JP2843062B2 - Limestone slurry storage tank - Google Patents
Limestone slurry storage tankInfo
- Publication number
- JP2843062B2 JP2843062B2 JP1191860A JP19186089A JP2843062B2 JP 2843062 B2 JP2843062 B2 JP 2843062B2 JP 1191860 A JP1191860 A JP 1191860A JP 19186089 A JP19186089 A JP 19186089A JP 2843062 B2 JP2843062 B2 JP 2843062B2
- Authority
- JP
- Japan
- Prior art keywords
- limestone
- bag
- storage tank
- limestone slurry
- slurry storage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 235000019738 Limestone Nutrition 0.000 title claims description 106
- 239000006028 limestone Substances 0.000 title claims description 106
- 239000002002 slurry Substances 0.000 title claims description 41
- 239000000843 powder Substances 0.000 claims description 21
- 238000006477 desulfuration reaction Methods 0.000 description 15
- 230000023556 desulfurization Effects 0.000 description 15
- 238000010926 purge Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 239000003546 flue gas Substances 0.000 description 5
- 230000008602 contraction Effects 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- TVZRAEYQIKYCPH-UHFFFAOYSA-N 3-(trimethylsilyl)propane-1-sulfonic acid Chemical compound C[Si](C)(C)CCCS(O)(=O)=O TVZRAEYQIKYCPH-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Treating Waste Gases (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、湿式排煙脱硫装置に用いられる石灰石スラ
リ貯槽に係り、特に石灰石投入口の詰まりを防止するの
に好適な石灰石スラリ貯槽に関するものである。Description: TECHNICAL FIELD The present invention relates to a limestone slurry storage tank used in a wet flue gas desulfurization apparatus, and particularly to a limestone slurry storage tank suitable for preventing clogging of a limestone input port. It is.
湿式排煙脱硫装置(以下、脱硫装置と略称することが
ある)においては、吸収液として水と吸収剤である石灰
石の粉末とを混合して調製した石灰石スラリが使用さ
れ、該石灰石スラリを調製する貯槽を一般に石灰石スラ
リ貯槽と呼んでいる。BACKGROUND ART In a wet flue gas desulfurization device (hereinafter, may be simply referred to as a desulfurization device), a limestone slurry prepared by mixing water and limestone powder as an absorbent is used as an absorbing solution, and the limestone slurry is prepared. The storage tanks are generally called limestone slurry storage tanks.
第3図、第4図および第5図は、それぞれ従来の石灰
石スラリ貯槽の説明図である。FIGS. 3, 4 and 5 are explanatory diagrams of a conventional limestone slurry storage tank, respectively.
第5図において、石灰石供給コンベア2によって搬入
される石灰石粉末は、導管3から供給されるパージ用空
気とともに石灰石投入口5を経て石灰石スラリ槽1に投
入され、該石灰石スラリ槽1内で撹拌機6により、導管
8から導入される水と撹拌、混合されて石灰石スラリと
なり、その後石灰石スラリポンプ9を経て槽外に取り出
される。In FIG. 5, the limestone powder carried in by the limestone supply conveyor 2 is introduced into the limestone slurry tank 1 through the limestone input port 5 together with the purge air supplied from the conduit 3, and the limestone slurry is stirred in the limestone slurry tank 1. By 6, the limestone slurry is stirred and mixed with the water introduced from the conduit 8 to form a limestone slurry, and then taken out of the tank via a limestone slurry pump 9.
石灰石粉末と混合される水は、通常工業用水または湿
式排煙脱硫装置の系内で発生する濾過水であり、ある程
度の温度を有しているので、石灰石スラリ貯槽1に導入
された時、液面から湯気が立ちのぼる。この湯気は石灰
石投入口5および石灰石供給コンベア2へ流入して凝縮
し、該石灰石投入口5または石灰石供給コンベア2内
で、石灰石の粉末が吸湿、固着する原因となるので、導
管3からパージ用空気を導入して湯気の流入を防止して
いる。The water mixed with the limestone powder is usually industrial water or filtered water generated in the system of a wet flue gas desulfurization device, and has a certain temperature, so that when introduced into the limestone slurry storage tank 1, Steam rises from the surface. The steam flows into the limestone charging port 5 and the limestone supply conveyor 2 and condenses. In the limestone charging port 5 or the limestone supply conveyor 2, the limestone powder absorbs moisture and adheres. Air is introduced to prevent steam from flowing in.
