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JP2007283444A - Brush material - Google Patents

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JP2007283444A
JP2007283444A JP2006114010A JP2006114010A JP2007283444A JP 2007283444 A JP2007283444 A JP 2007283444A JP 2006114010 A JP2006114010 A JP 2006114010A JP 2006114010 A JP2006114010 A JP 2006114010A JP 2007283444 A JP2007283444 A JP 2007283444A
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brush
resin
covering layer
abrasive
mixed
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Yuichiro Niizaki
優一郎 新崎
Tomoko Niizaki
朋子 新崎
Yunito Niizaki
優仁人 新崎
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  • Polishing Bodies And Polishing Tools (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a wear-resistant and durable brush material for use in polishing and grinding to polish and deburr the surface of a workpiece, with which deburring effects and polishing effects can be expected even if burrs occurring on the surface or corners of the workpiece are hard when used under such severe conditions as the brush material is brought into contact with the surface of the workpiece while rapidly rotated or strong pressing force is applied. <P>SOLUTION: A covering layer 14 with a fine-powdered polishing agent 13 mixed is provided on a surface of a bristle material 12a with a polishing agent 10 of large grains mixed and comprising an assembly of a plurality of resin bristles 12 with a circular or polygonal cross section. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、ワークの表面を研磨処理したりバリ取りをするための研磨、研削用に使用することができるブラシ素材に関するものである。   The present invention relates to a brush material that can be used for polishing and grinding for polishing or deburring the surface of a workpiece.

従来からワーク表面を研磨したりバリ取り等の研磨、研削用に使用することができるブラシ素材としては、例えば、研磨粒を混入した合成繊維の複数本を芯体として、この芯体の周囲に細い合成繊維のマルチフィラメントをカバーリングとして施してなるブラシ素材を使用したものが知られている。(特許文献1参照)
特開昭63−318907号公報
Conventionally, as a brush material that can be used for polishing the surface of a workpiece, polishing such as deburring, and grinding, for example, a plurality of synthetic fibers mixed with abrasive grains are used as a core, and around this core The thing using the brush raw material which gave multi filament of thin synthetic fiber as a cover ring is known. (See Patent Document 1)
JP-A-63-3318907

しかし、前記の細い合成繊維のマルチフィラメントのカバーリングを施してなるブラシ素材は、ワークの表面を研磨したりバリ取り等の研摩、研削用に使用され、ワークの表面に、高速回転させながら接触させたり、強い押圧力を与えられる等の過酷な条件の基で使用される場合、ワークの表面や隅部に発生しているバリが硬質であると、バリ取り効果や研磨効果を期待することができないので改善が望まれていた。   However, the above-mentioned brush material with multi-filament covering of synthetic fibers is used for polishing and grinding of the workpiece surface, deburring, etc., and contacting the workpiece surface while rotating at high speed If the burrs generated on the surface and corners of the workpiece are hard when used under severe conditions such as applying a strong pressing force, etc., expect deburring and polishing effects Because it was not possible, improvement was desired.

本発明は上記課題を解決するもので、ワークの表面を研磨したりバリ取り等の研摩、研削用に使用され、ワークの表面に、高速回転させながら接触させたり、強い押圧力を与える等の過酷な条件の基で使用される場合に、ワークの表面や隅部に発生しているバリが硬質であっても、バリ取り効果や研磨効果を期待できるような耐摩耗性、耐久性を有するブラシ素材を提供することを目的とする。   The present invention solves the above-described problems, and is used for polishing and grinding of the workpiece surface, deburring, etc., and contacting the workpiece surface while rotating at high speed, giving a strong pressing force, etc. When used under harsh conditions, even if the burrs generated on the surface and corners of the workpiece are hard, it has wear resistance and durability that can be expected to have a deburring effect and polishing effect An object is to provide a brush material.

