JP2002012521A - Emulsified hair cosmetic - Google Patents
Emulsified hair cosmeticInfo
- Publication number
- JP2002012521A JP2002012521A JP2000193486A JP2000193486A JP2002012521A JP 2002012521 A JP2002012521 A JP 2002012521A JP 2000193486 A JP2000193486 A JP 2000193486A JP 2000193486 A JP2000193486 A JP 2000193486A JP 2002012521 A JP2002012521 A JP 2002012521A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- polyoxyethylene
- emulsified cosmetic
- fatty acid
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- SFFVATKALSIZGN-UHFFFAOYSA-N hexadecan-7-ol Chemical compound CCCCCCCCCC(O)CCCCCC SFFVATKALSIZGN-UHFFFAOYSA-N 0.000 description 1
- PXDJXZJSCPSGGI-UHFFFAOYSA-N hexadecanoic acid hexadecyl ester Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 1
- QAKXLTNAJLFSQC-UHFFFAOYSA-N hexadecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC QAKXLTNAJLFSQC-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- VLHZUYUOEGBBJB-UHFFFAOYSA-N hydroxy stearic acid Natural products OCCCCCCCCCCCCCCCCCC(O)=O VLHZUYUOEGBBJB-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- FMMOOAYVCKXGMF-UHFFFAOYSA-N linoleic acid ethyl ester Natural products CCCCCC=CCC=CCCCCCCCC(=O)OCC FMMOOAYVCKXGMF-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229920002114 octoxynol-9 Polymers 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 229940056211 paraffin Drugs 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229940010310 propylene glycol dioleate Drugs 0.000 description 1
- 229940026235 propylene glycol monolaurate Drugs 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- DCBSHORRWZKAKO-UHFFFAOYSA-N rac-1-monomyristoylglycerol Chemical compound CCCCCCCCCCCCCC(=O)OCC(O)CO DCBSHORRWZKAKO-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 229940098385 triisostearin Drugs 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、頭髪用乳化化粧料
に関し、更に詳しくは、水中油型の頭髪用乳化化粧料に
関し、その目的は、整髪力に優れ、一旦整えたヘアスタ
イルを長時間保持できるとともに、ごわつき感やべたつ
き感などの手触りの悪さを与えず、しかも艶と弾力を付
与できる頭髪用乳化化粧料を提供することにある。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an emulsified cosmetic for hair, and more particularly, to an oil-in-water emulsified cosmetic for hair. It is an object of the present invention to provide an emulsified cosmetic for hair that can be retained, does not give a bad touch such as a stiffness or a sticky feeling, and can impart gloss and elasticity.
【0002】[0002]
【従来の技術】ヘアスタイルを整えるとともに、整えた
ヘアスタイルを保持することができる整髪料としては、
油性整髪料や液体整髪料などが用いられている。油性整
髪料としては、ヘアオイルやポマード、或いはチックな
どを挙げることができる。油性整髪料には、水は含まれ
ずに植物油やワックス等の油性成分が大量に含まれるた
めに整髪力に優れることから、多くの日本人のように硬
い髪質の人の間で主に用いられている。また、液体整髪
料としては、ヘアクリームやヘアリキッド等を挙げるこ
とができる。液体整髪料には、水と油性成分が含まれて
おり、これを各種界面活性剤を用いて油中水型又は水中
油型のエマルジョンとすることにより、さっぱりとした
使用感が得られることから、ソフトな仕上がり感を求め
る人の間で広く用いられている。2. Description of the Related Art As a hairdressing agent that can prepare a hairstyle and maintain the prepared hairstyle,
Oil-based hairdressings and liquid hairdressings are used. Examples of the oil-based hairdressing agent include hair oil, pomade, and tic. Oil-based hairdressing products do not contain water and contain a large amount of oily components such as vegetable oils and waxes, so they have excellent hair-dressing power, so they are mainly used by people with hard hair quality like many Japanese. Have been. Examples of the liquid hair styling agent include a hair cream and a hair liquid. Liquid hair styling contains water and oily components, which can be used as a water-in-oil type or oil-in-water type emulsion using various surfactants to provide a refreshing feel. Widely used by those who want a soft finish.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、従来の
整髪料には以下のような問題が存在した。まず、油性整
髪料には油性成分が多く含まれるために、整髪力に優れ
る反面、頭髪に対してべたつき感や不自然な光沢を与
え、しかもシャンプーで落としにくいという問題が存在
した。また、頭髪を使用者の好みの形状となるように変
化を与え、この変化を長時間保持することは困難であっ
た。また、従来の液体整髪料は、べたつき感や不自然な
光沢を抑制し、また洗髪も容易であるが、油性整髪料と
比較すると整髪力に劣るという問題が存在した。ところ
で、液体整髪料にガム質や樹脂類などの被膜形成性物質
を配合することにより、油性整髪料のようなべたつき感
や不自然な光沢を与えずに、強い整髪力を付与すること
が可能である。しかしながら、この場合は、被膜により
頭髪が固定されるために、ごわつき感を与え頭髪の手触
りが悪く、頭髪本来の弾力性が失われてしまうという問
題が存在した。However, the conventional hair styling has the following problems. First, the oil-based hairdressing agent contains a large amount of oily components, so that it has excellent hair-styling power, but has a problem that it gives sticky feeling and unnatural luster to the hair and that it is hard to remove with shampoo. Further, it is difficult to change the hair so that the hair has a shape desired by the user, and to maintain the change for a long time. Further, the conventional liquid hair styling suppresses stickiness and unnatural luster and is easy to wash hair, but has a problem in that hair styling power is inferior to oil-based hair styling. By combining film-forming substances such as gums and resins with liquid hair styling materials, strong hair styling power can be imparted without giving the oily hair styling a sticky feeling or unnatural luster. It is. However, in this case, since the hair is fixed by the coating, there is a problem that the stiffness is given, the touch of the hair is poor, and the original elasticity of the hair is lost.
