JP5026802B2 - Hair cosmetics - Google Patents

Description

  The present invention relates to a hair cosmetic that does not wash away.

  In recent years, due to the chemical treatment with hair color and the physical treatment with blow, etc., peeling of the cuticle on the hair surface and hollowing out of the hair due to the outflow of lipid inside the hair, etc., as a result, the hair becomes dry. It is said that bad fingering, loose hair, and loss of gloss occur.

  As a hair cosmetic of the type that is mainly used at present, hair that contains oils such as waxes and higher alcohols, surfactants, etc. in order to impart cohesiveness to the hair and prevent hair loss. There are emulsified products such as cream type, or gel containing a film-forming polymer (set polymer). Such a hair cosmetic can attach fats and oils and polymers to the hair surface and temporarily solve problems such as poor cohesiveness and dryness, but essentially prevents hair gloss and cohesiveness. It could not be improved.

  Several hair cosmetics aimed at modifying the hair are known, but those using specific organic acids and organic solvents are known as attempts to modify the hair by working inside it. (For example, see Patent Documents 1 to 4). These soften hard and hard-to-handle hair and promote hair unity.

Japanese Patent Laid-Open No. 7-112921 JP-A-6-172131 Japanese Patent Laid-Open No. 9-301831 JP-A-62-298625

  An object of the present invention is to provide a hair cosmetic of a type that does not wash away, which is essentially improved hair, improves the gloss, cohesiveness, and firmness of the hair, and has an excellent feel.

  The present inventors further added beeswax and / or sunflower oil to a hair cosmetic containing a specific organic dicarboxylic acid or a salt thereof and a specific organic solvent, thereby improving setability, hair-modifying effect, and drying. It was found that the smooth feel and gloss of the time improved significantly.

That is, the present invention includes the following components (A), (B), (C), (D) and (E)
(A) C2-C8 organic dicarboxylic acid or salt thereof which may have a hydroxy group
(B) An organic solvent selected from the group consisting of aromatic alcohol, N-alkylpyrrolidone, alkylene carbonate, propylene glycol, lactone and cyclic ketone, wherein ClogP is −2 to 3.
(C) Beeswax and / or sunflower oil
(D) Surfactant
(E) The present invention provides a non-washing-type hair cosmetic containing water and having a pH of 2 to 5 at 25 ° C. when diluted 20 times by weight with water.

  Furthermore, this invention provides the hair modification method which processes hair using the said hair cosmetics.

  The hair cosmetic composition of the present invention is damaged by repeated coloring, perm, and dryer drying, and can impart gloss, cohesion, suppleness and firmness to hair that tends to dry and dry.

  Examples of the organic dicarboxylic acid having 2 to 8 carbon atoms as component (A) include malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid and the like. Among these, malic acid and tartaric acid which are hydroxydicarboxylic acids, and malonic acid and succinic acid which are dicarboxylic acids having no hydroxy group are preferable, and malic acid is particularly preferable. Examples of salts of these organic dicarboxylic acids include salts with alkali metals, alkaline earth metals, ammonia, and organic amine compounds.

  Two or more kinds of these components (A) may be used in combination, and the content thereof is the hair makeup of the present invention from the viewpoint of the effect of internal modification (such as cavity repair) of hair, the effect of improving set retention, and the effect of improving unity. The content is preferably 0.01 to 30% by weight, more preferably 0.1 to 20% by weight, and particularly preferably 0.5 to 10% by weight.

  Examples of the organic solvent of component (B) include those selected from the following (b1) to (b5).

