JP2006225363A - Powder for cosmetic and cosmetic - Google Patents
Powder for cosmetic and cosmetic Download PDFInfo
- Publication number
- JP2006225363A JP2006225363A JP2005068024A JP2005068024A JP2006225363A JP 2006225363 A JP2006225363 A JP 2006225363A JP 2005068024 A JP2005068024 A JP 2005068024A JP 2005068024 A JP2005068024 A JP 2005068024A JP 2006225363 A JP2006225363 A JP 2006225363A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- cosmetic
- weight
- powder
- hydrogenated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は耐久性、落下強度、紫外線遮断効果、顔料分散性に優れたファンデーション等の化粧料が得られる化粧料用粉体に関する。 The present invention relates to a cosmetic powder from which cosmetics such as a foundation excellent in durability, drop strength, ultraviolet blocking effect and pigment dispersibility can be obtained.
有機ケイ素化合物で表面処理した顔料または体質顔料は撥水性に優れることからファンデーション等の化粧料に広く使用されている。 A pigment or extender surface-treated with an organosilicon compound is widely used in cosmetics such as foundations because of its excellent water repellency.
この撥水性の化粧料用粉体を得るために、有機ケイ素化合物で表面処理する方法として、従来、メチルハイドロジェンポリシロキサンを用いたり、アルキルポリシロキサンと有機溶媒等を用いて加熱処理をしたり（特許第３０７９３９５号）、特定の反応性ポリシロキサンを用いる（特開平７−１９６９４６）ことが行われてきた。 In order to obtain this water-repellent cosmetic powder, as a method of surface treatment with an organosilicon compound, conventionally, methylhydrogenpolysiloxane or heat treatment using an alkylpolysiloxane and an organic solvent is used. (Patent No. 3079395), a specific reactive polysiloxane has been used (Japanese Patent Laid-Open No. 7-196946).
しかしながら、これら従来の方法で得られた粉体は水素が残留していて、該粉体を用いての化粧料製造の際危険であったり、ファンデーション等の化粧料にした時、耐久性、落下強度、紫外線遮断効果、顔料分散性に劣るものであった。 However, the powders obtained by these conventional methods have hydrogen remaining, which is dangerous when producing cosmetics using the powders, and when used as cosmetics such as foundations, durability, drop It was inferior in strength, ultraviolet blocking effect, and pigment dispersibility.
本発明は、前記のような状況下でなされたものであり、耐久性、落下強度、紫外線遮断効果、顔料分散性に優れたファンデーション等の化粧料が得られる化粧料用粉体を提供することを課題とする。 The present invention has been made under the circumstances as described above, and provides a cosmetic powder from which a cosmetic such as a foundation excellent in durability, drop strength, ultraviolet blocking effect, and pigment dispersibility can be obtained. Is an issue.
本発明は、
１．水添パーム核油、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル、イソステアリン酸水添ヒマシ油および（水添ロジン・ジイソステアリン酸）グリセリルから成る油性組成物と有機ケイ素化合物との混合物を、顔料または体質顔料に混合処理して得ることを特徴とする化粧料用粉体。
２．油性組成物が水添パーム核油３９〜４３重量％、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル２４〜２５重量％、イソステアリン酸水添ヒマシ油１９〜２１重量％、（水添ロジン・ジイソステアリン酸）グリセリル１４〜１５重量％を含有する請求項１記載の化粧料用粉体。
３．有機ケイ素化合物がメチルポリシロキサンである請求項１または２記載の化粧料用粉体。
４．油性組成物と有機ケイ素化合物との混合物の混合比率が１：３（重量比）である請求項１〜３のいずれか１項記載の化粧料用粉体。
５．請求項１〜４のいずれか１項記載の化粧料用粉体を配合することを特徴とする化粧料。
よりなる手段によって、前記課題を解決するものである。The present invention
1. A mixture of an organic silicon compound and an oily composition comprising hydrogenated palm kernel oil, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, hydrogenated isostearic acid castor oil and (hydrogenated rosin diisostearic acid) glyceryl, Alternatively, a cosmetic powder obtained by mixing with extender pigments.