上記課題を解決するために請求項1記載の発明は、粗粒の研磨材を混入して断面が円形若しくは多角形状の樹脂ブラシ毛を複数本集束してなる樹脂ブラシ毛材の表面に、微粉の研磨材を混入した樹脂被膜によるカバーリング層を設けてなるブラシ素材である。   In order to solve the above-mentioned problem, the invention described in claim 1 is characterized in that a fine abrasive powder is mixed on the surface of a resin brush bristle material in which a coarse abrasive is mixed and a plurality of resin bristles having a circular or polygonal cross section are gathered. This is a brush material provided with a covering layer made of a resin film mixed with a polishing material.

また、請求項2記載の発明は、前記カバーリング層は、樹脂をコーティングしたり、樹脂被膜を螺旋状に巻成したり、樹脂薄膜のパイプ材を装着してなる請求項1記載のブラシ素材である。   Further, the invention according to claim 2 is the brush material according to claim 1, wherein the covering layer is formed by coating a resin, spirally winding a resin film, or mounting a resin thin film pipe material. It is.

また、請求項3記載の発明は、前記粗粒の研磨材は粒度がF50〜F100の範囲であり、前記微粉の研磨材は粒度が#2,500〜#8,000の範囲である請求項1又は2記載のブラシ素材である。   According to a third aspect of the present invention, the coarse abrasive has a particle size in the range of F50 to F100, and the fine abrasive has a particle size in the range of # 2,500 to # 8,000. The brush material according to 1 or 2.

本発明のブラシ素材によれば、ブラシ毛材はブラシ毛を複数本集束してなる樹脂ブラシ毛材の表面にカバーリング層を設けているので、耐摩耗性、耐久性があり、ワークの表面に、高速回転させながら接触させたり、強い押圧力を与える等の過酷な条件の基で使用される場合に、ワークの表面や隅部にバリが発生し、このバリが硬質であっても、バリ取り効果や研磨効果を期待できる。   According to the brush material of the present invention, the brush bristle material is provided with a covering layer on the surface of the resin brush bristle material obtained by converging a plurality of brush hairs. In addition, burrs are generated on the surface and corners of workpieces when they are used under severe conditions such as making contact while rotating at high speed or applying a strong pressing force. Deburring effect and polishing effect can be expected.

以下、図面に基づいて本発明の実施例を説明する。なお、各図における同一の符号は、同一の構成部分を示す。   Embodiments of the present invention will be described below with reference to the drawings. In addition, the same code | symbol in each figure shows the same component.

図1(a)は本発明に係る実施例1のブラシ素材を示す概略斜視図、図1(b)は、図1(a)のブラシ素材のA−A線拡大断面図である。   FIG. 1A is a schematic perspective view showing a brush material of Example 1 according to the present invention, and FIG. 1B is an enlarged sectional view taken along line AA of the brush material of FIG.

図1(a)(b)において、ブラシ素材11は、粗粒の研磨材(アルミナ、シリコンカーバイト、酸化セリウム、ダイヤモンドの1種若しくは2種以上)10を混入して断面が円形に成形した樹脂ブラシ毛12を4本集束してブラシ毛材12aを形成し、このブラシ毛材12aの表面に、微粉の研磨材13を混入させた樹脂被膜によるカバーリング層14を設けて形成されている。粗粒の研磨材10や微粉の研磨材13の粒子径や粒度はJIS R6001(1998)で規定されており、粗粒の研磨材10の粒度はF50〜F100の範囲であり、また、微粉の研磨材13の粒度は#2,500〜#8,000の範囲である。   1 (a) and 1 (b), a brush material 11 is formed into a circular cross section by mixing coarse abrasives (one or more of alumina, silicon carbide, cerium oxide, diamond) 10 therein. Four resin brush bristles 12 are converged to form a brush bristle material 12a, and a covering layer 14 is formed on the surface of the brush bristle material 12a by a resin film mixed with fine abrasive material 13. . The particle diameter and particle size of the coarse abrasive 10 and fine abrasive 13 are defined in JIS R6001 (1998), and the coarse abrasive 10 has a particle size in the range of F50 to F100. The particle size of the abrasive 13 is in the range of # 2,500 to # 8,000.

