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JP2011042726A - Circulating fluidized bed type gasification method and apparatus - Google Patents

Circulating fluidized bed type gasification method and apparatus Download PDF

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JP2011042726A
JP2011042726A JP2009191039A JP2009191039A JP2011042726A JP 2011042726 A JP2011042726 A JP 2011042726A JP 2009191039 A JP2009191039 A JP 2009191039A JP 2009191039 A JP2009191039 A JP 2009191039A JP 2011042726 A JP2011042726 A JP 2011042726A
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JP4930732B2 (en
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Masahiro Narikawa
正広 成川
Toshiyuki Suda
俊之 須田
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a circulating fluidized bed type gasification method and apparatus capable of separately performing thermal decomposition and gasification of a material, enhancing the carbon conversion ratio by preventing suppression of a gasification reaction by a thermal decomposition gas and effectively using heat of a combustion exhaust gas. <P>SOLUTION: A flowing medium separated by a medium separation apparatus 8 is returned to a gasification furnace 2 via a thermal decomposition furnace 15, and while the material is heat-exchanged with the combustion exhaust gas in a heat exchanger 14 for thermal decomposition to release a thermal decomposition gas containing a tar, it is fed to the thermal decomposition furnace 15 in which the fluidized bed 15a is formed by an inert gas and is further subjected to thermal decomposition to generate a thermal decomposition gas. The flowing medium containing the material in which the thermal decomposition gas is separated in the thermal decomposition furnace 15 is introduced into the gasification furnace 2, gasification of the material is only performed in the gasification furnace 2, and the flowing medium and an inflammable solid content are introduced into a combustion furnace 5. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、循環流動層式ガス化方法及び装置に関するものである。   The present invention relates to a circulating fluidized bed gasification method and apparatus.

従来より、燃料として、石炭、バイオマス、廃プラスチック、或いは各種の含水廃棄物等の原料を用い、ガス化ガスを生成する循環流動層式ガス化装置の開発が進められている。   2. Description of the Related Art Conventionally, development of a circulating fluidized bed gasifier that generates a gasification gas using raw materials such as coal, biomass, waste plastic, or various hydrated wastes as fuel has been promoted.

図3は従来の循環流動層式ガス化装置の一例を示すものであって、該循環流動層式ガス化装置は、前記原料が投入され且つガス化剤を兼ねる水蒸気等のガス化炉流動用ガスにより流動媒体(硅砂等)の流動層1を形成して前記原料のガス化を行いガス化ガスと可燃性固形分とを生成するガス化炉2と、該ガス化炉2で生成された可燃性固形分が流動媒体と共に抜出ループシール管3を介して導入され且つ空気又は酸素等の燃焼炉流動用ガスにより流動層4を形成して前記可燃性固形分の燃焼を行う燃焼炉5と、該燃焼炉5の燃焼排ガスを抜き出す排ガス配管6途中に設けられ且つ前記燃焼排ガスから流動媒体を分離し該分離した流動媒体を媒体流下管7を介して前記ガス化炉2に供給するサイクロン等の媒体分離装置8とを備えてなる構成を有している。   FIG. 3 shows an example of a conventional circulating fluidized bed type gasifier, and the circulating fluidized bed type gasifier is used for the flow of a gasifier such as water vapor that is charged with the raw material and also serves as a gasifying agent. A gasification furnace 2 for generating a gasified gas and a combustible solid content by gasifying the raw material by forming a fluidized bed 1 of a fluid medium (such as cinnabar) with gas, and the gasification furnace 2 Combustion furnace 5 in which combustible solids are introduced together with a fluid medium through an extraction loop seal tube 3 and fluidized bed 4 is formed by combustion furnace gas such as air or oxygen to burn the combustible solids. And a cyclone provided in the exhaust gas pipe 6 for extracting the combustion exhaust gas from the combustion furnace 5 and separating the fluid medium from the combustion exhaust gas and supplying the separated fluid medium to the gasification furnace 2 through the medium flow pipe 7 And a medium separating device 8 such as It is.

尚、図3中、9は前記原料をガス化炉2に投入する原料投入管、10は前記ガス化炉2の底部に形成されたウインドボックス、11は該ウインドボックス10へ導入されるガス化炉流動用ガスをガス化炉2内部へ均一に吹き込んで流動層1を形成するための多数の散気ノズル(図示せず)を有する散気板、12は前記燃焼炉5の底部に形成されたウインドボックス、13は該ウインドボックス12へ導入される燃焼炉流動用ガスを燃焼炉5内部へ均一に吹き込んで流動層4を形成するための多数の散気ノズル13aを有する散気板である。   In FIG. 3, 9 is a raw material charging pipe for charging the raw material into the gasification furnace 2, 10 is a wind box formed at the bottom of the gasification furnace 2, and 11 is gasification introduced into the wind box 10. A diffuser plate 12 having a large number of diffuser nozzles (not shown) for forming a fluidized bed 1 by uniformly blowing a gas for furnace flow into the gasification furnace 2 is formed at the bottom of the combustion furnace 5. The wind box 13 is a diffuser plate having a large number of diffuser nozzles 13a for uniformly blowing the combustion furnace flowing gas introduced into the wind box 12 into the combustion furnace 5 to form the fluidized bed 4. .

又、前記媒体流下管7の途中にはループシール部7aが形成され、前記ガス化炉2で生成されたガス化ガスが媒体分離装置8へ逆流しないようにしてある。   Further, a loop seal portion 7 a is formed in the middle of the medium flow down pipe 7 so that the gasified gas generated in the gasification furnace 2 does not flow backward to the medium separation device 8.

前述の如き循環流動層式ガス化装置においては、通常運転時、ガス化炉2において、ガス化剤を兼ねる水蒸気等のガス化炉流動用ガスによりウインドボックス10の散気板11上に流動層1が形成されており、ここに原料投入管9から石炭等の原料を投入すると、該原料はガス化され、ガス化ガスと可燃性固形分とが生成され、前記ガス化炉2で生成された可燃性固形分は流動媒体と共に抜出ループシール管3を介し抜き出されて、前記燃焼炉流動用ガスによりウインドボックス12の散気板13上に流動層4が形成されている燃焼炉5へ導入され、該可燃性固形分の燃焼が行われ、該燃焼炉5からの燃焼排ガスは、排ガス配管6を介して媒体分離装置8へ導入され、該媒体分離装置8において、前記燃焼排ガスから流動媒体が分離され、該分離された流動媒体は媒体流下管7を介して前記ガス化炉2に戻され、循環される。   In the circulating fluidized bed type gasifier as described above, the fluidized bed is formed on the diffuser plate 11 of the wind box 10 by the gasifying furnace flowing gas such as water vapor which also serves as a gasifying agent in the gasifying furnace 2 during normal operation. 1 is formed, and when a raw material such as coal is input from the raw material input pipe 9, the raw material is gasified, and a gasified gas and a combustible solid are generated and generated in the gasification furnace 2. The combustible solid content is extracted together with the fluid medium through the extraction loop seal tube 3, and the combustion furnace 5 in which the fluidized bed 4 is formed on the diffuser plate 13 of the wind box 12 by the combustion furnace flow gas. The combustible solid content is combusted, and the combustion exhaust gas from the combustion furnace 5 is introduced into the medium separation device 8 via the exhaust gas pipe 6. The fluid medium is separated and the Isolated fluidized medium is returned through a medium flow down tube 7 to the gasification furnace 2, it is circulated.

