JP4013200B2 - Sheet-shaped pack cosmetic and method for producing the same - Google Patents
Sheet-shaped pack cosmetic and method for producing the same Download PDFInfo
- Publication number
- JP4013200B2 JP4013200B2 JP2003142905A JP2003142905A JP4013200B2 JP 4013200 B2 JP4013200 B2 JP 4013200B2 JP 2003142905 A JP2003142905 A JP 2003142905A JP 2003142905 A JP2003142905 A JP 2003142905A JP 4013200 B2 JP4013200 B2 JP 4013200B2
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- Prior art keywords
- sheet
- amino acid
- pack cosmetic
- shaped pack
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Description
【０００１】
【発明の属する技術分野】
本発明は、シート状パック化粧料およびその製造方法に関し、さらに詳しくは、保湿効果および整肌効果が良好で、かつ保存安定性が優れたシート状パック化粧料およびその製造方法に関する。
【０００２】
【従来の技術】
アミノ酸やアミノ酸誘導体は、保湿効果が良好で、皮膚に対する活性作用を有し、かつ皮膚に対して栄養剤として働くことが報告されている（例えば、非特許文献１参照）。
【０００３】
【非特許文献１】
フレグランス ジャーナル Ｎｏ.８９（１９８８）、ｐ．１０２〜 １０８
【０００４】
従って、このアミノ酸やアミノ酸誘導体を化粧水や美容液などの皮膚用化粧品に利用すると、肌のはり、しわ、しみなどを改善する整肌効果が期待できるものと考えられる。しかしながら、アミノ酸やアミノ酸誘導体の水溶液を化粧品に利用する場合、その化粧品中のアミノ酸やアミノ酸誘導体が細菌や真菌により汚染されるおそれがあるため、それらの菌による汚染を防止する目的で、防腐剤が配合されることになる。また、変色や変臭を防止するためにキレート剤や酸化防止剤なども配合される。
【０００５】
しかしながら、防腐剤やキレート剤、酸化防止剤などは、それらの人体への影響を考慮して、規制された範囲内の配合量で使用し、かつ、それらの効果が充分に発現するようにしなければならないが、アミノ酸やアミノ酸誘導体の種類や量によっては、その効果が充分であるとは言えなかった。
【０００６】
また、アミノ酸を含有するセリシンと泥との混合物からなる化粧料を基材に塗布または含浸させ、泥による美顔、美肌効果を期待するとともに、セリシンによる保湿、美肌効果を期待した化粧用パックシートが提案されている（特許文献１参照）。
【０００７】
【特許文献１】
特開平１１−２２８３４４号公報（第２〜３頁）
【０００８】
しかしながら、上記化粧用パックシートの場合は、３０％以上の水を使用している上に、泥中の水分も存在するため、セリシンの保存安定性が悪く、また、保湿効果の点においても、充分なものとは言えなかった。
【０００９】
【発明が解決しようとする課題】
従って、本発明は、アミノ酸やアミノ酸誘導体をシート状パック化粧料に利用するにあたって、アミノ酸やアミノ酸誘導体の有する良好な保湿効果や整肌効果を最大限に発現させ、かつ製品としての保存安定性が優れたシート状パック化粧料を提供することを目的とする。
【００１０】
【課題を解決するための手段】
本発明者らは、アミノ酸やアミノ酸誘導体の有する保湿効果および整肌効果を最大限に引き出し、防腐剤やキレート剤、酸化防止剤などの安定化剤の添加量が少なくても、保存安定性が優れたシート状パック化粧料を得るため鋭意検討を重ねた結果、シート状基材にアミノ酸やアミノ酸誘導体などを特定の態様で保持させ、かつ、その水分量を５質量％以下にしてシート状パック化粧料を構成するときは、保湿効果および整肌効果が良好で、かつ菌汚染や変色、変臭がなく、保存安定性が優れたシート状パック化粧料を提供でき、それによって、前記課題を解決できることを見出し、本発明を完成するにいたった。
すなわち、本発明は、シート状基材にセリン、アルギニンおよびアスパラギン酸よりなる群から選ばれる２種以上のアミノ酸を保持させてなり、その水分量が５質量％以下であることを特徴とするシート状パック化粧料に関する。
また、本発明は、アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種を、水または水を主剤とする水性液に溶解して、得られた配合液をシート状基材に塗布、噴霧または含浸させ、その後、水分量が５質量％以下になるまで乾燥することにより得られたことを特徴とするシート状パック化粧料に関する。
