JP3299007B2 - Method of manufacturing rubber double color elastic pavement material - Google Patents
Method of manufacturing rubber double color elastic pavement materialInfo
- Publication number
- JP3299007B2 JP3299007B2 JP25237893A JP25237893A JP3299007B2 JP 3299007 B2 JP3299007 B2 JP 3299007B2 JP 25237893 A JP25237893 A JP 25237893A JP 25237893 A JP25237893 A JP 25237893A JP 3299007 B2 JP3299007 B2 JP 3299007B2
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- substrate
- raw material
- mold
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Description
【0001】[0001]
【産業上の利用分野】この発明は、表面が二色以上の複
色からなるゴム製複色弾性舗装材の製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a rubber double-colored elastic pavement having a surface of two or more colors.
【0002】[0002]
【従来の技術】従来、古タイヤ、ゴム廃材等を粉砕した
ゴムチップをウレタン系等の接着剤で板状に固めたゴム
製弾性舗装材が提案されている。このゴム製弾性舗装材
は、ゴムチップ間に形成される僅かな隙間が連通路を構
成して、その連通路により透水性が確保されるため弾性
舗装材として好適である。しかも、産業廃棄物を再利用
できるという点でも有用である。しかし、古タイヤ等の
ゴム廃材は通常黒色からなるため、そのゴム廃材からな
るゴムチップをそのまま用いて成形した弾性舗装材で
は、黒色の単調のものとなって装飾性に乏しい。そこ
で、近年、図5および図6に示されるようなゴム製二色
弾性舗装材が提案されるようになった。なお、図中の5
0と51で示す部分は互いに色が異なっている。2. Description of the Related Art Conventionally, there has been proposed a rubber elastic pavement material in which rubber chips obtained by pulverizing old tires, waste rubber materials and the like are solidified in a plate shape with an adhesive such as urethane. This rubber elastic pavement material is suitable as an elastic pavement material because a small gap formed between the rubber chips forms a communication path and the communication path ensures water permeability. Moreover, it is also useful in that industrial waste can be reused. However, since rubber waste such as old tires is usually made of black, an elastic pavement formed by using the rubber chip made of the rubber waste as it is becomes monotonous in black and has poor decorativeness. Therefore, recently, rubber two-color elastic pavement materials as shown in FIGS. 5 and 6 have been proposed. Note that 5 in FIG.
The portions indicated by 0 and 51 have different colors from each other.
【0003】前記ゴム製二色弾性舗装材の従来における
製造方法としては、図7および図8に示すように、あら
かじめ所定形状に成形したゴムチップ製弾性板52を金
型53内面に載置し、その後前記弾性板52とは色の異
なるゴムチップとウレタン系の接着剤とを混合したチッ
プ原料54を金型53内に充填し、前記金型53を閉じ
て熱プレスすることにより、チップ原料の接着剤を硬化
させてゴムチップを金型内面形状に固めるとともに、弾
性板52と一体に結合させる方法がある。[0003] As a conventional method of manufacturing the rubber two-color elastic pavement material, as shown in FIGS. 7 and 8, a rubber chip elastic plate 52 formed in a predetermined shape in advance is placed on an inner surface of a mold 53. Thereafter, a die material 53 in which rubber chips having different colors from the elastic plate 52 are mixed with a urethane-based adhesive is filled in a mold 53, and the die material 53 is closed and hot pressed to bond the chip material. There is a method in which the agent is cured to harden the rubber chip into the shape of the inner surface of the mold, and is integrally connected to the elastic plate 52.
【0004】また、図9に示すように、互いに色の異な
る弾性板55と弾性基板56とを各々別個にゴムチップ
より成形し、前記弾性基板56表面に設けた凹部57に
前記弾性板55を嵌めて接着する方法もある。As shown in FIG. 9, an elastic plate 55 and an elastic substrate 56 having different colors are separately formed from rubber chips, and the elastic plate 55 is fitted into a concave portion 57 provided on the surface of the elastic substrate 56. There is also a method of bonding.
