JP4721041B2 - Cosmetic powder and cosmetics - Google Patents
Cosmetic powder and cosmetics Download PDFInfo
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- JP4721041B2 JP4721041B2 JP2005122890A JP2005122890A JP4721041B2 JP 4721041 B2 JP4721041 B2 JP 4721041B2 JP 2005122890 A JP2005122890 A JP 2005122890A JP 2005122890 A JP2005122890 A JP 2005122890A JP 4721041 B2 JP4721041 B2 JP 4721041B2
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Description
本発明は耐久性、落下強度、紫外線遮断効果、顔料分散性、使用感触、粉体間の静電気防止効果に優れたファンデーション等の化粧料が得られる化粧料用粉体に関する。 The present invention relates to a cosmetic powder from which a cosmetic such as a foundation excellent in durability, drop strength, ultraviolet blocking effect, pigment dispersibility, feel in use, and antistatic effect between powders can be obtained.
有機ケイ素化合物で表面処理した顔料または体質顔料は撥水性に優れることからファンデーション等の化粧料に広く使用されている。 A pigment or extender surface-treated with an organosilicon compound is widely used in cosmetics such as foundations because of its excellent water repellency.
この撥水性の化粧料用粉体を得るために、有機ケイ素化合物で表面処理する方法として、従来、メチルハイドロジェンポリシロキサンを用いたり、アルキルポリシロキサンと有機溶媒等を用いて加熱処理をしたり（特許第３０７９３９５号）、特定の反応性ポリシロキサンを用いる（特開平７−１９６９４６）ことが行われてきた。 In order to obtain this water-repellent cosmetic powder, as a method of surface treatment with an organosilicon compound, conventionally, methylhydrogenpolysiloxane or heat treatment using an alkylpolysiloxane and an organic solvent is used. (Patent No. 3079395), a specific reactive polysiloxane has been used (Japanese Patent Laid-Open No. 7-196946).
しかしながら、これら従来の方法で得られた粉体は水素が残留していて、該粉体を用いての化粧料製造の際危険であったり、ファンデーション等の化粧料にした時、耐久性、落下強度、紫外線遮断効果、顔料分散性、使用感触、粉体間の静電気防止効果に劣るものであった。 However, the powders obtained by these conventional methods have hydrogen remaining, which is dangerous when producing cosmetics using the powders, and when used as cosmetics such as foundations, durability, drop It was inferior in strength, ultraviolet blocking effect, pigment dispersibility, use feeling and antistatic effect between powders.
本発明は、前記のような状況下でなされたものであり、耐久性、落下強度、紫外線遮断効果、顔料分散性、使用感触、粉体間の静電気防止効果に優れたファンデーション等の化粧料が得られる化粧料用粉体を提供することを課題とする。 The present invention was made under the above circumstances, and cosmetics such as a foundation excellent in durability, drop strength, ultraviolet blocking effect, pigment dispersibility, feel in use, and antistatic effect between powders. It is an object to provide a powder for cosmetics to be obtained.
本発明は、
１．水添植物油、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル、イソステアリン酸水添ヒマシ油および（水添ロジン・ジイソステアリン酸）グリセリルから成る油性組成物と有機ケイ素化合物との混合物を、顔料または体質顔料に混合処理して得ることを特徴とする化粧料用粉体。
２．油性組成物が水添植物油３５〜４５重量％、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル２０〜３０重量％、イソステアリン酸水添ヒマシ油１５〜２５重量％、（水添ロジン・ジイソステアリン酸）グリセリル１０〜２０重量％を含有する請求項１記載の化粧料用粉体。
３．水添植物油が水添パーム核油である請求項１または２記載の化粧料用粉体。
４．有機ケイ素化合物がメチルポリシロキサンである請求項１〜３のいずれか１項記載の化粧料用粉体。
５．油性組成物と有機ケイ素化合物との混合物の混合比率が１：７（重量比）〜３：５（重量比）である請求項１〜４のいずれか１項記載の化粧料用粉体。
６．請求項１〜５のいずれか１項記載の化粧料用粉体を配合することを特徴とする化粧料。
よりなる手段によって、前記課題を解決するものである。The present invention
1. A mixture of an oily composition comprising a hydrogenated vegetable oil, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, hydrogenated isostearic acid castor oil, and (hydrogenated rosin diisostearic acid) glyceryl and an organosilicon compound, a pigment or a constitution A powder for cosmetics obtained by mixing with a pigment.