【0004】かかる実情に鑑みて本発明者らは鋭意研究
を続けたところ、ポリオキシエチレンミツロウと非イオ
ン界面活性剤からなる水中油型のエマルジョンを形成す
ることにより、べたつき感や油っぽい不自然な光沢を付
与することなく、高い整髪力を与えることができ、しか
もごわつき感等の手触りの悪さを与えずに弾力性に優れ
た頭髪とすることができることを見いだし本発明の完成
に至った。In view of such circumstances, the present inventors have conducted intensive studies and found that an oil-in-water emulsion comprising polyoxyethylene beeswax and a nonionic surfactant was formed to give a sticky feeling and oily non-stickiness. It has been found that the hair can be given a high hair styling power without imparting a natural luster, and that the hair can be excellent in elasticity without giving a feeling of stiffness such as stiffness, and the present invention has been completed. .
【0005】[0005]
【課題を解決するための手段】即ち、請求項1に係る発
明は、ポリオキシエチレンミツロウと非イオン界面活性
剤が含有されてなることを特徴とする頭髪用乳化化粧料
に関する。請求項2に係る発明は、前記非イオン界面活
性剤が、ポリオキシエチレン付加型界面活性剤、糖脂肪
酸エステル、プロピレングリコール脂肪酸エステル、グ
リセリン脂肪酸エステルのうちから選択された一種以上
であることを特徴とする請求項1に記載の頭髪用乳化化
粧料に関する。請求項3に係る発明は、前記非イオン界
面活性剤が、ポリオキシエチレン硬化ヒマシ油、モノス
テアリン酸グリセリン、モノステアリン酸ソルビタン、
モノステアリン酸ポリオキシエチレンソルビタンのうち
から選択された一種以上であることを特徴とする請求項
1に記載の頭髪用乳化化粧料に関する。請求項4に係る
発明は、ポリオキシエチレンミツロウの配合量が0.1
〜10.0重量%であることを特徴とする請求項1乃至
3のいすれかに記載の頭髪用乳化化粧料に関する。請求
項5に係る発明は、非イオン界面活性剤の配合量が0.
1〜20.0重量%であることを特徴とする請求項1乃
至4のいずれかに記載の頭髪用乳化化粧料に関する。That is, the invention according to claim 1 relates to an emulsified cosmetic for hair, characterized by containing polyoxyethylene beeswax and a nonionic surfactant. The invention according to claim 2 is characterized in that the nonionic surfactant is at least one selected from a polyoxyethylene addition surfactant, a sugar fatty acid ester, a propylene glycol fatty acid ester, and a glycerin fatty acid ester. The emulsified cosmetic for hair according to claim 1, wherein The invention according to claim 3, wherein the nonionic surfactant is polyoxyethylene hydrogenated castor oil, glycerin monostearate, sorbitan monostearate,
The emulsified cosmetic for hair according to claim 1, wherein the cosmetic is at least one selected from polyoxyethylene sorbitan monostearate. The invention according to claim 4 is that the compounding amount of the polyoxyethylene beeswax is 0.1%.
The emulsified cosmetic for hair according to any one of claims 1 to 3, characterized in that the amount is from 1 to 10.0% by weight. In the invention according to claim 5, the compounding amount of the nonionic surfactant is 0.1.
The emulsified cosmetic for hair according to any one of claims 1 to 4, wherein the content is 1 to 20.0% by weight.