図2(a)は本発明に係る実施例2のブラシ素材を示す概略斜視図、図2(b)は、図2(a)のブラシ素材のB−B線拡大断面図である。   FIG. 2A is a schematic perspective view showing a brush material of Example 2 according to the present invention, and FIG. 2B is an enlarged sectional view taken along line BB of the brush material of FIG.

図2において、ブラシ素材21は、粗粒の研磨材10を混入して断面が三角形に成形した樹脂ブラシ毛22を4本集束してブラシ毛材22aを形成し、このブラシ毛材22aの表面に、微粉の研磨材13を混入させた樹脂被膜によるカバーリング層14を設けて形成されている。   In FIG. 2, a brush material 21 is formed by converging four resin brush bristles 22 mixed with coarse abrasive 10 and formed into a triangular cross section to form a brush bristle material 22a, and the surface of the brush bristle material 22a. In addition, a covering layer 14 made of a resin film mixed with fine abrasive powder 13 is provided.

図3(a)は本発明に係る実施例3のブラシ素材を示す概略斜視図、図3(b)は、図3(a)のブラシ素材のC−C線拡大断面図である。   FIG. 3A is a schematic perspective view showing a brush material of Example 3 according to the present invention, and FIG. 3B is an enlarged sectional view taken along the line C-C of the brush material of FIG.

図3において、ブラシ素材31は、粗粒の研磨材10を混入して断面が四角形に成形した樹脂ブラシ毛32を4本集束してなるブラシ毛材32aを形成し、このブラシ毛材32aの表面に、微粉の研磨材13を混入させた樹脂被膜によるカバーリング層14を設けて形成されている。   In FIG. 3, the brush material 31 forms a brush bristle material 32a formed by converging four resin brush hairs 32 mixed with the coarse abrasive 10 and formed into a square cross section. A covering layer 14 made of a resin film mixed with fine abrasive material 13 is provided on the surface.

図4(a)は本発明に係る実施例4のブラシ素材を示す概略斜視図、図4(b)は、図4(a)のブラシ素材のD−D線拡大断面図である。   FIG. 4A is a schematic perspective view showing a brush material of Example 4 according to the present invention, and FIG. 4B is an enlarged sectional view taken along line DD of the brush material of FIG.

図4において、ブラシ素材41は、粗粒の研磨材10を混入して、断面が円形に成形した樹脂ブラシ毛12、断面が三角形に成形した樹脂ブラシ毛22、断面が四角形に成形した樹脂ブラシ毛32の各1本を混合した計3本を集束してなるブラシ毛材42aの表面に、微粉の研磨材13を混入させた樹脂被膜によるカバーリング層14を設けて形成されたものである。   In FIG. 4, a brush material 41 includes a coarse abrasive 10 and a resin brush hair 12 having a circular cross section, a resin brush hair 22 having a triangular cross section, and a resin brush having a square cross section. It is formed by providing a covering layer 14 made of a resin film mixed with a fine powdery abrasive 13 on the surface of a brush bristle material 42a formed by converging a total of three hairs 32 each mixed. .

図5(a)は本発明に係る実施例5のブラシ素材を示す概略斜視図、図5(b)は、図5(a)のブラシ素材のE−E線拡大断面図である。   FIG. 5A is a schematic perspective view showing a brush material of Example 5 according to the present invention, and FIG. 5B is an enlarged sectional view taken along line EE of the brush material of FIG.

