JP6297783B2 - 炭化珪素半導体装置およびその製造方法 - Google Patents
炭化珪素半導体装置およびその製造方法 Download PDFInfo
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- JP6297783B2 JP6297783B2 JP2013046894A JP2013046894A JP6297783B2 JP 6297783 B2 JP6297783 B2 JP 6297783B2 JP 2013046894 A JP2013046894 A JP 2013046894A JP 2013046894 A JP2013046894 A JP 2013046894A JP 6297783 B2 JP6297783 B2 JP 6297783B2
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- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims description 111
- 229910010271 silicon carbide Inorganic materials 0.000 title claims description 111
- 239000004065 semiconductor Substances 0.000 title claims description 74
- 238000004519 manufacturing process Methods 0.000 title claims description 52
- 239000011229 interlayer Substances 0.000 claims description 123
- 239000010410 layer Substances 0.000 claims description 121
- 229910052751 metal Inorganic materials 0.000 claims description 83
- 239000002184 metal Substances 0.000 claims description 83
- 238000000034 method Methods 0.000 claims description 52
- 238000005530 etching Methods 0.000 claims description 48
- 239000000758 substrate Substances 0.000 claims description 48
- 239000012535 impurity Substances 0.000 claims description 37
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- 239000010936 titanium Substances 0.000 claims description 21
- 235000012239 silicon dioxide Nutrition 0.000 claims description 18
- 239000000377 silicon dioxide Substances 0.000 claims description 18
- 229910052719 titanium Inorganic materials 0.000 claims description 15
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 14
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 13
- 230000002093 peripheral effect Effects 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 11
- 238000001312 dry etching Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- -1 tungsten nitride Chemical class 0.000 claims description 7
- 238000001039 wet etching Methods 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- 210000000746 body region Anatomy 0.000 description 19
- 229910052782 aluminium Inorganic materials 0.000 description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 11
- 229910052698 phosphorus Inorganic materials 0.000 description 11
- 239000011574 phosphorus Substances 0.000 description 11
- 229910052710 silicon Inorganic materials 0.000 description 11
- MAKDTFFYCIMFQP-UHFFFAOYSA-N titanium tungsten Chemical compound [Ti].[W] MAKDTFFYCIMFQP-UHFFFAOYSA-N 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 238000009413 insulation Methods 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000002161 passivation Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 229910005883 NiSi Inorganic materials 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- HIVGXUNKSAJJDN-UHFFFAOYSA-N [Si].[P] Chemical compound [Si].[P] HIVGXUNKSAJJDN-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