ここで、前記燃焼炉5で可燃性固形分の燃焼に伴い高温になった流動媒体が燃焼排ガスと共に排ガス配管6を通り前記媒体分離装置8で分離され、前記媒体流下管7を介してガス化炉2に供給されることにより、ガス化炉2の高温が保持されると共に、原料の熱分解によって生成したガスや、その熱分解残渣(チャー)が水蒸気と反応することによって、水蒸気ガス化反応[C+H2O=H2+CO]や水素転換反応[CO+H2O=H2+CO2]が起こり、H2やCO等の可燃性のガス化ガスが生成される。 Here, the fluidized medium that has become high in temperature due to the combustion of combustible solids in the combustion furnace 5 is separated together with the combustion exhaust gas through the exhaust gas pipe 6 by the medium separation device 8, and is gasified through the medium flow down pipe 7. By supplying to the furnace 2, the high temperature of the gasification furnace 2 is maintained, and the gas generated by the thermal decomposition of the raw material and its thermal decomposition residue (char) react with the water vapor, thereby causing the water vapor gasification reaction. [C + H 2 O = H 2 + CO] and hydrogen conversion reaction [CO + H 2 O = H 2 + CO 2 ] occur, and combustible gasification gas such as H 2 and CO is generated.

前記ガス化炉2で生成されたガス化ガスは、図示していないサイクロン等の媒体分離装置で煤塵等が分離除去された後、化学プラント或いはガスタービン等に供給される一方、前記媒体分離装置8で流動媒体が分離された燃焼排ガスは、排ガス処理装置へ送られる。   The gasification gas generated in the gasification furnace 2 is supplied to a chemical plant or a gas turbine after the dust and the like are separated and removed by a medium separation device such as a cyclone (not shown), while the medium separation device The combustion exhaust gas from which the fluid medium is separated in 8 is sent to the exhaust gas treatment device.

因みに、前記循環流動層式ガス化装置における通常運転中の熱量不足時、即ち前記ガス化炉2において原料のガス化のための充分な熱が得られないような場合には、前記ガス化炉2へ供給される原料と同じ石炭等の燃料が補助的に前記燃焼炉5へ投入されて燃焼が行われ、不足する熱を補うようになっている。又、前記循環流動層式ガス化装置における通常運転に到る前段階での循環予熱運転時には、前記ガス化炉2への原料の投入は行わずに、該ガス化炉2の底部から水蒸気の代わりに流動用の空気を供給した状態で、前記石炭等の燃料が予熱用として前記燃焼炉5へ投入されて燃焼が行われ、該燃焼炉5での燃料の燃焼に伴い高温になった流動媒体が燃焼排ガスと共に排ガス配管6を通り前記媒体分離装置8で分離され、前記媒体流下管7を介してガス化炉2に供給されることにより、循環流動層式ガス化装置の循環予熱が行われるようになっている。   Incidentally, when the heat quantity during normal operation in the circulating fluidized bed gasifier is insufficient, that is, when the gasifier 2 cannot obtain sufficient heat for gasification of the raw material, the gasifier A fuel such as coal that is the same as the raw material supplied to 2 is supplied to the combustion furnace 5 in an auxiliary manner and burned to make up for the insufficient heat. In addition, during the circulation preheating operation in the stage before reaching the normal operation in the circulating fluidized bed gasifier, the raw material is not charged into the gasification furnace 2, and water vapor is supplied from the bottom of the gasification furnace 2. Instead, with the flow air supplied, the fuel such as coal is charged into the combustion furnace 5 for preheating and combusted, and the flow becomes high as the fuel burns in the combustion furnace 5. The medium is separated together with the combustion exhaust gas by the medium separation device 8 through the exhaust gas pipe 6 and supplied to the gasification furnace 2 through the medium flow pipe 7, whereby circulation preheating of the circulating fluidized bed gasification device is performed. It has come to be.

尚、前述の如き循環流動層式ガス化装置と関連する一般的技術水準を示すものとしては、例えば、特許文献1、2、3がある。   Examples of the general technical level related to the circulating fluidized bed gasifier as described above include Patent Documents 1, 2, and 3.

特開平3−287695号公報JP-A-3-287695 特開2006−265454号公報JP 2006-265454 A 特開2007−112872号公報JP 2007-112872 A

ところで、前述の如き循環流動層式ガス化装置の場合、石炭やバイオマス等の有機物原料の低温水蒸気ガス化反応(700〜900[℃])では、タールを含む熱分解ガスにより、可燃性固形分としての熱分解残渣(チャー)の水蒸気ガス化反応が阻害されるため、水蒸気ガス化反応から熱分解ガスを分離することが望まれる。   By the way, in the case of the circulating fluidized bed type gasifier as described above, in the low-temperature steam gasification reaction (700 to 900 [° C.]) of organic raw materials such as coal and biomass, combustible solid content is generated by pyrolysis gas containing tar. Therefore, it is desired to separate the pyrolysis gas from the steam gasification reaction.

因みに、熱分解残渣(チャー)の水蒸気ガス化反応が阻害されると、反応時間が長く必要となることから、その分、製品としての同じ量のガス化ガスを得るためには、ガス化炉2を長大化すると共に、ガス化剤を兼ねる水蒸気等のガス化炉流動用ガスの供給量を増加する必要が生じ、好ましくない。   Incidentally, if the steam gasification reaction of the pyrolysis residue (char) is hindered, a longer reaction time is required. Therefore, in order to obtain the same amount of gasification gas as a product, the gasification furnace It is necessary to increase the length of 2 and increase the amount of gasification furnace flow gas such as water vapor that also serves as a gasifying agent.

又、前記媒体分離装置8で流動媒体が分離された燃焼排ガスは、単に排ガス処理装置へ送られるのみで熱回収が充分に行われているとは言えなかった。   Further, the combustion exhaust gas from which the fluid medium has been separated by the medium separation device 8 is simply sent to the exhaust gas treatment device, and it cannot be said that heat recovery is sufficiently performed.

そして、流動層を用いた熱分解ガス化装置は前記特許文献1、2、3に開示されているが、次のような問題点があった。   And although the thermal decomposition gasification apparatus using a fluidized bed is disclosed by the said patent documents 1, 2, and 3, there existed the following problems.

前記特許文献1に開示されている石炭の熱分解・ガス化法においては、燃料として微粉炭しか使用できないため、バイオマス等の有機物原料が使用できず、又、一部の未反応チャーがガス化炉底部から排出されるため、炭素転化率が低くなる可能性があった。   In the coal pyrolysis and gasification method disclosed in Patent Document 1, since only pulverized coal can be used as fuel, organic materials such as biomass cannot be used, and some unreacted char is gasified. Since it is discharged from the bottom of the furnace, the carbon conversion rate may be lowered.

前記特許文献2に開示されている循環流動式ガス化炉においては、ガス化部であるダウンカマーの上部のサイクロン出口からガス化ガスが排出されるので、熱媒体である流動砂の循環速度が低くなり、放熱が大きくなる一方、足りない熱量は熱風炉バーナで補われるため、コストが高くなる可能性があった。   In the circulating fluidized gasification furnace disclosed in Patent Document 2, since the gasified gas is discharged from the cyclone outlet at the top of the downcomer that is the gasification section, the circulation speed of the fluidized sand that is the heat medium is high. While lowering and increasing heat dissipation, the lack of heat is compensated by the hot stove burner, which may increase the cost.