さらに、本発明は、アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種を、水または水を主剤とする水性液に溶解して、得られた配合液をシート状基材に塗布、噴霧または含浸させ、その後、水分量が５質量％以下になるまで乾燥することを特徴とするシート状パック化粧料の製造方法に関する。
【００１１】
【発明の実施の形態】
以下、本発明の実施の形態について詳細に説明する。まず、本発明のシート状パック化粧料の作製方法について説明すると、本発明のシート状パック化粧料は、例えば、アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種を水に溶解させ、得られた水溶液をシート状基材に含浸させ、水分量が５質量％以下になるまで水を乾燥することによって作製される。
【００１２】
そして、本発明のシート状パック化粧料の使用にあたっては、その使用前に水または化粧水や美容液などの水溶液をシート状パック化粧料に含浸させ、その状態で顔などの皮膚にパックを行うことによって、良好な保湿効果および整肌効果を発現させることができる。
【００１３】
本発明において、シート状パック化粧料の水分量を５質量％以下にしているのは、水分量が５質量％より多くなると、アミノ酸やアミノ酸誘導体が細菌や真菌などの菌によって汚染を受けたり、変色や変臭を生じるようになるためであり、この水分量は少ないほど好ましく、特に３質量％以下であることが好ましい。
【００１４】
本発明において用いるアミノ酸とは、例えば、アラニン、アルギニン、アスパラギン、アスパラギン酸、シトルリン、システイン、シスチン、グルタミン酸、グルタミン、グリシン、ヒスチジン、オキシプロリン、イソロイシン、ロイシン、リジン、メチオニン、オルニチン、フェニルアラニン、プロリン、セリン、スレオニン、トリプトファン、チロシン、バリンから選ばれる１種または２種以上であって、Ｌ体、Ｄ体、ＤＬ体のいずれであってもよく、また塩として用いてもよい。
【００１５】
本発明において用いるアミノ酸誘導体とは、前記のアミノ酸を環化、アシル化またはエステル化したものであって、具体的には、例えば、ピロリドンカルボン酸塩、アセチルシステイン、アセチルメチオニン、アシルグルタミン酸塩、アシルグリシン塩、アシルアラニン塩、アシルアルギニンエチルエステル塩などが挙げられる。
【００１６】
本発明において、特に好ましいアミノ酸としては、セリン、プロリン、アルギニン、グルタミン酸、アスパラギン酸、アラニンなどが挙げられ、それらの中でも、セリン、アルギニン、アスパラギン酸が好ましく、とりわけ、それらのアミノ酸を２種以上組み合わせて用いることが好ましい。すなわち、これらのアミノ酸はいずれも保湿性が良好である上に、セリンは中性アミノ酸で、アルギニンは塩基性アミノ酸であり、アスパラギン酸は酸性アミノ酸であることから、ｐＨを皮膚と同じ弱酸性にするには、これらのアミノ酸を組み合わせて用いることが好ましいからである。
【００１７】
本発明のシート状パック化粧料の作製方法をより具体的に説明すると、本発明のシート状パック化粧料は、例えば、次の方法によって作製される。
【００１８】
まず、上記アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種を水または水を主剤とする水性液に溶解して、配合液とする。その際、アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種の濃度を０．００１〜５０質量％にすることが好ましい。
【００１９】
そして、得られた配合液をシート状基材に塗布または噴霧するか、あるいはシート状基材を配合液中に浸漬して、シート状基材に配合液を含浸させ、その後、水分量が５質量％以下になるまで乾燥することによって、本発明のシート状パック化粧料が得られる。
【００２０】
上記のようにして本発明のシート状パック化粧料を作製した場合、通常、シート状パック化粧料中にアミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種が０．０００１〜２０質量％含有されることになるが、特にアミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種が０．０１〜１０質量％含有されるようにすることが好ましい。
【００２１】
本発明において用いるシート状基材としては、例えば、不織布、織布、繊維、紙、シートなどが挙げられ、その材料としては、例えば、パルプ、レーヨン、コットン、ポリプロピレン、ポリエチレンなどが挙げられるが、本発明においては、特にパルプの不織布が好ましい。
【００２２】
また、本発明においては、前記アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種を含む配合液中に美白剤を含有させ、アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種と美白剤とを含有するシート状パック化粧料とすることができ、その美白剤を含有させることによって、アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種による良好な保湿効果および整肌効果に加えて、顔などの肌に美しさを伴った白さを付与することができる。