【0005】しかし、前者の製造方法においては、弾性
板52を金型内に正しく配置することが難しく、また正
しく配置してもその後のチップ原料の充填および熱プレ
ス時に弾性板52がずれやすく、得られる二色弾性舗装
材の品質(装飾性)が一定しない問題がある。しかも、
あらかじめ弾性板52を別成形しておかねばならない煩
わしさがある。However, in the former manufacturing method, it is difficult to correctly arrange the elastic plate 52 in the mold, and even if it is correctly arranged, the elastic plate 52 tends to be displaced during subsequent filling of the chip material and hot pressing. There is a problem that the quality (decorativeness) of the obtained two-color elastic pavement material is not constant. Moreover,
There is an annoyance that the elastic plate 52 must be separately formed in advance.
【0006】一方、後者の製造方法においては、前記弾
性板55外周面と凹部57内周面間の隙間58が一定に
ならず、品質が一定しないのみならず、前記隙間58か
ら接着剤がはみ出して、見栄えが損なわれる問題があ
る。しかも、弾性板55と弾性基板56の両者をあらか
じめ別成形しておかねばならない煩わしさがある。な
お、後塗装により二色にする方法もあるが、その場合に
は塗装作業が面倒であるのみならず、ゴムチップ間に形
成される連通路が塗膜により塞がれて透水性が損なわれ
る問題もある。On the other hand, in the latter manufacturing method, the gap 58 between the outer peripheral surface of the elastic plate 55 and the inner peripheral surface of the concave portion 57 is not constant, and the quality is not constant. There is a problem that the appearance is impaired. In addition, there is a trouble that both the elastic plate 55 and the elastic substrate 56 must be separately formed in advance. In addition, there is a method to make two colors by post-painting, but in this case, not only the painting work is troublesome, but also the problem that the communication path formed between the rubber chips is blocked by the paint film and the water permeability is impaired. There is also.
【0007】[0007]
【発明が解決しようとする課題】そこでこの発明は、前
記の点に鑑みてなされたもので、品質が一定で装飾性お
よび透水性に優れる複色弾性舗装材を容易に得られる製
造方法を提供するものである。SUMMARY OF THE INVENTION Accordingly, the present invention has been made in view of the above-mentioned points, and provides a method for easily producing a multicolored elastic pavement material having a constant quality and excellent decorativeness and water permeability. Is what you do.
【0008】[0008]
【課題を解決するための手段】すなわちこの発明は、所
望の色のゴムチップと接着剤とを混合した第一原料を金
型内に投入し、内面に突部を有する押し型で前記金型内
の第一原料を熱プレスして前記接着剤を硬化させること
により、表面に凹部の形成されたゴム製基板を形成する
基板形成工程と、前記ゴム製基板の凹部に第一原料のゴ
ムチップとは異なる色のゴムチップと接着剤とを混合し
た第二原料を投入し、前記凹部以外のゴム製基板の表面
には該表面を覆って前記凹部の周囲を壁状に包囲する治
具を配置した状態で、前記凹部に対向する突部を有する
押し型を用い、該押し型と前記ゴム製基板間に前記治具
を介在させて当該押し型で前記ゴム製基板凹部の第二原
料を熱プレスして該第二原料の接着剤を硬化させること
により、前記ゴム製基板と一体に装飾体を形成する装飾
体形成工程と、前記ゴム製基板と装飾体が一体になった
成形品を前記金型から取り出す脱型工程とよりなること
を特徴とするゴム製複色弾性舗装材の製造方法に係る。That is, according to the present invention, a first raw material obtained by mixing a rubber chip of a desired color and an adhesive is put into a mold, and the inside of the mold is formed by a pressing die having a projection on the inner surface. A substrate forming step of forming a rubber substrate having a concave portion formed on its surface by hot pressing the first raw material to cure the adhesive, and a rubber chip of the first raw material in the concave portion of the rubber substrate. A second raw material obtained by mixing rubber chips of different colors and an adhesive is charged, and the surface of the rubber substrate other than the concave portion is charged.
To cover the surface and surround the periphery of the recess in a wall shape.
In the state where the tool is arranged, it has a projection facing the recess
Using a pressing die, the jig is provided between the pressing die and the rubber substrate.
