[go: up one dir, main page]

JP2010240629A - Carbon dioxide recovery system - Google Patents

Carbon dioxide recovery system Download PDF

Info

Publication number
JP2010240629A
JP2010240629A JP2009095678A JP2009095678A JP2010240629A JP 2010240629 A JP2010240629 A JP 2010240629A JP 2009095678 A JP2009095678 A JP 2009095678A JP 2009095678 A JP2009095678 A JP 2009095678A JP 2010240629 A JP2010240629 A JP 2010240629A
Authority
JP
Japan
Prior art keywords
liquid
gas
carbon dioxide
tower
absorption
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2009095678A
Other languages
Japanese (ja)
Inventor
Kiyohiko Iwaasa
浅 清 彦 岩
Masatoshi Hodozuka
塚 正 敏 程
Manabu Sakurai
井 学 桜
Kazuya Yamada
田 和 矢 山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP2009095678A priority Critical patent/JP2010240629A/en
Publication of JP2010240629A publication Critical patent/JP2010240629A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/151Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals

Landscapes

  • Carbon And Carbon Compounds (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To reduce heat energy required in an absorption liquid regeneration process in a carbon dioxide recovery system. <P>SOLUTION: Between an absorption tower 3 for making an absorption liquid absorb carbon dioxide included in a combustion exhaust gas and a regeneration tower 5 for regenerating the absorption liquid supplied from the absorption tower and discharging a discharge gas containing emitted carbon dioxide gas and steam, a regenerated heat exchanger 7 is provided which heats the absorption liquid which has absorbed the carbon dioxide and supplied from the absorption tower to the regeneration tower with the regenerated absorption liquid supplied from the regeneration tower to the absorption tower as a heat source. Also, between the absorption tower and the regenerated heat exchanger or between the regenerated heat exchanger and the regeneration tower, a heat exchanger 20 is provided which heats the absorption liquid which has absorbed the carbon dioxide and supplied from the absorption tower to the regeneration tower with the discharge gas discharged from the regeneration tower as a heat source. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、二酸化炭素回収システムに関するものである。   The present invention relates to a carbon dioxide recovery system.

近年、地球温暖化の原因の1つとして、化石燃料を燃焼させる際に生成される燃焼排ガスに含まれる二酸化炭素の温室効果が指摘されている。この問題に対処するため、気候変動に関する国際連合枠組条約の京都議定書に応じて、各国は、温室効果ガスの排出量削減に取り組んでいる。   In recent years, as one of the causes of global warming, the greenhouse effect of carbon dioxide contained in combustion exhaust gas generated when burning fossil fuel has been pointed out. To address this issue, countries are working to reduce greenhouse gas emissions in accordance with the Kyoto Protocol to the United Nations Framework Convention on Climate Change.

このような状況の下、多量の化石燃料を使用する火力発電所等において、化石燃料を燃焼して生成された燃焼排ガスをアミン系吸収液と接触させ、燃焼排ガスから二酸化炭素を分離して回収し、この回収された二酸化炭素を大気中へ放出することなく貯蔵する方法が研究されている。   Under such circumstances, in a thermal power plant that uses a large amount of fossil fuel, the combustion exhaust gas produced by burning fossil fuel is brought into contact with the amine-based absorbent, and carbon dioxide is separated and recovered from the combustion exhaust gas. However, a method for storing the recovered carbon dioxide without releasing it into the atmosphere has been studied.

具体的には、燃焼排ガスに含まれる二酸化炭素をアミン系吸収液に吸収させる吸収塔と、二酸化炭素を吸収した吸収液(リッチ液)が吸収塔から供給され、リッチ液を加熱し、リッチ液から二酸化炭素ガスを放出させるとともに、吸収液を再生する再生塔と、を備えた二酸化炭素回収システムが知られている(例えば特許文献1参照)。再生塔には、熱源を供給するリボイラーが連結されている。再生塔において再生された吸収液(リーン液)は吸収塔に供給され、このシステム内で吸収液が循環するようになっている。   Specifically, an absorption tower that absorbs carbon dioxide contained in combustion exhaust gas in an amine-based absorption liquid and an absorption liquid (rich liquid) that has absorbed carbon dioxide are supplied from the absorption tower, the rich liquid is heated, and the rich liquid A carbon dioxide recovery system including a regeneration tower for releasing carbon dioxide gas from the water and regenerating an absorbing solution is known (see, for example, Patent Document 1). A reboiler for supplying a heat source is connected to the regeneration tower. The absorption liquid (lean liquid) regenerated in the regeneration tower is supplied to the absorption tower, and the absorption liquid circulates in this system.

上記のような二酸化炭素回収システムは、既設の発電設備等に付加して設置されるため、その運転コストを出来るだけ低減することが求められる。特に、前記再生塔における吸収液の再生工程は、リッチ液から二酸化炭素ガスを放出させるために多量の熱エネルギーが必要とされる。従って、二酸化炭素回収システムの運転コストを低減するためには、吸収液の再生工程で必要となる熱エネルギーを低減することが重要となる。   Since the carbon dioxide recovery system as described above is installed in addition to existing power generation facilities and the like, it is required to reduce its operating cost as much as possible. Particularly, in the regeneration step of the absorbing liquid in the regeneration tower, a large amount of heat energy is required to release carbon dioxide gas from the rich liquid. Therefore, in order to reduce the operating cost of the carbon dioxide recovery system, it is important to reduce the thermal energy required in the absorption liquid regeneration process.

特開2005−254212号公報JP-A-2005-254212

本発明は、吸収液の再生工程で必要となる熱エネルギーを低減し、運転コストを低減した二酸化炭素回収システムを提供することを目的とする。   An object of this invention is to provide the carbon dioxide recovery system which reduced the thermal energy required by the reproduction | regeneration process of an absorption liquid, and reduced the operating cost.

本発明の一態様による二酸化炭素回収システムは、燃焼排ガスに含まれる二酸化炭素を吸収液に吸収させる吸収塔と、前記吸収塔から二酸化炭素を吸収した吸収液が供給され、当該吸収液から蒸気を含む二酸化炭素ガスを放出させるとともに当該吸収液を再生し、放出された二酸化炭素ガス及び蒸気を含む排出ガスを排出する再生塔と、前記吸収塔と前記再生塔との間に設けられ、前記再生塔から前記吸収塔に供給される再生された吸収液を熱源として、前記吸収塔から前記再生塔に供給される二酸化炭素を吸収した吸収液を加熱する再生熱交換器と、前記吸収塔と前記再生熱交換器との間、又は前記再生熱交換器と前記再生塔との間に設けられ、前記再生塔から排出される前記排出ガスを熱源として、前記吸収塔から前記再生塔に供給される二酸化炭素を吸収した吸収液を加熱する熱交換器と、を備えるものである。   A carbon dioxide recovery system according to an aspect of the present invention is provided with an absorption tower that absorbs carbon dioxide contained in combustion exhaust gas into an absorption liquid, an absorption liquid that absorbs carbon dioxide from the absorption tower, and vapor from the absorption liquid. A regeneration tower for releasing the carbon dioxide gas containing the carbon dioxide gas and regenerating the absorption liquid, and discharging the exhaust gas containing the released carbon dioxide gas and steam; and the regeneration tower is provided between the absorption tower and the regeneration tower. Using the regenerated absorption liquid supplied from the tower to the absorption tower as a heat source, the regenerative heat exchanger for heating the absorption liquid that has absorbed carbon dioxide supplied from the absorption tower to the regeneration tower, the absorption tower, and the Provided between the regenerative heat exchanger or between the regenerative heat exchanger and the regenerator, and supplied from the absorption tower to the regenerator with the exhaust gas discharged from the regenerator as a heat source A heat exchanger for heating the absorbing solution having absorbed carbon dioxide, in which comprises a.

