JP5994403B2 - Side wall pipe manufacturing method and side wall pipe manufacturing system - Google Patents

Description

  The present invention relates to a side wall pipe manufacturing method and a side wall pipe for manufacturing a side wall pipe that functions as a side wall of a reaction channel through which a reaction fluid that is a fluid to be reacted flows in a reactor such as a microreactor having a minute space as a reaction field. The present invention relates to a manufacturing system and a side wall pipe.

  A microreactor is a reaction device that uses a small space as a reaction field. By using such a small space as a reaction field, the collision frequency between molecules and heat transfer speed are increased, and the reaction speed and yield are increased. Can be improved.

  In such a microreactor, for example, a reaction channel having a small cross section is provided, a catalyst is arranged in the reaction channel, and a reaction fluid to be reacted is circulated through the reaction channel to promote the reaction.

  As a technique for manufacturing a reaction channel for a microreactor, a resist film is formed on a portion of the substrate other than a portion serving as a reaction channel, and then etching is performed to form a groove at a portion serving as a reaction channel on the substrate. A technique for removing a resist after forming a catalyst support layer on the surface of the formed groove is disclosed (for example, Patent Document 1).

  In addition, a technique is disclosed in which a slurry-like catalyst powder is applied to the surface of a metal substrate on which a flow path is formed, and then pressure is applied to the catalyst powder, whereby the catalyst is pressure-bonded to the flow path (for example, Patent Document 2).

JP 2008-69018 A JP 2009-78225 A

  However, in the technique of Patent Document 1, a device for depositing a resist or a catalyst-carrying layer or performing lithography or etching to form a reaction channel pattern on the resist is large. It was. Moreover, it is necessary to prepare a pattern for each channel cross-sectional area of the reaction channel and for each channel length, which requires a cost for creating the pattern.

  Moreover, since the catalyst is comprised with the metal oxide (ceramic), its adhesiveness with a metal is low. Therefore, even if the catalyst powder is simply pressure-bonded to the metal substrate using the technique of Patent Document 2, high adhesion between the metal substrate and the catalyst cannot be realized, and the catalyst falls off from the metal substrate ( There is a risk of peeling).

The present invention has been made in view of the above problems, a simple structure and low cost, the side wall tube manufacturing method capable of improving the adhesion of the catalyst in the reaction channel, and provides a side wall pipe production system The purpose is to do.

In order to solve the above problems, a side wall pipe manufacturing method of the present invention is a side wall pipe manufacturing method for manufacturing a side wall pipe that functions as a side wall of a reaction channel through which a reaction fluid that is a fluid to be reacted flows, the outer surface of the hollow porous material porous tube formed by composed Rutotomoni metals having an opening, the liquid particles of the catalyst composed of a metal oxide is dispersed in a solvent, or a metal oxide A step of contacting a catalyst liquid, which is a liquid in which catalyst precursor particles composed of the catalyst are dispersed in a solvent, and in a state where the porous tube is in contact with the catalyst liquid, the solvent is sucked from the opening to And a step of attaching the catalyst precursor particles to the outer surface of the porous tube, and a step of heating the catalyst particles or the porous tube to which the catalyst precursor particles are attached. It is characterized by that.

In order to solve the above problems, another side wall pipe manufacturing method of the present invention is a side wall pipe manufacturing method for manufacturing a side wall pipe that functions as a side wall of a reaction channel through which a reaction fluid that is a reaction target fluid flows. Te, on the inner surface of the hollow porous material porous tube formed by composed Rutotomoni metals having an opening, the liquid particles of the catalyst composed of a metal oxide is dispersed in a solvent or a metal The step of contacting the catalyst liquid, which is a liquid in which catalyst precursor particles composed of oxides are dispersed in a solvent, and the solvent from the outer surface of the porous tube in a state where the porous tube is in contact with the catalyst liquid To suck the catalyst particles or catalyst precursor particles to the inner surface of the porous tube, and heat the porous tube to which the catalyst particles or catalyst precursor particles are attached. And a step of performing.

