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JP2005154689A - Pressure sensitive adhesive sheet with separator, optical member-assembling body, and method for assembling the same - Google Patents

Pressure sensitive adhesive sheet with separator, optical member-assembling body, and method for assembling the same Download PDF

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JP2005154689A
JP2005154689A JP2003399186A JP2003399186A JP2005154689A JP 2005154689 A JP2005154689 A JP 2005154689A JP 2003399186 A JP2003399186 A JP 2003399186A JP 2003399186 A JP2003399186 A JP 2003399186A JP 2005154689 A JP2005154689 A JP 2005154689A
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separator
pressure
sensitive adhesive
adhesive layer
optical member
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Takashi Kikuchi
隆 菊池
Eisaku Ishikawa
栄作 石川
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Resonac Corp
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Hitachi Chemical Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To prepare a pressure sensitive adhesive sheet, excellent in transparency, hardly generating appearance defects such as bubble-contamination, linear streak, excellent in pasting workability and further produced at a low cost, and to provide an optical member-assembling body and a method for assembling the same. <P>SOLUTION: The pressure sensitive type adhesive sheet with a separator is prepared by installing a pressure sensitive adhesive layer for pasting an optical member at a one side surface of a plastic separator, further making it in a rolled state, and by contacting another surface of the separator, with the pressure sensitive type adhesive layer while having ≤0.1 μm surface roughness Ra of both surfaces of the plastic separator making a contact with the pressure sensitive type adhesive layer, and also while keeping ≥10 mN/25 mm difference in peeling strengths between both of the surfaces of the plastic separator from the pressure sensitive type adhesive layer and ≥80% total light transmittance of the pressure sensitive type adhesive layer. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、セパレータ付き感圧型接着シート及び光学部材組立体並びにその組立方法であり、特に板状やシート状の光学部材を貼り合わせるときに用いられ、透明性に優れ、貼り付け時の気泡混入やスジ跡等の外観欠陥が発生し難く、貼付け作業性に優れ、更に、安価に製造できる感圧型接着シートに関する。   The present invention is a pressure-sensitive adhesive sheet with a separator, an optical member assembly, and an assembling method thereof, and is particularly used when laminating a plate-like or sheet-like optical member. The present invention relates to a pressure-sensitive adhesive sheet that hardly causes appearance defects such as traces and streaks, is excellent in pasting workability, and can be manufactured at low cost.

液晶表示装置(LCD)、プラズマディスプレイ(PDP)、プロジェクションスクリーン(PJ)、ブラウン管(CRT)等のディスプレイ製品には、様々な板状、シート状の光学部材が数多く使用されている。これらの光学部材は、光学部材間の光散乱による光ロス低減の為、製品組立て時の効率アップの為、製品の強度保持の為などの目的で、透明な接着剤で光学部材間を接着することが行われている。例えば、LCDでは偏光板と液晶セルの接着、アンチリフレクション(AR)フィルムと偏光板の接着、PDPではARフィルム、電磁シールドフィルム、近赤外吸収(NIR)フィルム等の接着、CRTではARフィルムやアンチグレア(AG)フィルムとブラウン管との接着等が行われている。   A variety of plate-like and sheet-like optical members are used in display products such as a liquid crystal display (LCD), a plasma display (PDP), a projection screen (PJ), and a cathode ray tube (CRT). These optical members are bonded to each other with a transparent adhesive for the purpose of reducing the optical loss due to light scattering between the optical members, increasing the efficiency during product assembly, and maintaining the strength of the product. Things have been done. For example, for LCDs, the polarizing plate and the liquid crystal cell are bonded, for the anti-reflection (AR) film and the polarizing plate, for the PDP, an AR film, an electromagnetic shielding film, a near infrared absorption (NIR) film, etc., for the CRT, an AR film, Adhesion between an anti-glare (AG) film and a cathode ray tube is performed.

このような接着剤としては、感圧型接着剤、感熱型接着剤、紫外線(UV)硬化型接着剤等が開発されているが、貼付ける際の設備投資が比較的少なくすむ感圧型接着剤が最も広く普及している。   As such adhesives, pressure-sensitive adhesives, heat-sensitive adhesives, ultraviolet (UV) curable adhesives, and the like have been developed, but pressure-sensitive adhesives that require relatively little capital investment for application are available. Most widely used.

また、光学部材表面への接着剤層の形成方法としては、液状の接着剤を直接光学部材表面へ塗布する方法と予めセパレータフィルム上に形成しておいた接着シートを光学部材表面にラミネート転写する方法がある。液状の接着剤を直接塗布する方法は、接着剤自体が安価であるものの、塗布作業時に作業環境を汚染する(特に有機溶剤型接着剤を塗布する場合は、有機溶剤対策が必要となる)、厚み精度の良い接着剤層を形成するのが難しい、液状接着剤を塗布するため光学部材にダメージを与え易い等といった問題がある。一方、接着シートをラミネート転写する方法は、接着シート自体が比較的高価であり直接塗布する方法に比べコストは高くなり易いが、作業環境の汚染が少ない、接着するのに大掛かりな設備が必要ないといった特長もあり、2つの方式の特長に合わせて使い分けられている。   In addition, as a method of forming an adhesive layer on the surface of the optical member, a method in which a liquid adhesive is directly applied to the surface of the optical member and an adhesive sheet previously formed on a separator film are laminated and transferred to the surface of the optical member. There is a way. The method of directly applying a liquid adhesive, although the adhesive itself is inexpensive, contaminates the work environment during the application work (especially when applying an organic solvent type adhesive, an organic solvent countermeasure is required) There are problems that it is difficult to form an adhesive layer with good thickness accuracy and that the optical member is easily damaged due to the application of a liquid adhesive. On the other hand, the method of laminating and transferring the adhesive sheet is relatively expensive and the cost is likely to be higher than the method of direct application, but there is little contamination of the working environment and no large equipment is required for bonding. There are also features such as, are used properly according to the features of the two methods.

このような用途に使用される感圧型接着シートとしては、2枚のプラスチックセパレータの間に感圧型接着剤層を形成した接着シートが一般に使用されている。しかしながら、近年のディスプレイ表示精度の向上により、透明性が優れた、光学部材に貼り合せた時に気泡の混入や接着剤層の変形跡等の外観欠陥が極めて少ない、また、安価に製造できる接着シートが求められている。   As a pressure-sensitive adhesive sheet used for such applications, an adhesive sheet in which a pressure-sensitive adhesive layer is formed between two plastic separators is generally used. However, due to the recent improvement in display display accuracy, the adhesive sheet has excellent transparency, has very few appearance defects such as air bubbles and adhesive layer deformation when bonded to an optical member, and can be manufactured at low cost. Is required.