本発明によれば、吸収液の再生工程で必要となる熱エネルギーを低減し、二酸化炭素回収システムの運転コストを低減できる。   According to the present invention, it is possible to reduce the thermal energy required in the absorption liquid regeneration step and reduce the operating cost of the carbon dioxide recovery system.

本発明の第1の実施形態に係る二酸化炭素回収システムの概略構成図である。1 is a schematic configuration diagram of a carbon dioxide recovery system according to a first embodiment of the present invention. 変形例による二酸化炭素回収システムの概略構成図である。It is a schematic block diagram of the carbon dioxide collection system by a modification. 本発明の第2の実施形態に係る二酸化炭素回収システムの概略構成図である。It is a schematic block diagram of the carbon dioxide collection system which concerns on the 2nd Embodiment of this invention. 本発明の第3の実施形態に係る二酸化炭素回収システムの概略構成図である。It is a schematic block diagram of the carbon dioxide recovery system which concerns on the 3rd Embodiment of this invention. 本発明の第4の実施形態に係る二酸化炭素回収システムの概略構成図である。It is a schematic block diagram of the carbon dioxide collection system which concerns on the 4th Embodiment of this invention. 本発明の第5の実施形態に係る二酸化炭素回収システムの概略構成図である。It is a schematic block diagram of the carbon dioxide recovery system which concerns on the 5th Embodiment of this invention. 本発明の第6の実施形態に係る二酸化炭素回収システムの概略構成図である。It is a schematic block diagram of the carbon dioxide collection system which concerns on the 6th Embodiment of this invention.

以下、本発明の実施の形態を図面に基づいて説明する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings.

(第1の実施形態)図1に本発明の第1の実施形態に係る二酸化炭素回収システムの概略構成を示す。ここで二酸化炭素回収システムは、二酸化炭素を吸収可能な吸収液を用いて、化石燃料の燃焼により生成された燃焼排ガスに含まれる二酸化炭素を回収するものである。   (First Embodiment) FIG. 1 shows a schematic configuration of a carbon dioxide recovery system according to a first embodiment of the present invention. Here, the carbon dioxide recovery system recovers carbon dioxide contained in combustion exhaust gas generated by the combustion of fossil fuel using an absorbing liquid capable of absorbing carbon dioxide.

図1に示すように二酸化炭素回収システム1は、燃焼排ガス2aに含まれる二酸化炭素を吸収液に吸収させる吸収塔3と、吸収塔3から二酸化炭素を吸収した吸収液(以下、リッチ液4aと記す)が供給され、このリッチ液4aを加熱し、吸収液から蒸気を含む二酸化炭素ガスを放出させて、二酸化炭素ガスと蒸気とを含む排出ガス2cを排出するとともに吸収液を再生する再生塔5とを備える。例えば、火力発電所などの発電設備において生成された燃焼排ガス2aが吸収塔3の下部に供給され、吸収塔3の頂部から二酸化炭素が取り除かれた燃焼排ガス2bが排出されるようになっている。   As shown in FIG. 1, the carbon dioxide recovery system 1 includes an absorption tower 3 that absorbs carbon dioxide contained in the combustion exhaust gas 2a into an absorption liquid, and an absorption liquid that absorbs carbon dioxide from the absorption tower 3 (hereinafter, rich liquid 4a and A regenerating tower that heats the rich liquid 4a, releases carbon dioxide gas containing vapor from the absorbing liquid, discharges exhaust gas 2c containing carbon dioxide gas and steam, and regenerates the absorbing liquid 5. For example, the combustion exhaust gas 2a generated in a power generation facility such as a thermal power plant is supplied to the lower part of the absorption tower 3, and the combustion exhaust gas 2b from which carbon dioxide has been removed is discharged from the top of the absorption tower 3. .

吸収塔3は、吸収液が二酸化炭素を吸収することにより生成されたリッチ液4aを貯留する吸収塔タンク3aを有する。同様に、再生塔5は、リッチ液4aが二酸化炭素ガスを放出することにより再生された吸収液(以下、リーン液4bと記す)を貯留する再生塔タンク5aを有する。   The absorption tower 3 has an absorption tower tank 3a for storing the rich liquid 4a generated by the absorption liquid absorbing carbon dioxide. Similarly, the regeneration tower 5 has a regeneration tower tank 5a that stores an absorbing liquid regenerated by releasing the carbon dioxide gas from the rich liquid 4a (hereinafter referred to as a lean liquid 4b).

ここで、二酸化炭素を吸収可能な吸収液には、例えばアミン化合物を水に溶かしたアミン化合物水溶液が使用される。   Here, as the absorbing solution capable of absorbing carbon dioxide, for example, an amine compound aqueous solution in which an amine compound is dissolved in water is used.

図1に示すように、再生塔5にはリボイラー6が設けられている。リボイラー6は、発電設備から供給されるプラント蒸気等を熱源として、再生塔タンク5aに貯留されていたリーン液4bの一部を加熱してその温度を上昇させて蒸気を生成し、再生塔5に供給する。なお、リボイラー6においてリーン液4bを加熱する際、リーン液4bから微量の二酸化炭素ガスが放出され、蒸気とともに再生塔5に供給される。そして、この蒸気により、再生塔5においてリッチ液4aが加熱されて二酸化炭素ガスが放出される。   As shown in FIG. 1, a reboiler 6 is provided in the regeneration tower 5. The reboiler 6 generates a steam by heating a part of the lean liquid 4b stored in the regeneration tower tank 5a by using plant steam or the like supplied from the power generation equipment as a heat source to increase the temperature thereof. To supply. When heating the lean solution 4b in the reboiler 6, a small amount of carbon dioxide gas is released from the lean solution 4b and supplied to the regeneration tower 5 together with the vapor. Then, the rich liquid 4a is heated in the regeneration tower 5 by this steam, and carbon dioxide gas is released.

吸収塔3と再生塔5との間に、再生塔5から吸収塔3に供給されるリーン液4bを熱源として、吸収塔3から再生塔5に供給されるリッチ液4aを加熱する再生熱交換器7が設けられ、リーン液4bの熱を回収するように構成されている。ここで、上述したように、再生塔5においてリッチ液4aから二酸化炭素ガスを放出させる際、リッチ液4aはリボイラー6からの高温の蒸気を熱源として加熱される。従って、再生熱交換器7に供給されるリーン液4bの温度は比較的高く、このリーン液4bが熱源として用いられている。   Regeneration heat exchange between the absorption tower 3 and the regeneration tower 5 using the lean liquid 4b supplied from the regeneration tower 5 to the absorption tower 3 as a heat source and heating the rich liquid 4a supplied from the absorption tower 3 to the regeneration tower 5. A vessel 7 is provided and configured to recover the heat of the lean liquid 4b. Here, as described above, when the carbon dioxide gas is released from the rich liquid 4 a in the regeneration tower 5, the rich liquid 4 a is heated using high-temperature steam from the reboiler 6 as a heat source. Accordingly, the temperature of the lean liquid 4b supplied to the regenerative heat exchanger 7 is relatively high, and this lean liquid 4b is used as a heat source.