In order to solve the above problems, the side wall pipe manufacturing system of the present invention is a side wall pipe manufacturing system that manufactures a side wall pipe that functions as a side wall of a reaction channel through which a reaction fluid that is a fluid to be reacted flows. the outer surface of the hollow porous material porous tube formed by composed Rutotomoni metals having an opening, the liquid particles of the catalyst composed of a metal oxide is dispersed in a solvent, or a metal oxide A contact means for contacting the catalyst liquid, in which the catalyst precursor particles composed of the catalyst are dispersed in a solvent, and the contact means for removing the solvent from the opening while the porous tube is in contact with the catalyst liquid. Suction to attach the catalyst particles or catalyst precursor particles to the outer surface of the porous tube, and heat the porous tube to which the catalyst particles or catalyst precursor particles adhere A heating unit And butterflies.

In order to solve the above problems, another side wall pipe manufacturing system of the present invention is a side wall pipe manufacturing system that manufactures a side wall pipe that functions as a side wall of a reaction channel through which a reaction fluid that is a reaction target fluid flows. Te, on the inner surface of the hollow porous material porous tube formed by composed Rutotomoni metals having an opening, the liquid particles of the catalyst composed of a metal oxide is dispersed in a solvent or a metal Contact means for contacting the catalyst liquid, which is a liquid in which catalyst precursor particles composed of oxides are dispersed in a solvent, and the porous pipe in contact with the catalyst liquid by the contact means. The suction part that sucks the solvent from the outer surface and attaches the catalyst particles or catalyst precursor particles to the inner surface of the porous tube and the catalyst particles or catalyst precursor particles adhere Heating a porous tube Characterized by comprising a and.

  According to the present invention, it is possible to improve the adhesion of the catalyst in the reaction channel with a simple configuration and low cost.

It is a block diagram for demonstrating the structure of the side wall pipe manufacturing system concerning 1st Embodiment. It is a figure for demonstrating adhesion of the catalyst particle to the outer surface of a porous tube according to attraction | suction by a suction part. It is a figure for demonstrating formation of the catalyst layer in the outer surface of a porous tube according to the heating by a heating part. It is a figure for demonstrating a microreactor. It is a flowchart for demonstrating the flow of a process of the side wall pipe manufacturing method concerning 1st Embodiment. It is a block diagram for demonstrating the structure of the side wall pipe manufacturing system concerning 2nd Embodiment.

  Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. The dimensions, materials, and other specific numerical values shown in the embodiments are merely examples for facilitating the understanding of the invention, and do not limit the present invention unless otherwise specified. In the present specification and drawings, elements having substantially the same function and configuration are denoted by the same reference numerals, and redundant description is omitted, and elements not directly related to the present invention are not illustrated. To do.

(First embodiment)
For example, in a microreactor, the reaction rate and yield can be improved by using a microchannel flow path (reaction flow path) whose width or height is 1 mm or less as a reaction field. In addition, by arbitrarily configuring the convection and diffusion modes, it becomes possible to quickly mix, actively assign a concentration distribution, and the like, and to strictly control the reaction conditions.

  In such a microreactor, in order to improve reaction efficiency, a catalyst is arranged in the reaction channel, and a reaction fluid to be reacted is circulated through the reaction channel to promote the reaction. In order to further improve the reaction efficiency, a configuration is adopted in which a medium flow path through which the heat medium flows is arranged in parallel with the reaction flow path. When an exothermic reaction is performed in the reaction flow path, heat generated by the reaction is recovered by the heat medium flowing through the medium flow path, and when an endothermic reaction is performed, the heat medium flowing through the medium flow path As a result, heat is applied to the reaction fluid flowing through the reaction channel.

