JP3836499B2 - 低硫黄改質法 - Google Patents
低硫黄改質法 Download PDFInfo
- Publication number
- JP3836499B2 JP3836499B2 JP50830092A JP50830092A JP3836499B2 JP 3836499 B2 JP3836499 B2 JP 3836499B2 JP 50830092 A JP50830092 A JP 50830092A JP 50830092 A JP50830092 A JP 50830092A JP 3836499 B2 JP3836499 B2 JP 3836499B2
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- JP
- Japan
- Prior art keywords
- metal
- reforming
- tin
- paint
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 238000002407 reforming Methods 0.000 title claims abstract description 122
- 239000011593 sulfur Substances 0.000 title claims abstract description 107
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 107
- 238000000034 method Methods 0.000 title claims abstract description 106
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 104
- 229910052751 metal Inorganic materials 0.000 claims abstract description 167
- 239000002184 metal Substances 0.000 claims abstract description 167
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 67
- 239000003054 catalyst Substances 0.000 claims abstract description 65
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 62
- 230000008569 process Effects 0.000 claims abstract description 47
- 239000010457 zeolite Substances 0.000 claims abstract description 42
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 38
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 37
- 238000001833 catalytic reforming Methods 0.000 claims abstract description 16
- 238000003763 carbonization Methods 0.000 claims description 100
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 70
- 229910052718 tin Inorganic materials 0.000 claims description 68
- 238000005469 granulation Methods 0.000 claims description 58
- 230000003179 granulation Effects 0.000 claims description 58
- 238000000576 coating method Methods 0.000 claims description 57
- 239000011248 coating agent Substances 0.000 claims description 52
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 51
- 239000011651 chromium Substances 0.000 claims description 45
- 239000003973 paint Substances 0.000 claims description 45
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 43
- 239000000571 coke Substances 0.000 claims description 39
- 229910052804 chromium Inorganic materials 0.000 claims description 38
- 239000004215 Carbon black (E152) Substances 0.000 claims description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 35
- 239000001257 hydrogen Substances 0.000 claims description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims description 30
- 229910001220 stainless steel Inorganic materials 0.000 claims description 29
- 229910052742 iron Inorganic materials 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 150000002739 metals Chemical class 0.000 claims description 24
- 239000010935 stainless steel Substances 0.000 claims description 23
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 20
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 20
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 18
- 229910052782 aluminium Inorganic materials 0.000 claims description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 17
- -1 low moisture Substances 0.000 claims description 17
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- 239000000956 alloy Substances 0.000 claims description 16
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 16
- 239000000377 silicon dioxide Substances 0.000 claims description 16
- 239000011148 porous material Substances 0.000 claims description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052802 copper Inorganic materials 0.000 claims description 13
- 239000010949 copper Substances 0.000 claims description 13
- 229940071182 stannate Drugs 0.000 claims description 13
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 238000005253 cladding Methods 0.000 claims description 11
- 239000012298 atmosphere Substances 0.000 claims description 10
- 150000003606 tin compounds Chemical class 0.000 claims description 10
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 9
