JP2000143454A - Oily hair cosmetic - Google Patents
Oily hair cosmeticInfo
- Publication number
- JP2000143454A JP2000143454A JP10314556A JP31455698A JP2000143454A JP 2000143454 A JP2000143454 A JP 2000143454A JP 10314556 A JP10314556 A JP 10314556A JP 31455698 A JP31455698 A JP 31455698A JP 2000143454 A JP2000143454 A JP 2000143454A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- oil
- poe
- acid
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 44
- 206010039792 Seborrhoea Diseases 0.000 title claims description 31
- 210000004209 hair Anatomy 0.000 claims abstract description 86
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- 239000003921 oil Substances 0.000 claims abstract description 43
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- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 31
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- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 20
- 239000000194 fatty acid Substances 0.000 claims abstract description 20
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- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 5
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- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 1
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- 150000001298 alcohols Chemical class 0.000 description 1
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- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
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- 239000008346 aqueous phase Substances 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
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- 238000007664 blowing Methods 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
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- 239000000499 gel Substances 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 230000003648 hair appearance Effects 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、毛髪化粧料に関す
る技術分野の発明である。より具体的には、本発明は、
油性毛髪化粧料に関する発明であり、更に詳細には、使
用感が良好で、櫛通り性も良く、毛髪になめらかな感触
を付与し、かつ良好な整髪力を保持させるとともに、毛
髪に対して優れた光沢を与えることができる油性毛髪化
粧料に関する発明である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to the field of hair cosmetics. More specifically, the present invention provides:
The present invention relates to an oily hair cosmetic, and more specifically, has a good feeling in use, good combability, imparts a smooth feel to hair, and maintains good hair styling power, and is excellent in hair. The present invention relates to an oily hair cosmetic that can impart a glossy finish.
【0002】[0002]
【発明が解決しようとする課題】従来から広く使用され
ている毛髪セット剤は、被膜形成性を有する高分子化合
物を、水や低級アルコール、あるいはそれらの混合溶媒
等に溶解したものとして知られている。しかしながら、
これらの毛髪セット剤は、毛髪に塗布し、乾燥仕上げす
るまでの過程でべたつきを生じ、毛髪になめらかな感触
を与えることは困難であった。しかも、上記高分子化合
物を使用する毛髪セット剤は、毛髪表面上に被膜を形成
させて、毛髪同士を接着させることにより、はじめて整
髪性が発揮される毛髪セット剤である。そのため、一
旦、この毛髪セット剤を毛髪に塗布して乾燥させると、
櫛あるいは手櫛を通すことが困難になってしまう。そし
て、無理に櫛を通すと、上記のように整髪を目的に形成
されている、毛髪における被膜を破壊することになり、
毛髪セット剤本来の整髪性が損なわれてしまうという問
題が認められていた。A hair setting agent that has been widely used in the past is known as a solution in which a polymer compound having a film forming property is dissolved in water, a lower alcohol, or a mixed solvent thereof. I have. However,
These hair setting agents cause stickiness in the process of being applied to the hair and being dried, and it is difficult to give the hair a smooth feel. In addition, a hair setting agent using the above-mentioned polymer compound is a hair setting agent that exhibits hair styling properties only by forming a film on the hair surface and bonding the hairs together. Therefore, once this hair setting agent is applied to the hair and dried,
It becomes difficult to pass a comb or hand comb. And if you forcibly pass through the comb, it will destroy the coating on the hair that is formed for the purpose of hair styling as described above,
There has been recognized a problem that the original hair setting properties of hair setting agents are impaired.
【0003】そこで、このような欠点を解消するため、
高分子化合物に化粧品用油脂類、界面活性剤等を添加し
て、毛髪セット剤における使用感触を改善する試みがな
されてきた。しかし、充分に満足すべき、セット保持力
と使用感触を併せ有する毛髪セット剤は、未だ得られて
いない。[0003] In order to eliminate such disadvantages,
Attempts have been made to improve the feel of use in hair setting agents by adding cosmetic fats and oils, surfactants and the like to polymer compounds. However, a hair setting agent which has both satisfactory set holding power and use feeling, which is sufficiently satisfactory, has not yet been obtained.
