JP4294628B2 - Foam cleaning composition and foam cleaning agent - Google Patents

Description

  The present invention relates to a foam cleaning composition and a foam cleaning agent. Specifically, the present invention relates to a foam cleaning composition that forms foam with a non-aerosol type foam discharge container such as a squeeze foamer or a pump foamer, and a foam cleaning agent that contains the composition in a foam discharge container.

  Although there are solid, liquid, foam, etc., the detergent can be easily obtained by simply pressing the pump, etc., so the foam detergent is suitable for hand washing, face washing, hair washing, etc. Widely used in various applications such as

  This foamy detergent is mixed with the content composition and air by passing through a porous film inside a container such as a pump former to form a foam. However, since it is necessary to pass through the porous membrane for foam formation, there is a problem that the content composition is clogged with the porous membrane. In particular, when an anionic surfactant is used as the surfactant, there is a problem that the preparation stability is deteriorated during low-temperature storage and clogging is likely to occur.

  In order to solve such problems, for example, a skin cleansing product (see Patent Document 1) in which a foam discharge container is filled with a sulfate ester surfactant or a sulfonic acid surfactant and an anionic surfactant, sugar Skin cleansing product (see Patent Document 2) filled with foam non-ionic surfactant and anionic surfactant in foam discharge container, aqueous liquid detergent filled with former fatty acid salt and organic acid salt in foam container (Patent Document 3) Have been proposed). However, these attempts have not yet solved the problems such as formulation stability, clogging of the porous membrane, foam quality, foaminess, and feeling of use, and are still not satisfactory.

JP-A-8-183728 JP-A-8-183729 JP-A-8-92064

  The present invention has been made in view of the above-described prior art, and is excellent in storage stability at low temperatures. In use, it has excellent foaming properties and detergency, forms fine creamy foam, and maintains the foam. It is an object of the present invention to provide a foam cleaning composition having excellent properties (hereinafter referred to as foam), and a foam cleaning agent filled with the composition in a foam discharge container.

〔式中、Ｒは水素原子又は炭素数１〜５のアルキル基を表す。〕

〔式中、ＰはＮＲ ^２ を表す。Ｒ^１，Ｒ^２，Ｒ^３，Ｒ^４はそれぞれ独立して水素原子又は炭素数１〜５のアルキル基を表す。Ｒ^５は炭素数２〜１６のアルキレン基を表す。〕

〔式中、ＰはＮＲ ^２ を表す。Ｒ^１，Ｒ^２，Ｒ^３，Ｒ^４はそれぞれ独立して水素原子又は炭素数１〜５のアルキル基を表す。Ｒ^５は炭素数２〜１６のアルキレン基を表す。Ｒ^６は炭素数９〜２４のアルキル基を表す。Ｍ⁻はハロゲンイオン、ｐ−トルエンスルホン酸イオン又はリン酸イオンを表す。〕
〔２〕前記共重合体が、ポリクオタニウム−５５である前記〔１〕に記載の泡沫洗浄剤用組成物、並びに
〔３〕前記〔１〕又は〔２〕に記載の泡沫洗浄剤用組成物を、泡吐出容器に充填したことを特徴とする泡沫洗浄剤、
に関する。 That is, the present invention
[1] A composition for a foam cleaning agent comprising an anionic surfactant, a fatty acid alkylolamide, and a copolymer having a monomer represented by the following A to C as a copolymerization component;

[In formula, R represents a hydrogen atom or a C1-C5 alkyl group. ]

[In the formula, P represents NR ² . R ¹ , R ² , R ³ and R ⁴ each independently represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms. R ⁵ represents an alkylene group having 2 to 16 carbon atoms. ]

[ Wherein P represents NR ² . R ¹ , R ² , R ³ and R ⁴ each independently represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms. R ⁵ represents an alkylene group having 2 to 16 carbon atoms. R ⁶ represents an alkyl group having 9 to 24 carbon atoms. M ⁻ represents a halogen ion, p-toluenesulfonate ion or phosphate ion. ]
[2] The foam cleaning composition according to [1], wherein the copolymer is polyquaternium-55, and [3] the foam cleaning composition according to [1] or [2]. A foam cleaning agent characterized by filling a foam discharge container,
About.