前記特許文献3に開示されている燃料ガス化設備においては、ガス化反応から熱分解ガスを分離していないので、ガス化反応が阻害され炭素転化率が低くなる可能性があった。   In the fuel gasification facility disclosed in Patent Document 3, since the pyrolysis gas is not separated from the gasification reaction, the gasification reaction may be hindered and the carbon conversion rate may be lowered.

本発明は、斯かる実情に鑑み、原料の熱分解とガス化を分離して行うことができ、熱分解ガスによるガス化反応の阻害を防いで炭素転化率を向上し得、且つ燃焼排ガスの熱を有効活用し得る循環流動層式ガス化方法及び装置を提供しようとするものである。   In view of such circumstances, the present invention can separate the pyrolysis and gasification of the raw material, can prevent the gasification reaction by the pyrolysis gas, improve the carbon conversion rate, and It is an object of the present invention to provide a circulating fluidized bed gasification method and apparatus capable of effectively utilizing heat.

本発明は、ガス化炉でガス化剤を兼ねるガス化炉流動用ガスにより流動媒体の流動層を形成して原料のガス化を行いガス化ガスと可燃性固形分とを生成し、該ガス化炉で生成されたガス化ガスを取り出す一方、前記ガス化炉で生成された可燃性固形分を流動媒体と共にガス化炉から燃焼炉へ導入し且つ該燃焼炉で燃焼炉流動用ガスにより流動層を形成して前記可燃性固形分の燃焼を行いつつ該燃焼炉の燃焼排ガスから媒体分離装置で流動媒体を分離し該分離した流動媒体を前記ガス化炉に戻す循環流動層式ガス化方法において、
前記媒体分離装置で分離された流動媒体を熱分解炉を経由して前記ガス化炉へ戻すと共に、
前記原料を熱分解用熱交換器で前記燃焼排ガスと熱交換させてタールを含む熱分解ガスを放出させつつ、不活性ガスにより流動層が形成されている熱分解炉へ投入し更に熱分解させて熱分解ガスを発生させ、
前記熱分解炉で熱分解ガスが分離された原料を含む流動媒体を前記ガス化炉へ導入し、該ガス化炉で前記原料のガス化のみを行わせ、流動媒体と可燃性固形分とを前記燃焼炉へ導入することを特徴とする循環流動層式ガス化方法にかかるものである。
The present invention forms a fluidized bed of a fluidized medium by a gasification furnace fluidizing gas that also serves as a gasifying agent in a gasification furnace to gasify a raw material to generate a gasification gas and a combustible solid content. While the gasification gas generated in the gasification furnace is taken out, the combustible solid content generated in the gasification furnace is introduced into the combustion furnace from the gasification furnace together with the fluidized medium, and flows in the combustion furnace with the gas for flowing the combustion furnace. A circulating fluidized bed gasification method in which a fluidized medium is separated from a combustion exhaust gas of the combustion furnace by a medium separation device and the separated fluidized medium is returned to the gasification furnace while forming a layer and burning the combustible solid content. In
Returning the fluid medium separated by the medium separator to the gasification furnace via a pyrolysis furnace,
The raw material is heat-exchanged with the combustion exhaust gas by a heat decomposition heat exchanger to release a pyrolysis gas containing tar, and is put into a pyrolysis furnace in which a fluidized bed is formed with an inert gas and further pyrolyzed. To generate pyrolysis gas,
A fluid medium containing a raw material from which pyrolysis gas has been separated in the pyrolysis furnace is introduced into the gasification furnace, and only the raw material is gasified in the gasification furnace, and the fluid medium and combustible solids are obtained. The present invention relates to a circulating fluidized bed gasification method which is introduced into the combustion furnace.

又、本発明は、ガス化炉でガス化剤を兼ねるガス化炉流動用ガスにより流動媒体の流動層を形成して原料のガス化を行いガス化ガスと可燃性固形分とを生成し、該ガス化炉で生成されたガス化ガスを取り出す一方、前記ガス化炉で生成された可燃性固形分を流動媒体と共にガス化炉から燃焼炉へ導入し且つ該燃焼炉で燃焼炉流動用ガスにより流動層を形成して前記可燃性固形分の燃焼を行いつつ該燃焼炉の燃焼排ガスから媒体分離装置で流動媒体を分離し該分離した流動媒体を前記ガス化炉に戻す循環流動層式ガス化方法において、
前記媒体分離装置で分離された流動媒体を熱分解炉を経由して前記ガス化炉へ戻すと共に、
前記原料を不活性ガスにより流動層が形成されている熱分解炉へ投入し熱分解させて熱分解ガスを発生させ、該熱分解ガスをタール分解用熱交換器で前記燃焼排ガスと熱交換させてタールを分解し、
前記熱分解炉で熱分解ガスが分離された原料を含む流動媒体を前記ガス化炉へ導入し、該ガス化炉で前記原料のガス化のみを行わせ、流動媒体と可燃性固形分とを前記燃焼炉へ導入することを特徴とする循環流動層式ガス化方法にかかるものである。
Further, the present invention forms a fluidized bed of a fluidized medium by a gasification furnace fluidizing gas that also serves as a gasifying agent in a gasification furnace to gasify the raw material to produce a gasification gas and a combustible solid content, While taking out the gasification gas generated in the gasification furnace, the combustible solid content generated in the gasification furnace is introduced into the combustion furnace from the gasification furnace together with the fluidized medium, and the combustion furnace flowing gas in the combustion furnace A circulating fluidized bed gas for separating the fluidized medium from the combustion exhaust gas of the combustion furnace with a medium separation device and returning the separated fluidized medium to the gasification furnace while forming a fluidized bed by burning the combustible solids In the conversion method,
Returning the fluid medium separated by the medium separator to the gasification furnace via a pyrolysis furnace,
The raw material is put into a pyrolysis furnace in which a fluidized bed is formed with an inert gas, pyrolyzed to generate pyrolysis gas, and the pyrolysis gas is heat exchanged with the combustion exhaust gas in a tar decomposition heat exchanger. Break down tar,
A fluid medium containing a raw material from which pyrolysis gas has been separated in the pyrolysis furnace is introduced into the gasification furnace, and only the raw material is gasified in the gasification furnace, and the fluid medium and combustible solids are obtained. The present invention relates to a circulating fluidized bed gasification method which is introduced into the combustion furnace.