  (b1) Aromatic alcohol represented by general formula (1)

[Wherein R ¹ represents a group R ² —Ph—R ³ — (R ² ; a hydrogen atom, a methyl group or a methoxy group, R ³ ; a bond or a saturated or unsaturated divalent carbon atom having 1 to 3 carbon atoms. Hydrogen group, Ph; paraphenylene group), at least one hydroxyl group of Y and Z, the remainder represents a hydrogen atom, and p, q, and r represent integers of 0 to 5. ]

(b2) N-alkylpyrrolidone having a C1-C18 alkyl group bonded to a nitrogen atom

(b3) C3-4 alkylene carbonate

(b4) Propylene glycol

(b5) Lactone or cyclic ketone represented by general formula (2), (3) or (4)

[Wherein, X represents a methylene group or an oxygen atom, R ⁴ and R ⁵ represent different substituents, and a and b represent 0 or 1. ]

Among the organic solvents that are component (B), examples of (b1) include benzyl alcohol, cinnamyl alcohol, phenethyl alcohol, p-anisyl alcohol, p-methylbenzyl alcohol, phenoxyethanol, 2-benzyloxyethanol and the like. . Examples of (b2) include N-methylpyrrolidone, N-octylpyrrolidone, N-laurylpyrrolidone and the like. Examples of (b3) include ethylene carbonate and propylene carbonate. In (b5), R ⁴ and R ⁵ in the general formulas (2) to (4) are linear, branched or cyclic alkyl groups, hydroxyl groups, sulfonic acid groups, phosphoric acid groups, carboxy groups, phenyl groups. , A sulfoalkyl group, an alkyl phosphate group, a carboxyalkyl group, etc. are preferable. In particular, in the case of γ-lactone, the γ-position is substituted, and in the case of δ-lactone, the δ-position (that is, the methylene adjacent to the hetero oxygen atom) is substituted. C1-C6 linear or branched alkyl groups such as methyl, ethyl, propyl, isopropyl and butyl groups are preferred. When it is desired to increase the water solubility of the compounds (2) to (4), R ⁴ or R ⁵ has an acidic group such as a sulfonic acid group, a phosphoric acid group or a carboxy group, or an alkyl group substituted with these. Is preferred. Among (b5), examples of the lactone include γ-butyrolactone, γ-caprolactone, γ-valerolactone, δ-valerolactone, δ-caprolactone, δ-heptanolactone, and the like, from the viewpoint of lactone stability. Γ-lactone, particularly γ-butyrolactone and γ-caprolactone are preferred. Among (b5), examples of the cyclic ketone include cyclopentanone, cyclohexanone, cycloheptanone, 4-methylcycloheptanone and the like.

  Particularly preferred components (B) include benzyl alcohol, benzyloxyethanol, propylene carbonate and propylene glycol.

  The component (B) used in the present invention is required to have a ClogP of −2 to 3, and is preferably −1 to 2 from the viewpoint of promoting penetration. Here, ClogP is a calculated value of the octanol-water-partition coefficient (logP) defined by the following formula, which is a measure representing the distribution of substances between the octanol phase and the water phase. An example is described in Vol. 71, No. 6 (1971).

logP = log ([Substance] _Octanol / [Substance] _Water )

[In the formula, [Substance] _Octanol represents the molar concentration of the substance in the 1-octanol phase, and [Substance] _Water represents the molar concentration of the substance in the aqueous phase. ]

  Specifically, ClogP of the main component (B) is benzyl alcohol (1.1), 2-benzyloxyethanol (1.2), 2-phenylethanol (1.2), 1-phenoxy-2-propanol (1.1), propylene Glycol (-0.92), propylene carbonate (-0.41), and γ-butyrolactone (-0.64).

  Component (B) is preferably liquid at 25 ° C., and two or more kinds may be used in combination. In addition, the content is preferably 0.1 to 40% by weight in the hair cosmetic composition of the present invention, from the viewpoint of feeling of use, hair gloss and promotion of modification effect (improvement of elasticity, improvement of moisture resistance, etc.) Is preferably 0.5 to 10% by weight, particularly 1 to 5% by weight.

  In order to promote the hair modification effect, the weight ratio of the components (A) and (B) is preferably 5: 1 to 1: 2, particularly 3: 1 to 2: 1.