  The composition for foam cleaning agent of this invention is excellent in the storage stability of the formulation under low-temperature storage, and has the effect excellent in foaming power and detergency. In addition, foam discharged from the foam cleaning composition of the present invention using a foam discharge container such as a pump former forms a fine creamy foam, has an excellent effect on foam, and clogging occurs. There is an excellent effect that there is no.

  The foam cleaning composition of the present invention contains a copolymer composed of an anionic surfactant, a fatty acid alkylolamide, and three types of monomers.

  The anionic surfactant used in the present invention is not particularly limited as long as it has excellent detergency and foaming power. For example, sodium laurate, triethanolamine laurate, sodium myristate, triethanol myristate Higher fatty acid salts having 12 to 22 carbon atoms such as amine, sodium palmitate, triethanolamine palmitate, sodium stearate, triethanolamine stearate, coconut oil fatty acid potassium, coconut oil fatty acid triethanolamine; sodium lauryl sulfate, lauryl Alkyl sulfate esters such as triethanolamine sulfate, sodium myristyl sulfate, sodium stearyl sulfate, sodium oleyl sulfate, sodium cetyl sulfate; polyoxyethylene lauryl ether sulfate sodium, polyoxy Polyoxyethylene alkyl ether sulfates such as sodium tylene myristyl sulfate; α-olefin sulfonates such as sodium tetradecene sulfonate; N-acylmethyl taurine salts such as coconut oil fatty acid methyl taurine sodium; sulfosuccinic acid alkyl salts such as dioctyl sodium sulfosuccinate and lauryl disodium sulfosuccinate; and polyoxyethylene alkyl salts of sulfosuccinic acid such as polyoxyethylene lauryl disodium sulfosuccinate; Monoalkyl phosphorus such as sodium lauryl phosphate, sodium cetyl phosphate, diethanolamine cetyl phosphate Acid ester salt; polyoxyethylene lauryl ether sodium phosphate, polyoxyethylene cetyl ether sodium phosphate, polyoxyethylene oleyl ether sodium phosphate, polyoxyethylene alkylphenyl ether sodium phosphate, polyoxyethylene alkylphenyl ether triphosphate Polyoxyethylene alkyl ether phosphate ester salts such as ethanolamine; N-acyl sarcosine salts such as lauroyl sarcosine potassium, lauroyl sarcosine triethanolamine, myristoyl sarcosine sodium, coconut oil fatty acid sarcosine sodium; lauroylmethylalanine sodium, lauroylmethylalanine tri Ethanolamine, sodium myristoyl methylalanine, palm oil fatty acid methylalanine N-acyl-N-methyl-β-alanine salts such as lithium; sodium lauroyl glutamate, triethanolamine lauroyl glutamate, sodium myristoyl glutamate, potassium stearoyl glutamate, disodium stearoyl glutamate, palm oil fatty acid sodium acyl glutamate, palm oil fatty acid acyl N-acyl glutamates such as triethanolamine glutamate; N-acyl glycine salts such as coconut oil fatty acid acylglycine potassium and coconut oil fatty acid acylglycine sodium. These may be used alone or in appropriate combination of two or more. In the present invention, from the viewpoint of detergency and foaming power, higher fatty acid salts, polyoxyethylene alkyl ether sulfates, acyl glutamates, polyoxyethylene alkyl salts of sulfosuccinic acid, N-acyl glutamates, N-acyl glycine salts Etc. are preferably used.

  The content of the anionic surfactant is not particularly limited as long as the effect of the present invention is exhibited, but usually, 0.1% by weight or more is preferable in the composition from the viewpoint of foaming power and detergency, and more preferable. Is 1% by weight or more. Further, from the viewpoint of suppression of skin irritation and tension, and stability of the preparation, it is preferably 15% by weight or less, more preferably 10% by weight or less. Accordingly, the content of the anionic surfactant is preferably 0.1 to 15% by weight, more preferably 1 to 10% by weight.