一方、本発明は、ガス化剤を兼ねるガス化炉流動用ガスにより流動媒体の流動層を形成して原料のガス化を行いガス化ガスと可燃性固形分とを生成するガス化炉と、該ガス化炉で生成された可燃性固形分が流動媒体と共に導入され且つ燃焼炉流動用ガスにより流動層を形成して前記可燃性固形分の燃焼を行う燃焼炉と、該燃焼炉の燃焼排ガスから流動媒体を分離し該分離した流動媒体を前記ガス化炉に戻す媒体分離装置とを備えた循環流動層式ガス化装置において、
前記原料を前記燃焼排ガスと熱交換させてタールを含む熱分解ガスを放出させる熱分解用熱交換器と、
前記媒体分離装置で分離された流動媒体が導入され、不活性ガスにより流動層を形成し、該流動層で前記熱分解用熱交換器を通過した原料を更に熱分解させて熱分解ガスを発生させ、該熱分解ガスが分離された原料と流動媒体とを前記ガス化炉へ導く熱分解炉と
を備えたことを特徴とする循環流動層式ガス化装置にかかるものである。
On the other hand, the present invention comprises a gasification furnace that forms a fluidized bed of a fluidized medium by a gasification fluidizing gas that also serves as a gasifying agent to gasify a raw material to generate gasified gas and combustible solids, Combustion furnace in which combustible solids generated in the gasification furnace are introduced together with a fluidized medium and a fluidized bed is formed by a combustion furnace flow gas to burn the combustible solids, and combustion exhaust gas from the combustion furnace In a circulating fluidized bed type gasifier comprising a medium separator for separating the fluid medium from the medium and returning the separated fluid medium to the gasification furnace,
A heat exchanger for thermal decomposition, in which the raw material is subjected to heat exchange with the combustion exhaust gas to release pyrolysis gas containing tar;
The fluidized medium separated by the medium separator is introduced, a fluidized bed is formed with an inert gas, and the raw material that has passed through the heat exchanger for thermal decomposition is further pyrolyzed in the fluidized bed to generate a pyrolytic gas. And a pyrolysis furnace for introducing the raw material from which the pyrolysis gas has been separated and the fluidized medium to the gasification furnace.

前記循環流動層式ガス化装置においては、内管と外管とを同芯状に配設してなり、原料が内管内に導入されると共に、前記媒体分離装置で分離された燃焼炉からの燃焼排ガスが内管と外管との間に導入される二重管式熱交換器によって、前記熱分解用熱交換器を構成することができる。   In the circulating fluidized bed type gasifier, the inner pipe and the outer pipe are arranged concentrically, and the raw material is introduced into the inner pipe and from the combustion furnace separated by the medium separator. The heat exchanger for thermal decomposition can be constituted by a double pipe heat exchanger in which combustion exhaust gas is introduced between the inner pipe and the outer pipe.

又、本発明は、ガス化剤を兼ねるガス化炉流動用ガスにより流動媒体の流動層を形成して原料のガス化を行いガス化ガスと可燃性固形分とを生成するガス化炉と、該ガス化炉で生成された可燃性固形分が流動媒体と共に導入され且つ燃焼炉流動用ガスにより流動層を形成して前記可燃性固形分の燃焼を行う燃焼炉と、該燃焼炉の燃焼排ガスから流動媒体を分離し該分離した流動媒体を前記ガス化炉に戻す媒体分離装置とを備えた循環流動層式ガス化装置において、
前記媒体分離装置で分離された流動媒体が導入され、不活性ガスにより流動層を形成し、該流動層で投入される原料を熱分解させて熱分解ガスを発生させ、該熱分解ガスが分離された原料と流動媒体とを前記ガス化炉へ導く熱分解炉と、
該熱分解炉で発生した熱分解ガスを前記燃焼排ガスと熱交換させてタールを分解するタール分解用熱交換器と
を備えたことを特徴とする循環流動層式ガス化装置にかかるものである。
The present invention also includes a gasification furnace that forms a fluidized bed of a fluidized medium by a gasification fluidizing gas that also serves as a gasifying agent to gasify a raw material to generate a gasified gas and a combustible solid. Combustion furnace in which combustible solids generated in the gasification furnace are introduced together with a fluidized medium and a fluidized bed is formed by a combustion furnace flow gas to burn the combustible solids, and combustion exhaust gas from the combustion furnace In a circulating fluidized bed type gasifier comprising a medium separator for separating the fluid medium from the medium and returning the separated fluid medium to the gasification furnace,
The fluidized medium separated by the medium separator is introduced, a fluidized bed is formed with an inert gas, the raw material charged in the fluidized bed is pyrolyzed to generate a pyrolyzed gas, and the pyrolyzed gas is separated. A pyrolysis furnace for guiding the raw material and the fluidized medium to the gasification furnace;
The present invention relates to a circulating fluidized bed gasifier comprising a tar decomposition heat exchanger that decomposes tar by heat-exchanging pyrolysis gas generated in the pyrolysis furnace with the combustion exhaust gas. .

前記循環流動層式ガス化装置においては、内管と外管とを同芯状に配設してなり、前記熱分解炉で発生した熱分解ガスが内管内に導入されると共に、前記媒体分離装置で分離された燃焼炉からの燃焼排ガスが内管と外管との間に導入される二重管式熱交換器によって、前記タール分解用熱交換器を構成することができる。   In the circulating fluidized bed type gasifier, an inner tube and an outer tube are arranged concentrically, and pyrolysis gas generated in the pyrolysis furnace is introduced into the inner tube, and the medium separation is performed. The tar decomposition heat exchanger can be configured by a double pipe heat exchanger in which the flue gas from the combustion furnace separated by the apparatus is introduced between the inner pipe and the outer pipe.

本発明の循環流動層式ガス化方法及び装置によれば、原料の熱分解とガス化を分離して行うことができ、熱分解ガスによるガス化反応の阻害を防いで炭素転化率を向上し得、且つ燃焼排ガスの熱を有効活用し得るという優れた効果を奏し得る。   According to the circulating fluidized bed gasification method and apparatus of the present invention, the pyrolysis and gasification of the raw material can be performed separately, and the carbon conversion rate is improved by preventing the gasification reaction by the pyrolysis gas. And an excellent effect that the heat of the combustion exhaust gas can be effectively utilized.

本発明の第一実施例を示す全体概要構成図である。1 is an overall schematic configuration diagram showing a first embodiment of the present invention. 本発明の第二実施例を示す全体概要構成図である。It is a whole schematic block diagram which shows the 2nd Example of this invention. 従来の循環流動層式ガス化装置の一例を示す全体概要構成図である。It is a whole schematic block diagram which shows an example of the conventional circulating fluidized-bed type gasifier.

以下、本発明の実施の形態を添付図面を参照して説明する。   Embodiments of the present invention will be described below with reference to the accompanying drawings.

図1は本発明の第一実施例であって、図中、図3と同一の符号を付した部分は同一物を表わしており、基本的な構成は図3に示す従来のものと同様であるが、本第一実施例の特徴とするところは、図1に示す如く、原料を媒体分離装置8で分離された燃焼炉5からの燃焼排ガスと熱交換させてタールを含む熱分解ガスを放出させる熱分解用熱交換器14と、
前記媒体分離装置8で分離された流動媒体が媒体流下管7により導入され、不活性ガスにより流動層15aを形成し、該流動層15aで前記熱分解用熱交換器14を通過した原料を更に熱分解させて熱分解ガスを発生させ、該熱分解ガスが分離された原料と流動媒体とをオーバーフロー管16を介してガス化炉2へ導く熱分解炉15と
を追加装備した点にある。
FIG. 1 shows a first embodiment of the present invention. In the figure, the same reference numerals as those in FIG. 3 denote the same parts, and the basic configuration is the same as the conventional one shown in FIG. However, the feature of the first embodiment is that, as shown in FIG. 1, the raw material is subjected to heat exchange with the combustion exhaust gas from the combustion furnace 5 separated by the medium separation device 8 to produce pyrolysis gas containing tar. A heat exchanger 14 for pyrolysis to be discharged;
The fluid medium separated by the medium separator 8 is introduced by the medium flow pipe 7, and a fluidized bed 15a is formed by an inert gas. The raw material that has passed through the thermal decomposition heat exchanger 14 is further passed through the fluidized bed 15a. A pyrolysis furnace 15 is additionally provided which generates pyrolysis gas by pyrolysis and guides the raw material from which the pyrolysis gas has been separated and the fluidized medium to the gasification furnace 2 through the overflow pipe 16.

