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JP2013176886A - In-mold foam molding method - Google Patents

In-mold foam molding method Download PDF

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JP2013176886A
JP2013176886A JP2012041814A JP2012041814A JP2013176886A JP 2013176886 A JP2013176886 A JP 2013176886A JP 2012041814 A JP2012041814 A JP 2012041814A JP 2012041814 A JP2012041814 A JP 2012041814A JP 2013176886 A JP2013176886 A JP 2013176886A
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mold
steam
heating step
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Hidenori Nagasawa
英紀 永澤
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SEKISUI KASEIHIN SAKURA KK
Sekisui Kasei Co Ltd
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SEKISUI KASEIHIN SAKURA KK
Sekisui Plastics Co Ltd
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Abstract

【課題】型内発泡成形時の使用蒸気量を従来技術よりも削減でき、同等の品質を備えた熱可塑性樹脂発泡成形体を低コストで製造可能な方法の提供。
【解決手段】蒸気が流通可能な第1の型2と第2の型3とを合わせ、それぞれの型間に所望形状のキャビティ9を有するとともに、それぞれの型に、蒸気弁12,17を開いた時に該型に蒸気が供給される蒸気供給管路とドレン弁13,18を開いた時に該型内から流体を排出するドレン管路とが設けられた成形型の該キャビティ9内に、熱可塑性樹脂予備発泡粒子を充填した後、成形型加熱工程、一方加熱工程、逆一方加熱工程、両面加熱工程、保熱工程を順次行って発泡樹脂成形体を得る際に、逆一方加熱工程を、第1の型側と第2の型側の両方のドレン弁13,18を閉じた状態で行うことを特徴とする型内発泡成形方法。
【選択図】図1
An object of the present invention is to provide a method that can reduce the amount of steam used in foam molding in a mold compared to the prior art and that can produce a thermoplastic resin foam molded article having equivalent quality at low cost.
A first mold 2 and a second mold 3 through which steam can flow are combined, a cavity 9 having a desired shape is provided between the molds, and steam valves 12 and 17 are opened in the respective molds. In the cavity 9 of the mold provided with a steam supply line through which steam is supplied to the mold and a drain line for discharging fluid from the mold when the drain valves 13 and 18 are opened. After filling the plastic resin pre-expanded particles, when performing a mold heating step, one heating step, reverse one heating step, double-side heating step, heat retention step in order to obtain a foamed resin molded body, the reverse one heating step, An in-mold foam molding method, which is performed in a state where the drain valves 13 and 18 on both the first mold side and the second mold side are closed.
[Selection] Figure 1

Description

本発明は、ポリスチレン系樹脂発泡成形体などの熱可塑性樹脂発泡成形体を型内発泡成形によって製造する型内発泡成形方法に関し、特に、加熱媒体として使用する蒸気の使用量を従来方法よりも低減可能な型内発泡成形方法に関する。   The present invention relates to an in-mold foam molding method for producing a thermoplastic resin foam molded body such as a polystyrene-based resin foam molded body by in-mold foam molding, and in particular, reduces the amount of steam used as a heating medium compared to conventional methods. The present invention relates to a possible in-mold foam molding method.

従来、ポリスチレン系樹脂発泡成形体などの熱可塑性樹脂発泡成形体を型内発泡成形によって製造する型内発泡成形方法としては、例えば、特許文献1〜3に開示された技術が提案されている。   Conventionally, as an in-mold foam molding method for producing a thermoplastic resin foam molded article such as a polystyrene-based resin foam molded article by in-mold foam molding, for example, techniques disclosed in Patent Documents 1 to 3 have been proposed.

特許文献1には、型閉めされた移動金型と固定金型との間に形成されたキャビティ内に発泡樹脂の予備発泡粒を充填し、移動金型及び固定金型それぞれに高温蒸気を通して金型加熱を行い、金型加熱の完了後キャビティ内において予備発泡粒間を高温蒸気が高圧で通流するように0.8〜1.0kg/cmの蒸気圧にて一方の金型から他方の金型に向かって高温蒸気を所定時間通流させて、前記予備発泡粒を急速に発泡成形させる通流加熱を行い、然る後、両金型の蒸気出口を閉じ、0.4〜0.5kg/cmの蒸気圧にてキャビティ内の発泡成形体の表面を焼き上げる両面加熱を行う事を特徴とする発泡樹脂の発泡成形方法が開示されている。 In Patent Document 1, pre-foamed particles of foamed resin are filled in a cavity formed between a closed moving mold and a stationary mold, and high temperature steam is passed through each of the moving mold and the stationary mold. After the mold heating is completed, the mold is heated from one mold to the other at a vapor pressure of 0.8 to 1.0 kg / cm 2 so that high-temperature steam flows at high pressure between the pre-foamed grains in the cavity. High-temperature steam is passed through the molds for a predetermined time to carry out flow heating for rapidly foaming the pre-foamed grains, and then the steam outlets of both molds are closed, and 0.4-0 A foamed resin foam molding method is disclosed in which double-sided heating is performed to bake the surface of the foam molded body in the cavity at a vapor pressure of 0.5 kg / cm 2 .

特許文献2には、成形金型内のキャビティに発泡性の合成樹脂粒子を充填した後、そのキャビティ内に金型蒸気室から蒸気を供給して樹脂粒子を発泡させ、この各発泡粒子同士を融着させることにより発泡成形品を得る方法で、かつ、その加熱工程が、金型蒸気室への蒸気供給系に設けたコントロール弁の制御により、少なくとも、金型加熱工程、キャビティ内の樹脂粒子間に存在する空気を蒸気に置換する一方加熱工程、キャビティ内の樹脂粒子を発泡融着させる両面加熱工程に分けられる成形方法において、上記一方加熱を行うときに、蒸気圧の設定値を両面加熱時よりも低い値とし、その設定値と成形金型内の圧力検出値との偏差に比例した値を操作量として上記コントロール弁の開度を制御することを特徴とする発泡性合成樹脂の成形方法が開示されている。   In Patent Document 2, after filling foamable synthetic resin particles into a cavity in a molding die, steam is supplied from the mold vapor chamber into the cavity to foam the resin particles. A method of obtaining a foamed molded product by fusing, and the heating process is controlled by a control valve provided in a steam supply system to the mold steam chamber, and at least the mold heating process, the resin particles in the cavity In the molding method divided into one heating process that replaces the air present in between with steam and a double-sided heating process that foams and fuses resin particles in the cavity, when the one-side heating is performed, the set value of the vapor pressure is heated on both sides. The opening of the control valve is controlled by using a value proportional to the deviation between the set value and the pressure detection value in the molding die as the manipulated variable. Methods are disclosed.

