JP2017046600A - Packaged citric acid-rich acidic beverage having reduced citric acid-derived foreign taste - Google Patents
Packaged citric acid-rich acidic beverage having reduced citric acid-derived foreign taste Download PDFInfo
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 title claims abstract description 779
- 235000013361 beverage Nutrition 0.000 title claims abstract description 186
- 230000002378 acidificating effect Effects 0.000 title claims abstract description 120
- 235000019640 taste Nutrition 0.000 title abstract description 32
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims abstract description 52
- 238000004519 manufacturing process Methods 0.000 claims abstract description 48
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229960003975 potassium Drugs 0.000 claims abstract description 23
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 23
- 239000011591 potassium Substances 0.000 claims abstract description 23
- DATAGRPVKZEWHA-YFKPBYRVSA-N N(5)-ethyl-L-glutamine Chemical compound CCNC(=O)CC[C@H]([NH3+])C([O-])=O DATAGRPVKZEWHA-YFKPBYRVSA-N 0.000 claims description 28
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 27
- 239000011734 sodium Substances 0.000 claims description 27
- 229910052708 sodium Inorganic materials 0.000 claims description 27
- 239000002253 acid Substances 0.000 claims description 19
- 159000000000 sodium salts Chemical class 0.000 claims description 16
- 229940026510 theanine Drugs 0.000 claims description 14
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 3
- 239000001508 potassium citrate Substances 0.000 abstract description 26
- 229960002635 potassium citrate Drugs 0.000 abstract description 23
- 235000011082 potassium citrates Nutrition 0.000 abstract description 23
- 239000000796 flavoring agent Substances 0.000 abstract description 15
- 235000019658 bitter taste Nutrition 0.000 abstract description 13
- 235000019634 flavors Nutrition 0.000 abstract description 6
- 230000000694 effects Effects 0.000 description 24
- 238000011156 evaluation Methods 0.000 description 22
- 238000002360 preparation method Methods 0.000 description 19
- 239000001509 sodium citrate Substances 0.000 description 13
- 235000019629 palatability Nutrition 0.000 description 11
- 230000001953 sensory effect Effects 0.000 description 11
- 239000002994 raw material Substances 0.000 description 10
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 10
- 235000011083 sodium citrates Nutrition 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 230000036541 health Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 235000014214 soft drink Nutrition 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 235000003599 food sweetener Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000003765 sweetening agent Substances 0.000 description 4
- -1 Potassium citrate salt Chemical class 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000035790 physiological processes and functions Effects 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 235000015870 tripotassium citrate Nutrition 0.000 description 3
- 235000019263 trisodium citrate Nutrition 0.000 description 3
- 229940038773 trisodium citrate Drugs 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 230000002929 anti-fatigue Effects 0.000 description 2
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical compound CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 230000035622 drinking Effects 0.000 description 2
- 235000013373 food additive Nutrition 0.000 description 2
- 239000002778 food additive Substances 0.000 description 2
- 235000015203 fruit juice Nutrition 0.000 description 2
- 235000013402 health food Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000015110 jellies Nutrition 0.000 description 2
- 239000008274 jelly Substances 0.000 description 2
- 235000020124 milk-based beverage Nutrition 0.000 description 2
- 239000002444 monopotassium citrate Substances 0.000 description 2
- 235000015861 monopotassium citrate Nutrition 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- WKZJASQVARUVAW-UHFFFAOYSA-M potassium;hydron;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [K+].OC(=O)CC(O)(C(O)=O)CC([O-])=O WKZJASQVARUVAW-UHFFFAOYSA-M 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229940109850 royal jelly Drugs 0.000 description 2
- 235000013616 tea Nutrition 0.000 description 2
- 239000000052 vinegar Substances 0.000 description 2
- 235000021419 vinegar Nutrition 0.000 description 2
- WQNHWIYLCRZRLR-UHFFFAOYSA-N 2-(3-hydroxy-2,5-dioxooxolan-3-yl)acetic acid Chemical compound OC(=O)CC1(O)CC(=O)OC1=O WQNHWIYLCRZRLR-UHFFFAOYSA-N 0.000 description 1
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 description 1
- 108010011485 Aspartame Proteins 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000951471 Citrus junos Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- LPHGQDQBBGAPDZ-UHFFFAOYSA-N Isocaffeine Natural products CN1C(=O)N(C)C(=O)C2=C1N(C)C=N2 LPHGQDQBBGAPDZ-UHFFFAOYSA-N 0.000 description 1
- HLCFGWHYROZGBI-JJKGCWMISA-M Potassium gluconate Chemical compound [K+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O HLCFGWHYROZGBI-JJKGCWMISA-M 0.000 description 1
- 239000001744 Sodium fumarate Substances 0.000 description 1
- 244000228451 Stevia rebaudiana Species 0.000 description 1
- 239000004376 Sucralose Substances 0.000 description 1
- 239000000619 acesulfame-K Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 239000000605 aspartame Substances 0.000 description 1
- 235000010357 aspartame Nutrition 0.000 description 1
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 1
- 229960003438 aspartame Drugs 0.000 description 1
- 229960001948 caffeine Drugs 0.000 description 1
- VJEONQKOZGKCAK-UHFFFAOYSA-N caffeine Natural products CN1C(=O)N(C)C(=O)C2=C1C=CN2C VJEONQKOZGKCAK-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 235000014171 carbonated beverage Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000013325 dietary fiber Nutrition 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- UZLGHNUASUZUOR-UHFFFAOYSA-L dipotassium;3-carboxy-3-hydroxypentanedioate Chemical compound [K+].[K+].OC(=O)CC(O)(C([O-])=O)CC([O-])=O UZLGHNUASUZUOR-UHFFFAOYSA-L 0.000 description 1
- WPUMTJGUQUYPIV-JIZZDEOASA-L disodium (S)-malate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)CC([O-])=O WPUMTJGUQUYPIV-JIZZDEOASA-L 0.000 description 1
- 239000002526 disodium citrate Substances 0.000 description 1
- 235000019262 disodium citrate Nutrition 0.000 description 1
- MSJMDZAOKORVFC-SEPHDYHBSA-L disodium fumarate Chemical compound [Na+].[Na+].[O-]C(=O)\C=C\C([O-])=O MSJMDZAOKORVFC-SEPHDYHBSA-L 0.000 description 1
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 235000015897 energy drink Nutrition 0.000 description 1
- 235000020710 ginseng extract Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 239000008123 high-intensity sweetener Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- HWPKGOGLCKPRLZ-UHFFFAOYSA-M monosodium citrate Chemical compound [Na+].OC(=O)CC(O)(C([O-])=O)CC(O)=O HWPKGOGLCKPRLZ-UHFFFAOYSA-M 0.000 description 1
- 239000002524 monosodium citrate Substances 0.000 description 1
- 235000018342 monosodium citrate Nutrition 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 235000013615 non-nutritive sweetener Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000004224 potassium gluconate Substances 0.000 description 1
- 235000013926 potassium gluconate Nutrition 0.000 description 1
- 229960003189 potassium gluconate Drugs 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 1
- 235000019265 sodium DL-malate Nutrition 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229940005573 sodium fumarate Drugs 0.000 description 1
- 235000019294 sodium fumarate Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000001394 sodium malate Substances 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000019408 sucralose Nutrition 0.000 description 1
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 description 1
- 230000004102 tricarboxylic acid cycle Effects 0.000 description 1
- 235000015192 vegetable juice Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Non-Alcoholic Beverages (AREA)
Abstract
Description
本発明は、高濃度のクエン酸を含む酸性飲料であるにも関わらず、クエン酸由来の異味が低減されて飲みやすく嗜好性が高い、容器詰めクエン酸高含有酸性飲料、及びその製造方法に関する。 The present invention relates to a container-packed citric acid-rich acid beverage that is easy to drink and has high palatability, and a method for producing the same, even though it is an acidic beverage containing a high concentration of citric acid. .