【0004】一方、前述のようなタイプの毛髪セット剤
とは別に、毛髪化粧料において、カルナバロウ、キャン
デリラロウ等のワックス類、あるいは多価アルコール母
核にプロピレンオキサイド及び/又はエチレンオキサイ
ドが付加重合したポリエーテル化合物などが、整髪力を
付与する目的で配合されることがある。しかしながら、
このようなタイプの毛髪化粧料は、乾燥後においても
櫛、あるいは手櫛を何回でも通せるという点では優れて
いるものの、これを塗布する際の、毛髪及び手における
べたつきが著しく、また、毛髪において、ギラツキ等が
生じることがある等の問題が認められる。これらの問題
を解決するために、上記の配合成分を、各種エマルショ
ンとして用いる等の試みも、近年ではなされているが、
べたつきの解消という点については、未だ充分満足でき
る毛髪化粧料は提供されていない。On the other hand, apart from hair setting agents of the type described above, in hair cosmetics, propylene oxide and / or ethylene oxide are addition-polymerized to waxes such as carnauba wax and candelilla wax, or polyhydric alcohol nuclei. In some cases, a polyether compound or the like is blended for the purpose of imparting hair styling power. However,
Hair cosmetics of this type are excellent in that they can be passed through a comb or a hand comb any number of times even after drying, but when applied, the stickiness on hair and hands is remarkable, Problems such as glare and the like may occur in hair. In order to solve these problems, attempts have been made in recent years to use the above-mentioned components as various emulsions.
Regarding the elimination of stickiness, hair cosmetics that are sufficiently satisfactory have not yet been provided.
【0005】[0005]
【課題を解決するための手段】本発明は、前記従来技術
の課題に鑑みなされたものであり、その目的は、整髪力
に優れるだけでなく、べたついた使用感を伴わず、か
つ、毛髪になめらかさ、櫛通りの良さ、さらには、優れ
た光沢を付与することができる油性毛髪化粧料を提供す
ることにある。DISCLOSURE OF THE INVENTION The present invention has been made in view of the above-mentioned problems of the prior art, and has as its object not only excellent hair styling power but also without a sticky feeling of use, It is an object of the present invention to provide an oily hair cosmetic which can impart smoothness, good combability, and excellent gloss.
【0006】かかる実情において、本発明者は、鋭意研
究を行った結果、12−ヒドロキシステアリン酸と炭化
水素油の1種又は2種以上とシリコーン誘導体の1種又
は2種以上とを組み合わせた油性毛髪化粧料を提供する
ことにより、上記目的を達成できることを見出し、本発
明を完成した。[0006] Under such circumstances, the present inventors have conducted intensive studies and as a result, have found that oily properties of a combination of 12-hydroxystearic acid and one or more hydrocarbon oils and one or more silicone derivatives. The present inventors have found that the above object can be achieved by providing a hair cosmetic, and have completed the present invention.
【0007】すなわち、本発明者は、本願において、次
の成分(A)、(B)及び(C) (A)12−ヒドロキシステアリン酸 (B)炭化水素油の1種又は2種以上 (C)シリコーン誘導体の1種又は2種以上 を含有する油性毛髪化粧料(以下、本発明油性毛髪化粧
料という)を提供する。That is, the present inventor has determined in the present application that one or more of the following components (A), (B) and (C) (A) 12-hydroxystearic acid (B) hydrocarbon oil ) An oily hair cosmetic containing one or more silicone derivatives (hereinafter referred to as the oily hair cosmetic of the present invention).
【0008】[0008]
【発明の実施の形態】以下、本発明の実施の形態につい
て説明する。本発明油性毛髪化粧料に配合される(A)
成分の12−ヒドロキシステアリン酸は、12位の炭素
に不斉水酸基を有する飽和脂肪酸で、常温で白色の、固
くて脆いロウ状の固体である。本発明における12−ヒ
ドロキシステアリン酸は、常法に従って、ヒマシ油に8
0〜85%含まれるリシノール酸を水素添加すること等
により得ることができるが、市販品を使用することもで
きる。Embodiments of the present invention will be described below. (A) formulated in the oily hair cosmetic of the present invention
The component 12-hydroxystearic acid is a saturated fatty acid having an asymmetric hydroxyl group at the carbon at the 12-position, and is a hard, brittle, waxy solid that is white at room temperature. In the present invention, 12-hydroxystearic acid is added to castor oil according to a conventional method.
