JP2010265197A - Hair conditioning composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a hair conditioning composition which enhances a sense of use of an oil agent left on the surface of hair and in the hair after rinsed and used, further enhances the addition of a non-tacky sustained moist feeling to hair tips after used, and a feeling for collecting hair tips spread by external damage, and can impart a hair tip-collecting feeling, even when continuously used for a long period, a non-tacky continuous moist feeling and a finger-passing touch having a good slipping property to the hair tips. <P>SOLUTION: The hair conditioning composition includes (A) polyoxypropylene phytosterol having a propylene oxide addition mole number of 1 to 10, (B) a dicarboxylic acid ester, and (C) a cationic surfactant. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a hair conditioning composition.

  Hair care, hair treatments, hair packs, hair masks, non-washing-type treatments, etc. are used as care measures for damaged hair. These hair conditioning compositions are blended with a cationic surfactant having a hair flexibility effect as a main component. For example, amine compounds having linear alkyl groups, alkenyl groups or branched alkyl groups (for example, patents) Document 1) and quaternary ammonium salt cationic surfactants (for example, Patent Document 2) are blended for the purpose of imparting slipperiness, moist feeling, flexibility and antistatic properties to the hair. Furthermore, in order to enhance the conditioning effect, peptides or proteins derived from higher alcohols, liquid paraffin, ester oils, sterols, lipids, silicone oils, shellfish, fish, silk, plants, seaweed, etc., or derivatives thereof are also blended. These components are known to obtain the above-mentioned conditioning effect by physical adhesion, charge adsorption, or penetration into the hair surface even after rinsing with hot water or water in use.

  Conventionally, sterols have been blended into many cosmetics and compositions regardless of the site of use because they have excellent usability. In recent years, among sterols, phytosterol, which is a plant-derived sterol, is more likely to be used than animal-derived cholesterol. Since these phytosterols have a molecular structure similar to cholesterol, which is a lipid contained in the living body, they are used for wet retention of skin and hair, improvement of skin quality, and hair quality. However, since the melting point of sterols is as high as 100 ° C. or higher and the miscibility and solubility with oil components are poor, in order to increase the miscibility and solubility in oil components at 80 ° C. or less, alkylene oxides such as ethylene oxide and propylene oxide are used. Cosmetics containing a phytosterol derivative to which is added (for example, Patent Document 3) are known. It is known that these phytosterol derivatives can be blended stably in cosmetics and compositions as well as the feeling of use. In addition, hair cosmetics containing phytosterol derivatives to which ethylene oxide has been added (for example, Patent Documents 4 and 5) give a uniform feel from the tips of hairs to the roots with different degrees of damage, and further to hair that has undergone hair color treatment. It is known to prevent fading and give gloss. Moreover, not only hair cosmetics appropriately blended with ester compounds for the purpose of touch control (for example, Patent Document 6), but also hair cosmetics containing mixtures and specific amounts of various ester compounds in specific ratios (for example, Patent Document 7) and hair treatment agents (for example, Patent Document 8) that increase the permeability of lipid components formulated using two types of carboxylic acid diesters are known, and these are moist and excellent in hair. It is known to give a feeling of flexibility and non-stickiness.

Japanese Patent No. 3980520 Japanese Patent No. 3980521 Japanese Patent Publication No. 52-79031 JP 2003-176214 A JP 2007-8867 A JP 2002-187819 A JP 2005-239625 A JP 2007-1951 A

  However, in the conventional hair conditioning composition, the touch at the time of use is good, but the touch at the time of finishing is lowered, the hair feels moisturized and flexible, but stickiness occurs, and the feel to the root is good However, there were many cases where the effect on the hair ends was not sufficient.

  Therefore, the object of the present invention is to increase the feeling of use of the oil agent remaining on the surface or inside of the hair at the time of rinsing and finishing without reducing the advantages of conventional compositions and hair cosmetics, and to the hair tip after finishing. Gives a moist feeling with stickiness and a feeling of unity of the ends of the hair, and further suppresses the spread of the tip of the hair even in long-term continuous use, and the unity feeling of the hair bundle to the tip and the persistence without stickiness on the tip of the hair An object of the present invention is to provide a hair conditioning composition capable of imparting a certain moist feeling and a feeling of good sliding.