【００２３】
美白剤としては、例えば、ビタミンＣ、リン酸アスコルビン酸マグネシウム、アスコルビン酸グルコシドなどのビタミンＣ誘導体、アルブチン、エラグ酸、ルシノール、カンゾウエキス、カミツレエキス、コウジ酸、プラセンタエキスなどが挙げられ、特にリン酸アスコルビン酸マグネシウム、アスコルビン酸グルコシドが好ましい。これらの美白剤はアミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種に対して質量比で１／１００〜１０／１（美白剤／アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種）の範囲で含有させることが好ましく、特に１／５０〜５／１の範囲で含有させることが好ましい。
【００２４】
本発明のシート状パック化粧料には、上記のアミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種や美白剤以外に、それらの効果を損なわない範囲で他の成分を含有させることができる。そのような成分としては、例えば、アルコール、金属イオン封鎖剤、増粘剤、油分、薬剤、香料、着色料、紫外線吸収剤、界面活性剤、防腐剤などが挙げられる。
【００２５】
上記アルコールとしては、例えば、エタノール、イソプロパノールなどの１価のアルコール、エチレングリコール、プロピレングリコール、１，３−ブチレングリコール、１，２−ペンタンジオールなどの２価のアルコール、グリセリンなどの３価のアルコール、ペンタエリスリトールなどの４価のアルコール、キシリトールなどの５価のアルコール、ソルビトール、マンニトールなどの６価のアルコール、マルトール、キシリトース、デンプン分解糖還元アルコールなどの糖アルコールなどが挙げられる。
【００２６】
金属イオン封鎖剤としては、例えば、１−ヒドロキシエタン−１，１−ジフォスホン酸、１−ヒドロキシエタン−１，１−ジフォスホン酸四ナトリウム塩、エデト酸二ナトリウム、エデト酸三ナトリウム、エデト酸四ナトリウム、クエン酸ナトリウム、ポリリン酸ナトリウム、メタリン酸ナトリウム、グルコン酸などが挙げられる。
【００２７】
増粘剤としては、例えば、アラビアガム、カラギーナン、カラヤガム、トラガカントガム、キャロブガム、クインスシード、カゼイン、デキストリン、ゼラチン、ペクチン酸ナトリウム、アラギン酸ナトリウム、メチルセルロース、エチルセルロース、ＣＭＣ（カルボキシメチルセルロース）、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ＰＶＡ（ポリビニルアルコール）、ＰＶＭ（ポリビニルメチルエーテル）、ＰＶＰ（ポリビニルピロリドン）、ポリアクリル酸ナトリウム、カルボキシビニルポリマー、ローカストビーンガム、グアーガム、タマリンガム、ジアルキルジメチルアンモニウム硫酸セルロース、キサンタンガム、ケイ酸アルミニウムマグネシウム、ベントナイト、ヘクトライトなどが挙げられる。
【００２８】
油分としては、例えば、アボガト油、ツバキ油、タートル油、マカデミアナッツ油、トウモロコシ油、ミンク油、オリーブ油、ナタネ油、卵黄油、ゴマ油、パーシック油、小麦胚芽油、サザンカ油、ヒマシ油、アマニ油、サフラワー油、綿実油、エノ油、大豆油、落花生油、茶実油、カヤ油、コメヌカ油、シナギリ油、日本キリ油、ホホバ油、胚芽油、トリグリセリン、トリオクタン酸グリセリン、トリイソパルミチン酸グルセリンなどの液体油脂、カカオ脂、ヤシ油、馬脂、硬化ヤシ油、パーム油、牛脂、硬化牛脂、パーム核油、豚脂、牛骨脂、モクロウ核油、硬化油、牛脚油、モクロウ、硬化ヒマシ油などの固体油脂、ミツロウ、カンデリラロウ、綿ロウ、カルナバロウ、ベイベリーロウ、イボタロウ、鯨ロウ、モンタンロウ、ヌカロウ、ラノリン、カポックロウ、酢酸ラノリン、液状ラノリン、サトウキビロウ、ラノリン脂肪酸イソプロピル、ラウリン酸ヘキシル、セラックロウ、ＰＯＥ（ポリオキシエチレン）ラノリンアルコールアセテート、ＰＯＥコレステロールエーテル、ラノリン脂肪酸ポリエチレングリコール、ＰＯＥ水素添加ラノリンアルコールエーテルなどのロウ類、流動パラフィン、オゾケライト、スクワレン、ピリスタン、パファフィン、セレシン、スクワラン、ワセリン、マイクロクリスタンワックスなどの炭化水素などが挙げられる。
【００２９】
本発明のシート状パック化粧料の適用部位としては、例えば、顔、首、胸部、腕部、腹部、足部、背中、頭部などが挙げられる。従って、本発明のシート状パック化粧料は、形状に関して特に制限されることなく、上記の適用部位に適した形状にすればよい。例えば、顔に適用する場合でも、全顔、目元、額、頬、鼻など、それぞれの形状に適するようにすればよい。
【００３０】
【実施例】