本発明は、かかる従来の技術で述べたような欠点を解消し、透明性に優れ、貼り付け時の気泡混入やスジ跡等の外観欠陥が発生し難く、貼付け作業性に優れ、更に安価に製造できるセパレータ付き感圧型接着シート及び光学部材組立体並びにその組立方法を提供することを目的とする。   The present invention eliminates the drawbacks described in the prior art, is excellent in transparency, hardly causes appearance defects such as air bubbles and streak marks at the time of pasting, is superior in pasting workability, and more inexpensive. It is an object of the present invention to provide a pressure-sensitive adhesive sheet with a separator, an optical member assembly, and a method for assembling the separator.

本発明は、光学部材を貼り合わせる感圧型接着剤層をプラスチックセパレータの片面に設け、更に、巻物状としプラスチックセパレータのもう一方の面に感圧型接着剤層が接触するセパレータ付き感圧型接着シートにおいて、前記プラスチックセパレータの感圧型接着剤層に接する両面の表面粗さRaが共に0.1μm以下であり、かつ、両面のプラスチックセパレータの感圧型接着剤層からの剥離力の差が10mN/25mm以上であり、そして、感圧型接着剤層の全光線透過率が80%以上であることを特徴とするセパレータ付き感圧型接着シートである。
また、本発明は、上記プラスチックセパレータの感圧型接着剤層からの剥離力が共に200mN/25mm以下であるセパレータ付き感圧型接着シートである。
そして、本発明は、上記感圧型接着剤層のアクリル板への接着力が1N/25mm以上であるセパレータ付き感圧型接着シートである。
更に、本発明は、接着剤層が架橋型アクリル系接着剤であるセパレータ付き感圧型接着シートである。
また、本発明は、幅両端面に1mm〜50mmの接着剤層の無い部分を設けてなるセパレータ付き感圧型接着シートである。
そして、本発明は、光学部材を貼り合せて組立てた光学部材組立体であって、上記のセパレータ付き感圧型接着シートの両面のプラスチックセパレータを剥離した感圧型接着剤層により接着されている光学部材組立体である。
更に、本発明は、光学部材を貼り合わせた光学部材組立体を組立てる方法であって、上記のセパレータ付き感圧型接着シートの剥離力の弱いプラスチックセパレータを剥離した感圧型接着剤層と第2の光学部材とを接着させて組立てる光学部材組立体の組立方法である。
The present invention provides a pressure-sensitive adhesive sheet with a separator in which a pressure-sensitive adhesive layer for bonding an optical member is provided on one side of a plastic separator, and the pressure-sensitive adhesive layer contacts the other side of the plastic separator. The surface roughness Ra of both surfaces in contact with the pressure-sensitive adhesive layer of the plastic separator is both 0.1 μm or less, and the difference in peeling force from the pressure-sensitive adhesive layer of the double-sided plastic separator is 10 mN / 25 mm or more. The pressure-sensitive adhesive sheet with a separator is characterized in that the total light transmittance of the pressure-sensitive adhesive layer is 80% or more.
Moreover, this invention is a pressure sensitive adhesive sheet with a separator whose peeling force from the pressure sensitive adhesive layer of the said plastic separator is 200 mN / 25mm or less.
And this invention is a pressure sensitive adhesive sheet with a separator whose adhesive force to the acrylic board of the said pressure sensitive adhesive layer is 1 N / 25mm or more.
Furthermore, the present invention is a pressure-sensitive adhesive sheet with a separator whose adhesive layer is a cross-linked acrylic adhesive.
Moreover, this invention is a pressure-sensitive adhesive sheet with a separator formed by providing the part which does not have an adhesive bond layer of 1 mm-50 mm in the width | variety both end surfaces.
And this invention is the optical member assembly which bonded and assembled the optical member, Comprising: The optical member adhere | attached by the pressure sensitive adhesive layer which peeled the plastic separator of both surfaces of said pressure sensitive adhesive sheet with a separator It is an assembly.
Furthermore, the present invention is a method for assembling an optical member assembly in which an optical member is bonded to the pressure-sensitive adhesive layer obtained by peeling a plastic separator having a weak peeling force from the pressure-sensitive adhesive sheet with the separator, and a second method. This is an assembling method of an optical member assembly that is assembled by bonding an optical member.

本発明によれば、透明性に優れ、貼付け時の気泡混入やスジ跡等の外観欠陥が発生し難く、貼り付け作業性に優れ、更に、安価に製造できる感圧型接着シート及び光学部材組立体を得ることができる。 According to the present invention, the pressure-sensitive adhesive sheet and the optical member assembly are excellent in transparency, hardly cause appearance defects such as air bubbles and streak marks at the time of application, have excellent application workability, and can be manufactured at low cost. Can be obtained.

本発明のセパレータ付き感圧型接着シートは、プラスチックセパレータの片面に感圧型接着剤層を設け、更に、巻物状としプラスチックセパレータのもう一方の面に感圧型接着剤層が接触する形態である。一般的な構成である2枚のプラスチックセパレータの間に感圧型接着剤層を形成した接着シートと比べ、使用するプラスチックセパレータが1枚であり、製造コストを低減できる。   The pressure-sensitive adhesive sheet with a separator of the present invention is a form in which a pressure-sensitive adhesive layer is provided on one side of a plastic separator, and is further formed in a roll shape so that the pressure-sensitive adhesive layer is in contact with the other side of the plastic separator. Compared to an adhesive sheet in which a pressure-sensitive adhesive layer is formed between two plastic separators, which is a general configuration, the number of plastic separators used is one and manufacturing costs can be reduced.

本発明のセパレータ付き感圧型接着シートは高い透明性を有しており、全光線透過率が80%以上である。より好ましくは90%以上である。全光線透過率が80%より低いと光学部材を貼り合わせた時の光透過率が悪く、ディスプレイが暗くなったり、コントラストが落ちるといった問題が発生する。ここでの全光線透過率は、プラスチックセパレータを剥がし接着剤層のみの状態で、JIS−K7105に準じ、積分球式濁度計(日本電色工業株式会社製、NDH2000)により測定した。   The pressure-sensitive adhesive sheet with a separator of the present invention has high transparency and a total light transmittance of 80% or more. More preferably, it is 90% or more. When the total light transmittance is lower than 80%, the light transmittance when the optical member is bonded is poor, and there arises a problem that the display becomes dark or the contrast is lowered. The total light transmittance here was measured with an integrating sphere turbidimeter (Nippon Denshoku Industries Co., Ltd., NDH2000) in accordance with JIS-K7105 with the plastic separator peeled off and only the adhesive layer.

