JP2021187751A - Cosmetic - Google Patents

Abstract

To provide a thickener for a cosmetic which exhibits excellent gelling ability and excellent gel recoverability and to provide a cosmetic capable of sufficiently exhibiting excellent sense of use, excellent finished appearance such as transparency and performance such as a proper viscosity.SOLUTION: There are provided: a thickener for a cosmetic which comprises an ether compound (A) represented by the general formula (1) and general formula (2); and a cosmetic comprising the thickener for a cosmetic. (In the general formula (1) and general formula (2), R1 and R3 each represents a specific alkyl group, specific alkenyl group and specific alkynyl group and R2 represents a specific alkylene group.)SELECTED DRAWING: None

Description

The present invention relates to cosmetics.

A structure in which a fluid is contained in a three-dimensional network structure or a three-dimensional string-like structure formed by a substance (gelling agent) having an ability to form a gel or thicken a liquid is called a gel, and is generally called a fluid. When water is water, it is called hydrogel, and when it is an organic liquid other than water (organic solvent, oil agent, etc.), it is called oil gel (organogels).

Among these gels, oil gels are actively used in the field of cosmetics for adjusting the fluidity of oily components of cosmetics.

Gelling agents for forming oil gels are roughly classified into high molecular weight thickeners and low molecular weight thickeners.

The polymer thickener has a problem that the quality is not stable due to the variation in the molecular weight, and the oil gel becomes sticky, and when it is blended in a cosmetic, there is a problem that the usability is adversely affected.

On the other hand, as a low-molecular-weight thickener, a thickener having stable quality can be obtained, and since it exhibits thixotropy, an oil gel having an excellent usability can be obtained when blended in cosmetics. Examples of such a low molecular weight thickener include oligodextrin fatty acid ester (Patent Document 1), N-acyl amino acid derivative (Patent Documents 2 and 3), aminoamide derivative (Patent Document 4), and squaric acid amide derivative (Patent Document 1). Document 5) and the like have been reported.

However, these low-molecular-weight thickeners cannot be thickened or gelled depending on the type and polarity of the oily component contained in the cosmetic, the viscosity varies, long-term stability cannot be maintained, and the transparency after compounding is low. When a silicone oil or fluorine oil is used as an oily component, the thickening or gel is sufficient because it must be blended in a large amount for sufficient thickening or gelling, which affects the usability. There are drawbacks such as the inability to convert.

Japanese Unexamined Patent Publication No. 2005-145851 Japanese Unexamined Patent Publication No. 2010-260795 Japanese Unexamined Patent Publication No. 2008-22759 Japanese Patent Publication No. 2014-524901 Japanese Unexamined Patent Publication No. 2013-060496

The applicant has made diligent studies to develop a gelling agent that can sufficiently exhibit the performance as a cosmetic when blended in various cosmetics. As a result, it was found that the ether compound (A) having a specific structure is a useful compound as a thickener for cosmetics, and the cosmetic containing the ether compound (A) having such a specific structure is also found. We have found that the performance as a cosmetic can be sufficiently exhibited, and have completed the present invention.

The subject of the present invention is to provide a thickener for cosmetics which exhibits excellent gelling ability and excellent gel recovery, and has an excellent finished appearance such as excellent usability and transparency, and an appropriate viscosity. The purpose is to provide cosmetics that can fully exhibit such performance.

（一般式（１）および一般式（２）中、Ｒ^１は炭素数が６〜３０で飽和または不飽和の直鎖または分岐鎖のアルキル基、アルケニル基、またはアルキニル基であり、Ｒ^２は炭素数が１〜１０の直鎖のアルキレン基であり、Ｒ^３は炭素数が１〜３０で飽和または不飽和の直鎖または分岐鎖のアルキル基、アルケニル基、またはアルキニル基である。） The cosmetic thickener according to the embodiment of the present invention contains an ether compound (A) represented by the general formula (1) or the general formula (2).

(In the general formula (1) and the general formula (2), R ¹ is a linear or branched linear or branched alkyl group, alkenyl group, or alkynyl group having 6 to 30 carbon atoms and is saturated or unsaturated, and R ² is. a linear alkylene group having 1 to 10 carbon atoms, R ³ is a straight-chain or branched alkyl group, alkenyl group or alkynyl group, a saturated or unsaturated 1 to 30 carbon atoms.)

The cosmetic according to the embodiment of the present invention includes the above-mentioned thickener for cosmetics.

In one embodiment, the cosmetic is a basic cosmetic.

In one embodiment, the cosmetic is a make-up cosmetic.

In one embodiment, the cosmetic is a hair care cosmetic.

According to the present invention, a thickener for cosmetics that exhibits excellent gelling ability and excellent gel recovery, and performance such as excellent usability, excellent finished appearance such as transparency, and appropriate viscosity. It is possible to provide a cosmetic that can be sufficiently expressed.

When the expression "mass" is used in the present specification, it may be read as "weight" which is generally used as a unit of weight, and conversely, the expression "weight" in the present specification. If there is, it may be read as "mass" which is commonly used as an SI system unit indicating weight.

≪≪Thickener for cosmetics≫≫
The cosmetic thickener according to the embodiment of the present invention contains an ether compound (A) having a specific structure. The ether compound (A) having such a specific structure may be only one kind or two or more kinds.

As the content ratio of the ether compound (A) in the thickener for cosmetics according to the embodiment of the present invention, any appropriate content ratio may be adopted depending on the purpose of use of the thickener for cosmetics. Typically, it is preferably 50% by mass to 100% by mass, more preferably 70% by mass to 100% by mass, and further preferably 90% by mass to 100% by mass, based on the total amount of the thickener for cosmetics. %, Particularly preferably 95% by mass to 100% by mass, and most preferably substantially 100% by mass.

<< Ether compound (A) >>
The ether compound (A) is represented by the general formula (1) or the general formula (2).

In the general formula (1) or the general formula (2), R ¹ is a linear or branched alkyl group, alkenyl group, or alkynyl group having 6 to 30 carbon atoms and saturated or unsaturated.

R ¹ is preferably a linear or unsaturated linear or branched alkyl group having 6 to 30 carbon atoms and more preferably having 6 carbon atoms in that the effects of the present invention can be more exhibited. It is a linear or branched alkyl group saturated at ~ 30, and more preferably a straight chain alkyl group saturated at 6-30 carbon atoms.

The carbon number of R ¹ is preferably 8 to 30, more preferably 10 to 28, still more preferably 12 to 28, still more preferably 14 to 14 in that the effects of the present invention can be more exhibited. It is 28, particularly preferably 16 to 26, and most preferably 18 to 22.

In the general formula (1) or the general formula (2), R ² is a linear alkylene group having 1 to 10 carbon atoms.

The number of carbon atoms in R ² are points that can more exhibit the effect of the present invention is preferably 1 to 8, more is preferably 1-6, more preferably 1-5, particularly preferably 2 to It is 4, most preferably 2 to 3.

In the general formula (1) or the general formula (2), R ³ is a linear or branched alkyl group, alkenyl group, or alkynyl group having 1 to 30 carbon atoms and saturated or unsaturated.

R ³ is a straight-chain or branched alkyl group having 1 to 30 carbon atoms and saturated or unsaturated in that the effects of the present invention can be more exhibited, and more preferably 1 carbon atom. It is a linear or branched alkyl group saturated at ~ 30, and more preferably a branched alkyl group saturated at 1 to 30 carbon atoms.

The number of carbon atoms in R ³ are points that can more exhibit the effect of the present invention is preferably 1 to 24, more preferably 2 to 20, more preferably 3 to 14, more preferably 3 to It is 12, particularly preferably 4 to 10, and most preferably 6 to 10.

The ether compound (A) is represented by the general formula (1) or the general formula (2), and is preferably represented by the general formula (1) in that the effects of the present invention can be more exhibited.

The ether compound (A) is a novel low molecular weight compound having excellent gelling ability into an oil gel and gel recovery. In the ether compound (A), the skeleton having an amide bond contributes to excellent gelling ability by forming a three-dimensional network structure or a three-dimensional string-like structure by hydrogen bonding. Further, the ether compound (A), the skeleton having an ester bond, in addition to contributing to the compatibility with the oil by hydrocarbon group R ^3, by hydrogen bonding between the amide bond, superior gelling ability And contributes to gel recovery.

In the ether compound (A), _{the -C 3} H ₆ O- structure located between the ^{-NH- structure and the -R 3} is one of the important structures, whereby the effect of the present invention is further enhanced. Can be expressed.

The ether compound (A) can typically act as an excellent gelling agent.

The content ratio of the ether compound (A) in the gelling agent is preferably 50% by mass to 100% by mass, and more preferably 70% by mass to 100% by mass in that the effect of the present invention can be more exhibited. It is more preferably 90% by mass to 100% by mass, particularly preferably 95% by mass to 100% by mass, and most preferably substantially 100% by mass.