2. The oil-based composition was 39 to 43% by weight of hydrogenated palm kernel oil, 24 to 25% by weight of (hydroxystearic acid / stearic acid / rosinic acid), 24 to 25% by weight, 19 to 21% by weight of isostearic acid hydrogenated castor oil, (hydrogenated rosin The cosmetic powder according to claim 1, comprising 14 to 15% by weight of diisostearic acid) glyceryl.
3. The cosmetic powder according to claim 1 or 2, wherein the organosilicon compound is methylpolysiloxane.
4). The powder for cosmetics according to any one of claims 1 to 3, wherein a mixing ratio of the mixture of the oily composition and the organosilicon compound is 1: 3 (weight ratio).
5. Cosmetics which mix | blend the powder for cosmetics of any one of Claims 1-4.
The above-mentioned problem is solved by means comprising the above.
本発明による化粧料用粉体は、特定の油性組成物と有機ケイ素化合物との混合物を処理したものであるため、従来の有機ケイ素化合物単独の処理によるものに比べ落下強度、紫外線遮断効果、顔料分散性、使用感触に優れるものである。 The cosmetic powder according to the present invention is obtained by treating a mixture of a specific oily composition and an organosilicon compound, so that it has a drop strength, an ultraviolet blocking effect, and a pigment as compared with those obtained by treating a conventional organosilicon compound alone. It is excellent in dispersibility and use feeling.
以下、本発明の構成について詳述する。
本発明に用いる油性組成物は水添パーム核油、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル、イソステアリン酸水添ヒマシ油および（水添ロジン・ジイソステアリン酸）グリセリルから成る。水添パーム核油は撥水性を、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチルは艶、付着性、抱水性を、イソステアリン酸水添ヒマシ油は粉体および顔料の分散性を、そして（水添ロジン・ジイソステアリン酸）グリセリルは付着性、光沢性、顔料分散性等の物性を付与、向上する。これら４成分の組成割合は任意であるが、特に水添パーム核油３９〜４３重量％、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル２４〜２５重量％、イソステアリン酸水添ヒマシ油１９〜２１重量％、（水添ロジン・ジイソステアリン酸）グリセリル１４〜１５重量％である時、前記物性の付与、向上に効果がある。Hereinafter, the configuration of the present invention will be described in detail.
The oily composition used in the present invention comprises hydrogenated palm kernel oil, (hydroxystearic acid / stearic acid / rosin acid) dipentaerythrityl, isostearic acid hydrogenated castor oil and (hydrogenated rosin diisostearic acid) glyceryl. Hydrogenated palm kernel oil provides water repellency, (hydroxystearic acid / stearic acid / rosin acid) dipentaerythrityl provides gloss, adhesion, and water retention, isostearic acid hydrogenated castor oil provides powder and pigment dispersibility, and ( Hydrogenated rosin / diisostearic acid) glyceryl imparts and improves physical properties such as adhesion, gloss, and pigment dispersibility. The composition ratio of these four components is arbitrary, but especially 39 to 43% by weight of hydrogenated palm kernel oil, 24 to 25% by weight of (hydroxystearic acid / stearic acid / rosinic acid), and 25 to 25% by weight of isostearic acid hydrogenated castor oil 19 to When the content is 21% by weight and (hydrogenated rosin / diisostearic acid) glyceryl 14 to 15% by weight, the above-described physical properties are imparted and improved.
本発明に用いる有機ケイ素化合物としては、ジメチルポリシロキサン、モノヒドロキシシロキサン、ジヒドロキシポリジメチルシロキサン、モノアルコキシポリジメチルシロキサン、ジアルコキシポリジメチルシロキサン、トリアルコキシポリジメチルシロキサン、ヘキサアルコキシポリジメチルシロキサン、メチルハイドロジェンシロキサンなどが例示できるが、特にジメチルポリシロキサンが前記物性を付与、向上する上で好ましい。 Examples of the organosilicon compound used in the present invention include dimethylpolysiloxane, monohydroxysiloxane, dihydroxypolydimethylsiloxane, monoalkoxypolydimethylsiloxane, dialkoxypolydimethylsiloxane, trialkoxypolydimethylsiloxane, hexaalkoxypolydimethylsiloxane, methylhydrogen. Siloxane and the like can be exemplified, but dimethylpolysiloxane is particularly preferable for imparting and improving the physical properties.