現代社会では、健常人であってもそのほとんどが日常的に「疲労」を感じているといわれ、その疲労回復のために様々な取り組みが提案されている。そのうち最も手軽な取り組みのひとつが栄養ドリンクなどの健康飲食品の摂取である。各種機能性素材を配合した健康飲食品が数多く販売されていて、消費者の人気を博している。 In modern society, even healthy people are said to feel “fatigue” on a daily basis, and various efforts have been proposed to recover from the fatigue. One of the simplest efforts is the intake of health food and drinks such as energy drinks. Many health foods and drinks containing various functional ingredients are on the market and are gaining popularity among consumers.
その疲労回復の機能を有する素材のひとつとして、クエン酸が知られている。クエン酸は柑橘系の果実などに多く含まれる有機酸であり、酸味料として多くの飲食品に用いられている物質である。このクエン酸はTCAサイクル中の代謝成分であり、疲労回復に効果があることが報告されている。また、クエン酸は、安全性が高いため多量に長期間摂取しても問題なく、更に安価であることから、疲労回復の効果を有する飲食品の原料として、利用価値が非常に高い素材である。 Citric acid is known as one of the materials having the function of recovering from fatigue. Citric acid is an organic acid that is abundant in citrus fruits and is a substance used in many foods and drinks as an acidulant. This citric acid is a metabolic component in the TCA cycle and has been reported to be effective in fatigue recovery. In addition, citric acid is a material that has a very high utility value as a raw material for foods and drinks having an effect of relieving fatigue because citric acid is safe and has no problem even if it is ingested in a large amount for a long period of time. .
このことから、従来より、このクエン酸を疲労回復のための飲食品や医薬部外品などに利用しようとする試みが数多くなされている。例えば、特許文献1には、カルボキシル基を2つ以上有する有機酸またはその塩類を有効成分として配合した疲労改善剤として、クエン酸を配合した液剤や錠剤などが開示されている。また、特許文献2には、所定濃度のショ糖とクエン酸とを配合した肉体疲労時用の内服液剤が開示されている。さらに特許文献3には所定濃度のクエン酸又はその塩の一種以上とロイヤルゼリーを配合した、疲労回復効果を目的とした内服液剤が開示されている。 For this reason, many attempts have been made to use this citric acid in foods and drinks and quasi drugs for recovery from fatigue. For example, Patent Document 1 discloses a liquid agent or tablet containing citric acid as a fatigue reducing agent containing an organic acid having two or more carboxyl groups or a salt thereof as an active ingredient. Patent Document 2 discloses an internal liquid preparation for physical fatigue, which contains a predetermined concentration of sucrose and citric acid. Further, Patent Document 3 discloses an internal solution for the purpose of fatigue recovery effect, in which one or more kinds of citric acid or a salt thereof at a predetermined concentration and royal jelly are blended.
しかし、そもそもクエン酸は酸味料であることから酸味が強く、また独特のえぐみを有していることから、クエン酸濃度をあげると、それらクエン酸由来の異味が目立ってしまい、嗜好性が低く飲みにくい飲料となってしまう。前記の特許文献2においては、甘味物質であるショ糖とクエン酸の配合比を特定の範囲にすることで該内服液剤の嗜好性をあげているが、あくまでも少用量の内服液剤の製造を前提としているため、一般の清涼飲料水には応用しにくい。また、特許文献1及び特許文献3に関しては、嗜好性の重要度が比較的低く、更に様々な呈味性を有する複数の機能性素材を配合した内服液剤とすることを前提としているためか、クエン酸由来の過剰な酸味などの異味の問題については記載がない。 However, since citric acid is a sour agent in the first place, it has a strong acidity and has a peculiar taste, so if you increase the concentration of citric acid, the off-flavor from citric acid becomes conspicuous. It becomes a low and hard to drink beverage. In the above-mentioned Patent Document 2, the preference of the internal solution is raised by setting the mixing ratio of sucrose and citric acid, which are sweet substances, to a specific range, but it is premised on the manufacture of a small dose internal solution. Therefore, it is difficult to apply to general soft drinks. In addition, with respect to Patent Document 1 and Patent Document 3, since the importance of palatability is relatively low, and because it is based on the premise that it is a liquid preparation containing a plurality of functional materials having various tastes, There is no description of off-flavor problems such as excessive acidity derived from citric acid.
その一方、嗜好性がより重視される、一般の清涼飲料水の分野においては、機能効果を期待できる位に多量のクエン酸を配合する場合、嗜好性を低減させるクエン酸に由来する異味、特に過剰な酸味を問題視しており、その対応策について従来より各種提案がなされている。例えば、特許文献4ではコハク酸ナトリウム又はフマル酸ナトリウムを、また特許文献5では炭酸水素ナトリウムを、それぞれクエン酸とともに清涼飲料水に特定量配合することで、クエン酸が高濃度に含まれていても、そのクエン酸に由来する酸味を緩和できることが開示されている。しかし、配合成分による飲料味覚への影響と共に、その効果はまだ満足できるものではなく、更なる改善が求められている。 On the other hand, in the field of general soft drinks where palatability is more important, when blending a large amount of citric acid to the extent that a functional effect can be expected, an off-flavor derived from citric acid that reduces palatability, especially Excessive acidity is regarded as a problem, and various proposals have been made for countermeasures. For example, in Patent Document 4, sodium succinate or sodium fumarate, and in Patent Document 5, sodium bicarbonate are mixed with citric acid in a specific amount, respectively, so that citric acid is contained in a high concentration. It is disclosed that the acidity derived from the citric acid can be alleviated. However, along with the influence on the beverage taste by the blended ingredients, the effect is not yet satisfactory, and further improvement is required.
他方、特許文献6には、クエン酸カリウムとコーヒー入り乳飲料を構成成分とする健康飲料の開示がある。該健康飲料は、カリウムのもつ健康機能を利用したものであるが、用いるクエン酸カリウムには独特の苦味があり、クエン酸カリウムだけでは摂取しにくいという問題があることから、このクエン酸カリウムをコーヒー入り乳飲料に配合することで苦味がマスキングされ、摂取しやすい健康飲料としたものである。 On the other hand, Patent Document 6 discloses a health drink comprising potassium citrate and a coffee-containing milk drink as constituent components. The health drink uses the health function of potassium, but the potassium citrate used has a unique bitter taste, and there is a problem that it is difficult to take with potassium citrate alone. By blending into a coffee-containing milk beverage, the bitterness is masked, making it a healthy beverage that is easy to consume.
本発明の課題は、高濃度のクエン酸を含む酸性飲料であるにも関わらず、そのクエン酸由来の異味が低減されて飲みやすい、容器詰めのクエン酸高含有酸性飲料、及びその製造方法を提供することにある。 An object of the present invention is to provide an acidic beverage containing a high amount of citric acid in a container and a method for producing the same, which is easy to drink even though it is an acidic beverage containing a high concentration of citric acid. It is to provide.
本発明者らは、上記課題を解決するべく、クエン酸高含有酸性飲料に配合する様々な素材を鋭意検討していたところ、意外にも、独特の苦味があって使用しにくいといわれているクエン酸のカリウム塩を、原料として特定量を添加、含有させることで、高濃度のクエン酸を含む酸性飲料であっても、そのクエン酸由来の異味が低減できると同時に、クエン酸カリウム塩の苦味も感じにくい、嗜好性の高い飲みやすい飲料が調製できることを見出し、本発明を完成するに至った。 In order to solve the above-mentioned problems, the present inventors have intensively studied various materials to be blended in a high-citric acid-containing acidic beverage, and surprisingly, it is said that it has a unique bitter taste and is difficult to use. By adding and containing a specific amount of potassium salt of citric acid as a raw material, even if it is an acidic beverage containing a high concentration of citric acid, the off-taste derived from the citric acid can be reduced, and at the same time, the potassium citrate salt The present inventors have found that it is possible to prepare a drink with high palatability that is difficult to feel bitterness, and have completed the present invention.