  Therefore, the present inventor has conducted various studies on components that have been conventionally used. First, a conditioning composition that contains an amine compound having a linear alkyl group, an alkenyl group, or a branched alkyl group, and is neutralized with an organic acid to form an ammonium salt. On the other hand, there was no sufficient satisfactory effect in terms of feeling that the weight was reduced due to the persistence on the hair and that the volume was reduced or that the hair tips were sticky in summer. Furthermore, cationic surfactants such as monoalkyltrimethylammonium chloride have a non-sticky finish and flexibility, but lacked a feeling of moisture, slippery fingering and bristles. To compensate for this drawback, for example, even when a hydroxy ether type cationic surfactant and a highly polymerized methylpolysiloxane are combined, it suppresses the spread of the damaged hair tip and maintains a moist and slippery tip. There is a limit to the good fingering effect, and the smoothness and lack of fingering during rinsing are also lacking. It also lacked a good sense of fingering.

  In addition, when various esters are contained alone or in combination as an oil agent, they provide moisturizing feeling and flexibility, suppress stickiness, and increase permeability, but feel the hair bundle feeling after drying. Not satisfied with a smooth feeling of smoothness and smoothness on the tip of the hair, and a lasting feeling of moisture on the tip of the hair, but with a sense of penetration that will lead to improved hair quality depending on the type of lipid and its derivatives to be penetrated It wasn't.

  Furthermore, phytosterols added with ethylene oxide have a strong hydrophilicity of ethylene oxide, which reduces the persistence on the hair surface after washing and lowers the penetration effect into the hair. In addition, in the moist feeling of the hair ends after finishing, it was not satisfactory in terms of a moist feeling that lasted for a long time on the hair ends.

  Therefore, the present inventor paid attention to polyoxypropylene phytosterols to which propylene oxide was added, but those having a large number of added moles of propylene oxide have higher hydrophobicity and higher persistence on the hair surface, but are too easy to finish. It is not satisfactory for the stickiness and slippery finger of time, and the molecular weight of the phytosterol derivative increases, so the penetration effect into the hair also decreases, and the hair tip for long-term continuous use is also durable It was not satisfactory in terms of moisture.

  Therefore, as a result of further studies, combining polyoxypropylene phytosterol with a small number of added moles of propylene oxide, a dicarboxylic acid ester, and a cationic surfactant to provide a durable moist feeling and a feeling of unity of the hair tips, The present invention has been completed by finding that a hair conditioning composition capable of imparting a slippery finger feeling can be obtained.

  That is, the present invention is characterized by containing (A) polyoxypropylene phytosterol having an addition mole number of propylene oxide of 1 to 10, (B) dicarboxylic acid ester, and (C) a cationic surfactant. A hair conditioning composition is provided.

The hair conditioning composition of the present invention is capable of imparting a feeling of unity of the spreading hair peculiar to damaged hair, a persistent moist feeling without stickiness on the hair tip after use, and even a slippery fingering feeling, Even in continuous continuous use, these effects are excellent.
Therefore, if the conditioning composition of the present invention is used, it is damaged by UV damage, perm, coloring, excessive brushing and heat of a hair dryer, which are daily external factors, from the outflow of lipid inside the hair and the damage of the cuticle. The resulting split ends, the feeling of unity of the hair ends that spread with dryness and dryness, and the moisture that lasts without stickiness even after use, and also gives the fingertips that the hair ends are slippery. .

  Hereinafter, the configuration of the present invention will be described in detail.

The polyoxypropylene phytosterol having an addition mole number of propylene oxide of component (A) used in the hair conditioning composition of the present invention is 1 to 10, which is more hydrophobic than ethylene oxide adduct and has high persistence on hair, Moreover, since the added mole number is as low as 1 to 10, the molecular weight is small and the effect of penetrating into the hair is high, so that it is possible to maintain a lasting touch on the hair. These may be used singly or in combination of two or more types in which the number of added moles of propylene oxide is different within the above range. The number of moles of propylene oxide added is more preferably from 3 to 7, and particularly preferably from 3 to 5, from the viewpoint of penetrability and persistence into the hair and good slipperiness when finished. These raw materials can be obtained, for example, from Nikko Chemicals as NIKKOL PSR-5 (polyoxypropylene (5) phytosterol).
In addition, phytosterols include β-sitosterol, campesterol, stigmasterol, brush casterol, and the like. In the present invention, these may be used alone or as a mixture.

  The content of the component (A) in the hair conditioning composition of the present invention is preferably 0.01 to 5% by mass from the feeling of penetrating into the hair and following the finish, and the hair ends after use are not sticky. It is more preferably 0.1 to 3% by mass from the viewpoint of moisture with a long lasting feeling and good sliding. Also in the combination of two or more types of component (A), it is desirable that the amount is within the above range. Within these ranges, favorable effects can be obtained in terms of the penetration into the hair and the stickiness of the hair surface.