本発明に用いる油性組成物と有機ケイ素化合物との混合物の混合比率は任意であるが、特に１：３（重量比）とする時、前記物性を付与、向上する上で好ましい。 The mixing ratio of the mixture of the oil-based composition and the organosilicon compound used in the present invention is arbitrary, but particularly 1: 3 (weight ratio) is preferable for imparting and improving the physical properties.
本発明に用いる顔料または体質顔料としては、化粧料用に用いられるものであれば特に制限されることはなく、例えば、有機、無機の顔料、マイカ、タルク、セリサイト、カオリン等の体質顔料を挙げることができる。 The pigment or extender pigment used in the present invention is not particularly limited as long as it is used for cosmetics. For example, extender pigments such as organic and inorganic pigments, mica, talc, sericite, and kaolin are used. Can be mentioned.
本発明の混合処理において、油性組成物と有機ケイ素化合物との前記混合物は、顔料または体質顔料との合計量の０．１〜１０．０重量％が使用される。 In the mixing treatment of the present invention, 0.1 to 10.0% by weight of the total amount of the pigment or the extender pigment is used for the mixture of the oily composition and the organosilicon compound.
本発明の化粧料用粉体は前記の油性組成物と有機ケイ素化合物とを混合、溶解後、次いで顔料または体質顔料と混合処理することにより得られる。この時、他の有機溶媒、水などの溶媒を併用してもよい。混合は通常の混合機を用いればよく、また噴霧による混合でもよい。処理温度は用いる油性組成物、有機ケイ素化合物、顔料また体質顔料、溶媒の耐熱性、揮発性、反応性に応じて適宜選択される。 The cosmetic powder according to the present invention can be obtained by mixing and dissolving the oily composition and the organosilicon compound, and then mixing with a pigment or extender. At this time, other organic solvents and solvents such as water may be used in combination. Mixing may be performed using a normal mixer, or may be performed by spraying. The treatment temperature is appropriately selected according to the oily composition used, the organosilicon compound, the pigment or extender pigment, the heat resistance, volatility, and reactivity of the solvent.
本発明によって得られる化粧料用粉体は化粧料、特にパウダリーファンデーション、リキッドファンデーション、ルージュ、アイシャドー等に配合することができる。配合量は剤型により任意であり、例えばパウダリーファンデーションであれば、１０〜９５重量％配合される。 The powder for cosmetics obtained by the present invention can be blended in cosmetics, particularly powder foundations, liquid foundations, rouges, eye shadows and the like. The blending amount is arbitrary depending on the dosage form. For example, in the case of powdery foundation, 10 to 95% by weight is blended.
本発明によって得られる化粧料用粉体を化粧料に配合する場合、通常化粧料に配合し得る添加成分、例えば、油性成分、界面活性剤、保湿剤、高分子化合物、紫外線吸収剤、酸化防止剤、金属封鎖剤、防腐剤、色素、香料、薬剤等を、本発明の目的、効果を損なわない範囲内で適宜配合することができる。 When the cosmetic powder obtained according to the present invention is blended in cosmetics, additives that can be blended in cosmetics, such as oil components, surfactants, moisturizers, polymer compounds, ultraviolet absorbers, antioxidants, etc. An agent, a sequestering agent, a preservative, a pigment, a fragrance, a drug, and the like can be appropriately blended within a range that does not impair the object and effect of the present invention.
次に本発明について、実施例を挙げてさらに具体的に説明する。なお、本発明はこれらの実施例のみに限定されるものではない。 Next, the present invention will be described more specifically with reference to examples. In addition, this invention is not limited only to these Examples.