ところで、最近の火力発電所においては、電力需要の
動向に合わせて、電気使用量の多い時間帯のみ運転し、
夜間および休日は運転を停止するという、いわゆるDSS
運転が主流となっているので、湿式排煙脱硫装置もこれ
に合わせて断続的に運転されることになる。そこで第5
図の石灰石スラリ貯槽では、脱硫装置の停止時であって
も、石灰石投入口5および石灰石供給コンベア2への湯
気の流入を防ぐために、導管3からパージ用空気を供給
し続ける必要があるために、ユーティリティ消費を軽減
するための経済的な運用とはならず、解決が望まれてい
た。By the way, recent thermal power plants operate only during periods of high electricity usage in accordance with trends in power demand,
The so-called DSS that stops driving at night and on holidays
Since the operation is dominant, the wet flue gas desulfurization device is also operated intermittently. So the fifth
In the limestone slurry storage tank shown in the figure, even when the desulfurization device is stopped, it is necessary to continuously supply purge air from the conduit 3 in order to prevent steam from flowing into the limestone input port 5 and the limestone supply conveyor 2. However, it was not an economic operation to reduce utility consumption, and a solution was desired.
第3図および第4図に示す石灰石スラリ貯槽はこのよ
うな要求を満たすために改良されたものであり、第3図
は石灰石供給コンベア2の後流に開閉弁4を設け、脱硫
装置の運転停止時は開閉弁4を閉じるとともに、導管3
からのパージ用空気の供給を停止し、ユーティリティ消
費の低減を図るものである。また第4図の石灰石スラリ
貯槽は、開閉弁4を設けるとともに、該開閉弁4の後流
に湯気が流入するのを防ぐために、その後流部にパージ
用空気の導管10を連結したものである。The limestone slurry storage tank shown in FIGS. 3 and 4 has been improved to satisfy such demands. FIG. 3 shows the operation of the desulfurization device by providing an on-off valve 4 downstream of the limestone supply conveyor 2. When stopped, the on-off valve 4 is closed and the conduit 3
The purpose of this is to stop the supply of air for purging from, and to reduce utility consumption. The limestone slurry storage tank shown in FIG. 4 is provided with an on-off valve 4 and a purging air conduit 10 connected to the downstream of the on-off valve 4 in order to prevent steam from flowing into the downstream side thereof. .
しかしながら、第3図の石灰石スラリ貯槽は運転停止
時に石灰石投入口5から開閉弁4までに湯気が流入し、
凝縮して水分となるため、運転再開時にこの水分に石灰
石の粉末が付着して固化し、次第に成長して最終的には
投入口を閉塞するという問題がある。また、第4図の石
灰石スラリ貯槽は、第5図と同様に運転の停止時であっ
ても、開閉弁4の後流に湯気が流入するのを防ぐため
に、パージ用空気を流入し続けなければならず、ユーテ
ィリティ消費量が低減されないという問題がある。However, steam flows into the limestone slurry storage tank of FIG. 3 from the limestone input port 5 to the on-off valve 4 when the operation is stopped,
Since the water condenses into water, there is a problem that limestone powder adheres to the water when the operation is restarted, solidifies, gradually grows, and finally blocks the inlet. Also, in the limestone slurry storage tank of FIG. 4, even when the operation is stopped, purging air must be kept flowing in order to prevent steam from flowing downstream of the on-off valve 4 even when the operation is stopped. Therefore, there is a problem that the utility consumption is not reduced.
本発明の目的は、上記従来技術の問題点を解決し、石
灰石供給コンベアおよび石灰石投入口への石灰石粉末の
固着およびその成長を防止し、かつユーティリティ消費
量の少ない石灰石スラリ貯槽を提供することにある。An object of the present invention is to solve the above-mentioned problems of the prior art and to provide a limestone slurry storage tank which prevents limestone powder from sticking and growing to a limestone supply conveyor and a limestone input port, and has low utility consumption. is there.
上記目的を達成するため本発明は、石灰石の粉末を投
入する石灰石投入口に開閉手段を設けた石灰石スラリ貯
槽において、前記開閉手段として圧縮空気の供給または
部分的な押圧により膨張または収縮する可撓性の袋体を
前記石灰石投入口の内側に設けたことを特徴とするもの
である。In order to achieve the above object, the present invention provides a limestone slurry storage tank provided with opening / closing means at a limestone charging port for charging limestone powder, wherein the flexible means expands or contracts by supplying compressed air or partial pressing as the opening / closing means. The limestone bag is provided inside the limestone inlet.