【0006】[0006]
【発明の実施の形態】本発明に係る頭髪用乳化化粧料
は、ポリオキシエチレンミツロウと非イオン界面活性剤
からなる。以下、本発明に係る頭髪用乳化化粧料につい
て詳述する。本発明に係る頭髪用乳化化粧料の第一の必
須成分は、ポリオキシエチレンミツロウである。ポリオ
キシエチレンミツロウは、ミツロウの遊離の脂肪酸及び
水酸基に酸化エチレンを付加重合したものであり、付加
モル数としては、2〜40が好ましく、6〜20とする
ことがより好ましく、8が特に好ましい。DESCRIPTION OF THE PREFERRED EMBODIMENTS The emulsified cosmetic for hair according to the present invention comprises polyoxyethylene beeswax and a nonionic surfactant. Hereinafter, the emulsified cosmetic for hair according to the present invention will be described in detail. The first essential component of the emulsified cosmetic for hair according to the present invention is polyoxyethylene beeswax. Polyoxyethylene beeswax is obtained by addition polymerization of ethylene oxide to free fatty acids and hydroxyl groups of beeswax, and the number of moles added is preferably 2 to 40, more preferably 6 to 20, and particularly preferably 8 .
【0007】ポリオキシエチレンミツロウの配合量は特
に限定されないが、0.1〜10.0重量%とすること
が好ましく、2.0〜8.0重量%とすることがより好
ましい。これは、0.1重量%未満の場合、頭髪を整髪
してヘアスタイルを長時間保持することができず、また
10.0重量%を超えて配合したとしても、それ以上の
効果が望めないばかりか、べたつき感や油っぽい不自然
な光沢を与えるために、いずれの場合も好ましくないか
らである。The amount of the polyoxyethylene beeswax is not particularly limited, but is preferably 0.1 to 10.0% by weight, more preferably 2.0 to 8.0% by weight. If the amount is less than 0.1% by weight, the hair cannot be maintained for a long time by styling the hair, and even if the amount exceeds 10.0% by weight, no further effect can be expected. In addition, in any case, it is not preferable in order to give a sticky feeling or an unnatural luster like oil.
【0008】尚、市販のポリオキシエチレンミツロウと
しては、商品名リソレックスBW400(高級アルコー
ル工業社製)、商品名ESTOL EO4BW 375
2(Unichema社製)等を例示することができ
る。[0008] Commercially available polyoxyethylene beeswax is commercially available as Lisorex BW400 (trade name, manufactured by Higher Alcohol Industry Co., Ltd.) and trade name ESTOL EO4BW 375.
2 (manufactured by Unichema) and the like.
【0009】本発明に係る頭髪用乳化化粧料の第二の必
須成分は非イオン界面活性剤である。本発明において用
いられる非イオン界面活性剤は、化粧品原料として通常
用いられるものであれば特に限定はされず、グリセリ
ン、プロピレングリコール、ソルビトール、ショ糖等の
多価アルコールと脂肪酸のエステルとして、脂肪酸モノ
グリセリド、プロピレングリコール脂肪酸エステル、ソ
ルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ポリ
グリセリン脂肪酸エステル等を例示することができる。
また、高級アルコールや脂肪酸などの活性水素を有する
物質の酸化エチレン縮合物、即ち、ポリオキシエチレン
型界面活性剤として、ポリオキシエチレンアルキルエー
テル、ポリエチレングリコール脂肪酸エステル、ソルビ
タン脂肪酸エステルの酸化エチレン縮合物などを例示す
ることができる。The second essential component of the emulsified cosmetic for hair according to the present invention is a nonionic surfactant. The non-ionic surfactant used in the present invention is not particularly limited as long as it is usually used as a cosmetic raw material. Fatty acid monoglyceride is used as an ester of a polyhydric alcohol such as glycerin, propylene glycol, sorbitol, and sucrose with a fatty acid. , Propylene glycol fatty acid esters, sorbitan fatty acid esters, sucrose fatty acid esters, polyglycerin fatty acid esters, and the like.
In addition, ethylene oxide condensates of substances having active hydrogen such as higher alcohols and fatty acids, that is, polyoxyethylene-type surfactants such as polyoxyethylene alkyl ethers, polyethylene glycol fatty acid esters, and ethylene oxide condensates of sorbitan fatty acid esters Can be exemplified.