The dicarboxylic acid ester which is the component (B) used in the hair conditioning composition of the present invention acts as a penetration promoting component that further increases the penetration of the component (A) into the hair.
The dicarboxylic acid ester is not particularly limited as long as it is an ester of dicarboxylic acid, and includes dimer linoleic acid mixture fatty acid ester, acidic amino acid diester, dibasic acid ester and the like. Here, as the mixed fatty acid ester of dimerlinolinic acid, dimerlinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) “Plandool-H” (manufactured by Nippon Seika Co., Ltd.), dimerlinolinic acid dimerlinino Railbis (behenyl / isostearyl / phytosteryl) “Plandool-G” (manufactured by Nippon Seika Co., Ltd.) and the like can be mentioned. As diesters of acidic amino acids, N-lauroyl-L-glutamate di (phytosteryl 2-octyldodecyl) “Erudu PS-203” (manufactured by Ajinomoto Co.), N-lauroyl-L-glutamate di (phytosteryl behenyl 2-octyl) Dodecyl) “El Dew PS-306” (manufactured by Ajinomoto Co., Inc.). Examples of dibasic acid esters include diesters of fatty acid diglycerin and dibasic acids and diesters of dibasic acids. Diesters of fatty acid diglycerin and dibasic acids include diglyceryl adipic acid mixed fatty acid diesters. (Trade name: SOFTISAN 645 [manufactured by SASOL Germany]), diglyceryl sebacic acid mixed fatty acid diester, and the like. As the diester of dibasic acid, alkyl having 1 to 12 carbon atoms of dibasic acid having 2 to 18 carbon atoms. An ester or an alkoxyalkyl ester having 4 to 12 carbon atoms is preferred. Here, the dibasic acid having 2 to 18 carbon atoms includes a linear or branched saturated or unsaturated dibasic acid which may be substituted with a hydroxy group.

  Among these, a low molecular weight dicarboxylic acid ester having a molecular weight of 500 or less is preferred from the viewpoint of penetration into the hair and the effect of promoting penetration of the component (A) into the hair. Specific examples of such dicarboxylic acid esters include, for example, succinic acid diesters such as diethoxyethyl succinate and dioctyl succinate, adipic acid diesters such as diisopropyl adipate, diisobutyl adipate and diethoxyethyl adipate, Sebacic acid diesters such as diethyl sebacate, diisopropyl sebacate, and dioctyl sebacate are good, and among them, sebacic acid diesters can impart an excellent effect on penetrating feeling, rinsing feeling, and feeling after fingering after finishing. Furthermore, diethyl sebacate is mentioned as the most preferable sebacate diester from the feeling of use.

  The content of the component (B) used in the hair conditioning composition of the present invention is such that (A) / (B) (mass ratio) is 1/5 to 5/1 with respect to the content of the component (A). When it is within the range, it is preferable from the viewpoint of penetrating into the hair, stickiness, and lasting moist feeling, and (A) / (B) is in the range of 1/3 to 3/1. Is more preferable.

The cationic surfactant of component (C) used in the hair conditioning composition of the present invention is, for example, C ₁₂ -C such as cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, cetyltrimethylammonium methylsulfate and the like. C ₁₂ -C ₂₄ alkyl dimethyl hydroxyethyl ammonium salts, C ₁₂ -C ₂₄ alkyl dimethyl benzyl ammonium chloride, etc. stearyl dimethyl benzyl ammonium behenyl dimethyl hydroxyethyl ammonium chloride; distearyl dimethyl ammonium chloride, _C24 alkyl trimethyl ammonium salt di -C ₁₂ -C ₂₄ alkyl dimethyl ammonium chloride, etc. dicetyl dimethyl ammonium; chloride and stearyl oxy hydroxypropyl DOO Examples include hydroxy ether type cationic surfactants having a C ₁₂ -C ₂₄ alkyl group such as limethylammonium and behenyloxyhydroxypropyltrimethylammonium chloride.

  Among these cationic surfactants, a hydroxy ether type cationic surfactant represented by the following general formula (1), which is excellent in moisture feeling, good slipperiness and smoothness of hair tips, is particularly preferable. .

[Wherein, at least one of R ^{1 to} R ⁴ is a group represented by the following general formula (2), and the rest are alkyl groups having 1 to 3 carbon atoms, hydroxyalkyl groups having 1 to 3 carbon atoms, or Represents a benzyl group, and X ⁻ represents a monovalent anion.