Decorative body forming the decorative body integrally with the rubber substrate by hot pressing the second raw material in the rubber substrate concave portion with the pressing die and curing the adhesive of the second raw material with the pressing mold The present invention relates to a method for producing a rubber double-color elastic pavement material, comprising: a step of removing a molded product obtained by integrating the rubber substrate and the decorative body from the mold.
【0009】[0009]
【実施例】以下添付の図面に従ってこの発明を詳細に説
明する。図1はこの発明の実施例における基板形成工程
の一例を示す金型の断面図、図2は同実施例において基
板凹部に第二原料を投入する状態を示す金型の断面図、
図3は同じく装飾体形成工程の一例を示す金型の断面
図、図4は同実施例により得られたゴム製複色弾性舗装
材の断面図である。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail with reference to the accompanying drawings. FIG. 1 is a cross-sectional view of a mold showing an example of a substrate forming process in an embodiment of the present invention. FIG. 2 is a cross-sectional view of a mold showing a state where a second raw material is charged into a substrate recess in the embodiment.
FIG. 3 is a cross-sectional view of a mold showing an example of a decorative body forming step, and FIG. 4 is a cross-sectional view of a rubber double-colored elastic pavement obtained by the same embodiment.
【0010】この発明のゴム製複色弾性舗装材の製造方
法は、基板形成工程と装飾体形成工程と脱型工程とから
なる。図1にこの発明の製造方法を実施する金型の一例
を示す。符号10は金型で、成形品の取り出しが容易な
ように下型12、中型14および押し型16の3分割型
よりなり、型内部が弾性舗装材の形状を規定する成形空
間になっている。[0010] The method for producing a rubber double-colored elastic pavement material of the present invention comprises a substrate forming step, a decorative body forming step, and a mold releasing step. FIG. 1 shows an example of a mold for implementing the manufacturing method of the present invention. Reference numeral 10 denotes a mold, which comprises a lower mold 12, a middle mold 14, and a press mold 16 for easy separation of the molded product, and the inside of the mold is a molding space for defining the shape of the elastic pavement material. .
【0011】押し型16は、その内面に突部18を有し
ている。この突部18は、弾性舗装材のゴム製基板に異
なった色の装飾体を形成するための凹部を設けるための
もので、前記押し型16の内面に複数設けてもよく、ま
た弾性舗装材の外周が異なった色となるように内面の外
周全体を突形状としてもよい。The pressing die 16 has a projection 18 on its inner surface. The protrusions 18 are provided for providing concave portions for forming decorative bodies of different colors on the rubber substrate of the elastic pavement material, and a plurality of protrusions 18 may be provided on the inner surface of the pressing die 16. The entire outer periphery of the inner surface may have a protruding shape so that the outer periphery of the inner surface has a different color.
【0012】なお、この実施例において前記金型10の
成形空間は、150×200×15mmに形成されてい
る。また、前記突部18は、押し型16の内面略中央部
に100×150の大きさで、高さ5mmに形成されて
いる。In this embodiment, the molding space of the mold 10 is formed to be 150 × 200 × 15 mm. The protrusion 18 has a size of 100 × 150 and a height of 5 mm at a substantially central portion of the inner surface of the pressing die 16.
【0013】次に、前記金型10を用いて、この発明の
製造方法における基板形成工程について説明する。ま
ず、図1に示されるように、所望の色のゴムチップ21
と接着剤とを混合してなる第一原料23を、前記金型1
0の成形空間に投入する。この第一原料23の金型内へ
の充填は、熱プレス時にゴムチップが圧縮されるように
過充填とするのが好ましい。Next, a substrate forming step in the manufacturing method of the present invention using the mold 10 will be described. First, as shown in FIG.
The first raw material 23 obtained by mixing the first raw material 23 with the adhesive
0 is put into the molding space. It is preferable that the filling of the first raw material 23 into the mold is overfilled so that the rubber chips are compressed during hot pressing.