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Description
Claims (13)
- 互いに対向する第1の主面および第2の主面を有し、前記第1の主面に接してゲート絶縁膜が設けられ、前記ゲート絶縁膜に接してゲート電極が設けられ、かつ前記第1の主面に接する第1導電型領域を含む炭化珪素基板を準備する工程と、
前記ゲート電極および前記ゲート絶縁膜と接する層間絶縁膜を形成する工程と、
前記層間絶縁膜に接してマスク層を形成する工程と、
前記マスク層を用いて前記層間絶縁膜に対して第1の等方性エッチングを行うことにより前記層間絶縁膜に第1の内壁面を有する第1の凹部を形成する工程と、
前記第1の凹部を形成する工程の後、前記マスク層を用いて前記層間絶縁膜および前記ゲート絶縁膜に対して第1の異方性エッチングを行って前記炭化珪素基板の前記第1導電型領域を前記ゲート絶縁膜から露出させることにより、第2の内壁面を有する第2の凹部を形成する工程と、
前記第1導電型領域に接して第1の電極を形成する工程と、
前記第1の内壁面および前記第2の内壁面に接して配置され、かつ前記第1の電極に電気的に接続される配線を形成する工程とを備え、
前記層間絶縁膜を形成する工程は、前記層間絶縁膜を加熱することにより前記層間絶縁膜の上部表面の段差を低減させる工程を含み、
前記段差を低減させる工程においては、前記層間絶縁膜の肩部の形状が丸みを有するように変形し、
前記段差を低減させる工程後に、前記肩部に接する前記配線が形成され、
前記配線を形成する工程においては、前記第1の内壁面および前記第2の内壁面の各々に接して金属層を形成した後、前記第1の内壁面に形成された前記金属層の部分が除去され、前記第2の内壁面に形成された前記金属層の部分は残存し、
前記金属層はTiを含む膜である、炭化珪素半導体装置の製造方法。 - 前記層間絶縁膜を形成する工程は、前記ゲート電極に接し、かつ不純物がドープされていない第1の絶縁膜を形成する工程と、前記第1の絶縁膜を覆い、前記第1の絶縁膜よりも低い軟化点を有し、かつ不純物がドープされている第2の絶縁膜を形成する工程とを含む、請求項1に記載の炭化珪素半導体装置の製造方法。
- 前記層間絶縁膜を形成する工程は、前記第2の絶縁膜を覆いかつ二酸化珪素から構成された第3の絶縁膜を形成する工程をさらに含む、請求項2に記載の炭化珪素半導体装置の製造方法。
- 前記第1の等方性エッチングはウェットエッチングである、請求項1〜3のいずれか1項に記載の炭化珪素半導体装置の製造方法。
- 前記第1の異方性エッチングはドライエッチングである、請求項1〜4のいずれか1項に記載の炭化珪素半導体装置の製造方法。
- 前記ゲート電極上に配置された前記層間絶縁膜に対して第2の等方性エッチングを行うことにより第3の内壁面を有する第3の凹部を形成する工程と、
前記第3の凹部を形成する工程の後、前記層間絶縁膜に対して第2の異方性エッチングを行って前記ゲート電極を前記層間絶縁膜から露出させることにより第4の内壁面を有する第4の凹部を形成する工程とをさらに備え、
前記配線を形成する工程では、前記第3の内壁面および前記第4の内壁面に接して配置され、かつ前記ゲート電極と電気的に接続する前記配線が形成される、請求項1〜5のいずれか1項に記載の炭化珪素半導体装置の製造方法。 - 前記配線の厚みは2μm以上10μm以下である、請求項1〜6のいずれか1項に記載の炭化珪素半導体装置の製造方法。
- 互いに対向する第1の主面および第2の主面を有し、かつ前記第1の主面に接して設けられた第1導電型領域を含む炭化珪素基板と、
前記炭化珪素基板の前記第1の主面に接するゲート絶縁膜と、
前記ゲート絶縁膜に接するゲート電極と、
前記ゲート電極および前記ゲート絶縁膜と接する層間絶縁膜と、
前記第1の主面から離れるにつれて幅が大きくなるように形成され、かつ第1の内壁面が前記層間絶縁膜により形成された第1の凹部と、
前記第1の凹部と連接し、かつ第2の内壁面が前記層間絶縁膜および前記ゲート絶縁膜により形成された第2の凹部と、
前記第2の凹部内に配置され、かつ前記第1導電型領域に接する第1の電極と、
前記第1の内壁面および前記第2の内壁面に接して配置され、かつ前記第1の電極と電気的に接続する第1の配線とを備え、
前記層間絶縁膜の肩部の形状が丸みを有し、前記第1の配線は前記肩部に接し、
前記第1の配線は、前記第1の内壁面に接する第1金属層と、前記第2の内壁面に接する第2金属層とを含み、
前記第1金属層はチタンから構成され、かつ前記第2金属層は窒化チタンまたは窒化タングステンから構成されている、炭化珪素半導体装置。 - 前記層間絶縁膜の上部表面において前記ゲート電極の外周角部を囲む部分は、前記ゲート電極の前記外周角部よりも丸みを有する、請求項8に記載の炭化珪素半導体装置。
- 前記ゲート電極上に配置された前記層間絶縁膜に形成され、かつ前記第1の主面から離れるにつれて幅が大きくなるように形成された第3の内壁面を有する第3の凹部と、
前記第3の凹部と連接し、かつ第4の内壁面が前記層間絶縁膜により形成された第4の凹部と、
前記第3の内壁面および前記第4の内壁面に接して配置され、かつ前記ゲート電極と電気的に接続された第2の配線とをさらに備える、請求項8または9に記載の炭化珪素半導体装置。 - 前記層間絶縁膜は、前記ゲート電極に接しかつ不純物がドープされていない第1の絶縁膜と、前記第1の絶縁膜を覆い、前記第1の絶縁膜よりも低い軟化点を有しかつ不純物がドープされている第2の絶縁膜とを含む、請求項8〜10のいずれか1項に記載の炭化珪素半導体装置。
- 前記層間絶縁膜は、前記第2の絶縁膜を覆いかつ二酸化珪素から構成された第3の絶縁膜をさらに含む、請求項11に記載の炭化珪素半導体装置。
- 前記第1の配線の厚みは2μm以上10μm以下である、請求項8〜12のいずれか1項に記載の炭化珪素半導体装置。
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