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- 125000003118 aryl group Chemical group 0.000 claims description 8
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 8
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- 125000005402 stannate group Chemical group 0.000 claims description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 6
- 229910001887 tin oxide Inorganic materials 0.000 claims description 6
- 229910052785 arsenic Inorganic materials 0.000 claims description 5
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 229910001369 Brass Inorganic materials 0.000 claims description 3
- 239000010951 brass Substances 0.000 claims description 3
- 230000001965 increasing effect Effects 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 claims description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical class [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 2
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- 229910001245 Sb alloy Inorganic materials 0.000 claims 1
- 239000002140 antimony alloy Substances 0.000 claims 1
- KGHMFMDJVUVBRY-UHFFFAOYSA-N antimony copper Chemical compound [Cu].[Sb] KGHMFMDJVUVBRY-UHFFFAOYSA-N 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 238000010410 dusting Methods 0.000 abstract description 2
- 229910000831 Steel Inorganic materials 0.000 description 70
- 239000010959 steel Substances 0.000 description 70
- 239000011135 tin Substances 0.000 description 57
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- 238000004939 coking Methods 0.000 description 46
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 32
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 27
- 238000002474 experimental method Methods 0.000 description 24
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- 238000012360 testing method Methods 0.000 description 16
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 14
- 229910052710 silicon Inorganic materials 0.000 description 14
- 239000010703 silicon Substances 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 13
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- 239000000047 product Substances 0.000 description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
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- 230000002829 reductive effect Effects 0.000 description 10
- 238000005336 cracking Methods 0.000 description 9
- 230000008929 regeneration Effects 0.000 description 9
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- 210000002268 wool Anatomy 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
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- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 5
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- 150000002431 hydrogen Chemical class 0.000 description 5
- 150000001247 metal acetylides Chemical class 0.000 description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
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- 239000007864 aqueous solution Substances 0.000 description 1
- 238000005899 aromatization reaction Methods 0.000 description 1
- 150000001495 arsenic compounds Chemical class 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- XDFCIPNJCBUZJN-UHFFFAOYSA-N barium(2+) Chemical compound [Ba+2] XDFCIPNJCBUZJN-UHFFFAOYSA-N 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 150000001622 bismuth compounds Chemical class 0.000 description 1
- NSPSPMKCKIPQBH-UHFFFAOYSA-K bismuth;7,7-dimethyloctanoate Chemical compound [Bi+3].CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O NSPSPMKCKIPQBH-UHFFFAOYSA-K 0.000 description 1
- 239000003738 black carbon Substances 0.000 description 1
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- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
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- 150000001768 cations Chemical class 0.000 description 1
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- 229940112822 chewing gum Drugs 0.000 description 1
