JP5682556B2 - 半導体装置 - Google Patents
半導体装置 Download PDFInfo
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- JP5682556B2 JP5682556B2 JP2011518619A JP2011518619A JP5682556B2 JP 5682556 B2 JP5682556 B2 JP 5682556B2 JP 2011518619 A JP2011518619 A JP 2011518619A JP 2011518619 A JP2011518619 A JP 2011518619A JP 5682556 B2 JP5682556 B2 JP 5682556B2
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- 239000004065 semiconductor Substances 0.000 title claims description 50
- 239000010410 layer Substances 0.000 claims description 158
- 239000011229 interlayer Substances 0.000 claims description 122
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 40
- 239000012535 impurity Substances 0.000 claims description 40
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- 238000010438 heat treatment Methods 0.000 claims description 24
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- 229910045601 alloy Inorganic materials 0.000 claims description 11
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 5
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 5
- 238000004364 calculation method Methods 0.000 claims description 2
- 239000010408 film Substances 0.000 description 288
- 229910010271 silicon carbide Inorganic materials 0.000 description 91
- 238000000034 method Methods 0.000 description 75
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 64
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- 125000004430 oxygen atom Chemical group O* 0.000 description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910005883 NiSi Inorganic materials 0.000 description 4
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
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- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
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- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
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- 238000000206 photolithography Methods 0.000 description 2
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
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- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- OJCDKHXKHLJDOT-UHFFFAOYSA-N fluoro hypofluorite;silicon Chemical compound [Si].FOF OJCDKHXKHLJDOT-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
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- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000009279 wet oxidation reaction Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/0445—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising crystalline silicon carbide
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/0445—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising crystalline silicon carbide
- H01L21/045—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising crystalline silicon carbide passivating silicon carbide surfaces
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/0445—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising crystalline silicon carbide
- H01L21/048—Making electrodes
- H01L21/0485—Ohmic electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/0445—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising crystalline silicon carbide
- H01L21/048—Making electrodes
