JP4985148B2 - Method for processing asbestos-containing material using cement manufacturing process - Google Patents

Description

  The present invention relates to a method for treating an asbestos-containing material for detoxifying waste containing asbestos using a cement manufacturing process.

Asbestos (natural asbestos) is a naturally produced mineral fiber that has chemical stability and excellent heat resistance and strength. As materials, it was widely used for building walls, ceilings, floors, air-conditioning equipment, etc.
However, in recent years, this asbestos has no chemical toxicity, but its crystalline structure is acicular, so when inhaled by humans, it accumulates in the lung tissue without being excreted and accumulated for a long period of time. It has been pointed out that it causes serious illnesses.

Therefore, at present, measures are being taken to remove or remove asbestos sprayed on walls and ceilings that may be scattered and asbestos used as heat insulation materials in many buildings. Asbestos is generated as waste.
By the way, this kind of asbestos waste that may be scattered is designated as specially managed industrial waste in the “Waste Disposal and Cleaning Law”, and the processing standards from its discharge to collection, transportation and disposal are established. It has been.

  In addition, in the above processing standards related to collection and transportation, asbestos is stored in a container such as plastic and handled carefully so as not to be scattered due to breakage, etc. It is obliged to take measures. In addition, as a treatment standard related to the above disposal, double packing with water-resistant materials such as plastic bags and containers, or solidification with a sufficient amount of cement etc. and direct landfill disposal at a predetermined place It is stipulated that it is made harmless by a sufficient melting process using a melting method using a melting facility, and then treated as ordinary industrial waste.

  Of these asbestos disposal methods, the former direct landfill method requires a large amount of concrete, and there is concern about the early depletion of landfill sites against the expected emissions. ing. Further, the latter method of detoxifying disposal by intermediate treatment in the melting facility has a problem that it is difficult to completely detoxify asbestos depending on the melting temperature.

  Furthermore, in addition to the asbestos waste that may be scattered as described above, various asbestos wastes such as molded asbestos used as interior materials and roofing materials are also generated when demolishing and renovating old buildings. In addition, it is necessary to pay due consideration to the treatment of these asbestos wastes.

Therefore, in the following Patent Document 1, asbestos (asbestos) waste material pulverized to a maximum particle size of about 10 mm and stored in a hopper is disposed in the vicinity of a burner of a rotary kiln for cement raw material firing using an air pressure ejector. There has been proposed a method for producing cement which is supplied from the waste material supply pipe into the rotary kiln and detoxified.
JP-A-9-86982

  According to the above asbestos waste material processing method according to the prior art, since the heat treatment is performed at a temperature of 1450 ° C. or higher in the firing zone in the rotary kiln, the asbestos can be completely detoxified, and therefore, a landfill treatment or the like is performed. In addition, there is an advantage that the detoxified asbestos can be used as a part of the cement raw material.

  However, in the processing method of asbestos waste material according to the above-described prior art, since the asbestos waste material is pulverized to a maximum particle size of about 10 mm and then supplied into the rotary kiln by compressed air, the above pulverization process and compressed air There is a problem that asbestos is likely to be scattered in the transport process. For this reason, in these processes, it is necessary to take measures similar to the anti-scattering measures at the time of storage and collection / transport separately stipulated in the above law. Therefore, in order to ensure the desired safety, There exists a problem that the processing process of asbestos waste material will become a large-scale thing as a whole.

  The present invention has been made in view of such circumstances, and there is no risk of asbestos scattering from the asbestos-containing material, and thus a cement manufacturing process that can be easily detoxified in a rotary kiln used for cement manufacturing is used. It is an object of the present invention to provide a method for treating an asbestos-containing material.

In order to solve the above-mentioned problems, the invention according to claim 1 is characterized in that the cement raw material is supplied from the kiln bottom side of a rotary kiln whose inside is maintained in a high temperature atmosphere by a heating means provided on the front side of the kiln. A method for treating an asbestos-containing material using a cement manufacturing process that is fired while being sent to the front side, the solvent giving fluidity to the asbestos-containing material , and potassium chloride (KCl) and sodium chloride (NaCl) as main components ) In a molar ratio of KCl / NaCl = 0.5 to 0.9 and pulverized by a wet mill, and the slurry containing the asbestos-containing material pulverized in the wet mill is transferred to the above-mentioned slurry through a transfer pipe. The rotary kiln is supplied to the inside from the front side of the kiln and burned.

In this case, the invention described in claim 2 is characterized in that at least one kind of waste liquid, sludge, and water is used as the solvent.