すなわち、本発明は、クエン酸濃度が0.4〜1.5重量%の容器詰めクエン酸含有酸性飲料において、クエン酸カリウム塩をクエン酸濃度に対するカリウム濃度の比が0.001〜0.37となるように添加することを特徴とする、クエン酸由来の異味が低減された容器詰めクエン酸高含有酸性飲料からなる。容器詰めクエン酸高含有酸性飲料の製造において、クエン酸カリウム塩を添加し、含有させることにより、クエン酸が高濃度に含まれていても、クエン酸由来の異味が低減されて、嗜好性が高く飲みやすい酸性飲料を提供することが可能になった。また、該組成のクエン酸含有酸性飲料とすることにより、クエン酸カリウム塩の苦味も感じにくく、更に、クエン酸カリウム塩自体は、クエン酸の塩であることから、香味的にも違和感のない、嗜好性の高いクエン酸含有酸性飲料を提供することができる。 That is, according to the present invention, in a packaged citric acid-containing acidic beverage having a citric acid concentration of 0.4 to 1.5% by weight, the ratio of potassium citrate salt to citric acid concentration is 0.001 to 0.37. It consists of a container-packed high-citric acid-containing acidic beverage with reduced off-taste derived from citric acid. In the production of container-packed citric acid-rich acidic beverages, by adding and containing potassium citrate, even if citric acid is contained at a high concentration, the off-taste derived from citric acid is reduced, and palatability is improved. It has become possible to provide acidic drinks that are high and easy to drink. In addition, by making the citric acid-containing acidic beverage of this composition, it is difficult to feel the bitter taste of potassium citrate salt. Furthermore, since the potassium citrate salt itself is a salt of citric acid, there is no sense of incongruity in flavor. A citric acid-containing acidic beverage with high palatability can be provided.
本発明の容器詰めクエン酸高含有酸性飲料において、容器詰めクエン酸含有酸性飲料のクエン酸濃度は、好ましくは、0.4〜0.8重量%とすることができる。 In the container-packed citric acid-rich acidic beverage of the present invention, the citric acid concentration of the container-packed citric acid-containing acidic beverage can be preferably 0.4 to 0.8% by weight.
また、本発明の容器詰めクエン酸高含有酸性飲料においては、クエン酸濃度に対するナトリウム濃度の比が0.012〜0.2となるように、クエン酸カリウム塩の添加に加え、ナトリウムを含有させることで、クエン酸高含有酸性飲料におけるクエン酸由来の異味の低減作用をより増大させることができる。その際、クエン酸ナトリウム塩を添加することでナトリウム濃度を調整できる。 In addition, in the container-packed citric acid-rich acidic beverage of the present invention, sodium is contained in addition to the addition of potassium citrate so that the ratio of sodium concentration to citric acid concentration is 0.012-0.2. Thereby, the reduction | decrease effect of the citric acid origin taste in a citric acid high content acidic drink can be increased more. At that time, the sodium concentration can be adjusted by adding sodium citrate.
更に、容器詰めクエン酸含有酸性飲料中のカリウム濃度に対するナトリウム濃度の比が、0.1〜31となるようにすることができる。 Furthermore, the ratio of the sodium concentration to the potassium concentration in the packed citric acid-containing acidic beverage can be 0.1 to 31.
本発明の容器詰めクエン酸高含有飲料は、テアニンを含有するクエン酸含有酸性飲料のような酸性飲料に対しても適用することができる。 The container-packed citric acid-rich beverage of the present invention can also be applied to an acidic beverage such as a citric acid-containing acidic beverage containing theanine.
本発明は、クエン酸濃度が0.4〜1.5重量%の容器詰めクエン酸含有酸性飲料の製造において、クエン酸含有酸性飲料中に、クエン酸カリウム塩をクエン酸濃度に対するカリウム濃度の比が0.001〜0.37となるように添加することを特徴とする、クエン酸由来の異味が低減された、容器詰めクエン酸高含有酸性飲料の製造方法の発明を包含する。該容器詰めクエン酸高含有酸性飲料の製造方法において、クエン酸含有酸性飲料のクエン酸濃度は、0.4〜0.8重量%であるように調整することができる。 In the production of a citric acid-containing acidic beverage having a citric acid concentration of 0.4 to 1.5% by weight, the ratio of the potassium concentration to the citric acid concentration of potassium citrate in the citric acid-containing acidic beverage The invention includes an invention of a method for producing a container-packed citric acid-rich acidic beverage with reduced off-taste derived from citric acid, which is added so as to be 0.001 to 0.37. In the method for producing a container-packed citric acid-rich acidic beverage, the citric acid concentration of the citric acid-containing acidic beverage can be adjusted to be 0.4 to 0.8% by weight.
本発明のクエン酸濃度が0.4〜1.5重量%の容器詰めクエン酸含有酸性飲料の製造方法において、クエン酸含有酸性飲料中に、クエン酸カリウム塩の添加に加え、ナトリウム塩、好ましくはクエン酸ナトリウム塩を添加することによってナトリウムを含有させることにより、クエン酸由来の異味の低減作用がより増大された容器詰めクエン酸高含有酸性飲料を製造することができる。ナトリウムは、クエン酸含有酸性飲料中のクエン酸濃度に対するナトリウム濃度の比が0.012〜0.2となるように含有させることができる。また、ナトリウムは、クエン酸含有酸性飲料中のカリウム濃度に対するナトリウム濃度の比が、0.1〜31になるように含有させることができる。 In the method for producing a containerized citric acid-containing acidic beverage having a citric acid concentration of 0.4 to 1.5% by weight of the present invention, in addition to the addition of potassium citrate salt, a sodium salt, preferably By adding sodium citrate, sodium citrate can be used to produce an acidic beverage containing a high amount of citric acid in a container in which the effect of reducing the taste derived from citric acid is further increased. Sodium can be contained so that the ratio of the sodium concentration to the citric acid concentration in the citric acid-containing acidic beverage is 0.012 to 0.2. Moreover, sodium can be contained so that the ratio of the sodium concentration with respect to the potassium concentration in a citric acid containing acidic drink may be 0.1-31.
本発明の容器詰めクエン酸含有酸性飲料の製造方法は、テアニンを含有するクエン酸含有酸性飲料の製造に適用することができる。 The method for producing a containerized citric acid-containing acidic beverage of the present invention can be applied to the production of a citric acid-containing acidic beverage containing theanine.
本発明は、クエン酸濃度が0.4〜1.5重量%の容器詰めクエン酸含有酸性飲料の製造において、クエン酸含有酸性飲料中に、クエン酸カリウム塩を添加することを特徴とする容器詰めクエン酸高含有酸性飲料のクエン酸由来の異味を低減する方法の発明を包含する。 In the production of a citric acid-containing acidic beverage having a citric acid concentration of 0.4 to 1.5% by weight, a container characterized by adding potassium citrate to the citric acid-containing acidic beverage The invention of the method of reducing the off-flavor derived from the citric acid of the filling citric acid high content acidic drink is included.