  Beeswax of component (C) is a component that can increase the water retention of hair and suppress puffiness, and if it is necessary to be white, such as when the dosage form is a cream, use white beeswax Is preferred. Sunflower oil can improve the slipperiness and cohesiveness of the hair, and can suppress the floating hair and the hair from the hair surface. Beeswax and sunflower oil can be used either alone or in combination, and it is particularly preferable to use both in combination. The content as the component (C) is preferably 0.0001 to 10% by weight, more preferably 0.005 to 3% by weight, and particularly preferably 0.01 to 1% by weight in the hair cosmetic composition of the present invention. In addition, when using beeswax and sunflower oil in combination, beeswax: sunflower oil (weight ratio) is 1:10 to 10: 1, particularly 1: 5 to 5 in that both effects are effectively exhibited. A range of: 1 is preferred.

  The surfactant of component (D) is blended from the viewpoints of system stability including solubilization and dispersibility of the solvent, and improvement in feel. As the surfactant, any of a cationic surfactant, a nonionic surfactant, an amphoteric surfactant, and an anionic surfactant can be used.

  Examples of the cationic surfactant include quaternary ammonium salts represented by the following general formula (5).

[In the formula, R ⁶ and R ⁷ each independently represent a hydrogen atom, an alkyl group having 1 to 28 carbon atoms or a benzyl group, and simultaneously become a hydrogen atom or a benzyl group; Except when it becomes an alkyl group. A ⁻ represents an anion. ]

Here, one of R ⁶ and R ⁷ is preferably an alkyl group having 16 to 24 carbon atoms, more preferably 22 alkyl groups, particularly a linear alkyl group, and the other is a lower alkyl group having 1 to 3 carbon atoms, particularly A methyl group is preferred. Examples of the anion A ⁻ include halide ions such as chloride ions and bromide ions; organic anions such as ethyl sulfate ions and methyl carbonate ions, and halide ions, particularly chloride ions are preferable.

  As the cationic surfactant, mono long-chain alkyl quaternary ammonium salts are preferable, and specific examples include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, aralkyltrimethylammonium chloride, and behenyltrimethylammonium chloride. Stearyl trimethyl ammonium and behenyl trimethyl ammonium chloride are preferable.

  Nonionic surfactants include polyoxyalkylene alkyl ether, polyoxyalkylene alkenyl ether, higher fatty acid sucrose ester, polyglycerin fatty acid ester, higher fatty acid mono- or diethanolamide, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan fatty acid Examples thereof include esters, polyoxyethylene sorbite fatty acid esters, alkyl saccharide surfactants, alkyl amine oxides, and alkyl amido amine oxides. Of these, polyoxyalkylene alkyl ether and polyoxyethylene hydrogenated castor oil are preferable, and polyoxyethylene alkyl ether is particularly preferable.

  Examples of amphoteric surfactants include imidazoline series, carbobetaine series, amide betaine series, sulfobetaine series, hydroxysulfobetaine series, and amide sulfobetaine series.

  Anionic surfactants include alkyl benzene sulfonates, alkyl or alkenyl ether sulfates, alkyl or alkenyl sulfates, olefin sulfonates, alkane sulfonates, saturated or unsaturated fatty acid salts, alkyl or alkenyl ether carboxylates, Examples include α-sulfone fatty acid salts, N-acyl amino acid type surfactants, phosphate mono- or diester type surfactants, and sulfosuccinate esters. Counter ions of the anionic residue of the surfactant include alkali metal ions such as sodium ion and potassium ion; alkaline earth metal ions such as calcium ion and magnesium ion; ammonium ion; alkanol group having 2 or 3 carbon atoms Alkanolamine having 1 to 3 (for example, monoethanolamine, diethanolamine, triethanolamine, triisopropanolamine, etc.). Examples of the counter ion of the cationic residue include halide ions such as chloride ion, bromide ion and iodide ion, methosulphate ion and saccharinate ion.

  Of these, cationic surfactants are preferred from the viewpoint of feel. The surfactant can be used alone or in combination of two or more, and from the viewpoint of the stability of the system including solubilization of the solvent and emulsification of the oil agent, the content thereof is in the hair cosmetic composition of the present invention. 0.01 to 10% by weight, particularly 0.05 to 3% by weight is preferred.