- H01L21/049—Conductor-insulator-semiconductor electrodes, e.g. MIS contacts
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- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D12/00—Bipolar devices controlled by the field effect, e.g. insulated-gate bipolar transistors [IGBT]
- H10D12/01—Manufacture or treatment
- H10D12/031—Manufacture or treatment of IGBTs
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/64—Double-diffused metal-oxide semiconductor [DMOS] FETs
- H10D30/66—Vertical DMOS [VDMOS] FETs
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/80—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials
- H10D62/83—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge
- H10D62/832—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge being Group IV materials comprising two or more elements, e.g. SiGe
- H10D62/8325—Silicon carbide
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- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
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Description
まず、実施の形態1におけるMOSFETについて説明する。図1を参照して、実施の形態1におけるMOSFET100は、炭化珪素(SiC)からなり、導電型がn型(第1導電型)の基板であるn+SiC基板11と、SiCからなり、導電型がn型(第1導電型)の半導体層としてのn−SiC層12と、導電型がp型(第2導電型)の第2導電型領域としての一対のpボディ13と、導電型がn型(第1導電型)の高濃度第1導電型領域としてのn+ソース領域14と、導電型がp型(第2導電型)の高濃度第2導電型領域としてのp+領域18とを備えている。n+SiC基板11は、高濃度のn型不純物(導電型がn型である不純物)、たとえばN(窒素)を含んでいる。
図13を参照して、実施の形態2におけるMOSFET300は、MOSFET100と基本的に同様の構成を備えている。しかしMOSFET300においては、MOSFET100におけるゲート酸化膜15が、SixNyから形成されるゲート絶縁膜150となっている。
図21を参照して、実施の形態3におけるMOSFET400は、MOSFET100と基本的に同様の構成を備えている。しかしMOSFET400においては、層間絶縁膜がSiO2からなる層間絶縁膜21と、SixNyからなる層間絶縁膜210との二重構造となっている。
図28を参照して、実施の形態4におけるMOSFET500は、MOSFET400と基本的に同様の構成を備えている。しかしMOSFET500においては、たとえば上述したMOSFET300と同様に、ゲート酸化膜15の左右方向に関する長さが、ゲート電極17よりも長く、SiO2からなる層間絶縁膜21の左右方向に関する長さに等しくなっている。そして当該ゲート酸化膜15の左右方向の端部はSixNyからなる層間絶縁膜210と接触している。
図35を参照して、実施の形態5におけるMOSFET600は、上述した各実施の形態のMOSFETと基本的に同様の構成を備えている。しかしMOSFET600においては、SixNyからなる層間絶縁膜210の外周を覆うようにバリア層60が配置されている。当該バリア層60は、ソースコンタクト電極16とゲート酸化膜15との間にも配置されている。この点において、MOSFET600は上述した他のMOSFETと異なる。
図41を参照して、実施の形態6におけるMOSFET700は、MOSFET600と基本的に同様の構成を備えている。しかしMOSFET700においては、ソースコンタクト電極16とバリア層60とが不連続となっており、両者の間に間隙32が存在する。この点においてのみ、MOSFET700はMOSFET600と異なる。
ち実施の形態6について、上述しなかった構成や条件、手順や効果などは、全て実施の形態5に順ずる。
実施の形態7におけるMOSFET800は、図44を参照して、基本的にはMOSFET600と同様の態様を備えている。しかしMOSFET800においては、たとえばSixNyからなる層間絶縁膜210の代わりに、SiO2からなる層間絶縁膜21が用いられている。MOSFET800は、以上の点についてのみMOSFET600と異なる。同様に、当実施の形態7におけるMOSFET900は、図45を参照して、基本的にはMOSFET700と同様の態様を備えている。しかしMOSFET900においては、たとえばSixNyからなる層間絶縁膜210の代わりに、SiO2からなる層間絶縁膜21が用いられている。MOSFET900は、以上の点についてのみMOSFET700と異なる。
Claims (3)
- SiC層と、
前記SiC層の主表面上に形成され、Alを含む1つの合金層からなるオーミック電極と、
前記SiC層の前記主表面上において前記オーミック電極と間隔を隔てて配置された他の電極と、
前記オーミック電極と前記他の電極との間に位置し、SiO 2 以外の材質から形成される絶縁層と、
前記SiC層の内部に形成された第1導電型の第1不純物領域および第2導電型の第2不純物領域とを備え、
前記オーミック電極は、前記第1不純物領域および前記第2不純物領域の双方に対してオーミック接合可能であり、
前記オーミック電極は、前記SiC層の主表面に垂直な方向から見て前記第1不純物層および前記第2不純物層の双方にオーバーラップするように形成され、
前記オーミック電極と前記絶縁層とが隣接した状態で1200℃以下の加熱を行った場合での、前記絶縁層における電気抵抗の低下率が5%以下であり、
前記絶縁層における電気抵抗の低下率は、(a−b)/aという計算式により規定され、
aは1200℃以下の加熱を行なう前の絶縁層の電気抵抗値を、bは1200℃以下の加熱を行なった後の絶縁層の電気抵抗値を表示する、半導体装置。 - 前記絶縁層は前記オーミック電極と前記他の電極とを電気的に絶縁するための層間絶縁膜であり、前記層間絶縁膜の少なくとも前記オーミック電極に対向する表面は、窒化珪素または酸窒化珪素からなる、請求項1に記載の半導体装置。
- 前記半導体装置は前記SiC層と前記他の電極との間に厚みが30nm以上100nm以下の極薄絶縁膜をさらに備えており、
前記極薄絶縁膜および前記絶縁層と前記オーミック電極との間に間隙が配置されている、請求項1または請求項2に記載の半導体装置。