特許文献3には、蒸気が流通可能な第1の型と第2の型とを合わせ、それぞれの型間に所望形状のキャビティを有するとともに、それぞれの型に、蒸気弁を開いた時に該型に蒸気が供給される蒸気供給管路とドレン弁を開いた時に該型内から流体を排出するドレン管路とが設けられた成形型の該キャビティ内に、熱可塑性樹脂予備発泡粒子を充填した後、次の各加熱工程(a)〜(e)、
(a)第1の型と第2の型との蒸気弁及びドレン弁を開き、成形型に蒸気を流す成形型加熱工程、
(b)次いで、第1の型の蒸気弁と第2の型のドレン弁とを開き、第1の型のドレン弁と第2の型の蒸気弁とを閉じ、第1の型側から第2の型側に蒸気を流す一方加熱工程、
(c)次いで、第2の型の蒸気弁と第1の型のドレン弁とを開き、第2の型のドレン弁と第1の型の蒸気弁とを閉じ、第2の型側から第1の型側に蒸気を流す逆一方加熱工程、
(d)次いで、第1の型と第2の型のそれぞれの蒸気弁を開き、第1の型と第2の型のそれぞれのドレン弁を閉じて成形型を加熱する両面加熱工程、
(e)次いで、第1の型と第2の型のそれぞれの蒸気及びドレン弁を閉じ、保持された蒸気で成形型内を保熱する保熱工程を行い、次いで成形型を冷却し、発泡樹脂成形体を成形型から取り出す型内発泡成形方法において、
前記(b)一方加熱工程が7秒以上であり、(b)一方加熱工程終了時の成形型内の圧力が0.03MPa以上であり、且つ(e)保熱工程時間/(b)一方加熱工程時間の比率が0.8〜1.2の範囲内であることを特徴とする型内発泡成形方法が開示されている。
In Patent Document 3, a first mold and a second mold through which steam can flow are combined, each has a cavity having a desired shape, and the mold is opened when a steam valve is opened in each mold. Thermoplastic resin pre-expanded particles were filled into the cavity of the mold provided with a steam supply line through which steam is supplied and a drain line for discharging fluid from the mold when the drain valve is opened. Thereafter, the following heating steps (a) to (e),
(A) a mold heating step of opening the steam valve and the drain valve of the first mold and the second mold and causing the steam to flow into the mold;
(B) Next, the first-type steam valve and the second-type drain valve are opened, the first-type drain valve and the second-type steam valve are closed, and the first-type steam valve is closed from the first-type side. Heating process while flowing steam to the mold side of 2,
(C) Next, the second-type steam valve and the first-type drain valve are opened, the second-type drain valve and the first-type steam valve are closed, and the second-type steam valve is closed from the second-type side. A reverse one-side heating process in which steam flows to the mold side of 1;
(D) Next, a double-sided heating step in which the steam valves of the first mold and the second mold are opened, the drain valves of the first mold and the second mold are closed, and the mold is heated.
(E) Next, the steam and drain valve of each of the first mold and the second mold are closed, and a heat retention process is performed in which the inside of the mold is kept with the retained steam, and then the mold is cooled and foamed. In the in-mold foam molding method for removing the resin molded body from the mold,
(B) One heating step is 7 seconds or more, (b) Pressure in the mold at the end of one heating step is 0.03 MPa or more, and (e) Heat retention step time / (b) One heating An in-mold foam molding method is disclosed in which the process time ratio is in the range of 0.8 to 1.2.

特開平5−104649号公報JP-A-5-104649 特開平8−300385号公報JP-A-8-300385 特開2007−237468号公報JP 2007-237468 A

ポリスチレン系樹脂発泡成形体などの熱可塑性樹脂発泡成形体を型内発泡成形によって製造する型内発泡成形方法においては、省エネルギー及び製造コスト削減を図るために、型内発泡成形で使用する加熱媒体(蒸気)の使用量を現状よりも低減可能な方法の提供が求められている。   In the in-mold foam molding method for producing a thermoplastic resin foam molded article such as a polystyrene-based resin foam molded article by in-mold foam molding, a heating medium used in the in-mold foam molding (in order to save energy and reduce manufacturing costs) There is a need to provide a method that can reduce the amount of steam used.

前述した特許文献1〜3に開示されている型内発泡成形方法の従来技術では、使用蒸気量をある程度まで削減することが可能であるが、当該分野にあっては更なる使用蒸気量削減が求められている。   In the prior art of the in-mold foam molding method disclosed in Patent Documents 1 to 3 described above, the amount of steam used can be reduced to a certain extent. It has been demanded.

本発明は、前記事情に鑑みてなされ、型内発泡成形時の使用蒸気量を従来技術よりも削減でき、同等の品質を備えた熱可塑性樹脂発泡成形体を低コストで製造可能な方法の提供を課題とする。   The present invention has been made in view of the above circumstances, and provides a method capable of reducing the amount of steam used in foam molding in a mold as compared with the prior art and capable of producing a thermoplastic resin foam molded article having equivalent quality at low cost. Is an issue.

前記課題を達成するため、本発明は、蒸気が流通可能な第1の型と第2の型とを合わせ、それぞれの型間に所望形状のキャビティを有するとともに、それぞれの型に、蒸気弁を開いた時に該型に蒸気が供給される蒸気供給管路とドレン弁を開いた時に該型内から流体を排出するドレン管路とが設けられた成形型の該キャビティ内に、熱可塑性樹脂予備発泡粒子を充填した後、次の各加熱工程(a)〜(e)、
(a)成形型に蒸気を流す成形型加熱工程、
(b)次いで、第1の型側から第2の型側に蒸気を流す一方加熱工程、
(c)次いで、第2の型側から第1の型側に蒸気を流す逆一方加熱工程、
(d)次いで、両方の型に蒸気を流して成形型を加熱する両面加熱工程、
(e)次いで、保持された蒸気で成形型内を保熱する保熱工程を行い、次いで成形型を冷却し、発泡樹脂成形体を成形型から取り出す型内発泡成形方法において、
前記(c)逆一方加熱工程を、第1の型側と第2の型側の両方のドレン弁を閉じた状態で行うことを特徴とする型内発泡成形方法を提供する。
In order to achieve the above object, the present invention combines a first mold and a second mold through which steam can flow, has a cavity of a desired shape between the molds, and has a steam valve in each mold. In the cavity of the molding die provided with a steam supply line through which steam is supplied to the mold when opened and a drain line for discharging fluid from the mold when the drain valve is opened, After filling the expanded particles, the following heating steps (a) to (e),
(A) a mold heating step in which steam flows through the mold;
(B) Next, a heating step while flowing steam from the first mold side to the second mold side,
(C) Next, a reverse one-side heating step in which steam flows from the second mold side to the first mold side,
(D) Next, a double-sided heating step in which steam is passed through both molds to heat the mold,
(E) Next, in the in-mold foam molding method of performing a heat retaining step of retaining the inside of the mold with the retained steam, then cooling the mold and taking out the foamed resin molded body from the mold.
There is provided an in-mold foam molding method characterized in that the reverse heating step (c) is performed in a state in which both drain valves on the first mold side and the second mold side are closed.

本発明の型内発泡成形方法において、前記(b)一方加熱工程における加熱方向を蒸気室容積の小さい方から大きい方に向けて加熱することが好ましい。   In the in-mold foam molding method of the present invention, it is preferable to heat the heating direction in the (b) one heating step from the smaller steam chamber volume to the larger one.

本発明の型内発泡成形方法において、前記(a)成形型加熱工程を、成形型のキャビティに面した表面の温度が100℃以上に達するように行ってもよい。   In the in-mold foam molding method of the present invention, the (a) mold heating step may be performed so that the temperature of the surface facing the cavity of the mold reaches 100 ° C. or more.

本発明の型内発泡成形方法において、前記(b)一方加熱工程を、前記蒸気供給管路よりも高圧の蒸気が供給されるバイパス管路から前記成形型内に蒸気を導入して行ってもよい。   In the in-mold foam molding method of the present invention, the (b) one heating step may be performed by introducing steam into the mold from a bypass line to which steam having a pressure higher than that of the steam supply line is supplied. Good.

本発明の型内発泡成形方法は、前記(a)〜(e)の各加熱工程を備える型内発泡成形方法において、(c)逆一方加熱工程を、第1の型側と第2の型側の両方のドレン弁を閉じた状態で行うことによって、使用蒸気量が削減でき、高品質の熱可塑性樹脂発泡成形体を低コストで製造することができる。   The in-mold foam molding method of the present invention is the in-mold foam molding method including the heating steps (a) to (e), wherein (c) the reverse one heating step is performed by the first mold side and the second mold. By performing both the drain valves on the side closed, the amount of steam used can be reduced, and a high-quality thermoplastic resin foam molded article can be produced at low cost.

本発明の型内発泡成形方法を実施するために好適な成形装置の一例を示す構成図である。It is a block diagram which shows an example of a suitable shaping | molding apparatus in order to implement the in-mold foam molding method of this invention. 前記成形装置の蒸気供給管路を例示する構成図である。It is a block diagram which illustrates the steam supply pipe line of the said shaping | molding apparatus.