  Furthermore, the hair cosmetic composition of the present invention can contain ethanol. Ethanol contributes to solubilization or stable dispersion of component (B). Furthermore, it contributes to the solubilization of component (A), which promotes penetration into the hair. The content of ethanol is preferably 0.01 to 90% by weight, particularly 1 to 20% by weight in the hair cosmetic composition of the present invention.

  The hair cosmetic composition of the present invention further contains a set polymer from the viewpoints of improving hair styling, adjusting viscosity, stability, improving adhesion at the time of applying hair, improving touch, and early expression of hair modification effects. May be. Such polymers include polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, vinylpyrrolidone / vinyl acetate / vinyl propionate terpolymer, vinylpyrrolidone / alkylaminoacrylate (quaternary chloride) copolymer, vinyl Polyvinyl pyrrolidone polymer compounds such as pyrrolidone / acrylate / (meth) acrylic acid copolymer, vinyl pyrrolidone / alkyl amino acrylate / vinyl caprolactam copolymer; acidic vinyl ether such as methyl vinyl ether / alkyl maleic anhydride alkyl half ester copolymer Polymer compounds; acidic polyvinyl acetate polymer compounds such as vinyl acetate / crotonic acid copolymer, vinyl acetate / crotonic acid / vinyl neodecanoate copolymer, vinyl acetate / crotonic acid / vinyl propionate copolymer; Acid acrylic polymer such as (meth) acrylic acid / (meth) acrylic acid ester copolymer, acrylic acid / acrylic acid alkyl ester / alkylacrylamide copolymer; N-methacryloylethyl-N, N-dimethylammonium α Amphoteric acrylic polymer compounds such as -N-methylcarboxybetaine / butyl methacrylate copolymer, hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer; acrylamide / acrylic ester quaternary copolymer Examples include basic acrylic polymer compounds such as coalescence; cellulose derivatives such as cationic cellulose derivatives; chitin / chitosan derivatives such as hydroxypropyl chitosan, carboxymethyl chitin, and carboxymethyl chitosan.

  These set polymers can be used alone or in combination of two or more, and the content thereof is preferably 0.1 to 10% by weight, particularly 0.5 to 5% by weight in the hair cosmetic composition of the present invention.

The hair cosmetic composition of the present invention may contain a conditioning component selected from oils other than silicones and component (C) in order to further improve the conditioning effect. Silicones include dimethylpolysiloxane, polyether-modified silicone, amino-modified silicone, carboxy-modified silicone, methylphenylpolysiloxane, fatty acid-modified silicone, alcohol-modified silicone, aliphatic alcohol-modified silicone, epoxy-modified silicone, fluorine-modified silicone, cyclic Examples include silicone and alkyl-modified silicone. Of these, dimethylpolysiloxane, polyether-modified silicone, and amino-modified silicone are preferable. Dimethylpolysiloxane can impart good lubricity to hair, polyether-modified silicone can impart smoothness to hair, and amino-modified silicone can impart moist feeling to hair. . In the present invention, various silicones can be used alone or in combination of two or more depending on the desired performance. Dimethylpolysiloxane can be used from a viscosity of about 5 mm ² / s depending on the desired feel to a viscosity of about 10 million mm ² / s, which is often supplied as an emulsion. It is preferably mm ² / s, particularly 50,000 to 10 million mm ² / s. Polyether-modified silicone is a general term for polyoxyethylene / methylpolysiloxane copolymer and poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer, and those having various HLBs are known, but are commercially available. Examples of the products include Silicone KF351A, KF353A, KF6008, KF6016, KF6011, and KF6012, Shin-Etsu Chemical Co., Ltd., SH3771C, 3773C, and 3775C from Toray Dow Corning. The amino-modified silicone is preferably amodimethicone oil or an emulsion thereof, and commercially available products include Amodimethicone emulsion SM8704C manufactured by Toray Dow Corning, KT-1989, and XF42-B1989 manufactured by Toshiba Silicone.

  The content of the silicone is preferably 0.05 to 20% by weight, more preferably 0.1 to 10% by weight, particularly 0.5 to 5% by weight in the hair cosmetic composition of the present invention, from the viewpoints of fingering and lack of stickiness. Is preferred.