2. Oily composition is 35 to 45% by weight of hydrogenated vegetable oil, 20 to 30% by weight of (hydroxystearic acid / stearic acid / rosin acid) dipentaerythrityl, 15 to 25% by weight of isostearic acid hydrogenated castor oil, (hydrogenated rosin diisostearic acid 2. The cosmetic powder according to claim 1, comprising 10 to 20% by weight of glyceryl.
3. The cosmetic powder according to claim 1 or 2, wherein the hydrogenated vegetable oil is hydrogenated palm kernel oil.
4). The cosmetic powder according to any one of claims 1 to 3, wherein the organosilicon compound is methylpolysiloxane.
5. The powder for cosmetics according to any one of claims 1 to 4, wherein a mixing ratio of the mixture of the oil-based composition and the organosilicon compound is 1: 7 (weight ratio) to 3: 5 (weight ratio).
6). Cosmetics which mix | blend the powder for cosmetics of any one of Claims 1-5.
The above-mentioned problem is solved by means comprising the above.
本発明による化粧料用粉体は、特定の油性組成物と有機ケイ素化合物との混合物を処理したものであるため、従来の有機ケイ素化合物単独の処理によるものに比べ落下強度、紫外線遮断効果、顔料分散性、使用感触、粉体間の静電気防止効果に優れるものである。 The cosmetic powder according to the present invention is obtained by treating a mixture of a specific oily composition and an organosilicon compound, so that it has a drop strength, an ultraviolet blocking effect, and a pigment as compared with those obtained by treating a conventional organosilicon compound alone. Excellent dispersibility, feel of use, and antistatic effect between powders.
以下、本発明の構成について詳述する。
本発明に用いる油性組成物は水添植物油、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル、イソステアリン酸水添ヒマシ油および（水添ロジン・ジイソステアリン酸）グリセリルの４成分から成る。水添植物油は撥水性と人間の体温域で固体から液体になる融点特性（３４℃〜３７℃）を、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチルは艶、付着性、抱水性を、イソステアリン酸水添ヒマシ油は粉体および顔料の分散性と抱水性を、そして（水添ロジン・ジイソステアリン酸）グリセリルは付着性、光沢性、顔料分散性等の物性を付与、向上する。Hereinafter, the configuration of the present invention will be described in detail.
The oily composition used in the present invention comprises four components: hydrogenated vegetable oil, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, isostearic acid hydrogenated castor oil, and (hydrogenated rosin diisostearic acid) glyceryl. Hydrogenated vegetable oil has water repellency and melting point characteristics (34 ° C to 37 ° C) from solid to liquid in human body temperature range, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl has gloss, adhesion, and water retention Isostearic acid hydrogenated castor oil imparts and improves the dispersibility and water repellency of powders and pigments, and (hydrogenated rosin diisostearic acid) glyceryl imparts and improves physical properties such as adhesion, gloss, and pigment dispersibility.
本発明に用いる水添植物油としては、水添ナタネ油、水添パーム油、水添パーム核油、水添ヒマシ油、水添ヤシ油、水添綿実油、水添ピーナッツ油、水添大豆油、水添野菜油などが例示できるが、融点特性の点から特に水添パーム核油が好ましい。 Examples of the hydrogenated vegetable oil used in the present invention include hydrogenated rapeseed oil, hydrogenated palm oil, hydrogenated palm kernel oil, hydrogenated castor oil, hydrogenated palm oil, hydrogenated cottonseed oil, hydrogenated peanut oil, hydrogenated soybean oil, Although hydrogenated vegetable oil etc. can be illustrated, hydrogenated palm kernel oil is especially preferable from the point of melting | fusing point characteristic.
前記４成分の組成割合は任意であるが、特に水添植物油３５〜４５重量％、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル２０〜３０重量％、イソステアリン酸水添ヒマシ油１５〜２５重量％、（水添ロジン・ジイソステアリン酸）グリセリル１０〜２０重量％である時、前記物性の付与、向上に効果があり、また粉体間の静電気防止効果を付与する。 The composition ratio of the four components is arbitrary, but hydrogenated vegetable oil 35 to 45% by weight, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl 20 to 30% by weight, isostearic acid hydrogenated castor oil 15 to 25% by weight %, (Hydrogenated rosin diisostearic acid) glyceryl 10 to 20% by weight is effective in imparting and improving the above-mentioned physical properties and imparting an antistatic effect between powders.