  In this embodiment, a side wall pipe manufacturing system 100 that manufactures a side wall pipe that functions as a side wall of a reaction flow channel through which a reaction fluid (a gas or liquid) that is a reaction target flows, and a side wall pipe manufacturing using the side wall pipe manufacturing system 100 A method will be described.

  FIG. 1 is a block diagram for explaining a configuration of a side wall pipe manufacturing system 100 according to the first embodiment. As shown in FIG. 1, the side wall pipe manufacturing system 100 includes an attachment device 110, a heating unit 150, and a processing unit 160.

  The deposition apparatus 110 deposits catalyst particles or catalyst precursor particles on at least the outer surface of the porous tube 170. Here, a case where catalyst particles (hereinafter simply referred to as catalyst particles) are attached will be described as an example.

  In the present embodiment, the porous tube 170 is formed of a hollow porous body having an opening 170a. By configuring the porous tube 170 with a porous body, the porous tube 170 has a function of separating a large particle size and a small particle size (hereinafter simply referred to as a filter function) as a filter. . In the present embodiment, a bottom surface 170b is formed at the end of the porous tube 170 opposite to the opening 170a.

  The attaching device 110 attaches catalyst particles to the outer surface of the porous tube 170 using the filter function of the porous tube 170. If it demonstrates concretely, the adhesion apparatus 110 will be comprised including the immersion tank 112 and the suction part 120. FIG.

  The immersion tank 112 functions as a contact means, and contains the catalyst liquid SL in which catalyst particles are dispersed in a solvent (for example, water). The catalyst liquid SL is a slurry suspension. By immersing the porous tube 170 in the immersion tank 112, the catalyst solution SL is brought into contact with the outer surface of the porous tube 170.

  The suction unit 120 includes a suction pipe 122 and a pump 124 connected to the suction pipe 122. The suction pipe 122 is made of, for example, a resin pipe having elasticity, and communicates the opening 170 a of the porous pipe 170 (inside the porous pipe 170) and the pump 124.

  FIG. 2 is a view for explaining the attachment of the catalyst particles S to the outer surface 170 c of the porous tube 170 by the suction of the suction part 120.

  As described above, the porous tube 170 is composed of a porous body. That is, as shown in FIG. 2, the porous tube 170 is formed with a plurality of communication hole paths 170d that allow the outer surface 170c and the inner surface to communicate with each other. Further, the communication hole path 170d is not constant in the cross-sectional area of the flow path and is curved.

  By configuring the porous tube 170 with a porous body, the porous tube 170 can have a filter function. Therefore, when the driving of the pump 124 is started in a state where the catalyst liquid SL is in contact with the outer surface 170c of the porous tube 170, the catalyst liquid SL is compared with the catalyst particles S and the catalyst particles S by the porous tube 170. Thus, it is separated into a solvent L (solvent molecule) having a very small particle size. In other words, the catalyst liquid SL is filtered by the porous tube 170.

  More specifically, as shown in FIG. 2, when the suction unit 120 performs suction from the opening 170a in a state where the porous tube 170 is in contact with the catalyst solution SL, the solvent L passes through the communication hole 170d. While being sucked, the catalyst particles S are clogged from the inner surface toward the outer surface 170c in the communication hole 170d. When the suction unit 120 continues the suction, the catalyst particles S can be finally stacked on the outer surface 170c while the catalyst particles S are filled in the vicinity of the outer surface 170c of the porous tube 170.

  Here, the average value of the cross-sectional area of the communication hole path 170d is larger than the average particle diameter of the catalyst particles S, for example, 1 μm to 1 mm, preferably 10 μm to 100 μm. Moreover, the average particle diameter of the catalyst particle S is 0.1 micrometer-100 micrometers, for example, Preferably, they are 1 micrometer-10 micrometers.