The gelling agent may contain any suitable other components as long as the effects of the present invention are not impaired. Examples of such other components generally include known additive components that can be added to the gelling agent. Such other components may be only one kind or two or more kinds.

<Preferable Embodiment A of the ether compound (A)>
One preferred embodiment of the ether compound (A) (Embodiment A) is represented by the general formula (1), R ¹ is an alkyl linear or branched saturated or unsaturated 6 to 30 carbon atoms A group, an alkenyl group, or an alkynyl group, R ² is a linear alkylene group having 2 carbon atoms (ie, an ethylene group represented by _{−CH 2} CH ₂ ^{−), and R 3} has 1 carbon atom. It is a linear or branched alkyl group, alkenyl group, or alkynyl group saturated or unsaturated at ~ 30.

In Embodiment A, R ¹ is preferably a saturated or unsaturated linear or branched alkyl group having 6 to 30 carbon atoms in that the effects of the present invention can be more exhibited, and more preferably. , A linear or branched alkyl group saturated with 6 to 30 carbon atoms, more preferably a straight chain alkyl group saturated with 6 to 30 carbon atoms.

In embodiments A, the number of carbon atoms in ^{R 1} are points that can more exhibit the effect of the present invention is preferably 8 to 30, more preferably from 10 to 28, more preferably from 12 to 28, It is more preferably 14 to 28, particularly preferably 16 to 26, and most preferably 18 to 22.

In Embodiment A, R ³ is preferably a linear or branched alkyl group having 1 to 30 carbon atoms and saturated or unsaturated in that the effects of the present invention can be more exhibited, and more preferably. , A straight chain or branched alkyl group saturated with 1 to 30 carbon atoms, and more preferably a branched alkyl group saturated with 1 to 30 carbon atoms.

In embodiments A, the number of carbon atoms in ^{R 3} are points that can more exhibit the effect of the present invention is preferably 1 to 24, more preferably 2 to 20, more preferably from 3 to 14, It is more preferably 3 to 12, particularly preferably 4 to 10, and most preferably 6 to 10.

<Preferable Embodiment B of the ether compound (A)>
One preferred alternative embodiment of the ether compound (A) (Embodiment B) is represented by the general formula (1), R ¹ represents a linear or branched, saturated or unsaturated 6 to 30 carbon atoms Is an alkyl group, an alkenyl group, or an alkynyl group, R ² is a linear alkylene group having 3 carbon atoms (that is, a propylene group represented by _{−CH 2} CH ₂ CH ₂ ^{−), and R 3} is. A linear or branched alkyl, alkenyl, or alkynyl group saturated or unsaturated with 1 to 30 carbon atoms.

In Embodiment B, R ¹ is preferably a saturated or unsaturated linear or branched alkyl group having 6 to 30 carbon atoms in that the effects of the present invention can be more exhibited, and more preferably. , A linear or branched alkyl group saturated with 6 to 30 carbon atoms, more preferably a straight chain alkyl group saturated with 6 to 30 carbon atoms.

In embodiments B, the carbon number of ^{R 1} is, in that it can more exhibit the effect of the present invention is preferably 8 to 30, more preferably from 10 to 28, more preferably from 12 to 28, It is more preferably 14 to 28, particularly preferably 16 to 26, and most preferably 18 to 22.

In embodiments B, R ³ are points that can more exhibit the effect of the present invention is preferably a linear or branched chain alkyl group having a carbon number of saturated or unsaturated 1 to 30, more preferably , A straight chain or branched alkyl group saturated with 1 to 30 carbon atoms, and more preferably a branched alkyl group saturated with 1 to 30 carbon atoms.

In embodiments B, the number of carbon atoms of ^{R 3} are points that can more exhibit the effect of the present invention is preferably 1 to 24, more preferably 2 to 20, more preferably from 3 to 14, It is more preferably 3 to 12, particularly preferably 4 to 10, and most preferably 6 to 10.

<Preferable Embodiment C of the ether compound (A)>
One preferred further embodiment of the ether compound (A) (Embodiment C) is represented by the general formula (2), R ¹ is a linear or branched, saturated or unsaturated 6 to 30 carbon atoms The chain is an alkyl group, an alkenyl group, or an alkynyl group, R ² is a linear alkylene group having 1 to 10 carbon atoms, and R ³ is a saturated or unsaturated linear or unsaturated group having 1 to 30 carbon atoms. It is an alkyl group, an alkenyl group, or an alkynyl group of a branched chain.

In Embodiment C, R ¹ is preferably a saturated or unsaturated linear or branched alkyl group having 6 to 30 carbon atoms in that the effects of the present invention can be more exhibited, and more preferably. , A linear or branched alkyl group saturated with 6 to 30 carbon atoms, more preferably a straight chain alkyl group saturated with 6 to 30 carbon atoms.

In Embodiment C, ^{the carbon number of R 1} is preferably 8 to 30, more preferably 10 to 28, still more preferably 12 to 28, in that the effects of the present invention can be more exhibited. It is more preferably 14 to 28, particularly preferably 16 to 26, and most preferably 18 to 22.

In Embodiment C, ^{the carbon number of R 2} is preferably 1 to 8, more preferably 1 to 6, and even more preferably 1 to 5 in that the effects of the present invention can be more exhibited. It is particularly preferably 2 to 4, and most preferably 2 to 3.

In embodiments C, R ³ is a point capable of more express the effects of the present invention is preferably a linear or branched chain alkyl group having a carbon number of saturated or unsaturated 1 to 30, more preferably , A straight chain or branched alkyl group saturated with 1 to 30 carbon atoms, and more preferably a branched alkyl group saturated with 1 to 30 carbon atoms.

In an Form C, the number of carbon atoms of ^{R 3} are points that can more exhibit the effect of the present invention is preferably 1 to 24, more preferably 2 to 20, more preferably from 3 to 14, It is more preferably 3 to 12, particularly preferably 4 to 10, and most preferably 6 to 10.

<Method for producing ether compound (A)>
The ether compound (A) can be synthesized by any suitable method. As such a method, for example, a reaction for forming an ether such as a condensation reaction between an alkoxide and an organic halogen compound and a reaction for adding an alcohol to an olefin can be used for synthesis. In addition, dehydration condensation using an acid catalyst of carboxylic acid and amine, dehydration condensation using a base catalyst, dehydration condensation using carbodiimide, ester-amide exchange reaction, reaction of acid halide and amine, ring opening of imide by amine. It can be synthesized by using a reaction or the like that generally forms an amide, or a reaction that forms an imide with an amine and an acid anhydride, an acid halide, or an ester.

≪Makeup≫
The cosmetic according to the embodiment of the present invention includes the above-mentioned thickener for cosmetics.

As the content ratio of the thickener for cosmetics in the cosmetics according to the embodiment of the present invention, any appropriate content ratio may be adopted depending on the type of cosmetics. Typically, it is preferably 0.001% by mass to 99.99% by mass, more preferably 0.005% by mass to 80% by mass, and further preferably 0.01% by mass with respect to the total amount of cosmetics. % To 50% by mass, particularly preferably 0.01% by mass to 30% by mass, and most preferably 0.01% by mass to 10% by mass.

The cosmetic according to the embodiment of the present invention typically contains a conventional base material in addition to the above-mentioned thickener for cosmetics.

The content ratio of the base material in the cosmetic according to the embodiment of the present invention can be appropriately adjusted depending on the purpose of use.

The cosmetic according to the embodiment of the present invention preferably contains an oil-based base material as the base material.

Examples of the oil-based base include the following. The oily base may be only one kind or two or more kinds.

(1) Hydrocarboned polyisobutene, isododecane, isohexadecane, zokerite, squalane, pristane, liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, ceresin, squalane, α-olefin oligomer, polyisobutene, polybutene, olive-derived squalane Hydrocarbon oils such as petrolatum, solid paraffin, and microcrystalline wax.