以下、実施例を挙げて本発明をより具体的に詳細に説明する。ただし、本発明はそれらの実施例のみに限定されるものではない。
【００３１】
実施例１〜４および比較例１〜３
シート状パック化粧料の作製にあたって用いる配合液を表１および表２に示す組成で調製し、シート状基材としてはパルプ製の不織布（秤量：３５ｇ／ｍ2 ）を１５０ｃｍ×３０ｃｍに裁断して１０枚積層したものを用い、その不織布に前記配合液を塗布することによって含浸させ、その後、加熱または風乾して水分を乾燥することにより（それぞれのシート状パック化粧料に応じて時間を変えて乾燥する）、シート状パック化粧料を作製した。それぞれのシート状パック化粧料における水分量を表１および表２に示す。
【００３２】
表１および表２に示す各成分の配合液中の量は質量％によるものであり、精製水の量を示す残余とは全体として１００質量％にする量を言う。そして、実施例４や比較例２ではリン酸アスコルビン酸マグネシウムとアスコルビン酸グルコシドを配合しているが、それらは美白剤である。また、実施例１〜４および比較例１〜３のいずれにもグリセリンとブチレングリコールを配合しているが、それらはこの種の化粧品に通常配合されるものであるからであり、グリセリンやブチレングリコールは必ずしも必要ではない。
【００３３】
そして、シート状パック化粧料の水分量は、カールフィッシャー水分計によって、シート状パック化粧料全体中の水分量を測定することによって求めた。
【００３４】
【表１】
【表２】
得られた実施例１〜４および比較例１〜３のシート状パック化粧料を用いて保湿・整肌効果の評価を行うとともに、それらのシート状パック化粧料の保存安定性を評価した。その結果を表３に示す。なお、保湿・整肌効果の評価方法および保存安定性の評価方法は次の通りである。
【００３７】
保湿・整肌効果の評価方法：
実施例１〜４および比較例１〜３のシート状パック化粧料のそれぞれに、精製水を含浸させ、その精製水を含浸した状態のシート状パック化粧料を１０人の専門パネラーの顔面（全顔）に５分間パックを行って保湿・整肌効果を評価させ、その評価結果を次の基準により点数化する。
【００３８】
５：優れた保湿・整肌効果が感じられる。
４：良好な保湿・整肌効果が感じられる。
３：保湿・整肌効果が感じられる。
２：保湿・整肌効果がほとんど感じられない。
１：保湿・整肌効果がまったく感じられない。
【００３９】
そして、１０人の専門パネラーの評価点の平均値を求め、表３には保湿・整肌効果を次のように記号化して示す。
◎：パネラー１０人の平均値が４点以上
○：パネラー１０人の平均値が３点以上４点未満
△：パネラー１０人の平均値が２点以上３点未満
×：パネラー１０人の平均値が２点未満
【００４０】
保存安定性の評価方法：
実施例１〜４および比較例１〜３のシート状パック化粧料をそれぞれガラス容器に入れ、５０℃で３０日間保存し、シート状パック化粧料の変色の有無を目視により観察するとともに、変臭の有無を調べた。その結果を次の基準により記号化して表３に示す。
◎：変色・変臭がまったくない。
○：変色・変臭がほとんどない。
△：変色・変臭がある。
×：明らかな変色・変臭がある。
【００４１】
上記のような保湿・整肌効果の評価結果および保存安定性の評価結果を表３に示すが、表３にはシート状パック化粧料の水分量についても再度示す。
【００４２】
【表３】
表３に示すように、実施例１〜４のシート状パック化粧料は、保湿・整肌効果が良好で、かつ保存安定性が優れていた。これに対して、アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種を含有していない比較例１のシート状パック化粧料は、保湿・整肌効果がなく、また、アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種を含有させずに美白剤であるリン酸アスコルビン酸マグネシウムとアスコルビン酸グルコシドのみを含有させた比較例２のシート状パック化粧料も、保湿・整肌効果が充分でなく、アミノ酸およびアミノ酸誘導体よりなる群から選ばれる少なくとも１種を含有させているものの水分量が多い比較例３のシート状パック化粧料は、保存安定性に欠けていた。
【００４４】
【発明の効果】
以上説明したように、本発明によれば、保湿効果および整肌効果が良好で、かつ保存安定性が優れたシート状パック化粧料を提供することができる。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a sheet-shaped pack cosmetic and a method for producing the same, and more particularly to a sheet-shaped pack cosmetic having a good moisturizing effect and skin conditioning effect and excellent storage stability and a method for producing the same.