以下、図面を参照して本発明の型内発泡成形方法の実施形態を説明する。
図1及び図2は、本発明の型内発泡成形方法を実施するために好適な成形装置の一例を示す図であり、図1は成形装置の構成図、図2は該成形装置の蒸気供給管路を例示する構成図である。
Hereinafter, an embodiment of an in-mold foam molding method of the present invention will be described with reference to the drawings.
1 and 2 are views showing an example of a molding apparatus suitable for carrying out the in-mold foam molding method of the present invention. FIG. 1 is a configuration diagram of the molding apparatus, and FIG. 2 is a steam supply of the molding apparatus. It is a block diagram which illustrates a pipe line.

この成形装置1は、第1の型である凹型2と、第2の型である凸型3とを備え、これらの型が接近・離間することで型閉め・型開きが可能な成形型4を有している。凹型2は、多数の蒸気孔が設けられた凹型本体5とそれを支持しているフレーム6とを備え、また凸型3も多数の蒸気孔が設けられた凸型本体7とそれを支持しているフレーム8とを備えている。図1に示す型閉め状態において、凹型本体5と凸型本体7との間には、魚箱など、製造しようとする発泡成形体の外径に合致したキャビティ9が形成される。凹型本体5とフレーム6との間には、蒸気室10が設けられ、また凸型本体7とフレーム8との間にも蒸気室11が設けられている。凹型2側の蒸気室10の容積は、凹型本体5とフレーム6で囲まれた空間の容積である。また、凸型3側の蒸気室11の容積は、凸型本体7とフレーム8で囲まれた空間の容積である。   The molding apparatus 1 includes a concave mold 2 that is a first mold and a convex mold 3 that is a second mold, and a mold 4 that can be closed and opened when these molds approach and separate from each other. have. The concave mold 2 includes a concave main body 5 provided with a large number of vapor holes and a frame 6 supporting the concave mold body 2. The convex mold 3 also supports the convex main body 7 provided with a large number of vapor holes and the same. The frame 8 is provided. In the mold closed state shown in FIG. 1, a cavity 9 is formed between the concave mold body 5 and the convex mold body 7 that matches the outer diameter of the foamed molded product to be manufactured, such as a fish box. A steam chamber 10 is provided between the concave body 5 and the frame 6, and a steam chamber 11 is also provided between the convex body 7 and the frame 8. The volume of the steam chamber 10 on the concave mold 2 side is the volume of the space surrounded by the concave mold body 5 and the frame 6. The volume of the steam chamber 11 on the convex mold 3 side is the volume of the space surrounded by the convex main body 7 and the frame 8.

凹型2側の蒸気室10には、凹型側調圧蒸気弁12を介して蒸気供給管路が接続され、その対向位置には凹型側ドレン弁13を介してドレン管路が接続され、このドレン管路には、真空弁14を介して真空排気管路が接続されている。また凹型2側の蒸気室10には、冷却水弁15を介して冷却水供給管路が挿入され、さらに適所には圧力計16が接続されている。   A steam supply line is connected to the steam chamber 10 on the concave side 2 via a concave side pressure regulating steam valve 12, and a drain line is connected to the opposite position via a concave side drain valve 13. A vacuum exhaust pipe line is connected to the pipe line via a vacuum valve 14. Further, a cooling water supply pipe line is inserted into the steam chamber 10 on the concave mold 2 side via a cooling water valve 15, and a pressure gauge 16 is connected to an appropriate place.

同様に、凸型3側の蒸気室11には、凸型側調圧蒸気弁17を介して蒸気供給管路が接続され、その対向位置には凸型側ドレン弁18を介してドレン管路が接続され、このドレン管路には、真空弁19を介して真空排気管路が接続されている。また凸型3側の蒸気室11には、冷却水弁20を介して冷却水供給管路が挿入され、さらに適所には圧力計21が接続されている。なお、図示していないが、この成形型4の適所には、キャビティ9内に予備発泡粒子を充填するための供給管路が接続した予備発泡粒子供給口が設けられている。   Similarly, a steam supply conduit is connected to the steam chamber 11 on the convex 3 side via a convex pressure regulating steam valve 17, and a drain conduit is connected to the opposite position via a convex drain valve 18. And a vacuum exhaust line is connected to the drain line via a vacuum valve 19. In addition, a cooling water supply pipe line is inserted into the steam chamber 11 on the convex mold 3 side via a cooling water valve 20, and a pressure gauge 21 is connected to an appropriate place. Although not shown, a pre-expanded particle supply port connected to a supply line for filling the pre-expanded particles in the cavity 9 is provided at an appropriate position of the mold 4.

それぞれの蒸気室10,11に蒸気を供給するための蒸気供給管路22は、図2に示すように、高圧の蒸気が通る蒸気主管23に接続され、その管路内には、蒸気減圧弁24とオリフィス型蒸気流量計25とが設けられている。前記蒸気減圧弁24は、供給蒸気圧力を通常0.20〜0.55MPa程度に設定している。オリフィス型蒸気流量計25は、流量計に接続された表示部26により、蒸気供給管路22を経て供給される蒸気流量を表示可能になっている。   As shown in FIG. 2, a steam supply line 22 for supplying steam to each of the steam chambers 10 and 11 is connected to a steam main pipe 23 through which high-pressure steam passes. 24 and an orifice type steam flow meter 25 are provided. The steam pressure reducing valve 24 normally has a supply steam pressure set to about 0.20 to 0.55 MPa. The orifice type steam flow meter 25 can display the flow rate of steam supplied through the steam supply line 22 by a display unit 26 connected to the flow meter.

また、前記蒸気供給管路22の蒸気減圧弁24よりも下流側であって、凹型2と凸型3の上流側には、それぞれ凹型側調圧蒸気弁12と凸型側調圧蒸気弁17とが設けられている。凹型側調圧蒸気弁12、凸型側調圧蒸気弁17は、蒸気減圧弁24からの高圧の蒸気を更に減圧させるもので、供給蒸気圧力を通常0.03〜0.18MPa程度に設定している。そして、凹型側調圧蒸気弁12から凹型2へ、凸型側調圧蒸気弁17から凸型3へ蒸気が供給される。
また、前記蒸気供給管路22の蒸気減圧弁24よりも下流側であって、凹型2の上流側には、凹型側調圧蒸気弁12を介さずに凹型2へ高圧の蒸気を供給できる凹型側バイパス管路27が設けられている。このバイパス管路27には凹型側バイパス蒸気弁29が設けられており、このバイパス蒸気弁29を開くことで凹型2へ高圧の蒸気を供給できる。
また、前記蒸気供給管路22の蒸気減圧弁24よりも下流側であって、凸型3の上流側には、凸型側調圧蒸気弁17を介さずに凸型3へ高圧の蒸気を供給できる凸型側バイパス管路28が設けられている。このバイパス管路28には凸型側バイパス蒸気弁30が設けられており、このバイパス蒸気弁30を開くことで凸型3へ高圧の蒸気を供給できる。
Further, on the downstream side of the steam pressure reducing valve 24 of the steam supply line 22 and on the upstream side of the concave mold 2 and the convex mold 3, the concave pressure regulating steam valve 12 and the convex pressure regulating steam valve 17 are respectively provided. And are provided. The concave side pressure regulating steam valve 12 and the convex side pressure regulating steam valve 17 further depressurize the high-pressure steam from the steam pressure reducing valve 24. The supply steam pressure is usually set to about 0.03 to 0.18 MPa. ing. Then, steam is supplied from the concave-side pressure regulating steam valve 12 to the concave mold 2 and from the convex-side pressure regulating steam valve 17 to the convex mold 3.
Further, a concave type that is capable of supplying high-pressure steam to the concave mold 2 without the concave-side pressure regulating steam valve 12 on the downstream side of the steam pressure reducing valve 24 of the steam supply line 22 and upstream of the concave mold 2. A side bypass line 27 is provided. The bypass pipe 27 is provided with a concave-side bypass steam valve 29, and high-pressure steam can be supplied to the concave mold 2 by opening the bypass steam valve 29.
Further, on the downstream side of the steam pressure reducing valve 24 in the steam supply line 22 and upstream of the convex mold 3, high-pressure steam is supplied to the convex mold 3 without using the convex pressure regulating steam valve 17. A convex side bypass pipe 28 that can be supplied is provided. The bypass pipe 28 is provided with a convex bypass steam valve 30, and high-pressure steam can be supplied to the convex mold 3 by opening the bypass steam valve 30.