The invention described in Claim 3 is for the Solvent according to claim 1 or 2, characterized in that the addition of chlorine bypass dust discharged from the cement manufacturing process.

Moreover, invention of Claim 4 supplies the slurry containing the said pulverized said asbestos containing material in the said rotary kiln using compressed air in the invention in any one of Claims 1-3. It is characterized by this.

Furthermore, the invention according to claim 5 is characterized in that, in the wet mill according to any one of claims 1 to 4 , the asbestos-containing material is pulverized to a maximum dimension of 1 mm or less. .

The invention according to claim 6 is the invention according to any one of claims 1 to 5 , wherein the slurry has a viscosity of 10,000 mPa · s or less.

According to the invention according to any one of claims 1 to 6 , since the solvent is added to the asbestos-containing material and pulverized by a wet mill, for example, the scattering scattered in the plastic container in accordance with the above law Asbestos waste that is likely to be crushed can also be crushed by throwing the entire container into the wet mill and crushing the asbestos reliably.

In addition, since it is discharged from the wet mill as a slurry containing pulverized asbestos, by supplying it from the front side of the kiln of the rotary kiln through the transfer pipe to the inside, in the transfer step after pulverization of asbestos, Similarly, there is no risk of asbestos scattering. In addition, a general-purpose pump can be used as the conveying means.
As a result, the rotary kiln can be detoxified easily and reliably without taking additional measures to prevent scattering.

  At this time, if waste liquid, sludge, sewage or the like is used as a solvent for imparting fluidity in addition to the wet mill, the waste can be treated at the same time. And economical.

Further, according to the invention described in claim 1, as the solvent, because using a solvent comprising by mainly potassium chloride (KCl) and sodium chloride (NaCl), these KCl and NaCl, the asbestos as possible out to more efficiently and effectively harmless.

  That is, the inventors prepared samples 1 to 5 of the solvent shown in FIG. 2, mixed with asbestos and placed in an electric furnace in an atmosphere of 650 ° C. to 850 ° C. The fiber structure of was observed. As a result, as shown in the lower column of the figure, it was confirmed that the solvent containing KCl and NaCl as main components can effectively detoxify the asbestos.

  Furthermore, according to the above results, it has been found that a remarkable effect can be obtained particularly in the range of KCl / NaCl = 0.5 to 0.9. This is because, as shown in FIG. 3, when KCl / NaCl = 0.49, there is a minimum melting point, so that the solvent forms a liquid phase around asbestos compared to using KCl and NaCl alone. It is thought that this facilitated the destruction of the fiber structure of asbestos.

  In addition, the cement manufacturing process includes a process of extracting a part of the exhaust gas from the rotary kiln from the chlorine bypass and removing the chlorine component contained in the exhaust gas. And the chlorine bypass dust discharged | emitted from this chlorine bypass contains comparatively much KCl and NaCl.

Therefore, as in the invention described in claim 3 , it is more economical to produce a solvent mainly composed of KCl and NaCl by adding chlorine bypass dust discharged from the cement production process. At this time, in order to obtain the desired KCl / NaCl, when only the NaCl in the chlorine bypass dust is insufficient, it can be adjusted by adding NaCl separately. In addition, the cement manufacturing process which concerns on this claim is not limited to the cement manufacturing process which processes the said asbestos containing material.

Further, since the asbestos-containing material is slurried by the wet mill, even if it is supplied into the rotary kiln using compressed air as in the invention described in claim 4, there is no fear of scattering as described above, and It becomes possible to supply the slurry into the rotary kiln smoothly and in a constant amount.

By the way, when supplying the asbestos-containing material from the front side of the kiln of the rotary kiln, if the supply amount greatly fluctuates, the rotary kiln itself and the quality of the cement produced thereby may be adversely affected.
In contrast, according to the present invention, since the asbestos-containing material is pulverized and slurried together with the solvent by a wet mill, the supply amount per unit time into the rotary kiln can be easily and uniformly maintained. Further, as in the invention of claim 5 , if the asbestos-containing material is pulverized to the maximum dimension of 1 mm or less in the wet mill, the supply amount of the asbestos-containing material can be made uniform and dispersed in the cement raw material. Therefore, the above adverse effects are not caused.

Further, in the invention according to claim 6 , since the viscosity of the slurry is 10000 mPa · s or less, the pulverization step and the transfer step are performed using a general-purpose wet mill or pump without causing any trouble. It can be performed.