本発明のセパレータ付き感圧型接着シートにおける接着剤層は、感圧型接着剤であり、アクリル板に貼付けた時の接着力が1N/25mm以上である。1N/25mm未満であると光学部材に対し十分な接着力が得られず剥れ等の問題が発生する。ここでのアクリル板に対する接着力は、巻き出した接着シートをアクリル板(住友化学工業製スミペックE000、厚み1.5mmフラット板)に圧力5880N/mをかけたゴムロールを用い2m/分の速度で貼付け、プラスチックセパレータを剥がし同様条件にて25μmPETフィルム(ユニチカ製S−25)を貼付けて試験片を作製し、更に30分間室温で放置し、その後、剥離角度180度、剥離速度0.3m/分、室温にて接着力を測定した値である。 The adhesive layer in the pressure-sensitive adhesive sheet with a separator of the present invention is a pressure-sensitive adhesive, and has an adhesive force of 1 N / 25 mm or more when attached to an acrylic plate. If it is less than 1 N / 25 mm, sufficient adhesion to the optical member cannot be obtained, causing problems such as peeling. The adhesive force with respect to an acrylic board here is the speed | rate of 2 m / min using the rubber roll which applied the pressure 5880 N / m to the acrylic board (Sumitomo Chemical Industries Sumipec E000, thickness 1.5mm flat board) for the unwound adhesive sheet. Pasting, peeling off the plastic separator and pasting a 25 μm PET film (Unit-25 S-25) under the same conditions to prepare a test piece, and leaving it at room temperature for 30 minutes, then peeling angle 180 degrees, peeling speed 0.3 m / min The value obtained by measuring the adhesive strength at room temperature.

この感圧型接着剤としては、接着剤とし一般に用いられる、各種アクリルモノマーを共重合して得られるアクリル系接着剤、天然ゴム系接着剤、ポリイソブチレン、ブチルゴム、スチレン−ブチレン−スチレン共重合体(SBS)等の合成ゴム系接着剤、エチレン−酢酸ビニル共重合体(EVA)系接着剤等、及び、これらの混合系接着剤を使用することができる。この中で特に、接着シートの全光線透過率が80%以上になるような高透明接着剤が得易い等の理由から架橋型アクリル系接着剤が好適に用いられる。 As this pressure-sensitive adhesive, acrylic adhesives obtained by copolymerizing various acrylic monomers, natural rubber adhesives, polyisobutylene, butyl rubber, styrene-butylene-styrene copolymers (commonly used as adhesives) Synthetic rubber adhesives such as SBS), ethylene-vinyl acetate copolymer (EVA) adhesives, and mixed adhesives thereof can be used. Among these, a cross-linked acrylic adhesive is preferably used because it is easy to obtain a highly transparent adhesive such that the total light transmittance of the adhesive sheet is 80% or more.

この架橋型アクリル系接着剤は、アクリル酸ブチル、アクリル酸エチル、2−エチルヘキシルアクリレート等の低Tgモノマーを主モノマーとし、アクリル酸、メタクリル酸、ヒドロキシエチルメタクリレート、ヒドロキシエチルアクリレート、アクリルアミド、アクリロニトリル等の官能基モノマーと共重合することで得られたアクリル共重合体を架橋剤にて架橋することにより得ることができる。
このアクリル共重合体としては、重量平均分子量が10万〜150万の範囲内のものが好ましく用いられる。重量平均分子量が10万より小さいと、接着剤中の低分子量物が多くなるため、接着剤の凝集力が低くなり易く、光学部材を接着した時に剥がれ等の不具合が発生し易くなる。また、重量平均分子量が150万を超えると溶剤に溶かした時の粘度が高く、接着シートにした時に平滑な接着剤塗工外観が得難い問題がある。また、このアクリル共重合体のガラス転移点(Tg)は、−20℃以下のものが好ましく使用できる。−20℃よりTgが高いと接着剤が硬くなり、室温にて圧着しても光学部材に対して適度な接着力が得られなくなる。
This cross-linked acrylic adhesive is mainly composed of a low Tg monomer such as butyl acrylate, ethyl acrylate, 2-ethylhexyl acrylate, acrylic acid, methacrylic acid, hydroxyethyl methacrylate, hydroxyethyl acrylate, acrylamide, acrylonitrile, etc. It can be obtained by crosslinking an acrylic copolymer obtained by copolymerization with a functional group monomer with a crosslinking agent.
As this acrylic copolymer, those having a weight average molecular weight in the range of 100,000 to 1,500,000 are preferably used. If the weight average molecular weight is less than 100,000, the amount of low molecular weight substances in the adhesive increases, so the cohesive force of the adhesive tends to be low, and problems such as peeling are likely to occur when the optical member is bonded. Further, when the weight average molecular weight exceeds 1,500,000, there is a problem that the viscosity when dissolved in a solvent is high, and it is difficult to obtain a smooth adhesive coating appearance when formed into an adhesive sheet. The glass transition point (Tg) of this acrylic copolymer is preferably -20 ° C or lower. If the Tg is higher than −20 ° C., the adhesive becomes hard, and an appropriate adhesive force to the optical member cannot be obtained even if it is pressure-bonded at room temperature.

この架橋剤としては、イソシアネート系、メラミン系、エポキシ系等公知の架橋剤を用いることができる。また、この架橋剤としては、接着剤中に緩やかに広がった網目状構造を形成するために、3官能、4官能といった多官能架橋剤がより好ましく用いられる。   As this crosslinking agent, known crosslinking agents such as isocyanate, melamine, and epoxy can be used. In addition, as this crosslinking agent, a polyfunctional crosslinking agent such as trifunctional or tetrafunctional is more preferably used in order to form a network structure that gently spreads in the adhesive.

また、この接着剤層には必要に応じて、粘着付与剤、酸化防止剤、紫外線吸収剤、軟化剤、充填剤等を適量添加してもよい。   In addition, an appropriate amount of a tackifier, an antioxidant, an ultraviolet absorber, a softener, a filler and the like may be added to the adhesive layer as necessary.

本発明における接着剤層の厚みは、通常5〜100μmが好ましい。更に好ましくは、10〜50μmである。5μmより薄いと光学部材表面の凹凸に追従することができず十分な接着力が得られなくなる。また、100μmより厚いと単位面積当たりの価格が上がる、厚みにより透明性が低下する等の問題が発生する。   As for the thickness of the adhesive bond layer in this invention, 5-100 micrometers is preferable normally. More preferably, it is 10-50 micrometers. When the thickness is less than 5 μm, it is impossible to follow the unevenness on the surface of the optical member and a sufficient adhesive force cannot be obtained. On the other hand, when the thickness is larger than 100 μm, problems such as an increase in price per unit area and a decrease in transparency due to the thickness occur.