  Oils are used to improve the feeling of hair unity after drying. Oils include hydrocarbons such as squalene, squalane, liquid isoparaffin, light liquid isoparaffin, heavy liquid isoparaffin, α-olefin oligomer, liquid paraffin, cycloparaffin; castor oil, cacao oil, mink oil, avocado oil, olive oil, etc. Glycerides; waxes such as whale wax, lanolin, microcrystalline wax, ceresin wax, carnauba wax; higher alcohols such as cetyl alcohol, oleyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecanol; octyldodecyl myristate Hexyl laurate, cetyl lactate, propylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, isononyl isononanoate, tridecyl isononanoate Esters such as capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, coconut oil fatty acid, isostearyl acid, isopalmitic acid and other higher fatty acids; other isostearyl glyceryl ether, poly And oxypropylene butyl ether. Among these, branched hydrocarbons such as squalene, squalane, liquid isoparaffin, light liquid isoparaffin, heavy liquid isoparaffin, and α-olefin oligomer are particularly preferable.

  The content of the oil is preferably 0.05 to 20% by weight, more preferably 0.1 to 10% by weight, particularly 0.5 to 5% by weight in the hair cosmetic composition of the present invention, from the viewpoint of good unity and no stickiness. Is preferred.

  Furthermore, the hair cosmetic composition of the present invention can contain a polyhydric alcohol. The polyhydric alcohol contributes to the solubilization and stable dispersion of the component (B), and works synergistically with the component (B) to promote the improvement of gloss and hair modification effects. Examples of the polyhydric alcohol include ethylene glycol, glycerin, sorbitol, 1,3-butylene glycol, dipropylene glycol and the like, and glycerin is particularly preferable. The polyhydric alcohol can be used alone or in combination of two or more, and the content thereof is preferably 0.1 to 10% by weight, particularly preferably 0.5 to 5% by weight in the hair cosmetic composition of the present invention.

  In addition to the above-described components, the hair cosmetic of the present invention can be appropriately mixed with components used in normal hair cosmetics depending on the purpose. Examples of such components include anti-dandruff agents; vitamin agents; bactericides; anti-inflammatory agents; antiseptics; chelating agents; moisturizers such as sorbitol and panthenol; colorants such as dyes and pigments; hydroxyethyl cellulose, methyl cellulose, Viscosity modifiers such as polyethylene glycol and clay minerals; pH adjusters such as organic acids other than component (A), sodium hydroxide, potassium hydroxide; plant extracts; pearling agents; fragrances; dyes; Inhibitors; and other components described in ENCYCLOPEDIA OF SHAMPOO INGREDIENTS (MICELLE PRESS).

  The hair cosmetic composition of the present invention promotes the permeation and adsorption of the components (A) and (B) into the hair, and is applied to the hair from the viewpoint of imparting gloss, flexibility, cohesion and suppleness to the hair. The pH (when diluted 20 times by weight, 25 ° C.) is adjusted to 2 to 5, preferably pH 2.5 to 4, particularly pH 3 to 4.

  The form of the hair cosmetic composition of the present invention can be appropriately selected from liquid form, gel form, paste form, cream form, wax form and the like, but as a medium, in addition to the water of component (E), lower alcohols such as ethanol and isopropanol It is also preferable to use.

  The hair cosmetic composition of the present invention is preferably used as a hair styling agent, hair conditioning agent or the like. Examples of the dosage form include pump spray, aerosol spray, pump foam, aerosol foam, gel, lotion and the like.

  Furthermore, the penetration of the components (A) and (B) into the hair can be promoted by heating after applying the hair cosmetic composition of the present invention to the hair. For heating, a dryer, heater, iron or the like can be used. The temperature is preferably 60 ° C. or higher, particularly 70 ° C. or higher.

  In the following examples, pH indicates a value at 25 ° C. when diluted 20 times by weight with water.

Example 1
The hair cosmetics shown in Table 2 were prepared, and “Setability”, “Hariness / Stiffness Improvement Effect”, “Smoothness”, “Feel”, “Suppression of floating hairs”, “Glossy” and “Continuation of set” Evaluation of “sex” was performed. These results are shown in Table 2.