- 235000015218 chewing gum Nutrition 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- RPBPCPJJHKASGQ-UHFFFAOYSA-K chromium(3+);octanoate Chemical compound [Cr+3].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O RPBPCPJJHKASGQ-UHFFFAOYSA-K 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
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- 238000001816 cooling Methods 0.000 description 1
- 229940120693 copper naphthenate Drugs 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
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- 230000000593 degrading effect Effects 0.000 description 1
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- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
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- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 229940093920 gynecological arsenic compound Drugs 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910001293 incoloy Inorganic materials 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
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- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
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- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- APGNMHZUERWZME-UHFFFAOYSA-L palladium(2+);3,3,5,5-tetramethylhexanoate Chemical compound [Pd+2].CC(C)(C)CC(C)(C)CC([O-])=O.CC(C)(C)CC(C)(C)CC([O-])=O APGNMHZUERWZME-UHFFFAOYSA-L 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
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- 229910000579 plumbide Inorganic materials 0.000 description 1
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- TURAMGVWNUTQKH-UHFFFAOYSA-N propa-1,2-dien-1-one Chemical compound C=C=C=O TURAMGVWNUTQKH-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000004043 responsiveness Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- RQZVTOHLJOBKCW-UHFFFAOYSA-M silver;7,7-dimethyloctanoate Chemical compound [Ag+].CC(C)(C)CCCCCC([O-])=O RQZVTOHLJOBKCW-UHFFFAOYSA-M 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001134 stannide Inorganic materials 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- HDVLQIDIYKIVRE-UHFFFAOYSA-N tetrabutylgermane Chemical compound CCCC[Ge](CCCC)(CCCC)CCCC HDVLQIDIYKIVRE-UHFFFAOYSA-N 0.000 description 1
- XOOGZRUBTYCLHG-UHFFFAOYSA-N tetramethyllead Chemical compound C[Pb](C)(C)C XOOGZRUBTYCLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- BXJWDOYMROEHEN-UHFFFAOYSA-N tributylstibane Chemical compound CCCC[Sb](CCCC)CCCC BXJWDOYMROEHEN-UHFFFAOYSA-N 0.000 description 1
- UKHQRARQNZOXRL-UHFFFAOYSA-N trimethyltin Chemical compound C[SnH](C)C UKHQRARQNZOXRL-UHFFFAOYSA-N 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- BPLUKJNHPBNVQL-UHFFFAOYSA-N triphenylarsine Chemical compound C1=CC=CC=C1[As](C=1C=CC=CC=1)C1=CC=CC=C1 BPLUKJNHPBNVQL-UHFFFAOYSA-N 0.000 description 1
- HVYVMSPIJIWUNA-UHFFFAOYSA-N triphenylstibine Chemical compound C1=CC=CC=C1[Sb](C=1C=CC=CC=1)C1=CC=CC=C1 HVYVMSPIJIWUNA-UHFFFAOYSA-N 0.000 description 1
- VSRBKQFNFZQRBM-UHFFFAOYSA-N tuaminoheptane Chemical compound CCCCCC(C)N VSRBKQFNFZQRBM-UHFFFAOYSA-N 0.000 description 1
- 229960003986 tuaminoheptane Drugs 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US66669691A | 1991-03-08 | 1991-03-08 | |
US666,696 | 1991-03-08 | ||
US80282191A | 1991-12-06 | 1991-12-06 | |
US80306391A | 1991-12-06 | 1991-12-06 | |
US80321591A | 1991-12-06 | 1991-12-06 | |
US803,215 | 1991-12-06 | ||
US803,063 | 1991-12-06 | ||
PCT/US1992/001856 WO1992015653A1 (en) | 1991-03-08 | 1992-03-06 | Low-sulfur reforming processes |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2001000112A Division JP2001220586A (ja) | 1991-03-08 | 2001-01-04 | 低硫黄改質法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06507191A JPH06507191A (ja) | 1994-08-11 |
JP3836499B2 true JP3836499B2 (ja) | 2006-10-25 |
Family
ID=27505330
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP50830092A Expired - Fee Related JP3836499B2 (ja) | 1991-03-08 | 1992-03-06 | 低硫黄改質法 |
Country Status (16)
Country | Link |
---|---|
EP (3) | EP0845521B1 (no) |
JP (1) | JP3836499B2 (no) |
KR (1) | KR100230727B1 (no) |
CN (1) | CN1039720C (no) |