すなわち、具体的には本発明は、[1]クエン酸濃度が0.4〜1.5重量%の容器詰めクエン酸高含有酸性飲料において、クエン酸カリウム塩をクエン酸濃度に対するカリウム濃度の比が0.001〜0.37となるように添加することを特徴とする、クエン酸由来の異味が低減された、容器詰めクエン酸高含有酸性飲料や、[2]容器詰めクエン酸高含有酸性飲料のクエン酸濃度が、0.4〜0.8重量%であることを特徴とする、前記[1]に記載の容器詰めクエン酸高含有酸性飲料や、[3]容器詰めクエン酸高含有酸性飲料中のクエン酸濃度に対するナトリウム濃度の比が、0.012〜0.2であることを特徴とする、前記[1]又は[2]に記載の容器詰めクエン酸高含有酸性飲料や、[4]クエン酸カリウム塩に加え、クエン酸ナトリウム塩を添加することを特徴とする、前記[3]に記載の容器詰めクエン酸高含有酸性飲料や、[5]容器詰めクエン酸高含有酸性飲料中のカリウム濃度に対するナトリウム濃度の比が、0.1〜31であることを特徴とする、前記[1]〜[4]のいずれかに記載の容器詰めクエン酸高含有酸性飲料や、[6]容器詰めクエン酸高含有酸性飲料が、テアニンを含有するクエン酸含有酸性飲料であることを特徴とする、前記[1]〜[5]のいずれかに記載の容器詰めクエン酸高含有飲料からなる。 That is, the present invention specifically relates to [1] a container-packed high-citric acid-containing acidic beverage having a citric acid concentration of 0.4 to 1.5% by weight, wherein the potassium citrate salt is a ratio of the potassium concentration to the citric acid concentration. In a container-packed citric acid-rich acidic beverage with reduced off-taste derived from citric acid, and [2] container-packed citric acid-rich acid drink The citric acid concentration of the beverage is 0.4 to 0.8% by weight, characterized in that the container-packed citric acid-rich acidic beverage according to [1] above, and [3] the container-packed citric acid-rich content The ratio of sodium concentration to citric acid concentration in the acidic beverage is 0.012 to 0.2, the container-packed citric acid-rich acidic beverage according to [1] or [2], [4] In addition to potassium citrate salt, The ratio of the sodium concentration to the potassium concentration in the container-packed citric acid-rich acidic beverage according to [3] above, or [5] the container-packed citric acid-rich acid beverage, wherein the sodium salt is added. 0.1-31, the container-packed citric acid-rich acidic beverage according to any one of [1] to [4], and [6] the container-packed citric acid-rich acid beverage It is a citric acid-containing acidic beverage containing theanine, and consists of a container-packed citric acid-rich beverage according to any one of the above [1] to [5].
また、本発明は、[7]クエン酸濃度が0.4〜1.5重量%の容器詰めクエン酸高含有酸性飲料の製造において、クエン酸高含有酸性飲料中に、クエン酸カリウム塩をクエン酸濃度に対するカリウム濃度の比が0.001〜0.37となるように添加することを特徴とする、クエン酸由来の異味が低減された、容器詰めクエン酸高含有酸性飲料の製造方法や、[8]クエン酸高含有酸性飲料のクエン酸濃度が0.4〜0.8重量%であることを特徴とする、前記[7]に記載の容器詰めクエン酸高含有酸性飲料の製造方法や、[9]クエン酸濃度が0.4〜1.5重量%の容器詰めクエン酸高含有酸性飲料の製造方法において、クエン酸高含有酸性飲料中に、クエン酸カリウム塩の添加に加え、ナトリウム塩を添加することを特徴とする、前記[7]又は[8]に記載の容器詰めクエン酸高含有酸性飲料の製造方法や、[10]ナトリウム塩の添加が、クエン酸含有酸性飲料中のクエン酸濃度に対するナトリウム濃度の比が0.012〜0.2となるように添加するものであることを特徴とする、前記[9]に記載の容器詰めクエン酸高含有酸性飲料の製造方法や、[11]ナトリウム塩が、クエン酸ナトリウム塩であることを特徴とする、前記[9]又は[10]に記載の容器詰めクエン酸高含有飲料の製造方法や、[12]ナトリウム塩の添加が、クエン酸含有酸性飲料中のカリウム濃度に対するナトリウム濃度の比が、0.1〜31になるように添加するものであることを特徴とする、前記[9]〜[11]のいずれかに記載の容器詰めクエン酸高含有酸性飲料の製造方法や、[13]容器詰めクエン酸高含有酸性飲料の製造方法が、テアニンを含有するクエン酸高含有酸性飲料の製造方法であることを特徴とする、前記[8]〜[12]のいずれかに記載の容器詰めクエン酸高含有飲料の製造方法や、[14]クエン酸濃度が0.4〜1.5重量%の容器詰めクエン酸含有酸性飲料の製造において、クエン酸含有酸性飲料中に、クエン酸カリウム塩をクエン酸濃度に対するカリウム濃度の比が0.001〜0.37となるように添加することを特徴とする、容器詰めクエン酸高含有酸性飲料のクエン酸由来の異味を低減する方法からなる。 The present invention also provides [7] production of a container-packed high-citric acid-containing acidic beverage having a citric acid concentration of 0.4 to 1.5% by weight with citric acid-containing potassium beverage containing citric acid potassium salt. A method for producing a highly stuffed citric acid-containing acidic beverage with reduced off-taste derived from citric acid, wherein the ratio of potassium concentration to acid concentration is 0.001 to 0.37, [8] The method for producing a container-packed citric acid-rich acid beverage according to [7], wherein the citric acid concentration of the citric acid-rich acid beverage is 0.4 to 0.8% by weight, [9] In the method for producing a containerized high citric acid-containing acidic beverage having a citric acid concentration of 0.4 to 1.5% by weight, in addition to the addition of potassium citrate salt, sodium Characterized by adding salt, [7] The method for producing a container-packed citric acid-rich acidic beverage according to [7] or [8] and the addition of [10] sodium salt result in a ratio of sodium concentration to citric acid concentration in the citric acid-containing acidic beverage being 0. 0.012 to 0.2, the method for producing a container-packed citric acid-rich acidic beverage according to [9] above, or [11] sodium salt is citric acid. The method for producing a container-packed citric acid-rich beverage according to [9] or [10] above, wherein [12] potassium salt in the citric acid-containing acidic beverage is characterized by being a sodium salt The container-packed citric acid-rich acidic beverage according to any one of [9] to [11] above, wherein the sodium concentration is added such that the ratio of sodium concentration to concentration is 0.1 to 31 Manufacturing method [13] The method for producing a packed citric acid-rich acidic beverage, the method for producing a citric acid-rich acidic beverage containing theanine, according to any one of the above [8] to [12] In the method for producing a container-filled citric acid-containing beverage as described in [14] Citric acid-containing acidic beverage having a citric acid concentration of 0.4 to 1.5% by weight, Addition of potassium citrate salt such that the ratio of potassium concentration to citric acid concentration is 0.001 to 0.37, reducing the off-flavor of citric acid derived from a highly packed acidic beverage containing citric acid It consists of a method.
本発明によって、クエン酸を多く含む酸性飲料であっても、そのクエン酸由来の異味が低減されて、健康機能を有する上に嗜好性が高く飲みやすい容器詰めクエン酸高含有飲料を提供することができる。また本発明の容器詰めクエン酸高含有酸性飲料の製造方法は、クエン酸由来の異味が低減された、健康機能を有する上に嗜好性が高く飲みやすい容器詰めクエン酸高含有飲料を、その酸性飲料の味覚上への影響を極力回避した条件で、製造し、提供することを可能とする。 According to the present invention, even in an acidic beverage containing a large amount of citric acid, the off-taste derived from the citric acid is reduced, and it has a health function and provides a highly packed beverage with high citric acid content that is easy to drink. Can do. Further, the method for producing a container-packed citric acid-rich acidic beverage of the present invention is a method for producing a container-packed citric acid-rich beverage that has a healthy function and is easy to drink and has a healthy function with reduced taste derived from citric acid. It is possible to manufacture and provide the beverage under conditions that avoid the influence on the taste of the beverage as much as possible.