本発明に用いるプラスチックセパレータの両面の接着剤層からの剥離力の差は、10mN/25mm以上である。10mN/25mm未満であると、光学部材に接着シートを貼り付ける際に巻物状から巻き出した時に、プラスチックセパレータの接着剤層を剥がそうとした面に接着剤層が付着し、プラスチックセパレータ上に平滑で外観が良い状態の接着剤層が残留しない現象(泣き別れ現象)が発生する。この泣き別れ現象が発生すると、接着剤層を光学部材に平滑に貼り付けることができず、光学部材を外観良く貼り合わせることができない。   The difference in peel force from the adhesive layers on both sides of the plastic separator used in the present invention is 10 mN / 25 mm or more. When the adhesive sheet is less than 10 mN / 25 mm, when the adhesive sheet is applied to the optical member, the adhesive layer adheres to the surface on which the adhesive layer of the plastic separator is to be peeled off and is placed on the plastic separator. The phenomenon that the adhesive layer in a smooth and good appearance does not remain (crying phenomenon) occurs. When this tear-off phenomenon occurs, the adhesive layer cannot be applied smoothly to the optical member, and the optical member cannot be attached with good appearance.

また、本発明に用いるプラスチックセパレータの両面の接着剤層からの剥離力は共に200mN/25mm以下である。200mN/25mmより剥離力が高いと、巻物状からの巻き出し作業性やセパレータの剥離作業性が悪化する、プラスチックセパレータのスムーズな剥離ができず接着剤層に折れシワや接着剤層表面に段差が発生し、光学部材に貼り付けた時にその変形が残留し外観欠陥になる、貼り合わせ時に気泡が混入し易くなるといった問題が発生する。ここでの剥離力は、剥離角度180度、剥離速度1m/分、室温にて測定した値である。
本発明に用いるプラスチックセパレータの感圧型接着剤に接触した両面の表面粗さRaは共に0.1μm以下である。表面粗さRaが0.1μmより大きくなると、セパレータ表面の粗さが接着剤層に転写し、接着剤層面が粗れ、貼り合わせ時に気泡が混入し易くなるといった問題が発生する。ここでの表面粗さは接触型表面粗さ計(例えば、株式会社小坂研究所製、測定装置SE−3C、解析装置AY−22)で測定した中心線平均粗さ(Ra)又はJIS B 0601(1994年)若しくはJIS B 0601(2001年)で定義される算術平均粗さ(Ra)を意味する。
このプラスチックセパレータの基材材質としては、例えば、ポリエステルフィルム、ポリプロピレンフィルム、ポリエチレンフィルム、ポリカーボネートフィルム、ポリスチレンフィルム、トリアセチルセルロースフィルム等を挙げることができる。これらの中で、平滑な表面が得易く生産性に優れる二軸延伸ポリエステルフィルムが好ましく使用できる。
また、このプラスチックセパレータの接着剤層と接する両面には離型剤処理を行っている。この離型剤としては、シリコーン樹脂、フッ素樹脂、ポリビニルアルコール樹脂、アルキル基を有する樹脂等の単体や変性体、混合物等が挙げられる。その中で、接着剤層の軽剥離が容易に得ることができるシリコーン樹脂が好ましく使用でき、特に熱や紫外線、電子線等で硬化したシリコーン樹脂は、接着剤層へのシリコーン樹脂の転着が少ない等の理由からより好ましく使用できる。
プラスチックセパレータの厚さとしては、10〜200μmが好ましく用いられる。更に好ましくは、20〜75μmである。10μmより薄いとフィルム強度が不足し、接着シート製造時にフィルムが破れる、シワが入り易い等の問題が発生する。また、200μmより厚いとフィルム自体が高価になる等の問題が発生する。
Moreover, the peeling force from the adhesive layers on both sides of the plastic separator used in the present invention is 200 mN / 25 mm or less. If the peeling force is higher than 200 mN / 25 mm, the unwinding workability from the roll shape and the peeling workability of the separator deteriorate, the plastic separator cannot be smoothly peeled off, and it is folded into the adhesive layer and wrinkles or steps on the surface of the adhesive layer Occurs, the deformation remains when it is attached to the optical member, resulting in an appearance defect, and bubbles are likely to be mixed during the attachment. The peeling force here is a value measured at room temperature at a peeling angle of 180 degrees, a peeling speed of 1 m / min.
Both surface roughness Ra of the plastic separator used for this invention which contacted the pressure sensitive adhesive is 0.1 micrometer or less. When the surface roughness Ra is larger than 0.1 μm, the roughness of the separator surface is transferred to the adhesive layer, the adhesive layer surface becomes rough, and bubbles are likely to be mixed during bonding. The surface roughness here is centerline average roughness (Ra) measured with a contact-type surface roughness meter (for example, measuring device SE-3C, analysis device AY-22, manufactured by Kosaka Laboratory Ltd.) or JIS B 0601. (1994) or JIS B 0601 (2001) means arithmetic mean roughness (Ra).
Examples of the material for the plastic separator include polyester film, polypropylene film, polyethylene film, polycarbonate film, polystyrene film, and triacetyl cellulose film. Among these, a biaxially stretched polyester film that is easy to obtain a smooth surface and excellent in productivity can be preferably used.
Moreover, the mold release agent process is performed on both surfaces which contact | connect the adhesive bond layer of this plastic separator. Examples of the releasing agent include simple substances such as silicone resins, fluororesins, polyvinyl alcohol resins, and resins having an alkyl group, modified products, and mixtures. Among them, a silicone resin that can easily be easily peeled off from the adhesive layer can be preferably used. Particularly, a silicone resin cured by heat, ultraviolet rays, electron beams, etc. can transfer the silicone resin to the adhesive layer. It can be more preferably used for the reason of few.
The thickness of the plastic separator is preferably 10 to 200 μm. More preferably, it is 20-75 micrometers. If the thickness is less than 10 μm, the film strength is insufficient, and problems such as tearing of the film during the production of the adhesive sheet, and easy wrinkling occur. On the other hand, if it is thicker than 200 μm, the film itself becomes expensive.