  Examples of the fatty acid alkylolamide used in the present invention include fatty acid monoethanolamide, fatty acid monoisopropanolamide, fatty acid diethanolamide, and the like. Examples of fatty acids used include higher fatty acids having 12 to 20 carbon atoms such as lauric acid, myristic acid, palmitic acid, stearic acid, and oleic acid; vegetable oils such as coconut oil and palm oil; animals such as beef tallow Oils and fats can be exemplified. In the present invention, lauric acid diethanolamide, stearic acid diethanolamide, coconut oil fatty acid diethanolamide, palm kernel fatty acid diethanolamide and the like can be preferably used from the viewpoints of foam stability, detergency and foaming power.

  Commercially available fatty acid alkylolamides that can be used in the present invention include, for example, Aminone L-02 (trade name, manufactured by Kao Corporation) as lauric acid diethanolamide; Amisol SDE (trade name, Kawaken Fine Chemical Co.); As palm oil fatty acid diethanolamide, Amisole CDE (trade name, manufactured by Kawaken Fine Chemical Co., Ltd.), Amikol CDE-1 (trade name, manufactured by Miyoshi Oil & Fats Co., Ltd.); Aminone PK-02S (trade name, manufactured by Kao Corporation) and the like can be exemplified.

  The content of fatty acid alkylolamide is not particularly limited as long as the effect of the present invention is exhibited, but usually 0.1% by weight or more in the composition from the viewpoint of foam stability, detergency and foaming power. Is more preferable, and more preferably 1% by weight or more. Moreover, from a viewpoint of suppressing the sticky feeling after washing | cleaning, 7 weight% or less is preferable, More preferably, it is 5 weight% or less. From these viewpoints, the content of fatty acid alkylolamide is preferably 0.1 to 7% by weight, more preferably 1 to 5% by weight.

〔式中、Ｒは水素原子又は炭素数１〜５のアルキル基を表す。〕

〔式中、ＰはＮＲ ^２ を表す。Ｒ^１，Ｒ^２，Ｒ^３，Ｒ^４はそれぞれ独立して水素原子又は炭素数１〜５のアルキル基を表す。Ｒ^５は炭素数２〜１６のアルキレン基を表す。〕

〔式中、ＰはＮＲ ^２ を表す。Ｒ^１，Ｒ^２，Ｒ^３，Ｒ^４はそれぞれ独立して水素原子又は炭素数１〜５のアルキル基を表す。Ｒ^５は炭素数２〜１６のアルキレン基を表す。Ｒ^６は炭素数９〜２４のアルキル基を表す。Ｍ⁻はハロゲンイオン、トシルイオン又はリン酸イオンを表す。〕 The copolymer used in the present invention is a copolymer having monomers represented by the following A to C as copolymerization components, and is finely grained while maintaining the excellent foaming power of the anionic surfactant. For the purpose of forming a good foam quality.

[In formula, R represents a hydrogen atom or a C1-C5 alkyl group. ]

[In the formula, P represents NR ² . R ¹ , R ² , R ³ and R ⁴ each independently represent a hydrogen atom or an alkyl group having 1 to 5 carbon atoms. R ⁵ represents an alkylene group having 2 to 16 carbon atoms. ]

[In the formula, P represents NR ² . R ¹ , R ² , R ³ and R ⁴ each independently represent a hydrogen atom or an alkyl group having 1 to 5 carbon atoms. R ⁵ represents an alkylene group having 2 to 16 carbon atoms. R ⁶ represents an alkyl group having 9 to 24 carbon atoms. M ⁻ represents a halogen ion, a tosyl ion or a phosphate ion. ]

  The content of the constituent component in the copolymer consisting of the monomers A to C is not particularly limited, but the constituent component consisting of the monomer A is preferably 40 to 95% by weight, more preferably 60 to 90% by weight. It is. The constituent component consisting of the monomer B is preferably 0.1 to 55% by weight, more preferably 5 to 30% by weight. The component consisting of monomer C is preferably 0.25 to 50% by weight, more preferably 1 to 30% by weight. Further, as a method for producing a copolymer, for example, each monomer may be heated and polymerized in a solvent under an inert gas atmosphere, and the method described in US Pat. No. 6,207,778 is used. Can also be manufactured.