前述したように構成された成形装置を用い、ポリスチレン系樹脂発泡成形体などの熱可塑性樹脂発泡成形体を製造するには、凹型2と凸型3とを接近させて成形型4を閉じ、そのキャビティ9内に予備発泡粒子を充填し、次いで成形型4を蒸気加熱して発泡させながら予備発泡粒子同士を融着させて型内発泡成形し、次いで成形型4を冷却し、次いで成形型4を開き、発泡成形体を離型して取り出すことにより行われる。   In order to produce a thermoplastic resin foam molded article such as a polystyrene-based resin foam molded article using the molding apparatus configured as described above, the concave mold 2 and the convex mold 3 are brought close to each other and the mold 4 is closed. The pre-expanded particles are filled in the cavity 9, and then the pre-expanded particles are fused together while being foamed by steam heating of the mold 4, then the in-mold foam molding is performed, and then the mold 4 is cooled, and then the mold 4 Is performed, and the foamed molded product is released from the mold.

本発明の型内発泡成形方法において用いる予備発泡粒子は、発泡剤を含有させた合成樹脂粒子を予備発泡させて得られるものであり、この合成樹脂粒子を構成する合成樹脂としては、従来から発泡樹脂成形品製造のために用いられている樹脂材料の中から適宜選択して用いることができ、特に限定されず、例えば、ポリスチレン、ハイインパクトポリスチレン、スチレン−無水マレイン酸共重合体、スチレン−アクリロニトリル共重合体等のポリスチレン系樹脂、ポリエチレン、ポリプロピレン、エチレン−酢酸ビニル共重合体等のポリオレフィン系樹脂、ポリエチレンテレフタレート等のポリエステル系樹脂等を挙げることができ、強度と成形性の良さからポリスチレン系樹脂が好ましい。   The pre-foamed particles used in the in-mold foam molding method of the present invention are obtained by pre-foaming synthetic resin particles containing a foaming agent, and the synthetic resins constituting the synthetic resin particles are conventionally foamed. Can be appropriately selected from resin materials used for the production of resin molded products, and is not particularly limited. For example, polystyrene, high impact polystyrene, styrene-maleic anhydride copolymer, styrene-acrylonitrile Polystyrene resins such as copolymers, polyolefin resins such as polyethylene, polypropylene, and ethylene-vinyl acetate copolymers, polyester resins such as polyethylene terephthalate, etc., and polystyrene resins because of their strength and moldability Is preferred.

また、前記発泡剤としては、沸点が合成樹脂の軟化点以下であって、常圧でガス状もしくは液状の有機化合物が適しており、例えば、プロパン、ブタン、ペンタン、シクロペンタン、シクロペンタジエン、ヘキサン、石油エーテル等の炭化水素、ジメチルエーテル、ジエチルエーテル、ジプロピルエーテル、メチルエチルエーテル等の低沸点のエーテル化合物、炭酸ガス、窒素等の無機ガス等が用いられる。これらの発泡剤は、一種のみを使用してもよく、また、二種以上を併用してもよい。発泡剤の含有率としては、合成樹脂粒子質量に対して1〜20質量%、好ましくは2〜10質量%である。発泡剤の含有量が前記範囲を下回ると、発泡成形品の発泡倍率が不十分で軽量発泡体が得られない。一方、発泡剤の含有量が前記範囲を超えても、発泡倍率の更なる上昇は実質的に見込めず、また発泡が不安定になり好ましくない。   Further, as the foaming agent, organic compounds that have a boiling point below the softening point of the synthetic resin and are gaseous or liquid at normal pressure are suitable. For example, propane, butane, pentane, cyclopentane, cyclopentadiene, hexane Further, hydrocarbons such as petroleum ether, low boiling point ether compounds such as dimethyl ether, diethyl ether, dipropyl ether, and methyl ethyl ether, inorganic gases such as carbon dioxide and nitrogen, and the like are used. These foaming agents may use only 1 type and may use 2 or more types together. As a content rate of a foaming agent, it is 1-20 mass% with respect to the synthetic resin particle mass, Preferably it is 2-10 mass%. When the content of the foaming agent is less than the above range, the foaming ratio of the foamed molded product is insufficient and a lightweight foam cannot be obtained. On the other hand, even if the content of the foaming agent exceeds the above range, a further increase in the expansion ratio cannot be substantially expected, and foaming becomes unstable, which is not preferable.

(第1の実施形態)
本発明の型内発泡成形方法では、成形型4のキャビティ9内に予備発泡粒子を充填した後、次の各加熱工程(a)〜(e)、
(a)凹型側調圧蒸気弁12、凸型側調圧蒸気弁17、凹型側ドレン弁13及び凸型側ドレン弁18を開き、成形型4に蒸気を流す成形型加熱工程、
(b)次いで、凹型側調圧蒸気弁12と凸型側ドレン弁18を開き、凸型側調圧蒸気弁17と凹型側ドレン弁13を閉じて凹型2側から凸型3側に、或いは凸型側調圧蒸気弁17と凹型側ドレン弁13を開き、凹型側調圧蒸気弁12と凸型側ドレン弁18を閉じて凸型3側から凹型2側に蒸気を流す一方加熱工程、
(c)次いで、凸型側調圧蒸気弁17を開き、凹型側調圧蒸気弁12を閉じて凸型3側から凹型2側に、或いは凹型側調圧蒸気弁12を開き、凸型側調圧蒸気弁17を閉じて凹型2側から凸型3側に蒸気を流す逆一方加熱工程、
(d)次いで、凹型側調圧蒸気弁12と凸型側調圧蒸気弁17を開き、凹型側ドレン弁13と凸型側ドレン弁18を閉じて成形型4を加熱する両面加熱工程、
(e)次いで、凹型側調圧蒸気弁12、凸型側調圧蒸気弁17、凹型側ドレン弁13及び凸型側ドレン弁18を閉じ、保持された蒸気で成形型4内を保熱する保熱工程、
とを行う。
そして本発明の型内発泡成形方法では、前記(c)逆一方加熱工程は、凹型側ドレン弁13と凸型側ドレン弁18を閉じた状態で行うことを特徴とする。
(First embodiment)
In the in-mold foam molding method of the present invention, after filling the pre-expanded particles in the cavity 9 of the mold 4, the following heating steps (a) to (e),
(A) a molding die heating step of opening the concave side pressure regulating steam valve 12, the convex side pressure regulating steam valve 17, the concave side drain valve 13 and the convex side drain valve 18 and flowing steam to the molding die 4;
(B) Next, the concave side pressure regulating steam valve 12 and the convex side drain valve 18 are opened, and the convex side pressure regulating steam valve 17 and the concave side drain valve 13 are closed and the concave mold 2 side is shifted to the convex mold 3 side, or Opening the convex pressure regulating steam valve 17 and the concave drain valve 13, closing the concave pressure regulating steam valve 12 and the convex drain valve 18, and allowing the steam to flow from the convex 3 side to the concave 2 side while heating,
(C) Next, the convex side pressure regulating steam valve 17 is opened, the concave side pressure regulating steam valve 12 is closed, and the convex side is opened from the convex mold 3 side, or the concave side pressure regulating steam valve 12 is opened. A reverse heating process in which the pressure regulating steam valve 17 is closed and the steam flows from the concave mold 2 side to the convex mold 3 side;
(D) Next, a double-sided heating step in which the concave side pressure regulating steam valve 12 and the convex side pressure regulating steam valve 17 are opened, the concave side drain valve 13 and the convex side drain valve 18 are closed, and the mold 4 is heated.
(E) Next, the concave-side pressure regulating steam valve 12, the convex-side pressure regulating steam valve 17, the concave-side drain valve 13 and the convex-side drain valve 18 are closed, and the inside of the mold 4 is kept warm with the retained steam. Heat insulation process,
And do.
The in-mold foam molding method of the present invention is characterized in that the (c) reverse one-side heating step is performed in a state where the concave side drain valve 13 and the convex side drain valve 18 are closed.