本発明のセパレータ付き感圧型接着シートは、幅両端面に1mm〜50mmの接着剤層の無い部分を設けていることが好ましい。接着剤層がプラスチックセパレータ端部まで全面に設けてあると、巻物状から巻き出した時に、剥がしたプラスチックセパレータ端面に接着剤層が付着し、もう一方のプラスチックセパレータ面上に平滑で外観の良い状態の接着剤が残留しない現象(泣き別れ現象)が発生する。この泣き別れ現象が発生すると、接着剤層を光学部材に平滑に貼り付けることができず、光学部材を外観良く貼り合わせることができない。また、幅両端面に50mmより大きい接着剤層が無い部分を設けると、巻物とした場合に接着剤層が無い部分とある部分でのひずみが大きくなり、端部からプラスチックセパレータが剥離する現象(トンネリング現象)が発生し易くなる。   In the pressure-sensitive adhesive sheet with a separator of the present invention, it is preferable to provide a portion having no adhesive layer of 1 mm to 50 mm on both end faces of the width. If the adhesive layer is provided on the entire surface up to the end of the plastic separator, the adhesive layer adheres to the peeled end surface of the plastic separator when unrolled from the roll, and the other plastic separator surface is smooth and has a good appearance. The phenomenon that the adhesive in the state does not remain (crying separation phenomenon) occurs. When this tear-off phenomenon occurs, the adhesive layer cannot be applied smoothly to the optical member, and the optical member cannot be attached with good appearance. In addition, when a portion having no adhesive layer larger than 50 mm is provided on both end faces of the width, a phenomenon in which the plastic separator is peeled off from the end portion due to increased distortion in a portion where there is no adhesive layer when the roll is formed ( Tunneling phenomenon) is likely to occur.

このトンネリング現象が発生すると、接着剤層にプラスチックセパレータが剥離した凹凸形状が転写し、光学部材に貼り合わせた時にその形状が残留し外観欠陥になる。50mm以下であれば、巻物とした場合の接着剤層が無い部分とある部分でのひずみは小さく、端部からプラスチックセパレータが剥離する現象(トンネリング現象)が発生し難くなる。   When this tunneling phenomenon occurs, the concavo-convex shape from which the plastic separator is peeled off is transferred to the adhesive layer, and when it is bonded to the optical member, the shape remains, resulting in an appearance defect. If it is 50 mm or less, the distortion at the part where there is no adhesive layer and the part where it is made into a roll is small, and the phenomenon (tunneling phenomenon) in which the plastic separator peels from the end part becomes difficult to occur.

ここでの粘着剤層の形成方法としては、有機溶剤に溶解し粘度を調整した接着剤を塗布する方法、接着剤を溶融し塗布する方法や水に分散し塗布する方法等の公知の方法を用いることができるが、架橋型アクリル系接着剤の形成方法としては、有機溶剤に溶解し粘度を調整した接着剤を塗布する方法が一般的である。
更に、このプラスチックセパレータには、必要に応じてプラスチックフィルム表面に離型剤層との密着力を向上するために、コロナ処理、プラズマ処理といった表面処理や下塗り剤(プライマ)の塗布等を行ってもよい。また、必要に応じて静電気発生を防止する目的で帯電防止剤の塗布を行ってもよい。ここでの帯電防止剤としては、例えば、第4級アンモニウム塩、ピリジニウム塩、第1〜3級アミノ基等のカチオン性基を有する各種カチオン性帯電防止剤、スルホン酸塩基、硫酸エステル塩基、リン酸エステル塩基、スルホン酸塩基等のアニオン性基を有するアニオン系帯電防止剤、アミノ酸系、アミノ硫酸エステル系等の両性帯電防止剤、アミノアルコール系、グリセリン系、ポリエチレングリコール系等のノニオン性帯電防止剤等の各種帯電防止剤、更には、これらの帯電防止剤を高分子量化した高分子型帯電防止剤等が挙げられる。
As a method for forming the pressure-sensitive adhesive layer, known methods such as a method of applying an adhesive whose viscosity is adjusted by dissolving in an organic solvent, a method of melting and applying an adhesive, and a method of dispersing and applying in water are used. Although it can be used, as a method for forming a cross-linked acrylic adhesive, a method of applying an adhesive having a viscosity adjusted by dissolving in an organic solvent is common.
Furthermore, this plastic separator is subjected to surface treatment such as corona treatment or plasma treatment or application of a primer (primer) to improve the adhesion of the release agent layer to the surface of the plastic film as necessary. Also good. Moreover, you may apply | coat an antistatic agent in order to prevent static electricity generation as needed. Examples of the antistatic agent here include various cationic antistatic agents having a cationic group such as a quaternary ammonium salt, a pyridinium salt, and a primary to tertiary amino group, a sulfonate group, a sulfate ester base, and phosphorus. Anionic antistatic agents having an anionic group such as acid ester base and sulfonate group, amphoteric antistatic agents such as amino acid and aminosulfate ester, nonionic antistatic agents such as amino alcohol, glycerin and polyethylene glycol Examples thereof include various antistatic agents such as an agent, and polymer antistatic agents obtained by increasing the molecular weight of these antistatic agents.

主モノマーとしてブチルアクリレートを用い、官能基モノマーとしてアクリル酸とメタクリル酸を用いたアクリル共重合体を溶液重合法にて合成した。この合成したアクリル共重合体の重量平均分子量は40万であった。
このアクリル共重合体100重量部に対し、エポキシ系架橋剤を0.1重量部配合した接着剤溶液を調整し、厚さ25μm、幅400mmのニ軸延伸ポリエステルフィルムの両面に剥離力の異なる熱硬化型シリコーン樹脂系離型剤を塗布したセパレータの重剥離離型剤処理面に、乾燥時の接着剤厚さが40μmになるよう塗工乾燥し、巻物状に巻き取った。この接着シートを室温で1週間放置し十分にエージングを行った後、試験に使用した。
尚、この接着シートにおける接着剤を塗工したセパレータの接着剤層からの剥離力は75mN/25mmであり、また、セパレータのもう一方の面(背面)の接着剤層からの剥離力は42mN/25mmであった。また、セパレータの表面粗さを測定した結果は共に0.05μmであった。
An acrylic copolymer using butyl acrylate as the main monomer and acrylic acid and methacrylic acid as the functional group monomers was synthesized by a solution polymerization method. The synthesized acrylic copolymer had a weight average molecular weight of 400,000.
An adhesive solution containing 0.1 part by weight of an epoxy-based cross-linking agent is prepared with respect to 100 parts by weight of this acrylic copolymer, and heat having different peeling forces on both sides of a biaxially stretched polyester film having a thickness of 25 μm and a width of 400 mm. The separator coated with the curable silicone resin release agent was coated and dried on the heavy release release agent treated surface of the separator so that the thickness of the adhesive when dried was 40 μm, and wound into a roll. This adhesive sheet was allowed to stand at room temperature for 1 week and sufficiently aged, and then used for the test.
The peeling force from the adhesive layer of the separator coated with the adhesive in this adhesive sheet is 75 mN / 25 mm, and the peeling force from the adhesive layer on the other side (back surface) of the separator is 42 mN / It was 25 mm. Moreover, the result of measuring the surface roughness of the separator was both 0.05 μm.