It can be obtained by hydrogenating ricinoleic acid contained at 0 to 85%, but a commercially available product can also be used.
【0009】本発明油性毛髪化粧料において、12−ヒ
ドロキシステアリン酸は、固形化剤として働き、これを
配合することによって得られるゲルは、粘着感(べたつ
き)がなく、伸展性が良好で、毛髪への付着性に優れ、
さらに、広い温度範囲にわたって硬度変化あるいは粘度
変化が少ないという利点を有する。In the oily hair cosmetic composition of the present invention, 12-hydroxystearic acid acts as a solidifying agent, and the gel obtained by blending the same has no stickiness (stickiness), good extensibility, and hair. Excellent adhesion to
Further, there is an advantage that a change in hardness or a change in viscosity is small over a wide temperature range.
【0010】本発明油性毛髪化粧料における、12−ヒ
ドロキシステアリン酸の配合量は、目的の油性毛髪化粧
料の形状、硬度、粘度などにより適宜選択されるべきも
のであるが、通常、毛髪化粧料全体に対して1.0〜7
0.0重量%が好ましく、特に同3.0〜30.0重量
%が好ましい。12−ヒドロキシステアリン酸の配合量
が、毛髪化粧料全体に対して1.0重量%未満では毛髪
化粧料の安定性に問題を生じる傾向が強くなり好ましく
なく、同70.0重量%を超えると、毛髪化粧料の硬度
が上がりすぎて毛髪に塗布しづらくなる傾向が強まり、
好ましくない。The amount of 12-hydroxystearic acid in the oily hair cosmetic composition of the present invention should be appropriately selected depending on the shape, hardness, viscosity and the like of the target oily hair cosmetic composition. 1.0-7 for the whole
It is preferably 0.0% by weight, particularly preferably 3.0 to 30.0% by weight. If the blending amount of 12-hydroxystearic acid is less than 1.0% by weight based on the total weight of the hair cosmetic composition, the stability of the hair cosmetic composition tends to cause a problem, and if it exceeds 70.0% by weight. , The tendency of the hair cosmetics to become too hard to apply to the hair,
Not preferred.
【0011】本発明油性毛髪化粧料において配合される
(B)成分の炭化水素油は、通常化粧料、皮膚外用剤等
に用いられるものであれば特に限定さるものではない。
具体例を挙げると例えば、アボガド油、ツバキ油、ター
トル油、マカデミアナッツ油、トウモロコシ油、ミンク
油、オリーブ油、ナタネ油、卵黄油、ゴマ油、パーシッ
ク油、小麦胚芽油、サザンカ油、ヒマシ油、アマニ油、
サフラワー油、綿実油、エノ油、大豆油、落花生油、茶
実油、カヤ油、コメヌカ油、シナギリ油、日本キリ油、
ホホバ油、胚芽油、トリグリセリン、トリオクタン酸グ
リセリン、トリイソパルミチン酸グリセリン等の液体油
脂;The hydrocarbon oil of the component (B) blended in the oily hair cosmetic of the present invention is not particularly limited as long as it is generally used for cosmetics, skin external preparations and the like.