石灰石投入口の内側に圧縮空気の供給または部分的な
押圧により膨張または収縮する可撓性の袋体を配置した
ことにより、前記可撓性の袋体を膨張させると石灰石投
入口が閉じ、一方、前記袋体を収縮させると石灰石投入
口が開くようになる。また、前記可撓性袋体に一旦付着
して固化した石灰石の粉末は前記袋体を膨張、収縮させ
て石灰石投入口を開閉するたびに払い落とされ、常に付
着物のない状態が再生されるので、石灰石の付着による
投入口の閉塞が防止される。By disposing a flexible bag that expands or contracts due to the supply of compressed air or partial pressing inside the limestone inlet, when the flexible bag is expanded, the limestone inlet closes, When the bag is contracted, the limestone inlet is opened. Also, the limestone powder once adhered to the flexible bag and solidified is blown off each time the bag is expanded and contracted to open and close the limestone input port, and a state in which there is no deposit is always reproduced. Therefore, the blocking of the input port due to the adhesion of limestone is prevented.
本発明において脱硫装置の運転時には、前記可撓性の
袋体が収縮されて石灰石投入口が開かれ、石灰石の粉末
はパージ用空気とともに石灰石スラリ槽に導入される。
一方、脱硫装置の運転停止時は前記可撓性袋体を膨張さ
せて石灰石投入口が閉じられ、それより前流側への湯気
の流入が阻止されるので、石灰石粉末の付着は起こらな
い。また前記可撓性袋体を閉じている間に該袋体の閉鎖
部分に付着した水分により、脱硫装置の運転開始時、す
なわち前記袋体を開いた時に投入される石灰石粉末が吸
湿して付着したとしても、石灰石粉末とともに導入され
るパージ用空気によってその成長が防止されるうえ、再
度前記可撓性袋体を膨張させて石灰石投入口を閉じる際
に、前記袋体の膨張、収縮操作を数回繰り返し、該袋体
を波打つように動かせば、前記付着物が払い落とされ、
付着物のない状態が再生される。In the present invention, when the desulfurization apparatus is operated, the flexible bag is contracted to open the limestone charging port, and the limestone powder is introduced into the limestone slurry tank together with the purge air.
On the other hand, when the operation of the desulfurization device is stopped, the flexible bag body is inflated to close the limestone charging port and the flow of steam to the upstream side is prevented, so that the limestone powder does not adhere. In addition, moisture adhering to the closed portion of the bag while the flexible bag is closed causes limestone powder to be introduced when the desulfurization apparatus starts operation, that is, when the bag is opened, to absorb moisture and adhere. Even if it does, the growth is prevented by the air for purge introduced together with the limestone powder, and when the flexible bag is expanded again to close the limestone inlet, the expansion and contraction operations of the bag are performed. Repeat several times, if the bag is moved in a wavy manner, the deposits are washed off,
The condition without deposits is regenerated.
本発明において可撓性袋体とは、柔軟な袋状物であ
り、石灰石投入口の内側に配置されて圧縮空気の導入、
排出または部分的な押圧により、膨張または収縮して石
灰石投入口を開閉するものである。In the present invention, the flexible bag body is a flexible bag-like material, which is disposed inside the limestone charging port to introduce compressed air,
The limestone inlet is opened or closed by expansion or contraction by discharging or partial pressing.
可撓性の袋体は、石灰石投入口の内側に環状に設けた
り、または数個の袋体を投入口の内側に沿って設けても
よい。袋体には圧縮空気の導入手段およびバルブが設け
られるが、押圧により膨張、収縮を行う場合は空気を密
閉するだけでよい。The flexible bag may be provided annularly inside the limestone input port, or several bags may be provided along the inside of the input port. The bag is provided with a means for introducing compressed air and a valve. When the bag expands and contracts by pressing, it is sufficient to seal the air.
なお、前記可撓性袋体を石灰石投入口配管の一部とし
て用い、該袋体を外部から縛ったり、その縛りを解いた
りして石灰石投入口を開閉させてもよい。The flexible bag may be used as a part of the limestone inlet pipe, and the bag may be tied from the outside or the tie may be released to open and close the limestone inlet.
本発明において、前記可撓性袋体の材質としては、例
えばポリアミド、ポリエチレン、ポリ塩化ビニル、ポリ
プロピレン等のフィルム、織布、不織布等が用いられる
が、可撓性および一定の強度を有するものであれば特に
限定されない。In the present invention, as the material of the flexible bag, for example, a film of polyamide, polyethylene, polyvinyl chloride, polypropylene, or the like, woven fabric, non-woven fabric, or the like is used. There is no particular limitation as long as it exists.
次に、本発明を実施例によりさらに詳細に説明する。 Next, the present invention will be described in more detail with reference to examples.
第1図は、本発明の一実施例を示す石灰石スラリ貯槽
の断面図、第2図は、第1図の部分拡大図である。FIG. 1 is a sectional view of a limestone slurry storage tank showing one embodiment of the present invention, and FIG. 2 is a partially enlarged view of FIG.