図5において、ブラシ素材51は、粗粒の研磨材10を混入して、断面が円形で径の大きい樹脂ブラシ毛52と断面が円形で径の小さい樹脂ブラシ毛53とを成形して、径の大きい樹脂ブラシ毛52の1本を中心として、その周りに径の小さい樹脂ブラシ毛53の複数本(図5では12本)を配置して集束してなるブラシ毛材54の表面に、微粉の研磨材13を混入させた樹脂被膜によるカバーリング層14を設けて形成されたものである。   In FIG. 5, the brush material 51 is mixed with the coarse abrasive 10 to form resin brush hairs 52 having a circular cross section and a large diameter, and resin brush bristles 53 having a circular cross section and a small diameter. A fine powder is formed on the surface of a brush bristle material 54 formed by arranging and concentrating a plurality (12 in FIG. 5) of resin brush hairs 53 having a small diameter around one resin brush hair 52 having a large diameter. This is formed by providing a covering layer 14 made of a resin film mixed with the abrasive 13.

前述した各カバーリング層14は、微粉の研磨材13としてアルミナ、シリコンカーバイト、酸化セリウム、ダイヤモンドの1種若しくは2種以上を混入させた樹脂被膜により形成した。樹脂被膜に混入される微粉の研磨材13の割合は、ダイヤモンドが1〜10重量%、その他の研磨材が90〜99重量%となるようにした。   Each of the covering layers 14 described above was formed of a resin film in which one or more of alumina, silicon carbide, cerium oxide, and diamond were mixed as the fine abrasive 13. The proportion of fine abrasive 13 mixed in the resin coating was 1 to 10% by weight of diamond and 90 to 99% by weight of other abrasives.

また、各カバーリング層14は、微粉の研磨材13とともに、芳香性パウダー若しくは消臭性パウダーを混入してもよい。このように微粉の研磨材に芳香性パウダー若しくは消臭性パウダーを混入しておけば、ワークの研摩処理時にブラシ毛材12aに芳香性や消臭性を持たせることができる。   Moreover, each covering layer 14 may mix aromatic powder or deodorant powder with the fine abrasive 13. Thus, if aromatic powder or deodorant powder is mixed in the fine abrasive material, the brush bristle material 12a can be given aromaticity and deodorant during the polishing process of the workpiece.

図6(a)(b)(c)は、共に粒度がF50〜F100の範囲の粗粒の研磨材(アルミナ、シリコンカーバイト、酸化セリウム、ダイヤモンドの1種若しくは2種以上)を混入した樹脂ブラシ毛12,22,32である。図6(a)は断面が円形の樹脂ブラシ毛12を示し、図6(b)は断面が三角形の樹脂ブラシ毛22を示し、図6(c)は断面が四角形の樹脂ブラシ毛32を示す。   6 (a), 6 (b), and 6 (c) show a resin mixed with a coarse abrasive (alumina, silicon carbide, cerium oxide, or one or more kinds of diamond) having a particle size in the range of F50 to F100. Brush hairs 12, 22, and 32. 6A shows the resin brush bristles 12 having a circular cross section, FIG. 6B shows the resin brush bristles 22 having a triangular cross section, and FIG. 6C shows the resin brush bristles 32 having a square cross section. .

図7は各種の樹脂ブラシ毛の断面形状の例を示す概略図である。実施例1〜4における樹脂ブラシ毛12,22,32は、断面形状が丸形、三角、四角(正方形)のものについて図示したが、この他にも、六角形33、八角形34等の多角形、楕円形35、十字形36、瓢箪のようなメガネ形37、四葉のクローバ形38(または、図示しない三つ葉クローバ形)、長方形39のものでも良い。   FIG. 7 is a schematic view showing examples of cross-sectional shapes of various resin brush hairs. The resin brush bristles 12, 22 and 32 in Examples 1 to 4 are illustrated with a cross-sectional shape of a round shape, a triangular shape and a quadrangular shape (square). A rectangular shape, an elliptical shape 35, a cross shape 36, a glass shape 37 like a heel, a four-leaf clover shape 38 (or a three-leaf clover shape not shown), and a rectangular shape 39 may be used.