接着剤を塗工したセパレターの離型剤処理面の離型性をやや重くした以外は、実施例1と同様にして接着シートを作製した。
尚、この接着シートにおける接着剤を塗工したセパレータの接着剤層からの剥離力は118mN/25mmであった。
An adhesive sheet was produced in the same manner as in Example 1 except that the release property of the release agent-treated surface of the separator coated with the adhesive was slightly increased.
In addition, the peeling force from the adhesive bond layer of the separator which apply | coated the adhesive agent in this adhesive sheet was 118 mN / 25mm.

比較例1
セパレータの両面の離型性を同じにした以外は、実施例1と同様にして接着シートを作製した。
尚、この接着シートにおける接着剤を塗工したセパレータの接着剤層からの剥離力は48mN/25mmであり、また、セパレータのもう一方の面(背面)の接着剤層からの剥離力は42mN/25mmであった。
Comparative Example 1
An adhesive sheet was produced in the same manner as in Example 1 except that the releasability on both sides of the separator was the same.
The peeling force from the adhesive layer of the separator coated with the adhesive in this adhesive sheet is 48 mN / 25 mm, and the peeling force from the adhesive layer on the other side (back surface) of the separator is 42 mN / It was 25 mm.

比較例2
接着剤を塗工したセパレターの離型剤処理面の離型性を重くした以外は、実施例1と同様にして接着シートを作製した。
尚、この接着シートにおける接着剤を塗工したセパレータの接着剤層からの剥離力は490mN/25mmであった。
Comparative Example 2
An adhesive sheet was produced in the same manner as in Example 1 except that the release property of the release agent-treated surface of the separator coated with the adhesive was increased.
In addition, the peeling force from the adhesive bond layer of the separator which apply | coated the adhesive agent in this adhesive sheet was 490 mN / 25mm.

比較例3
セパレータの基材フィルムにニ軸延伸ポリプロピレンフィルムを使用した以外は、実施例1と同様にして接着シートを作製した。
尚、この接着シートにおける接着剤を塗工したセパレータの接着剤層からの剥離力は89mN/25mmであり、また、セパレータのもう一方の面(背面)の接着剤層からの剥離力は52mN/25mmであった。また、セパレータの表面粗さを測定した結果は共に0.30μmであった。
上記の各実施例及び比較例の接着シートの特性値を下記の方法で測定した。それぞれの結果を表1にまとめた。
Comparative Example 3
An adhesive sheet was produced in the same manner as in Example 1 except that a biaxially stretched polypropylene film was used as the separator base film.
The peeling force from the adhesive layer of the separator coated with the adhesive in this adhesive sheet is 89 mN / 25 mm, and the peeling force from the adhesive layer on the other side (back surface) of the separator is 52 mN / It was 25 mm. The result of measuring the surface roughness of the separator was 0.30 μm.
The characteristic values of the adhesive sheets of the above examples and comparative examples were measured by the following methods. The results are summarized in Table 1.

Figure 2005154689
(1)全光線透過率
全光線透過率は、2枚のプラスチックセパレータを剥がし接着剤層のみの状態で、積分球式濁度計(日本電色工業株式会社製、NDH2000型)を用いて、JIS−K7105に順じて測定した。
(2)対アクリル板接着力
一方のプラスチックセパレータを剥がした接着シートをアクリル板(住友化学工業製スミペックE000、厚み1.5mmフラット板)に圧力5880N/mをかけたゴムロールを用い2m/分の速度で貼付け、更にもう一方のプラスチックセパレータを剥がし同様の条件にて25μmPETフィルム(ユニチカ製S−25)を貼付けて試験片を作製し、更に30分間室温で放置し、その後、剥離角度180度、剥離速度0.3m/分、室温にて接着力(N/25mm)を測定した。
(3)セパレータの剥離力
接着シートを25mm幅に切断し、粘着剤層からプラスチックセパレータを剥離角度180度、剥離速度1m/分、室温雰囲気下で剥がす時の剥離力(mN/25mm)を測定した。
(4)貼り合わせ作業性
巻物から巻出した接着シートを、大きさ200mm×300mmのアクリル板(住友化学工業製スミペックE000、厚み1.5mmフラット板)に圧力5880N/mをかけたゴムロールを用い2m/分の速度で貼付けた。更にもう一方のプラスチックセパレータを剥がし、50μmPETフィルム(ユニチカ製S−50)を同様の条件にてラミネートした。
このときの貼り合わせ作業性を、以下の基準で評価した。
:巻物から容易に巻出すことができ、貼り合わせ作業が容易にできた。
× :巻物から巻出し時に泣き別れ現象が発生し、貼り合わせ作業性ができなかった。
(5)貼り合わせ外観
貼り合わせ作業性を評価した試験片の外観を確認し、以下の基準で評価した。
:気泡の混入や接着剤層の変形跡等がみられず外観が良好であった。
× :気泡の混入や接着剤層の変形跡等の外観欠陥が観察された。
− :貼り合わせ作業ができす、外観を確認できなかった。
表1から明らかなように、本発明の接着シートである実施例1〜2は、貼り合わせ作業性に優れ、また、貼り合わせた試験片の外観も良好であった。
それに対し、プラスチックセパレータの両面の離型性を同じにした比較例1はセパレータ剥離時に泣き別れ現象が発生し、貼り合わせ作業性が悪かった。また、接着剤を塗工したセパレターの離型剤処理面からの剥離力が490mN/25mmと高い比較例2は、アクリル板に貼り合わせた後のセパレータの剥離がスムーズにできない為に接着剤表面に段差が発生し、貼り合わせた試験片にも接着剤層の変形による外観異常が観察された。また、セパレータの表面粗さRaが0.3μmと大きい比較例3では、接着剤層に粗さが転写し、貼り合わせた試験片に気泡混入が観察された。
Figure 2005154689
(1) Total light transmittance The total light transmittance is measured using an integrating sphere turbidimeter (NDH2000 model, manufactured by Nippon Denshoku Industries Co., Ltd.) with only two adhesive separators peeled off. It measured according to JIS-K7105.
(2) Adhesive strength against acrylic plate 2 m / min using a rubber roll with a pressure of 5880 N / m applied to an acrylic plate (Sumipec E000 manufactured by Sumitomo Chemical Co., Ltd., thickness 1.5 mm flat plate) after peeling off one plastic separator At a speed, the other plastic separator was peeled off, and a 25 μm PET film (S-25 manufactured by Unitika) was attached under the same conditions to prepare a test piece. The test piece was further left at room temperature for 30 minutes, and then the peeling angle was 180 degrees. The adhesive force (N / 25 mm) was measured at a peeling speed of 0.3 m / min at room temperature.
(3) Separation force of the separator The adhesive sheet is cut to a width of 25 mm, and the peeling force (mN / 25 mm) when the plastic separator is peeled from the adhesive layer at a peeling angle of 180 degrees, a peeling speed of 1 m / min at room temperature is measured. did.
(4) Bonding workability A rubber roll in which a pressure of 5880 N / m is applied to an acrylic sheet (Sumitomo Chemical Industries Sumipec E000, thickness 1.5 mm flat plate) having a size of 200 mm × 300 mm is used. Affixed at a speed of 2 m / min. The other plastic separator was peeled off, and a 50 μm PET film (S-50 manufactured by Unitika) was laminated under the same conditions.
The bonding workability at this time was evaluated according to the following criteria.
: Can be easily unwound from the scroll, and can be easily bonded.
X: Peeling phenomenon occurred when unwinding from the scroll, and the bonding workability could not be achieved.
(5) Bonding appearance The appearance of the test piece evaluated for bonding workability was confirmed and evaluated according to the following criteria.
: Appearance was good with no mixing of bubbles or deformation marks of the adhesive layer.
X: Appearance defects such as bubbles and deformation marks of the adhesive layer were observed.
-: The pasting work can be performed, but the appearance cannot be confirmed.
As is clear from Table 1, Examples 1 and 2 which are adhesive sheets of the present invention were excellent in bonding workability, and the appearance of the bonded test pieces was also good.
On the other hand, in Comparative Example 1 in which the releasability on both sides of the plastic separator was the same, a tearing phenomenon occurred when the separator was peeled off, and the bonding workability was poor. In addition, Comparative Example 2 in which the separation force from the release agent-treated surface of the separator coated with adhesive is as high as 490 mN / 25 mm is because the separator cannot be smoothly peeled off after being bonded to the acrylic plate. A difference in level was observed in the specimen, and abnormal appearance due to deformation of the adhesive layer was also observed in the bonded specimens. Further, in Comparative Example 3 where the surface roughness Ra of the separator was as large as 0.3 μm, the roughness was transferred to the adhesive layer, and bubble mixing was observed in the bonded test piece.