(2) Diisostearyl malate, hydrogenated castor oil monoisostearate, cetyl lactate, γ-elcalactone, octyldodecyl myristate, butyl stearate, hexyl laurate, hexyldecyl myristate, octyldodecyl isostearate, parimitinic acid Cetyl, octyldodecyl palmitate, cetyl octanate, hexyldecyl octanate, isotridecyl isononanoate, isononyl isononanolate, octyl isononanoate, isotridecyl isononanoate, isodesyl neopentate, isotrydecyl neopentate, isostearyl neopentate, octyldodecyl neopentane, Oleyl oleate, decyl oleate, octyldodecyl oleate, octyldodecyl licinoleate, octyldodecyl lanolin fatty acid, hexyldecyl dimethyloctaneate, octyldodecylerkaate, hardened castor oil isostearate, ethyl oleate, avocado oil fatty acid ethyl, myristin Isopropyl acid, isopropyl palmitate, octyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl, methylheptyl laurate, methylheptyl myristate, myristyl myristate, methylheptyl palmitate, methylheptyl isostearate, diethyl sebacate, diisopropyl sebacate , Dioctyl sevacinate, diisopropyl adipate, dibutyloctyl sevacinate, diisobutyl adipate, dioctyl succinate, triethyl citrate, glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, tri (caprylic acid / caprylic acid / caprylic acid) Acid) Glyceryl, Tri (caprylic acid / capric acid / myristic acid / stearic acid) Glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl beecosanate, trimethylol trioctanoate , Trimethylolpropane triisostearate, neopentylglycol dioctanoate, neopentylglycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogen Added rosinpentaerythrityl, ditrimethylolpropane triethylhexanoate, (isostearic acid / sebashi) Acid) Ditrimethylol propane, Pentaerythrityl triethylhexarate, (Hydroxystearic acid / Steeric acid / Logonic acid) Dipentaerythrityl, Diglyceryl diisostearate, Polyglyceryl tetraisostearate, Polyglyceryl-10 nonaisostearate, Deca (Elcaic acid / Isostearic) Acid / ricinoleic acid) polyglyceryl-8, (hexyldecanoic acid / sevacinic acid) diglyceryl oligoester, glycol distearate (ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopentanoate, 2,4-pentanoic acid Diethyl-1,5-pentanediol, myristyl lactate, isosetyl stearate, isocetyl isostearate, cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, di-lauroyl-L-glutamate (cholesteryl / Behenyl / octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyl) Dodecyl), acylsarcosine alkyl esters such as N-lauroyl sarcosin isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, phytosteryl isostearate, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid. Cholesteryl, long-chain α-hydroxy fatty acid cholesteryl, di-2-ethylhexanoic acid ethylene glycol, dipentaerythritol fatty acid ester, monoisostearate N-alkylglycol, di-2-heptylundecanoate glycerin, tri-2-ethylhexanoic acid Trimethylol Propane, Trimethylol Propane Triisostearate, Pentaerythritol Tetra-2-ethylhexanoate, Glycerin Tri-2-ethylhexanoate, Glycerin Trioctanoate, Glycerin Triisopalmitate, Cetyl 2-Ethylhexanoate, 2- Ethylhexyl palmitate, glycerin trimyristate, glyceride tri-2-heptylundecanoic acid, methyl ester of castor oil fatty acid, acetoglycerai Do, palmitic acid 2-heptylundecyl, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, adi-2-heptylundesyl adipic acid, ethyllaurate, di-2-ethylhexyl sebacate, 2-myristic acid Ester oils such as hexyldecyl, 2-hexyldecyl palmitate, 2-hexyldecyl adipic acid, and 2-ethylhexyl succinate.

(3) Dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, (aminoethylaminopropyl). Meticone / Dimethicone) Copolymer, Dimethiconol, Dimethiconol Cross Polymer, Silicone Resin, Silicone Rubber, Amino-Modified Silicones such as Aminopropyl Dimethicone and Amodimethicone, Cationic-Modified Silicones, Polyether-Modified Silicones such as Dimethicone Copolyol, Polyglycerin-Modified Silicones, Sugars Modified silicones, carboxylic acid-modified silicones, phosphate-modified silicones, sulfuric acid-modified silicones, alkyl-modified silicones, fatty acid-modified silicones, alkylether-modified silicones, amino acid-modified silicones, peptide-modified silicones, fluorine-modified silicones, cationic-modified and polyether-modified silicones, Silicones such as amino-modified and polyether-modified silicones, alkyl-modified and polyether-modified silicones, amidoalkyl-modified silicones, aminoglycol-modified silicones, aminophenyl-modified silicones, and polysiloxane-oxyalkylene copolymers.

(4) Fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether.

(5) Linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, etc.), branched alcohols (eg, monostearyl glycerin ether (batyl alcohol), 2- Higher alcohols such as decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, octyldodecanol, etc.).

(6) Aralkyl alcohol such as benzyl alcohol and its derivatives.

(7) Lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, palmitic oleic acid, oleic acid, linoleic acid, linoleic acid, erucic acid, docosahexaenoic acid, Higher fatty acids such as eikosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long-chain branched fatty acids, dimer acid, hydrogenated dimer acid, and their aluminum salts, calcium salts, magnesium salts, zinc salts, potassium, sodium. Metallic soaps such as salts, and nitrogen-containing derivatives such as amides.

(8) Candelilla wax, carnauba wax, rice wax, wood wax, honey wax, montan wax, ozokelite, selecin, paraffin wax, microcrystallin wax, petrolatum, Fishertropsh wax, polyethylene wax, ethylene / propylene copolymer and other waxes. ..

(9) Palm oil, palm oil, palm kernel oil, safflower oil, olive oil, sunflower oil, avocado oil, sesame oil, brown oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rose hip oil, Meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, flaxseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil , Vegetable oils and fats such as hydrogenated castor oil, jojoba oil, and hydrogenated jojoba oil.

(10) Animal fats and oils such as beef tallow, milk fat, horse fat, egg yolk oil, mink oil, and turtle oil.

(11) Animal waxes such as whale wax, lanolin, and orange raffy.

(12) Liquid lanolin, reduced lanolin, adsorption-purified lanolin, acetate lanolin, acetate liquid lanolin, hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin acetate alcohol, acetic acid (cetyl lanolin) ester, etc. Lanolins.

(13) Sphingophospholipids such as lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin, and phospholipids such as phosphatidic acid and lysolecithin.

(14) Phospholipid derivatives such as hydrogenated soybean phospholipids, partially hydrogenated soybean phospholipids, hydrogenated egg yolk phospholipids, and partially hydrogenated egg yolk phospholipids.

(15) Sterols such as cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phytosterol, and cholic acid.

(16) Sapogenins.

(17) Saponins.

(18) Lipid complexes such as phospholipid / cholesterol complex and phospholipid / phytosterol complex.

(19) Diisopropyl linoleic acid, diisostearyl dimersylinoleate, dimariginoleate di (isostearyl / phytosteryl), dimeri linoleic acid (phytosteryl / behenyl), dimeri linoleic acid (phytosteryl / isostearyl / cetyl) / Stearyl / Behenyl), Dimer dilinoleic acid Dimerjilinoleil, Dimersy linoleic acid Dimerjirinoleil, Dimerjilinoleyl hydrogenated rosin condensate, Dimerjilinoleic acid hardened castor oil, Hydroxyalkyl linoleic acid Dimer such as dimer Derivatives of acid or dimerdiol.

(20) Palm oil fatty acid monoethanolamide (coconut MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide) MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (coconut methyl MEA) and other fatty acid alkanolamides.

(21) A benzoic acid-based ultraviolet absorber (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxyPABA ethyl ester, N, N- Dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester, etc.); Anthranilic acid-based ultraviolet absorber (for example, homomentyl-N-acetylanthranilate, etc.); Salicylic acid-based ultraviolet absorber (For example, amyl salicylate, menthyl salicylate, homomentyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc.); , Methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p-methoxy cinnamate, isopropyl-p-methoxy cinnamate, isoamyl-p -Methoxysinnamete, octyl-p-methoxysinamate (2-ethylhexyl-p-methoxysinamate), 2-ethoxyethyl-p-methoxysinamate, cyclohexyl-p-methoxysinemate, ethyl-α-cyano-β -Phenyl cinnamate, 2-ethylhexyl-α-cyano-β-phenyl cinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxy cinnamate, etc.); benzophenone-based ultraviolet absorbers (eg, 2,4-dihydroxybenzophenone) , 2,2'-Dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2', 4,4'-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone , 2-Hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate , 2-Hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc.); Ah; 2-Phenyl-5-Methylbenzoxazole; 2,2'-Hydroxy-5-methylphenylbenzotriazole; 2- (2'-Hydroxy-5'-t-octylphenyl) benzotriazole; 2-( 2'-Hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoilmethane; 4-methoxy-4'-t-butyldibenzoylmethane; 5- (3,3-dimethyl-2-norbornylidene) -3-pentane -2-On; UV absorbers such as.

The cosmetic according to the embodiment of the present invention may contain other ingredients that can be generally incorporated into the cosmetic, depending on the purpose. The other components may be only one kind or two or more kinds.

Other components include, for example, water, lower alcohols, polyhydric alcohols, thickeners, moisturizers, surfactants, antioxidants, antioxidant aids, powder components (eg, inorganic powders, organic powders, pigments, etc. (Dyes, etc.), natural water-soluble polymers, semi-synthetic water-soluble polymers, synthetic water-soluble polymers, chelating agents, saccharides and their derivatives, amino acids and their derivatives, organic amines, polymer emulsions, pH adjusters (acids, (Alkaline, etc.), vitamins, preservatives / antibacterial agents, anti-inflammatory agents, whitening agents, various extracts, activators, blood circulation promoters, anti-fat leak agents, anti-inflammatory agents, fragrances, etc. For each of these other components, only one kind may be used, or two or more kinds may be used.