[0002]
[Prior art]
It has been reported that amino acids and amino acid derivatives have a good moisturizing effect, have an active action on the skin, and act as a nutrient on the skin (see, for example, Non-Patent Document 1).
[0003]
[Non-Patent Document 1]
Fragrance Journal No. 89 (1988), p. 102-108
[0004]
Therefore, when this amino acid or amino acid derivative is used in cosmetics for skin such as skin lotion or beauty essence, it is considered that a skin conditioning effect that improves skin peeling, wrinkles, spots and the like can be expected. However, when an aqueous solution of amino acids or amino acid derivatives is used in cosmetics, the amino acid or amino acid derivative in the cosmetics may be contaminated by bacteria or fungi. Will be blended. In addition, chelating agents and antioxidants are also blended to prevent discoloration and odor.
[0005]
However, preservatives, chelating agents, antioxidants, etc. should be used in a regulated amount in consideration of their effects on the human body and their effects should be fully expressed. However, depending on the types and amounts of amino acids and amino acid derivatives, the effect was not sufficient.
[0006]
In addition, a cosmetic pack sheet that is applied to or impregnates a base material made of a mixture of amino acid-containing sericin and mud on the base material to expect a beautiful face and skin effect by mud, and a moisturizing and skin-beautifying effect by sericin. It has been proposed (see Patent Document 1).
[0007]
[Patent Document 1]
JP-A-11-228344 (pages 2 to 3)
[0008]
However, in the case of the above-described cosmetic pack sheet, 30% or more of water is used, and water in the mud is also present, so the storage stability of sericin is poor, and also in terms of the moisturizing effect, That wasn't enough.
[0009]
[Problems to be solved by the invention]
Therefore, the present invention, when using amino acids and amino acid derivatives in sheet-like pack cosmetics, maximizes the good moisturizing effect and skin conditioning effect of amino acids and amino acid derivatives, and has a storage stability as a product. An object is to provide an excellent sheet-shaped pack cosmetic.
[0010]
[Means for Solving the Problems]
The present inventors have maximized the moisturizing effect and skin conditioning effect of amino acids and amino acid derivatives, and have storage stability even when the amount of stabilizers such as preservatives, chelating agents and antioxidants is small. As a result of intensive studies to obtain an excellent sheet-shaped pack cosmetic, a sheet-shaped pack is made to hold amino acids and amino acid derivatives in a specific form on a sheet-like base material, and its water content is 5% by mass or less. When constituting a cosmetic, it is possible to provide a sheet-shaped pack cosmetic that has a good moisturizing effect and skin conditioning effect, is free of bacterial contamination, discoloration, and odor, and has excellent storage stability. The inventors have found that this can be solved, and have completed the present invention.
That is, the present invention is a sheet characterized in that two or more amino acids selected from the group consisting of serine, arginine and aspartic acid are held in a sheet-like base material, and the water content thereof is 5% by mass or less. In the form of pack cosmetics.
In the present invention, at least one selected from the group consisting of an amino acid and an amino acid derivative is dissolved in water or an aqueous liquid containing water as a main ingredient, and the obtained compounded liquid is applied to a sheet-like substrate, sprayed, or The present invention relates to a sheet-like pack cosmetic characterized by being impregnated and then dried until the water content is 5% by mass or less.