本第一実施例の場合、前記熱分解用熱交換器14は、内管14aと外管14bとを同芯状に配設してなり、原料が内管14a内に導入されると共に、前記媒体分離装置8で分離された燃焼炉5からの燃焼排ガスが内管14aと外管14bとの間に導入される二重管式熱交換器によって構成してある。尚、前記熱分解用熱交換器14は、二重管の周りに蓄熱材(図示せず)を設けることにより、保温するようにしてある。   In the case of the first embodiment, the thermal decomposition heat exchanger 14 has an inner tube 14a and an outer tube 14b arranged concentrically, and a raw material is introduced into the inner tube 14a. Combustion exhaust gas from the combustion furnace 5 separated by the medium separator 8 is constituted by a double tube heat exchanger in which the flue gas is introduced between the inner tube 14a and the outer tube 14b. The thermal decomposition heat exchanger 14 is kept warm by providing a heat storage material (not shown) around the double pipe.

又、前記熱分解炉15の底部には、前記ガス化炉2と同様のウインドボックス17を形成すると共に、該ウインドボックス17に導入される窒素等の不活性ガスを熱分解炉15内部へ均一に吹き込んで流動層15aを形成するための多数の散気ノズル(図示せず)を有する散気板18を設け、前記熱分解炉15の側部には、前記熱分解用熱交換器14を通過した原料を投入するための原料投入管9を接続してある。   In addition, a wind box 17 similar to the gasification furnace 2 is formed at the bottom of the pyrolysis furnace 15 and an inert gas such as nitrogen introduced into the wind box 17 is uniformly introduced into the pyrolysis furnace 15. A diffuser plate 18 having a large number of diffuser nozzles (not shown) for forming a fluidized bed 15a by being blown into the thermal decomposition furnace 15 is provided, and the thermal decomposition heat exchanger 14 is provided at the side of the thermal decomposition furnace 15. A raw material input pipe 9 for supplying the passed raw material is connected.

次に、上記第一実施例の作用を説明する。   Next, the operation of the first embodiment will be described.

前記媒体分離装置8で分離された流動媒体は、媒体流下管7により熱分解炉15に導入され、該熱分解炉15の流動層15aからオーバーフロー管16を介してガス化炉2へ戻される形となる。   The fluid medium separated by the medium separator 8 is introduced into the pyrolysis furnace 15 by the medium flow down pipe 7 and returned to the gasification furnace 2 from the fluidized bed 15a of the pyrolysis furnace 15 through the overflow pipe 16. It becomes.

同時に、原料は、前記媒体分離装置8で分離された燃焼炉5からの燃焼排ガスが内管14aと外管14bとの間に導入されている熱分解用熱交換器14の内管14a内に導入され、該熱分解用熱交換器14において、前記媒体分離装置8で分離された燃焼炉5からの燃焼排ガスと熱交換してタールを含む熱分解ガスを放出しつつ、可燃性固形分としての熱分解残渣(チャー)を含んだ形で、原料投入管9から熱分解炉15へ投入される。又、前記原料と熱交換することにより熱回収された燃焼排ガスは排ガス処理装置へ送られる。   At the same time, the raw material is introduced into the inner pipe 14a of the thermal decomposition heat exchanger 14 in which the combustion exhaust gas from the combustion furnace 5 separated by the medium separator 8 is introduced between the inner pipe 14a and the outer pipe 14b. In the pyrolysis heat exchanger 14, the heat exchange with the combustion exhaust gas from the combustion furnace 5 separated by the medium separation device 8 exchanges heat to release the pyrolysis gas containing tar, and as a combustible solid content. The pyrolysis residue (char) is introduced into the pyrolysis furnace 15 from the raw material input tube 9. The combustion exhaust gas heat-recovered by exchanging heat with the raw material is sent to an exhaust gas treatment device.

ここで、前記熱分解炉15の内部には、ウインドボックス17に導入され且つ散気板18の多数の散気ノズル(図示せず)から吹き出される窒素等の不活性ガスにより流動層15aが形成されており、前記原料投入管9から熱分解炉15へ投入された前記可燃性固形分としての熱分解残渣(チャー)を含む原料は、更に熱分解されて熱分解ガスを発生する。   Here, in the pyrolysis furnace 15, a fluidized bed 15 a is introduced by an inert gas such as nitrogen introduced into the wind box 17 and blown out from a number of diffuser nozzles (not shown) of the diffuser plate 18. The formed raw material containing the pyrolysis residue (char) as the combustible solid content introduced into the pyrolysis furnace 15 from the raw material input pipe 9 is further pyrolyzed to generate pyrolysis gas.

前記熱分解炉15で熱分解ガスが分離された原料を含む流動媒体は、オーバーフロー管16を介して前記ガス化炉2へ導入され、該ガス化炉2で前記原料のガス化のみが行われ、流動媒体と可燃性固形分(チャーを含むガス化残渣)とが抜出ループシール管3を介して前記燃焼炉5へ導入され、該燃焼炉5で可燃性固形分の燃焼により流動媒体が昇温し、高温となった流動媒体が循環される。   The fluid medium containing the raw material from which the pyrolysis gas has been separated in the pyrolysis furnace 15 is introduced into the gasification furnace 2 through the overflow pipe 16, and only the raw material is gasified in the gasification furnace 2. The fluid medium and the combustible solid content (gasification residue containing char) are introduced into the combustion furnace 5 through the extraction loop seal pipe 3, and the fluid medium is burned by the combustion of the combustible solid content in the combustion furnace 5. The fluidized medium is heated and circulated.

尚、前記熱分解炉15は、ガス化ガスと熱分解ガスをシールする役割をも果たしている。又、熱分解ガスは、燃焼炉5(或いは図示していない蒸気生成装置等)の補助燃料として使用することが可能となる。   The pyrolysis furnace 15 also serves to seal the gasification gas and the pyrolysis gas. In addition, the pyrolysis gas can be used as an auxiliary fuel for the combustion furnace 5 (or a steam generator not shown).

この結果、ガス化剤を兼ねるガス化炉流動用ガスを水蒸気とした場合であっても、タールを含む熱分解ガスは熱分解炉15で原料から分離された後にガス化炉2へ導入されるため、該ガス化炉2において、前記熱分解ガスにより可燃性固形分としての熱分解残渣(チャー)の水蒸気ガス化反応が阻害されることが避けられ、炭素転化率を高めることが可能となる。しかも、前記媒体分離装置8で流動媒体が分離された燃焼排ガスの熱は、原料の熱分解に有効に活用されることとなる。   As a result, even when the gasification furnace flowing gas that also serves as the gasifying agent is steam, the pyrolysis gas containing tar is introduced into the gasification furnace 2 after being separated from the raw material in the pyrolysis furnace 15. Therefore, in the gasification furnace 2, it is possible to avoid the steam gasification reaction of the pyrolysis residue (char) as combustible solid content by the pyrolysis gas, and to increase the carbon conversion rate. . Moreover, the heat of the combustion exhaust gas from which the fluid medium has been separated by the medium separation device 8 is effectively utilized for the thermal decomposition of the raw material.

