JP2010064296A - Heat barrier sheet - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a heat barrier sheet which is inexpensive and maintains heat barrier properties. <P>SOLUTION: The heat barrier sheet 10 includes: an aluminum base-material 1, at least one surface of which has a surface roughness Ra of ≤0.2 μm; a non-porous anodic oxidation film 2 deposited on the surface having the surface roughness Ra of ≤0.2 μm, of the aluminum base-material, and having a thickness of 50 to 150 nm and thickness variation of ≤±5 nm; and a protection film 3 deposited on the non-porous anodic oxidation film 2, formed of acrylic resin having a thickness of 0.5 to 3 μm and a dynamic friction coefficient of ≤0.15. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a heat shield sheet provided outdoors such as a roof of a building, a container, or a truck bed.

  Light (electromagnetic waves) that reaches the ground from the sun is called solar radiation, and a thermal insulation sheet is a sheet that shields summer solar heat from outside the building, etc., so that there is no effect on the interior, especially in summer. This leads to power saving for air conditioners and the like used for temperature adjustment, and is highly desirable from the viewpoint of the global environment.

Aluminum is known to reflect sunlight well. However, when aluminum is used outdoors, the reflectance gradually decreases due to generation of white rust due to moisture, dust, etc., or scratches due to contact objects.
As a heat shield sheet, a sheet in which the front side of an aluminum vapor deposition film is reinforced with a film, and a heat insulating material such as a woven fabric or a foam sheet is laminated on the back side with an adhesive has been proposed (for example, a patent) Literature 1, Patent Literature 2).
In the heat shield sheets disclosed in Patent Document 1 and Patent Document 2, although the heat shield effect is high, the durability of the film on the surface and the deposited film of aluminum cannot be said to be sufficient. When washed, there was a problem that the film and the deposited film peeled off. Moreover, it was expensive in cost.

On the other hand, it has also been proposed to perform a base treatment such as chemical conversion treatment on an aluminum substrate and to spread a coating film containing a reflective pigment thereon (Patent Document 3), but such a paint is generally expensive. In addition, a film thickness exceeding 5 μm is required, resulting in high costs.
JP 2001-191453 A Japanese Patent Laid-Open No. 2007-7907 Japanese Patent No. 3376949

  The present invention has been made based on such a technical problem, and an object thereof is to provide a heat shield sheet that is inexpensive and can maintain heat shield characteristics.

  As a result of earnest research on the heat shield sheet, the conventional heat shield sheet tried to obtain a heat shield effect by using solar reflection by aluminum and heat insulation by a coating film, foam sheet, etc. Heat is mostly due to solar reflection, and heat insulation is not very effective. That is, a practically sufficient heat shielding effect can be obtained if the high reflectance of aluminum can be maintained. As a method for maintaining a high reflectance of aluminum, a method of providing a transparent protective film on a nonporous anodic oxide film is the most inexpensive and highly effective. Based on this knowledge, the heat-shielding sheet of the present invention has an aluminum substrate having a surface roughness Ra of 0.2 μm or less on at least one surface, and a surface having an Ra surface roughness Ra of 0.2 μm or less on the surface. A nonporous anodized film having a thickness of 50 to 150 nm and a thickness variation of ± 5 nm or less, and a nonporous anodized film having a thickness of 0.5 to 3 μm and a dynamic friction And an acrylic resin film having a coefficient of 0.15 or less.

  The heat-shielding sheet of the present invention preferably has a solar reflectance of 70% or more at a wavelength of 300 to 2100 nm according to JIS R3106.

  According to the present invention, it is possible to provide a heat shield sheet that is inexpensive and can maintain heat shield characteristics.