【0010】具体的には、脂肪酸モノグリセリドとし
て、モノステアリン酸グリセリン、モノオレイン酸グリ
セリン、モノラウリン酸グリセリン、モノミリスチン酸
グリセリン、モノパルミチン酸グリセリン、モノリノー
ル酸グリセリン等を例示することができる。プロピレン
グリコール脂肪酸エステルとして、モノステアリン酸プ
ロピレングリコール、モノラウリン酸プロピレングリコ
ール、モノオレイン酸プロピレングリコール等を例示す
ることができる。ソルビタン脂肪酸エステルとして、ト
リオレイン酸ソルビタン、モノオレイン酸ソルビタン、
モノステアリン酸ソルビタン、モノパルミチン酸ソルビ
タン、モノラウリン酸ソルビタン等を例示することがで
きる。ポリオキシエチレンアルキルエーテルとして、ポ
リオキシエチレンオクチルフェニルエーテル、ポリオキ
シエチレンオレイルエーテル、ポリオキシエチレンセチ
ルエーテル、ポリオキシエチレンラウリルエーテル、ポ
リオキシエチレンステアリルエーテル等を例示すること
ができる。ポリエチレングリコール脂肪酸エステルとし
て、モノオレイン酸ポリエチレングリコール、モノステ
アリン酸ポリエチレングリコール、モノラウリン酸ポリ
エチレングリコール等を例示することができる。ソルビ
タン脂肪酸エステルの酸化エチレン縮合物として、モノ
オレイン酸ポリオキシエチレンソルビタン、モノステア
リン酸ポリオキシエチレンソルビタン、モノラウリン酸
ポリオキシエチレンソルビタン、トリオレイン酸ポリオ
キシエチレンソルビタン等を例示することができる。こ
の他、ポリオキシエチレン硬化ヒマシ油、ポリオキシエ
チレンヒマシ油、ポリオキシエチレンラノリン、テトラ
オレイン酸ポリオキシエチレンソルビット、モノラノリ
ン酸ポリオキシエチレンソルビット等を例示することが
できる。Specifically, examples of the fatty acid monoglyceride include glyceryl monostearate, glyceryl monooleate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monolinoleate and the like. Examples of the propylene glycol fatty acid ester include propylene glycol monostearate, propylene glycol monolaurate, and propylene glycol monooleate. As sorbitan fatty acid esters, sorbitan trioleate, sorbitan monooleate,
Examples thereof include sorbitan monostearate, sorbitan monopalmitate, and sorbitan monolaurate. Examples of the polyoxyethylene alkyl ether include polyoxyethylene octyl phenyl ether, polyoxyethylene oleyl ether, polyoxyethylene cetyl ether, polyoxyethylene lauryl ether, and polyoxyethylene stearyl ether. Examples of the polyethylene glycol fatty acid ester include polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol monolaurate, and the like. Examples of the ethylene oxide condensate of the sorbitan fatty acid ester include polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monolaurate, and polyoxyethylene sorbitan trioleate. Other examples include polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene lanolin, polyoxyethylene sorbite tetraoleate, and polyoxyethylene sorbite monolanophosphate.
【0011】本発明に係る頭髪用乳化化粧料は、上記し
たような非イオン界面活性剤の一種又は二種以上を用い
るとよい。特に本発明においては、ポリオキシエチレン
硬化ヒマシ油、モノスレアリン酸グリセリン、モノステ
アリン酸ソルビタン、モノステアリン酸ポリオキシエチ
レンソルビタン等の非イオン界面活性剤を用いることが
好ましい。The emulsified cosmetic for hair according to the present invention may use one or more of the above-mentioned nonionic surfactants. Particularly, in the present invention, it is preferable to use a nonionic surfactant such as polyoxyethylene hydrogenated castor oil, glyceryl monostearate, sorbitan monostearate, and polyoxyethylene sorbitan monostearate.
【0012】非イオン界面活性剤の配合量は特に限定さ
れないが、0.1〜20.0重量%とすることが好まし
く、0.3〜15.0重量%とすることがより好まし
い。これは、0.1重量%未満の配合量では、良好なエ
マルジョンを形成することができず、また20.0重量
%を超えて配合したとしても、それ以上の効果は望めな
いばかりか、べたつき感を与えるために、いずれの場合
も好ましくないからである。The amount of the nonionic surfactant is not particularly limited, but is preferably 0.1 to 20.0% by weight, more preferably 0.3 to 15.0% by weight. This is because, if the amount is less than 0.1% by weight, a good emulsion cannot be formed. Even if the amount exceeds 20.0% by weight, no further effect can be expected, and the stickiness is not improved. This is because in any case, it is not preferable to give a feeling.