The content ratio of these other components in the cosmetic according to the embodiment of the present invention can be appropriately adjusted depending on the purpose of use.

Examples of the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

Examples of the polyhydric alcohol include divalent alcohols (eg, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, and the like. Pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.; trivalent alcohol (eg, glycerin, trimethylolpropane, etc.); tetravalent alcohol (eg, 1,2,6) -Pentaerythritol such as hexanetriol); pentavalent alcohol (eg, xylitol, etc.); hexavalent alcohol (eg, sorbitol, mannitol, etc.); polyhydric alcohol polymer (eg, diethylene glycol, dipropylene glycol, triethylene glycol, etc.) Polypylene glycol, tetraethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.; divalent alcohol alkyl ethers (eg, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, etc.) Ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol mono2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, etc. ); Divalent alcohol alkyl ethers (eg, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl). Ether, Propylene Glycol Monomethyl Ether, Propylene Glycol Monoethyl Ether, Propylene Glycol Monobutyl Ether, Propylene Glycol Isole Ether, Dipropylene Glycol Methyl Ether, Dipropylene Glycol Ethyl Ether, Dipropylene Glycol Lubutyl ether, etc.); Dihydric alcohol ether esters (eg, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, ethylene glycol diazibate, ethylene glycol disakushi) Nate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monophenyl ether acetate, etc.; glycerin monoalkyl ether (eg, xyl). Alcohols, cerakil alcohols, batyl alcohols, etc.); Sugar alcohols (eg, sorbitol, martitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, starch-degrading sugars, maltose, xylitos, starch-degrading sugar-reducing alcohols, etc. ); Glysolid; Tetrahydroflufuryl alcohol; POE-Tetrahydrofurfuryl alcohol; POP-butyl ether; POP / POE-butyl ether; Tripolyoxypropylene glycerin ether; POP-glycerin ether; POP-glycerin ether phosphoric acid; POP / POE -Pentane erythritol ether; polyglycerin; etc.

Examples of the thickener include arabic gum, carrageenan, carrageenan, tragacanto gum, carob gum, quince seed (malmero), casein, dextrin, gelatin, sodium pectinate, sodium aragnate, methyl cellulose, ethyl cellulose, CMC, hydroxyethyl cellulose, hydroxypropyl. Cellulose, PVA, PVM, PVP, Sodium Polyacrylate, Carrageenan Polymer, Locust Bean Gum, Gua Gum, Tamarinto Gum, Dialkyldimethylammonium Sulfate Cellulose, Xanthan Gum, Aluminum Magnesium Silate, Bentnite, Hectrite, AlMg Silica (Bea Gum), Examples include laponite and silicic anhydride.

Examples of the moisturizing agent include dipropylene glycol, glycerin, polyethylene glycol, propylene glycol, 1,3-butylene glycol, xylitol, sorbitol, martitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, and cholesteryl-12. -Hydroxystearate, sodium lactate, bile acid salt, dl-pyrrolidone carboxylate, short chain soluble collagen, diglycerin (EO) PO adduct, Izayoi rose extract, sardine extract, melilot extract and the like.

Examples of the surfactant include anionic surfactants, cationic surfactants, amphoteric surfactants, hydrophilic nonionic surfactants, lipophilic nonionic surfactants and the like.

Examples of the anionic surfactant include fatty acid sequent (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfate ester salts (eg, sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfate ester salts (eg, eg, sodium lauryl sulfate). POE lauryl sulfate triethanolamine, POE sodium lauryl sulfate, etc.); N-acylsarcosic acid (eg, sodium lauroyl sulcocin); higher fatty acid amide sulfonate (eg, N-myristoyl-N-methyltaurine sodium, coconut oil fatty acid) Methyl taurid sodium, lauryl methyl taurid sodium, etc.); Phosphate ester salts (POE oleyl ether phosphate sodium, POE stearyl ether phosphoric acid, etc.); Monoethanolamide polyoxyethylene sodium sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc.); Alkylbenzene sulfonate (eg, sodium linear dodecylbenzene sulfonate, triethanolamine lineardodecylbenzene sulfonate, lineardodecylbenzene sulfonic acid, etc.); Higher fatty acid ester sulfate ester salt (eg, hardened coconut oil fatty acid sodium glycyl sulfate, etc.); N-acylglutamate (eg, N-sodium lauroyl glutamate, disodium N-stearoyl glutamate, monosodium N-myristoyl-L-glutamate). Etc.); Sulfated oil (eg, funnel oil, etc.); POE alkyl ether carboxylic acid; POE alkyl allyl ether sulfonate; α-olefin sulfonate; higher fatty acid ester sulfonate; secondary alcohol sulfate ester salt; higher Examples thereof include fatty acid alkyrrole amide sulfate ester salt; sodium lauroyl monoethanolamide succinate; N-palmitoyl aspartate ditriethanolamine; sodium caseinate; and the like.

Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (eg, cetylpyridinium chloride, etc.); disstearyldimethylammonium chloride dialkyldimethylammonium salts; Polychloride (N, N'-dimethyl-3,5-methylenepiperidinium); alkyl quaternary ammonium salt; alkyldimethylbenzylammonium salt; alkylisoquinolinium salt; dialkylmoriphonium salt; POE alkylamine; alkyl Ammonium salts; polyamine fatty acid derivatives; ammonium alcohol fatty acid derivatives; benzalconium chloride; benzethonium chloride; and the like.

Examples of the amphoteric surfactant include imidazoline-based amphoteric surfactants (eg, 2-undesyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroki. Side-1-carboxyethyroxy 2-sodium salt, etc.); Betaine-based surfactants (eg, 2-heptadecyl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide betaine) , Sulfobetaine, etc.); and the like.

Examples of the hydrophilic non-ionic surfactant include POE sorbitan fatty acid esters (eg, POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monooleate, POE sorbitan tetraoleate, etc.); POE sorbitan fatty acid esters. Classes (eg, POE sorbit monolaurate, POE sorbit monooleate, POE sorbit pentaoleate, POE sorbit monosteerate, etc.); POE glycerin fatty acid esters (eg, POE glycerin monostearate, POE glycerin monoisostearate, etc.) , POE monooleate such as POE glycerin triisostearate); POE fatty acid esters (eg, POE distearate, POE monodiolate, ethylene glycol distearate, etc.); POE alkyl ethers (eg, POE lauryl ether, POE oleyl ether, POE) Stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE cholestanol ether, etc.; Pluronic types (eg, Pluronic, etc.); POE / POP alkyl ethers (eg, POE / POP cetyl ether, POE, etc.) POP-2-decyltetradecyl ether, POE / POP monobutyl ether, POE / POP hydrogenated lanolin, POE / POP glycerin ether, etc.); Tetra POE / Tetra POP ethylenediamine condensates (eg, Tetronic); POE castor oil Hardened castor oil derivatives (eg POE castor oil, POE cured castor oil, POE cured castor oil monoisostearate, POE cured castor oil triisostearate, POE cured castor oil monopyroglutamic acid monoisostearic acid diester, POE cured castor oil Maleic acid, etc.); POE mitsuro / lanolin derivative (eg, POE sorbit honeyslow, etc.); Alkanol amide (eg, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE propylene glycol fatty acid ester; POE alkyl Examples include amines; POE fatty acid amides; sucrose fatty acid esters; alkylethoxydimethylamine oxides; trioleyl phosphates; and the like.

Examples of the lipophilic nonionic surfactant include sorbitan fatty acid esters (eg, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, etc. Solbitan trioleate, penta-2-ethylhexylate diglycerol sorbitan, tetra-2-ethylhexylate diglycerol sorbitan, etc.; , Α, α'-glycerin pyroglutamate oleate, glycerin malic acid monostearate, polyglyceryl monoisostearate, polyglyceryl diisostearate, etc.); propylene glycol fatty acid esters (eg, propylene glycol monostearate, etc.); cured castor oil derivative ; Glycerin alkyl ether; and the like.

Examples of the antioxidant include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.

Examples of the antioxidant aid include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, ethylenediamine tetraacetic acid and the like.