AT (1) | ATE159040T1 (no) |
AU (1) | AU665534B2 (no) |
BR (1) | BR9205738A (no) |
DE (3) | DE69232891T2 (no) |
ES (3) | ES2190551T3 (no) |
HU (1) | HUT75107A (no) |
MY (1) | MY109992A (no) |
NO (1) | NO933165D0 (no) |
OA (1) | OA09910A (no) |
SA (1) | SA92130085B1 (no) |
SG (2) | SG96561A1 (no) |
WO (1) | WO1992015653A1 (no) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5413700A (en) * | 1993-01-04 | 1995-05-09 | Chevron Research And Technology Company | Treating oxidized steels in low-sulfur reforming processes |
US5405525A (en) * | 1993-01-04 | 1995-04-11 | Chevron Research And Technology Company | Treating and desulfiding sulfided steels in low-sulfur reforming processes |
CN1043037C (zh) * | 1993-01-04 | 1999-04-21 | 切夫里昂化学公司 | 加氢脱烷基化方法 |
US5658452A (en) * | 1994-01-04 | 1997-08-19 | Chevron Chemical Company | Increasing production in hydrocarbon conversion processes |
US5575902A (en) * | 1994-01-04 | 1996-11-19 | Chevron Chemical Company | Cracking processes |
US5516421A (en) * | 1994-08-17 | 1996-05-14 | Brown; Warren E. | Sulfur removal |
US5565087A (en) * | 1995-03-23 | 1996-10-15 | Phillips Petroleum Company | Method for providing a tube having coke formation and carbon monoxide inhibiting properties when used for the thermal cracking of hydrocarbons |
ES2248821T3 (es) * | 1995-06-07 | 2006-03-16 | Chevron Phillips Chemical Company Lp | Utilizacion de flujos hidrocarburos para preparar una capa protectora metalica. |
ES2201194T3 (es) * | 1995-08-18 | 2004-03-16 | Chevron Phillips Chemical Company Lp | Barreras anti-difusion para prevenir el ataque por hidrogeno a elevada temperatura. |
US6497809B1 (en) * | 1995-10-25 | 2002-12-24 | Phillips Petroleum Company | Method for prolonging the effectiveness of a pyrolytic cracking tube treated for the inhibition of coke formation during cracking |
ES2232859T3 (es) * | 1996-02-02 | 2005-06-01 | Chevron Phillips Chemical Company Lp | Procesado de hidrocarburos en un equipo que tiene una resistencia aumentada a la fractura por corrosion debido a tensiones en presencia de haluros. |
CN1043782C (zh) * | 1996-03-21 | 1999-06-23 | 中国石油化工总公司 | 提高低品质汽油辛烷值的催化转化方法 |
US5914028A (en) * | 1997-01-10 | 1999-06-22 | Chevron Chemical Company | Reforming process with catalyst pretreatment |
US5879538A (en) * | 1997-12-22 | 1999-03-09 | Chevron Chemical Company | Zeolite L catalyst in conventional furnace |
US6120926A (en) * | 1998-11-10 | 2000-09-19 | International Fuel Cells, Llc | Inhibition of carbon deposition on fuel gas steam reformer walls |
US6258330B1 (en) * | 1998-11-10 | 2001-07-10 | International Fuel Cells, Llc | Inhibition of carbon deposition on fuel gas steam reformer walls |
US6936567B2 (en) | 2000-06-28 | 2005-08-30 | Sanyo Electric Co., Ltd. | Fuel reformer and manufacturing method of the same |
CN1394981A (zh) * | 2001-07-09 | 2003-02-05 | 李兰根 | 气氛热处理助剂及其用法 |
US8475650B2 (en) * | 2007-10-31 | 2013-07-02 | China Petroleum & Chemical Corporation | Pre-passivation process for a continuous reforming apparatus, and passivation process for a continuous reforming apparatus during the initial reaction |
DE202009005950U1 (de) | 2009-04-27 | 2009-08-20 | Holland-Letz, Peter | Gewebe zur Körperabdeckung zur Applikation von Arzneimitteln |
US20120277500A1 (en) * | 2011-04-29 | 2012-11-01 | Uop Llc | High Temperature Platforming Process |
US20120277511A1 (en) * | 2011-04-29 | 2012-11-01 | Uop Llc | High Temperature Platformer |
CN102898265B (zh) * | 2011-07-29 | 2014-08-06 | 中国石油化工股份有限公司 | 一种烯烃的生产方法 |
ES2549704B1 (es) * | 2014-04-30 | 2016-09-08 | Abengoa Hidrógeno, S.A. | Tubo reactor de reformado con vapor de agua |
PL3336055T3 (pl) | 2016-12-19 | 2019-10-31 | Air Liquide | Zabezpieczona przed korozją rura reformera z wewnętrznym wymiennikiem ciepła |
CN115463662B (zh) * | 2022-10-08 | 2023-06-02 | 中国矿业大学 | 一种负载型金属间化合物催化剂的制备及其在木质素衍生酚类化合物加氢脱氧中的应用 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1149163A (en) * | 1966-03-22 | 1969-04-16 | Ici Ltd | Protection against carburisation |