各樹脂ブラシ毛12,22,32は、直線状の線材について図示したが、この他にも、図8(a)に示すように捻れ線状の金属ブラシ毛22c、図8(b)に示すように微細な波線状に形成した樹脂ブラシ毛22dを使用することができる。   Each of the resin brush bristles 12, 22, and 32 is illustrated with respect to a linear wire, but in addition to this, as shown in FIG. 8 (a), the twisted wire-shaped metal brush bristles 22c and FIG. 8 (b) are illustrated. Thus, the resin brush bristles 22d formed in a fine wavy line shape can be used.

また、各樹脂ブラシ毛12,22,32を2本以上束ねてブラシ毛材を形成する場合には、複数の各種線状の樹脂ブラシ毛12をそのまま纏めて束ねてブラシ毛材を形成しても良いし、図9に示すように複数(図9では3本)の各種線状の樹脂ブラシ毛12を網組みしてブラシ毛材60を形成しても良い。   Further, when a brush bristle material is formed by bundling two or more resin brush bristles 12, 22 and 32, a plurality of various linear resin brush bristles 12 are bundled together to form a brush bristle material. Alternatively, as shown in FIG. 9, a plurality of (three in FIG. 9) various linear resin brush bristles 12 may be meshed to form the brush bristle material 60.

また、カバーリング層14は、樹脂をコーティングして形成できるが、図10(a)に示すように樹脂被膜を螺旋状に巻成してカバーリング層14aを形成しても良いし、図10(b)に示すように樹脂薄膜のパイプ材を装着してカバーリング層14bを形成しても良い。   The covering layer 14 can be formed by coating a resin. However, as shown in FIG. 10A, the covering layer 14a may be formed by spirally winding a resin film. As shown in (b), a resin thin film pipe material may be attached to form the covering layer 14b.

図11(a)〜(e)は、その他のブラシ素材の断面形状の例を示す概略図である。実施例1〜5におけるブラシ素材11,21,31,41,51は、カバーリング層14の断面形状を丸い環形に形成したものについて図示したが、ブラシ素材のカバーリング層は、図11(a)に示す断面形状が孔の丸い四角環形61、図11(b)に示す断面形状が三角環形62、図11(c)に示す断面形状が六角環形63、図11(d)に示す断面形状が八角環形64、図11(e)に示す断面形状が楕円環形65の各種のカバーリング層にすることができる。   11A to 11E are schematic views showing examples of cross-sectional shapes of other brush materials. The brush materials 11, 21, 31, 41, and 51 in Examples 1 to 5 are illustrated with the cross-sectional shape of the covering layer 14 formed in a circular ring shape, but the covering layer of the brush material is illustrated in FIG. ) Is a square ring 61 with round holes, the cross-sectional shape shown in FIG. 11 (b) is a triangular ring 62, the cross-sectional shape shown in FIG. 11 (c) is a hexagonal ring 63, and the cross-sectional shape shown in FIG. 11 (d). Can be made into various covering layers having an octagonal ring shape 64 and an elliptical ring shape 65 in cross section shown in FIG.

本発明は前記実施の形態に限定されるものではなく、特許請求の範囲に記載の構成を変更しない限りどのようにでも実施することができる。例えば、カバーリング層内の樹脂ブラシ毛は、実施例1〜5では、3本又は4本としたが、他の複数本であってもよい。   The present invention is not limited to the above-described embodiment, and can be implemented in any way as long as the configuration described in the claims is not changed. For example, the resin brush bristles in the covering layer are three or four in Examples 1 to 5, but may be other plural pieces.