本発明に用いる有機ケイ素化合物としては、メチルポリシロキサン、モノヒドロキシシロキサン、ジヒドロキシポリジメチルシロキサン、モノアルコキシポリジメチルシロキサン、ジアルコキシポリジメチルシロキサン、トリアルコキシポリジメチルシロキサン、ヘキサアルコキシポリジメチルシロキサン、メチルハイドロジェンシロキサンなどが例示できるが、特にメチルポリシロキサンが前記物性を付与、向上する上で好ましい。 Examples of the organosilicon compound used in the present invention include methylpolysiloxane, monohydroxysiloxane, dihydroxypolydimethylsiloxane, monoalkoxypolydimethylsiloxane, dialkoxypolydimethylsiloxane, trialkoxypolydimethylsiloxane, hexaalkoxypolydimethylsiloxane, methylhydrogen. Siloxane and the like can be exemplified, but methylpolysiloxane is particularly preferable for imparting and improving the physical properties.
本発明に用いる油性組成物と有機ケイ素化合物との混合物の混合比率は任意であるが、特に１：３（重量比）とする時、前記物性を付与、向上する上で好ましい。 The mixing ratio of the mixture of the oil-based composition and the organosilicon compound used in the present invention is arbitrary, but particularly 1: 3 (weight ratio) is preferable for imparting and improving the physical properties.
本発明に用いる顔料または体質顔料としては、化粧料用に用いられるものであれば特に制限されることはなく、例えば、有機、無機の顔料、マイカ、タルク、セリサイト、カオリン等の体質顔料を挙げることができる。 The pigment or extender pigment used in the present invention is not particularly limited as long as it is used for cosmetics. For example, extender pigments such as organic and inorganic pigments, mica, talc, sericite, and kaolin are used. Can be mentioned.
本発明の混合処理において、油性組成物と有機ケイ素化合物との前記混合物は、顔料または体質顔料との合計量の０．１〜２０．０重量％が使用される。 In the mixing treatment of the present invention, the mixture of the oily composition and the organosilicon compound is used in an amount of 0.1 to 20.0% by weight of the total amount of the pigment or extender pigment.
本発明の化粧料用粉体は前記の油性組成物と有機ケイ素化合物とを混合、溶解後、次いで顔料または体質顔料と混合処理することにより得られる。この時、他の有機溶媒、水などの溶媒を併用してもよい。混合は通常の混合機を用いればよく、また噴霧による混合でもよい。処理温度は用いる油性組成物、有機ケイ素化合物、顔料また体質顔料、溶媒の耐熱性、揮発性、反応性に応じて適宜選択される。 The cosmetic powder according to the present invention can be obtained by mixing and dissolving the oily composition and the organosilicon compound, and then mixing with a pigment or extender. At this time, other organic solvents and solvents such as water may be used in combination. Mixing may be performed using a normal mixer or may be mixing by spraying. The treatment temperature is appropriately selected according to the oily composition used, the organosilicon compound, the pigment or extender pigment, the heat resistance, volatility, and reactivity of the solvent.
本発明によって得られる化粧料用粉体は化粧料、特にパウダリーファンデーション、リキッドファンデーション、ルージュ、アイシャドー等に配合することができる。配合量は剤型により任意であり、例えばパウダリーファンデーションであれば、１０〜９５重量％配合される。 The powder for cosmetics obtained by the present invention can be blended in cosmetics, particularly powder foundations, liquid foundations, rouges, eye shadows and the like. The blending amount is arbitrary depending on the dosage form. For example, in the case of powdery foundation, 10 to 95% by weight is blended.
本発明によって得られる化粧料用粉体を化粧料に配合する場合、通常化粧料に配合し得る添加成分、例えば、油性成分、界面活性剤、保湿剤、高分子化合物、紫外線吸収剤、酸化防止剤、金属封鎖剤、防腐剤、色素、香料、薬剤等を、本発明の目的、効果を損なわない範囲内で適宜配合することができる。 When the cosmetic powder obtained according to the present invention is blended in cosmetics, additives that can be blended in cosmetics, such as oil components, surfactants, moisturizers, polymer compounds, ultraviolet absorbers, antioxidants, etc. An agent, a sequestering agent, a preservative, a pigment, a fragrance, a drug, and the like can be appropriately blended within a range that does not impair the object and effect of the present invention.