  In the present embodiment, the porous body is made of metal, and the catalyst particles S are made of metal oxide. As a porous body, stainless steel, such as SUS316L, SUS630, SUS310Mo, SUS410L, SUS420J2, SUS440C, may be sufficient, for example. Moreover, titanium may be sufficient and titanium alloys, such as Ti-6Al-4V, may be sufficient. Furthermore, low alloy steels such as copper, copper alloy, nickel, aluminum, SCM415 may be used.

Further, the catalyst particles S may be appropriately selected according to the target reaction. For example, when the target reaction is an exothermic reaction of Chemical Formula 1 or an endothermic reaction of Chemical Formula 2, particles of Ni or Ru as active metals and Al ₂ O ₃ , SiO ₂ , CeO as supports ₂ , a mixture of ZrO ₂ and TiO ₂ particles is used as the catalyst particles S.
CO + 3H ₂ → CH ₄ + H ₂ O (Chemical formula 1)
CH ₄ + H ₂ O → CO + 3H ₂ (Chemical formula 2)

  Referring back to FIG. 1, the heating unit 150 first heats the porous tube 170 to which the catalyst particles S are attached to a predetermined first temperature. By doing so, the solvent L attached to the porous tube 170 and the catalyst particles S can be dried.

  Subsequently, the heating unit 150 fires (sinters) the catalyst particles S by heating the porous tube 170 to which the dried catalyst particles S adhere to a second temperature higher than the first temperature. To do.

  FIG. 3 is a diagram for explaining the formation of the catalyst layer CL on the outer surface 170 c of the porous tube 170 in accordance with the heating by the heating unit 150. When the heating unit 150 calcinates the catalyst particles S, as shown in FIG. 3, in the attachment device 110, the catalyst particles S filled inside the vicinity of the outer surface 170 c of the porous tube 170 and the outer surface 170 c are stacked. The catalyst particles S melted and then solidified to form a sintered body (dense catalyst layer CL). Therefore, the catalyst layer CL can be formed on the outer surface 170c of the porous tube 170.

  As described above, the porous body (porous tube 170) is made of metal, and the catalyst particles S are made of metal oxide. Since the adhesion between metal and metal oxide is low, even if a catalyst layer is formed by simply laminating (depositing) a catalyst on the surface of the metal, high adhesion between the metal and the catalyst cannot be realized. The catalyst will easily fall off from the metal.

  In the present embodiment, as shown in FIG. 3, the catalyst layer CL can be embedded not only in the outer surface 170c of the porous tube 170 but also in the communication hole 170d near the outer surface 170c. As described above, the communication hole path 170d is not constant in the cross-sectional area of the flow path, and is curved, so that the catalyst layer CL embedded in the communication hole path 170d has a mesh shape in the vicinity of the outer surface 170c. It will be stretched around. Therefore, the catalyst layer CL embedded in the communication hole passage 170d is firmly attached by being locked to the porous tube 170, and is integrally formed with the catalyst layer CL embedded in the communication hole passage 170d. A situation in which the catalyst layer CL on the outer surface 170c falls off can be avoided.

  Returning to FIG. 1, the processing unit 160 cuts the bottom surface portion 170 b in the porous tube 170 in which the catalyst layer CL is in close contact with the outer surface 170 c by the heating unit 150. Thus, a side wall pipe 180 having openings at both ends, that is, a side wall pipe 180 through which fluid can flow can be manufactured.

  As described above, according to the side wall pipe manufacturing system 100 according to the present embodiment, it is possible to form the catalyst layer CL having high adhesion on the outer surface 170c of the porous pipe 170 with a simple configuration. .

(Microreactor 200)
Next, the microreactor 200 using the side wall pipe 180 manufactured by the side wall pipe manufacturing system 100 will be described. 4A and 4B are diagrams for explaining the microreactor 200. In particular, FIG. 4A is a perspective view of the microreactor 200, FIG. 4B is an enlarged view of the XZ section of FIG. 4 (c) shows an enlarged view of the YZ cross section of FIG. 4 (a). In FIG. 4 of the present embodiment, the X axis, the Y axis, and the Z axis that intersect perpendicularly are defined as illustrated. In FIG. 4, for easy understanding, a microreactor 200 provided with one reaction channel RFC and one medium channel MFC will be described. The microreactor 200 includes a reaction channel RFC and a medium. A plurality of flow paths MFC may be arranged.

