wをそのまま燃焼炉9、12で燃焼させ、燃焼炉9、12から排出された燃焼ガス及び可燃性ガスGを仮焼炉4に供給するため、可燃性廃棄物Wの前処理が不要で、燃焼性の悪い可燃性廃棄物でも低コストで有効利用することができる。   As described above, in this embodiment, the combustible waste W is burned in the combustion furnaces 9 and 12 as they are, and the combustion gas and the combustible gas G discharged from the combustion furnaces 9 and 12 are supplied to the calcining furnace 4. Therefore, pretreatment of the flammable waste W is unnecessary, and even flammable waste with poor flammability can be effectively used at low cost.

尚、上記実施の形態では、燃焼炉9、12から排出された燃焼ガス及び可燃性ガスGを仮焼炉4に供給したが、セメントキルン2やライジングダクト6(セメントキルン2の排ガスを仮焼炉4に案内するダクト)に供給してもよい。   In the above embodiment, the combustion gas and the combustible gas G discharged from the combustion furnaces 9 and 12 are supplied to the calcining furnace 4, but the cement kiln 2 and the rising duct 6 (the exhaust gas from the cement kiln 2 are calcined). You may supply to the duct) guided to the furnace 4.

また、クリンカクーラ3から排出された熱ガス(クーラ抽気ダクト3aを通過する熱ガス)を用いて燃焼炉9、12に供給するガスの酸素濃度を調整してもよい。   Further, the oxygen concentration of the gas supplied to the combustion furnaces 9 and 12 may be adjusted using the hot gas discharged from the clinker cooler 3 (the hot gas passing through the cooler bleed duct 3a).

さらに、燃焼炉から回収された燃焼残渣は、セメント原料として再利用することができるが、一部を採取し、化学組成を分析することによりセメント品質に悪影響を及ぼす、或いは希少金属等が回収可能と判断された場合には、セメント焼成装置への投入を制限(投入量の調節、系外排出)する制御を組み込むこともできる。   In addition, the combustion residue recovered from the combustion furnace can be reused as a raw material for cement. However, it is possible to recover rare metals, etc., by adversely affecting the cement quality by collecting a part and analyzing the chemical composition. If it is determined, it is possible to incorporate a control for restricting the input to the cement baking apparatus (adjustment of input amount, discharge outside the system).

1 セメント焼成装置
2 セメントキルン
2a 主バーナ
2b 窯前
2c 窯尻
3 クリンカクーラ
3a クーラ抽気ダクト
4 仮焼炉
4a バーナ4a
5 プレヒータ
5a 最下段サイクロン
5b 2段目サイクロン
5c 3段目サイクロン
5d 最上段サイクロン
6 ライジングダクト
7 原料シュート
8 ファン
9 燃焼炉
10 原料シュート
11 可燃性廃棄物の処理装置
12 燃焼炉
A 大気
G 燃焼ガス及び可燃性ガス
M セメント原料
R 燃焼残渣
W 可燃性廃棄物
DESCRIPTION OF SYMBOLS 1 Cement baking apparatus 2 Cement kiln 2a Main burner 2b In front of kiln 2c Kiln bottom 3 Clinker cooler 3a Cooler bleed duct 4 Calciner 4a Burner 4a
5 Preheater 5a Lowermost cyclone 5b Second stage cyclone 5c Third stage cyclone 5d Uppermost cyclone 6 Rising duct 7 Raw material chute 8 Fan 9 Combustion furnace 10 Raw material chute 11 Combustible waste treatment device 12 Combustion furnace A Atmosphere G Combustion gas And combustible gas M Cement raw material R Combustion residue W Combustible waste

Claims (1)

セメント焼成装置の仮焼炉に隣接して設けられ、熱硬化性・熱可塑性樹脂や繊維強化プラスチック、カーボンファイバー、光ファイバー、太陽電池、有機性汚泥、都市ごみ、バイオマス燃料から選択される1種以上の可燃性廃棄物を前処理しないでそのまま燃焼させる燃焼炉と、該燃焼炉から排出された燃焼ガス及び可燃性ガス並びに燃焼残渣を、ダクトを介さずに直接前記仮焼炉に供給する供給装置とを備えることを特徴とする可燃性廃棄物の処理装置。 One or more types selected from thermosetting / thermoplastic resin, fiber reinforced plastic, carbon fiber, optical fiber, solar cell, organic sludge, municipal waste, and biomass fuel. a combustion furnace for burning as combustible wastes without pretreatment, the combustion gas and the combustible gas and combustion residues discharged from the combustion furnace, supply device for supplying directly the calciner without passing through the duct And a combustible waste treatment apparatus.
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