【0013】また、本発明に係る頭髪用乳化化粧料に用
いられる油性成分としては、油脂、炭化水素類、ロウ
類、高級脂肪酸、高級アルコール、ステロール、高級脂
肪酸エステル等を例示することができる。具体的には、
油脂として、アボガド油、オリーブ油、カカオ脂、椿
油、ヒマシ油、ヤシ油、モクロウ、或いは、硬化ヒマシ
油、硬化ヤシ油、硬化カカオ油等の硬化油等を例示する
ことができる。炭化水素類としては、流動パラフィン、
ワセリン、パラフィン、セレシン、マイクロクリスタリ
ンワックス、スクワラン等を、ロウ類としては、カルナ
ウバロウ、キャンデリラロウ、ホホバ油、モンタンロ
ウ、ミツロウ、ラノリン、鯨ロウ等を例示することがで
きる。高級脂肪酸としては、ラウリン酸、ミリスチン
酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘニ
ン酸、ウンデシレン酸、オキシステアリン酸、リノール
酸、ラノリン脂肪酸、或いはイソパルミチン酸やイソス
テアリン酸等の合成脂肪酸等を例示することができる。
高級アルコールとしては、ラウリルアルコール、セチル
アルコール、セトステアリルアルコール、ステアリルア
ルコール、オレイルアルコール、ベヘニルアルコール、
ラノリンアルコール、水素添加ラノリンアルコール、ヘ
キシルデカノール、オクチルドデカノール等を、ステロ
ールとしては、コレステロール、ジヒドロコレステロー
ル、フィトステロール等を例示することができる。高級
脂肪酸エステルとしては、リノール酸エチル、ミリスチ
ン酸イソプロピル、ラノリン酸イソプロピル、ラノリン
酸ヘキシル、ミリスチン酸ミリスチル、ミリスチン酸セ
チル、オレイン酸デシル、パルミチン酸セチル、トリミ
リスチン酸グリセリン、ジオレイン酸プロピレングリコ
ール、トリイソステアリン酸グリセリン、トリイソオク
タン酸グリセリン、乳酸セチル、乳酸ミリスチル、ステ
アリン酸コレステリル等を例示することができる。Examples of the oily component used in the emulsified cosmetic for hair according to the present invention include oils and fats, hydrocarbons, waxes, higher fatty acids, higher alcohols, sterols, higher fatty acid esters and the like. In particular,
Examples of fats and oils include avocado oil, olive oil, cocoa butter, camellia oil, castor oil, coconut oil, mokuro, and hardened oils such as hardened castor oil, hardened coconut oil, hardened cocoa oil, and the like. As hydrocarbons, liquid paraffin,
Vaseline, paraffin, ceresin, microcrystalline wax, squalane, and the like, and examples of the waxes include carnauba wax, candelilla wax, jojoba oil, montan wax, beeswax, lanolin, and whale wax. Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, undecylenic acid, oxystearic acid, linoleic acid, lanolin fatty acid, and synthetic fatty acids such as isopalmitic acid and isostearic acid. can do.
As higher alcohols, lauryl alcohol, cetyl alcohol, cetostearyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol,
Lanolin alcohol, hydrogenated lanolin alcohol, hexyldecanol, octyldodecanol and the like, and sterols include cholesterol, dihydrocholesterol, phytosterol and the like. Examples of higher fatty acid esters include ethyl linoleate, isopropyl myristate, isopropyl lanolinate, hexyl lanolinate, myristyl myristate, cetyl myristate, decyl oleate, cetyl palmitate, glyceryl trimyristate, propylene glycol dioleate, and triisostearin. Examples include glycerin acid, glycerin triisooctanoate, cetyl lactate, myristyl lactate, cholesteryl stearate, and the like.
【0014】特に、本発明に係る頭髪用乳化化粧料にお
いては、油性成分として、流動パラフィン、パラフィン
ワックス、セチルアルコール、ベヘニルアルコール等を
用いることが好ましい。In particular, in the emulsified cosmetic for hair according to the present invention, it is preferable to use liquid paraffin, paraffin wax, cetyl alcohol, behenyl alcohol or the like as the oily component.
【0015】本発明に係る頭髪用乳化化粧料において、
上記したような油性成分を配合する場合、その配合量は
特に限定されないが、1.0〜50.0重量%とするこ
とが好ましく、3.0〜40.0重量%とすることがよ
り好ましい。これは、1.0重量%未満の配合では、配
合による効果が得られず、また、50.0重量%を超え
て配合したとしても、それ以上の効果が望めないばかり
か、頭髪に対してべたつき感や不自然な光沢を与えるた
めに、いずれの場合も好ましくないからである。[0015] In the emulsified cosmetic for hair according to the present invention,
When blending the above-mentioned oily component, the blending amount is not particularly limited, but is preferably 1.0 to 50.0% by weight, more preferably 3.0 to 40.0% by weight. . This is because if the composition is less than 1.0% by weight, the effect of the composition cannot be obtained, and even if the composition is more than 50.0% by weight, no more effect can be expected, and also the hair This is because in any case, it is not preferable in order to give a sticky feeling or an unnatural luster.