前記(a)〜(d)の各加熱工程において、凹型2と凸型3に供給される蒸気の圧力が0.03〜0.18MPaである場合、前記(a)成形型加熱工程は、1〜3秒程度とすることが好ましい。(b)一方加熱工程は、6〜15秒程度とすることが好ましい。(c)逆一方加熱工程は、2〜5秒程度とすることが好ましい。(d)両面加熱工程は、5〜10秒程度とすることが好ましい。また、(e)保熱工程は、5〜7秒程度とすることが好ましい。   In each of the heating processes (a) to (d), when the pressure of the steam supplied to the concave mold 2 and the convex mold 3 is 0.03 to 0.18 MPa, the (a) mold heating process is 1 It is preferable to be about 3 seconds. (B) On the other hand, the heating step is preferably about 6 to 15 seconds. (C) The reverse one heating step is preferably about 2 to 5 seconds. (D) The double-sided heating step is preferably about 5 to 10 seconds. Moreover, it is preferable that (e) heat retention process be about 5 to 7 seconds.

前記(e)保熱工程の終了後、冷却水弁15,20を開いて冷却水を成形装置1内に導入し、凹型2と凸型3に向けて流し、型を冷却する水冷工程を行う。この水冷工程は、1〜5秒程度とすることが好ましい。
前記水冷工程後、凹型側ドレン弁13と凸型側ドレン弁18、冷却水弁15,20を閉じ、真空弁14,19を開くことによって成形型4内を真空排気して凹型2と凸型3を放冷する(放冷工程)。この放冷は、20〜100秒程度とすることが好ましい。
(E) After completion of the heat retention step, the cooling water valves 15 and 20 are opened to introduce the cooling water into the molding apparatus 1 and flow toward the concave mold 2 and the convex mold 3 to cool the mold. . This water cooling step is preferably about 1 to 5 seconds.
After the water cooling step, the concave side drain valve 13, the convex side drain valve 18, the cooling water valves 15 and 20 are closed, and the vacuum valves 14 and 19 are opened to evacuate the inside of the molding die 4 so that the concave die 2 and the convex die are provided. 3 is allowed to cool (cooling step). This cooling is preferably about 20 to 100 seconds.

放冷後、凹型2と凸型3とを離間する方向に移動させて型開きし、型内発泡成形により得られた発泡成形体を取り出す。
その後、再び型閉めし、キャビティ9内に予備発泡粒子を充填し、前記各工程を繰り返し行う。
After standing to cool, the concave mold 2 and the convex mold 3 are moved away from each other to open the mold, and the foam molded body obtained by in-mold foam molding is taken out.
Thereafter, the mold is closed again, pre-expanded particles are filled into the cavity 9, and the above steps are repeated.

本実施形態では、前記(c)逆一方加熱工程は、凹型側ドレン弁13と凸型側ドレン弁18を閉じた状態で行うことにより、(c)逆一方加熱工程において使用する蒸気流量を削減することができ、高品質の熱可塑性樹脂発泡成形体を低コストで製造することができる。   In the present embodiment, the (c) reverse one-side heating step is performed with the concave-side drain valve 13 and the convex-side drain valve 18 closed, thereby reducing the steam flow rate used in the (c) reverse one-side heating step. Therefore, a high-quality thermoplastic resin foam molded article can be produced at a low cost.

(第2の実施形態)
本発明の型内発泡成形方法において、前記(b)一方加熱工程における加熱方向を、蒸気室容積の小さい方から大きい方に向けて加熱することが好ましい。
前記凹型2の蒸気室10の容積と凸型3の蒸気室11の容積が、凹型>凸型の関係である場合、前記(b)一方加熱工程は、凸型側調圧蒸気弁17と凹型側ドレン弁13を開き、凸型側ドレン弁18と凹型側調圧蒸気弁12とを閉じ、凸型3側から凹型2側に向けて蒸気を流して行う。
この場合、(c)逆一方加熱工程は、凹型側調圧蒸気弁12を開き、凸型側調圧蒸気弁17、凹型側ドレン弁13と凸型側ドレン弁18を閉じた状態で、凹型2側から凸型3側に蒸気を流して行われる。
前記凹型2の蒸気室10の容積と凸型3の蒸気室11の容積が、凹型<凸型の関係である場合、前記(b)一方加熱工程は、凹型側調圧蒸気弁12と凸型側ドレン弁18を開き、凹型側ドレン弁13と凸型側調圧蒸気弁17とを閉じ、凹型2側から凸型3側に向けて蒸気を流して行う。
この場合、(c)逆一方加熱工程は、凸型側調圧蒸気弁17を開き、凹型側調圧蒸気弁12、凹型側ドレン弁13と凸型側ドレン弁18を閉じた状態で、凸型3側から凹型2側に蒸気を流して行われる。
(Second Embodiment)
In the in-mold foam molding method of the present invention, it is preferable to heat the heating direction in the (b) one heating step from a smaller steam chamber volume to a larger one.
When the volume of the concave chamber 2 and the volume of the convex chamber 3 has a relationship of concave> convex, the (b) one heating step includes the convex side pressure regulating steam valve 17 and the concave mold. The side drain valve 13 is opened, the convex side drain valve 18 and the concave side pressure regulating steam valve 12 are closed, and steam is flowed from the convex 3 side toward the concave 2 side.
In this case, (c) the reverse one-side heating step is performed with the concave side pressure regulating steam valve 12 opened, the convex side pressure regulating steam valve 17, the concave side drain valve 13 and the convex side drain valve 18 closed. This is done by flowing steam from the 2 side to the convex 3 side.
When the volume of the steam chamber 10 of the concave mold 2 and the volume of the steam chamber 11 of the convex mold 3 are in the relationship of concave <convex, the (b) one heating step is performed by using the concave side pressure regulating steam valve 12 and the convex The side drain valve 18 is opened, the concave side drain valve 13 and the convex side pressure regulating steam valve 17 are closed, and steam is flowed from the concave 2 side toward the convex 3 side.
In this case, (c) the reverse one-side heating step is performed with the convex side pressure regulating steam valve 17 opened and the concave side pressure regulating steam valve 12, the concave side drain valve 13 and the convex side drain valve 18 closed. It is performed by flowing steam from the mold 3 side to the concave mold 2 side.

本実施形態では、(b)一方加熱工程における加熱方向を、蒸気室容積の小さい方から大きい方に向けて加熱することによって、一方加熱工程の所要時間を短縮でき、使用蒸気量が削減できる。   In this embodiment, (b) by heating the heating direction in the one heating step from the smaller one of the steam chamber volumes to the larger one, the time required for the one heating step can be shortened and the amount of steam used can be reduced.

(第3の実施形態)
本発明の型内発泡成形方法において、前記(a)成形型加熱工程を、成形型4のキャビティ9に面した表面の温度が100℃以上に達するように行うことが好ましい。
(a)成形型加熱工程において成形型4のキャビティ9に面した表面の温度を100℃以上とするために、前記(a)成形型加熱工程は、1.5〜3秒程度とすることが好ましい。
(Third embodiment)
In the in-mold foam molding method of the present invention, the (a) mold heating step is preferably performed so that the temperature of the surface of the mold 4 facing the cavity 9 reaches 100 ° C. or more.
(A) In order to set the temperature of the surface of the mold 4 facing the cavity 9 in the mold heating process to 100 ° C. or higher, the (a) mold heating process should be about 1.5 to 3 seconds. preferable.