吸収塔3と再生熱交換器7との間に、吸収塔タンク3aの底部から再生熱交換器7にリッチ液4aを供給する第1リッチ液ライン8が連結されている。この第1リッチ液ライン8に、吸収塔3からのリッチ液4aを再生熱交換器7に送り込むリッチ液ポンプ9が設けられている。   A first rich liquid line 8 for supplying the rich liquid 4a from the bottom of the absorption tower tank 3a to the regenerative heat exchanger 7 is connected between the absorption tower 3 and the regenerative heat exchanger 7. A rich liquid pump 9 for sending the rich liquid 4 a from the absorption tower 3 to the regenerative heat exchanger 7 is provided in the first rich liquid line 8.

再生熱交換器7と再生塔5との間に、再生熱交換器7から再生塔5の上部にリッチ液4aを供給する第2リッチ液ライン10が連結されている。   Between the regeneration heat exchanger 7 and the regeneration tower 5, a second rich liquid line 10 for supplying the rich liquid 4a from the regeneration heat exchanger 7 to the upper portion of the regeneration tower 5 is connected.

再生塔5と再生熱交換器7との間に、再生塔タンク5aの底部から再生熱交換器7にリーン液4bを供給する第1リーン液ライン11が連結されている。   Between the regeneration tower 5 and the regeneration heat exchanger 7, a first lean liquid line 11 for supplying the lean liquid 4b to the regeneration heat exchanger 7 from the bottom of the regeneration tower tank 5a is connected.

再生熱交換器7からのリーン液4bは、リーン液ポンプ12により吸収塔3の上部に供給される。なお、リーン液4bは、吸収塔3に供給される前に、吸収液冷却器13により冷却される。吸収液冷却器13は、冷却水(冷却媒体)を冷却源としている。   The lean liquid 4 b from the regenerative heat exchanger 7 is supplied to the upper part of the absorption tower 3 by the lean liquid pump 12. The lean liquid 4b is cooled by the absorption liquid cooler 13 before being supplied to the absorption tower 3. The absorption liquid cooler 13 uses cooling water (cooling medium) as a cooling source.

吸収塔3の上部に供給されたリーン液4bは、吸収塔3内において上部から吸収塔タンク3aに向けて下降する。一方、吸収塔3に供給された燃焼排ガス2aは、吸収塔3内において下部から頂部に向けて上昇する。そのため、二酸化炭素を含む燃焼排ガス2aとリーン液4bが向流接触(直接接触)し、燃焼排ガス2aから二酸化炭素が取り除かれてリーン液4bに吸収され、リッチ液4aが生成される。二酸化炭素が取り除かれた燃焼排ガス2bは、吸収塔3の頂部から排出されるとともに、リッチ液4aは吸収塔3の吸収塔タンク3aに貯留される。   The lean liquid 4b supplied to the upper part of the absorption tower 3 descends from the upper part toward the absorption tower tank 3a in the absorption tower 3. On the other hand, the combustion exhaust gas 2 a supplied to the absorption tower 3 rises from the lower part toward the top in the absorption tower 3. Therefore, the combustion exhaust gas 2a containing carbon dioxide and the lean liquid 4b come into countercurrent contact (direct contact), carbon dioxide is removed from the combustion exhaust gas 2a and absorbed by the lean liquid 4b, and the rich liquid 4a is generated. The combustion exhaust gas 2b from which carbon dioxide has been removed is discharged from the top of the absorption tower 3, and the rich liquid 4a is stored in the absorption tower tank 3a of the absorption tower 3.

再生塔5から排出された二酸化炭素ガスと蒸気とを含む排出ガス2cは、第2リッチ液ライン10に設けられた熱交換器20を介して気液分離器21へ送られる。排出ガス2cとリッチ液4aとが熱交換器20で交流熱交換する。これにより、リッチ液4aは、再生塔5に供給される前に加熱されることになる。   The exhaust gas 2 c containing carbon dioxide gas and steam discharged from the regeneration tower 5 is sent to the gas-liquid separator 21 through the heat exchanger 20 provided in the second rich liquid line 10. The exhaust gas 2 c and the rich liquid 4 a exchange heat with the heat exchanger 20. As a result, the rich liquid 4a is heated before being supplied to the regeneration tower 5.

気液分離器21では排出ガス2cがガス(二酸化炭素)23と液体(水)24に分離される。気液分離器21の頂部から放出されたガス23は、ガス冷却器14で冷却され、気液分離器15に供給される。気液分離器15は、ガス23を凝縮(冷却)して、二酸化炭素ガス(気相成分)と生成された凝縮液(液相成分)とを分離する。気液分離器15から排出された二酸化炭素ガス2dは、貯蔵設備(図示せず)で貯蔵される。ガス冷却器14は、冷却水(冷却媒体)を用いてガス23を冷却する
気液分離器15内の凝縮液16は、凝縮液ポンプ17によって、再生塔5の上部に供給される。
In the gas-liquid separator 21, the exhaust gas 2 c is separated into a gas (carbon dioxide) 23 and a liquid (water) 24. The gas 23 released from the top of the gas-liquid separator 21 is cooled by the gas cooler 14 and supplied to the gas-liquid separator 15. The gas-liquid separator 15 condenses (cools) the gas 23 to separate the carbon dioxide gas (gas phase component) and the generated condensate (liquid phase component). The carbon dioxide gas 2d discharged from the gas-liquid separator 15 is stored in a storage facility (not shown). The gas cooler 14 cools the gas 23 using cooling water (cooling medium). The condensate 16 in the gas-liquid separator 15 is supplied to the upper part of the regeneration tower 5 by a condensate pump 17.

気液分離器21内の液体(水)24は、気液分離器21の底部から排出され、ポンプ22によって第2リッチ液ライン10へ送られる。液体24により、リッチ液4aはさらに加熱され得る。   The liquid (water) 24 in the gas-liquid separator 21 is discharged from the bottom of the gas-liquid separator 21 and sent to the second rich liquid line 10 by the pump 22. The liquid 24 can be further heated by the liquid 24.

再生塔5で吸収液が加熱されるとき、吸収液中の水が蒸発する。従って、リボイラー6によって供給された熱エネルギーの一部が水の蒸発潜熱として消費される。すなわち、リボイラー6によって供給された熱エネルギーの一部が、吸収液中の二酸化炭素の解離に使用されないことになる。   When the absorption liquid is heated in the regeneration tower 5, the water in the absorption liquid evaporates. Therefore, a part of the heat energy supplied by the reboiler 6 is consumed as latent heat of vaporization of water. That is, a part of the thermal energy supplied by the reboiler 6 is not used for dissociation of carbon dioxide in the absorbing liquid.