【0016】尚、本発明に係る頭髪用乳化化粧料には所
望により、風合いを向上させる目的のために多価アルコ
ールを更に配合することができる。多価アルコールとし
ては、例えば、ポリエチレングリコール、エチレングリ
コール、プロピレングリコール、1,3−ブチレングリ
コール、グリセリン、ジグリセリン、トリグリセリン、
グルコース、マルトース、マルチトール、スクロース、
マンニトール、ソルビトール及びこれらの誘導体などが
例示でき、ポリオキシエチレンメチルグルコシドやグリ
セリンを用いることが好ましい。また、これらは一種又
は二種以上を組み合わせて用いることもできる。多価ア
ルコールの配合量は、毛髪用化粧料中0.01〜10.
0重量%とするのが好ましい。これは、0.01重量%
未満の配合では添加による効果が得られず、また、1
0.0重量%より多く配合すると、べたつきなどにより
風合いが悪くなり、いずれの場合も好ましくないからで
ある。The emulsified cosmetic for hair according to the present invention may further contain, if desired, a polyhydric alcohol for the purpose of improving the texture. Examples of the polyhydric alcohol include polyethylene glycol, ethylene glycol, propylene glycol, 1,3-butylene glycol, glycerin, diglycerin, triglycerin,
Glucose, maltose, maltitol, sucrose,
Examples thereof include mannitol, sorbitol, and derivatives thereof, and it is preferable to use polyoxyethylene methyl glucoside or glycerin. These can be used alone or in combination of two or more. The compounding amount of the polyhydric alcohol is from 0.01 to 10 in the cosmetic for hair.
It is preferably 0% by weight. This is 0.01% by weight
If the content is less than 1%, the effect of the addition cannot be obtained.
If the content is more than 0.0% by weight, the texture becomes poor due to stickiness and the like, and in any case, it is not preferable.
【0017】更に、本発明に係る頭髪用乳化化粧料は、
その安定性が損なわれない範囲であれば上記に記した成
分の他、水溶性高分子、アルコール類、紫外線防止剤、
香料、防腐剤、キレート剤、抗菌剤、保湿剤、清涼剤、
ビタミン類、植物抽出液、噴射剤などを目的に応じて配
合してもよい。Further, the emulsified cosmetic for hair according to the present invention comprises:
In addition to the components described above as long as the stability is not impaired, a water-soluble polymer, alcohols, an ultraviolet inhibitor,
Fragrances, preservatives, chelating agents, antibacterial agents, humectants, cooling agents,
Vitamins, plant extracts, propellants and the like may be added according to the purpose.
【0018】以上説明したような成分により本発明に係
る頭髪用乳化化粧料を調製するには、必要な配合成分と
水とから常法に従って水中油型のエマルジョンとすれば
よい。配合される水は一般には精製水であり、その配合
量は各化粧品原料の配合量に合わせて適量を配合すれば
よい。In order to prepare the emulsified cosmetic for hair according to the present invention from the components described above, an oil-in-water emulsion may be prepared from the necessary components and water according to a conventional method. The water to be blended is generally purified water, and the blending amount may be an appropriate amount according to the blending amount of each cosmetic raw material.
【0019】尚、本発明に係る頭髪用乳化化粧料は、種
々の剤型に適用することができるが、ヘアクリーム、ヘ
アワックス、ヘアミルク、ジェル等の剤型に好ましく用
いることができる。The emulsified cosmetic for hair according to the present invention can be applied to various dosage forms, but can be preferably used for dosage forms such as hair cream, hair wax, hair milk and gel.
【0020】[0020]
【実施例】以下、本発明を実施例に基づき詳細に説明す
るが、本発明はこれらの実施例により何ら限定されるも
のではない。尚、配合量は重量%である。 (試料の調製)後記表1及び表2に記した組成に従い、
実施例1〜9び比較例1〜5の各試料を常法に従い調製
した。尚、表1中のポリオキシエチレンミツロウとして
は、商品名リソレックスBW400(高級アルコール工
業社製)を用い、ポリオキシエチレン硬化ヒマシ油とし
ては、商品名EMALEX HC−20及び商品名EM
ALEX HC−50(日本サーファクタント社製)
を、モノステアリン酸グリセリンとしては、商品名エキ
セル84(花王社製)を用いた。EXAMPLES Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited to these examples. In addition, the compounding amount is weight%. (Preparation of sample) According to the composition described in Tables 1 and 2 below,
Each sample of Examples 1 to 9 and Comparative Examples 1 to 5 was prepared according to a conventional method. The polyoxyethylene beeswax in Table 1 was Lisolex BW400 (trade name, manufactured by Higher Alcohol Industry Co., Ltd.), and the polyoxyethylene hydrogenated castor oil was EMALEX HC-20 and EM.
ALEX HC-50 (manufactured by Nippon Surfactant)
As the glycerin monostearate, Exel 84 (trade name, manufactured by Kao Corporation) was used.