次に本発明について、実施例を挙げてさらに具体的に説明する。なお、本発明はこれらの実施例のみに限定されるものではない。 Next, the present invention will be described more specifically with reference to examples. In addition, this invention is not limited only to these Examples.
＜本発明の化粧料用粉体Ａ＞
水添パーム核油４０重量％、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル２５重量％、イソステアリン酸水添ヒマシ油２０重量％、（水添ロジン・ジイソステアリン酸）グリセリル１５重量％から成る油性組成物２５．０重量％とジメチルポリシロキサン７５．０重量％とを混合し、次いでこの油性組成物４．０重量％とセリサイト９６．０重量％とをミキサーで室温下、混合して化粧料用粉体Ａを得た。
＜実施例１：パウダリーファンデーションＡ＞
本発明の化粧料用粉体Ａ ６０．０重量％
メチルハイドロジェンポリシロキサン被覆タルク １９．３
酸化チタン ９．０
メタクリル酸メチルクロスポリマー ４．０
トリオクタノイン ６．０
パラベン ０．１
着色剤 １．６
１００．０
＜比較例１：パウダリーファンデーションＢ＞
パウダリーファンデーションＡ中の本発明の化粧料用粉体Ａに代えて、メチルハイドロジェンポリシロキサン被覆セリサイトを６０．０重量％配合してパウダリーファンデーションＢを得た。<Cosmetic powder A of the present invention>
Oily composition comprising 40% by weight of hydrogenated palm kernel oil, 25% by weight of (hydroxystearic acid / stearic acid / rosinic acid), 25% by weight of hydrogenated castor oil isostearic acid, and 15% by weight of (hydrogenated rosin diisostearic acid) glyceryl The composition was mixed with 25.0% by weight and 75.0% by weight of dimethylpolysiloxane, and then 4.0% by weight of this oily composition and 96.0% by weight of sericite were mixed with a mixer at room temperature to make up. A powder A was obtained.
<Example 1: Powdery foundation A>
Cosmetic powder A of the present invention 60.0% by weight
Methyl hydrogen polysiloxane coated talc 19.3
Titanium oxide 9.0
Methyl methacrylate cross polymer 4.0
Trioctanoin 6.0
Paraben 0.1
Colorant 1.6
100.0
<Comparative Example 1: Powder Foundation B>
Instead of the powder A for cosmetics of the present invention in the powdery foundation A, 60.0% by weight of methylhydrogenpolysiloxane-coated sericite was blended to obtain a powdery foundation B.
＜パウダリーファンデーションの落下強度の比較＞
成型品を高さ５０ｃｍから鉄板上に落下させ、欠けるまでの回数を測定して、平均値（ｎ＝５）を比較した結果、実施例１は５．０回、比較例は２．８回であった。<Comparison of drop strength of powdery foundation>
The molded product was dropped from a height of 50 cm onto an iron plate, the number of times until it was chipped was measured, and the average value (n = 5) was compared. As a result, Example 1 was 5.0 times and Comparative Example was 2.8 times. Met.
＜紫外線の遮断効果の比較＞
ＳＰＦアナライザーを用いて、ＳＰＦ値、ＰＡ値を測定した結果、次の値を得た。
実施例１：ＳＰＦ値２６、ＰＡ値５．８（＋＋）
比較例１：ＳＰＦ値２０、ＰＡ値４．０（＋＋）<Comparison of UV blocking effect>
As a result of measuring the SPF value and the PA value using an SPF analyzer, the following values were obtained.
Example 1: SPF value 26, PA value 5.8 (++)
Comparative Example 1: SPF value 20, PA value 4.0 (++)
＜顔料分散性の比較＞
測色機（ミノルタ３６１０：Ｄ６５光源、角度−１０度）を用いて測色した結果、次の結果を得た。
実施例１：Ｌ値７５．４７、ａ値１１．９１、ｂ値２５．６６
比較例１：Ｌ値７８．０６、ａ値１０．７９、ｂ値２３．６７
実施例１は比較例１に比べ濃い色調を示しており、分散程度が大きいことが確認できた。<Comparison of pigment dispersibility>
As a result of color measurement using a colorimeter (Minolta 3610: D65 light source, angle −10 degrees), the following results were obtained.