Hereinafter, the present invention will be described in detail based on embodiments shown in the accompanying drawings.
FIG. 1 is a diagram showing a cross-sectional structure of a heat shield sheet 10 in the present embodiment. As shown in FIG. 1, the heat shield sheet 10 includes an aluminum substrate 1, a nonporous anodized film 2 formed on one surface of the aluminum substrate 1, and a protection formed on the anodized film 2. It is comprised from the membrane | film | coat 3. The aluminum substrate 1 is a basic component of the heat shield sheet 10 having a function of reflecting solar radiation. The nonporous anodized film 2 is formed in order to improve the adhesion of the protective film 3 to the aluminum substrate 1. The protective film 3 is provided only for the aluminum substrate 1 in order to prevent the decrease in reflectance due to the occurrence of white rust or scratches caused by contact objects. Hereinafter, each element will be described in order. In FIG. 1, the nonporous anodic oxide film 2 and the protective film 3 are sequentially formed on one surface of the aluminum base material 1, but the nonporous anodic oxide film 2 and the protective film 3 are formed on the aluminum base material 1. You may form in order on the other surface. The term “nonporous” in the present invention means that substantially no pores are observed when the cross section of the oxide film is observed at a magnification of 100,000 times using an electron microscope.

<Aluminum substrate 1>
The aluminum substrate 1 is preferably a thin plate having a thickness of 0.05 mm to 0.3 mm.
If the thickness of the aluminum base material 1 is 0.05 mm or more, the rigidity as the heat shield sheet 10 can be secured, and the heat shield sheet 10 can be prevented from being torn during construction.
On the other hand, when the thickness of the aluminum substrate 1 exceeds 0.3 mm, the weight increases and the workability deteriorates. Further, when the thickness exceeds 0.3 mm, the rigidity becomes strong, and when the surface on which the heat shield sheet 10 is applied is not flat, the heat shield sheet 10 is applied along the unevenness of the adherend surface. It becomes difficult. In addition, the amount of aluminum used increases and the cost increases. The preferable thickness of the aluminum substrate 1 is 0.06 to 0.2 mm, and the more preferable thickness is 0.08 to 0.15 mm.

The surface roughness of the aluminum base 1 is Ra (hereinafter Ra may be omitted) and is 0.2 μm or less. If the surface roughness is 0.2 μm or less, irregular reflection of solar radiation on the aluminum substrate 1 can be reduced and absorption of solar radiation energy can be reduced, so that a high heat shielding effect can be obtained by solar reflection. The surface roughness of the aluminum substrate 1 is preferably 0.15 μm or less, more preferably 0.1 μm or less. However, since it takes cost to reduce the surface roughness, the practical lower limit of the surface roughness is 0.02 μm. In addition, surface roughness can be adjusted with the roughness of the roll surface at the time of rolling an aluminum plate.
Regardless of the material of the aluminum substrate 1, pure aluminum 1000 series alloy, Al-Cu series, Al-Cu-Mg series 2000 series alloy, Al-Mn series 3000 series alloy, Al-Si series 4000 series Alloy, Al-Mg-based 5000 alloy, Al-Mg-Si-based 6000-based alloy, Al-Zn-Mg-Cu-based, Al-Zn-Mg-based 7000-based alloy, Al-Fe-Mn-based 8000 Any of these alloys can be used, but 1000 is preferred from the viewpoint of corrosion resistance.

<Nonporous anodized film 2>
In order to increase the adhesion of the protective film 3 to the aluminum substrate 1, a base treatment is required. In the present invention, the surface of the aluminum substrate 1 is formed by electrolytic treatment, and the non-porous material having high film thickness uniformity. The anodized film 2 is used as a base treatment. By doing so, favorable adhesiveness with the protective film 3 is obtained, suppressing the fall of a reflectance.
The average film thickness of the nonporous anodic oxide film 2 is 50 to 150 nm.
If the average film thickness is less than 50 nm, the protective coating 3 is too thin to form a localized hydrated oxide film, and the surface irregularities of the aluminum substrate 1 become large, causing irregular reflection of solar radiation and lowering the reflectance. On the other hand, if the average film thickness exceeds 150 nm, the solar radiation absorption by the nonporous anodic oxide coating 2 itself becomes a level that cannot be ignored, leading to a decrease in reflectance. The preferable average film thickness of the nonporous anodic oxide film 2 is 60 to 130 nm, and the more preferable average film thickness is 70 to 120 nm.
In the present invention, even if the average film thickness of the nonporous anodic oxide film 2 is within the above range, the reflectance decreases when the thickness variation is large. Therefore, in the present invention, the variation with respect to the average film thickness of the nonporous anodic oxide film 2 is made ± 5 nm or less. The variation in thickness is preferably ± 4 nm or less, more preferably ± 3 nm or less. In the present invention, the variation of ± 5 nm or less means that 20 arbitrary film thicknesses are measured within a square area of 10 cm in length and width of the aluminum substrate 1, and the measured film thicknesses of 20 points are average values. It is included within ± 5 nm.

