JP2008515050A - 電気めっきされた外観が銀白色の金属とその製造方法 - Google Patents
電気めっきされた外観が銀白色の金属とその製造方法 Download PDFInfo
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- JP2008515050A JP2008515050A JP2007533509A JP2007533509A JP2008515050A JP 2008515050 A JP2008515050 A JP 2008515050A JP 2007533509 A JP2007533509 A JP 2007533509A JP 2007533509 A JP2007533509 A JP 2007533509A JP 2008515050 A JP2008515050 A JP 2008515050A
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- Prior art keywords
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- copper
- metal
- nickel
- electroplating
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- 238000004519 manufacturing process Methods 0.000 title abstract description 24
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 title abstract description 11
- 229910001361 White metal Inorganic materials 0.000 title abstract description 5
- 239000010969 white metal Substances 0.000 title abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 88
- 229910052751 metal Inorganic materials 0.000 claims abstract description 72
- 239000002184 metal Substances 0.000 claims abstract description 72
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 57
- 229910052802 copper Inorganic materials 0.000 claims abstract description 57
- 239000010949 copper Substances 0.000 claims abstract description 57
- 238000009713 electroplating Methods 0.000 claims abstract description 50
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 46
- 229910000881 Cu alloy Inorganic materials 0.000 claims abstract description 18
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 15
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 14
- 239000011701 zinc Substances 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 2
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 2
- 229910000838 Al alloy Inorganic materials 0.000 claims 1
- 229910000640 Fe alloy Inorganic materials 0.000 claims 1
- 238000007747 plating Methods 0.000 abstract description 68
- 229910000906 Bronze Inorganic materials 0.000 abstract description 50
- 239000010974 bronze Substances 0.000 abstract description 44
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 abstract description 44
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract description 10
- 239000002131 composite material Substances 0.000 abstract description 10
- 229910001431 copper ion Inorganic materials 0.000 abstract description 10
- 229910001432 tin ion Inorganic materials 0.000 abstract description 6
- 230000000172 allergic effect Effects 0.000 abstract description 4
- 208000010668 atopic eczema Diseases 0.000 abstract description 4
- 238000003672 processing method Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 103
- 238000000034 method Methods 0.000 description 28
- 239000000463 material Substances 0.000 description 12
- 229910000831 Steel Inorganic materials 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000010959 steel Substances 0.000 description 10
- 229910045601 alloy Inorganic materials 0.000 description 9
- 239000000956 alloy Substances 0.000 description 9
- 239000000758 substrate Substances 0.000 description 9
- 239000000356 contaminant Substances 0.000 description 8
- 229910021645 metal ion Inorganic materials 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 229910001092 metal group alloy Inorganic materials 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 229910001369 Brass Inorganic materials 0.000 description 3