(Evaluation methods)
Evaluation of “Setability” and “Setability” 1) Evaluation hair bundle Using hair of a Japanese woman who has not been subjected to chemical treatment such as perm and hair color, it is 10cm long, 1.5cm wide and 1g in weight. Make a hair bundle and perform bleach treatment (Kaosha, PRETTIA Happy Fantasy Bleach Hybrid) twice to make a set evaluation hair bundle.

2) Treatment of hair bundles ・ Evaluation before washing (7 times treatment)
After shampooing the evaluation hair bundle (Kao Co., pure skin cleansing shampoo), towel drying, 0.1 g of the product of the present invention or a comparative product (hereinafter referred to as “treatment agent”) is uniformly applied and heated with a warm air of 70 ° C. Let dry for minutes. This process was repeated a total of 6 times. Next, after applying shampoo, towel drying and treatment agent in the same manner as described above, the hair bundle was wound around a cylinder having a diameter of 4 cm and dried with hot air at 70 ° C. for 10 minutes.

-Evaluation after hair washing By evaluating the set retention after washing the treatment agent on the hair surface, the effect of modifying the inside of the hair was examined. After completion of the pre-shampoo evaluation, each hair bundle was shampooed and towel-dried, wound around a 4 cm diameter cylinder without a treatment agent, and dried with hot air at 70 ° C. for 10 minutes.

・ Evaluation of shampoo durability (Evaluation of the durability of the set after 3 washings)
In order to evaluate the sustainability (shampoo resistance) of the modification effect inside the hair, the set retention after repeated washing (shampoo 3 times) was evaluated. Each hair bundle evaluated after the hair washing was shampooed and towel-dried, and dried for 10 minutes with warm air at 70 ° C. without applying a treatment agent. Furthermore, it was shampooed and towel-dried, wound around a cylinder with a diameter of 4 cm without applying a treatment agent, and dried for 10 minutes with hot air at 70 ° C.

3) Evaluation procedure and criteria The set hair bundle was removed from the cylinder, and the hair bundle was separated by passing the comb (ring comb) 20 times. This was suspended in a constant temperature and humidity box (25 ° C., 98% RH), and the set holding power was judged. Judgment measures the length of the suspended hair bundle (distance from the bundled part to the tip of the hair) and sets the length of the hair bundle just after hanging the set retention rate 100%, the original hair bundle without curl The length (10 cm) was set at a set retention rate of 0%, and the relative value (%) of the length of the hair bundle after 30 minutes, that is, the set retention rate was determined by the following formula.

"Hariness and firmness improvement effect", "Smoothness", "Feeling (smoothness, moistness, softness, stickiness, stickiness)", "Suppression of floating hair" and "Glossy" 1) Evaluation hair bundle Using a Japanese woman's hair that has not undergone chemical treatment such as perm and hair color, make a hair bundle of 25cm in length and 6g in weight, and then bleaching treatment (using Kao, PRETIA Happy Fantasy Bleach Hybrid) Repeat to make the evaluation hair bundle.

2) Treatment of hair bundles ・ Evaluation before shampooing After shampooing the evaluation hair bundle (Kao Co., pure skin cleansing shampoo), towel-drying, uniformly apply 0.6 g of the treatment agent, and apply ring comb with warm air at 70 ° C. Used to dry for 10 minutes while combing. This process was repeated a total of 7 times.

・ Evaluation after hair washing In order to examine the effect of modifying the inside of the hair, each hair bundle for which the above pre-wash evaluation has been completed is shampooed, towel-dried, and combed using a ring comb with hot air of 70 ° C. for 10 minutes. Dried.

3) Evaluation criteria Sensory evaluation was performed according to the criteria shown in Table 1 by five expert panelists, and the average value of the evaluation points is shown in Table 2.