FIG. 1 shows a cement production facility used in an embodiment of a method for treating an asbestos-containing material using a cement production process according to the present invention and an asbestos-containing material treatment facility attached thereto.
1, a cement kiln for code 1 is fired cement material. This cement kiln 1 is a rotary kiln provided so as to be rotatable around an axis, and a preheater 3 for preheating the cement raw material is provided in a left kiln bottom portion 2 in the figure, and a right kiln in the figure. A main burner 5 for heating the inside is provided in front of the kiln 4. In addition, the code | symbol 6 in a figure is a clinker cooler for cooling the cement clinker after baking.

  Here, the preheater 3 is composed of a plurality of cyclones arranged in series in the vertical direction, and the cement raw material is supplied to the uppermost cyclone via the supply pipe 7, and the lowermost cyclone Connected to the bottom is a transfer pipe 3 a for sending the internal cement raw material to the kiln bottom part 2 of the cement kiln 1.

On the other hand, in the kiln inlet part 2, the combustion exhaust gas discharged from the cement kiln 1 exhaust gas pipe 3b is provided for supplying to the lowermost cyclone Contact is, the exhaust gas discharged from the top of the uppermost cyclone, Exhaust air (not shown) is exhausted through the exhaust line 8.

And the processing equipment of the asbestos containing material which consists of the following structure is attached to the cement manufacturing equipment which consists of the said structure.
In FIG. 1, reference numeral 10 denotes a hopper into which an asbestos-containing material such as asbestos waste is charged. The lower discharge port of the hopper 10 is connected to the supply side of the wet mill 12 via a large-diameter opening / closing means 11. The wet mill 12 is connected to a solvent supply pipe 13 that supplies at least one of waste liquid, sludge, water, and fluidizing agent as a solvent that gives fluidity to the inside.

  Here, as the solvent, it is more preferable to use a solvent mainly composed of KCl and NaCl by adding potassium chloride (KCl) and sodium chloride (NaCl) to the waste liquid, sludge, water and fluidizing agent. It is. Moreover, when obtaining such a solvent, the chlorine bypass dust discharged | emitted from the chlorine removal process in the cement manufacturing process shown in FIG. 1 or another cement manufacturing process can be used.

On the other hand, one end of a transfer pipe 15 provided with a transfer pump 14 is connected to the discharge side of the wet mill 12, and the other end of the transfer pipe 15 is the front 4 of the rotary kiln 1. And is introduced above the main burner 5.
Further, a compressed air supply pipe 16 is connected to the upstream side of the transfer pipe 15 before the kiln 4. Here, the compressed air supply pipe 16 sprays compressed air in the transfer pipe 15 to the front side of the kiln 4 of the rotary kiln 1 so as to promote the transfer of the slurry in the transfer pipe 15 to the rotary kiln 1 side. So that the pipe is inclined.

Next, an embodiment of the asbestos-containing material processing method according to the present invention using the cement manufacturing facility and the asbestos-containing material processing facility having the above-described configuration will be described.
First, the cement raw material supplied from the supply pipe 7 to the first-stage cyclone of the preheater 3 is preheated by the high-temperature exhaust gas from the cement kiln 1 that rises from below as it sequentially falls to the lower cyclone. In particular, the lowermost cyclone is introduced into the kiln bottom portion 2 of the cement kiln 1 through the transfer pipe 3a.

  And in this cement kiln 1, in the process gradually sent from the kiln bottom part 2 side to the kiln front 4 side, it is heated to about 1450 ° C. by the combustion exhaust gas from the main burner 5 and burned to become a clinker. Next, the clinker that has reached the front 4 is dropped into the clinker cooler 6 and sent to the right in the figure. At this time, the air is cooled to a predetermined temperature by the air supplied into the clinker cooler 6 and finally taken out from the clinker cooler 6.

  In parallel with this, the asbestos waste stored in the plastic container and carried into the cement manufacturing facility is directly fed into the hopper 10 together with the container, and the opening / closing means 11 is opened to supply the wet mill 12. . Further, the waste mill, sludge, water or fluidizing agent for supplying fluidity is supplied into the wet mill 12 by opening the valve 13a of the solvent supply pipe 13.

  And in this wet mill 12, the asbestos waste is pulverized to the maximum dimension of 1 mm or less in a wet manner together with the container. At this time, the viscosity of the slurry composed of the asbestos waste after pulverization and the solvent generated in the wet mill 12 is adjusted to 10000 mPa · s or less. Next, the slurry containing the pulverized asbestos waste discharged from the wet mill 12 is sent to the front kiln 4 side of the rotary kiln 1 through the transfer pipe 15 by the pump 14.