Among the copolymers used in the present invention, P is NR ² , R, R ¹ , R ² , R ³ , and R ⁴ are hydrogen or an alkyl group having 1 to 3 carbon atoms, and R ⁵ is 2 carbon atoms. A copolymer of ˜4 alkyl groups and R ⁶ is an alkyl group having 9 to 16 carbon atoms, and in particular, P is NR ² , R and R ² are hydrogen, and R ¹ , R ³ , and R ⁴ are methyl Group, R ⁵ is an alkyl group having 3 carbon atoms, R ⁶ is an alkyl group having 12 carbon atoms, and is expressed as polyquaternium-55 (POLYQUATERNIUM-55) under the INCI name (CTFA Dictionary, 10th edition, 2004) A vinylpyrrolidone / dimethylaminopropylmethacrylamide / lauryldimethylaminopropylmethacrylamide copolymer is preferred.

  Examples of commercially available polyquaternium-55 that can be used in the present invention include STYLEZE W-20, W-10 (trade names, both manufactured by ISP) and the like.

  The content of the copolymer is not particularly limited as long as the effect of the present invention is exerted, but usually 0.01% by weight or more is preferable in the composition from the viewpoint of obtaining a stable fine foam quality. Preferably it is 0.1 weight% or more. Moreover, from a viewpoint of suppressing the sticky feeling after washing | cleaning and suppressing a clogging of the porous film | membrane inside a foam discharge container, 2 weight% or less is preferable, More preferably, it is 1 weight% or less. From these, the content of the copolymer is preferably 0.01 to 2% by weight, more preferably 0.1 to 1% by weight.

  In addition, the foam cleaning composition of the present invention may contain a polyhydric alcohol in order to suppress a feeling of sticking after towel drying and to impart a moderate moist feeling. The polyhydric alcohol used is not particularly limited. For example, glycerin, diglycerin, 1,3-butylene glycol, ethylene glycol, propylene glycol, dipropylene glycol, sorbitol, maltitol, 1,2-pentanediol, 1 , 2-hexanediol, 1,2-octanediol and the like. Among these, one can be used alone, or two or more can be used in appropriate combination.

  The content of the polyhydric alcohol is not particularly limited as long as the effect of the present invention is exhibited, but usually 3% by weight in the composition from the viewpoint of suppressing the feeling of sticking after towel drying and imparting a moderate moist feeling. The above is preferable, and more preferably 5% by weight or more. Moreover, from a viewpoint of suppressing the irritation | stimulation to skin and the sticky feeling after washing | cleaning, 20 weight% or less is preferable, More preferably, it is 15 weight% or less. Accordingly, the content of the polyhydric alcohol is preferably 3 to 20% by weight, more preferably 5 to 15% by weight.

  In the foam cleaning composition of the present invention, within the range not impairing the effects of the present invention, in addition to the above-described components, components usually used in cosmetics, for example, fresheners, extracts derived from animals and plants, derived from animals and plants Fats and oils, silicones, lower alcohols, water-soluble polymers, moisturizers, ultraviolet absorbers, flame retardants, metal sequestering agents, vitamins, antioxidants, antiseptics / disinfectants, pH adjusters, antioxidants, colorants, Various fragrance | flavors, water, etc. can be mix | blended suitably according to the objective.

  By filling the foam discharge container with the foam cleaning composition described in detail above, the foam cleaning agent according to the present invention is obtained. The foam discharge container used in the present invention means a non-aerosol type foam discharge container other than an aerosol type using a propellant, and the foam cleaning composition filled in the discharge container is mixed with air. And it is a container which can be discharged in foam form by allowing a porous membrane to pass through. Specifically, a pump former, a squeeze former, etc. can be illustrated.