第1図において、この石灰石スラリ貯槽は、石灰石ス
ラリ槽1と、該石灰石スラリ槽1に石灰石の投入口5を
経て石灰石の粉末を搬入する石灰石供給コンベア2と、
該石灰石供給コンベア2に連結されたパージ用空気の導
管3と、前記石灰石投入口5の内側に設けられた可撓性
の環状袋体12(13)と、前記石灰石スラリ槽1に水投入
口を経て水を投入する導管8と、石灰石スラリ槽1に付
設された、石灰石粉末と水とを混合して石灰石スラリを
調製する撹拌機6と、排気口7と、調製された石灰石ス
ラリを槽外へ搬送する石灰石スラリポンプ9とから主と
して構成されている。In FIG. 1, the limestone slurry storage tank includes a limestone slurry tank 1 and a limestone supply conveyor 2 for carrying limestone powder into the limestone slurry tank 1 through a limestone inlet 5.
A conduit 3 for purging air connected to the limestone supply conveyor 2, a flexible annular bag body 12 (13) provided inside the limestone inlet 5, and a water inlet for the limestone slurry tank 1. , A stirrer 6 attached to the limestone slurry tank 1 for mixing limestone powder and water to prepare limestone slurry, an exhaust port 7, and a tank for supplying the prepared limestone slurry. It mainly comprises a limestone slurry pump 9 to be transported outside.
石灰石供給コンベア2によって搬入される石灰石の粉
末は、導管3から導入されるパージ用空気とともに石灰
石投入口5を経て石灰石スラリ槽1に投入され、導管8
から投入される水と撹拌、混合されて石灰石スラリとな
り、その後石灰石スラリポンプ9を経て槽外へ取り出さ
れる。The limestone powder carried in by the limestone supply conveyor 2 is introduced into the limestone slurry tank 1 through the limestone inlet 5 together with the purge air introduced from the conduit 3, and the conduit 8
The limestone slurry is stirred and mixed with water supplied from the reactor to form a limestone slurry, which is then taken out of the tank via a limestone slurry pump 9.
第2図において、石灰石投入口5の開閉弁ケーシング
15の内壁面に設けられた可撓性の環状袋体は、脱硫装置
の運転時には収縮して垂れ下がった状態12となって投入
口5を開き、一方、脱硫装置の運転停止時には前記開閉
弁ケーシング15と袋体との間の空間部に、図示省略され
た圧縮空気の導入手段から圧縮空気が導入されて膨張
し、環状袋体中央の空間が閉じた状態13となって石灰石
投入口5を閉鎖する。In FIG. 2, the on-off valve casing of the limestone inlet 5
The flexible annular bag body provided on the inner wall surface of the device 15 contracts and hangs down when the desulfurization device is operating, and opens the charging port 5 while the operation of the desulfurization device is stopped. Compressed air is introduced from a compressed air introducing means (not shown) into the space between the bag 15 and the bag body, and expands, so that the space 13 at the center of the annular bag body is closed and the limestone inlet 5 is closed. To close.
脱硫装置の運転時に開放状態となった環状袋体12には
該環状袋体が閉鎖されていた時に付着凝縮した水分に投
入開始時の石灰石粉末が固着することがあるが、運転中
は導管3からパージ用空気が供給されるため、それ以上
成長せず、投入口5が閉塞することはない。また、脱硫
装置を停止する場合には、環状袋体に圧縮空気が導入さ
れ、該環状袋体を膨張させて投入口5が閉じられるが、
このときに圧縮空気の導入および排出操作、すなわち環
状袋体の膨張、収縮操作を繰り返すことにより、一旦付
着した石灰石粉末の付着物16が払い落とされる。次に付
着物16の払い落とされた前記環状袋体に再度圧縮空気が
導入され、該袋体を膨張させた状態13を保ち、再度運転
を開始するまで投入口5は閉鎖され、石灰石粉末の投入
およびパージ用空気の導入が停止される。運転を再開す
るときは、前記開閉ケーシングと環状袋体との間の圧縮
空気を排出し、膨張した袋体を縮ませて該環状袋体中央
部の空間を開いて投入口5が開放され、石灰石粉末がパ
ージ用空気とともに投入される。The limestone powder at the start of charging may be adhered to moisture condensed and condensed when the annular bag is closed in the annular bag 12 opened during the operation of the desulfurization device. Since the purge air is supplied from the inlet, the growth air does not grow any more and the inlet 5 is not blocked. When the desulfurization device is stopped, compressed air is introduced into the annular bag, the annular bag is expanded, and the charging port 5 is closed.