GB1362374A (en) * | 1970-06-17 | 1974-08-07 | Wisniewski L | Method of and composition for anti-corrosive protection by reduc tion of ionised metals on metal substrate |
CH556396A (de) * | 1971-11-03 | 1974-11-29 | Buechler Josef Heinrich | Verfahren zum aufbringen einer korrosionsschutzschicht auf ein metall und vorrichtung zur durchfuehrung des verfahrens. |
US4348271A (en) * | 1981-07-14 | 1982-09-07 | Exxon Research & Engineering Co. | Catalytic reforming process |
US4447316A (en) * | 1982-02-01 | 1984-05-08 | Chevron Research Company | Composition and a method for its use in dehydrocyclization of alkanes |
US4456527A (en) * | 1982-10-20 | 1984-06-26 | Chevron Research Company | Hydrocarbon conversion process |
US4634515A (en) * | 1985-10-25 | 1987-01-06 | Exxon Research And Engineering Company | Nickel adsorbent for sulfur removal from hydrocarbon feeds |
US4692234A (en) * | 1986-04-09 | 1987-09-08 | Phillips Petroleum Company | Antifoulants for thermal cracking processes |
JPS62256946A (ja) * | 1986-04-30 | 1987-11-09 | Nippon Kokan Kk <Nkk> | 耐クリ−プ脆化性および耐低温割れ性に優れたCr−Mo鋼 |
FR2600668B1 (fr) * | 1986-06-25 | 1989-05-19 | Inst Francais Du Petrole | Procede de reformage catalytique a travers au moins deux lits de catalyseur |
-
1992
- 1992-03-06 BR BR9205738A patent/BR9205738A/pt not_active IP Right Cessation
- 1992-03-06 JP JP50830092A patent/JP3836499B2/ja not_active Expired - Fee Related
- 1992-03-06 HU HU9302543A patent/HUT75107A/hu unknown
- 1992-03-06 AT AT92908806T patent/ATE159040T1/de not_active IP Right Cessation
- 1992-03-06 EP EP98100396A patent/EP0845521B1/en not_active Expired - Lifetime
- 1992-03-06 AU AU15801/92A patent/AU665534B2/en not_active Ceased
- 1992-03-06 ES ES98100396T patent/ES2190551T3/es not_active Expired - Lifetime
- 1992-03-06 WO PCT/US1992/001856 patent/WO1992015653A1/en active IP Right Grant
- 1992-03-06 EP EP97110024A patent/EP0798363B1/en not_active Expired - Lifetime
- 1992-03-06 KR KR1019930702697A patent/KR100230727B1/ko not_active IP Right Cessation
- 1992-03-06 DE DE69232891T patent/DE69232891T2/de not_active Expired - Lifetime
- 1992-03-06 EP EP92908806A patent/EP0576571B1/en not_active Expired - Lifetime
- 1992-03-06 DE DE69222633T patent/DE69222633T2/de not_active Expired - Lifetime
- 1992-03-06 SG SG200004098A patent/SG96561A1/en unknown
- 1992-03-06 ES ES97110024T patent/ES2201223T3/es not_active Expired - Lifetime
- 1992-03-06 DE DE69233084T patent/DE69233084T2/de not_active Expired - Lifetime
- 1992-03-06 SG SG1996009668A patent/SG72690A1/en unknown
- 1992-03-06 ES ES92908806T patent/ES2108112T3/es not_active Expired - Lifetime
- 1992-03-07 MY MYPI92000372A patent/MY109992A/en unknown
- 1992-03-07 CN CN92102539A patent/CN1039720C/zh not_active Expired - Fee Related
- 1992-09-05 SA SA92130085A patent/SA92130085B1/ar unknown
-
1993
- 1993-09-06 NO NO933165A patent/NO933165D0/no unknown
- 1993-09-06 OA OA60409A patent/OA09910A/en unknown
Also Published As
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HU9302543D0 (en) | 1993-12-28 |
EP0798363B1 (en) | 2003-05-28 |
AU1580192A (en) | 1992-10-06 |
EP0798363A3 (en) | 1998-03-11 |
SA92130085B1 (ar) | 2006-04-22 |
EP0576571A1 (en) | 1994-01-05 |
BR9205738A (pt) | 1994-08-23 |
EP0845521A1 (en) | 1998-06-03 |
DE69233084T2 (de) | 2004-01-29 |
CN1039720C (zh) | 1998-09-09 |
SG96561A1 (en) | 2003-06-16 |
SG72690A1 (en) | 2000-05-23 |
MY109992A (en) | 1997-10-31 |
JPH06507191A (ja) | 1994-08-11 |
EP0845521B1 (en) | 2003-01-08 |
DE69232891T2 (de) | 2003-11-06 |
DE69232891D1 (de) | 2003-02-13 |
DE69233084D1 (de) | 2003-07-03 |
EP0576571B1 (en) | 1997-10-08 |
DE69222633D1 (de) | 1997-11-13 |
ES2190551T3 (es) | 2003-08-01 |
ES2201223T3 (es) | 2004-03-16 |
HUT75107A (en) | 1997-04-28 |
WO1992015653A1 (en) | 1992-09-17 |
NO933165D0 (no) | 1993-09-06 |
DE69222633T2 (de) | 1998-04-23 |
ES2108112T3 (es) | 1997-12-16 |
OA09910A (en) | 1994-09-15 |
ATE159040T1 (de) | 1997-10-15 |
EP0798363A2 (en) | 1997-10-01 |
EP0576571A4 (no) | 1994-03-23 |
KR100230727B1 (ko) | 1999-11-15 |
AU665534B2 (en) | 1996-01-11 |
CN1067258A (zh) | 1992-12-23 |
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