  In addition, one or a plurality of porous membranes inside the discharge container are provided, and the number of pores in the membrane is not particularly limited, but 100 to 400 mesh is preferable, and 200 to 300 mesh is preferable from the viewpoint of fine foam quality. It is more preferable to use those.

  The foam cleaning composition of the present invention can be produced by a conventional method, and the foam cleaning agent filled with the composition in a foam discharge container is used for body cleaning such as a facial cleanser, body soap, hand soap, shampoo and the like. It can be used as an agent. Among them, it is excellent in foaming power at the time of discharge and has a fine foam quality, so it is suitable for use as a skin cleanser, especially a facial cleanser, body soap, hand soap, etc. be able to.

  EXAMPLES Next, although this invention is demonstrated still in detail based on an Example, this invention is not limited only to these Examples.

(Production Example 1: Preparation of composition for foam cleaning agent)
According to the composition described in Table 1 and Table 2, each component was mixed by the conventional method, and each foam cleaning composition of Examples 1-6 and Comparative Examples 1-3 was prepared. Further, the blending amount represents “% by weight” unless otherwise specified. In addition, in the table, Polyquaternium-55 used STYLEZE W-10 (trade name, manufactured by ISP), and the compounding amount of each component was converted into a pure component.

(Test Example 1: Evaluation of low-temperature stability of the preparation)
The foam cleaning compositions of Examples 1 to 6 and Comparative Examples 1 to 3 were each enclosed in a 50 mL transparent sample tube, stored in a thermostatic bath at −3 ° C. for 120 hours, and visually in accordance with the following evaluation criteria. And evaluated. The results are shown in Tables 1-2.

<Evaluation criteria for low-temperature stability>
○: Precipitation and separation are not recognized ×: Precipitation and separation are recognized

(Test Example 2: Evaluation of foaming power)
About 1 g of each detergent composition for foams of Examples 1 to 6 and Comparative Examples 1 to 3 was put on a palm and actually foamed, and the foaming power was evaluated by 20 professional panels based on the following evaluation criteria. The results are shown in Tables 1-2.

<Evaluation criteria>
○: Good (15/20 people answered that they have excellent foaming properties)
△: Normal (6 to 14 out of 20 responded that they have excellent foaming properties)
X: Defect (answer that 5 or less of 20 people are excellent in foaming property)

(Test Example 3: Evaluation of detergency)
A keratin cloth (3 cm × 3 cm) is dipped in warmed artificial sebum to give a contaminated cloth. This is 50 ° C. in a 10% aqueous solution of each of the foam detergent compositions of Examples 1-6 and Comparative Examples 1-3. And then washed with water. The detergency (%) of each sample was evaluated according to the following evaluation criteria by calculating the removal rate of artificial sebum from the change in the weight of the contaminated cloth by the following formula. The results are shown in Tables 1-2.
Detergency (%) = (Artificial sebum amount at application-Artificial sebum amount after washing) / (Artificial sebum amount at application) x 100

  Artificial sebum is 40% by weight of Tonshi, 13% by weight of oleic acid, 12% by weight of myristic acid, 12% by weight of squalene, 10% by weight of paraffin wax, 3% by weight of monoglyceryl stearate, 2% by weight of cholesterol, Red No. 202 The remaining composition was prepared and used.

<Evaluation criteria>
○: Detergency 70% or more Δ: Detergency 30% or more and less than 70% ×: Detergency 30% or less

(Production Example 2: Preparation of foam cleaning agent)
Pump formers having two porous membranes of 200 mesh and 255 mesh (commercial name: F2 pump former: Daiwa Can Co., Ltd.) The foam detergents of Examples 7 to 12 and Comparative Examples 4 to 6 were used respectively.