[R ⁵ represents a linear or branched alkyl group having 12 to 24 carbon atoms, an alkenyl group, or a hydroxyalkyl group, and n represents an integer of 1 to 5. ]

The hydroxy ether type cationic surfactant can be produced, for example, by the method described in Japanese Patent No. 3980521, but the production method of the hydroxy ether type cationic surfactant is not particularly limited in the present invention. The hydroxy ether type cationic surfactant from the viewpoint of stability and conditioning benefits, the R ⁵ represented by the general formula (2) is an alkyl group having 16 to 24 carbon atoms is preferred, behenyl group Things are preferable.

  In the hair conditioning composition of this invention, it is preferable to contain 0.1-10 mass% of (C) component with respect to the quantity of the whole conditioning composition, 0.5-5 mass% is more preferable, 1.0 ˜3.5% by weight is particularly preferred.

  In addition, the hair conditioning composition of the present invention may contain (D) a higher alcohol from the viewpoint of elongation at the time of application and smoothness at the time of application. The higher alcohol is a monohydric alcohol having 12 to 30 carbon atoms, and specific examples include myristyl alcohol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, batyl alcohol, hardened rapeseed oil alcohol, and isostearyl alcohol. Among these, it can be used 1 type or in combination of 2 or more types. (D) The content of the higher alcohol is preferably 0.1 to 20% by mass, more preferably 0.3 to 15% by mass, and further preferably 0.5 to 10% by mass in the hair conditioning composition.

  (A) Polyoxypropylene phytosterol having an addition mole number of propylene oxide of 1 to 10 constituting the hair conditioning composition of the present invention, (B) dicarboxylic acid ester, (C) cationic surfactant is previously (A ) + (B) + (C) are preferably contained in the same composition because they are uniformly dispersed. For example, a composition containing (A) + (B) component (one agent) ) And the composition (2 agents) containing the component (A) + (C) or mixed immediately before use, or the composition (1 agent) containing the component (A) + (C) By mixing the composition (B) containing the component (B) immediately before use, it is possible to obtain a unique feel due to a non-uniform feeling of mixing, and it is an object of the present invention. There is also an effect. As a method of mixing just before use, even if it is a method of simple mixing in the user's palm or another container and then applying to hair, or a method of filling and using a container that simply mixes two agents at the time of discharge good.

  The hair conditioning composition of the present invention can further contain other components as long as the effects of the present invention are not impaired. Such components include anionic surfactants, amphoteric surfactants, nonionic surfactants, polymers, cationized polymers, plant extracts, seaweed extracts, vitamins, amino acids, amino acid derivatives, alcohols, other than the above Oils, pearlizing agents, moisturizing ingredients, fragrances, pigments, ultraviolet absorbers, antioxidants, bactericides, anti-inflammatory agents, preservatives and the like can be mentioned.

  The hair conditioning composition of the present invention may be used after rinsing and applying to the hair and rinsing well, or not rinsing, but it is a type of hair conditioning used after rinsing. Is particularly suitable.

  Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto.

(A) a phytosterol derivative in which the number of added moles of propylene oxide contained in the hair conditioning composition of the present invention is 1 to 10, and (B) a dicarboxylic acid ester, and (C) a cationic surfactant. Compositions containing the three components in the same composition were produced in accordance with conventional methods according to the formulations shown in Tables 1 and 2, and the following evaluations were performed.
In addition, as the hydroxy ether type cationic surfactant as the component (C), in the general formula (1), X is chlorine (Cl), and R ¹ is a group represented by the general formula (2). R ^{2 to} R ⁴ are methyl groups, and R ⁵ and n number are those having chemical formulas shown in Tables 1 and 2.

<Sensory test evaluation for feel evaluation>
Hair finish test after use (half-head method)
After the panel (20 persons) shampooed with 20% aqueous solution of polyoxyethylene (3) sodium lauryl ether sulfate, the hair was divided into left and right halves, and on the other hand, a wash-type hair conditioning composition shown below was applied as a control, On the other hand, each of the rinse-type hair conditioning compositions shown in the Examples and Comparative Examples was applied and rinsed at the same time, and then the hair was dried, and the hair tips of the left and right hairs were united, the tips of the tips were not sticky, Sensory evaluation was performed for the moisturizing feeling and durability of the hair tips. Further, the same operation as described above was performed once a day, and the sensory evaluation was performed according to the above items for the finish of the hair after continuous use for one week.