Further, in the present invention, at least one selected from the group consisting of an amino acid and an amino acid derivative is dissolved in water or an aqueous liquid containing water as a main component, and the obtained compounded liquid is applied to a sheet-like substrate, sprayed, or The present invention relates to a method for producing a sheet-shaped pack cosmetic, which is impregnated and then dried until the water content becomes 5% by mass or less.
[0011]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments of the present invention will be described in detail. First, the method for producing the sheet-shaped pack cosmetic of the present invention will be described. The sheet-shaped pack cosmetic of the present invention is obtained by, for example, dissolving at least one selected from the group consisting of amino acids and amino acid derivatives in water. It is prepared by impregnating a sheet-like base material with an aqueous solution and drying the water until the water content is 5% by mass or less.
[0012]
In using the sheet-shaped pack cosmetic of the present invention, before use, the sheet-shaped pack cosmetic is impregnated with water or an aqueous solution such as a lotion or a cosmetic liquid, and in that state, the pack is applied to the skin such as the face. By this, a favorable moisturizing effect and skin conditioning effect can be expressed.
[0013]
In the present invention, the moisture content of the sheet-shaped pack cosmetic is 5% by mass or less, when the moisture content is more than 5% by mass, the amino acid or amino acid derivative is contaminated by bacteria such as bacteria or fungi, This is because discoloration and odor change occur, and the smaller the moisture content, the more preferable, and particularly preferably 3% by mass or less.
[0014]
Amino acids used in the present invention include, for example, alanine, arginine, asparagine, aspartic acid, citrulline, cysteine, cystine, glutamic acid, glutamine, glycine, histidine, oxyproline, isoleucine, leucine, lysine, methionine, ornithine, phenylalanine, proline, One or more selected from serine, threonine, tryptophan, tyrosine and valine, which may be any of L-form, D-form and DL-form, and may be used as a salt.
[0015]
The amino acid derivatives used in the present invention are those obtained by cyclization, acylation or esterification of the above-mentioned amino acids. Specifically, for example, pyrrolidone carboxylate, acetylcysteine, acetylmethionine, acylglutamate, acyl Examples thereof include glycine salt, acylalanine salt, acylarginine ethyl ester salt and the like.
[0016]
In the present invention, particularly preferred amino acids include serine, proline, arginine, glutamic acid, aspartic acid, alanine, etc. Among them, serine, arginine, and aspartic acid are preferable, and in particular, a combination of two or more of these amino acids. Are preferably used. In other words, all of these amino acids have good moisturizing properties, serine is a neutral amino acid, arginine is a basic amino acid, and aspartic acid is an acidic amino acid. This is because these amino acids are preferably used in combination.
[0017]
The production method of the sheet-shaped pack cosmetic of the present invention will be described more specifically. The sheet-shaped pack cosmetic of the present invention is produced, for example, by the following method.
[0018]
First, at least one selected from the group consisting of the above amino acids and amino acid derivatives is dissolved in water or an aqueous liquid containing water as a main ingredient to obtain a compounded liquid. In that case, it is preferable that the concentration of at least one selected from the group consisting of an amino acid and an amino acid derivative is 0.001 to 50% by mass.
[0019]
And the obtained compounded liquid is applied or sprayed on the sheet-like substrate, or the sheet-like substrate is immersed in the compounded solution to impregnate the sheet-like substrate with the compounded solution. The sheet-shaped pack cosmetic of the present invention can be obtained by drying until the content is less than or equal to mass%.
[0020]
When the sheet-shaped pack cosmetic of the present invention is produced as described above, usually 0.0001 to 20% by mass of at least one selected from the group consisting of amino acids and amino acid derivatives is contained in the sheet-shaped pack cosmetic. In particular, it is preferable that at least one selected from the group consisting of amino acids and amino acid derivatives is contained in an amount of 0.01 to 10% by mass.
[0021]
Examples of the sheet-like substrate used in the present invention include non-woven fabrics, woven fabrics, fibers, papers, sheets, and the like, and examples of the materials include pulp, rayon, cotton, polypropylene, polyethylene, In the present invention, a nonwoven fabric of pulp is particularly preferable.
[0022]
Further, in the present invention, a whitening agent is contained in a combination liquid containing at least one selected from the group consisting of the above amino acids and amino acid derivatives, and at least one selected from the group consisting of amino acids and amino acid derivatives and a whitening agent, In addition to the good moisturizing effect and skin conditioning effect due to at least one selected from the group consisting of amino acids and amino acid derivatives by containing the whitening agent, the face-shaped pack cosmetic containing Whiteness with beauty can be given to the skin.
