JP4938018B2 - セラミック基板の製造方法、および、セラミック基板 - Google Patents
セラミック基板の製造方法、および、セラミック基板 Download PDFInfo
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- JP4938018B2 JP4938018B2 JP2008533187A JP2008533187A JP4938018B2 JP 4938018 B2 JP4938018 B2 JP 4938018B2 JP 2008533187 A JP2008533187 A JP 2008533187A JP 2008533187 A JP2008533187 A JP 2008533187A JP 4938018 B2 JP4938018 B2 JP 4938018B2
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- ceramic
- sintered body
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- hole
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/11—Printed elements for providing electric connections to or between printed circuits
- H05K1/115—Via connections; Lands around holes or via connections
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B18/00—Layered products essentially comprising ceramics, e.g. refractory products
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Description
12 セラミックグリーンシート
20 セラミック焼結体層
22 セラミックペースト層
24 孔又は開口部
30 ビアホール
32 金属ペースト
40 導体部
70 導体部上の表面配線パターン
72 外側の配線パターン
100 第1前駆体
110 第2前駆体
200A〜E セラミック基板
まず、図1に基づいて、本発明のセラミック基板の製造方法の概要について説明する。
図1(a)は、セラミックグリーンシート12の所定の位置に穿孔し、金属ペースト32を充填した第1前駆体100の平面図である。図示した形態のセラミックグリーンシート12は、複数のセラミック基板を形成するための母材であり、図示の点線で切断されて、九つのセラミック基板とされる。図1(a)の工程においては、まず、それぞれのセラミック基板の中央部が穿孔され、金属ペーストが充填される。
図2に本発明のセラミック基板の製造方法の各工程の概要を表した模式図を示す。本発明のセラミック基板の製造方法は、ビアホール30を有するセラミック焼結体基板10(第2前駆体110)上に、ポストファイア法により配線パターンとの接続箇所に孔又開口部24を有するセラミック焼結体層20を形成する工程を備えて構成される。より具体的には、ビアホール30を有するセラミック焼結体基板10(第2前駆体110)を形成する工程(図2(a)、(b))、および、セラミック焼結体層20を形成する工程(図2(c)、(d))を備えて構成される。以下、各工程に分けて説明する。
まず、セラミックグリーンシート12の所定の位置に穿孔して貫通孔を形成し、該貫通孔に金属ペースト32を充填して、第1前駆体100を作製する。セラミックグリーンシート12は、セラミック原料粉末、および、必要に応じて、焼結助剤、有機バインダー等が含まれていてもよい原料を、ドクターブレード法等によりシート状に成形して得られる。セラミック原料粉末としては、公知のセラミック材料を特に限定なく使用することができる。例えば、(i)酸化アルミニウム系セラミック、酸化ケイ素系セラミック、酸化カルシウム系セラミック、酸化マグネシウム系セラミック等の酸化物系セラミック;(ii)窒化アルミニウム系セラミック、窒化ケイ素系セラミック、窒化ホウ素系セラミック等の窒化物系セラミック;(iii)酸化ベリリウム、炭化ケイ素、ムライト、ホウケイ酸ガラス等を使用することができる。中でも、(ii)窒化物系セラミックが、そのグリーンシートを焼成した際の変形が激しくビアホールの位置の変化が激しいことから、本発明の効果が顕著であるため好ましく、特に窒化アルミニウム系セラミックが、熱伝導率が高いため好ましく使用することができる。
上記において作製した第2前駆体110の少なくとも一方の面、つまり、精密な表面配線パターンを形成する面には、底面がビアホール30の露出端面の少なくとも一部で構成される孔又は開口部24を有するようにしてセラミックペースト層22を形成して、該セラミックペースト層22を焼成して、セラミック焼結体層20を形成する。
基板200Aの表面が平坦であることが要求される場合は、図2(e)に示すように、孔又は開口部24に金属ペーストを充填し、これを焼成して、導体部40を形成したセラミック基板200Bとすることできる。金属ペーストとしては、上記したビアホール30の形成の際に使用したものと同様のものを使用することができる。
配線パターン52、54、56の形成工程の概要を図3に示した。図3(a)(b)に示すように、孔又は開口部24に導体部40を形成し、この導体部40を介して配線パターン52を形成してもよいし、あるいは、図3(c)(d)、図3(c)(e)に示すように、孔又は開口部24上に直接配線パターン54、56を形成してもよい。この場合、孔又は開口部24の内部に存在する配線パターンが導体部40となり、孔又は開口部24の外側の配線パターンが表面配線パターンとなる。配線パターンの形成方法としては、金属ペーストを印刷、焼成して、表面にメッキを施す方法、あるいは、薄膜法により形成する方法を挙げることができる。
上記方法により製造した本発明のセラミック基板200A〜Eは、ビアホール30を有するセラミック焼結体基板10、および、底面が前記ビアホール30の露出端面の少なくとも一部で構成される孔又は開口部24を有するセラミック焼結体層20を備えて構成される。