Examples of the powder component include inorganic powders (eg, talc, kaolin, mica, silk mica (serisite), white mica, gold mica, synthetic mica, red mica, black mica, permiculite, magnesium carbonate, calcium carbonate, silicic acid. Aluminum, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tung acid salt, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (baked sekko), calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder , Metal soap (eg, zinc myristate, calcium palmitate, aluminum stearate), titanium dioxide, etc.); Organic powder (eg, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene) And acrylic acid copolymer resin powder, benzoguanamine resin powder, polytetrafluorinated ethylene powder, cellulose powder, etc.); Inorganic white pigments (eg, titanium dioxide, zinc oxide, etc.); Inorganic red pigments (eg, iron oxide (eg, iron oxide) Bengala), iron titanate, etc.); Inorganic brown pigments (eg, γ-iron oxide, etc.); Inorganic yellow pigments (eg, yellow iron oxide, ocher, etc.); Inorganic black pigments (eg, black iron oxide, low) Titanium oxide, etc.); Inorganic purple pigments (eg, mango violet, cobalt violet, etc.); Inorganic green pigments (eg, chromium oxide, chromium hydroxide, cobalt titanate, etc.); Inorganic blue pigments (eg, ultramarine, etc.) Navy blue, etc.); Pearl pigments (eg, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, etc.); Metal powder pigments (eg, aluminum powder, etc.) Copper powder, etc.); Organic pigments such as zirconium, barium or aluminum lake (eg, Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Organic pigments such as orange 203, orange 204, yellow 205, yellow 401, and blue 404, red 3, red 104, red 106, red 227, red 230, red 401, red. 505, orange 205, yellow 4, yellow 5, yellow 202, yellow 203, green 3 and blue 1, etc.); natural pigments (eg, chlorophyll, β-carotene, etc.); etc. ..

Examples of the natural water-soluble polymer include plant-based polymers (for example, Arabic gum, tragacant gum, galactan, guagam, carob gum, karaya gum, carrageenan, pectin, canten, quinsseed (malmero), algae colloid (cassow extract), starch (for example). Rice, corn, potato, wheat), glycyrrhizinic acid); microbial macromolecules (eg, xanthan gum, dextran, succinoglucan, burran, etc.); animal macromolecules (eg, collagen, casein, albumin, gelatin, etc.); etc. Can be mentioned.

Examples of the semi-synthetic water-soluble polymer include starch-based polymers (for example, carboxymethyl starch, methyl hydroxypropyl starch, etc.); cellulose-based polymers (methyl cellulose, ethyl cellulose, methyl hydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, etc.). Hydroxypropyl cellulose, carboxymethyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, etc.); Arginic acid-based polymers (for example, sodium alginate, propylene glycol alginate, etc.); and the like.

Examples of the synthetic water-soluble polymer include vinyl polymers (for example, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymers, etc.); polyoxyethylene polymers (for example, polyethylene glycol 20,000, 40, etc.). 000, 60,000, etc.); Acrylic polymers (eg, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); Polyethyleneimine; Cationic polymers; and the like.

Examples of the chelating agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, tetrasodium edetate, and quen. Examples thereof include sodium acid, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, and ethylenediamine hydroxyethyl triacetate trisodium.

Examples of saccharides and their derivatives include monosaccharides, oligosaccharides, polysaccharides and the like.

Examples of the monosaccharide include tricarbose (eg, D-glycerylaldehyde, dihydroxyacetone, etc.); tetracarbose (eg, D-erythrose, D-erythrose, D-treose, erythritol, etc.); , L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-librose, D-xylrose, L-xylrose, etc.); -Bushicose, D-galactose, D-fluctose, L-galactose, L-mannose, D-tagatose, etc.); Seven-carbon sugar (eg, aldoheptose, heprose, etc.); For example, 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, etc.; amino sugars (eg, D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.) ); Uronic acid (for example, D-glucuronic acid, D-mannuronic acid, L-gluuronic acid, D-galacturonic acid, L-isulonic acid, etc.); and the like.

Examples of oligosaccharides include sucrose, gunthianose, umbelliferose, lactose, planteose, isolikunoses, α, α-trehalose, raffinose, lycnoses, umbilicin, stachyose velvas and the like.

Examples of polysaccharides include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, Arabic gum, heparan sulfate, hyaluronic acid, tragant gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guagam, dextran, and keratosulfate. , Locust bean gum, succinoglucan, caronic acid and the like.

Amino acids and their derivatives include, for example, neutral amino acids (eg, threonine, cysteine, etc.), basic amino acids (eg, hydroxylysine, etc.), acylsarcosine sodium (lauroylsarcosine sodium), acylglutamate, acyl-β-alanine. Examples include sodium, glutathione, pyrrolidone carboxylic acid and the like.

Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-1-propanol and the like. Can be mentioned.

Examples of the polymer emulsion include an acrylic resin emulsion, an ethyl polyacrylic acid emulsion, an acrylic resin liquid, a polyacrylic alkyl ester emulsion, a polyvinyl acetate resin emulsion, and a natural rubber latex.

Examples of the pH adjuster include lactic acid-sodium lactate, citric acid-sodium citrate, succinic acid-sodium succinate, alkali metals (sodium and potassium, etc.) or alkali earth metal (calcium, etc.) hydroxides, and ammonia. Examples include water, citric acid, tartrate acid, lactic acid, phosphoric acid and the like.

Examples of vitamins include vitamin A, vitamin B1, vitamin B2, vitamin B6, vitamin C, vitamin E, derivatives thereof, pantothenic acid, this derivative, biotin and the like.

Examples of preservatives and antibacterial agents include parabens such as ethylparaben, isopropylparaben, butylparaben, and benzylparaben and their sodium salts, benzoic acid, benzoate, alkyldiaminoethylglycine hydrochloride, and photosensitizers. Chlorcrezole, chlorobutanol, salicylic acid, salicylates, sorbic acid and its salts, dehydroacetic acid and its salts, trichlorohydroxydiphenyl ether (also known as triclosan), phenoxyethanol, phenol, lauryldiaminoethylglycine sodium, resorcin, zinc / ammonia / silver composite substitution Type zeolite, pantothenyl ethyl benzoate, isopropylmethylphenol, cetylpyridinium chloride, benzalkonium chloride, benzethonium chloride, chlorhexidine hydrochloride, orthophenylphenol, orthophenylphenol sodium, silver-copper zeolite, chlorhexidine gluconate, cresol, chloramine Examples thereof include T, chlorxylenol, chlorphenesin, chlorhexidine, 1,3-dimethylol-5,5-dimethylhydantoin, alkylisoquinolinium bromide, thiantoll, timol and the like.

Examples of the anti-inflammatory agent include glycyrrhizic acid derivative, glycyrrhetinic acid derivative, salicylic acid derivative, hinokitiol, zinc oxide, allantoin and the like.

Examples of the whitening agent include placenta extract, saxifraga stolon extract, arbutin and the like.

Examples of various extracts include Swertia japonica, Coptis chinensis, Coptis chinensis, Swertia japonica, Swertia japonica, Birch, Sage, Loquat, Carrot, Aloe, Mallow, Iris, Grape, Yokuinin, Loofah, Yuri, Saffron, Senkyu, Shokyu, Otogirisou, Ononis. , Garlic, capsicum, chili, swertia japonica, seaweed and the like.

Examples of the activator include royal jelly, photosensitizers, cholesterol derivatives and the like.

Examples of the blood circulation promoter include nonylate valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingeron, cantalistinki, ictamol, tannic acid, α-borneol, tocopherol nicotinate, and inositol hexanicotinate. , Cicrandelate, cinnaridine, trazoline, acetylcholine, verapamil, cepharanthin, γ-oryzanol and the like.

Examples of the antiseborrheic agent include sulfur, thiantoll and the like.

Examples of the anti-inflammatory agent include tranexamic acid, thiotaurine, hypotaurine and the like.

Examples of the fragrance include citral, menthol, ginger, salvinolin A, cannabinoid, hinokithiol, limonene, farnesol, terpenoids such as vitamin A; aromatic alcohols such as phenoxyethanol, phenols such as eugenol and ginger; butyric acid esters, Examples thereof include esters such as propionic acid esters; lactones such as γ-nonalactone and γ-undecalactone; aldehydes having 6 to 20 carbon atoms; and the like.

Other components include, for example, colorants, antiperspirants, refreshing agents, astringents, antihistamines, hair growth agents, reducing agents / oxidizing agents, enzymes, nucleic acids, hormones and the like. ..

As other ingredients, even those not specifically listed above can be adopted as long as they are other ingredients that can be generally blended in cosmetics. For example, the latest cosmetic science (published by Pharmaceutical Affairs Daily), etc. Cosmetic Ingredient Standards, Ingredient Standards for Cosmetic Ingredients, Ingredient Labeling Name List of Japan Cosmetic Industry Association, INCI Dictionary (The International Cosmetic Ingredient Handbook), Ingredient Standards for Non-pharmaceutical Products, Japanese Pharmacy, Pharmaceutical Additives Standards, Food Additions Known ingredients such as those described in official regulations can be adopted.

≪Types of cosmetics≫
The cosmetics according to the embodiment of the present invention are classified into oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type, etc. Emulsifying cosmetics, oily cosmetics, solid cosmetics, liquid cosmetics, paste cosmetics, stick cosmetics, volatile oil cosmetics, powder cosmetics, jelly cosmetics, gel cosmetics, pastes Examples thereof include make-up, emulsified polymer-type make-up, sheet-like make-up, mist-like make-up, and spray-type make-up.