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JP2011518619A JP5682556B2 (ja) | 2009-10-05 | 2010-07-08 | 半導体装置 |
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JP2009231647 | 2009-10-05 | ||
JP2009231647 | 2009-10-05 | ||
JP2011518619A JP5682556B2 (ja) | 2009-10-05 | 2010-07-08 | 半導体装置 |
PCT/JP2010/061613 WO2011043116A1 (ja) | 2009-10-05 | 2010-07-08 | 半導体装置 |
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JPWO2011043116A1 JPWO2011043116A1 (ja) | 2013-03-04 |
JP5682556B2 true JP5682556B2 (ja) | 2015-03-11 |
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US (1) | US8963163B2 (ja) |
EP (1) | EP2487720A4 (ja) |
JP (1) | JP5682556B2 (ja) |
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JP4858791B2 (ja) * | 2009-05-22 | 2012-01-18 | 住友電気工業株式会社 | 半導体装置およびその製造方法 |
JP5728954B2 (ja) * | 2011-01-13 | 2015-06-03 | 住友電気工業株式会社 | 炭化珪素半導体装置の製造方法 |
JP2013122982A (ja) * | 2011-12-12 | 2013-06-20 | Sumitomo Electric Ind Ltd | 半導体装置の製造方法 |
JP6261155B2 (ja) * | 2012-02-20 | 2018-01-17 | 富士電機株式会社 | SiC半導体デバイスの製造方法 |
KR101386119B1 (ko) * | 2012-07-26 | 2014-04-21 | 한국전기연구원 | SiC MOSFET의 오믹 접합 형성방법 |
JP2014038899A (ja) * | 2012-08-13 | 2014-02-27 | Sumitomo Electric Ind Ltd | 炭化珪素半導体装置およびその製造方法 |
JP6068918B2 (ja) * | 2012-10-15 | 2017-01-25 | 住友電気工業株式会社 | 半導体装置およびその製造方法 |
CN104704611B (zh) * | 2013-10-08 | 2017-04-05 | 新电元工业株式会社 | 碳化硅半导体装置的制造方法 |
JP2016081995A (ja) * | 2014-10-14 | 2016-05-16 | 住友電気工業株式会社 | 炭化珪素半導体装置の製造方法および炭化珪素半導体装置 |
JP6690985B2 (ja) * | 2016-02-24 | 2020-04-28 | 株式会社神戸製鋼所 | オーミック電極 |
CN109524456A (zh) * | 2018-11-19 | 2019-03-26 | 中国电子科技集团公司第十三研究所 | 适用于高温的碳化硅欧姆接触制作方法及碳化硅功率器件 |
IT202300001455A1 (it) * | 2023-01-31 | 2024-07-31 | St Microelectronics Int Nv | Dispositivo mosfet di potenza con protezione dagli agenti contaminanti e relativo processo di fabbricazione |
JP2024155630A (ja) * | 2023-04-21 | 2024-10-31 | ミネベアパワーデバイス株式会社 | 半導体装置および半導体装置の製造方法 |
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JP2002093742A (ja) * | 2000-09-18 | 2002-03-29 | National Institute Of Advanced Industrial & Technology | オーミック電極構造体、その製造方法、半導体装置及び半導体装置の製造方法 |
JP2008192691A (ja) * | 2007-02-01 | 2008-08-21 | Denso Corp | 炭化珪素半導体装置およびその製造方法 |
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JPH10173169A (ja) | 1996-12-16 | 1998-06-26 | Toshiba Corp | 半導体装置及びその製造方法 |
JP4003296B2 (ja) * | 1998-06-22 | 2007-11-07 | 株式会社デンソー | 炭化珪素半導体装置及びその製造方法 |
US6686616B1 (en) | 2000-05-10 | 2004-02-03 | Cree, Inc. | Silicon carbide metal-semiconductor field effect transistors |
JP3952978B2 (ja) * | 2003-03-24 | 2007-08-01 | 日産自動車株式会社 | 炭化珪素半導体素子 |
JP2005276978A (ja) * | 2004-03-24 | 2005-10-06 | Nissan Motor Co Ltd | オーミック電極構造体の製造方法、オーミック電極構造体、半導体装置の製造方法および半導体装置 |
WO2009013886A1 (ja) * | 2007-07-20 | 2009-01-29 | Panasonic Corporation | 炭化珪素半導体装置およびその製造方法 |
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WO2011043116A1 (ja) | 2011-04-14 |
KR20120065962A (ko) | 2012-06-21 |
TW201133835A (en) | 2011-10-01 |
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EP2487720A4 (en) | 2014-01-01 |
US20110227096A1 (en) | 2011-09-22 |
JPWO2011043116A1 (ja) | 2013-03-04 |
CN102227812A (zh) | 2011-10-26 |
US8963163B2 (en) | 2015-02-24 |
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