  From the above results, it can be confirmed that the present invention can achieve a good setting property, a firmness and stiffness improvement effect, a cohesiveness, and a feeling improvement effect without being stiff or sticky like the existing technology. It was. In addition to the removal of surface adhering components by shampooing, the effect persists, and the effects of hair modification, such as the absence of cavities inside the hair and the high unit retention under high humidity, can also be confirmed. It was.

Example 2 (pump spray)
(weight%)
Malic acid 4.0
Stearyl trimethyl ammonium chloride 0.5
Cetanol 0.8
Glycerin 1.0
Benzyl alcohol 2.5
Ethanol 5.0
White beeswax 0.1
Sunflower oil 0.5
Perfume 0.02
Residual amount of water Sodium hydroxide (pH adjuster) Adjusted to pH 3.7

Example 3 (Aerosol Mist)
(weight%)
Stock solution Malic acid 0.5
Malonic acid 0.5
Stearyltrimethylammonium chloride 0.2
Benzyl alcohol 1.0
Polyvinylpyrrolidone 1.0
Sara beeswax 2.0
Fragrance 0.05
Water 2.0
Ethanol remaining
Sodium hydroxide (pH adjuster) Adjustable to pH 3.7 40.0
Propellant
LPG gas (0.25 MPa) 60.0

Example 4 (hair gel)
(weight%)
Malic acid 2.5
Succinic acid 1.5
Sorbitan monostearate0.5
Sodium polyoxyethylene lauryl ether phosphate (4E.O.) 0.5
Carrageenan 0.5
Cetanol 3.0
Glycerin 5.0
Dipropylene glycol 2.0
Benzyloxyethanol 2.5
Hydroxyethyl cellulose 2.0
Ethanol 10.0
Sarah Beeswax 1.0
Fragrance 0.05
Residual amount of water Sodium hydroxide (pH adjuster) Adjusted to pH 3.7

Example 5 (hair cream)
Malic acid 1.0
Lactic acid 1.0
Benzyl alcohol 0.5
Polyoxyethylene stearyl ether (12E.O.) 7.0
Glycerin 5.0
Sara honey bees 3.0
Liquid paraffin 35.0
Perfume 0.03
Residual amount of water Sodium hydroxide (pH adjuster) Adjusted to pH 3.7

Example 6 (hair treatment)
(weight%)
Malic acid 0.5
Lactic acid 0.5
Benzyl alcohol 2.5
Stearyltrimethylammonium chloride 0.4
Cetanol 1.5
Sorbitan stearate 1.0
Isopropyl palmitate 3.0
Sarah Beeswax 1.0
Silicone BY22-060 (Toray Dow Corning) 1.5
Residual amount of water Sodium hydroxide (pH adjuster) Adjusted to pH 3.7

Example 7 (pump foam)
(weight%)
Malic acid 2.5
Lactic acid 2.5
Polyoxyethylene lauryl ether (16E.O.) 1.0
Stearyl trimethylammonium chloride 0.1
Glycerin 1.0
1,3-butylene glycol 5.0
Benzyl alcohol 2.5
Ethanol 5.0
Light liquid isoparaffin 5.0
White beeswax 0.2
Sunflower oil 0.5
Perfume 0.02
Residual amount of water Sodium hydroxide (pH adjuster) Adjusted to pH 3.7

Claims (4)

The following components (A), (B), (C), (D) and (E)
(A) C2-C8 organic dicarboxylic acid or salt thereof which may have a hydroxy group
(B) An organic solvent selected from the group consisting of aromatic alcohol, N-alkylpyrrolidone, alkylene carbonate, propylene glycol, lactone and cyclic ketone, wherein ClogP is −2 to 3.
(C) beeswax及Bihi around oil 0.01 to 10 wt%
(D) Surfactant
(E) Containing water, beeswax: sunflower oil (weight ratio) is 1: 5 to 5: 1, and pH is 2 to 5 at 25 ° C. when diluted 20 times by weight with water. Hair cosmetics.   The hair cosmetic according to claim 1, further comprising a conditioning component selected from silicones and oils.   The hair cosmetic composition according to claim 1, wherein (D) is a cationic surfactant.   The hair modification method which processes hair using the hair cosmetics in any one of Claims 1-3.