Claims (7)

光学部材を貼り合わせる感圧型接着剤層をプラスチックセパレータの片面に設け、更に、巻物状としプラスチックセパレータのもう一方の面に感圧型接着剤層が接触するセパレータ付き感圧型接着シートにおいて、前記プラスチックセパレータの感圧型接着剤層に接する両面の表面粗さRaが共に0.1μm以下であり、かつ、両面のプラスチックセパレータの感圧型接着剤層からの剥離力の差が10mN/25mm以上であり、そして、感圧型接着剤層の全光線透過率が80%以上であることを特徴とするセパレータ付き感圧型接着シート。 In the pressure-sensitive adhesive sheet with a separator, the pressure-sensitive adhesive layer for bonding the optical member is provided on one side of the plastic separator, and the pressure-sensitive adhesive layer is in a roll shape and the pressure-sensitive adhesive layer contacts the other side of the plastic separator. The surface roughness Ra on both sides in contact with the pressure-sensitive adhesive layer is 0.1 μm or less, and the difference in peel force from the pressure-sensitive adhesive layer of the double-sided plastic separator is 10 mN / 25 mm or more, and A pressure-sensitive adhesive sheet with a separator, wherein the pressure-sensitive adhesive layer has a total light transmittance of 80% or more. 上記プラスチックセパレータの感圧型接着剤層からの剥離力が共に200mN/25mm以下であることを特徴とする請求項1記載のセパレータ付き感圧型接着シート。 2. The pressure-sensitive adhesive sheet with a separator according to claim 1, wherein the peeling force of the plastic separator from the pressure-sensitive adhesive layer is 200 mN / 25 mm or less. 上記感圧型接着剤層のアクリル板への接着力が1N/25mm以上であることを特徴とする請求項1又は2記載のセパレータ付き感圧型接着シート。 The pressure-sensitive adhesive sheet with a separator according to claim 1 or 2, wherein an adhesive force of the pressure-sensitive adhesive layer to the acrylic plate is 1 N / 25 mm or more. 接着剤層が架橋型アクリル系接着剤であることを特徴とする請求項1〜3のいずれか1項に記載のセパレータ付き感圧型接着シート。 The pressure-sensitive adhesive sheet with a separator according to any one of claims 1 to 3, wherein the adhesive layer is a cross-linked acrylic adhesive. 幅両端面に1mm〜50mmの接着剤層の無い部分を設けてなることを特徴とする請求項1〜4のいずれか1項に記載のセパレータ付き感圧型接着シート。 The pressure-sensitive adhesive sheet with a separator according to any one of claims 1 to 4, wherein portions having no adhesive layer of 1 mm to 50 mm are provided on both end faces of the width. 光学部材を貼り合せて組立てた光学部材組立体であって、請求項1〜5のいずれか1項に記載のセパレータ付き感圧型接着シートの両面のプラスチックセパレータを剥離した感圧型接着剤層により接着されていることを特徴とする光学部材組立体。 An optical member assembly assembled by bonding optical members, and bonded by a pressure-sensitive adhesive layer from which the plastic separators on both sides of the pressure-sensitive adhesive sheet with a separator according to any one of claims 1 to 5 are peeled off. An optical member assembly, wherein 光学部材を貼り合わせた光学部材組立体を組立てる方法であって、請求項1〜5のいずれか1項に記載のセパレータ付き感圧型接着シートの剥離力の弱いプラスチックセパレータを剥離した感圧型接着剤層と第2の光学部材とを接着させて組立てることを特徴とする光学部材組立体の組立方法。


A method for assembling an optical member assembly in which optical members are bonded to each other, wherein the pressure-sensitive adhesive is a pressure-sensitive adhesive sheet with a separator having a weak peeling force. A method of assembling an optical member assembly, comprising assembling a layer and a second optical member by bonding.