そこで、本実施形態では、水が持つ蒸発潜熱を利用して、再生塔5からの排出ガス2cとリッチ液4aとを交流熱交換し、リッチ液4aを加熱する。これにより、再生熱交換器7で加熱されたリッチ液4aをさらに加熱することができ、リボイラー6で必要な熱エネルギーを低減できる。   Therefore, in the present embodiment, the latent heat of vaporization of water is used to exchange heat between the exhaust gas 2c from the regeneration tower 5 and the rich liquid 4a to heat the rich liquid 4a. As a result, the rich liquid 4a heated by the regenerative heat exchanger 7 can be further heated, and the necessary heat energy can be reduced by the reboiler 6.

例えば、リッチ液4aは、再生熱交換器7で加熱されて約100℃になり、熱交換器20によってさらに加熱され約105℃になる。リッチ液4aが5℃上昇した分だけ、リボイラー6で必要な熱エネルギーを低減できる。   For example, the rich liquid 4 a is heated by the regenerative heat exchanger 7 to about 100 ° C., and further heated by the heat exchanger 20 to about 105 ° C. The amount of heat energy required by the reboiler 6 can be reduced by the amount of the rich liquid 4a increased by 5 ° C.

本実施形態に係る二酸化炭素回収システムは、排出ガス2cの余熱を利用してリッチ液4aを加熱するため、再生塔5からの排出ガス2cをガス冷却器14へ直接送る場合よりも、リボイラー6で必要な熱エネルギーが小さくなる。   Since the carbon dioxide recovery system according to the present embodiment heats the rich liquid 4a using the residual heat of the exhaust gas 2c, the reboiler 6 is used rather than the case where the exhaust gas 2c from the regeneration tower 5 is sent directly to the gas cooler 14. This reduces the required heat energy.

本実施形態では、再生塔5からの排出ガス2cをガス冷却器14へ送る場合と比較して、気液分離器21内の液体(水)24を第2リッチ液ライン10へ送るポンプ22の運転コストが余分にかかるが、これはリボイラー6で必要な熱エネルギーを低減できる分より小さく、二酸化炭素回収システム全体としての運転コストを低減できる。   In the present embodiment, the pump 22 that sends the liquid (water) 24 in the gas-liquid separator 21 to the second rich liquid line 10 is compared with the case where the exhaust gas 2 c from the regeneration tower 5 is sent to the gas cooler 14. Although the operation cost is excessive, this is smaller than the amount of heat energy required for the reboiler 6 can be reduced, and the operation cost of the entire carbon dioxide recovery system can be reduced.

このように、再生塔5からの排出ガス2cの熱を利用してリッチ液4aを加熱することで、吸収液の再生工程で必要となる熱エネルギーを低減し、二酸化炭素回収システムの運転コストを低減できる。   In this way, by heating the rich liquid 4a using the heat of the exhaust gas 2c from the regeneration tower 5, the thermal energy required in the regeneration process of the absorbing liquid is reduced, and the operating cost of the carbon dioxide recovery system is reduced. Can be reduced.

上記第1の実施形態では、図1に示すように、熱交換器20を再生熱交換器7と再生塔5との間(第2リッチ液ライン10)に設けていたが、図2に示すように、吸収塔3と再生熱交換器7との間(第1リッチ液ライン8)に設けてもよい。このような構成にしても、同様の効果を得ることができる。   In the first embodiment, as shown in FIG. 1, the heat exchanger 20 is provided between the regeneration heat exchanger 7 and the regeneration tower 5 (second rich liquid line 10). Thus, you may provide between the absorption tower 3 and the regeneration heat exchanger 7 (1st rich liquid line 8). Even if it is such a structure, the same effect can be acquired.

また、上記第1の実施形態において、気液分離器21を設けず、熱交換器20を通過した排出ガス2cをガス冷却器14へ直接送るようにしてもよい。   In the first embodiment, the gas-liquid separator 21 may not be provided, and the exhaust gas 2c that has passed through the heat exchanger 20 may be sent directly to the gas cooler 14.

また、気液分離器21が高い気液分離性能を有する場合は、気液分離器15を設けず、ガス冷却器14を通過したガス(二酸化炭素ガス)23を排出し、貯蔵設備(図示せず)で貯蔵するようにしてもよい。   When the gas-liquid separator 21 has high gas-liquid separation performance, the gas-liquid separator 15 is not provided, the gas (carbon dioxide gas) 23 that has passed through the gas cooler 14 is discharged, and storage equipment (not shown) You may make it store it.

(第2の実施形態)図3に本発明の第2の実施形態に係る二酸化炭素回収システムの概略構成を示す。本実施形態では、リッチ液4aが気液分離器201で気相成分(二酸化炭素)と液相成分に分離され、気相成分がガス冷却器14へ送られ、液相成分がポンプ22により再生塔5に供給されており、他の構成は、図1に示す第1の実施形態と同様となっている。図3において、図1に示す第1の実施形態と同一部分には同一符号を付して説明を省略する。   (Second Embodiment) FIG. 3 shows a schematic configuration of a carbon dioxide recovery system according to a second embodiment of the present invention. In the present embodiment, the rich liquid 4 a is separated into a gas phase component (carbon dioxide) and a liquid phase component by the gas-liquid separator 201, the gas phase component is sent to the gas cooler 14, and the liquid phase component is regenerated by the pump 22. The other configuration is supplied to the tower 5 and is the same as that of the first embodiment shown in FIG. In FIG. 3, the same parts as those of the first embodiment shown in FIG.

気液分離器201により、リッチ液4aに含まれる二酸化炭素の一部が放出され、ガス冷却器14へ送られる。すなわち、気液分離器201の下部から排出される液相成分は、リッチ液4aから二酸化炭素が一部放出されたものとなる。   A part of the carbon dioxide contained in the rich liquid 4 a is released by the gas-liquid separator 201 and sent to the gas cooler 14. That is, the liquid phase component discharged from the lower part of the gas-liquid separator 201 is a part of carbon dioxide released from the rich liquid 4a.

本実施形態では、上記第1の実施形態と比較して、再生塔5に供給されるリッチ液中の二酸化炭素量を低減できる。従って、再生塔5において、吸収液から放出させる二酸化炭素量を減らせるため、再生塔5内での二酸化炭素の吸収液への再吸収を減らせることで、必要とされるリボイラー6の熱エネルギーをさらに低減できる。   In the present embodiment, the amount of carbon dioxide in the rich liquid supplied to the regeneration tower 5 can be reduced as compared with the first embodiment. Therefore, in the regeneration tower 5, the amount of carbon dioxide released from the absorption liquid can be reduced. Therefore, the resorption of the carbon dioxide in the absorption liquid in the regeneration tower 5 can be reduced, so that the necessary thermal energy of the reboiler 6 is obtained. Can be further reduced.

このように、再生塔5からの排出ガス2cの熱を利用してリッチ液4aを加熱し、加熱後のリッチ液4a中の二酸化炭素の一部を気液分離器201で分離、放出させることで、吸収液の再生工程で必要となる熱エネルギーをさらに低減し、二酸化炭素回収システムの運転コストをさらに低減できる。   Thus, the rich liquid 4a is heated using the heat of the exhaust gas 2c from the regeneration tower 5, and a part of the carbon dioxide in the rich liquid 4a after heating is separated and released by the gas-liquid separator 201. Thus, it is possible to further reduce the thermal energy required in the absorption liquid regeneration process and further reduce the operating cost of the carbon dioxide recovery system.