＜本発明の化粧料用粉体Ａ＞
水添パーム核油４０重量％、（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル２５重量％、イソステアリン酸水添ヒマシ油２０重量％、（水添ロジン・ジイソステアリン酸）グリセリル１５重量％から成る油性組成物２５．０重量％とジメチルポリシロキサン７５．０重量％とを混合し、次いでこの油性組成物５．０重量％とセリサイト９５．０重量％とをミキサーで室温下、混合して化粧料用粉体Ａを得た。
＜実施例１：パウダリーファンデーションＡ＞
本発明の化粧料用粉体Ａ ６０．０重量％
メチルハイドロジェンポリシロキサン被覆タルク １９．３
酸化チタン ９．０
メタクリル酸メチルクロスポリマー ４．０
トリオクタノイン ６．０
パラベン ０．１
着色剤 １．６
１００．０
＜比較例１：パウダリーファンデーションＢ＞
パウダリーファンデーションＡ中の本発明の化粧料用粉体Ａに代えて、メチルハイドロジェンポリシロキサン被覆セリサイトを６０．０重量％配合してパウダリーファンデーションＢを得た。<Cosmetic powder A of the present invention>
Oily composition comprising 40% by weight of hydrogenated palm kernel oil, 25% by weight of (hydroxystearic acid / stearic acid / rosinic acid), 25% by weight of hydrogenated castor oil isostearic acid, and 15% by weight of (hydrogenated rosin diisostearic acid) glyceryl The composition 25.0% by weight and dimethylpolysiloxane 75.0% by weight were mixed, and then the oily composition 5.0% by weight and sericite 95.0% by weight were mixed at room temperature with a mixer to make up. A powder A was obtained.
<Example 1: Powdery foundation A>
Cosmetic powder A of the present invention 60.0% by weight
Methyl hydrogen polysiloxane coated talc 19.3
Titanium oxide 9.0
Methyl methacrylate cross polymer 4.0
Trioctanoin 6.0
Paraben 0.1
Colorant 1.6
100.0
<Comparative Example 1: Powder Foundation B>
Instead of the powder A for cosmetics of the present invention in the powdery foundation A, 60.0% by weight of methylhydrogenpolysiloxane-coated sericite was blended to obtain a powdery foundation B.
＜パウダリーファンデーションの落下強度の比較＞
成型品を高さ５０ｃｍから鉄板上に落下させ、欠けるまでの回数を測定して、平均値（ｎ＝５）を比較した結果、実施例１は５．０回、比較例は２．８回であった。<Comparison of drop strength of powdery foundation>
The molded product was dropped from a height of 50 cm onto an iron plate, and the number of times until it was chipped was measured, and the average value (n = 5) was compared. As a result, Example 1 was 5.0 times and Comparative Example was 2.8 times. Met.
＜紫外線の遮断効果の比較＞
ＳＰＦアナライザーを用いて、ＳＰＦ値、ＰＡ値を測定した結果、次の値を得た。
実施例１：ＳＰＦ値２６、ＰＡ値５．８（＋＋）
比較例１：ＳＰＦ値２０、ＰＡ値４．０（＋＋）<Comparison of UV blocking effect>
As a result of measuring the SPF value and the PA value using an SPF analyzer, the following values were obtained.
Example 1: SPF value 26, PA value 5.8 (++)
Comparative Example 1: SPF value 20, PA value 4.0 (++)
＜顔料分散性の比較＞
測色機（ミノルタ３６１０：Ｄ６５光源、角度−１０度）を用いて測色した結果、次の結果を得た。
実施例１：Ｌ値７５．４７、ａ値１１．９１、ｂ値２５．６６
比較例１：Ｌ値７８．０６、ａ値１０．７９、ｂ値２３．６７
実施例１は比較例１に比べ濃い色調を示しており、分散程度が大きいことが確認できた。<Comparison of pigment dispersibility>
As a result of color measurement using a colorimeter (Minolta 3610: D65 light source, angle −10 degrees), the following results were obtained.
Example 1: L value 75.47, a value 11.91, b value 25.66
Comparative Example 1: L value 78.06, a value 10.79, b value 23.67
Example 1 showed a darker color tone than Comparative Example 1, and it was confirmed that the degree of dispersion was large.