Then, by supplying compressed air from the compressed air supply pipe 16 into the transfer pipe 15, the slurry is ejected from the front 4 side of the rotary kiln 1 to the inside.
Thereby, the asbestos waste is burned at a high temperature of about 2000 ° C. in the vicinity of the flame from the main burner 5 in the rotary kiln 1. As a result, for example, water of crystallization in asbestos, which is a hydrate, is dehydrated and made harmless by changing the mineral composition to make it non-asbestos. Furthermore, it is used as a part of the cement raw material. Further, the water in the slurry is instantly vaporized and exhausted together with the combustion exhaust gas.

  Therefore, according to the asbestos-containing material processing method using the cement manufacturing process having the above-described configuration, the solvent supplied from the solvent supply pipe 13 is added to the asbestos waste charged from the hopper 10 and wetted by the wet mill 12. Since it is pulverized, asbestos waste that has been stored and transported in plastic containers to prevent scattering can be put into the wet mill 12 together with the containers and crushed in a wet manner to ensure asbestos scattering. Therefore, the asbestos can be pulverized.

  Moreover, since it is discharged from the wet mill 12 as a slurry containing pulverized asbestos, the asbestos waste is supplied to the inside from the front 4 side of the rotary kiln 1 through the transfer pipe 15 by the pump 14. Similarly, in the transfer step after crushing, asbestos is not likely to be scattered. In addition, a general-purpose pump 14 can be used as the conveying means.

In addition, since the compressed air is supplied from the compressed air supply pipe 16 and the slurry in the transfer pipe 15 is ejected into the rotary kiln 1, the slurry is supplied to a wide area in the rotary kiln 1 and instantly burned. be able to.
As a result, the rotary kiln can be detoxified easily and reliably without taking additional measures to prevent scattering.

  Further, since the asbestos waste is pulverized together with the solvent by the wet mill 12 and slurried and supplied into the rotary kiln 1, the supply amount per unit time into the rotary kiln 1 can be easily and uniformly maintained. At the same time, since the asbestos waste is pulverized to a maximum dimension of 1 mm or less in the wet mill 12, the non-asbestos-treated product after the combustion treatment can be uniformly dispersed in the cement raw material. There is no negative impact on the quality of the product.

It is a schematic block diagram of the whole installation for demonstrating one Embodiment of this invention. It is a graph which shows the specification of the sample in the experiment conducted in order to confirm the detoxification effect of asbestos by the solvent which has KCl and NaCl as a main component, and its observation result. It is a graph which shows the relationship between KCl / NaCl and melting | fusing point.

Explanation of symbols

1 Rotary kiln 4 In front of kiln 5 Main burner (heating means)
10 Hopper 12 Wet Mill 13 Solvent Supply Pipe 15 Transfer Pipe 16 Compressed Air Supply Pipe

Claims (6)

Treatment of asbestos-containing materials using a cement manufacturing process in which cement raw material is supplied from the kiln bottom side of a rotary kiln whose interior is maintained in a high-temperature atmosphere by heating means provided on the front side of the kiln and fired while being sent to the front side of the kiln A method,
A solvent that imparts fluidity to an asbestos-containing material and that contains potassium chloride (KCl) and sodium chloride (NaCl) as main components in a molar ratio of KCl / NaCl = 0.5 to 0.9. In addition, a cement manufacturing process characterized by pulverizing with a wet mill and supplying the slurry containing the asbestos-containing material pulverized in the wet mill from the front side of the kiln of the rotary kiln to the inside through a transfer pipe for combustion treatment. Processing method of used asbestos-containing material. The said solvent uses at least 1 sort (s) of a waste liquid, sludge, and water, The processing method of the asbestos containing material using the cement manufacturing process of Claim 1 characterized by the above-mentioned. The method for treating an asbestos-containing material using a cement production process according to claim 1 or 2, wherein chlorine bypass dust discharged from the cement production process is added to the solvent. The asbestos-containing material using a cement manufacturing process according to any one of claims 1 to 3, wherein the pulverized slurry containing the asbestos-containing material is supplied into the rotary kiln using compressed air . Processing method. 5. The method for treating asbestos-containing material using a cement manufacturing process according to claim 1, wherein the asbestos-containing material is pulverized to a maximum dimension of 1 mm or less in the wet mill . The slurry is processing method according to claim 1 to asbestos-containing material with a cement manufacturing process according to any one of the 5 viscosity characterized by the following der Rukoto 10000 mPa · s.

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