本発明は、クエン酸濃度が0.4〜1.5重量%の容器詰めクエン酸含有酸性飲料であって、クエン酸カリウム塩を、クエン酸濃度に対するカリウム濃度の比が0.001〜0.37となるように含有させることを特徴とする、クエン酸由来の異味が低減された容器詰めクエン酸高含有酸性飲料、及びその製造方法を提供することからなる。ここでクエン酸由来の異味とは、過剰な酸味やえぐみなど、クエン酸を高濃度で含んだ飲料を飲んだ時に感じる異味のことであり、該飲料の嗜好性を下げる原因となるものである。 The present invention is a containerized citric acid-containing acidic beverage having a citric acid concentration of 0.4 to 1.5% by weight, wherein the potassium citrate salt has a ratio of potassium concentration to citric acid concentration of 0.001 to 0.00. It consists of providing a container-packed high citric acid-containing acidic drink with reduced off-taste derived from citric acid, and a method for producing the same. Here, the citric acid-derived taste is a taste that is felt when drinking a beverage containing a high concentration of citric acid, such as excessive sourness and sashimi, and causes a decrease in the palatability of the beverage. .
<クエン酸>
本発明で使用するクエン酸は、クエン酸無水物又はクエン酸水和物のいずれを用いても良い。また、クエン酸の供給源として、クエン酸を豊富に含む、果汁など天然物や微生物の発酵物などを利用しても良いが、通常は酸味料として用いられる食品添加物グレードのクエン酸を使用する方が、品質が安定しており本発明の効果も明確になるので好ましい。クエン酸は、クエン酸カリウム塩やクエン酸ナトリウム塩に由来する分も含めて、酸性飲料中に、0.4〜1.5重量%、好ましくは0.4〜0.8重量%となるように調整される。クエン酸がそれより少ないと、クエン酸の持つ抗疲労効果等の効果を十分に発揮するためには大量の飲料を摂取する必要が出てしまい、またそれより多いと、過剰な酸味などの異味が強くなりすぎて、本発明の効果が十分に発揮できず嗜好性の高い飲料が製造できなくなる。容器詰め飲料一本あたりではクエン酸を2〜7.5g、好ましくは2〜5g含むように調整される。なお、本発明のクエン酸含有酸性飲料中の「クエン酸濃度」は、飲料中のクエン酸及びクエン酸塩を、「クエン酸」に換算して表示される。
<Citric acid>
Citric acid used in the present invention may be either citric acid anhydride or citric acid hydrate. As a source of citric acid, natural products such as fruit juices and fermented microorganisms containing abundant citric acid may be used, but food additive grade citric acid usually used as an acidulant is used. This is preferable because the quality is stable and the effect of the present invention becomes clear. Citric acid is 0.4 to 1.5% by weight, preferably 0.4 to 0.8% by weight, in the acidic beverage, including the portion derived from potassium citrate salt and sodium citrate salt. Adjusted to If citric acid is less than that, it will be necessary to ingest a large amount of beverage in order to fully demonstrate the anti-fatigue effect etc. of citric acid. Becomes too strong, and the effects of the present invention cannot be fully exerted, making it impossible to produce beverages with high palatability. It is adjusted to contain 2 to 7.5 g, preferably 2 to 5 g of citric acid per bottled beverage. The “citric acid concentration” in the citric acid-containing acidic beverage of the present invention is displayed by converting citric acid and citrate in the beverage into “citric acid”.
<クエン酸カリウム塩>
本発明では高クエン酸含有酸性飲料に対して、クエン酸カリウム塩を添加し、含有させることを特徴とする。クエン酸カリウム塩は独特の苦味を有しており、通常は飲料に使用した場合、その苦味のために飲料の嗜好性が低下してしまうが、クエン酸高含有酸性飲料に使用した場合には、意外にも、該飲料のクエン酸の酸味によって、クエン酸カリウム塩の苦味が目立たなくなるばかりか、逆にクエン酸の酸味などの異味を低減する効果を発揮することで、結果として嗜好性の高い飲料とすることができる。
<Potassium citrate salt>
The present invention is characterized in that potassium citrate is added and contained in a high citric acid-containing acidic beverage. Potassium citrate has a unique bitterness, and when used in beverages, the bitterness of the beverage decreases due to its bitterness, but when used in acidic citrate-rich beverages Surprisingly, the citric acid sourness of the beverage not only makes the bitter taste of potassium citrate inconspicuous, but conversely, by showing the effect of reducing the taste of citric acid sourness, etc. It can be a high beverage.
本発明においてクエン酸カリウム塩は、飲料中のクエン酸濃度に対するカリウム濃度の比として0.001〜0.37、好ましくは0.003〜0.3、より好ましくは0.02〜0.2になるように添加量を調整する。飲料中のカリウム濃度としては、好ましくは0.003〜0.32重量%、より好ましくは0.003〜0.15重量%、最も好ましくは0.02〜0.1重量%となるように調整する。クエン酸カリウム塩は、これらの濃度範囲より少ないとクエン酸由来の異味の低減効果が十分でなくなり、逆にそれより多いと、クエン酸カリウム塩の持つ独特の苦味が目立ってしまい、該飲料の嗜好性が落ちてしまうので好ましくない。なお、容器詰め飲料一本当たりでは、カリウム量として好ましくは15〜750mg、より好ましくは50〜500mgとなるように調整する。 In the present invention, potassium citrate is 0.001 to 0.37, preferably 0.003 to 0.3, more preferably 0.02 to 0.2 as a ratio of potassium concentration to citric acid concentration in the beverage. The addition amount is adjusted so that The potassium concentration in the beverage is preferably adjusted to 0.003 to 0.32% by weight, more preferably 0.003 to 0.15% by weight, and most preferably 0.02 to 0.1% by weight. To do. When the potassium citrate salt is less than these concentration ranges, the effect of reducing the off-flavor derived from citric acid is not sufficient, and conversely when it is more, the unique bitterness of potassium citrate salt becomes conspicuous, This is not preferable because the taste is reduced. In addition, per container-packed beverage, the amount of potassium is preferably adjusted to 15 to 750 mg, more preferably 50 to 500 mg.
使用するクエン酸カリウム塩はクエン酸一カリウム、クエン酸二カリウム又はクエン酸三カリウムのいずれも使用可能である。食品添加物としての製品が入手可能であるという点で、クエン酸一カリウム又はクエン酸三カリウムを使用することが好ましい。更に、クエン酸カリウム塩には水和物、無水物があるがいずれも使用できる。 As the potassium citrate used, any of monopotassium citrate, dipotassium citrate or tripotassium citrate can be used. It is preferred to use monopotassium citrate or tripotassium citrate in that products as food additives are available. Furthermore, although there exist a hydrate and an anhydride in a potassium citrate salt, all can be used.
<ナトリウム塩>
本発明では、クエン酸カリウム塩に加えて、ナトリウム塩を併用することでクエン酸由来の異味の低減効果をより増大させることができる。使用できるナトリウム塩としては、有機酸ナトリウム塩が好ましく、クエン酸ナトリウム塩、リンゴ酸ナトリウム塩、酒石酸ナトリウム塩などが例示できるが、香味バランスの面、及びクエン酸濃度を効率的にあげるという目的からはクエン酸ナトリウム塩を使用することが最も好ましい。
<Sodium salt>
In the present invention, in addition to the potassium citrate salt, a sodium salt can be used in combination to further increase the taste-reducing effect derived from citric acid. The sodium salt that can be used is preferably an organic acid sodium salt, and examples include sodium citrate, sodium malate, sodium tartrate, and the like, from the viewpoint of increasing the balance of flavor and the concentration of citric acid efficiently. Most preferably, sodium citrate is used.