Example 1: L value 75.47, a value 11.91, b value 25.66
Comparative Example 1: L value 78.06, a value 10.79, b value 23.67
Example 1 showed a darker color tone than Comparative Example 1, and it was confirmed that the degree of dispersion was large.
＜使用感触＞
１７名の女性パネル（１９〜６０才）が実施例１のパウダリーファンデーションＡを使用した時の使用感触は次のようであった。
透明感：８２．４％が満足
付着性：６４．６％が満足
シットリ感：６４．７％が満足<Usage feeling>
When 17 female panels (19 to 60 years old) used the powdery foundation A of Example 1, the feeling of use was as follows.
Transparency: Satisfied 82.4% Adhesion: Satisfied 64.6% Tightness: Satisfied 64.7%
＜本発明の化粧料用粉体Ｂ＞
水添パーム核油４０重量％、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル２５重量％、イソステアリン酸水添ヒマシ油２０重量％、（水添ロジン・ジイソステアリン酸）グリセリル１５重量％から成る油性組成物２５．０％重量％とジメチルポリシロキサン７５．０重量％を混合し、次いでこの油性組成物４．０重量％とセリサイト９６．０重量％とをミキサーで室温下、混合して化粧料用粉体Ｂを得た。
＜実施例２ ： パウダリーファンデーションＣ＞
本発明の化粧料用粉体Ｂ ４５．０重量％
メチルハイドロジェンポリシロキサン被覆合成金雲母 １５．０
メチルハイドロジェンポリシロキサン被覆酸化チタン ９．０
メチルハイドロジェンポリシロキサン被覆タルク ８．０
トリオクタノイン ７．０
ナイロンパウダー ５．０
メタクリル酸メチルクロスポリマー ５．０
酸化亜鉛 ３．０
酸化鉄 １．７
スクワラン １．０
防腐剤 ０．２
トコフェロール ０．１
１００．０
＜比較例２ ： パウダリーファンデーションＤ＞
パウダリーファンデーションＣ中の本発明の化粧料用粉体Ｂに代えて、メチルハイドロジェンポリシロキサン被覆セリサイト４５．０重量％を配合してパウダリーファンデーションＤを得た。<Cosmetic powder B of the present invention>
Oily composition comprising 40% by weight of hydrogenated palm kernel oil, 25% by weight of (hydroxystearic acid / stearic acid / rosinic acid), 25% by weight of hydrogenated castor oil isostearic acid, and 15% by weight of (hydrogenated rosin diisostearic acid) glyceryl 25.0% by weight of the composition and 75.0% by weight of dimethylpolysiloxane were mixed, and then 4.0% by weight of this oily composition and 96.0% by weight of sericite were mixed at room temperature with a mixer to make up. A powder B was obtained.
<Example 2: Powdery foundation C>
Powder B for cosmetics of the present invention 45.0% by weight
Methylhydrogenpolysiloxane-coated synthetic phlogopite 15.0
Methyl hydrogen polysiloxane-coated titanium oxide 9.0
Methyl hydrogen polysiloxane coated talc 8.0
Trioctanoin 7.0
Nylon powder 5.0
Methyl methacrylate cross polymer 5.0
Zinc oxide 3.0
Iron oxide 1.7
Squalane 1.0
Preservative 0.2
Tocopherol 0.1
100.0
<Comparative Example 2: Powder Foundation D>
Instead of the powder B for cosmetics of the present invention in the powder foundation C, 45.0% by weight of methylhydrogenpolysiloxane-coated sericite was blended to obtain a powder foundation D.
＜粉体間の静電気防止効果の比較＞
実施例２の成型品と比較例２の成型品をそれぞれ５００個ずつ製造し、粉体加工時及び成型時静電気を帯びるため成型品表面に生じる斑点の数を比較したところ、次のような結果であった。
実施例２ ： 斑点が生じた成型品の数は１３個（２．６％）であった。
比較例２ ： 斑点が生じた成型品の数は５６個（１１．２％）であった。
周知のようにファンデーション、アイシャドー等は配合される粉体間で粉体同士或いは粉体単体で静電気を帯び１次凝集、２次凝集し易い物質、例えばナイロンパウダー、ポリメタクリル酸メチル等の滑剤、酸化チタン、酸化亜鉛等の無機粉体、顔料が配合されており成型する際不良率発生が大きな問題であった。本発明品は上記結果から明らかなようにかなりの確率でこの問題を解消し作業性の改善と原価削減を可能にするものである。<Comparison of antistatic effect between powders>
The molded product of Example 2 and the molded product of Comparative Example 2 were manufactured in 500 pieces each, and the number of spots generated on the surface of the molded product due to static electricity during powder processing and molding was compared. Met.