[0023]
Examples of the whitening agent include vitamin C, vitamin C derivatives such as magnesium ascorbate phosphate and glucoside ascorbate, arbutin, ellagic acid, lucinol, licorice extract, chamomile extract, kojic acid, and placenta extract. Acid magnesium ascorbate and ascorbyl glucoside are preferred. These whitening agents are 1/100 to 10/1 in mass ratio (at least one selected from the group consisting of whitening agents / amino acids and amino acid derivatives) to at least one selected from the group consisting of amino acids and amino acid derivatives. It is preferable to make it contain in the range, and it is especially preferable to make it contain in the range of 1 / 50-5 / 1.
[0024]
In addition to at least one selected from the group consisting of the above amino acids and amino acid derivatives and a whitening agent, the sheet-like pack cosmetic of the present invention can contain other components as long as the effects thereof are not impaired. Examples of such components include alcohols, sequestering agents, thickeners, oils, chemicals, fragrances, coloring agents, ultraviolet absorbers, surfactants, preservatives, and the like.
[0025]
Examples of the alcohol include monohydric alcohols such as ethanol and isopropanol, dihydric alcohols such as ethylene glycol, propylene glycol, 1,3-butylene glycol, and 1,2-pentanediol, and trihydric alcohols such as glycerin. , Tetravalent alcohols such as pentaerythritol, pentavalent alcohols such as xylitol, hexavalent alcohols such as sorbitol and mannitol, and sugar alcohols such as maltol, xylitol and amylolytic sugar-reducing alcohol.
[0026]
Examples of the sequestering agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and tetrasodium edetate. Sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid and the like.
[0027]
Examples of the thickener include gum arabic, carrageenan, caraya gum, gum tragacanth, carob gum, quince seed, casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, CMC (carboxymethylcellulose), hydroxyethylcellulose, hydroxy Propyl cellulose, PVA (polyvinyl alcohol), PVM (polyvinyl methyl ether), PVP (polyvinyl pyrrolidone), sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarin gum, dialkyldimethylammonium cellulose sulfate, xanthan gum, aluminum silicate Examples thereof include magnesium, bentonite, and hectorite.
[0028]
Oils include, for example, avocato oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern oil, castor oil, flaxseed oil, Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin, trioctanoic acid glycerin, glycerin triisopalmitate Liquid oils such as cocoa butter, coconut oil, horse fat, hydrogenated coconut oil, palm oil, beef tallow, hydrogenated beef tallow, palm kernel oil, pork tallow, beef bone fat, owl kernel oil, hydrogenated oil, cow leg oil, owl, Solid fats and oils such as hardened castor oil, beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nukarou Lanolin, kapok wax, lanolin acetate, liquid lanolin, sugarcane wax, lanolin fatty acid isopropyl, hexyl laurate, shellac wax, POE (polyoxyethylene) lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, etc. Examples thereof include hydrocarbons such as waxes, liquid paraffin, ozokerite, squalene, pyristan, puffafin, ceresin, squalane, petrolatum, and microcrystalline wax.
[0029]
Examples of the application site of the sheet-shaped pack cosmetic of the present invention include face, neck, chest, arm, abdomen, foot, back, head, and the like. Therefore, the sheet-shaped pack cosmetic of the present invention is not particularly limited with respect to the shape, and may be in a shape suitable for the application site. For example, even when applied to the face, it may be adapted to each shape such as the entire face, the eyes, the forehead, the cheek, and the nose.
[0030]
【Example】
Hereinafter, the present invention will be described in more detail with reference to examples. However, this invention is not limited only to those Examples.
[0031]
Examples 1-4 and Comparative Examples 1-3
Formulation liquids used in the preparation of the sheet-shaped pack cosmetics were prepared with the compositions shown in Tables 1 and 2, and a pulp nonwoven fabric (weighed: 35 g / m 2 ) was cut into 150 cm × 30 cm as a sheet-like substrate. Using a laminate of 10 sheets, impregnating the non-woven fabric by applying the compounded liquid, and then heating or air-drying to dry the moisture (change the time according to each sheet pack cosmetic) A sheet-shaped pack cosmetic was prepared. Tables 1 and 2 show the amount of water in each sheet-shaped pack cosmetic.