なお、クエン酸ナトリウム塩についても、クエン酸一ナトリウム、クエン酸二ナトリウム又はクエン酸三ナトリウムのいずれもが使用可能であるが、カリウム塩と同様な理由により、クエン酸三ナトリウムを使用することが好ましい。また、クエン酸ナトリウム塩についても、無水物、水和物いずれも使用できる。 As for sodium citrate, any of monosodium citrate, disodium citrate or trisodium citrate can be used, but for the same reason as potassium salt, trisodium citrate may be used. preferable. In addition, regarding sodium citrate, both anhydrides and hydrates can be used.
飲料中のナトリウム濃度は、クエン酸濃度に対するナトリウム濃度の比が、好ましくは0.012〜0.2、より好ましくは、0.04〜0.1になるように調整する。また、飲料中のナトリウム濃度としては好ましくは0.007〜0.12重量%、より好ましくは、0.01〜0.1重量%とする。ナトリウム濃度がこれらの好ましい範囲にあるとき、クエン酸由来の異味の低減効果がより明確に発揮される。なお、容器詰め飲料一本当たりのナトリウム量は好ましくは、35〜600mg、より好ましくは50〜500mgである。 The sodium concentration in the beverage is adjusted so that the ratio of the sodium concentration to the citric acid concentration is preferably 0.012 to 0.2, more preferably 0.04 to 0.1. The sodium concentration in the beverage is preferably 0.007 to 0.12% by weight, more preferably 0.01 to 0.1% by weight. When the sodium concentration is in these preferable ranges, the effect of reducing the taste of citric acid is more clearly exhibited. In addition, the amount of sodium per container-packed beverage is preferably 35 to 600 mg, more preferably 50 to 500 mg.
更に、飲料に添加、含有させるクエン酸カリウム塩に対するナトリウムの比率が一定以上になると、ナトリウムイオンに由来する、飲用時の“ぬめり感”が強くなる一方、逆に一定以下になると、今度はクエン酸カリウム塩由来の苦味が感じられて好ましくない。従って、該飲料中のカリウム濃度に対するナトリウム濃度が好ましくは0.1〜31、より好ましくは、0.12〜12、最も好ましくは、0.15〜10になるように調整する。 Furthermore, when the ratio of sodium to the potassium citrate salt added to and contained in the beverage exceeds a certain level, the “smoothness” at the time of drinking, which is derived from sodium ions, becomes stronger. The bitterness derived from an acid potassium salt is felt and is not preferable. Therefore, the sodium concentration with respect to the potassium concentration in the beverage is preferably adjusted to 0.1 to 31, more preferably 0.12 to 12, and most preferably 0.15 to 10.
<酸性飲料>
本発明の高クエン酸含有酸性飲料は、pHが1.5〜6.0、好ましくは2.0〜5.0より好ましくは2.5〜4.6の酸性をしめす清涼飲料水である。クエン酸の他にも、酸性物質を含有させることは可能ではあるが、クエン酸の抗疲労効果などの効果をシャープに発揮させるため及び飲料の香味設計を容易にするためには、クエン酸を実質的に唯一の酸性物質とすることが好ましい。ここで実質的に唯一とは、他の酸性物質を該飲料中に0.01重量%以上含有させないことをいう。また、同様の理由から、飲料中には果実酢や穀物酢を含有しないことが望ましい。
<Acid drink>
The high-citric acid-containing acidic beverage of the present invention is a soft drink that has an acidity of pH 1.5 to 6.0, preferably 2.0 to 5.0, more preferably 2.5 to 4.6. In addition to citric acid, it is possible to contain an acidic substance, but citric acid is used to sharpen the anti-fatigue effect of citric acid and to facilitate the flavor design of beverages. It is preferred that it is substantially the only acidic substance. Here, “substantially only” means that no other acidic substance is contained in the beverage in an amount of 0.01% by weight or more. For the same reason, it is desirable that the beverage does not contain fruit vinegar or grain vinegar.
該飲料は、クエン酸の摂取量の面から、小容量の栄養ドリンクタイプのものよりも、200ml以上、好ましくは350ml以上の容量の通常の清涼飲料水が好ましい。更に酸性であればよいので、炭酸ガスを付与した、いわゆる炭酸飲料であってもよい。一方、酸性であっても、半固形タイプのゲル化した飲料、ゼリータイプの飲料は本発明には含まれない。すなわち、本発明の容器詰めクエン酸高含有飲料は、ゼリー強度が3.5×103N/m2(20℃)以下の飲料である。 The beverage is preferably a normal soft drink with a capacity of 200 ml or more, preferably 350 ml or more, rather than a small-volume nutrition drink type from the viewpoint of the intake of citric acid. Furthermore, since what is necessary is just acidic, what is called a carbonated drink which provided the carbon dioxide gas may be sufficient. On the other hand, even if it is acidic, the semi-solid type gelled beverage and the jelly type beverage are not included in the present invention. That is, the container-packed citric acid-rich beverage of the present invention is a beverage having a jelly strength of 3.5 × 10 3 N / m 2 (20 ° C.) or less.
本発明の飲料の原料としては、各種生薬類、ビタミン類、アミノ酸類、カフェイン、ロイヤルゼリー、高麗ニンジンエキス、ポリフェノール類、食物繊維などの生理機能が期待できる各種素材を、本発明の効果が発揮できる範囲であれば添加できる。また、果汁や野菜汁、更には茶抽出液なども添加できる。 As the raw material of the beverage of the present invention, various raw materials that can be expected to have physiological functions such as various herbal medicines, vitamins, amino acids, caffeine, royal jelly, ginseng extract, polyphenols, dietary fiber, etc. It can be added as long as it can be exhibited. In addition, fruit juice, vegetable juice, and tea extract can be added.
クエン酸高含有酸性飲料は、クエン酸の健康機能を有する嗜好性酸性飲料として提供することができる。また、該飲料に、更に別の健康機能成分を加えて、複数の健康機能を有する嗜好性酸性飲料として、提供することもできる。該健康機能(生理機能)を期待できる成分として、テアニンを挙げることができる。テアニンは、茶葉に多く含まれるアミノ酸の一種であり、心身のリラックス効果などの生理機能効果が期待できる。更に、テアニンは、本発明の効果である、クエン酸高含有酸性飲料の、クエン酸由来の異味の低減効果をも併せ持つ。テアニンは、該飲料に0.001〜0.5重量%の範囲、該飲料のクエン酸濃度に対する比で3〜400、好ましくは3〜200の範囲で添加、含有させることにより、本発明のクエン酸カリウム塩の効果、及びクエン酸カリウム塩とナトリウム塩の併用効果を更に強化することができ、より高い健康機能及び嗜好性の酸性飲料を提供することができる。 A citric acid-rich acidic beverage can be provided as a palatable acidic beverage having a citric acid health function. Moreover, another health function component can be added to this drink, and it can also provide as a favorite acidic drink which has a some health function. An example of a component that can be expected to have the health function (physiological function) is theanine. Theanine is a kind of amino acid that is abundant in tea leaves and can be expected to have physiological function effects such as a mental and physical relaxation effect. Furthermore, theanine also has the effect of reducing the off-flavor of citric acid in the citric acid-rich acidic beverage, which is the effect of the present invention. Theanine is added to and contained in the beverage in the range of 0.001 to 0.5% by weight, and the ratio to the citric acid concentration of the beverage in the range of 3 to 400, preferably 3 to 200. The effect of the potassium acid salt and the combined effect of the potassium citrate salt and the sodium salt can be further enhanced, and an acidic beverage with higher health function and palatability can be provided.