Control (wash-in type hair conditioning composition) (% by mass)
・ Cetanol 5.0
・ Behentrimonium chloride 2.0
・ Concentrated glycerin 2.0
Paraffin 1.0
・ Phenoxyethanol 0.2
・ Ion exchange water

The standard of evaluation was set as follows (set by the number of people who answered that it was better than the control).
4: 18 or more people who answered good 3: 15 or more people who answered good, less than 18 2: 11 or more people who answered good, less than 15 1: 10 people who answered good Below

Examples 1 to 15 and Comparative Examples 1 to 4 (hair conditioning compositions)

  As is clear from Tables 1 and 2, in the example satisfying the configuration of the present invention, good results were obtained in all items. On the other hand, in the comparative example in which any of the constitutions of the present invention is lacking or the component (A) of the present invention is replaced with a phytosterol derivative to which ethylene oxide is added or a propylene oxide having a large added mole number, any evaluation item In addition, the object of the present invention could not be satisfied in the continuous test.

  Hereinafter, Examples were produced according to a conventional method.

Example 16 Hair Treatment (Prescription Component) (mass%)
Stearyl alcohol 6.5
Cetanol 0.5
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Concentrated glycerin 1.0
Propylene glycol 2.0
Hydroxy ether type cationic surfactant (C) 2.0
(R ⁵ = C ₂₂ H ₄₅ , n = 1)
Hydroxypropyltrimonium honey 0.1
(Brand name: Honey coat 50 [Arch Personal Products LP Co., Ltd.])
Hydrolyzed conchiolin solution 0.1
(Product name: Pearl protein extract [Maruzen Pharmaceutical Co., Ltd.])
Hydrolyzed collagen solution 0.1
(Product name: Promois WU-32R [manufactured by Seiwa Kasei Co., Ltd.])
Hydrolyzed silk solution 0.1
(Product name: Fibroin solution [KB Seiren])
Dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) 0.5
(Product name: Plandool-L [made by Nippon Seika Co., Ltd.])
Bisdiglyceryl polyacyl adipate-2 0.5
(Product name: Softizan 649 [manufactured by SASOL])
Lauroyl glutamate di (phytosteryl / octidodecyl) 0.1
(Product name: L-Du PS-203 [manufactured by Ajinomoto Co., Inc.])
Highly polymerized dimethylpolysiloxane emulsion 2.0
(Product name: KM-902 [manufactured by Shin-Etsu Chemical Co., Ltd.])
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion-exchanged water

  The above-mentioned hair treatment not only excels in imparting a feeling of unity of the hair ends after drying, a durable moist feeling and a slippery finger feeling on the hair tips, but also a rich feeling during rinsing and a sticky feeling without stickiness Goodness was also good.

Example 17 Hair Treatment (Prescription Component) (mass%)
Stearyl alcohol 6.5
Cetanol 0.5
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Concentrated glycerin 1.0
Propylene glycol 2.0
Behenamidopropyldimethylamine 0.5
Behentrimonium chloride (C) 1.0
Hydroxy ether type cationic surfactant (C) 1.0
(R ⁵ = C ₂₂ H ₄₅ , n = 1)
Paraffin 1.0
Hydroxypropyltrimonium honey 0.1
(Brand name: Honey coat 50 [Arch Personal Products LP Co., Ltd.])
Hydrolyzed conchiolin solution 0.1
(Product name: Pearl protein extract [Maruzen Pharmaceutical Co., Ltd.])
Hydrolyzed collagen solution 0.1
(Product name: Promois WU-32R [manufactured by Seiwa Kasei Co., Ltd.])
Hydrolyzed silk solution 0.1
(Product name: Fibroin solution [KB Seiren])
Olive oil 0.1
Hydrolyzed wheat protein 0.1
(Product name: GLUADIN WLM [manufactured by Cognis Japan])
Hydrolyzed wheat powder 0.1
(Product name: Promois WG [manufactured by Seiwa Kasei Co., Ltd.])
Lactic acid 0.2
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion-exchanged water

  The above hair treatment not only provides a feeling of unity of the hair after drying, a moist feeling without stickiness on the hair tip, and a smooth feeling of fingering, but also a rich feeling when rinsing and good fingering without stickiness Was also good.