【0021】(試験例1;セット力の評価)実施例1〜
9及び比較例1〜5で得た各試料を、25℃の条件下
で、10cm、1gの毛束に各々0.1gづつ塗布し、
毛束の毛先を根元方向に曲げた状態で20秒間保持し
た。次に、毛束を吊るした状態の毛先の形状を以下の評
価基準に従い評価した。結果を後記表1及び表2に示
す。 ○:毛先がカールした形状となる。 △:毛先がややカールした形状となる。 ×:毛先が元に戻り、カールした形状を残さない。(Test Example 1; Evaluation of Set Force)
9 and each of the samples obtained in Comparative Examples 1 to 5 were each applied to a hair bundle of 10 cm and 1 g in an amount of 0.1 g at 25 ° C.,
The hair bundle was held for 20 seconds with the tip of the hair bundle bent in the root direction. Next, the shape of the hair tips in the state where the hair bundle was suspended was evaluated according to the following evaluation criteria. The results are shown in Tables 1 and 2 below. :: The tip of the hair is curled. Δ: The hair tip has a slightly curled shape. ×: The tip of the hair returns to its original shape and does not leave a curled shape.
【0022】(試験例2;ヘアスタイルの保持性の評
価)上記試験例1で評価した毛束を、その状態で10分
間放置した後に、毛先の形状を以下の評価基準に従い評
価した。結果を後記表1及び表2に示す。 ○;毛先が当初の形状を保持している。 △;毛先が当初より下降するが、カールした形状を保持
している。 ×;毛先が元に戻り、カールした形状を保持していな
い。Test Example 2 Evaluation of Hairstyle Retention After the hair bundle evaluated in Test Example 1 was left in that state for 10 minutes, the shape of the hair tips was evaluated according to the following evaluation criteria. The results are shown in Tables 1 and 2 below. ;: The hair tips retain the original shape. Δ: The tip of the hair is lowered from the beginning, but retains a curled shape. ×: Hair tips returned to their original shape and did not retain their curled shape.
【0023】(試験例3;柔軟性の評価)上記試験例1
で評価した毛束の柔軟性を、以下の評価基準に従って、
専門パネラー7名により官能評価し、最も多い評価を採
用した。結果を後記表1及び表2に示す。 ○:やわらかい ×:かたいTest Example 3 Evaluation of Flexibility Test Example 1 above
The flexibility of the hair bundle evaluated in the following evaluation criteria,
Sensory evaluation was carried out by seven specialized panelists, and the highest evaluation was adopted. The results are shown in Tables 1 and 2 below. ○: Soft ×: Hard
【0024】[0024]
【表1】 [Table 1]
【0025】[0025]
【表2】 [Table 2]
【0026】表1及び表2の結果から、本発明に係る頭
髪用乳化化粧料は、短時間でヘアスタイルを整えて整髪
することができ、整えた頭髪は十分な柔軟性を有してい
る。さらに、一旦整えたヘアスタイルを長時間略同じ形
状のまま維持できることが分かる。From the results shown in Tables 1 and 2, the emulsified cosmetic for hair according to the present invention can form and style hair in a short time, and the prepared hair has sufficient flexibility. . Further, it can be seen that the hairstyle once prepared can be maintained in substantially the same shape for a long time.
【0027】以下、本発明に係る頭髪用乳化化粧料の処
方例を示す。尚、配合量は重量%である。 (処方例1;スタイリングクリーム)Hereinafter, examples of the formulation of the emulsified cosmetic for hair according to the present invention will be described. In addition, the compounding amount is weight%. (Prescription example 1; styling cream)
【表3】 [Table 3]
【0028】(処方例2;ヘアワックス)(Formulation Example 2; Hair Wax)
【表4】 [Table 4]
【0029】(処方例3;ヘアミルク)(Formulation Example 3; Hair Milk)
【表5】 [Table 5]
【0030】(処方例4;ヘアジェル)(Formulation Example 4; Hair Gel)
【表6】 [Table 6]
【0031】[0031]
【発明の効果】以上詳述した如く、本発明に係る頭髪用
乳化化粧料は、ポリオキシエチレンミツロウと非イオン
界面活性剤からなるものであるから、整髪力に優れるた
めに、短時間で簡単にヘアスタイルを整えることができ
る。さらに、一旦整えたヘアスタイルを略同じ形状のま
ま長時間保持でき、しかも、ごわつき感やべたつき感な
どの手触りの悪さを与えずに艶と弾力を付与することが
できる。As described in detail above, the emulsified cosmetic for hair according to the present invention is composed of polyoxyethylene beeswax and a nonionic surfactant. You can prepare your hairstyle. Furthermore, the hairstyle that has been prepared can be held for a long time while maintaining the same shape, and gloss and elasticity can be imparted without giving a bad touch such as a stiffness or a sticky feeling.