こうして、原料の熱分解とガス化を分離して行うことができ、熱分解ガスによるガス化反応の阻害を防いで炭素転化率を向上し得、且つ燃焼排ガスの熱を有効活用し得る。   Thus, the pyrolysis and gasification of the raw material can be performed separately, the gasification reaction by the pyrolysis gas can be prevented, the carbon conversion rate can be improved, and the heat of the combustion exhaust gas can be effectively utilized.

図2は本発明の第二実施例であって、図中、図3と同一の符号を付した部分は同一物を表わしており、基本的な構成は図3に示す従来のものと同様であるが、本第二実施例の特徴とするところは、図2に示す如く、媒体分離装置8で分離された流動媒体が媒体流下管7により導入され、ウインドボックス17に導入され且つ散気板18の多数の散気ノズル(図示せず)から吹き出される窒素等の不活性ガスにより流動層15aを形成し、該流動層15aで原料投入管9から投入される原料を熱分解させて熱分解ガスを発生させ、該熱分解ガスが分離された原料と流動媒体とをオーバーフロー管16を介してガス化炉2へ導く熱分解炉15と、
該熱分解炉15で発生した熱分解ガスを前記媒体分離装置8で分離された燃焼炉5からの燃焼排ガスと熱交換させてタールを分解するタール分解用熱交換器19と
を追加装備した点にある。
FIG. 2 shows a second embodiment of the present invention. In the figure, the same reference numerals as those in FIG. 3 denote the same parts, and the basic configuration is the same as the conventional one shown in FIG. However, the second embodiment is characterized in that, as shown in FIG. 2, the fluid medium separated by the medium separator 8 is introduced by the medium flow down pipe 7, introduced into the wind box 17, and the diffuser plate. A fluidized bed 15a is formed by an inert gas such as nitrogen blown out from a large number of 18 aeration nozzles (not shown), and the raw material introduced from the raw material introduction pipe 9 is thermally decomposed and heated by the fluidized bed 15a. A pyrolysis furnace 15 that generates cracked gas and guides the raw material and the fluidized medium from which the pyrolyzed gas is separated to the gasification furnace 2 through the overflow pipe 16;
And a tar-decomposing heat exchanger 19 for decomposing tar by heat-exchanging the pyrolysis gas generated in the pyrolysis furnace 15 with the combustion exhaust gas from the combustion furnace 5 separated by the medium separator 8. It is in.

本第二実施例の場合、前記タール分解用熱交換器19は、内管19aと外管19bとを同芯状に配設してなり、前記熱分解炉15で発生した熱分解ガスが内管19a内に導入されると共に、前記媒体分離装置8で分離された燃焼炉5からの燃焼排ガスが内管19aと外管19bとの間に導入される二重管式熱交換器によって構成してある。尚、前記タール分解用熱交換器19は、二重管の周りに蓄熱材(図示せず)を設けることにより、保温するようにしてある。   In the case of the second embodiment, the tar decomposition heat exchanger 19 has an inner tube 19a and an outer tube 19b arranged concentrically, and the pyrolysis gas generated in the pyrolysis furnace 15 is contained inside. In addition to being introduced into the pipe 19a, the exhaust gas from the combustion furnace 5 separated by the medium separator 8 is constituted by a double pipe heat exchanger that is introduced between the inner pipe 19a and the outer pipe 19b. It is. The tar-decomposing heat exchanger 19 is kept warm by providing a heat storage material (not shown) around the double pipe.

次に、上記第二実施例の作用を説明する。   Next, the operation of the second embodiment will be described.

前記媒体分離装置8で分離された流動媒体は、媒体流下管7により熱分解炉15に導入され、該熱分解炉15の流動層15aからオーバーフロー管16を介してガス化炉2へ戻される形となる。   The fluid medium separated by the medium separator 8 is introduced into the pyrolysis furnace 15 by the medium flow down pipe 7 and returned to the gasification furnace 2 from the fluidized bed 15a of the pyrolysis furnace 15 through the overflow pipe 16. It becomes.

同時に、原料は、原料投入管9から熱分解炉15へ投入されるが、該熱分解炉15の内部には、ウインドボックス17に導入され且つ散気板18の多数の散気ノズル(図示せず)から吹き出される窒素等の不活性ガスにより流動層15aが形成されており、前記原料投入管9から熱分解炉15へ投入された原料は、熱分解されて熱分解ガスを発生すると共に、可燃性固形分としての熱分解残渣(チャー)が生成される。   At the same time, the raw material is fed into the pyrolysis furnace 15 from the raw material feed pipe 9. Inside the pyrolysis furnace 15, a large number of diffuser nozzles (not shown) are introduced into the wind box 17 and the diffuser plate 18. The fluidized bed 15a is formed by an inert gas such as nitrogen blown out from the gas), and the raw material charged into the pyrolysis furnace 15 from the raw material charging tube 9 is pyrolyzed to generate pyrolysis gas. A pyrolysis residue (char) is produced as a combustible solid.

前記熱分解炉15で熱分解ガスが分離された原料を含む流動媒体は、オーバーフロー管16を介して前記ガス化炉2へ導入され、該ガス化炉2で前記原料のガス化のみが行われ、流動媒体と可燃性固形分(チャーを含むガス化残渣)とが抜出ループシール管3を介して前記燃焼炉5へ導入され、該燃焼炉5で可燃性固形分の燃焼により流動媒体が昇温し、高温となった流動媒体が循環される。   The fluid medium containing the raw material from which the pyrolysis gas has been separated in the pyrolysis furnace 15 is introduced into the gasification furnace 2 through the overflow pipe 16, and only the raw material is gasified in the gasification furnace 2. The fluid medium and the combustible solid content (gasification residue containing char) are introduced into the combustion furnace 5 through the extraction loop seal pipe 3, and the fluid medium is burned by the combustion of the combustible solid content in the combustion furnace 5. The fluidized medium is heated and circulated.

一方、前記熱分解炉15で発生した熱分解ガスは、前記媒体分離装置8で分離された燃焼炉5からの燃焼排ガスが内管19aと外管19bとの間に導入されているタール分解用熱交換器19の内管19a内に導入され、該タール分解用熱交換器19において、前記媒体分離装置8で分離された燃焼炉5からの燃焼排ガスと熱交換してタールが分解される。ここで、前記熱分解ガス中のタールは凝縮・吸着しやすく、後段の配管・装置等に悪影響を及ぼす可能性があるが、前記熱分解炉15で分離された熱分解ガスは、タール分解用熱交換器19でタールが分解されているため、燃焼炉5(或いは図示していない蒸気生成装置等)の補助燃料として使用可能となる。又、前記熱分解ガスと熱交換することにより熱回収された燃焼排ガスは排ガス処理装置へ送られる。   On the other hand, the pyrolysis gas generated in the pyrolysis furnace 15 is used for tar decomposition in which the combustion exhaust gas from the combustion furnace 5 separated by the medium separator 8 is introduced between the inner pipe 19a and the outer pipe 19b. The tar is decomposed by heat exchange with the combustion exhaust gas from the combustion furnace 5 which is introduced into the inner pipe 19a of the heat exchanger 19 and separated by the medium separation device 8 in the tar decomposition heat exchanger 19. Here, tar in the pyrolysis gas is likely to condense and adsorb, and may adversely affect the piping and equipment in the subsequent stage. However, the pyrolysis gas separated in the pyrolysis furnace 15 is used for tar decomposition. Since tar is decomposed in the heat exchanger 19, it can be used as an auxiliary fuel for the combustion furnace 5 (or a steam generator not shown). The combustion exhaust gas heat-recovered by heat exchange with the pyrolysis gas is sent to an exhaust gas treatment device.