Examples of the type of cosmetics according to the embodiment of the present invention include any appropriate type of cosmetics as long as the effects of the present invention are not impaired. Examples of such types include basic cosmetics, make-up cosmetics, hair care cosmetics, aromatic cosmetics, body cosmetics, external skin preparations, oral cosmetics and the like.

Basic cosmetics include, for example, cleansing gels, cleansing oils, cleansing foams, cleansing creams, cleansing milks, cleansing lotions, cleansing masks, washing powders, facial cleansing powders, and other washing pigments; softening lotions, astringent lotions, and washing lotions. , Multi-layered lotion, etc .; Massage oil; Sunscreen; Emollient lotion, Moisture lotion, Milky lotion, Nourishing lotion, Nourishing milk, Skin moisture, Moistur emulsion, Massage lotion, Cleansing lotion, Protect emulsion, Emulsions such as Sun Protect, Sun Protector, UV Care Milk, Sun Screen, Makeup Lotion, Cleanser, Elbow Lotion, Hand Lotion, Body Lotion; W / O Cream, Emollient Cream, Nourishing Cream, Nourishing Cream, Vanishing Cream, Moisture cream, night cream, massage cream, cleansing cream, make-up cream, base cream, pre-makeup cream, sunscreen cream, suntan cream, hair removal cream, deodorant cream, shaving cream, keratin softening cream, etc.; Moisture gel Gels such as; Moisturizing essence, whitening essence, UV protection essence, etc .; Lipstick beauty liquid, liposome cosmetics such as liposome cosmetics; Peel-off packs, powder packs, washing packs, oil packs, cleansing masks, etc. ; Soaps such as cosmetic soaps, cleansers, medicated soaps, liquid soaps, shaving soaps, and synthetic cosmetic soaps;

Examples of make-up cosmetics include lip gloss, white powder / dusting powder, foundations, lipsticks, blushers, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment. ..

Hair care cosmetics include, for example, hair oil, oil shampoo, cream shampoo, conditioning shampoo, indulgence shampoo, hair color shampoo, rinse-integrated shampoo, other shampoos, rinses, treatments, hair packs, hair foams, hair mousses, hair. Spray, Hair Mist, Hair Wax, Hair Gel, Water Grease, Set Lotion, Color Lotion, Hair Tonic, Hair Liquid, Pomade, Chick, Hair Cream, Hair Blow, Split Hair Coat, Permanent Wave Agent, Straight Perm Agent, Oxidation Hair Dye , Hair bleach, hair color pre-treatment, hair color after-treatment, perma pre-treatment, perma after treatment, hair manicure, hair styling product and the like.

Examples of aromatic cosmetics include perfumes, perfumes, parfume, eau de parfum, eau de toilette, eau de cologne, perfumes, aromatic powders, perfume soaps, body lotions, bath oils and the like.

Examples of body cosmetics include body cleaning agents such as body shampoo; deodorant cosmetics such as deodorant lotion, deodorant powder, deodorant spray, and deodorant stick; depigmenting agents, depilatory / depilatory agents; bathing agents; insect repellent sprays, etc. Insectripeller; etc.

Examples of the external skin preparation include ointments, patches, lotions, liniments, liquid coatings and the like.

Examples of the oral cosmetics include toothpaste and mouthwash.

As described above, the cosmetics according to the embodiment of the present invention include basic cosmetics such as cleansing gel, massage oil, sunscreen, W / O cream, makeup cosmetics such as lip gloss, and hair care cosmetics such as hair oil. It can be used as such.

Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited to these examples. Unless otherwise specified, "part" means "part by mass" and "%" means "% by mass".

[Manufacturing Example 1]
Succinic anhydride (19.7 g, 197 mmol) and N, N- in a mixed solution of N, N-dimethylformamide (100 ml), tetradecylamine (40.0 g, 187 mmol), and triethylamine (37.9 g, 374 mmol). A mixed solution of dimethylformamide (100 ml) was added over 10 minutes and stirred at 80 ° C. for 15 minutes. Acetic anhydride (20.1 g, 197 mmol) was added dropwise over 10 minutes and stirred at 80 ° C. for 30 minutes. The reaction mixture was poured into water (500 ml), the precipitate was filtered and washed with distilled water. The crude product was purified by recrystallization with acetone. As a result, 52.1 g (176 mmol) of tetradecylsuccinimide was obtained as a 94% white crystalline powder. The obtained tetradecylsuccinimide (5.0 g, 16.9 mmol) and 3- (2-ethylhexanoyl) propylamine (9.51 g, 50.8 mmol) were reacted at 125 ° C. for 72 hours. 40 mL of acetonitrile was added to the reaction mixture at about 100 ° C., the mixture was cooled to room temperature, the precipitated crystals were filtered, and the mixture was washed with a small amount of acetonitrile. The crude product was dried and purified by recrystallization with acetone. Compound (1) was obtained as a white crystalline powder in a yield of 73.2% (5.97 g, 12.4 mmol).

[Manufacturing Example 2]
Succinic anhydride (15.6 g, 156 mmol) and N, N-dimethylformamide in a mixed solution of N, N-dimethylformamide (100 ml), hexadecylamine (35.6 g, 148 mmol), and triethylamine (30 g, 297 mmol). A mixed solution of (100 ml) was added over 10 minutes and stirred at 80 ° C. for 15 minutes. Acetic anhydride (15.9 g, 156 mmol) was added dropwise over 10 minutes and stirred at 80 ° C. for 30 minutes. The reaction mixture was poured into water (500 ml), the precipitate was filtered and washed with distilled water. The crude product was purified by recrystallization with acetone. As a result, 45.1 g (140 mmol) of hexadecylsuccinimide was obtained as a 94% white crystalline powder. The obtained hexadecylsuccinimide (5.4 g, 16.9 mmol) and 3- (2-ethylhexanoyl) propylamine (9.51 g, 50.8 mmol) were reacted at 125 ° C. for 72 hours. 40 mL of acetonitrile was added to the reaction mixture at about 100 ° C., the mixture was cooled to room temperature, the precipitated crystals were filtered, and the mixture was washed with a small amount of acetonitrile. The crude product was dried and purified by recrystallization with acetone. Compound (2) was obtained as a white crystalline powder in a yield of 65.0% (5.60 g, 11.0 mmol).

[Manufacturing Example 3]
Succinic anhydride (15.6 g, 156 mmol) and N, N-dimethylformamide (15.6 g, 156 mmol) in a mixed solution of N, N-dimethylformamide (100 ml), octadecylamine (40.0 g, 148 mmol), and triethylamine (30 g, 297 mmol). 100 ml) of the mixed solution was added over 10 minutes and stirred at 80 ° C. for 15 minutes. Acetic anhydride (15.9 g, 156 mmol) was added dropwise over 10 minutes and stirred at 80 ° C. for 30 minutes. The reaction mixture was poured into water (500 ml), the precipitate was filtered and washed with distilled water. The crude product was purified by recrystallization with acetone. As a result, 49.1 g (140 mmol) of octadecylsuccinimide was obtained as a 94% white crystalline powder. The obtained heoctadecylsuccinimide (5.93 g, 16.9 mmol) and 3- (2-ethylhexanoyl) propylamine (9.51 g, 50.8 mmol) were reacted at 125 ° C. for 72 hours. 40 mL of acetonitrile was added to the reaction mixture at about 100 ° C., the mixture was cooled to room temperature, the precipitated crystals were filtered, and the mixture was washed with a small amount of acetonitrile. The crude product was dried and purified by recrystallization with acetone. Compound (3) was obtained as a white crystalline powder in a yield of 83.8% (7.63 g, 14.2 mmol).

[Manufacturing Example 4]
Succinic anhydride (15.6 g, 156 mmol) and N, N-dimethylformamide (100 ml) in a mixed solution of N, N-dimethylformamide (100 ml), docosylamine (48.4 g, 148 mmol), and triethylamine (30 g, 297 mmol). ) Was added over 10 minutes and stirred at 80 ° C. for 15 minutes. Acetic anhydride (15.9 g, 156 mmol) was added dropwise over 10 minutes and stirred at 80 ° C. for 30 minutes. The reaction mixture was poured into water (500 ml), the precipitate was filtered and washed with distilled water. The crude product was purified by recrystallization with acetone. As a result, 57.3 g (140 mmol) of docosyl succinimide was obtained as a 94% white crystalline powder. The obtained heoctadecylsuccinimide (6.91 g, 16.9 mmol) and 3- (2-ethylhexanoyl) propylamine (9.51 g, 50.8 mmol) were reacted at 125 ° C. for 72 hours. 40 mL of acetonitrile was added to the reaction mixture at about 100 ° C., the mixture was cooled to room temperature, the precipitated crystals were filtered, and the mixture was washed with a small amount of acetonitrile. The crude product was dried and purified by recrystallization with acetone. Compound (4) was obtained as a white crystalline powder in a yield of 54.8% (5.52 g, 9.26 mmol).