フロントページの続き (72)発明者 椿原 操 大阪市中央区十二軒町5番12号 株式会社 マンダム中央研究所内 Fターム(参考) 4C083 AA081 AA082 AC012 AC022 AC072 AC122 AC172 AC391 AC421 AC422 AC431 AC432 AC441 AC482 AC542 AD041 AD042 AD072 AD092 AD221 BB04 CC32 DD21 DD31 DD41Continuing on the front page (72) Inventor: Tsubakihara No. 5-12, Junkencho, Chuo-ku, Osaka-shi F-term in Mandom Central Research Laboratory Co., Ltd. (reference) 4C083 AA081 AA082 AC012 AC022 AC072 AC122 AC172 AC391 AC421 AC422 AC431 AC432 AC441 AC482 AC542 AD041 AD042 AD072 AD092 AD221 BB04 CC32 DD21 DD31 DD41
Claims (5)
界面活性剤が含有されてなることを特徴とする頭髪用乳
化化粧料。1. An emulsified cosmetic for hair comprising a polyoxyethylene beeswax and a nonionic surfactant.
エチレン付加型界面活性剤、糖脂肪酸エステル、プロピ
レングリコール脂肪酸エステル、グリセリン脂肪酸エス
テルのうちから選択された一種以上であることを特徴と
する請求項1に記載の頭髪用乳化化粧料。2. The nonionic surfactant is at least one selected from a polyoxyethylene addition surfactant, a sugar fatty acid ester, a propylene glycol fatty acid ester, and a glycerin fatty acid ester. Item 8. The emulsified cosmetic for head hair according to Item 1.
エチレン硬化ヒマシ油、モノステアリン酸グリセリン、
モノステアリン酸ソルビタン、モノステアリン酸ポリオ
キシエチレンソルビタンのうちから選択された一種以上
であることを特徴とする請求項1に記載の頭髪用乳化化
粧料。3. The method of claim 1, wherein the nonionic surfactant is polyoxyethylene hydrogenated castor oil, glyceryl monostearate,
2. The emulsified cosmetic for hair according to claim 1, wherein the cosmetic is at least one selected from sorbitan monostearate and polyoxyethylene sorbitan monostearate.
0.1〜10.0重量%であることを特徴とする請求項
1乃至3のいすれかに記載の頭髪用乳化化粧料。4. The emulsified cosmetic for head hair according to claim 1, wherein the amount of the polyoxyethylene beeswax is 0.1 to 10.0% by weight.
20.0重量%であることを特徴とする請求項1乃至4
のいずれかに記載の頭髪用乳化化粧料。5. The compounding amount of the nonionic surfactant is from 0.1 to
The amount is 20.0% by weight.
The emulsified cosmetic for hair according to any one of the above.
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JP2000193486A JP3573337B2 (en) | 2000-06-27 | 2000-06-27 | Emulsion cosmetic for hair |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005068521A1 (en) * | 2004-01-20 | 2005-07-28 | Lg Chem, Ltd. | Acrylic pressure-sensitive adhesive composition for polarizing film |
WO2009093677A1 (en) | 2008-01-25 | 2009-07-30 | Shiseido Company, Ltd. | Emulsion-type hair-dressing preparation |
US9011995B2 (en) | 2005-12-14 | 2015-04-21 | Lg Chem, Ltd. | Acrylic pressure-sensitive adhesive compositions |
JP2016216403A (en) * | 2015-05-22 | 2016-12-22 | 株式会社マンダム | Hairdressing composition |
JP2019131521A (en) * | 2018-02-01 | 2019-08-08 | 株式会社アリミノ | Hair grease |
-
2000
- 2000-06-27 JP JP2000193486A patent/JP3573337B2/en not_active Expired - Fee Related
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005068521A1 (en) * | 2004-01-20 | 2005-07-28 | Lg Chem, Ltd. | Acrylic pressure-sensitive adhesive composition for polarizing film |
US9011995B2 (en) | 2005-12-14 | 2015-04-21 | Lg Chem, Ltd. | Acrylic pressure-sensitive adhesive compositions |
WO2009093677A1 (en) | 2008-01-25 | 2009-07-30 | Shiseido Company, Ltd. | Emulsion-type hair-dressing preparation |
JP2016216403A (en) * | 2015-05-22 | 2016-12-22 | 株式会社マンダム | Hairdressing composition |
JP2019131521A (en) * | 2018-02-01 | 2019-08-08 | 株式会社アリミノ | Hair grease |
JP7220443B2 (en) | 2018-02-01 | 2023-02-10 | 株式会社アリミノ | hair grease |
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