(第3の実施形態)図4に本発明の第3の実施形態に係る二酸化炭素回収システムの概略構成を示す。本実施形態では、気液分離器21内の液体(水)24が、ポンプ22によってリボイラー6へ送られており、他の構成は、図1に示す第1の実施形態と同様となっている。図4において、図1に示す第1の実施形態と同一部分には同一符号を付して説明を省略する。   (Third Embodiment) FIG. 4 shows a schematic configuration of a carbon dioxide recovery system according to a third embodiment of the present invention. In this embodiment, the liquid (water) 24 in the gas-liquid separator 21 is sent to the reboiler 6 by the pump 22, and the other configuration is the same as that of the first embodiment shown in FIG. . In FIG. 4, the same parts as those of the first embodiment shown in FIG.

液体24は、リボイラー6に供給され、液体24に溶存する二酸化炭素の放出が行われる。これにより、再生塔5における加熱により放出された二酸化炭素が、再生塔5に供給された液体24に再吸収されることを防止することができ、必要とされるリボイラー6の熱エネルギーをさらに低減できる。   The liquid 24 is supplied to the reboiler 6 and carbon dioxide dissolved in the liquid 24 is released. As a result, carbon dioxide released by heating in the regeneration tower 5 can be prevented from being reabsorbed by the liquid 24 supplied to the regeneration tower 5, and the required thermal energy of the reboiler 6 can be further reduced. it can.

本実施形態では、上記第1の実施形態と同様に、再生塔5からの排出ガス2cの熱を利用してリッチ液4aを加熱することで、吸収液の再生工程で必要となる熱エネルギーを低減し、二酸化炭素回収システムの運転コストを低減できる。   In the present embodiment, as in the first embodiment, the heat of the exhaust gas 2c from the regeneration tower 5 is used to heat the rich liquid 4a, so that the thermal energy required for the absorption liquid regeneration process is obtained. This can reduce the operating cost of the carbon dioxide recovery system.

また、再生塔5に供給された液体24への二酸化炭素の再吸収を防止し、吸収液の再生工程で必要となる熱エネルギーをさらに低減し、二酸化炭素回収システムの運転コストをさらに低減できる。   Further, it is possible to prevent the carbon dioxide from being reabsorbed into the liquid 24 supplied to the regeneration tower 5, further reduce the thermal energy required in the regeneration process of the absorbent, and further reduce the operating cost of the carbon dioxide recovery system.

また、本実施形態では、気液分離器21が高い気液分離性能を有する場合は、気液分離器15を設けず、ガス冷却器14を通過したガス(二酸化炭素ガス)23を排出し、貯蔵設備(図示せず)で貯蔵するようにしてもよい。   Further, in the present embodiment, when the gas-liquid separator 21 has high gas-liquid separation performance, the gas (carbon dioxide gas) 23 that has passed through the gas cooler 14 is discharged without providing the gas-liquid separator 15, You may make it store with a storage facility (not shown).

(第4の実施形態)図5に本発明の第4の実施形態に係る二酸化炭素回収システムの概略構成を示す。本実施形態では、リッチ液4aが気液分離器401で気相成分(二酸化炭素)と液相成分に分離され、気相成分がガス冷却器14へ送られ、液相成分がポンプ402により再生塔5に供給されており、他の構成は、図4に示す第3の実施形態と同様となっている。図5において、図4に示す第3の実施形態と同一部分には同一符号を付して説明を省略する。   (Fourth Embodiment) FIG. 5 shows a schematic configuration of a carbon dioxide recovery system according to a fourth embodiment of the present invention. In the present embodiment, the rich liquid 4 a is separated into a gas phase component (carbon dioxide) and a liquid phase component by the gas-liquid separator 401, the gas phase component is sent to the gas cooler 14, and the liquid phase component is regenerated by the pump 402. The other components are supplied to the tower 5 and are the same as those of the third embodiment shown in FIG. In FIG. 5, the same parts as those of the third embodiment shown in FIG.

気液分離器401により、リッチ液4aに含まれる二酸化炭素の一部が放出され、ガス冷却器14へ送られる。すなわち、気液分離器401の下部から排出される液相成分は、リッチ液4aから二酸化炭素が一部放出されたものとなる。   A part of the carbon dioxide contained in the rich liquid 4 a is released by the gas-liquid separator 401 and sent to the gas cooler 14. That is, the liquid phase component discharged from the lower part of the gas-liquid separator 401 is a part of carbon dioxide released from the rich liquid 4a.

本実施形態では、上記第3の実施形態と比較して、再生塔5に供給されるリッチ液中の二酸化炭素量を低減できる。従って、再生塔5において、吸収液から放出させる二酸化炭素量を減らせるため、再生塔5内での二酸化炭素の吸収液への再吸収を減らせることで、必要とされるリボイラー6の熱エネルギーをさらに低減できる。   In the present embodiment, the amount of carbon dioxide in the rich liquid supplied to the regeneration tower 5 can be reduced as compared with the third embodiment. Therefore, in the regeneration tower 5, the amount of carbon dioxide released from the absorption liquid can be reduced. Therefore, the resorption of the carbon dioxide in the absorption liquid in the regeneration tower 5 can be reduced, so that the necessary thermal energy of the reboiler 6 is obtained. Can be further reduced.

このように、再生塔5からの排出ガス2cの熱を利用してリッチ液4aを加熱し、加熱後のリッチ液4a中の二酸化炭素の一部を気液分離器401で分離、放出させ、気液分離器21中の液体24をリボイラー6へ供給することで、吸収液の再生工程で必要となる熱エネルギーをさらに低減し、二酸化炭素回収システムの運転コストをさらに低減できる。   Thus, the rich liquid 4a is heated using the heat of the exhaust gas 2c from the regeneration tower 5, and a part of carbon dioxide in the rich liquid 4a after heating is separated and released by the gas-liquid separator 401, By supplying the liquid 24 in the gas-liquid separator 21 to the reboiler 6, it is possible to further reduce the thermal energy required in the regeneration process of the absorbing liquid and further reduce the operating cost of the carbon dioxide recovery system.

(第5の実施形態)図6に本発明の第5の実施形態に係る二酸化炭素回収システムの概略構成を示す。本実施形態では、気液分離器21内の液体24がポンプ22により第1リッチ液ライン8に設けられた熱交換器501に送られ、他の構成は、図1に示す第1の実施形態と同様となっている。図6において、図1に示す第1の実施形態と同一部分には同一符号を付して説明を省略する。   (Fifth Embodiment) FIG. 6 shows a schematic configuration of a carbon dioxide recovery system according to a fifth embodiment of the present invention. In the present embodiment, the liquid 24 in the gas-liquid separator 21 is sent to the heat exchanger 501 provided in the first rich liquid line 8 by the pump 22, and the other configuration is the first embodiment shown in FIG. It has become the same. In FIG. 6, the same parts as those of the first embodiment shown in FIG.