(Test Example 4: Evaluation of fineness of foam grain)
Each foam cleaning agent of Examples 7-12 and Comparative Examples 4-6 was used by 20 professional panels, and the foam quality immediately after discharge was evaluated based on the following evaluation criteria. The results are shown in Tables 3-4.

<Evaluation criteria>
○: Good (15 or more out of 20 responded that they were fine bubbles)
Δ: Normal (6 to 14 out of 20 responded that they were fine bubbles)
X: Defect (answer that 5 or less of 20 people are fine bubbles)

(Test Example 5: Evaluation of foam glutinous)
Each of the foam cleaning agents of Examples 7 to 12 and Comparative Examples 4 to 6 was used by 20 professional panels, and the foaminess immediately after discharge was evaluated based on the following evaluation criteria. The results are shown in Tables 3-4.

<Evaluation criteria>
○: Good (15 out of 20 respondents said that foam is good)
△: Normal (6 to 14 out of 20 responded that foam is good)
×: Defect (answer that 5 or less of 20 people have good foam)

(Test Example 6: Evaluation of clogging)
Each foam-like cleaning agent of Examples 7 to 12 and Comparative Examples 4 to 6 was subjected to a use test once a day for 30 days, and the discharge state of each time was evaluated based on the following evaluation criteria. The results are shown in Tables 3-4.

<Evaluation criteria>
○: Bubbles of approximately the same amount are discharged from the first day of the test to the last day. Δ: The amount of foam discharged is clearly reduced from the first day of the test to the last day. And bubbles do not discharge

  From the results of Tables 1 and 2, the foam detergent composition of the present invention is excellent in foaming power and detergency, and does not cause precipitation of an anionic surfactant and separation of the preparation under low temperature storage. It can be seen that the storage stability is excellent. Moreover, from the results of Tables 3 to 4, the foam discharged from the foam cleaning composition of the present invention using a foam discharge container such as a pump former forms a fine creamy foam and has an excellent effect on the foam. It can be seen that clogging does not occur.

Hereinafter, the formulation example of the composition for foam cleaning agents which concerns on this invention is shown. The content is% by weight.
(Prescription example: facial cleanser)
Palm oil fatty acid diethanolamide 4.0
Polyquaternium-55 0.4
Lauric acid 3.0
Myristic acid 1.0
Stearic acid 1.0
Palmitic acid 1.0
Triethanolamine 5.0
Glycerin 3.0
Dipropylene glycol 2.0
Sorbitol 5.0
Menthol 0.2
Methyl paraoxybenzoate 0.1
Propyl paraoxybenzoate 0.1
Total remaining amount of purified water 100.0

  In the foam cleaning composition and the foam cleaning agent of the present invention, the foam discharged from a foam discharge container such as a pump former has excellent foaming properties, forms fine creamy foam, and has excellent cleaning power. Therefore, it can be suitably used as a foam cleaning agent for the body such as a facial cleanser, body soap, hand soap and the like.

Claims (3)

A foam cleaning composition comprising an anionic surfactant, a fatty acid alkylolamide, and a copolymer having a monomer represented by the following A to C as a copolymerization component.

[In formula, R represents a hydrogen atom or a C1-C5 alkyl group. ]

[In the formula, P represents NR ² . R ¹ , R ² , R ³ and R ⁴ each independently represent a hydrogen atom or an alkyl group having 1 to 5 carbon atoms. R ⁵ represents an alkylene group having 2 to 16 carbon atoms. ]

[In the formula, P represents NR ² . R ¹ , R ² , R ³ and R ⁴ each independently represent a hydrogen atom or an alkyl group having 1 to 5 carbon atoms. R ⁵ represents an alkylene group having 2 to 16 carbon atoms. R ⁶ represents an alkyl group having 9 to 24 carbon atoms. M ^- is a halogen ion, p- toluenesulfonate ion or phosphate ion. ]   The foam cleaning composition according to claim 1, wherein the copolymer is polyquaternium-55.   The foam cleaning agent filled with the foam cleaning composition of Claim 1 or 2 in the foam discharge container.