(a)は本発明に係る実施例1を示す概略斜視図、図1(b)は、図1(a)のブラシ素材のA−A線拡大断面図である。(A) is a schematic perspective view which shows Example 1 which concerns on this invention, FIG.1 (b) is an AA line expanded sectional view of the brush raw material of Fig.1 (a). (a)は本発明に係る実施例2を示す概略斜視図、(b)は、(a)のブラシ素材のB−B線拡大断面図である。(A) is a schematic perspective view which shows Example 2 which concerns on this invention, (b) is a BB line expanded sectional view of the brush raw material of (a). (a)は本発明に係る実施例3を示す概略斜視図、(b)は、(a)のブラシ素材のC−C線拡大断面図である。(A) is a schematic perspective view which shows Example 3 which concerns on this invention, (b) is CC expanded sectional view of the brush raw material of (a). (a)は本発明に係る実施例4を示す概略斜視図、(b)は、(a)のブラシ素材のD−D線拡大断面図である。(A) is a schematic perspective view which shows Example 4 which concerns on this invention, (b) is the DD line expanded sectional view of the brush raw material of (a). (a)は本発明に係る実施例5を示す概略斜視図、(b)は、(a)のブラシ素材のE−E線拡大断面図である。(A) is a schematic perspective view which shows Example 5 which concerns on this invention, (b) is the EE line expanded sectional view of the brush raw material of (a). (a)(b)(c)は、本発明に係る実施例1〜5に使用された断面が円形、三角形、四角形の樹脂ブラシ毛を示す概略斜視図である。(A) (b) (c) is a schematic perspective view which shows the resin brush bristles whose cross section used for Examples 1-5 which concerns on this invention is circular, a triangle, and a rectangle. 各種の樹脂ブラシ毛の断面形状の例を示す概略図である。It is the schematic which shows the example of the cross-sectional shape of various resin brush bristles. (a)(b)は他の樹脂ブラシ毛の例を示す概略斜視図である。(A) (b) is a schematic perspective view which shows the example of the other resin brush hair. 他のブラシ毛材を示す概略斜視図である。It is a schematic perspective view which shows another brush bristle material. (a)(b)は本発明に係るカバーリング層の例を示す概略斜視図である。(A) (b) is a schematic perspective view which shows the example of the covering layer which concerns on this invention. (a)〜(e)は、その他のブラシ素材の断面形状の例を示す概略図である。(A)-(e) is the schematic which shows the example of the cross-sectional shape of another brush raw material.

符号の説明Explanation of symbols

10,13 研磨材
11,21,31,41,51 ブラシ素材
12,22,32,52,53 樹脂ブラシ毛
12a,22a,32a,42a,54 ブラシ毛材
14,61〜65 カバーリング層
22c 捻れ線状の樹脂ブラシ毛
22d 波線状に形成した樹脂ブラシ毛
60 樹脂ブラシ毛を網組みして形成したブラシ毛材
10, 13 Abrasive material 11, 21, 31, 41, 51 Brush material 12, 22, 32, 52, 53 Resin brush hair 12a, 22a, 32a, 42a, 54 Brush bristle material 14, 61-65 Covering layer 22c Twist Linear resin brush bristles 22d Resin bristles formed into wavy lines 60 Brush bristles formed by netting resin bristles

Claims (3)

粗粒の研磨材を混入して断面が円形若しくは多角形状の樹脂ブラシ毛を複数本集束してなる樹脂ブラシ毛材の表面に、微粉の研磨材を混入したカバーリング層を設けてなるブラシ素材。   A brush material in which a coarse abrasive material is mixed to cover a surface of a resin brush bristle material in which a plurality of resin brush hairs having a circular or polygonal cross section are gathered, and a covering layer containing fine powder abrasive material is provided on the surface. . 前記カバーリング層は、樹脂をコーティングしたり、樹脂被膜を螺旋状に巻成したり、樹脂薄膜のパイプ材を装着してなる請求項1記載のブラシ素材。   2. The brush material according to claim 1, wherein the covering layer is formed by coating a resin, winding a resin film in a spiral shape, or mounting a pipe material of a resin thin film. 前記粗粒の研磨材は粒度がF50〜F100の範囲であり、前記微粉の研磨材は粒度が#2,500〜#8,000の範囲である請求項1又は2記載のブラシ素材。   The brush material according to claim 1 or 2, wherein the coarse abrasive has a particle size in the range of F50 to F100, and the fine abrasive has a particle size in the range of # 2,500 to # 8,000.
JP2006114010A 2006-04-18 2006-04-18 Brush material Pending JP2007283444A (en)

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Cited By (12)