気液分離器21中の液体24は高温であり、この液体24を熱源とし、水が持つ顕熱を利用して、熱交換器501においてリッチ液4aが加熱される。リッチ液4aを加熱した後の液体24は、気液分離器15へ供給され、還流液として再利用される。このような構成にすることで、再生塔5からの排出ガス2cの熱を最大限に回収できるようになり、必要とされるリボイラー6の熱エネルギーをさらに低減できる。   The liquid 24 in the gas-liquid separator 21 has a high temperature, and the rich liquid 4a is heated in the heat exchanger 501 using the liquid 24 as a heat source and utilizing sensible heat of water. The liquid 24 after heating the rich liquid 4a is supplied to the gas-liquid separator 15 and reused as a reflux liquid. With such a configuration, the heat of the exhaust gas 2c from the regeneration tower 5 can be recovered to the maximum, and the required thermal energy of the reboiler 6 can be further reduced.

本実施形態では、上記第1の実施形態と同様に、再生塔5からの排出ガス2cの熱を利用してリッチ液4aを加熱することで、吸収液の再生工程で必要となる熱エネルギーを低減し、二酸化炭素回収システムの運転コストを低減できる。   In the present embodiment, as in the first embodiment, the heat of the exhaust gas 2c from the regeneration tower 5 is used to heat the rich liquid 4a, so that the thermal energy required for the absorption liquid regeneration process is obtained. This can reduce the operating cost of the carbon dioxide recovery system.

さらに、気液分離器21中の液体24の顕熱を利用してリッチ液4aをさらに加熱することで、吸収液の再生工程で必要となる熱エネルギーを低減し、二酸化炭素回収システムの運転コストを低減できる。   Furthermore, by further heating the rich liquid 4a using the sensible heat of the liquid 24 in the gas-liquid separator 21, the thermal energy required in the regeneration process of the absorbing liquid is reduced, and the operating cost of the carbon dioxide recovery system Can be reduced.

(第6の実施形態)図7に本発明の第6の実施形態に係る二酸化炭素回収システムの概略構成を示す。本実施形態では、リッチ液4aが気液分離器601で気相成分(二酸化炭素)と液相成分に分離され、気相成分がガス冷却器14へ送られ、液相成分がポンプ602により再生塔5に供給されており、他の構成は、図6に示す第5の実施形態と同様となっている。図7において、図6に示す第5の実施形態と同一部分には同一符号を付して説明を省略する。   (Sixth Embodiment) FIG. 7 shows a schematic configuration of a carbon dioxide recovery system according to a sixth embodiment of the present invention. In the present embodiment, the rich liquid 4 a is separated into a gas phase component (carbon dioxide) and a liquid phase component by the gas-liquid separator 601, the gas phase component is sent to the gas cooler 14, and the liquid phase component is regenerated by the pump 602. The other structure is supplied to the tower 5 and is the same as that of the fifth embodiment shown in FIG. In FIG. 7, the same parts as those of the fifth embodiment shown in FIG.

気液分離器601により、リッチ液4aに含まれる二酸化炭素の一部が放出され、ガス冷却器14へ送られる。すなわち、気液分離器601の下部から排出される液相成分は、リッチ液4aから二酸化炭素が一部放出されたものとなる。   A part of carbon dioxide contained in the rich liquid 4 a is released by the gas-liquid separator 601 and sent to the gas cooler 14. That is, the liquid phase component discharged from the lower part of the gas-liquid separator 601 is a part of carbon dioxide released from the rich liquid 4a.

本実施形態では、上記第5の実施形態と比較して、再生塔5に供給されるリッチ液中の二酸化炭素量を低減できる。従って、再生塔5において、吸収液から放出させる二酸化炭素量を減らせるため、再生塔5内での二酸化炭素の吸収液への再吸収を減らせることで、必要とされるリボイラー6の熱エネルギーをさらに低減できる。   In the present embodiment, the amount of carbon dioxide in the rich liquid supplied to the regeneration tower 5 can be reduced as compared with the fifth embodiment. Therefore, in the regeneration tower 5, the amount of carbon dioxide released from the absorption liquid can be reduced. Therefore, the resorption of the carbon dioxide in the absorption liquid in the regeneration tower 5 can be reduced, so that the necessary thermal energy of the reboiler 6 is obtained. Can be further reduced.

このように、再生塔5からの排出ガス2cの熱を利用してリッチ液4aを加熱し、加熱後のリッチ液4a中の二酸化炭素の一部を気液分離器601で分離、放出させ、気液分離器21中の液体24でリッチ液4aを加熱することで、吸収液の再生工程で必要となる熱エネルギーをさらに低減し、二酸化炭素回収システムの運転コストをさらに低減できる。   Thus, the rich liquid 4a is heated using the heat of the exhaust gas 2c from the regeneration tower 5, and a part of carbon dioxide in the rich liquid 4a after heating is separated and released by the gas-liquid separator 601. Heating the rich liquid 4a with the liquid 24 in the gas-liquid separator 21 can further reduce the thermal energy required in the regeneration process of the absorbent and further reduce the operating cost of the carbon dioxide recovery system.

なお、本発明は上記実施形態そのままに限定されるものではなく、実施段階ではその要旨を逸脱しない範囲で構成要素を変形して具体化できる。また、上記実施形態に開示されている複数の構成要素の適宜な組み合わせにより、種々の発明を形成できる。例えば、実施形態に示される全構成要素から幾つかの構成要素を削除してもよい。さらに、異なる実施形態にわたる構成要素を適宜組み合わせてもよい。   Note that the present invention is not limited to the above-described embodiment as it is, and can be embodied by modifying the constituent elements without departing from the scope of the invention in the implementation stage. In addition, various inventions can be formed by appropriately combining a plurality of components disclosed in the embodiment. For example, some components may be deleted from all the components shown in the embodiment. Furthermore, constituent elements over different embodiments may be appropriately combined.

1 二酸化炭素回収システム
3 吸収塔
5 再生塔
6 リボイラー
7 再生熱交換器
13 吸収液冷却器
14 ガス冷却器
15、21 気液分離器
20 熱交換器
DESCRIPTION OF SYMBOLS 1 Carbon dioxide recovery system 3 Absorption tower 5 Regeneration tower 6 Reboiler 7 Regenerative heat exchanger 13 Absorbent liquid cooler 14 Gas cooler 15, 21 Gas-liquid separator 20 Heat exchanger

Claims (7)