尚、第一実施例の場合と同様、前記熱分解炉15は、ガス化ガスと熱分解ガスをシールする役割をも果たしている。   As in the case of the first embodiment, the pyrolysis furnace 15 also serves to seal the gasification gas and the pyrolysis gas.

この結果、第一実施例の場合と同様、ガス化剤を兼ねるガス化炉流動用ガスを水蒸気とした場合であっても、タールを含む熱分解ガスは熱分解炉15で原料から分離された後にガス化炉2へ導入されるため、該ガス化炉2において、前記熱分解ガスにより可燃性固形分としての熱分解残渣(チャー)の水蒸気ガス化反応が阻害されることが避けられ、炭素転化率を高めることが可能となる。しかも、前記媒体分離装置8で流動媒体が分離された燃焼排ガスの熱は、熱分解ガスに含まれるタールの分解に有効に活用されることとなる。   As a result, the pyrolysis gas containing tar was separated from the raw material in the pyrolysis furnace 15 even when the gasification furnace flowing gas that also serves as the gasifying agent was steam, as in the first embodiment. Since it is introduced later into the gasification furnace 2, it is avoided in the gasification furnace 2 that the pyrolysis gas inhibits the steam gasification reaction of the pyrolysis residue (char) as combustible solids. The conversion rate can be increased. Moreover, the heat of the combustion exhaust gas from which the fluid medium has been separated by the medium separation device 8 is effectively utilized for the decomposition of tar contained in the pyrolysis gas.

こうして、第二実施例においても第一実施例の場合と同様、原料の熱分解とガス化を分離して行うことができ、熱分解ガスによるガス化反応の阻害を防いで炭素転化率を向上し得、且つ燃焼排ガスの熱を有効活用し得る。   Thus, in the second embodiment, as in the case of the first embodiment, the pyrolysis and gasification of the raw material can be performed separately, and the gas conversion reaction by the pyrolysis gas is prevented and the carbon conversion rate is improved. In addition, the heat of the combustion exhaust gas can be effectively used.

尚、本発明の循環流動層式ガス化方法及び装置は、上述の実施例にのみ限定されるものではなく、本発明の要旨を逸脱しない範囲内において種々変更を加え得ることは勿論である。   The circulating fluidized-bed gasification method and apparatus of the present invention are not limited to the above-described embodiments, and various modifications can be made without departing from the scope of the present invention.

1 流動層
2 ガス化炉
3 抜出ループシール管
4 流動層
5 燃焼炉
7 媒体流下管
8 媒体分離装置
9 原料投入管
10 ウインドボックス
11 散気板
14 熱分解用熱交換器
14a 内管
14b 外管
15 熱分解炉
15a 流動層
16 オーバーフロー管
17 ウインドボックス
18 散気板
19 タール分解用熱交換器
19a 内管
19b 外管
DESCRIPTION OF SYMBOLS 1 Fluidized bed 2 Gasification furnace 3 Extraction loop seal pipe 4 Fluidized bed 5 Combustion furnace 7 Medium flow-down pipe 8 Medium separator 9 Raw material input pipe 10 Wind box 11 Air diffuser plate 14 Pyrolysis heat exchanger 14a Inner pipe 14b Outside Pipe 15 Pyrolysis furnace 15a Fluidized bed 16 Overflow pipe 17 Wind box 18 Air diffuser plate 19 Heat exchanger for tar decomposition 19a Inner pipe 19b Outer pipe

Claims (6)