  As shown in FIG. 4, the microreactor 200 is configured to include a side wall pipe 180 and an outer pipe 210, and is a double pipe in which the side wall pipe 180 is disposed inside the outer pipe 210.

  In the present embodiment, since the catalyst layer CL is formed on the outer surface of the side wall pipe 180, the space formed between the side wall pipe 180 and the outer pipe 210 functions as the reaction channel RFC, and the side wall pipe A space formed inside 180 functions as a medium flow path MFC. A heat medium flows through the medium flow path MFC, and the heat medium exchanges heat with a fluid flowing through the reaction flow path RFC.

  As described above, the microreactor 200 according to the present embodiment has a simple configuration in which only the side wall pipe 180 is inserted into the outer pipe 210, and the reaction flow path RFC and the medium flow path MFC having a fine flow path cross-sectional area of μm order. Can be formed.

  Further, by changing the inner diameter of the outer tube 210, the channel cross-sectional area (XZ cross-sectional area in FIG. 4) of the reaction channel RFC can be easily changed.

  Furthermore, as described above, the heat exchange efficiency between the reaction channel RFC and the medium channel MFC can be improved by forming the porous tube 170 constituting the side wall tube 180 with metal. Therefore, regardless of whether the reaction using the reaction channel RFC as a reaction field is an exothermic reaction or an endothermic reaction, heat transfer to or from the heat medium flowing through the adjacent medium channel MFC Can be performed efficiently.

(Side wall pipe manufacturing method)
Then, the side wall pipe manufacturing method using the side wall pipe manufacturing system 100 mentioned above is demonstrated. FIG. 5 is a flowchart for explaining a process flow of the method for manufacturing the side wall tube according to the first embodiment.

  As shown in FIG. 5, first, the catalyst tube SL is brought into contact with the outer surface 170c of the porous tube 170 by immersing the porous tube 170 in the immersion tank 112 in which the catalyst solution SL is accommodated (contact process: S310). Then, the suction unit 120 sucks the solvent L from the opening 170a through the suction tube 122 in a state where the porous tube 170 is in contact with the catalyst solution SL, and the catalyst particles S are sucked out from the outer surface 170c of the porous tube 170. (Suction / attachment step: S312).

  When the suction / adhesion step S312 is completed, the porous tube 170 to which the catalyst particles S have adhered is taken out of the immersion tank 112, and the heating unit 150 heats the porous tube 170 to which the catalyst particles S have adhered at the first temperature. Then, the porous tube 170 to which the catalyst particles S adhere is dried (drying step: S314).

  Subsequently, the heating unit 150 raises the temperature for heating the porous tube 170 to which the catalyst particles S are adhered to the second temperature, and the catalyst particles S are fired on the outer surface 170c of the porous tube 170 (heating). Step: S316).

  And the process part 160 cut | disconnects the bottom face part 170b in the porous pipe | tube 170 which the catalyst layer CL contact | adhered to the outer surface 170c by the heating part 150 (process process: S318).

  As described above, according to the side wall tube manufacturing method according to the present embodiment, it is possible to improve the adhesion of the catalyst in the reaction channel RFC with a simple configuration and low cost.

(2nd Embodiment: Side wall pipe manufacturing system 400)
In the first embodiment described above, the technique for manufacturing the side wall pipe 180 in which the catalyst layer CL is adhered to the outer surface 170c of the porous tube 170 has been described. However, the catalyst layer CL is formed on the inner surface 170e of the porous tube 170. An adhering side wall tube can also be manufactured.