燃焼排ガスに含まれる二酸化炭素を吸収液に吸収させる吸収塔と、
前記吸収塔から二酸化炭素を吸収した吸収液が供給され、当該吸収液から蒸気を含む二酸化炭素ガスを放出させるとともに当該吸収液を再生し、放出された二酸化炭素ガス及び蒸気を含む排出ガスを排出する再生塔と、
前記吸収塔と前記再生塔との間に設けられ、前記再生塔から前記吸収塔に供給される再生された吸収液を熱源として、前記吸収塔から前記再生塔に供給される二酸化炭素を吸収した吸収液を加熱する再生熱交換器と、
前記吸収塔と前記再生熱交換器との間、又は前記再生熱交換器と前記再生塔との間に設けられ、前記再生塔から排出される前記排出ガスを熱源として、前記吸収塔から前記再生塔に供給される二酸化炭素を吸収した吸収液を加熱する熱交換器と、
を備える二酸化炭素回収システム。
An absorption tower for absorbing carbon dioxide contained in the combustion exhaust gas into the absorption liquid;
An absorption liquid that absorbs carbon dioxide is supplied from the absorption tower, and carbon dioxide gas containing vapor is released from the absorption liquid and the absorption liquid is regenerated, and the discharged carbon dioxide gas and exhaust gas containing vapor are discharged. A regenerating tower,
The carbon dioxide supplied from the absorption tower to the regeneration tower is absorbed by the regenerated absorption liquid provided between the absorption tower and the regeneration tower and supplied from the regeneration tower to the absorption tower as a heat source. A regenerative heat exchanger for heating the absorption liquid;
Provided between the absorption tower and the regeneration heat exchanger, or between the regeneration heat exchanger and the regeneration tower, and using the exhaust gas discharged from the regeneration tower as a heat source, the regeneration from the absorption tower. A heat exchanger for heating the absorption liquid that has absorbed carbon dioxide supplied to the tower;
A carbon dioxide recovery system.
前記熱交換器を通過した前記排出ガスを液相成分と気相成分とに分離する気液分離器と、
前記液相成分を前記再生塔へ供給するポンプと、
をさらに備えることを特徴とする請求項1に記載の二酸化炭素回収システム。
A gas-liquid separator that separates the exhaust gas that has passed through the heat exchanger into a liquid phase component and a gas phase component;
A pump for supplying the liquid phase component to the regeneration tower;
The carbon dioxide recovery system according to claim 1, further comprising:
前記気相成分を凝縮し、生成された凝縮液を分離する第2の気液分離器と、
前記再生熱交換器及び前記熱交換器を通過した前記吸収塔から前記再生塔に供給される二酸化炭素を吸収した吸収液を液相成分と気相成分とに分離する第3の気液分離器と、
をさらに備え、
前記第3の気液分離器で分離された気相成分は前記第2の気液分離器へ供給され、前記第3の気液分離器で分離された液相成分は前記ポンプにより前記再生塔へ供給されることを特徴とする請求項2に記載の二酸化炭素回収システム。
A second gas-liquid separator that condenses the gas phase component and separates the generated condensate;
A third gas-liquid separator that separates an absorption liquid that has absorbed carbon dioxide supplied to the regeneration tower from the regeneration heat exchanger and the absorption tower that has passed through the heat exchanger into a liquid phase component and a gas phase component When,
Further comprising
The gas phase component separated by the third gas-liquid separator is supplied to the second gas-liquid separator, and the liquid phase component separated by the third gas-liquid separator is supplied to the regeneration tower by the pump. The carbon dioxide recovery system according to claim 2, wherein the carbon dioxide recovery system is supplied to.
前記再生塔内の吸収液を加熱するリボイラーと、
前記熱交換器を通過した前記排出ガスを液相成分と気相成分とに分離する気液分離器と、
前記液相成分を前記リボイラーへ供給するポンプと、
をさらに備えることを特徴とする請求項1に記載の二酸化炭素回収システム。
A reboiler for heating the absorbent in the regeneration tower;
A gas-liquid separator that separates the exhaust gas that has passed through the heat exchanger into a liquid phase component and a gas phase component;
A pump for supplying the liquid phase component to the reboiler;
The carbon dioxide recovery system according to claim 1, further comprising:
前記気相成分を凝縮し、生成された凝縮液を分離する第2の気液分離器と、
前記再生熱交換器及び前記熱交換器を通過した前記吸収塔から前記再生塔に供給される二酸化炭素を吸収した吸収液を液相成分と気相成分とに分離する第3の気液分離器と、
前記第3の気液分離器で分離された液相成分を前記再生塔へ供給する第2のポンプと、
をさらに備え、
前記第3の気液分離器で分離された気相成分は前記第2の気液分離器へ供給されることを特徴とする請求項4に記載の二酸化炭素回収システム。
A second gas-liquid separator that condenses the gas phase component and separates the generated condensate;
A third gas-liquid separator that separates an absorption liquid that has absorbed carbon dioxide supplied to the regeneration tower from the absorption tower that has passed through the regeneration heat exchanger and the heat exchanger into a liquid phase component and a gas phase component When,
A second pump for supplying the liquid phase component separated by the third gas-liquid separator to the regeneration tower;
Further comprising
The carbon dioxide recovery system according to claim 4, wherein the gas phase component separated by the third gas-liquid separator is supplied to the second gas-liquid separator.
前記熱交換器を通過した前記排出ガスを液相成分と気相成分とに分離する第1の気液分離器と、
前記気相成分を凝縮し、生成された凝縮液を分離する第2の気液分離器と、
前記吸収塔と前記再生熱交換器との間、又は前記再生熱交換器と前記再生塔との間に設けられ、前記液相成分を熱源として、前記吸収塔から前記再生塔に供給される二酸化炭素を吸収した吸収液を加熱する第2の熱交換器と、
前記第1の気液分離器からの前記液相成分を前記第2の熱交換器へ供給するポンプと、
をさらに備え、
前記第2の熱交換器を通過した前記液相成分は前記第2の気液分離器へ供給されることを特徴とする請求項1に記載の二酸化炭素回収システム。
A first gas-liquid separator that separates the exhaust gas that has passed through the heat exchanger into a liquid phase component and a gas phase component;
A second gas-liquid separator that condenses the gas phase component and separates the generated condensate;
Provided between the absorption tower and the regeneration heat exchanger, or between the regeneration heat exchanger and the regeneration tower, and supplied from the absorption tower to the regeneration tower using the liquid phase component as a heat source. A second heat exchanger for heating the absorbing liquid that has absorbed carbon;
A pump for supplying the liquid phase component from the first gas-liquid separator to the second heat exchanger;
Further comprising
The carbon dioxide recovery system according to claim 1, wherein the liquid phase component that has passed through the second heat exchanger is supplied to the second gas-liquid separator.
前記再生熱交換器、前記熱交換器、及び前記第2の熱交換器を通過した前記吸収塔から前記再生塔に供給される二酸化炭素を吸収した吸収液を液相成分と気相成分とに分離する第3の気液分離器と、
前記第3の気液分離器で分離された液相成分を前記再生塔へ供給する第2のポンプと、
をさらに備え、
前記第3の気液分離器で分離された気相成分は前記第2の気液分離器へ供給されることを特徴とする請求項6に記載の二酸化炭素回収システム。
An absorption liquid that has absorbed carbon dioxide supplied to the regeneration tower from the absorption tower that has passed through the regeneration heat exchanger, the heat exchanger, and the second heat exchanger is converted into a liquid phase component and a gas phase component. A third gas-liquid separator to be separated;
A second pump for supplying the liquid phase component separated by the third gas-liquid separator to the regeneration tower;
Further comprising
The carbon dioxide recovery system according to claim 6, wherein the gas phase component separated by the third gas-liquid separator is supplied to the second gas-liquid separator.
JP2009095678A 2009-04-10 2009-04-10 Carbon dioxide recovery system Pending JP2010240629A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009095678A JP2010240629A (en) 2009-04-10 2009-04-10 Carbon dioxide recovery system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2009095678A JP2010240629A (en) 2009-04-10 2009-04-10 Carbon dioxide recovery system