本実施形態では、(a)成形型加熱工程を、成形型4のキャビティ9に面した表面の温度が100℃以上に達するように行うことによって、次の(b)一方加熱工程の加熱時間を短縮することができ、成形サイクルのトータルとしての使用蒸気量を削減することができる。   In this embodiment, (a) the mold heating step is performed so that the temperature of the surface of the mold 4 facing the cavity 9 reaches 100 ° C. or higher, thereby reducing the heating time of the next (b) one heating step. The amount of steam used as a total of the molding cycle can be reduced.

(第4の実施形態)
本発明の型内発泡成形方法において、(b)一方加熱工程を、凹型側調圧蒸気弁12或いは凸型側調圧蒸気弁17から供給される低圧の蒸気よりも高圧の蒸気が供給される凹型側バイパス管路27或いは凸型側バイパス管路28から成形型4内に蒸気を導入して行うことが好ましい。この(b)一方加熱工程では、凹型側バイパス蒸気弁29或いは凸型側バイパス蒸気弁30を開くことによって、減圧されてない高圧の蒸気が成形型4内に導入される。
この(b)一方加熱工程は、蒸気圧0.20〜0.55MPa程度の高圧蒸気を導入することによって、(b)一方加熱工程の所要時間が6〜9秒程度に短縮される。
この(b)一方加熱工程において、凹型側調圧蒸気弁12或いは凸型側調圧蒸気弁17を閉じて、凹型側バイパス管路27或いは凸型側バイパス管路28からの高圧の蒸気のみを成形型4内に導入することができる。また、凹型側調圧蒸気弁12或いは凸型側調圧蒸気弁17を開けて低圧の蒸気と共に、凹型側バイパス管路27或いは凸型側バイパス管路28からの高圧の蒸気を成形型4内に導入することができる。低圧の蒸気と共に、高圧の蒸気を成形型4内に導入することは、蒸気の圧力変動が小さく、蒸気を安定して供給できるのでより好ましい態様である。
(Fourth embodiment)
In the in-mold foam molding method of the present invention, (b) the one heating step is supplied with higher pressure steam than the low pressure steam supplied from the concave side pressure regulating steam valve 12 or the convex side pressure regulating steam valve 17. Preferably, steam is introduced into the mold 4 from the concave side bypass conduit 27 or the convex side bypass conduit 28. In this (b) one heating step, high pressure steam that is not decompressed is introduced into the mold 4 by opening the concave side bypass steam valve 29 or the convex side bypass steam valve 30.
In this (b) one-side heating step, by introducing high-pressure steam having a vapor pressure of about 0.20 to 0.55 MPa, the time required for the (b) one-side heating step is shortened to about 6 to 9 seconds.
In this (b) one heating step, the concave-side pressure regulating steam valve 12 or the convex-side pressure regulating steam valve 17 is closed, and only high-pressure steam from the concave-side bypass conduit 27 or the convex-side bypass conduit 28 is discharged. It can be introduced into the mold 4. Further, the concave side pressure regulating steam valve 12 or the convex side pressure regulating steam valve 17 is opened, and the high pressure steam from the concave side bypass pipe 27 or the convex side bypass pipe 28 is fed into the molding die 4 together with the low pressure steam. Can be introduced. Introducing high-pressure steam into the mold 4 together with low-pressure steam is a more preferable aspect because the pressure fluctuation of the steam is small and the steam can be supplied stably.

本実施形態では、(b)一方加熱工程を、凹型側調圧蒸気弁12或いは凸型側調圧蒸気弁17から供給される低圧の蒸気よりも高圧の蒸気が供給される凹型側バイパス管路27或いは凸型側バイパス管路28から成形型4内に蒸気を導入して行うことによって、(b)一方加熱工程の所要時間を削減でき、成形サイクルのトータルとしての使用蒸気量を削減することができる。   In the present embodiment, (b) the one-side heating step is a concave-side bypass pipe that is supplied with higher-pressure steam than low-pressure steam supplied from the concave-side pressure-regulating steam valve 12 or the convex-side pressure-regulating steam valve 17. 27 or by introducing steam into the mold 4 from the convex side bypass conduit 28 (b) On the other hand, the time required for the heating process can be reduced, and the total amount of steam used in the molding cycle can be reduced. Can do.

[比較例]
比較例では、従来の成形条件下でポリスチレン系樹脂発泡成形体を製造した。
成形装置は、笠原工業社製AD1313を使用した。この成形装置に、外寸法480mm×310mm×120 mm)、内寸法435mm×265mm×100mm)の角形箱状の魚箱を成形可能な凹型と凸型を取り付けた。
型閉め後、キャビティ内にポリスチレン系樹脂予備発泡粒子を充填した。予備発泡粒子としては、積水化成品工業社製HDMF(嵩発泡倍数60倍)を用いた。
次に、凹型側調圧蒸気弁12、凸型側調圧蒸気弁17から0.065MPaの蒸気を成形型4に導入し、(a)〜(e)の各加熱工程を連続して実施した。なお、凹型側バイパス蒸気弁29、凸型側バイパス蒸気弁30は閉とした。
[Comparative example]
In the comparative example, a polystyrene resin foam molded article was produced under conventional molding conditions.
As the molding apparatus, AD1313 manufactured by Kasahara Kogyo Co., Ltd. was used. A concave mold and a convex mold capable of molding a square box-shaped fish box having an outer dimension of 480 mm × 310 mm × 120 mm) and an inner dimension of 435 mm × 265 mm × 100 mm) were attached to this molding apparatus.
After closing the mold, polystyrene resin pre-expanded particles were filled in the cavity. As the pre-expanded particles, HDMF (bulk expansion ratio 60 times) manufactured by Sekisui Plastics Co., Ltd. was used.
Next, 0.065 MPa of steam was introduced into the molding die 4 from the concave side pressure regulating steam valve 12 and the convex side pressure regulating steam valve 17, and the respective heating steps (a) to (e) were continuously performed. . The concave side bypass steam valve 29 and the convex side bypass steam valve 30 were closed.

(a)凹型側調圧蒸気弁12、凸型側調圧蒸気弁17、凹型側ドレン弁13及び凸型側ドレン弁18を開き、成形型4に蒸気を流す成形型加熱工程(1.0秒)、
(b)次いで、凹型側調圧蒸気弁12と凸型側ドレン弁18を開き、凹型側ドレン弁13と凸型側調圧蒸気弁17とを閉じ、凹型2側から凸型3側に蒸気を流す一方加熱工程(13.2秒)〔一方加熱工程の歩進圧力(キャビティ9の圧力)は0.020MPaに設定し、0.020MPaに達したとき一方加熱工程を終了し、次の逆一方加熱工程に移るように設定した〕、
(c)次いで、凸型側調圧蒸気弁17と凹型側ドレン弁13とを開き、凹型側調圧蒸気弁12と凸型側ドレン弁18を閉じ、凸型3側から凹型2側に蒸気を流す逆一方加熱工程(3.0秒)、
(d)次いで、凹型側調圧蒸気弁12と凸型側調圧蒸気弁17を開き、凹型側ドレン弁13と凸型側ドレン弁18を閉じて成形型4を加熱する両面加熱工程(5.0秒)、
(e)次いで、凹型側調圧蒸気弁12、凸型側調圧蒸気弁17、凹型側ドレン弁13及び凸型側ドレン弁18を閉じ、保持された蒸気で成形型4内を保熱する保熱工程(5.0秒)。
(A) Opening the concave side pressure regulating steam valve 12, the convex side pressure regulating steam valve 17, the concave mold side drain valve 13 and the convex mold side drain valve 18, and a mold heating process (1.0 Seconds),
(B) Next, the concave side pressure regulating steam valve 12 and the convex side drain valve 18 are opened, the concave side drain valve 13 and the convex side pressure regulating steam valve 17 are closed, and the steam is transferred from the concave mold 2 side to the convex mold 3 side. Heating step (13.2 seconds) [Step pressure of the one heating step (pressure in the cavity 9) is set to 0.020 MPa, and when the pressure reaches 0.020 MPa, the one heating step is terminated and the next reverse On the other hand, it was set to move to the heating process)
(C) Next, the convex side pressure regulating steam valve 17 and the concave side drain valve 13 are opened, the concave side pressure regulating steam valve 12 and the convex side drain valve 18 are closed, and the steam is transferred from the convex type 3 side to the concave type 2 side. Reverse heating process (3.0 seconds),
(D) Next, a double-side heating step (5) in which the concave side pressure regulating steam valve 12 and the convex side pressure regulating steam valve 17 are opened, the concave side drain valve 13 and the convex side drain valve 18 are closed, and the molding die 4 is heated. .0 seconds),
(E) Next, the concave-side pressure regulating steam valve 12, the convex-side pressure regulating steam valve 17, the concave-side drain valve 13 and the convex-side drain valve 18 are closed, and the inside of the mold 4 is kept warm with the retained steam. Thermal insulation process (5.0 seconds).