  FIG. 6 is a block diagram for explaining a configuration of a side wall pipe manufacturing system 400 according to the second embodiment. As shown in FIG. 6, the side wall pipe manufacturing system 400 includes an attachment device 410, a heating unit 150, and a processing unit 160, and the attachment device 410 includes an immersion tank 112 and a suction unit 420. Consists of. The suction unit 420 includes a suction pipe 422 and a pump 124.

  Note that the immersion tank 112, the pump 124, the heating unit 150, and the processing unit 160 that have already been described as constituent elements in the first embodiment have substantially the same functions, and thus redundant description is omitted. Here, the configurations are different. The suction pipe 422 to be described will be mainly described.

  The suction tube 422 is formed of, for example, a resin tube having elasticity, and, as shown in FIG. 6, one end side encloses the outer surface 170c of the porous tube 170 and a surface on which the opening 170a is formed. Seal the outer edge of. The other end side of the suction pipe 422 is connected to the pump 124.

  When the pump 124 starts to be driven in a state where the porous tube 170 is in contact with the catalyst solution SL, the catalyst solution SL enters the inside of the porous tube 170 from the opening 170a, and the inner surface 170e of the porous tube 170 is removed. As a result, the solvent L is sucked from the outer surface 170c.

  As described above, by forming the porous tube 170 with a porous body, a filter function can be provided. Therefore, when the suction part 420 sucks the solvent L from the outer surface 170c, the catalyst particles S are clogged from the outer surface 170c toward the inner surface 170e in the communication hole 170d. When the suction unit 420 continues to suck, the catalyst particles S can be finally stacked on the inner surface 170e while filling the catalyst particles S in the vicinity of the inner surface 170e of the porous tube 170.

  And the process part 160 cut | disconnects the bottom face part 170b in the porous pipe | tube 170 which the catalyst layer CL contact | adhered to the inner surface 170e by the heating part 150. FIG. Thus, a side wall tube having openings at both ends, that is, a side wall tube through which a reaction fluid can flow can be manufactured.

  As described above, according to the side wall pipe manufacturing system 400 according to the present embodiment, a side wall pipe in which the catalyst layer CL having high adhesion is formed on the inner surface 170e of the porous pipe 170 is manufactured with a simple configuration. It becomes possible to do.

  Further, according to the side wall pipe manufacturing system 400 according to the present embodiment, a side wall pipe in which the catalyst layer CL is formed on the inner surface 170e of the porous pipe 170 can be manufactured. RFC can be used. That is, a side wall pipe can be used alone without using a double pipe. Therefore, it can also be used when performing a reaction that does not require heat exchange with the heat medium.

  In addition, a reaction channel RFC and a medium channel MFC are formed as a double pipe by arranging an outer tube outside the side wall tube in which the catalyst layer CL is formed on the inner surface 170e of the porous tube 170. May be. In this case, the space formed inside the side wall tube functions as the reaction flow channel RFC, and the space formed between the side wall tube and the outer tube functions as the medium flow channel MFC.

  As mentioned above, although preferred embodiment of this invention was described referring an accompanying drawing, it cannot be overemphasized that this invention is not limited to this embodiment. It will be apparent to those skilled in the art that various changes and modifications can be made within the scope of the claims, and these are naturally within the technical scope of the present invention. Is done.

  For example, in the above-described embodiment, the attachment devices 110 and 410 have been described by taking the case where the catalyst particles S are attached to the outer surface 170c or the inner surface 170e of the porous tube 170 as an example. However, the attaching devices 110 and 410 may attach not only the catalyst particles S but also substances (catalyst precursor particles) that become catalysts through the heating step S316.

  In the above-described embodiment, the immersion tank 112 has been described as an example of the contact means. However, if the catalyst liquid SL can be brought into contact with the outer surface 170c or the inner surface 170e of the porous tube 170, the configuration can be provided. There is no limitation.

  Further, in the embodiment described above, the porous tube 170 having a circular cross section in the flow channel direction has been described as an example. However, the porous tube 170 has an opening and is configured by a hollow porous body. If it is done, there is no limitation on the shape. For example, the cross section in the flow path direction may be rectangular.