Publications (1)

Publication Number Publication Date
JP2010240629A true JP2010240629A (en) 2010-10-28

Family

ID=43094299

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2009095678A Pending JP2010240629A (en) 2009-04-10 2009-04-10 Carbon dioxide recovery system

Country Status (1)

Country Link
JP (1) JP2010240629A (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011213494A (en) * 2010-03-31 2011-10-27 Nippon Steel Engineering Co Ltd Carbon dioxide gas recovery apparatus
JP2012106180A (en) * 2010-11-17 2012-06-07 Toshiba Corp Carbon dioxide recovery apparatus and carbon dioxide recovery method
JP2013184090A (en) * 2012-03-06 2013-09-19 Toshiba Corp Carbon dioxide recovery apparatus and carbon dioxide recovery method
JP2015024374A (en) * 2013-07-26 2015-02-05 株式会社Ihi Carbon dioxide recovery method and recovery device
KR20150019394A (en) * 2013-08-13 2015-02-25 한국전력공사 Apparatus for carbon dioxide separation and removal
WO2015076449A1 (en) * 2013-11-21 2015-05-28 한국에너지기술연구원 Energy-saving acidic gas capture system and method using condensed water
CN105477990A (en) * 2014-09-04 2016-04-13 汪上晓 Carbon dioxide capture system
KR101899600B1 (en) * 2012-09-28 2018-09-17 한국전력공사 Apparatus for treating carbon dioxide
CN111701402A (en) * 2020-06-24 2020-09-25 中国石油大学(华东) A carbon dioxide capture and regeneration tower top waste heat recovery system and process
CN112933886A (en) * 2021-04-02 2021-06-11 中国华电科工集团有限公司 Carbon dioxide entrapment waste heat flash regeneration system
WO2022031074A1 (en) * 2020-08-07 2022-02-10 주식회사 엘지화학 Method and apparatus for manufacturing silica aerogel blanket
CN114788992A (en) * 2022-03-09 2022-07-26 国家电投集团远达环保股份有限公司 Carbon capture system and power plant boiler steam turbine system coupled with carbon capture system

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008144918A1 (en) * 2007-05-29 2008-12-04 University Of Regina Method and absorbent composition for recovering a gaseous component from a gas stream
JP2009214089A (en) * 2008-03-13 2009-09-24 Research Institute Of Innovative Technology For The Earth Carbon dioxide recovery apparatus and method therefor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008144918A1 (en) * 2007-05-29 2008-12-04 University Of Regina Method and absorbent composition for recovering a gaseous component from a gas stream
JP2010527774A (en) * 2007-05-29 2010-08-19 ユニヴァーシティ オブ レジャイナ Method and absorbent composition for recovering a gas component from a gas stream
JP2009214089A (en) * 2008-03-13 2009-09-24 Research Institute Of Innovative Technology For The Earth Carbon dioxide recovery apparatus and method therefor

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011213494A (en) * 2010-03-31 2011-10-27 Nippon Steel Engineering Co Ltd Carbon dioxide gas recovery apparatus
US9155991B2 (en) 2010-11-17 2015-10-13 Kabushiki Kaisha Toshiba Carbon dioxide recovery apparatus and carbon dioxide recovery method
JP2012106180A (en) * 2010-11-17 2012-06-07 Toshiba Corp Carbon dioxide recovery apparatus and carbon dioxide recovery method
US9731244B2 (en) 2010-11-17 2017-08-15 Kabushiki Kaisha Toshiba Carbon dioxide recovery apparatus and carbon dioxide recovery method
JP2013184090A (en) * 2012-03-06 2013-09-19 Toshiba Corp Carbon dioxide recovery apparatus and carbon dioxide recovery method
KR101899600B1 (en) * 2012-09-28 2018-09-17 한국전력공사 Apparatus for treating carbon dioxide
JP2015024374A (en) * 2013-07-26 2015-02-05 株式会社Ihi Carbon dioxide recovery method and recovery device
KR20150019394A (en) * 2013-08-13 2015-02-25 한국전력공사 Apparatus for carbon dioxide separation and removal
KR102077344B1 (en) 2013-08-13 2020-02-13 한국전력공사 Apparatus for carbon dioxide separation and removal
WO2015076449A1 (en) * 2013-11-21 2015-05-28 한국에너지기술연구원 Energy-saving acidic gas capture system and method using condensed water
CN105477990A (en) * 2014-09-04 2016-04-13 汪上晓 Carbon dioxide capture system
CN111701402A (en) * 2020-06-24 2020-09-25 中国石油大学(华东) A carbon dioxide capture and regeneration tower top waste heat recovery system and process
WO2022031074A1 (en) * 2020-08-07 2022-02-10 주식회사 엘지화학 Method and apparatus for manufacturing silica aerogel blanket
CN112933886A (en) * 2021-04-02 2021-06-11 中国华电科工集团有限公司 Carbon dioxide entrapment waste heat flash regeneration system
CN114788992A (en) * 2022-03-09 2022-07-26 国家电投集团远达环保股份有限公司 Carbon capture system and power plant boiler steam turbine system coupled with carbon capture system

Similar Documents

Publication Publication Date Title
JP2010240629A (en) Carbon dioxide recovery system
JP5021917B2 (en) CO2 recovery apparatus and method
JP4875303B2 (en) Carbon dioxide recovery system, power generation system using the same, and methods thereof
JP4745682B2 (en) CO2 recovery apparatus and method
JP4690659B2 (en) CO2 recovery device
JP5922451B2 (en) CO2 recovery device
JP4956519B2 (en) Carbon dioxide recovery system
RU2389534C2 (en) Device to extract co2 and method of wastes removal
JP5349221B2 (en) Carbon dioxide recovery device
JP2010100492A (en) Method and apparatus for recovering carbon dioxide
JP4773865B2 (en) CO2 recovery device and CO2 recovery method
JP2010235395A (en) Apparatus for recovering carbon dioxide, and thermal power system with apparatus for recovering carbon dioxide
JP5931834B2 (en) Reclaiming apparatus and method, CO2 and / or H2S recovery apparatus
JP2011173047A (en) Co2 recovery apparatus and co2 recovering method
JP2008307520A (en) Co2 or h2s removal system, co2 or h2s removal method
JP6088240B2 (en) Carbon dioxide recovery device and method of operating the recovery device
JP5591083B2 (en) CO2 recovery system
JP5174194B2 (en) CO2 recovery apparatus and method
CN104936678B (en) Containing CO2And H2The recovery system and recovery method of the gas of S
US20140005460A1 (en) Heat recovery from sorbent-based co2 capture
JP5737916B2 (en) CO2 recovery system
JP2005195283A (en) CO2 absorption method in by-product gas using waste heat of circulating refrigerant of stave cooler
KR20120013588A (en) CO2 recovery device
US20170014767A1 (en) Acid gas capture system and method saving energy by cooling absorbent, which has passed reboiler, by means of steam condensate
JP2014205102A (en) Method and apparatus for recovering carbon dioxide in gas to be treated

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20120220

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20120829

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130705

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20140121