次に、成形型を冷却(冷却水冷却(3.0秒)及び真空排気(55.0秒))し、その後成形型を開き、魚箱を得た。使用した蒸気流量の合計量は6.6kg/shotであった。
この比較例で得られた魚箱について、外観検査と内部融着検査によって発泡成形体としての品質を調べた結果、品質は良好(○)であった。
この比較例において使用した蒸気流量の合計量を表1に記す。
Next, the mold was cooled (cooling water cooling (3.0 seconds) and evacuation (55.0 seconds)), and then the mold was opened to obtain a fish box. The total amount of steam flow used was 6.6 kg / shot.
About the fish box obtained in this comparative example, as a result of investigating the quality as a foam-molded product by appearance inspection and internal fusion inspection, the quality was good (◯).
The total amount of steam flow used in this comparative example is shown in Table 1.

[実施例1]
(c)逆一方加熱工程において、凹型側ドレン弁13と凸型側ドレン弁18を閉じて逆一方加熱を行ったこと以外は、比較例と同様の条件として、魚箱を製造した。
歩進圧力に達するまでの一方加熱工程の時間は比較例と同じ13.2秒であったが、蒸気流量の合計量が6.2kg/shotに減少した。
この実施例1で得られた魚箱の品質は良好(○)であった。
この実施例1において使用した蒸気流量の合計量を表1に記す。
[Example 1]
(C) In the reverse one-side heating step, a fish box was manufactured under the same conditions as in the comparative example, except that the concave-side drain valve 13 and the convex-type drain valve 18 were closed and reverse one-side heating was performed.
The time of the one heating process until reaching the stepping pressure was 13.2 seconds, which was the same as the comparative example, but the total amount of steam flow was reduced to 6.2 kg / shot.
The quality of the fish box obtained in Example 1 was good (◯).
The total amount of steam flow used in Example 1 is shown in Table 1.

[実施例2]
凹型2と凸型3の蒸気室容積は、凹型>凸型の関係であった。そこで、(b)一方加熱工程において加熱方向(比較例では凹→凸)を凸型から凹型に変更し、(c)逆一方加熱工程において加熱方向を凹型→凸型に変更し、それ以外は実施例1と同じ条件で型内発泡成形を行った。
(b)一方加熱工程は、凸型側調圧蒸気弁17と凹型側ドレン弁13を開き、凸型側ドレン弁18と凹型側調圧蒸気弁12とを閉じ、凸型3側から凹型2側に向けて蒸気を流して行った(11.8秒)。
(c)逆一方加熱工程は、凹型側調圧蒸気弁12を開き、凸型側調圧蒸気弁17、凹型側ドレン弁13と凸型側ドレン弁18を閉じた状態で、凹型2側から凸型3側に蒸気を流して行った(3.0秒)。
蒸気室容積の小さな凸型から蒸気を吹き込むことによって、歩進圧力に達するまでの一方加熱工程の時間が11.8秒に短縮され、蒸気流量の合計量が6.0kg/shotに減少した。
この実施例2で得られた魚箱の品質は良好(○)であった。
この実施例2において使用した蒸気流量の合計量を表1に記す。
[Example 2]
The vapor chamber volumes of the concave mold 2 and the convex mold 3 were in the relationship of concave> convex. Therefore, (b) the heating direction (concave to convex in the comparative example) is changed from a convex shape to a concave shape in the one heating step, and (c) the heating direction is changed from a concave shape to a convex shape in the reverse one heating step. In-mold foam molding was performed under the same conditions as in Example 1.
(B) On the other hand, in the heating step, the convex side pressure regulating steam valve 17 and the concave side drain valve 13 are opened, the convex side drain valve 18 and the concave side pressure regulating steam valve 12 are closed, and the convex shape 3 side to the concave shape 2 The steam flowed to the side (11.8 seconds).
(C) In the reverse one-side heating step, the concave side pressure regulating steam valve 12 is opened and the convex side pressure regulating steam valve 17, the concave side drain valve 13 and the convex side drain valve 18 are closed, and the concave side pressure regulating valve 12 is closed. This was carried out by flowing steam on the convex mold 3 side (3.0 seconds).
By blowing steam from a convex mold having a small steam chamber volume, the one heating process time until reaching the stepping pressure was shortened to 11.8 seconds, and the total amount of steam flow was reduced to 6.0 kg / shot.
The quality of the fish box obtained in Example 2 was good (◯).
The total amount of steam flow used in Example 2 is shown in Table 1.

[実施例3]
(a)成形型加熱工程の時間を1.0秒から2.0秒としたこと以外は、実施例2と同じ条件で型内発泡成形を行った。(a)成形型加熱工程の時間を1.0秒とした比較例では、成形型のキャビティに面した表面の温度が97℃であったが、(a)成形型加熱工程の時間を2.0秒にした場合、成形型のキャビティに面した表面の温度が103℃に達した。
歩進圧力に達するまでの一方加熱工程の時間が11.4秒に短縮され、蒸気流量の合計量が5.8kg/shotに減少した。
この実施例3で得られた魚箱の品質は良好(○)であった。
この実施例3において使用した蒸気流量の合計量を表1に記す。
[Example 3]
(A) In-mold foam molding was performed under the same conditions as in Example 2 except that the time of the mold heating step was changed from 1.0 second to 2.0 seconds. (A) In the comparative example in which the time of the mold heating step was 1.0 second, the temperature of the surface facing the cavity of the mold was 97 ° C., but the time of the (a) mold heating step was 2. In the case of 0 seconds, the temperature of the surface facing the mold cavity reached 103 ° C.
The time of the one heating process until reaching the stepping pressure was shortened to 11.4 seconds, and the total amount of steam flow was reduced to 5.8 kg / shot.
The quality of the fish box obtained in Example 3 was good (◯).
The total amount of steam flow used in Example 3 is shown in Table 1.

[実施例4]
(b)一方加熱工程において、凸型側調圧蒸気弁17からの蒸気(0.065MPa)と共に、凸型側バイパス管路28に設けた凸型側バイパス蒸気弁30を開にして高圧の蒸気(0.30MPa)を成形型に導入して行ったこと以外は、実施例3と同じ条件で型内発泡成形を行った。
歩進圧力に達するまでの一方加熱工程の時間が8.5秒に短縮され、蒸気流量の合計量が5.2kg/shotに減少した。
この実施例4で得られた魚箱の品質は良好(○)であった。
この実施例4において使用した蒸気流量の合計量を表1に記す。
[Example 4]
(B) On the other hand, in the heating step, together with the steam (0.065 MPa) from the convex-side pressure regulating steam valve 17, the convex-side bypass steam valve 30 provided in the convex-side bypass conduit 28 is opened and the high-pressure steam is opened. In-mold foam molding was performed under the same conditions as in Example 3 except that (0.30 MPa) was introduced into the mold.
The time of the one heating process until reaching the stepping pressure was shortened to 8.5 seconds, and the total amount of steam flow was reduced to 5.2 kg / shot.
The quality of the fish box obtained in Example 4 was good (◯).
The total amount of steam flow used in Example 4 is shown in Table 1.