- 229910000570 Cupronickel Inorganic materials 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- DOBRDRYODQBAMW-UHFFFAOYSA-N copper(i) cyanide Chemical compound [Cu+].N#[C-] DOBRDRYODQBAMW-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- -1 dirt Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010012442 Dermatitis contact Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000002009 allergenic effect Effects 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- FJMNNXLGOUYVHO-UHFFFAOYSA-N aluminum zinc Chemical compound [Al].[Zn] FJMNNXLGOUYVHO-UHFFFAOYSA-N 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 208000010247 contact dermatitis Diseases 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- IOUCSUBTZWXKTA-UHFFFAOYSA-N dipotassium;dioxido(oxo)tin Chemical compound [K+].[K+].[O-][Sn]([O-])=O IOUCSUBTZWXKTA-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000010956 nickel silver Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
- B32B15/015—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium the said other metal being copper or nickel or an alloy thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/017—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of aluminium or an aluminium alloy, another layer being formed of an alloy based on a non ferrous metal other than aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C13/00—Alloys based on tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/02—Alloys based on copper with tin as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/021—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/58—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/60—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of tin
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/005—Jewels; Clockworks; Coins
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
- Y10T428/12715—Next to Group IB metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
- Y10T428/12722—Next to Group VIII metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12903—Cu-base component
- Y10T428/1291—Next to Co-, Cu-, or Ni-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12903—Cu-base component
- Y10T428/12917—Next to Fe-base component
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Electroplating Methods And Accessories (AREA)
- Control Of Vending Devices And Auxiliary Devices For Vending Devices (AREA)
- Laminated Bodies (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
Description
Claims (8)
- 外側表面を有する金属コアと、
該金属コアの該外側表面に付着され、これを覆う第1電気めっき層であって、約4μm〜約25μmの厚みを有し約60重量%〜約100重量%の銅を含む第1電気めっき層と、
該第1電気めっき層に付着され、これを覆う第2電気めっき層であって、約4μm〜約25μmの厚みを有し約70重量%〜約10重量%の銅と残りの約30重量%〜約90重量%のスズとを含む第2電気めっき層と、
を備えたコイン。 - 前記金属コアが、亜鉛または亜鉛合金の一方を含む請求項1に記載のコイン。
- 前記金属コアが、ニッケルまたはニッケル合金の一方を含む請求項1に記載のコイン。
- 前記金属コアが、鉄または鉄合金の一方を含む請求項1に記載のコイン。
- 前記金属コアが、銅または銅合金の一方を含む請求項1に記載のコイン。
- 前記金属コアが、アルミニウムまたはアルミニウム合金の一方を含む請求項1に記載のコイン。
- 前記金属コアが地板を含む請求項1に記載のコイン。
- 前記地板の厚みが約500μm〜約4,000μmである請求項7に記載のコイン。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/950,242 US7296370B2 (en) | 2004-09-24 | 2004-09-24 | Electroplated metals with silvery-white appearance and method of making |
US10/950,242 | 2004-09-24 | ||
US11/187,046 | 2005-07-22 | ||
US11/187,046 US20060068234A1 (en) | 2004-09-24 | 2005-07-22 | Electroplated metals with silvery-white appearance and method of making |
PCT/US2005/031735 WO2006036479A1 (en) | 2004-09-24 | 2005-09-06 | Electroplated metals with silvery-white appearance and method of making |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008515050A true JP2008515050A (ja) | 2008-05-08 |
JP4927742B2 JP4927742B2 (ja) | 2012-05-09 |
Family
ID=36099548
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007533509A Expired - Fee Related JP4927742B2 (ja) | 2004-09-24 | 2005-09-06 | 電気めっきされた外観が銀白色のコイン |
Country Status (6)
Country | Link |
---|---|
US (2) | US7296370B2 (ja) |
JP (1) | JP4927742B2 (ja) |
CN (1) | CN101056760A (ja) |
BR (1) | BRPI0515910B1 (ja) |
ES (1) | ES2389444T3 (ja) |
MX (1) | MX2007003422A (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2016505703A (ja) * | 2012-11-08 | 2016-02-25 | モネ ロワイヤル カナディエンヌ/ロイヤル カナディアン ミントMonnaie Royale Canadienne/Royal Canadian Mint | 制御された条件下における錫と銅との相互拡散による金色の青銅のための改良された技法 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060286400A1 (en) * | 2005-06-17 | 2006-12-21 | Jarden Zinc Products, Inc. | Substrate with alloy finish and method of making |