[0032]
The amount of each component shown in Table 1 and Table 2 in the compounded liquid is based on mass%, and the remainder indicating the amount of purified water refers to the amount to be 100 mass% as a whole. In Example 4 and Comparative Example 2, magnesium ascorbate phosphate and glucoside ascorbate are blended, but they are whitening agents. Moreover, although glycerin and butylene glycol are mix | blended in any of Examples 1-4 and Comparative Examples 1-3, it is because they are normally mix | blended with this kind of cosmetics, and glycerin and butylene glycol. Is not necessarily required.
[0033]
The moisture content of the sheet-shaped pack cosmetic was determined by measuring the moisture content in the entire sheet-shaped pack cosmetic with a Karl Fischer moisture meter.
[0034]
[Table 1]
[Table 2]
The sheet-shaped pack cosmetics of Examples 1 to 4 and Comparative Examples 1 to 3 thus obtained were evaluated for moisturizing / skin conditioning effects, and the storage stability of those sheet-shaped pack cosmetics was evaluated. The results are shown in Table 3. The evaluation method of the moisturizing / skin conditioning effect and the evaluation method of the storage stability are as follows.
[0037]
Method for evaluating moisturizing and skin conditioning effects:
Each of the sheet-shaped pack cosmetics of Examples 1 to 4 and Comparative Examples 1 to 3 was impregnated with purified water, and the sheet-shaped pack cosmetic in a state impregnated with the purified water was subjected to the face of 10 professional panelists (all The face) is packed for 5 minutes to evaluate the moisturizing / skin conditioning effect, and the evaluation result is scored according to the following criteria.
[0038]
5: An excellent moisturizing and skin conditioning effect is felt.
4: Good moisturizing / skin conditioning effect is felt.
3: A moisturizing and skin conditioning effect is felt.
2: Moisturizing and skin conditioning effects are hardly felt.
1: No moisturizing / skin conditioning effect is felt.
[0039]
And the average value of the evaluation score of 10 professional panelists was calculated, and Table 3 shows the moisturizing and skin conditioning effects as symbolized as follows.
◎: The average value of 10 panelists is 4 points or more ○: The average value of 10 panelists is 3 points or more and less than 4 points △: The average value of 10 panelists is 2 points or more and less than 3 points ×: The average value of 10 panelists Is less than 2 points
Storage stability evaluation method:
Each of the sheet-shaped pack cosmetics of Examples 1 to 4 and Comparative Examples 1 to 3 is put in a glass container and stored at 50 ° C. for 30 days. The presence or absence of was investigated. The results are symbolized according to the following criteria and shown in Table 3.
A: No discoloration or odor.
○: Almost no discoloration or odor.
Δ: Discoloration / odor change
×: Clear discoloration / odour.
[0041]
The evaluation results of the moisturizing / skin conditioning effect and the storage stability as described above are shown in Table 3, and Table 3 also shows the moisture content of the sheet-shaped pack cosmetic.
[0042]
[Table 3]
As shown in Table 3, the sheet-shaped pack cosmetics of Examples 1 to 4 had good moisturizing / skin conditioning effects and excellent storage stability. On the other hand, the sheet-like pack cosmetic of Comparative Example 1 that does not contain at least one selected from the group consisting of amino acids and amino acid derivatives has no moisturizing / skin conditioning effect, and also consists of amino acids and amino acid derivatives. The sheet-like pack cosmetic of Comparative Example 2 containing only the whitening magnesium ascorbate and ascorbic acid glucoside without containing at least one selected from the group is also not sufficiently moisturizing / skin conditioning. The sheet-shaped pack cosmetic of Comparative Example 3 containing at least one selected from the group consisting of an amino acid and an amino acid derivative, but having a large water content, lacked storage stability.
[0044]
【The invention's effect】
As described above, according to the present invention, it is possible to provide a sheet-shaped pack cosmetic that has a good moisturizing effect and skin conditioning effect and excellent storage stability.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| JP2003142905A JP4013200B2 (en) | 2003-05-21 | 2003-05-21 | Sheet-shaped pack cosmetic and method for producing the same |
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| Application Number | Priority Date | Filing Date | Title |
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| JP2003142905A JP4013200B2 (en) | 2003-05-21 | 2003-05-21 | Sheet-shaped pack cosmetic and method for producing the same |
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| JP2004345983A JP2004345983A (en) | 2004-12-09 |
| JP4013200B2 true JP4013200B2 (en) | 2007-11-28 |
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