【0014】そして、押し型16で前記第一原料23を
熱プレスする。この熱プレスによって第一原料23内の
接着剤が硬化して、ゴムチップ21が金型10の内面形
状に固められてゴム製基板25が形成される。このゴム
製基板25の表面には、前記突部18によって凹部24
が形成されている。なお、この熱プレスの条件は、用い
られるゴムチップや接着剤の種類や量にもよるが、16
0℃で3分程度が好適である。前記ゴム製基板25の成
形に用いられるゴムチップ21は、前記した古タイヤや
ゴム廃材などの粉砕品が好適で、黒色または有色のもの
をそのまま、あるいは必要により着色して使用される。
なお、前記ゴムチップ21には、ウレタンスポンジチッ
プや木チップなどのようなゴム以外のチップ類を含んで
いてもよい。接着剤には、ウレタン系などゴムチップの
接着に用いられている公知のものが使用される。Then, the first raw material 23 is hot-pressed by the pressing die 16. The adhesive in the first raw material 23 is hardened by the hot pressing, and the rubber chip 21 is solidified into the inner shape of the mold 10 to form the rubber substrate 25. On the surface of the rubber substrate 25, the concave portion 24
Are formed. The condition of the hot press depends on the type and amount of the rubber chip and the adhesive to be used.
About 3 minutes at 0 ° C. is preferable. The rubber chip 21 used for molding the rubber substrate 25 is preferably a pulverized product such as a used tire or a waste rubber material described above. A black or colored material is used as it is or is colored as necessary.
The rubber chip 21 may include chips other than rubber, such as urethane sponge chips and wood chips. As the adhesive, a known adhesive such as a urethane-based adhesive used for bonding a rubber chip is used.
【0015】次いで、装飾体形成工程によって前記ゴム
製基板25に装飾体を形成する。図2に示されるよう
に、前記基板成形工程によって得られたゴム製基板25
の凹部24内に装飾体を構成する第二原料26が投入さ
れる。この第二原料26も、第一原料23と同様に、熱
プレス時にゴムチップが圧縮されるように過充填とする
のが好ましい。Next, a decorative body is formed on the rubber substrate 25 in a decorative body forming step. As shown in FIG. 2, the rubber substrate 25 obtained by the substrate molding process is used.
The second raw material 26 constituting the decorative body is put into the concave portion 24 of FIG. Like the first raw material 23, the second raw material 26 is preferably overfilled so that the rubber chips are compressed during hot pressing.
【0016】この第二原料26は、前記第一原料23に
用いられたゴムチップ21とは異なった色を有するゴム
チップ27に適宜の接着剤が混合されてなるもので、前
記ゴム製基板25の表面に装飾体を形成する。なお、前
記ゴムチップ27は前記ゴム製基板25の色とは異なる
所望の色とされるが、前記ゴム製基板25の色が黒以外
の場合には着色せずに黒のままにされることもある。The second raw material 26 is obtained by mixing a rubber chip 27 having a color different from that of the rubber chip 21 used for the first raw material 23 with an appropriate adhesive. To form a decorative body. The rubber chip 27 has a desired color different from the color of the rubber substrate 25. However, when the color of the rubber substrate 25 is other than black, it may be left black without coloring. is there.
【0017】その際、前記ゴム製基板25の表面におい
て、凹部24以外の部分には治具29が配される。この
治具29はゴム製基板表面を覆うとともに、少なくとも
前記凹部24の周囲をゴム製基板25の上面より高く壁
状に包囲して、ゴム製基板25の表面を平滑に保ち、か
つ前記凹部24内に過充填された第二原料26がゴム製
基板25の他の部分に至るのを防ぐためのもので、前記
突部18の突出高さとほぼ同じ厚みに形成されている。At this time, a jig 29 is arranged on a portion other than the concave portion 24 on the surface of the rubber substrate 25. This jig 29 covers the surface of the rubber substrate and surrounds at least the periphery of the concave portion 24 in a wall shape higher than the upper surface of the rubber substrate 25 to keep the surface of the rubber substrate 25 smooth and This is for preventing the second raw material 26 overfilled from reaching the other portion of the rubber substrate 25 and is formed to have a thickness substantially equal to the height of the protrusion 18.