[Manufacturing Example 5]
Glutaric anhydride (17.8 g, 156 mmol) and N, N-dimethylformamide (17.8 g, 156 mmol) in a mixed solution of N, N-dimethylformamide (100 ml), octadecylamine (40.0 g, 148 mmol), and triethylamine (30 g, 297 mmol). 100 ml) of the mixed solution was added over 10 minutes and stirred at 80 ° C. for 15 minutes. Acetic anhydride (15.9 g, 156 mmol) was added dropwise over 10 minutes and stirred at 80 ° C. for 30 minutes. The reaction mixture was poured into water (500 ml), the precipitate was filtered and washed with distilled water. The crude product was purified by recrystallization with acetone. This gave 24.3 g (66.6 mmol) of octadecylglutarimide as a 45% white crystalline powder. The obtained octadecylglutarimide (6.17 g, 16.9 mmol) and 3- (2-ethylhexanoyl) propylamine (9.51 g, 50.8 mmol) were reacted at 125 ° C. for 72 hours. 40 mL of acetonitrile was added to the reaction mixture at about 100 ° C., the mixture was cooled to room temperature, the precipitated crystals were filtered, and the mixture was washed with a small amount of acetonitrile. The crude product was dried and purified by recrystallization with acetone. Compound (5) was obtained as a white crystalline powder in a yield of 75.0% (7.01 g, 12.7 mmol).

[Manufacturing Example 6]
β-Alanine (6.0 g, 67.3 mmol) and potassium hydroxide (3.15 g, 56.1 mmol) were dissolved in a 30% 2-propanol aqueous solution (50 mL). Millistyl chloride (2.77 g, 11.2 mmol) was added dropwise to this solution in 1 minute, and the mixture was stirred for 5 minutes, then a 5% aqueous potassium hydroxide solution (12.6 g) was added, and the mixture was stirred for 1 minute. After repeating this operation 5 times, the mixture was stirred for 30 minutes (myristyl chloride: 13.85 g in total, 56.1 mmol). 120 mL of 5% hydrochloric acid was added to the reaction solution to make it acidic, and the obtained solid was filtered and washed with water. The obtained solid was dried to obtain crudely purified N-myristoyl-β-alanine (14.4 g, 48.1 mmol, 85.7%). N-myristoyl-β-alanine (5.30 g, 17.7 mmol), benzyl alcohol (9.56 g, 88.5 mmol), and p-toluenesulfonic acid monohydrate (505 mg, 2.66 mmol) in 40 mL of toluene It was dissolved, heated under reflux and dehydrated (about 2 hours). After the generation of water was completed, toluene was removed, 3- (2-ethylhexanoyl) propylamine (6.63 g, 35.4 mmol) was added, and the mixture was stirred at 180 ° C. for 1 hour. The reaction solution was poured into water, and the obtained solid was collected by filtration and washed with water. The obtained solid was purified by recrystallization with acetone to obtain compound (6) as a white crystal in a yield of 89.2% (4.72 g, 15.8 mmol).

[Manufacturing Example 7]
β-Alanine (8.05 g, 90.4 mmol) and potassium hydroxide (4.2 g, 75.3 mmol) were dissolved in a 30% 2-propanol aqueous solution (60 mL). Lauroyl chloride (3.29 g, 15.1 mmol) was added dropwise to this solution in 1 minute, and the mixture was stirred for 5 minutes, then a 5% aqueous potassium hydroxide solution (16.9 g) was added, and the mixture was stirred for 1 minute. After repeating this operation 5 times, the mixture was stirred for 30 minutes (myristyl chloride: 16.5 g in total, 75.3 mmol). 140 mL of 5% hydrochloric acid was added to the reaction solution to make it acidic, and the obtained solid was filtered and washed with water. The obtained solid was dried to obtain crudely purified N-lauroyl-β-alanine (18.3 g, 66.6 mmol, 88.5%). N-myristoyl-β-alanine (5.0 g, 18.4 mmol), butyl carbitol (14.9 g, 162.2 mmol), and p-toluenesulfonic acid monohydrate (530 mg, 2.76 mmol) at 170 ° C. Was dehydrated under reduced pressure for 1 hour. To this solution was added 3- (2-ethylhexanoyl) propylamine (6.90 g, 36.8 mmol), and the mixture was stirred at 170 ° C. for 1 hour. The reaction solution was poured into water, and the obtained solid was collected by filtration and washed with water. The obtained solid was purified by recrystallization with acetone to obtain compound (7) as a white crystal in a yield of 47.0% (3.82 g, 8.67 mmol).

[Manufacturing Example 8]
16.2 g of dextrin (average degree of polymerization of 30) was dispersed in 111 g of 3-methylpyridine to adjust the temperature to 50 ° C. 82.5 g of palmitic acid chloride was added dropwise for 30 minutes. After completion of the dropping, the reaction was carried out for 4 hours at a reaction temperature of 90 ° C. The reaction solution was precipitated in methanol, filtered, and the solid content was washed with methanol and then dried to obtain 80 g of compound (8) as a white powder.

[Examples A to E]
The compounds (1) to (5) obtained in Production Examples 1 to 5 were used as cosmetic thickeners (A) to (E).
The obtained cosmetic thickeners (A) to (E) were evaluated for gelling ability and gel recovery. The results are shown in Tables 1 and 2.

<Evaluation of gelling ability>
To cyclopentasiloxane, liquid paraffin, indodecane, squalane, 2-ethylhexyl palmitate, tri (caprylic acid / capric acid) glyceryl, diisostearyl malate, olive oil, 2-ethylhexyl methoxycinnamate, 1,3-butanediol , A thickener for cosmetics was blended so as to have a concentration of 1% by mass, and the mixture was placed in a vial. Then, after heating at 100 degreeC for 30 minutes, it was allowed to stand at room temperature for 1 hour, and it was visually judged whether or not it was gelled. The results are shown in Table 1.
◯: It was gelled.
X: Not gelled.

<Evaluation of gel recovery>
For the gelled product in the vial whose gelling ability was evaluated as ○, stirring the vial with a spatula for 10 seconds in a normal standing state was performed for 2 days (0 minutes, 5 minutes, 15 minutes later). , 30 minutes, 1 hour, 2 hours, 12 hours, 24 hours, 24 hours 5 minutes, 24 hours 15 minutes, 24 hours 30 minutes, 25 hours, 26 hours, 36 hours. , 48 hours later), after which the vial was laid 90 degrees sideways and allowed to stand for 1 minute, and the degree of gel recovery was evaluated on a 4-point scale (0, 1, 2, 3). The higher the number, the better the gel recovery. The results are shown in Table 2.

[Examples 1 to 7, Comparative Example 1]
Using the compounds (1) to (8) obtained in Production Examples 1 to 8, lip gloss was produced by the formulation shown in Table 1. Specifically, it is as follows.
Any of the compounds (1) to (8) was blended with Pearl Ream EX (hydrogenated polyisobutene, manufactured by NOF) and heated at 100 ° C. for 30 minutes to dissolve. Pearl Dream 18 (hydrogenated polyisobutene, manufactured by NOF) and Cosmol 222 (diisostearyl malate, manufactured by NOF) were sequentially added to the obtained liquid at room temperature and mixed so as to be uniform. To the obtained mixed solution, add RonaStar Golden Jewel (pearl pigment, borosilicate (Ca / Al), titanium oxide, iron oxide, silica, tin oxide, manufactured by Merck) at room temperature to make it uniform. To produce lip gloss.
The initial state of the obtained lip gloss and the dispersibility of the pearl pigment were evaluated. The evaluation method and evaluation criteria are as follows. The results are shown in Table 3.

[Comparative Example 2]
Lip gloss was produced by the formulation shown in Table 1 without using the compounds (1) to (8) obtained in Production Examples 1 to 8. Specifically, it is as follows.
Pearl Ream 18 (hydrogenated polyisobutene, manufactured by NOF) and Cosmol 222 (diisostearyl malate, manufactured by NOF) are sequentially added to Pearl Ream EX (hydrogenated polyisobutene, manufactured by NOF) at room temperature, and uniformly added. It was mixed so as to be. To the obtained mixed solution, add RonaStar Golden Jewel (pearl pigment, borosilicate (Ca / Al), titanium oxide, iron oxide, silica, tin oxide, manufactured by Merck) at room temperature to make it uniform. To produce lip gloss.
The initial state of the obtained lip gloss and the dispersibility of the pearl pigment were evaluated. The evaluation method and evaluation criteria are as follows. The results are shown in Table 3.