ガス化炉でガス化剤を兼ねるガス化炉流動用ガスにより流動媒体の流動層を形成して原料のガス化を行いガス化ガスと可燃性固形分とを生成し、該ガス化炉で生成されたガス化ガスを取り出す一方、前記ガス化炉で生成された可燃性固形分を流動媒体と共にガス化炉から燃焼炉へ導入し且つ該燃焼炉で燃焼炉流動用ガスにより流動層を形成して前記可燃性固形分の燃焼を行いつつ該燃焼炉の燃焼排ガスから媒体分離装置で流動媒体を分離し該分離した流動媒体を前記ガス化炉に戻す循環流動層式ガス化方法において、
前記媒体分離装置で分離された流動媒体を熱分解炉を経由して前記ガス化炉へ戻すと共に、
前記原料を熱分解用熱交換器で前記燃焼排ガスと熱交換させてタールを含む熱分解ガスを放出させつつ、不活性ガスにより流動層が形成されている熱分解炉へ投入し更に熱分解させて熱分解ガスを発生させ、
前記熱分解炉で熱分解ガスが分離された原料を含む流動媒体を前記ガス化炉へ導入し、該ガス化炉で前記原料のガス化のみを行わせ、流動媒体と可燃性固形分とを前記燃焼炉へ導入することを特徴とする循環流動層式ガス化方法。
A gasification fluid and a combustible solid content are generated by forming a fluidized bed of a fluidized medium by using a gasifying fluid that also serves as a gasifying agent in a gasification furnace, and generating a gasified gas and combustible solids. While taking out the gasified gas, the combustible solid content generated in the gasification furnace is introduced into the combustion furnace from the gasification furnace together with the fluidizing medium, and in the combustion furnace, a fluidized bed is formed by the combustion furnace fluidizing gas. In the circulating fluidized bed gasification method, the fluidized medium is separated from the combustion exhaust gas of the combustion furnace by a medium separator while the combustible solid is burned, and the separated fluidized medium is returned to the gasifier.
Returning the fluid medium separated by the medium separator to the gasification furnace via a pyrolysis furnace,
The raw material is heat-exchanged with the combustion exhaust gas by a heat decomposition heat exchanger to release a pyrolysis gas containing tar, and is put into a pyrolysis furnace in which a fluidized bed is formed with an inert gas and further pyrolyzed. To generate pyrolysis gas,
A fluid medium containing a raw material from which pyrolysis gas has been separated in the pyrolysis furnace is introduced into the gasification furnace, and only the raw material is gasified in the gasification furnace, and the fluid medium and combustible solids are obtained. A circulating fluidized bed gasification method, wherein the gasification method is introduced into the combustion furnace.
ガス化炉でガス化剤を兼ねるガス化炉流動用ガスにより流動媒体の流動層を形成して原料のガス化を行いガス化ガスと可燃性固形分とを生成し、該ガス化炉で生成されたガス化ガスを取り出す一方、前記ガス化炉で生成された可燃性固形分を流動媒体と共にガス化炉から燃焼炉へ導入し且つ該燃焼炉で燃焼炉流動用ガスにより流動層を形成して前記可燃性固形分の燃焼を行いつつ該燃焼炉の燃焼排ガスから媒体分離装置で流動媒体を分離し該分離した流動媒体を前記ガス化炉に戻す循環流動層式ガス化方法において、
前記媒体分離装置で分離された流動媒体を熱分解炉を経由して前記ガス化炉へ戻すと共に、
前記原料を不活性ガスにより流動層が形成されている熱分解炉へ投入し熱分解させて熱分解ガスを発生させ、該熱分解ガスをタール分解用熱交換器で前記燃焼排ガスと熱交換させてタールを分解し、
前記熱分解炉で熱分解ガスが分離された原料を含む流動媒体を前記ガス化炉へ導入し、該ガス化炉で前記原料のガス化のみを行わせ、流動媒体と可燃性固形分とを前記燃焼炉へ導入することを特徴とする循環流動層式ガス化方法。
A gasification fluid and a combustible solid content are generated by forming a fluidized bed of a fluidized medium by using a gasifying fluid that also serves as a gasifying agent in a gasification furnace, and generating a gasified gas and combustible solids. While taking out the gasified gas, the combustible solid content generated in the gasification furnace is introduced into the combustion furnace from the gasification furnace together with the fluidizing medium, and in the combustion furnace, a fluidized bed is formed by the combustion furnace fluidizing gas. In the circulating fluidized bed gasification method, the fluidized medium is separated from the combustion exhaust gas of the combustion furnace by a medium separator while the combustible solid is burned, and the separated fluidized medium is returned to the gasifier.
Returning the fluid medium separated by the medium separator to the gasification furnace via a pyrolysis furnace,
The raw material is put into a pyrolysis furnace in which a fluidized bed is formed with an inert gas, pyrolyzed to generate pyrolysis gas, and the pyrolysis gas is heat exchanged with the combustion exhaust gas in a tar decomposition heat exchanger. Break down tar,
A fluid medium containing a raw material from which pyrolysis gas has been separated in the pyrolysis furnace is introduced into the gasification furnace, and only the raw material is gasified in the gasification furnace, and the fluid medium and combustible solids are obtained. A circulating fluidized bed gasification method, wherein the gasification method is introduced into the combustion furnace.
ガス化剤を兼ねるガス化炉流動用ガスにより流動媒体の流動層を形成して原料のガス化を行いガス化ガスと可燃性固形分とを生成するガス化炉と、該ガス化炉で生成された可燃性固形分が流動媒体と共に導入され且つ燃焼炉流動用ガスにより流動層を形成して前記可燃性固形分の燃焼を行う燃焼炉と、該燃焼炉の燃焼排ガスから流動媒体を分離し該分離した流動媒体を前記ガス化炉に戻す媒体分離装置とを備えた循環流動層式ガス化装置において、
前記原料を前記燃焼排ガスと熱交換させてタールを含む熱分解ガスを放出させる熱分解用熱交換器と、
前記媒体分離装置で分離された流動媒体が導入され、不活性ガスにより流動層を形成し、該流動層で前記熱分解用熱交換器を通過した原料を更に熱分解させて熱分解ガスを発生させ、該熱分解ガスが分離された原料と流動媒体とを前記ガス化炉へ導く熱分解炉と
を備えたことを特徴とする循環流動層式ガス化装置。
A gasification furnace that also serves as a gasifying agent forms a fluidized bed of a fluidized medium by using a gas for fluidizing the gasifying medium, and gasifies the raw material to generate gasified gas and combustible solids. A combustible solid is introduced together with the fluidized medium, and a fluidized bed is formed by the combustion furnace fluidizing gas to burn the combustible solid, and the fluidized medium is separated from the combustion exhaust gas of the combustion furnace. In a circulating fluidized bed type gasifier comprising a medium separator for returning the separated fluid medium to the gasification furnace,
A heat exchanger for thermal decomposition, in which the raw material is subjected to heat exchange with the combustion exhaust gas to release pyrolysis gas containing tar;
The fluidized medium separated by the medium separator is introduced, a fluidized bed is formed with an inert gas, and the raw material that has passed through the heat exchanger for thermal decomposition is further pyrolyzed in the fluidized bed to generate a pyrolytic gas. And a pyrolysis furnace for guiding the raw material from which the pyrolysis gas has been separated and the fluidized medium to the gasification furnace.
内管と外管とを同芯状に配設してなり、原料が内管内に導入されると共に、前記媒体分離装置で分離された燃焼炉からの燃焼排ガスが内管と外管との間に導入される二重管式熱交換器によって、前記熱分解用熱交換器を構成した請求項3記載の循環流動層式ガス化装置。   The inner tube and the outer tube are arranged concentrically, and the raw material is introduced into the inner tube, and the combustion exhaust gas from the combustion furnace separated by the medium separator is between the inner tube and the outer tube. The circulating fluidized-bed gasifier according to claim 3, wherein the heat exchanger for thermal decomposition is constituted by a double-pipe heat exchanger introduced into the heat exchanger. ガス化剤を兼ねるガス化炉流動用ガスにより流動媒体の流動層を形成して原料のガス化を行いガス化ガスと可燃性固形分とを生成するガス化炉と、該ガス化炉で生成された可燃性固形分が流動媒体と共に導入され且つ燃焼炉流動用ガスにより流動層を形成して前記可燃性固形分の燃焼を行う燃焼炉と、該燃焼炉の燃焼排ガスから流動媒体を分離し該分離した流動媒体を前記ガス化炉に戻す媒体分離装置とを備えた循環流動層式ガス化装置において、
前記媒体分離装置で分離された流動媒体が導入され、不活性ガスにより流動層を形成し、該流動層で投入される原料を熱分解させて熱分解ガスを発生させ、該熱分解ガスが分離された原料と流動媒体とを前記ガス化炉へ導く熱分解炉と、
該熱分解炉で発生した熱分解ガスを前記燃焼排ガスと熱交換させてタールを分解するタール分解用熱交換器と
を備えたことを特徴とする循環流動層式ガス化装置。
A gasification furnace that also serves as a gasifying agent forms a fluidized bed of a fluidized medium by using a gas for fluidizing the gasifying medium, and gasifies the raw material to generate gasified gas and combustible solids. A combustible solid is introduced together with the fluidized medium, and a fluidized bed is formed by the combustion furnace fluidizing gas to burn the combustible solid, and the fluidized medium is separated from the combustion exhaust gas of the combustion furnace. In a circulating fluidized bed type gasifier comprising a medium separator for returning the separated fluid medium to the gasification furnace,
The fluidized medium separated by the medium separator is introduced, a fluidized bed is formed with an inert gas, the raw material charged in the fluidized bed is pyrolyzed to generate a pyrolyzed gas, and the pyrolyzed gas is separated. A pyrolysis furnace for guiding the raw material and the fluidized medium to the gasification furnace;
A circulating fluidized bed type gasifier comprising: a tar decomposition heat exchanger that decomposes tar by thermally exchanging pyrolysis gas generated in the pyrolysis furnace with the combustion exhaust gas.
内管と外管とを同芯状に配設してなり、前記熱分解炉で発生した熱分解ガスが内管内に導入されると共に、前記媒体分離装置で分離された燃焼炉からの燃焼排ガスが内管と外管との間に導入される二重管式熱交換器によって、前記タール分解用熱交換器を構成した請求項5記載の循環流動層式ガス化装置。   Combustion exhaust gas from a combustion furnace in which an inner pipe and an outer pipe are arranged concentrically and pyrolysis gas generated in the pyrolysis furnace is introduced into the inner pipe and separated by the medium separator The circulating fluidized bed gasifier according to claim 5, wherein the tar decomposition heat exchanger is constituted by a double pipe heat exchanger introduced between an inner pipe and an outer pipe.
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