Example 18 Hair conditioner (prescription ingredient) (mass%)
Stearyl alcohol 0.5
Cetanol 5.0
Behentrimonium chloride (C) 0.7
Concentrated glycerin 2.0
Paraffin 1.0
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Hydroxy ether type cationic surfactant (C) 1.0
(R ⁵ = C ₂₂ H ₄₅ , n = 1)
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion-exchanged water

  The above hair conditioner not only excels in providing a feeling of unity of the hair after drying, a durable moist feeling without sticking to the hair tip, and a feeling of slippery fingering, but also good soft fingering when rinsing Was also good.

Example 19 Out bath treatment mist (component name) (mass%)
Ethanol 15.0
Glycerin 2.0
Dipropylene glycol 2.0
1,3-butylene glycol 0.5
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Hydroxy ether type cationic surfactant (C) 1.0
(R ⁵ = C ₂₂ H ₄₅ , n = 1)
Behentrimonium chloride (C) 0.5
Dimethicone 0.2
Aminopropyl dimethicone 0.05
Behenyl alcohol 0.05
Phenoxyethanol 0.2
Fragrance 0.05
Ion exchange water

  The above-mentioned out bath treatment mist not only excels in providing a feeling of unity of the hair tips after use, a durable moistness without stickiness on the hair tips, and a finger-feeling feeling with slipperiness of the hair tips, but also softness of the hair tips Sex persistence was also good.

Example 20 Out bath treatment milk (component name) (mass%)
Glycerin 1.0
Propylene glycol 5.0
1,3-butylene glycol 2.0
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Hydroxy ether type cationic surfactant (C) 0.2
(R ⁵ = C ₂₂ H ₄₅ , n = 1)
Dimethicone 0.4
Polysilicone-13 0.1
Sucrose stearate 2.0
Carbomer 0.4
Triethanolamine 0.35
Sodium edetate 0.01
Phenoxyethanol 0.3
Ethanol 8.0
Fragrance 0.1
Ion exchange water

  The above bath treatment milk is not only excellent in providing a feeling of unity of the hair tips after use, a lasting moist feeling without stickiness on the hair tips, and a finger feeling that is slippery on the hair tips, but also the softness of the hair tips. Sex persistence was also good.

Example 21 Out bath treatment cream (ingredient name) (mass%)
Cetostearyl alcohol 1.5
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Behentrimonium chloride (C) 0.1
Hydroxy ether type cationic surfactant (C) 0.1
(R ⁵ = C ₂₂ H ₄₅ , n = 1)
Propylene glycol 1.0
Dipropylene glycol 1.5
Dimethicone 1.5
Phenyltrimethicone 0.5
Sodium lauryl sulfate 2.0
Macadamia nut fatty acid phytosteryl 1.3
PEG-10 hydrogenated castor oil 0.7
Hydroxypropyl methylcellulose 0.3
Sodium benzoate 0.2
Phenoxyethanol 0.5
Fragrance 0.3
Ion exchange water

  The above-mentioned out bath treatment cream not only excels in providing a feeling of unity of the hair tips after use, a lasting moist feeling without stickiness on the hair tips, and a feeling of finger slipping that is slippery on the hair tips, but also softens the hair tips Sex persistence was also good.

  Table 3 shows the fragrances used in the compositions of the examples of the present invention.

  The present invention can be used for unprecedented use because it can provide a durable moistness without stickiness on the tip of the hair that spreads due to damage, and a smooth feeling to the tip of the finger that is slippery to the tip of the hair. A rinse-type hair conditioning composition that can be expected to have a feeling of finishing and finishing.

Claims (4)

A hair conditioning composition containing the following components (A) to (C).
(A) Polyoxypropylene phytosterol derivative having 1 to 10 added moles of propylene oxide (B) Dicarboxylic acid ester (C) Cationic surfactant The hair conditioning composition according to claim 1, wherein (C) the cationic surfactant is a hydroxy ether type cationic surfactant represented by the following general formula (1).

[Wherein, at least one of R ^{1 to} R ⁴ is a group represented by the following general formula (2), and the rest are alkyl groups having 1 to 3 carbon atoms, hydroxyalkyl groups having 1 to 3 carbon atoms, or Represents a benzyl group, and X ⁻ represents a monovalent anion.

[R ⁵ represents a linear or branched alkyl group having 16 to 24 carbon atoms, an alkenyl group, or a hydroxyalkyl group, and n represents an integer of 1 to 5. ]   The hair conditioning composition according to claim 1 or 2, wherein (B) the dicarboxylic acid ester is a sebacic acid diester.   (B) The hair conditioning composition according to any one of claims 1 to 3, wherein the dicarboxylic acid ester is diethyl sebacate.