Figure 2013176886
Figure 2013176886

表1の結果から、(c)逆一方加熱工程において、凹型側ドレン弁13と凸型側ドレン弁18を閉じて逆一方加熱を行った実施例1は、ドレン弁からの蒸気の排出を防いだことによって、比較例に比べて蒸気流量を削減することができた。
実施例2では、実施例1の加熱条件において、加熱方向を凸→凹に変更し、蒸気室容積の小さな凸型から蒸気を吹き込んだことによって、一方加熱工程の時間が13.2秒から11.8秒に短縮され、実施例1よりもさらに蒸気流量を削減することができた。
実施例3では、実施例2の加熱条件において、成形型加熱工程の時間を1.0秒から2.0秒としたことによって、一方加熱工程の時間が11.8秒から11.4秒に短縮され、実施例2よりもさらに蒸気流量を削減することができた。
実施例4では、実施例3の加熱条件において、一方加熱工程で高圧の蒸気を成形型に導入したことによって、一方加熱工程の時間が11.4秒から8.5秒に短縮され、実施例3よりもさらに蒸気流量を削減することができた。
From the results of Table 1, (c) in the reverse one-side heating step, Example 1 in which the concave-side drain valve 13 and the convex-side drain valve 18 are closed and reverse one-side heating is performed prevents the steam from being discharged from the drain valve. As a result, the steam flow rate was reduced compared to the comparative example.
In Example 2, the heating direction was changed from convex to concave under the heating conditions of Example 1, and steam was blown from a convex mold having a small steam chamber volume. It was shortened to 8 seconds, and the steam flow rate could be further reduced as compared with Example 1.
In Example 3, the heating time of the mold was changed from 1.0 seconds to 2.0 seconds under the heating conditions of Example 2, while the heating time was changed from 11.8 seconds to 11.4 seconds. As a result, the steam flow rate could be further reduced as compared with Example 2.
In Example 4, by introducing high-pressure steam into the mold in one heating step under the heating conditions of Example 3, the time of one heating step was shortened from 11.4 seconds to 8.5 seconds. The steam flow rate could be further reduced than 3.

本発明は、ポリスチレン系樹脂発泡成形体などの熱可塑性樹脂発泡成形体を型内発泡成形によって製造する型内発泡成形方法に関し、特に、加熱媒体として使用する蒸気の使用量を従来方法よりも低減可能な型内発泡成形方法に関する。   The present invention relates to an in-mold foam molding method for producing a thermoplastic resin foam molded body such as a polystyrene-based resin foam molded body by in-mold foam molding, and in particular, reduces the amount of steam used as a heating medium compared to conventional methods. The present invention relates to a possible in-mold foam molding method.

1…成形装置、2…凹型、3…凸型、4…成形型、5…凹型本体、6…フレーム、7…凸型本体、8…フレーム、9…キャビティ、10,11…蒸気室、12…凹型側調圧蒸気弁、13…凹型側ドレン弁、14,19…真空弁、15,20…冷却水弁、16,21…圧力計、17…凸型側調圧蒸気弁、18…凸型側ドレン弁、22…蒸気供給管路、23…蒸気主管、24…蒸気減圧弁、25…オリフィス型蒸気流量計、26…表示部、27…凹型側バイパス管路、28…凸型側バイパス管路、29…凹型側バイパス蒸気弁、30…凸型側バイパス蒸気弁。   DESCRIPTION OF SYMBOLS 1 ... Molding apparatus, 2 ... Concave mold, 3 ... Convex mold, 4 ... Mold, 5 ... Concave body, 6 ... Frame, 7 ... Convex mold body, 8 ... Frame, 9 ... Cavity, 10, 11 ... Steam chamber, 12 ... concave side pressure regulating steam valve, 13 ... concave side drain valve, 14, 19 ... vacuum valve, 15, 20 ... cooling water valve, 16, 21 ... pressure gauge, 17 ... convex side pressure regulating steam valve, 18 ... convex Die side drain valve, 22 ... Steam supply pipe, 23 ... Steam main pipe, 24 ... Steam pressure reducing valve, 25 ... Orifice type steam flow meter, 26 ... Display section, 27 ... Concave side bypass pipe, 28 ... Convex side bypass Pipe line, 29 ... concave side bypass steam valve, 30 ... convex side bypass steam valve.

Claims (4)

蒸気が流通可能な第1の型と第2の型とを合わせ、それぞれの型間に所望形状のキャビティを有するとともに、それぞれの型に、蒸気弁を開いた時に該型に蒸気が供給される蒸気供給管路とドレン弁を開いた時に該型内から流体を排出するドレン管路とが設けられた成形型の該キャビティ内に、熱可塑性樹脂予備発泡粒子を充填した後、次の各加熱工程(a)〜(e)、
(a)成形型に蒸気を流す成形型加熱工程、
(b)次いで、第1の型側から第2の型側に蒸気を流す一方加熱工程、
(c)次いで、第2の型側から第1の型側に蒸気を流す逆一方加熱工程、
(d)次いで、両方の型に蒸気を流して成形型を加熱する両面加熱工程、
(e)次いで、保持された蒸気で成形型内を保熱する保熱工程を行い、次いで成形型を冷却し、発泡樹脂成形体を成形型から取り出す型内発泡成形方法において、
前記(c)逆一方加熱工程を、第1の型側と第2の型側の両方のドレン弁を閉じた状態で行うことを特徴とする型内発泡成形方法。
The first mold and the second mold through which steam can flow are combined, each has a cavity of a desired shape, and steam is supplied to each mold when the steam valve is opened. After filling the cavity of the mold provided with a steam supply line and a drain line for discharging a fluid from the mold when the drain valve is opened, each of the following heating Steps (a) to (e),
(A) a mold heating step in which steam flows through the mold;
(B) Next, a heating step while flowing steam from the first mold side to the second mold side,
(C) Next, a reverse one-side heating step in which steam flows from the second mold side to the first mold side,
(D) Next, a double-sided heating step in which steam is passed through both molds to heat the mold,
(E) Next, in the in-mold foam molding method of performing a heat retaining step of retaining the inside of the mold with the retained steam, then cooling the mold and taking out the foamed resin molded body from the mold.
(C) The reverse one-side heating step is performed in a state in which the drain valves on both the first mold side and the second mold side are closed.
前記(b)一方加熱工程における加熱方向を蒸気室容積の小さい方から大きい方に向けて加熱することを特徴とする請求項1に記載の型内発泡成形方法。   2. The in-mold foam molding method according to claim 1, wherein the heating direction in the (b) one heating step is performed from a smaller steam chamber volume to a larger steam chamber volume. 前記(a)成形型加熱工程を、成形型のキャビティに面した表面の温度が100℃以上に達するように行うことを特徴とする請求項1又は2に記載の型内発泡成形方法。   The in-mold foam molding method according to claim 1 or 2, wherein (a) the mold heating step is performed such that the temperature of the surface facing the cavity of the mold reaches 100 ° C or higher. 前記(b)一方加熱工程を、前記蒸気供給管路よりも高圧の蒸気が供給されるバイパス管路から前記成形型内に蒸気を導入して行うことを特徴とする請求項1〜3のいずれか1項に記載の型内発泡成形方法。   The said (b) one-side heating process is performed by introduce | transducing a vapor | steam in the said shaping | molding die from the bypass line to which a high voltage | pressure vapor | steam is supplied rather than the said vapor | steam supply line. The in-mold foam molding method according to claim 1.
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