The nonporous anodic oxide film 2 preferably has a porosity of 3% or less.
In general, a nonporous anodic oxide film is obtained by constant voltage electrolysis, and theoretically has a thickness of 1 V = 1.4 nm. The nonporous anodic oxide film 2 having excellent film thickness uniformity is divided into electrolysis three or more times, the voltage at the first electrolysis is ½ or less of the voltage calculated backward from the film thickness, and the current density is 1.5A. / Dm ² or less is preferable.
For example, when an anodic oxide film having a film thickness of 140 nm (= 100 V) is to be obtained, the voltage at the first electrolysis is set to 50 V. Then, a 140 nm nonporous anodic oxide film can be obtained by performing the electrolytic treatment three times with the voltage of the second electrolysis set to 75 V and the voltage of the third electrolysis set to 100 V.
The nonporous anodic oxide film 2 can be applied with a silane coupling agent, an undercoat or the like in order to further improve the adhesion with the protective film 3.

<Protective film 3>
For the protective film 3, an acrylic resin having high solar transmittance and excellent weather resistance is used. In addition, it is effective to make the protective film 3 slippery, that is, to reduce the coefficient of dynamic friction, and to mix silicone, polyethylene wax, carnauba wax, etc., which are difficult to dissolve in water, as a lubricating substance, in order to prevent damage caused by dust and brush cleaning. Good. Among these, it is preferable to contain silicone that is difficult to remove with an aqueous detergent. When a lubricant is contained and the coefficient of dynamic friction of the protective film 3 is 0.15 or less, an excellent effect for preventing scratches can be obtained.
If the thickness of the protective film 3 is less than 0.5 μm, a sufficient protective effect cannot be obtained, and if it exceeds 3 μm, the solar radiation absorption of the film itself increases, leading to a decrease in reflectance. Further, it is not preferable in terms of cost. Therefore, the thickness of the protective film 3 of the present invention is set to 0.5 to 3 μm. The preferable thickness of the protective film 3 is 0.7 to 2.0 μm, and the more preferable thickness is 0.8 to 1.5 μm.
A clear coating is suitable for the protective coating 3 in order to maintain a high reflectance, but the protective coating 3 can be colored with a pigment or the like as long as the reflectance is not significantly reduced.

Next, the manufacturing method of the thermal insulation sheet 10 of this invention is demonstrated.
First, the aluminum base material 1 which consists of said aluminum or aluminum alloy is prepared.
The aluminum substrate 1 is preferably pretreated in advance. The means for this pretreatment is not particularly limited as long as it can remove the oil and fat adhering to the surface of the aluminum substrate 1 and remove the heterogeneous oxide film on the surface. For example, after performing a degreasing treatment with a weak alkaline degreasing solution, after performing alkali etching with a sodium hydroxide aqueous solution, a method of performing a desmut treatment in a nitric acid aqueous solution or a method of performing acid cleaning after a degreasing treatment is appropriately selected. Used.

  Next, the nonporous anodic oxide film 2 is formed by electrolytically treating the surface of the aluminum substrate 1 in an electrolytic bath. In the electrolytic bath, boric acid, borate, phosphate, adipate, phthalate, benzoate, which are electrolytes that are difficult to dissolve the generated anodic oxide film and produce a nonporous film, An aqueous solution in which one or more selected from the group of tartrate, citrate, silicate and the like is dissolved is used. Among these electrolytes, boric acid, adipate, phthalate, and silicate are preferable from the viewpoints of properties of the oxide film, cost, and the like. The electrolyte concentration in the electrolytic bath is selected in the range of 2% by mass to the saturated concentration of the electrolyte. For example, in the case of boric acid, the range of 2 to 10% by mass is preferable. If the electrolyte concentration is too high, the film solubility may be increased to form a porous film, and the anion content may be increased. The bath temperature of the electrolytic bath is sufficient in the range of 20 to 50 ° C, and the bath temperature does not have to be higher than 50 ° C. The pH of the electrolytic bath is preferably in the range of pH 6.0 to 8.0. If the pH is too high, it is not preferable because it tends to be porous.