【0018】続いて、図3に示されるように、前記押し
型16を前記治具29を介して下型12方向に押し付
け、前記凹部24に対向する突部18によって凹部24
内の第二原料26を熱プレスする。プレス時の熱によっ
て第二原料26内の接着剤が硬化して、前記ゴム製基板
25の表面に一体に装飾体が形成される。図3におい
て、符号13はスペーサーである。このスペーサー13
は、前記突部29が第二原料26を過剰にプレスするの
を防ぐためのもので、前記凹部24の深さ(突部18の
突出高さ)と同じ寸法の厚みを有している。なお、この
実施例において、前記装飾体を形成するためのプレス条
件は160℃で5分である。Subsequently, as shown in FIG. 3, the pressing die 16 is pressed in the direction of the lower die 12 via the jig 29, and the pressing portion 16 is opposed to the concave portion 24 by the projecting portion 18.
The second raw material 26 is hot-pressed. The adhesive in the second raw material 26 is hardened by the heat at the time of pressing, and the decorative body is integrally formed on the surface of the rubber substrate 25. In FIG. 3, reference numeral 13 denotes a spacer. This spacer 13
Is for preventing the protrusion 29 from pressing the second raw material 26 excessively, and has a thickness of the same size as the depth of the recess 24 (the protrusion height of the protrusion 18). In this embodiment, the pressing condition for forming the decorative body is 160 ° C. for 5 minutes.
【0019】その後、押し型16を開け、中型14を下
型12から分離させて成形品を金型10から脱型すれ
ば、図4に示される複色弾性舗装材30が得られる。符
号31は装飾体であるThereafter, when the pressing die 16 is opened, the middle die 14 is separated from the lower die 12, and the molded product is released from the die 10, the multicolor elastic pavement material 30 shown in FIG. 4 is obtained. Reference numeral 31 denotes a decorative body
【0020】[0020]
【発明の効果】以上図示し説明したように、この発明方
法によれば、装飾部分の位置が一定でその境界部におけ
る色の混ざりがない一定した品質からなる、装飾性に優
れるゴム製複色弾性舗装材を容易に得ることができる。
しかも、得られるゴム製複色弾性舗装材は、ゴムチップ
間の隙間からなる連通路により透水性が確保されるた
め、舗装材として最適である。また、この発明の製造方
法は、ゴム製基板と装飾体をあらかじめ別成形しておく
必要がなく、連続して成形できるため、きわめて作業性
に優れる。As shown and described above, according to the method of the present invention, a rubber double color with excellent decorativeness, having a constant quality of a decorative portion and a constant quality without color mixing at its boundary. An elastic pavement material can be easily obtained.
Moreover, the obtained rubber double-colored elastic pavement material is most suitable as a pavement material because water permeability is ensured by the communication path formed by the gap between the rubber chips. Further, the production method of the present invention does not require separate molding of the rubber substrate and the decorative body in advance, and can be continuously molded.
【図1】この発明の実施例における基板形成工程の一例
を示す金型の断面図である。FIG. 1 is a sectional view of a mold showing an example of a substrate forming step in an embodiment of the present invention.
【図2】同実施例において基板凹部に第二原料を投入す
る状態を示す金型の断面図である。FIG. 2 is a sectional view of a mold showing a state in which a second raw material is charged into a concave portion of a substrate in the embodiment.
【図3】同じく装飾体形成工程の一例を示す金型の断面
図である。FIG. 3 is a sectional view of a mold showing an example of a decorative body forming step.
【図4】同実施例により得られたゴム製複色弾性舗装材
の断面図である。FIG. 4 is a cross-sectional view of a rubber double-colored elastic pavement obtained according to the example.
【図5】一般的なゴム製二色弾性舗装材の断面図であ
る。FIG. 5 is a sectional view of a general rubber two-color elastic pavement material.
【図6】その他の例を示す断面図である。FIG. 6 is a sectional view showing another example.
【図7】従来の製造方法における弾性板配置時を示す断
面図である。FIG. 7 is a cross-sectional view illustrating a conventional manufacturing method when an elastic plate is arranged.
【図8】従来の製造方法におけるチップ原料充填状態を
示す断面図である。FIG. 8 is a cross-sectional view showing a state in which a chip material is filled in a conventional manufacturing method.