＜使用感触＞
１７名の女性パネル（１９〜６０才）が実施例１のパウダリーファンデーションＡを使用した時の使用感触は次のようであった。
透明感：８２．４％が満足
付着性：６４．６％が満足
シットリ感：６４．７％が満足<Usage feeling>
When 17 female panels (19 to 60 years old) used the powdery foundation A of Example 1, the feeling of use was as follows.
Transparency: Satisfied 82.4% Adhesion: Satisfied 64.6% Tightness: Satisfied 64.7%
以上、本発明の化粧料用粉体は、化粧料、特にパウダリーファンデーションに用いた時、落下強度、紫外線の遮断効果、顔料分散性、使用感触に優れるものであり、当該化粧料の品質を向上させるものである。 As described above, the cosmetic powder of the present invention has excellent drop strength, ultraviolet blocking effect, pigment dispersibility, and feel when used in cosmetics, particularly powder foundations, and improves the quality of the cosmetics. It is something to be made.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005068024A JP2006225363A (en) | 2005-02-14 | 2005-02-14 | Powder for cosmetic and cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005068024A JP2006225363A (en) | 2005-02-14 | 2005-02-14 | Powder for cosmetic and cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2006225363A true JP2006225363A (en) | 2006-08-31 |
Family
ID=36987042
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005068024A Pending JP2006225363A (en) | 2005-02-14 | 2005-02-14 | Powder for cosmetic and cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2006225363A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006273829A (en) * | 2005-03-25 | 2006-10-12 | Ookemu Tsusho Kk | Powder for cosmetic and the resultant cosmetic |
-
2005
- 2005-02-14 JP JP2005068024A patent/JP2006225363A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006273829A (en) * | 2005-03-25 | 2006-10-12 | Ookemu Tsusho Kk | Powder for cosmetic and the resultant cosmetic |
| JP4721041B2 (en) * | 2005-03-25 | 2011-07-13 | オーケム通商株式会社 | Cosmetic powder and cosmetics |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6184099B2 (en) | Self-dispersing metal oxide coating powder, its production method and use | |
| JP2007238690A (en) | Water- and oil-repellent pigment and cosmetic containing the same | |
| JP2008037813A (en) | Water repellent and oil repellent powder pigment for cosmetics, and cosmetic containing the same | |
| KR101262037B1 (en) | Novel method for preparing composite particle comprising surface treatment layer of sunscreening agent formed thereon | |
| JP2007302647A (en) | Cosmetic | |
| WO2005079739A1 (en) | Sun-block cosmetic | |
| TW201124165A (en) | Oil-in-water-type emulsion cosmetic | |
| JP2007326902A (en) | Pigment for cosmetic material and cosmetic material containing the same | |
| JP6644482B2 (en) | Surface-treated powder, method for producing the same, and cosmetic containing the same | |
| JP5782256B2 (en) | Powder cosmetics | |
| TWI825044B (en) | Solid powder cosmetics | |
| JP6905726B2 (en) | Manufacturing method of solid powder cosmetics and solid powder cosmetics | |
| JP2016204345A (en) | Cosmetic | |
| JP4721041B2 (en) | Cosmetic powder and cosmetics | |
| JP2016041674A (en) | Eyeliner cosmetics | |
| JP2006225363A (en) | Powder for cosmetic and cosmetic | |
| JP2010126445A (en) | Solid powder cosmetic | |
| JP6144602B2 (en) | Marble beauty nail | |
| JP2008050388A (en) | Water-repellent and oil-repellent pigment and cosmetic containing the same | |
| JP3492937B2 (en) | Cosmetics | |
| WO2020166576A1 (en) | Aqueous dispersion of black iron oxide and liquid cosmetic preparation using same | |
| JP6498144B2 (en) | Solid powder cosmetic | |
| JP2007211131A (en) | Black-colored spherical cellulose powder and cosmetic | |
| JP2007291090A (en) | Powdery cosmetic | |
| JP2000086433A (en) | Water-based double layer type cosmetic |