At this time, by repeatedly performing the operation of introducing and discharging the compressed air, that is, the operation of expanding and contracting the annular bag, the deposit 16 of the limestone powder once deposited is removed. Next, compressed air is again introduced into the annular bag from which the deposits 16 have been removed, and the bag is kept in an expanded state 13, and the charging port 5 is closed until the operation is started again. The introduction and the introduction of the purge air are stopped. When restarting the operation, the compressed air between the openable casing and the annular bag is discharged, the expanded bag is contracted to open the space in the center of the annular bag, and the inlet 5 is opened, Limestone powder is injected with the purging air.
本実施例によれば、石灰石投入口5の内側に圧縮空気
の供給または排出により膨張または収縮して石灰石投入
口を開閉する可撓性の環状袋体を配置したことにより、
一旦付着して固化した石灰石粉末を前記環状袋体の膨張
または収縮により払い落とすことができるので、常に固
着物のない状態が再生でき、投入口5の閉塞を防止でき
る。また、前記環状袋体の膨張により石灰石投入口5が
閉鎖されている間はパージ用の空気を導入する必要がな
いので、ユーティリティ消費を低減することができる。According to the present embodiment, a flexible annular bag that opens and closes the limestone inlet by expanding or contracting by supplying or discharging compressed air is arranged inside the limestone inlet 5.
Since the limestone powder once adhered and solidified can be wiped off by expansion or contraction of the annular bag body, a state without any adhered substance can always be regenerated, and blockage of the charging port 5 can be prevented. Further, it is not necessary to introduce air for purging while the limestone charging port 5 is closed due to the expansion of the annular bag, so that utility consumption can be reduced.
本発明によれば、石灰石粉末の吸湿、付着による石灰
石投入口の閉塞を防止できるとともに、湿式排煙脱硫装
置の頻繁な起動停止に対しても、パージ用空気の消費量
を節約することができる。Advantageous Effects of Invention According to the present invention, it is possible to prevent the limestone charging port from being blocked due to moisture absorption and adhesion of limestone powder, and to save the consumption of purge air even when the wet flue gas desulfurization device is frequently started and stopped. .
第1図は、本発明の一実施例を示す石灰石スラリ貯槽の
断面図、第2図は第1図の部分拡大図、第3図、第4図
および第5図は、従来のスラ貯槽を示す説明図である。 1……石灰石スラリ槽、2……石灰石供給コンベア、3
……導管、5……石灰石投入口、6……撹拌機、7……
排気口、8……導管、9……石灰石スラリポンプ、12
(13)……袋体。FIG. 1 is a sectional view of a limestone slurry storage tank showing an embodiment of the present invention, FIG. 2 is a partially enlarged view of FIG. 1, and FIGS. 3, 4 and 5 show a conventional slurry storage tank. FIG. 1 limestone slurry tank 2 limestone supply conveyor 3
... conduit, 5 ... limestone inlet, 6 ... stirrer, 7 ...
Exhaust port, 8 ... conduit, 9 ... limestone slurry pump, 12
(13) ... A bag.
Claims (1)
閉手段を設けた石灰石スラリ貯槽において、前記開閉手
段として圧縮空気の供給または部分的な押圧により膨張
または収縮する可撓性の袋体を前記石灰石投入口の内側
に設けたことを特徴とする石灰石スラリ貯槽。In a limestone slurry storage tank provided with an opening / closing means at a limestone charging port for charging limestone powder, a flexible bag which expands or contracts by supply of compressed air or partial pressing is used as the opening / closing means. A limestone slurry storage tank provided inside the limestone charging port.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1191860A JP2843062B2 (en) | 1989-07-25 | 1989-07-25 | Limestone slurry storage tank |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1191860A JP2843062B2 (en) | 1989-07-25 | 1989-07-25 | Limestone slurry storage tank |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0356119A JPH0356119A (en) | 1991-03-11 |
JP2843062B2 true JP2843062B2 (en) | 1999-01-06 |
Family
ID=16281703
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1191860A Expired - Fee Related JP2843062B2 (en) | 1989-07-25 | 1989-07-25 | Limestone slurry storage tank |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2843062B2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4514029B2 (en) * | 2004-05-27 | 2010-07-28 | バブコック日立株式会社 | Flue gas desulfurization method and apparatus |
JP6172972B2 (en) * | 2013-02-28 | 2017-08-02 | 京楽産業.株式会社 | Amusement park equipment |
-
1989
- 1989-07-25 JP JP1191860A patent/JP2843062B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH0356119A (en) | 1991-03-11 |
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