JP2003399186A 2003-11-28 2003-11-28 Pressure sensitive adhesive sheet with separator, optical member-assembling body, and method for assembling the same Pending JP2005154689A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007119722A (en) * 2005-10-26 2007-05-17 Cheil Industries Inc Near-infrared ray absorbing and color-correcting pressure-sensitive adhesive composition and film using the same
JP2010185038A (en) * 2009-02-13 2010-08-26 Mitsubishi Plastics Inc Adhesive sheet and adhesive sheet wound body
WO2011152305A1 (en) * 2010-06-03 2011-12-08 日東電工株式会社 Sheet product
WO2011162191A1 (en) * 2010-06-22 2011-12-29 日東電工株式会社 Adhesive layer, adhesive film, and optical device
JP2012027260A (en) * 2010-07-23 2012-02-09 Dainippon Printing Co Ltd Polarizing sheet laminate
EP2634228A2 (en) 2012-02-29 2013-09-04 Nitto Denko Corporation Self-rolling adhesive film
US8809454B2 (en) 2006-02-23 2014-08-19 Lintec Corporation Pressure-sensitive adhesive composition and pressure-sensitive adhesive sheet using the same
CN104073177A (en) * 2013-03-28 2014-10-01 琳得科株式会社 Double-sided adhesive sheet and roll thereof
WO2022071212A1 (en) * 2020-09-30 2022-04-07 日東電工株式会社 Optical pressure-sensitive adhesive sheet with separator
WO2022071213A1 (en) * 2020-09-30 2022-04-07 日東電工株式会社 Separator-attached optical adhesive sheet

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0345939U (en) * 1989-09-09 1991-04-26
JPH064047U (en) * 1991-12-24 1994-01-18 株式会社スリオンテック Double-sided adhesive tape with no base material for postcards
JPH11106714A (en) * 1997-10-08 1999-04-20 Hitachi Chem Co Ltd Film adhesive for circuit connection
JP2000247181A (en) * 1999-03-01 2000-09-12 Mazda Motor Corp Vehicle lighting system
JP2000247010A (en) * 1999-03-03 2000-09-12 Riso Kagaku Corp Digital stencil printing machine
JP2001026759A (en) * 1999-04-28 2001-01-30 Bridgestone Corp Adhesive composition for optical function member integrated display device, adhesive film, adhesive film laminate, optical function member integrated display device, and method of manufacturing the same
JP2001030427A (en) * 1999-07-23 2001-02-06 Teijin Ltd Laminated film for surface protection and laminate comprising the same
JP2001074933A (en) * 1999-09-01 2001-03-23 Nitto Denko Corp Surface protective film
JP2001106991A (en) * 1999-10-01 2001-04-17 Teijin Ltd Surface-protecting film and laminate composed thereof
JP2002060707A (en) * 2000-08-17 2002-02-26 Teijin Ltd Surface protective film and its laminate
JP2002210879A (en) * 2001-01-17 2002-07-31 Toray Ind Inc Mold releasable film
JP2002363510A (en) * 2001-06-06 2002-12-18 Hitachi Chem Co Ltd Pressure-sensitive adhesive film for protecting optical sheet
JP2003201452A (en) * 2002-01-09 2003-07-18 Hitachi Chem Co Ltd Pressure-sensitive adhesive sheet with separator, assembly of optical member and method for assembling the same

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0345939U (en) * 1989-09-09 1991-04-26
JPH064047U (en) * 1991-12-24 1994-01-18 株式会社スリオンテック Double-sided adhesive tape with no base material for postcards
JPH11106714A (en) * 1997-10-08 1999-04-20 Hitachi Chem Co Ltd Film adhesive for circuit connection
JP2000247181A (en) * 1999-03-01 2000-09-12 Mazda Motor Corp Vehicle lighting system
JP2000247010A (en) * 1999-03-03 2000-09-12 Riso Kagaku Corp Digital stencil printing machine
JP2001026759A (en) * 1999-04-28 2001-01-30 Bridgestone Corp Adhesive composition for optical function member integrated display device, adhesive film, adhesive film laminate, optical function member integrated display device, and method of manufacturing the same
JP2001030427A (en) * 1999-07-23 2001-02-06 Teijin Ltd Laminated film for surface protection and laminate comprising the same
JP2001074933A (en) * 1999-09-01 2001-03-23 Nitto Denko Corp Surface protective film
JP2001106991A (en) * 1999-10-01 2001-04-17 Teijin Ltd Surface-protecting film and laminate composed thereof
JP2002060707A (en) * 2000-08-17 2002-02-26 Teijin Ltd Surface protective film and its laminate
JP2002210879A (en) * 2001-01-17 2002-07-31 Toray Ind Inc Mold releasable film
JP2002363510A (en) * 2001-06-06 2002-12-18 Hitachi Chem Co Ltd Pressure-sensitive adhesive film for protecting optical sheet
JP2003201452A (en) * 2002-01-09 2003-07-18 Hitachi Chem Co Ltd Pressure-sensitive adhesive sheet with separator, assembly of optical member and method for assembling the same

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8679725B2 (en) 2005-10-26 2014-03-25 Cheil Industries, Inc. Near-infrared absorbing and color compensation film composition for electronic devices
US7935475B2 (en) 2005-10-26 2011-05-03 Cheil Industries, Inc. Near-infrared absorbing and color compensation film composition for electronic devices
JP2007119722A (en) * 2005-10-26 2007-05-17 Cheil Industries Inc Near-infrared ray absorbing and color-correcting pressure-sensitive adhesive composition and film using the same
US8809454B2 (en) 2006-02-23 2014-08-19 Lintec Corporation Pressure-sensitive adhesive composition and pressure-sensitive adhesive sheet using the same
JP2010185038A (en) * 2009-02-13 2010-08-26 Mitsubishi Plastics Inc Adhesive sheet and adhesive sheet wound body
WO2011152305A1 (en) * 2010-06-03 2011-12-08 日東電工株式会社 Sheet product
JP2011252109A (en) * 2010-06-03 2011-12-15 Nitto Denko Corp Sheet product
CN102947404A (en) * 2010-06-22 2013-02-27 日东电工株式会社 Adhesive layer, adhesive film, and optical device
WO2011162191A1 (en) * 2010-06-22 2011-12-29 日東電工株式会社 Adhesive layer, adhesive film, and optical device
US9102852B2 (en) 2010-06-22 2015-08-11 Nitto Denko Corporation Pressure-sensitive adhesive layer, pressure-sensitive adhesive film, and optical device
JP2012027260A (en) * 2010-07-23 2012-02-09 Dainippon Printing Co Ltd Polarizing sheet laminate
EP2634228A2 (en) 2012-02-29 2013-09-04 Nitto Denko Corporation Self-rolling adhesive film
CN104073177A (en) * 2013-03-28 2014-10-01 琳得科株式会社 Double-sided adhesive sheet and roll thereof
WO2022071212A1 (en) * 2020-09-30 2022-04-07 日東電工株式会社 Optical pressure-sensitive adhesive sheet with separator
WO2022071213A1 (en) * 2020-09-30 2022-04-07 日東電工株式会社 Separator-attached optical adhesive sheet

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