本発明のクエン酸高含有酸性飲料においては、他に、通常の容器詰め酸性飲料に使用するような甘味料、香料、着色料などを用いることができる。使用する香料としては、クエン酸の香味との相性の点で、レモン、グレープフルーツ、ゆず、オレンジなどの柑橘系香料が好ましい。 In addition to the citric acid-rich acidic beverage of the present invention, sweeteners, fragrances, coloring agents, and the like that are used in ordinary container-packed acidic beverages can be used. As the fragrance used, citrus fragrances such as lemon, grapefruit, yuzu and orange are preferable from the viewpoint of compatibility with the flavor of citric acid.
また甘味料は、果糖ブドウ糖液糖やショ糖などの通常の甘味料のほか、アセスルファムK、スクラロース、アスパルテーム、ステビアなどの高甘味度甘味料を使用することができる。高甘味度甘味料を使用した、固形分濃度が比較的低い、例えば、0〜5°Bxの飲料の場合には、クエン酸由来の異味をより感じやすくなるので、クエン酸カリウム塩及びナトリウム塩の添加、含有量を最適条件の範囲にするほか、上記テアニンをも併用して、クエン酸由来の異味の低減効果を高めることが重要である。 In addition to normal sweeteners such as fructose, glucose liquid sugar and sucrose, high-sweetness sweeteners such as acesulfame K, sucralose, aspartame, and stevia can be used as the sweetener. In the case of a beverage having a relatively low solid content, for example, 0 to 5 ° Bx, using a high-intensity sweetener, it becomes easier to feel the taste of citric acid, so potassium citrate and sodium salts It is important to increase the effect of reducing the taste derived from citric acid by using the theanine in addition to making the addition and content within the optimum range.
<容器詰め飲料>
本発明のクエン酸含有酸性飲料は、容器詰めしたクエン酸高含有酸性飲料として調製することができる。原料調合後、長期保存のために必要な加熱殺菌を行った上で、常法に従い、PETボトルや缶などの容器に充填して、長期保存が可能である容器詰め飲料にできる。本発明の容器詰めクエン酸高含有酸性飲料は、賞味期間内は、本発明の効果が持続して過剰な酸味などの異味が低減されているほか、香味の変化も少なく、また外観の面でも沈殿や濁りが発生せず、安定していることから、長期保存が可能な容器詰め飲料としても有用である。
<Contained beverages>
The citric acid-containing acidic beverage of the present invention can be prepared as a highly citric acid-containing acidic beverage packed in a container. After the raw material preparation, after heat sterilization necessary for long-term storage, it is filled into a container such as a PET bottle or a can according to a conventional method, and can be made into a container-packed beverage that can be stored for a long time. In the packed citric acid-rich acidic beverage of the present invention, during the shelf life, the effects of the present invention are maintained and the off-flavors such as excessive sourness are reduced. Since precipitation and turbidity do not occur and it is stable, it is also useful as a container-packed beverage that can be stored for a long time.
<容器詰め飲料の製造>
本発明の容器詰めクエン酸高含有飲料の製造は、クエン酸含有飲料原料溶液に、所定量のクエン酸カリウム塩、或いは、クエン酸カリウム塩及びナトリウム塩を添加し、クエン酸含有酸性飲料中のクエン酸濃度を、0.4〜1.5重量%の原料溶液を調製し、該原料溶液を所定の製造条件で処理した後、容器詰めすることによって製造することができる。該クエン酸高含有飲料の製造は、本願発明で特定する、所定の原料の配合の点を除いて、その製造方法において、特に変わるところはない。
<Manufacture of container-packed beverages>
The production of the container-packed citric acid-rich beverage of the present invention is carried out by adding a predetermined amount of potassium citrate salt or potassium citrate salt and sodium salt to the citric acid-containing beverage raw material solution, It can be manufactured by preparing a raw material solution having a citric acid concentration of 0.4 to 1.5% by weight, treating the raw material solution under predetermined manufacturing conditions, and then filling the container. The production of the beverage with a high citric acid content is not particularly changed in its production method except for the point of blending the predetermined raw materials specified in the present invention.
以下、実施例を挙げて本発明を更に具体的に説明するが、本発明はこれらの実施例に限定されるものではない。 EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated further more concretely, this invention is not limited to these Examples.
<容器詰めクエン酸高含有酸性飲料の調製例1>
表1に示す配合割合で原料をイオン交換水に添加して、合計1kgのクエン酸高含有酸性飲料調合液を得た。得られた調合液を飲料試作用のガラス瓶に充填した後、パストライザーで殺菌し、容器詰めクエン酸高含有酸性飲料を得た。これら飲料の固形分濃度は、0.6°BXであった。なお、全ての調製例において、クエン酸は無水物、クエン酸三カリウムは1水和物、クエン酸三ナトリウムは2水和物を用いた。
<Preparation example 1 of container-packed citric acid-rich acid beverage>
The raw materials were added to ion-exchanged water at the blending ratio shown in Table 1 to obtain a total citric acid-containing acidic beverage preparation liquid of 1 kg. After filling the obtained preparation liquid in the glass bottle for drink trial manufacture, it sterilized with the pasteurizer and obtained the container-packed citric acid high content acidic drink. The solid content concentration of these beverages was 0.6 ° BX. In all the preparation examples, citric acid was anhydrous, tripotassium citrate was monohydrate, and trisodium citrate was dihydrate.
<官能評価>
訓練を受けたパネリスト7人を選定し、これらのパネリストに調製した試験飲料を提
示して、「クエン酸由来の異味」について評価した。評価は表2に示す評価基準を用い、各自の結果をパネリスト間で協議して最終的な評価結果とした。
<Sensory evaluation>
Seven trained panelists were selected and the test drinks prepared were presented to these panelists and evaluated for “taste derived from citric acid”. The evaluation used the evaluation criteria shown in Table 2, and the results of each discussion were discussed between panelists to obtain the final evaluation results.
試験例1の飲料を対照に、試験例2の飲料を評価したところ、結果は「△」であった。すなわち、クエン酸のみ配合された試験例1の飲料に比べて、クエン酸由来の過剰な酸味などの異味が低減できていた。またクエン酸カリウムの由来の苦味はほとんど感じず、飲みやすい飲料であった。クエン酸カリウムを添加することで、クエン酸由来の異味が低減した飲料が調製できた。 When the beverage of Test Example 2 was evaluated using the beverage of Test Example 1 as a control, the result was “Δ”. That is, as compared with the beverage of Test Example 1 containing only citric acid, it was possible to reduce off-flavors such as excessive acidity derived from citric acid. Moreover, the bitterness derived from potassium citrate was hardly felt, and it was a drink that was easy to drink. By adding potassium citrate, a beverage with a reduced taste derived from citric acid could be prepared.
<容器詰めクエン酸高含有酸性飲料の調製例2>
配合割合を表3に変えた以外は調製例1と同様にして、クエン酸カリウム塩の濃度を変えた容器詰めクエン酸高含有酸性飲料を得た。
<Preparation Example 2 for Container-Packed Citric Acid High-Contained Acidic Beverage>
Except having changed the mixture ratio into Table 3, it carried out similarly to the preparation example 1, and obtained the container-packed citric acid high content acidic drink which changed the density | concentration of the potassium citrate salt.
<官能評価>
7人の選抜パネリストにより、前記の「クエン酸由来の異味」の評価に加えて、「ナトリウム由来の異味」の評価と「総合(嗜好性)評価」をおこなった。後二者の評価基準を表4及び表5に示す。いずれも絶対評価でおこなった。特に、総合(嗜好性)評価の結果を重視し、△以上の評価で本発明の効果が発揮できていると判断した。
<Sensory evaluation>
In addition to the above-mentioned evaluation of “taste derived from citric acid”, evaluation of “taste derived from sodium” and “total (taste) evaluation” were performed by seven selected panelists. The evaluation criteria for the latter two are shown in Tables 4 and 5. All were performed by absolute evaluation. In particular, the results of comprehensive (preference) evaluation were emphasized, and it was determined that the effect of the present invention could be exhibited with an evaluation of Δ or more.