窒化アルミニウム粉末100質量部に、酸化イットリウム5.0質量部、テトラグリセリンモノオレート1.0質量部、トルエン50質量部、ポリn−ブチルメタクリレート13質量部、ジブチルフタレート4.2質量部、酢酸ブチル5.0質量部を加えて混合し、白色の泥漿を得た。次いで、得られた泥漿を用い、ドクターブレード法にグリーンシートを作製し、該グリーンシートを□60mm(「60mm×60mm」の正方形の意である。)に切り出し、厚さ0.35mmのグリーンシート二枚を熱圧着させて、厚さ0.7mmのグリーンシートを作製した。
実施例1と同様にして、タングステンビアを有する窒化アルミニウム焼結体基板に、窒化アルミニウムペーストの塗布、タングステンペーストの充填、および乾燥をして、片面に「タングステンペーストが充填された孔を有する窒化アルミニウムペースト層」を有する窒化アルミニウム焼結体基板を作製した。
実施例1と同様にして、タングステンビアを有する窒化アルミニウム焼結体基板に、窒化アルミニウムペーストの塗布、タングステンペーストの充填、および乾燥をして、片面に「タングステンペーストが充填された孔を有する窒化アルミニウムペースト層」を有する窒化アルミニウム焼結体基板を作製した。このとき、窒化アルミニウムペーストの塗布は、2回重ね塗りを行った。実施例1と同様の操作で乾燥後の窒化アルミニウムペースト層の平均膜厚は20μmであった。そして、得られた、片面に窒化アルミニウムペースト層を有する窒化アルミニウム焼結体基板を実施例1と同様に焼成・メタライズ付与を行い、配線パターンが形成された、タングステンビアを有する窒化アルミニウム基板を得た。
実施例1において、窒化アルミニウム焼結体層を形成しないで、タングステンビアを有する窒化アルミニウム焼結体基板をそのまま用いて、その両面にTi層/Pt層/Au層をメタライズして、実施例1と同様にして配線パターンを形成した。
Claims (12)
- ビアホール、および該ビアホールと電気的に接続する表面配線パターンを有するセラミック基板を製造するために使用されるセラミック基板を製造する方法であって、ビアホールを有するセラミック焼結体基板を準備する工程、該セラミック焼結体基板上に、底面が前記ビアホールの露出端面の少なくとも一部で構成される孔又は開口部を有するセラミック焼結体層をポストファイア法により形成する工程を含むセラミック基板の製造方法。
- ビアホール、および該ビアホールと電気的に接続する表面配線パターンを有するセラミック基板を製造する方法であって、ビアホールを有するセラミック焼結体基板を準備する工程、該セラミック焼結体基板上に、底面が前記ビアホールの露出端面の少なくとも一部で構成される孔又は開口部を有するセラミック焼結体層をポストファイア法により形成する工程、前記孔又は開口部の内部に、前記セラミック焼結体層の表面と前記ビアホールとを電気的に接合する導体部を形成する工程、および、前記セラミック焼結体層の表面に、前記導体部と電気的に接合する表面配線パターンを形成する工程を含むセラミック基板の製造方法。
- ビアホールを有するセラミック焼結体基板を準備する工程が、セラミックグリーンシートの所定の位置に穿孔し、金属ペーストを充填して、第1前駆体を形成し、該第1前駆体を焼成してビアホールを有する第2前駆体を形成する工程を含み、セラミック焼結体層をポストファイア法により形成する工程が、ビアホールを有するセラミック焼結体基板上に、底面が前記ビアホールの露出端面の少なくとも一部で構成される孔又は開口部を有するセラミックペースト層を形成し、該セラミックペースト層を焼成する工程を含む、請求の範囲第2項に記載の方法。
- 前記セラミックグリーンシートおよび前記セラミックペースト層を形成するセラミックが、窒化アルミニウムである、請求の範囲第3項に記載の方法。
- 前記導体部の形成と前記セラミック焼結体層の形成とを同時に行う、請求の範囲第2項〜第4項のいずれかに記載の方法。
- セラミック焼結体層をポストファイア法により形成する工程において、前記孔又は開口部に金属ペーストを充填して金属ペースト層を形成し、前記セラミックペースト層を焼成すると同時に該金属ペースト層を焼成することにより、前記導体部の形成と前記セラミック焼結体層の形成とを同時に行う、請求の範囲第5項に記載の方法。
- セラミックペースト層の形成と金属ペースト層の形成を交互に繰り返して行うと共に、第1層のセラミックペースト層の第一孔又は第一開口部の口径を前記ビアホールの口径以上として該第一孔又は第一開口部の底面に前記ビアホールの端面の全面が含まれるようにし、さらに、第1層より上に新たに形成させるセラミックペースト層の上方孔又は上方開口部の口径を、その直下の層に存在する金属ペースト層の口径よりも小さくして、該金属ペースト層の表面によって前記上方孔又は上方開口部の底面の全面が構成されるようにする、請求の範囲第6項に記載の方法。
- 前記導体部の形成と前記表面配線パターンの形成とを同時に行う、請求の範囲第2項〜第4項のいずれかに記載の方法。
- 前記導体部の形成と、前記セラミック焼結体層の形成と、前記表面配線パターンの形成とを同時に行う、請求の範囲第2項〜第4項のいずれかに記載の方法。
- 前記表面配線パターンを形成する工程が、金属ペーストを印刷、焼成して、その表面にメッキを施して形成する工程、あるいは、薄膜法により配線パターンとなるメタライズ層を形成する工程、のいずれかである、請求の範囲第2項〜第9項のいずれかに記載の方法。
- コファイア法により形成されたビアホールを有するセラミック焼結体基板、および、ポストファイア法により該セラミック焼結体基板上に形成されたセラミック焼結体層を備えたセラミック基板であって、
前記セラミック焼結体層が、底面が前記ビアホールの露出端面の少なくとも一部で構成される孔又は開口部を有するセラミック基板。 - コファイア法により形成されたビアホールを有するセラミック焼結体基板、ポストファイア法により該セラミック焼結体基板上に形成されたセラミック焼結体層、および該セラミック焼結体層に形成された、前記ビアホールと電気的に接合する表面配線パターンを備えたセラミック基板であって、
前記セラミック焼結体層には底面が前記ビアホールの露出端面の少なくとも一部で構成される孔又は開口部が形成されており、該孔又は開口部の内部には前記ビアホールと前記表面配線パターンとを電気的に接合する導体部が形成されているセラミック基板。
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