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Publication number Priority date Publication date Assignee Title
JP2008012632A (en) * 2006-07-07 2008-01-24 Yuichiro Niizaki Brush bristle material and brush
JP2012006117A (en) * 2010-06-25 2012-01-12 Yuichiro Niizaki Cover for brush bristle
JP2012106308A (en) * 2010-11-17 2012-06-07 Yuichiro Niizaki Brush bristle
CN104093526A (en) * 2013-02-05 2014-10-08 株式会社马山 Filaments, multi-filaments, and manufacturing methods thereof
WO2017155252A1 (en) * 2016-03-09 2017-09-14 비비씨 주식회사 Dual-structured filament
JP2017170082A (en) * 2016-03-25 2017-09-28 優一郎 新崎 Brush bristle material and brush
US10251470B1 (en) 2017-10-10 2019-04-09 The Procter & Gamble Company Head for an oral care implement and oral care implement
US10856646B2 (en) 2014-07-15 2020-12-08 The Procter & Gamble Company Oral-care implement having color-communicative element
US11206916B2 (en) 2016-06-03 2021-12-28 The Procter & Gamble Company Head for an oral care implement and oral care implement
US11219302B2 (en) 2017-10-10 2022-01-11 The Procter & Gamble Company Head for an oral care implement and oral care implement
US11284707B2 (en) 2016-06-03 2022-03-29 The Procter & Gamble Company Filament for an oral care implement and oral care implement
US11425991B2 (en) 2014-03-11 2022-08-30 The Procter & Gamble Company Head for an oral care implement

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JPS63318907A (en) * 1987-06-23 1988-12-27 株式会社 ホタニ Brashing material of washing brush roll
JPH0549250U (en) * 1991-11-29 1993-06-29 日新製鋼株式会社 Brushing equipment for pretreatment of steel strip in continuous melting plating
JPH11301136A (en) * 1998-04-20 1999-11-02 Fuji Photo Film Co Ltd Method and apparatus for surface treating aluminum support for printing plate
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JP2005200455A (en) * 2004-01-13 2005-07-28 Yuichiro Niizaki Brush bristle material made of self-repairing plastic and brush tool formed of brush bristle made of self-repairing plastic
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008012632A (en) * 2006-07-07 2008-01-24 Yuichiro Niizaki Brush bristle material and brush
JP2012006117A (en) * 2010-06-25 2012-01-12 Yuichiro Niizaki Cover for brush bristle
JP2012106308A (en) * 2010-11-17 2012-06-07 Yuichiro Niizaki Brush bristle
CN104093526A (en) * 2013-02-05 2014-10-08 株式会社马山 Filaments, multi-filaments, and manufacturing methods thereof
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CN104093526B (en) * 2013-02-05 2017-07-07 株式会社马山 Filaments, multi-filaments, and manufacturing methods thereof
US11425991B2 (en) 2014-03-11 2022-08-30 The Procter & Gamble Company Head for an oral care implement
US10856646B2 (en) 2014-07-15 2020-12-08 The Procter & Gamble Company Oral-care implement having color-communicative element
WO2017155252A1 (en) * 2016-03-09 2017-09-14 비비씨 주식회사 Dual-structured filament
JP2017170082A (en) * 2016-03-25 2017-09-28 優一郎 新崎 Brush bristle material and brush
US11206916B2 (en) 2016-06-03 2021-12-28 The Procter & Gamble Company Head for an oral care implement and oral care implement
US11284707B2 (en) 2016-06-03 2022-03-29 The Procter & Gamble Company Filament for an oral care implement and oral care implement
US11259623B2 (en) 2017-05-31 2022-03-01 The Procter & Gamble Company Head for an oral care implement and oral care implement
US10251470B1 (en) 2017-10-10 2019-04-09 The Procter & Gamble Company Head for an oral care implement and oral care implement
US11219302B2 (en) 2017-10-10 2022-01-11 The Procter & Gamble Company Head for an oral care implement and oral care implement

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