  In the above-described embodiment, the microreactor 200 using the side wall tube 180 has been described. However, the side wall tube according to the present embodiment can be used not only for a microreactor but also for a compact reactor having a channel cross-sectional area of the order of mm.

The present invention, the side wall pipe production method, and can be utilized in the side wall pipe production system.

100, 400 ... side wall pipe manufacturing system 112 ... immersion bath (contact means)
120, 420 ... Suction part 150 ... Heating part 170 ... Porous pipe 170a ... Opening part 170c ... Outer surface 170e ... Inner surface 180 ... Side wall pipes 110, 410 ... Adhering device

Claims (4)

A side wall pipe manufacturing method for manufacturing a side wall pipe that functions as a side wall of a reaction channel through which a reaction fluid that is a reaction target flows.
The outer surface of the hollow porous material porous tube formed by composed Rutotomoni metals having an opening, the liquid particles of the catalyst composed of a metal oxide is dispersed in a solvent, or a metal oxide A step of contacting a catalyst liquid, which is a liquid in which particles of a catalyst precursor composed of :
With the porous tube in contact with the catalyst solution, the solvent is sucked from the opening, and the catalyst particles or the catalyst precursor particles adhere to the outer surface of the porous tube. A process of
Heating the porous tube to which the catalyst particles or the catalyst precursor particles are attached;
A method for manufacturing a side wall pipe, comprising: A side wall pipe manufacturing method for manufacturing a side wall pipe that functions as a side wall of a reaction channel through which a reaction fluid that is a reaction target flows.
On the inner surface of the hollow porous material porous tube formed by composed Rutotomoni metals having an opening, the liquid particles of the catalyst composed of a metal oxide is dispersed in a solvent, or a metal oxide A step of contacting a catalyst liquid, which is a liquid in which particles of a catalyst precursor composed of :
With the porous tube in contact with the catalyst solution, the solvent is sucked from the outer surface of the porous tube, and the catalyst particles or the catalyst precursor particles are removed from the porous tube. Adhering to the inner surface;
Heating the porous tube to which the catalyst particles or the catalyst precursor particles are attached;
A method for manufacturing a side wall pipe, comprising: A side wall pipe manufacturing system that manufactures a side wall pipe that functions as a side wall of a reaction channel through which a reaction fluid that is a reaction target flows.
The outer surface of the hollow porous material porous tube formed by composed Rutotomoni metals having an opening, the liquid particles of the catalyst composed of a metal oxide is dispersed in a solvent, or a metal oxide Contact means for contacting a catalyst liquid, which is a liquid in which particles of a catalyst precursor composed of :
In the state where the porous tube is in contact with the catalyst solution by the contact means, the solvent is sucked from the opening, and the catalyst particles or the catalyst precursor particles are removed from the porous tube. A suction part attached to the outer surface of the
A heating section for heating the porous tube to which the catalyst particles or the catalyst precursor particles are attached;
A side wall pipe manufacturing system comprising: A side wall pipe manufacturing system that manufactures a side wall pipe that functions as a side wall of a reaction channel through which a reaction fluid that is a reaction target flows.
On the inner surface of the hollow porous material porous tube formed by composed Rutotomoni metals having an opening, the liquid particles of the catalyst composed of a metal oxide is dispersed in a solvent, or a metal oxide Contact means for contacting a catalyst liquid, which is a liquid in which particles of a catalyst precursor composed of :
In the state where the porous tube is in contact with the catalyst solution by the contact means, the solvent is sucked from the outer surface of the porous tube, and the catalyst particles or the catalyst precursor particles are removed. A suction part attached to the inner surface of the porous tube;
A heating section for heating the porous tube to which the catalyst particles or the catalyst precursor particles are attached;
A side wall pipe manufacturing system comprising:

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