TWM286096U (en) * | 2005-09-06 | 2006-01-21 | Yu-Jiun Lin | Identification mark structure of tool sleeve |
RU2438544C2 (ru) | 2008-06-13 | 2012-01-10 | Канадский Королевский Монетный Двор | Управление электромагнитными характеристиками монет с помощью технологии нанесения многослойных покрытий |
EP2625301A4 (en) * | 2010-10-07 | 2016-03-02 | Jarden Zinc Products Llc | COPPER ZINC MANGAN ALLOYS WITH SILVER-WHITE APPEARANCE FOR COINS AND TOYS |
US20130277225A1 (en) * | 2010-12-10 | 2013-10-24 | Royal Canadian Mint | Method to Produce Golden Bronze by Diffusion of Tin Into Copper Under Controlled Conditions |
CN102293487B (zh) * | 2011-07-05 | 2013-04-10 | 上海造币有限公司 | 多种金属组合的硬币、章坯饼及制备方法 |
EP2565297A3 (en) * | 2011-08-30 | 2013-04-24 | Rohm and Haas Electronic Materials LLC | Adhesion promotion of cyanide-free white bronze |
ITVI20120300A1 (it) * | 2012-11-08 | 2014-05-09 | Italo Caoduro | Oggetto con strato superficiale di copertura ottenuto per deposizione elettrolitica, soluzione elettrolitica impiegata in tale deposizione e metodo di realizzazione di tale oggetto. |
MX385751B (es) * | 2013-08-27 | 2025-03-18 | Artazn Llc | Aleación de zinc con conductividad reducida y firma electromagnética única. |
RU2016124913A (ru) | 2013-12-20 | 2018-01-25 | ЖАРДЕН ЦИНК ПРОДУКТС, ЭлЭлСи | Никелированные цинковые сплавы для чеканки монет |
CN108166029A (zh) * | 2017-12-28 | 2018-06-15 | 广东达志环保科技股份有限公司 | 无氰白铜锡电镀液和电镀方法 |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2511395A (en) * | 1939-02-20 | 1950-06-13 | City Auto Stamping Co | Process for the electrodeposition of tin alloys |
US2658032A (en) * | 1949-06-11 | 1953-11-03 | City Auto Stamping Co | Electrodeposition of bright copper-tin alloy |
JPS60114589A (ja) * | 1983-11-02 | 1985-06-21 | デグツサ・アクチエンゲゼルシヤフト | 地色ないし光沢のある銅・スズ合金被膜を電着させるためのアルカリ性シアン化物浴 |
JPS6111895A (ja) * | 1984-05-01 | 1986-01-20 | シエリツト・ゴ−ドン・マインズ・リミテツド | コイン |
DE3940244A1 (de) * | 1989-12-05 | 1991-06-06 | Ver Deutsche Nickel Werke Ag V | Muenzrohling und verfahren zu dessen herstellung |
JPH08120481A (ja) * | 1994-08-31 | 1996-05-14 | Nippon Shinkinzoku Kako Kk | 装飾部材 |
JPH10102278A (ja) * | 1996-09-30 | 1998-04-21 | Nippon New Chrome Kk | 銅−スズ合金メッキ用ピロリン酸浴 |
JP2001295092A (ja) * | 2000-04-14 | 2001-10-26 | Nippon New Chrome Kk | 銅−スズ合金めっき用ピロリン酸浴 |
JP2004010907A (ja) * | 2002-06-03 | 2004-01-15 | Kyoto Ichi | 銅−錫合金めっき浴及び該めっき浴を用いた銅−錫合金めっき方法 |
WO2004035875A2 (de) * | 2002-10-11 | 2004-04-29 | Enthone Inc. | Verfahren zur galvanischen abscheidungvon bronzen |
EP1533397A2 (de) * | 2003-11-21 | 2005-05-25 | Enthone Inc. | Verfahren zur Abscheidung von nickel- und chrom(VI)-freien, metallischen Mattschichten |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1015905A (en) * | 1974-09-16 | 1977-08-23 | Arthur G. Mcmullen | Nickel clad steel coinage blank |
DE3116135C2 (de) * | 1981-04-23 | 1983-02-10 | Metallgesellschaft Ag, 6000 Frankfurt | Verwendung einer Kupferlegierung als Werkstoff für goldfarbene Münzen |
US4550819A (en) * | 1982-09-24 | 1985-11-05 | Umc Industries, Inc. | Coin apparatus |
GB8305610D0 (en) * | 1983-03-01 | 1983-03-30 | Imi Kynoch Ltd | Alloy |
JPS6288877A (ja) * | 1985-10-11 | 1987-04-23 | Hamamatsu Gasket Seisakusho:Kk | 金属ガスケツト |
CA2013639C (en) * | 1990-04-02 | 1998-06-23 | Mitsuhiro Yasuda | Electroplated blank for coins, medallions and tokens |
US5139886A (en) * | 1990-06-21 | 1992-08-18 | Royal Canadian Mint | Coins coated with nickel, copper and nickel |
US5151167A (en) * | 1990-06-21 | 1992-09-29 | Royal Canadian Mint | Coins coated with nickel, copper and nickel and process for making such coins |