Example 2: The number of molded products with spots was 13 (2.6%).
Comparative Example 2: The number of molded products with spots was 56 (11.2%).
As is well known, foundations, eye shadows and the like are lubricants such as nylon powder, polymethyl methacrylate, etc., which are electrostatically charged between powders or single powders, and easily aggregate to the secondary or secondary, such as nylon powder or polymethyl methacrylate. Inorganic powders such as titanium oxide and zinc oxide, and pigments are blended, and the occurrence of defective rate was a big problem when molding. As is apparent from the above results, the product of the present invention solves this problem with considerable probability, and improves workability and reduces costs.
以上、本発明の化粧料用粉体は、化粧料、特にパウダリーファンデーションに用いた時、耐久性、落下強度、紫外線の遮断効果、顔料分散性、使用感触、粉体間の静電気防止効果に優れるものであり、当該化粧料の品質を向上させ且つ作業性の改善と原価削減を可能にするものである。As described above, the cosmetic powder of the present invention is excellent in durability, drop strength, ultraviolet blocking effect, pigment dispersibility, feel in use, and antistatic effect between powders when used in cosmetics, especially powdery foundations. It is intended to improve the quality of the cosmetic and improve workability and reduce costs.
Claims (6)
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| JP2005122890A JP4721041B2 (en) | 2005-03-25 | 2005-03-25 | Cosmetic powder and cosmetics |
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| JP2005122890A JP4721041B2 (en) | 2005-03-25 | 2005-03-25 | Cosmetic powder and cosmetics |
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| JP2006273829A JP2006273829A (en) | 2006-10-12 |
| JP4721041B2 true JP4721041B2 (en) | 2011-07-13 |
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| JP4880047B2 (en) * | 2010-02-23 | 2012-02-22 | 三好化成株式会社 | Coated powder and cosmetics using the powder |
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| JPS6261911A (en) * | 1985-09-12 | 1987-03-18 | Noebia:Kk | Makeup cosmetic |
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| JPH07242515A (en) * | 1994-03-03 | 1995-09-19 | Kanebo Ltd | Oil-based point make-up cosmetic |
| JPH0859431A (en) * | 1994-08-26 | 1996-03-05 | Noevir Co Ltd | Powder having coated water repellent-treated surface and powdery solid cosmetic containing the same blended therein |
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| JP2000297012A (en) * | 1999-04-14 | 2000-10-24 | Shiseido Co Ltd | Lipstick composition |
| JP2002080748A (en) * | 2000-09-11 | 2002-03-19 | Miyoshi Kasei Kk | Powder oily dispersion having ultra dispersion stability and cosmetic formulated with the same |
| JP2006225363A (en) * | 2005-02-14 | 2006-08-31 | Ookemu Tsusho Kk | Powder for cosmetic and cosmetic |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2561857B2 (en) * | 1987-06-05 | 1996-12-11 | 株式会社コーセー | Oily makeup cosmetics |
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|---|---|---|---|---|
| JPS6261911A (en) * | 1985-09-12 | 1987-03-18 | Noebia:Kk | Makeup cosmetic |
| JPS643108A (en) * | 1987-06-23 | 1989-01-06 | Kobayashi Kose Co Ltd | Powder make-up cosmetic |
| JPH07242515A (en) * | 1994-03-03 | 1995-09-19 | Kanebo Ltd | Oil-based point make-up cosmetic |
| JPH0859431A (en) * | 1994-08-26 | 1996-03-05 | Noevir Co Ltd | Powder having coated water repellent-treated surface and powdery solid cosmetic containing the same blended therein |
| JPH08120300A (en) * | 1994-10-21 | 1996-05-14 | Max:Kk | Solid soap or bath agent containing pancreatin microcapsule |
| JP2000297012A (en) * | 1999-04-14 | 2000-10-24 | Shiseido Co Ltd | Lipstick composition |
| JP2002080748A (en) * | 2000-09-11 | 2002-03-19 | Miyoshi Kasei Kk | Powder oily dispersion having ultra dispersion stability and cosmetic formulated with the same |
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