<Dispersibility of pearl pigment>
Evaluation method: The pigment dispersibility of the pearl pigment was evaluated. 5 mL of the prepared lip gloss was placed in a glass container having an inner diameter of 1 cm, and the degree of sedimentation of the pearl pigment was visually confirmed at 25 ° C. for 2 weeks, starting immediately after the preparation.
Evaluation criteria:
〇: It has not settled at all and is evenly dispersed.
X: A sedimentation of 0.5 cm or more was observed from the liquid surface.

In Examples 1 to 7, since the thread was not pulled, it was easy to take out with a coating tool. In addition, it was excellent in film forming property and stretchability, had a transparent feeling, and was excellent in dispersibility over time. In Comparative Example 1, the initial dispersibility was good, but the dispersibility over time was poor, and the pigment settled. In addition, a peculiar odor was felt. In Comparative Example 2 in which none of the compounds (1) to (8) was added, the pigment settled from the initial stage.

[Examples 8 to 14, Comparative Examples 3 to 4]
W / O creams were produced by the formulations shown in Table 2 with or without the compounds (1) to (8) obtained in Production Examples 1-8. Specifically, it is as follows.
Any of the compounds (1) to (8) was blended with squalane (manufactured by Kanto Chemical Co., Inc.) and heated at 100 ° C. for 30 minutes to dissolve, or the liquid was used as it was without blending. In the obtained liquid, at room temperature, KF-96A-10CS (dimethicone, manufactured by Shinetsu Silicone), KF-6017 (PEG-10 dimethicone, manufactured by Shinetsu Silicone) and KF-6028 (PEG-9 polydimethylsiloxyethyl dimethicone, Shinetsu). (Made of silicone) was added in sequence and mixed so as to be uniform to obtain a mixed solution A.
Separately, purified water (MilliQ water), 1,3-butylene glycol-P (abbreviated as BG, manufactured by KH Neochem), concentrated glycerin for cosmetics (manufactured by Sakamoto Pharmaceutical Co., Ltd.), phenoxyethanol-SP (phenoxyethanol, manufactured by Yokkaichi Chemical Co., Ltd.) and chloride. Sodium was mixed, and the mixture was uniformly mixed and dissolved to prepare a mixed solution B.
At room temperature, the mixture B was gradually added to the mixture A and stirred at a disper 2000 rpm for 5 minutes to emulsify to produce a W / O cream.
The feeling of use and emulsion stability (initial and 50 ° C. x 2 weeks) of the obtained W / O cream were evaluated. The evaluation method and evaluation criteria are as follows. The results are shown in Table 4.

<Emulsification stability>
Evaluation method: The emulsion stability of the W / O creams obtained in Examples 8 to 14 and Comparative Examples 3 to 4 was evaluated. Immediately after the preparation of the W / O cream was set as the initial stage, and the product was allowed to stand at 50 ° C. for 2 weeks was visually confirmed and evaluated according to the following criteria.
Evaluation criteria:
〇: Emulsified particle size does not change, no separation ×: Clearly separated <Usage>
Evaluation method: A usability test was conducted with 5 subjects.
Evaluation criteria:
⊚: The ductility and familiarity are particularly excellent.
〇: Excellent ductility and familiarity.
×: Poor ductility and familiarity.

In Examples 8 to 14, no undissolved substance remained, the ductility and familiarity were excellent, the feeling of use was moist, and the emulsified state was stably maintained. In Comparative Example 3, the oil content floated over time. Further, in Comparative Example 3, a peculiar odor was felt. Comparative Example 4 could not be emulsified from the initial stage.

[Examples 15 to 23, Comparative Examples 5 to 6]
Cleansing oils were produced by the formulations shown in Table 3 with or without the compounds (1) to (8) obtained in Production Examples 1-8. Specifically, it is as follows.
Mix any of compounds (1) to (8) in mineral oil K-230 (mineral oil, manufactured by Kaneda) and heat at 100 ° C for 30 minutes to dissolve, or the liquid as it is without blending. And said. In the obtained liquid, at room temperature, mineral oil K-230 (mineral oil, manufactured by Kaneda), M fine oil ISG-8M (PEG-8 glyceryl isostearate, manufactured by Miyoshi Oil & Fat) and concentrated glycerin for cosmetics (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) ) Was added sequentially and mixed so as to be uniform. Purified water (milli-Q water) was gradually added to the obtained mixed solution and mixed so as to be uniform to produce a cleansing oil.
Evaluate the initial condition, appearance (initial and 50 ° C x 2 weeks), degreasing (initial and 50 ° C x 2 weeks), and no dripping (initial and 50 ° C x 2 weeks) of the resulting cleansing oil. did. The evaluation method and evaluation criteria are as follows. The results are shown in Table 5.

<Oil removal (initial and 50 ° C x 2 weeks later)>
Evaluation method: The emulsification stability of cleansing oil was evaluated. Immediately after the preparation of the cleansing oil, the presence or absence of oil release after 2 weeks at 50 ° C. was visually confirmed.
Evaluation criteria:
〇: There is no oil separation and it is uniformly emulsified.
×: There is oil release.
<No dripping (initial and 50 ° C x 2 weeks later)>
Evaluation method: The dripping of cleansing oil was evaluated. The cleansing oil was stirred with a spatula, and the dripping of the cleansing oil when the container was tilted at 90 ° after 10 seconds was visually confirmed.
Evaluation criteria:
〇: Restores geliness and does not drip.
×: Loss of gel property and dripping.

In Examples 15 to 23, all of them had high transparency, the gel was soft and crumbled at the time of use, and were excellent in ductility and familiarity, but the gel state was quickly restored and no dripping occurred. In Comparative Example 5, although it became thick, dripping and a peculiar odor were felt. Comparative Example 6 was thick, but dripping.

[Examples 24 to 32, Comparative Examples 7 to 8]
Hair oil was produced by the formulation shown in Table 4 with or without the compounds (1) to (8) obtained in Production Examples 1 to 8. Specifically, it is as follows.
Mix any of compounds (1) to (8) in mineral oil K-230 (mineral oil, manufactured by Kaneda) and heat at 100 ° C for 30 minutes to dissolve, or the liquid as it is without blending. And said. In the obtained liquid, at room temperature, Marcazole R (isododecane, manufactured by Maruzen Petrochemical), Pearlream EX (hydrogenated polyisobutene, manufactured by NOF), LUSPLAN SR-DC5 (dimer linoleic acid dimer dilinoleil and PPG-3). -A product containing capril ether (manufactured by Nippon Fine Chemical Co., Ltd.) was added in sequence and mixed so as to be uniform. Purified water (milli-Q water) was gradually added to the obtained mixed solution and mixed so as to be uniform to produce hair oil.
The initial state, appearance (initial and 50 ° C. x 2 weeks), and no dripping (initial and 50 ° C. x 2 weeks) of the obtained hair oil were evaluated. The evaluation method and evaluation criteria are as follows. The results are shown in Table 6.

<Appearance (initial and 50 ° C x 2 weeks later)>
Evaluation method: The appearance was visually evaluated after 2 weeks at 50 ° C., starting immediately after the preparation of the hair oil.
Evaluation criteria:
〇: Uniform and highly transparent.
Δ: Transparency is lower than in the initial stage.
X: Non-uniform. Or remarkably turbid <no dripping (initial and 50 ° C x 2 weeks later)>
Evaluation method: The dripping of cleansing oil was evaluated. The cleansing oil was stirred with a spatula, and the dripping of the cleansing oil when the container was tilted at 90 ° after 10 seconds was visually confirmed.
Evaluation criteria:
〇: Restores geliness and does not drip.
×: Loss of gel property and dripping.

Examples 24 to 32 had a smooth feeling of use, and had good elongation and a smooth feel after application. In Comparative Example 7, unevenness occurred after 50 ° C. × 2 weeks, the uniformity was deteriorated, and a peculiar odor was felt. Comparative Example 8 was not thick and dripping.

The cosmetic of the present invention containing the thickener for cosmetics of the present invention is a cosmetic that can sufficiently exhibit performance such as excellent usability, excellent finished appearance such as transparency, and appropriate viscosity. It can be used as cosmetics, for example, basic cosmetics such as cleansing oil, massage oil, sunscreen, W / O cream, make-up cosmetics such as lip gloss, and hair care cosmetics such as hair oil.

Claims (5)

A cosmetic thickener containing the ether compound (A) represented by the general formula (1) or the general formula (2).

(In the general formula (1) and the general formula (2), R ¹ is a linear or branched linear or branched alkyl group, alkenyl group, or alkynyl group having 6 to 30 carbon atoms and is saturated or unsaturated, and R ² is. a linear alkylene group having 1 to 10 carbon atoms, R ³ is a straight-chain or branched alkyl group, alkenyl group or alkynyl group, a saturated or unsaturated 1 to 30 carbon atoms.) A cosmetic containing the cosmetic thickener according to claim 1. The cosmetic according to claim 2, which is a basic cosmetic. The cosmetic according to claim 2, which is a make-up cosmetic. The cosmetic according to claim 2, which is a hair care cosmetic.