In this electrolytic bath, the aluminum substrate 1 is electrolyzed by being connected to a power source so as to be an anode even if it is continuous or intermittent. An insoluble conductive material is used for the cathode. As the electrolysis current, a direct current is used. In direct current electrolysis, electrolysis is performed with a direct current density of 1.5 A / dm ² or less and an electrolysis time of several seconds to 10 minutes. Since the applied voltage has a relation that the thickness of the oxide film formed with respect to a voltage of 1 V is about 1.4 nm in a direct current, the electrolysis is divided into three or more times as described above, and the initial electrolysis is performed. The voltage is set to ½ or less of the voltage calculated backward from the film thickness.

A JIS A1200 alloy plate having a plate thickness and surface roughness Ra (both front and back surfaces) shown in Table 1 was prepared, degreased with an alkaline degreasing solution, sufficiently washed with water, and then desmutted with nitric acid.
Next, it electrolyzed in the silicate aqueous solution, and the non-porous anodic oxide film shown in Table 2 was formed in the both surfaces of the said alloy board. Table 1 shows a representative example of the electrolytic treatment of the example.

  Using a water-based acrylic resin paint (trade name: Jurimer AT-515, manufactured by Nippon Pure Chemical Co., Ltd.) to which silicone (silicone, product name: X-22-2426 manufactured by Shin-Etsu Silicone Co., Ltd.) was added, A protective film was formed. The dynamic friction coefficient of the protective film was changed by adjusting the amount of silicone added.

Using the samples obtained above, the solar reflectance before the test, such as weather resistance, heat shielding properties, scratch resistance, and weather resistance, was evaluated. The evaluation method is as follows. The results are shown in Table 2.
(1) Weather resistance The surface condition after 6 months of the atmospheric exposure test was visually observed and evaluated according to the following criteria. Before the atmospheric exposure test (initial state), all samples are evaluated as “good”.
○… No abnormality △… Slight flaws, corrosion, and discoloration are slightly observed ×: Scratches, corrosion, and discoloration are severe (2) Thermal insulation The specimen (shield) is covered with a 2 mm thick steel plate with the protective film on the front side The temperature of the iron plate was measured after irradiating with a 100 W incandescent lamp for 30 minutes from a place 200 mm away, and the temperature difference from the temperature when the sample (heat shield sheet) was not attached was determined. . The evaluation was performed using two types of samples, a sample in an initial state and a sample after 6 months of the atmospheric exposure test.
○: Difference of 10 ° C. or more Δ… Difference of less than 5-10 ° C. × ... Difference of less than 0-5 ° C. (3) Scratch resistance 100 The surface condition after the rubbing was visually observed and evaluated according to the following criteria.
○… No abnormality △… Slight scratches are seen ×… Scratches are severe

  From the results shown in Table 2, it can be seen that the product of the present invention can be produced at low cost and that excellent characteristics as a heat shield sheet can be obtained. In addition, although it evaluated also about the sample which formed the nonporous anodic oxide film in the single side | surface of the alloy plate, the result similar to the sample of the front and back both surfaces mentioned above was obtained.

It is a figure which shows the cross-section of the thermal insulation sheet | seat in this Embodiment.

Explanation of symbols

  DESCRIPTION OF SYMBOLS 10 ... Thermal insulation sheet, 1 ... Aluminum base material, 2 ... Nonporous anodic oxide film, 3 ... Protective film

Claims (1)

An aluminum substrate having a surface roughness Ra of 0.2 μm or less on at least one surface;
A non-porous anodic oxide film having a surface roughness Ra of 0.2 μm or less formed on the surface of the aluminum substrate, a thickness of 50 to 150 nm, and a thickness variation of ± 5 nm or less;
A protective film made of an acrylic resin formed on the nonporous anodic oxide film and having a thickness of 0.5 to 3 μm and a dynamic friction coefficient of 0.15 or less;
A heat shielding sheet characterized by comprising:

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