結果を表6に示す。クエン酸カリウムを、クエン酸濃度に対するカリウム濃度の比が
0.001〜0.37になるように添加した試験例の飲料はクエン酸由来の異味が低減されて、嗜好性が高い飲料であった。
The results are shown in Table 6. The beverage of the test example in which potassium citrate was added so that the ratio of the potassium concentration to the citric acid concentration was 0.001 to 0.37 was a beverage having high palatability and reduced taste of citric acid. .
<容器詰めクエン酸高含有酸性飲料の調製例3>
配合割合を表7に変えた以外は調製例1と同様にして、飲料中のクエン酸濃度を変えた容器詰めクエン酸高含有酸性飲料を得た。これらの飲料についても同様に官能評価をおこなった。
<Preparation example 3 of container-packed citric acid-rich acidic beverage>
Except having changed the mixture ratio into Table 7, it carried out similarly to the preparation example 1, and obtained the container-packed citric acid high content acidic drink which changed the citric acid density | concentration in a drink. The sensory evaluation was similarly performed about these drinks.
官能評価結果を表8に示す。クエン酸の濃度を変えても、クエン酸カリウムとクエン酸ナトリウムを併用した試験例11及び試験例13の飲料は、クエン酸由来の異味が低減されて、非常に飲みやすい、嗜好性の高い飲料であった。 The sensory evaluation results are shown in Table 8. Even if the concentration of citric acid is changed, the beverages of Test Example 11 and Test Example 13 in which potassium citrate and sodium citrate are used in combination have a reduced taste of citric acid and are very easy to drink. Met.
<容器詰めクエン酸高含有酸性飲料の調製例4>
配合割合を表9に変えた以外は調製例1と同様にして、カリウム塩の種類を変えた容器詰めクエン酸高含有酸性飲料を得た。これらの飲料についても同様に官能評価をおこなった。
<Preparation example 4 of container-packed citric acid-rich acid beverage>
Except having changed the mixture ratio into Table 9, it carried out similarly to the preparation example 1, and obtained the container-packed citric acid high content acidic drink which changed the kind of potassium salt. The sensory evaluation was similarly performed about these drinks.
官能評価結果を表10に示す。クエン酸カリウム以外のカリウム塩を使用したクエン酸高含有酸性飲料は、クエン酸カリウムを使用した該飲料に比べてクエン酸由来の異味、特に酸味の低減度合いがやや低かった。また、塩化カリウム及びグルコン酸カリウムの香味が影響して総合的な嗜好性評価は低かった。 The sensory evaluation results are shown in Table 10. The citric acid-rich acidic beverage using a potassium salt other than potassium citrate had a slightly lower degree of reduction in off-taste derived from citric acid, particularly acidity, compared to the beverage using potassium citrate. In addition, the overall taste evaluation was low due to the influence of the flavors of potassium chloride and potassium gluconate.
<容器詰めクエン酸高含有酸性飲料の調製例5>
配合割合を表11に変えた以外は調製例1と同様にして、クエン酸ナトリウム塩の濃度を変えた容器詰めクエン酸高含有酸性飲料を得た。これらの飲料についても同様に官能評価をおこなった。
<Preparation Example 5 of Container-Packed Citric Acid High Content Acidic Beverage>
Except having changed the mixture ratio into Table 11, it carried out similarly to the preparation example 1, and obtained the container-packed citric acid high content acidic drink which changed the density | concentration of the sodium citrate salt. The sensory evaluation was similarly performed about these drinks.
官能評価結果を表12に示す。クエン酸カリウム塩の添加に加え、ナトリウム塩を添加することにより、更なるクエン酸由来の異味の低減効果が確認できた。 The sensory evaluation results are shown in Table 12. By adding sodium salt in addition to addition of potassium citrate salt, a further effect of reducing the taste of citric acid was confirmed.
<容器詰めクエン酸高含有酸性飲料の調製例6>
配合割合を表13に変えた以外は調製例1と同様にして、クエン酸カリウム塩とクエン酸ナトリウム塩の配合割合を変えた容器詰めクエン酸高含有酸性飲料を得た。これらの飲料についても同様に官能評価をおこなった。
<Preparation Example 6 of Container-Packed Citric Acid High Content Acidic Beverage>
Except having changed the mixture ratio into Table 13, it carried out similarly to the preparation example 1, and obtained the container-packed citric acid high content acidic drink which changed the mixture ratio of potassium citrate salt and sodium citrate salt. The sensory evaluation was similarly performed about these drinks.
官能評価結果を表14に示す。クエン酸カリウムとクエン酸ナトリウムを、カリウム濃度に対するナトリウム濃度比が一定範囲におさまるように調整して添加することでクエン酸由来の異味が低減されている上に、クエン酸カリウムやナトリウム由来の異味も感じにくく、総合的に嗜好性が高い飲料となった。 The sensory evaluation results are shown in Table 14. Potassium citrate and sodium citrate are added so that the ratio of sodium concentration to potassium concentration is kept within a certain range. It was a soft drink with a high overall taste.
<容器詰めクエン酸高含有酸性飲料の調製例7>
配合割合を表15に変えた以外は調製例1と同様にして、更にテアニンを添加した容器詰めクエン酸高含有酸性飲料を得た。この飲料の固形物濃度は0.4〜0.5°Bxであった。
<Preparation Example 7 of Container-Packed Citric Acid High Content Acidic Beverage>
Except having changed the mixture ratio into Table 15, it carried out similarly to the preparation example 1, and obtained the container stuffing citric acid high content acidic drink which added theanine further. The solids concentration of this beverage was 0.4 to 0.5 ° Bx.
これらの飲料を官能評価したところ、クエン酸カリウム塩とクエン酸ナトリウム塩を併用した上に、更にテアニンを添加した試験例の飲料、特に試験例36の飲料は、テアニン無添加の試験例34の飲料に比べて、クエン酸由来の異味の低減効果がより顕著であった。 When these beverages were subjected to sensory evaluation, the beverage of the test example in which theanine was further added to the combination of potassium citrate and sodium citrate, in particular the beverage of Test Example 36, was the test example 34 with no theanine added. Compared to beverages, the effect of reducing the taste derived from citric acid was more remarkable.
本発明によって、クエン酸を多く含む酸性飲料であっても、そのクエン酸由来の異味が低減されて、健康機能を有する嗜好性の高い飲みやすい容器詰めクエン酸高含有飲料を提供することができる。また本発明の容器詰めクエン酸高含有酸性飲料の製造方法は、クエン酸由来の異味が低減された、健康機能を有する上に嗜好性が高く飲みやすい容器詰めクエン酸高含有飲料を、その酸性飲料の味覚上への影響を極力回避した条件で、製造し、提供することを可能とする。
According to the present invention, even if it is an acidic beverage containing a lot of citric acid, the off-taste derived from the citric acid is reduced, and a highly packed beverage with a high taste and easy to drink can be provided. . Further, the method for producing a container-packed citric acid-rich acidic beverage of the present invention is a method for producing a container-packed citric acid-rich beverage that has a healthy function and is easy to drink and has a healthy function with reduced taste derived from citric acid. It is possible to manufacture and provide the beverage under conditions that avoid the influence on the taste of the beverage as much as possible.
Claims (14)
In the production of a citric acid-containing acidic beverage having a citric acid concentration of 0.4 to 1.5% by weight, the ratio of the potassium concentration to the citric acid concentration is 0.001 in the citric acid-containing acidic beverage. A method for reducing the off-taste derived from citric acid in a container-packed high-citric acid-containing acidic beverage, characterized by adding to 0.37.
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JP7595800B1 (en) | 2023-07-31 | 2024-12-06 | ハルナプロデュース株式会社 | Acidity suppressant, its use as an additive or raw material |
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