【図9】別の従来方法により製造されたゴム製二色弾性
舗装材の一例を示す断面図である。FIG. 9 is a cross-sectional view showing an example of a rubber two-color elastic pavement material manufactured by another conventional method.
10 金型 12 下型 14 中型 16 押し型 18 突部 21 ゴムチップ 23 第一原料 24 凹部 25 ゴム製基板 26 第二原料 27 ゴムチップ 30 複色弾性舗装材 31 装飾体 REFERENCE SIGNS LIST 10 Mold 12 Lower mold 14 Middle mold 16 Press mold 18 Protrusion 21 Rubber chip 23 First raw material 24 Concave 25 Rubber substrate 26 Second raw material 27 Rubber chip 30 Multicolored elastic pavement material 31 Decoration
フロントページの続き (58)調査した分野(Int.Cl.7,DB名) B29C 39/02 - 39/12 B29C 43/02 - 43/20 B29C 43/36 E01C 5/18 - 5/22 Continuation of the front page (58) Field surveyed (Int. Cl. 7 , DB name) B29C 39/02-39/12 B29C 43/02-43/20 B29C 43/36 E01C 5/18-5/22
Claims (1)
した第一原料を金型内に投入し、内面に突部を有する押
し型で前記金型内の第一原料を熱プレスして前記接着剤
を硬化させることにより、表面に凹部の形成されたゴム
製基板を形成する基板形成工程と、 前記ゴム製基板の凹部に第一原料のゴムチップとは異な
る色のゴムチップと接着剤とを混合した第二原料を投入
し、前記凹部以外のゴム製基板の表面には該表面を覆っ
て前記凹部の周囲を壁状に包囲する治具を配置した状態
で、前記凹部に対向する突部を有する押し型を用い、該
押し型と前記ゴム製基板間に前記治具を介在させて当該
押し型で前記ゴム製基板凹部の第二原料を熱プレスして
該第二原料の接着剤を硬化させることにより、前記ゴム
製基板と一体に装飾体を形成する装飾体形成工程と、 前記ゴム製基板と装飾体が一体になった成形品を前記金
型から取り出す脱型工程と よりなることを特徴とするゴム製複色弾性舗装材の製造
方法。1. A first raw material obtained by mixing a rubber chip of a desired color and an adhesive is put into a mold, and the first raw material in the mold is hot-pressed by a pressing die having a projection on an inner surface. By curing the adhesive, a substrate forming step of forming a rubber substrate having a concave portion formed on the surface thereof, and a rubber chip and an adhesive having a color different from that of the first raw material rubber chip in the concave portion of the rubber substrate. The mixed second raw material is charged, and the surface of the rubber substrate other than the concave portion is covered with the surface.
State in which a jig surrounding the recess in a wall shape is arranged
In this, using a pressing die having a projection facing the recess,
The jig is interposed between the pressing die and the rubber substrate to
A decorative body forming step of forming a decorative body integrally with the rubber substrate by hot-pressing the second raw material in the rubber substrate concave portion with a pressing die to cure the adhesive of the second raw material; A method for producing a rubber double-colored elastic pavement, comprising: a removing step of taking out a molded article in which a substrate and a decorative body are integrated from the mold.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25237893A JP3299007B2 (en) | 1993-09-14 | 1993-09-14 | Method of manufacturing rubber double color elastic pavement material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25237893A JP3299007B2 (en) | 1993-09-14 | 1993-09-14 | Method of manufacturing rubber double color elastic pavement material |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0780867A JPH0780867A (en) | 1995-03-28 |
JP3299007B2 true JP3299007B2 (en) | 2002-07-08 |
Family
ID=17236483
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP25237893A Expired - Fee Related JP3299007B2 (en) | 1993-09-14 | 1993-09-14 | Method of manufacturing rubber double color elastic pavement material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3299007B2 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020147916A (en) * | 2019-03-11 | 2020-09-17 | 清田軌道工業株式会社 | Method of producing railroad crossing pavement plate |
-
1993
- 1993-09-14 JP JP25237893A patent/JP3299007B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH0780867A (en) | 1995-03-28 |
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