WO1997020970A1 (fr) * | 1995-08-23 | 1997-06-12 | Citizen Watch Co., Ltd. | Element ornemental |
US5614327A (en) * | 1994-09-09 | 1997-03-25 | Sarthoise De Revetements Electrolytiques | Process for protecting a silver or silver-coated part |
TW577938B (en) * | 1998-11-05 | 2004-03-01 | Uyemura C & Co Ltd | Tin-copper alloy electroplating bath and plating process therewith |
HK1041297B (en) * | 1999-05-05 | 2003-10-10 | Gbc金属有限公司 | Copper alloy with golden surface |
US20020166774A1 (en) * | 1999-12-10 | 2002-11-14 | Shipley Company, L.L.C. | Alloy composition and plating method |
WO2002000958A1 (fr) * | 2000-06-27 | 2002-01-03 | Citizen Watch Co., Ltd. | Article decoratif comportant une pellicule blanche et procede de production associe |
US6656606B1 (en) * | 2000-08-17 | 2003-12-02 | The Westaim Corporation | Electroplated aluminum parts and process of production |
US6383657B1 (en) * | 2000-12-18 | 2002-05-07 | Alltrista Zinc Products | Aluminum clad zinc bimetallic coin planchet |
US20060260948A2 (en) * | 2005-04-14 | 2006-11-23 | Enthone Inc. | Method for electrodeposition of bronzes |
US20060286400A1 (en) * | 2005-06-17 | 2006-12-21 | Jarden Zinc Products, Inc. | Substrate with alloy finish and method of making |
-
2004
- 2004-09-24 US US10/950,242 patent/US7296370B2/en not_active Expired - Fee Related
-
2005
- 2005-07-22 US US11/187,046 patent/US20060068234A1/en not_active Abandoned
- 2005-09-06 BR BRPI0515910A patent/BRPI0515910B1/pt not_active IP Right Cessation
- 2005-09-06 CN CNA2005800388779A patent/CN101056760A/zh active Pending
- 2005-09-06 MX MX2007003422A patent/MX2007003422A/es active IP Right Grant
- 2005-09-06 JP JP2007533509A patent/JP4927742B2/ja not_active Expired - Fee Related
- 2005-09-06 ES ES05794287T patent/ES2389444T3/es active Active
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2511395A (en) * | 1939-02-20 | 1950-06-13 | City Auto Stamping Co | Process for the electrodeposition of tin alloys |
US2658032A (en) * | 1949-06-11 | 1953-11-03 | City Auto Stamping Co | Electrodeposition of bright copper-tin alloy |
JPS60114589A (ja) * | 1983-11-02 | 1985-06-21 | デグツサ・アクチエンゲゼルシヤフト | 地色ないし光沢のある銅・スズ合金被膜を電着させるためのアルカリ性シアン化物浴 |
JPS6111895A (ja) * | 1984-05-01 | 1986-01-20 | シエリツト・ゴ−ドン・マインズ・リミテツド | コイン |
DE3940244A1 (de) * | 1989-12-05 | 1991-06-06 | Ver Deutsche Nickel Werke Ag V | Muenzrohling und verfahren zu dessen herstellung |
JPH08120481A (ja) * | 1994-08-31 | 1996-05-14 | Nippon Shinkinzoku Kako Kk | 装飾部材 |
JPH10102278A (ja) * | 1996-09-30 | 1998-04-21 | Nippon New Chrome Kk | 銅−スズ合金メッキ用ピロリン酸浴 |
JP2001295092A (ja) * | 2000-04-14 | 2001-10-26 | Nippon New Chrome Kk | 銅−スズ合金めっき用ピロリン酸浴 |
JP2004010907A (ja) * | 2002-06-03 | 2004-01-15 | Kyoto Ichi | 銅−錫合金めっき浴及び該めっき浴を用いた銅−錫合金めっき方法 |
WO2004035875A2 (de) * | 2002-10-11 | 2004-04-29 | Enthone Inc. | Verfahren zur galvanischen abscheidungvon bronzen |
EP1533397A2 (de) * | 2003-11-21 | 2005-05-25 | Enthone Inc. | Verfahren zur Abscheidung von nickel- und chrom(VI)-freien, metallischen Mattschichten |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016505703A (ja) * | 2012-11-08 | 2016-02-25 | モネ ロワイヤル カナディエンヌ/ロイヤル カナディアン ミントMonnaie Royale Canadienne/Royal Canadian Mint | 制御された条件下における錫と銅との相互拡散による金色の青銅のための改良された技法 |
US10266959B2 (en) | 2012-11-08 | 2019-04-23 | Monnaie Royale Canadienne / Royal Canadian Mint | Enhanced techniques for production of golden bronze by inter-diffusion of tin and copper under controlled conditions |
Also Published As
Publication number | Publication date |
---|---|
JP4927742B2 (ja) | 2012-05-09 |
MX2007003422A (es) | 2008-03-04 |
US20060068234A1 (en) | 2006-03-30 |
BRPI0515910A (pt) | 2008-08-12 |
BRPI0515910B1 (pt) | 2016-04-05 |
ES2389444T3 (es) | 2012-10-26 |
CN101056760A (zh) | 2007-10-17 |
US7296370B2 (en) | 2007-11-20 |
US20060068219A1 (en) | 2006-03-30 |
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