Specific examples include, for example, avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern oil, castor oil, linseed oil ,
Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, teaseed oil, kaya oil, rice bran oil, sinagiri oil, Japanese kiri oil,
Liquid oils such as jojoba oil, germ oil, triglycerin, glyceryl trioctanoate, glycerin triisopalmitate;
【0012】カカオ脂、ヤシ油、馬脂、硬化ヤシ油、パ
ーム油、牛脂、羊脂、硬化牛脂、パーム核油、豚脂、牛
骨脂、モクロウ核油、硬化油、牛脚脂、モクロウ、硬化
ヒマシ油等の固形油脂類;Cocoa butter, coconut oil, horse fat, hardened coconut oil, palm oil, beef tallow, sheep butter, hardened tallow, palm kernel oil, lard, beef bone fat, mocro kernel oil, hardened oil, beef tallow, mokuro Solid oils such as hardened castor oil;
【0013】ミツロウ、キャンデリラロウ、綿ロウ、カ
ルナバロウ、ベイベリーロウ、イボタロウ、鯨ロウ、モ
ンタンロウ、ヌカロウ、ラノリン、カボックロウ、酢酸
ラノリン、液状ラノリン、サトウキビロウ、ラノリン脂
肪酸イソプロピル、ラウリン酸ヘキシル、還元ラノリ
ン、ホホバロウ、硬質ラノリン、セラックロウ、ポリオ
キシエチレン(以下、POEと略す)ラノリンアルコー
ルエーテル、POEラノリンアルコールアセテート、P
OEコレステロールエーテル、ラノリン脂肪酸ポリエチ
レングリコール、POE水素添加ラノリンアルコール等
のロウ類;ミリスチルアルコール、ステアリルアルコー
ル、セチルアルコール、オレイルアルコール、アラキル
アルコール、ベヘニルアルコール、ヘキサデシルアルコ
ール等の高級アルコール類;Beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, cabock wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax , Hard lanolin, shellac wax, polyoxyethylene (hereinafter abbreviated as POE) lanolin alcohol ether, POE lanolin alcohol acetate, P
Waxes such as OE cholesterol ether, lanolin fatty acid polyethylene glycol, and POE hydrogenated lanolin alcohol; higher alcohols such as myristyl alcohol, stearyl alcohol, cetyl alcohol, oleyl alcohol, aralkyl alcohol, behenyl alcohol, hexadecyl alcohol;
【0014】流動パラフィン、スクワラン、イソパラフ
ィン、軽質流動イソパラフィン等の液状炭化水素油;オ
ゾケライト、プリスタン、パラフィン、セレシン、ワセ
リン、マイクロクリスタリンワックス等の固形又は半固
形状炭化水素油;ミリスチン酸、パルミチン酸、ステア
リン酸、オレイン酸、イソステアリン酸等の高級脂肪酸
類;Liquid hydrocarbon oils such as liquid paraffin, squalane, isoparaffin, light liquid isoparaffin; solid or semi-solid hydrocarbon oils such as ozokerite, pristane, paraffin, ceresin, vaseline, microcrystalline wax; myristic acid, palmitic acid, Higher fatty acids such as stearic acid, oleic acid and isostearic acid;
【0015】2−エチルヘキサン酸セチル、パルミチン
酸−2−エチルヘキシル、パルミチン酸オクチル、イソ
ステアリン酸−2−ヘキシルデシル、アジピン酸イソブ
チル、ミリスチン酸−2−オクチルドデシル、オレイン
酸−2−オクチルドデシル、ミリスチン酸イソプロピル
等の脂肪酸エステル類;Cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, octyl palmitate, 2-hexyldecyl isostearate, isobutyl adipate, 2-octyldodecyl myristate, 2-octyldodecyl oleate, myristine Fatty acid esters such as isopropyl acid;
【0016】イソノナン酸イソノニル、オクタン酸イソ
セチル、イソノナン酸−2−エチルヘキシル、ジ−2−
エチルヘキサン酸ネオペンチルグリコール等のエステル
油;トリ−2−エチルヘキサン酸グリセリル、トリオク
タン酸グリセリル、トリイソステアリン酸グリセリル、
トリヤシ油脂肪酸グリセリル、ジ−パラメトキシケイ皮
酸−モノ−2−エチルヘキサン酸グリセリル、モノ綿実
油脂肪酸グリセリル、モノエルカ酸グリセリル、セスキ
オレイン酸グリセリル、モノオレイン酸グリセリル、モ
ノステアリン酸グリセリル、水素添加ロジンのグリセリ
ンエステル、ジグリセリルジイソステアレート等のグリ
セリンエステル類;ソルビタンモノオレエート、ソルビ
タンモノイソステアレート、ソルビタンモノラウレー
ト、ソルビタンモノパルミテート、ソルビタンモノステ
アレート、ソルビタンセスキオレエート、ソルビタント
リオレエート、ペンタ−2−エチルヘキシル酸ジグリセ
ロールソルビタン、テトラ−2−エチルヘキシル酸ジグ
リセロールソルビタン等のソルビタン脂肪酸エステル
類;Isononyl isononanoate, isocetyl octoate, 2-ethylhexyl isononanoate, di-2-
Ester oils such as neopentyl glycol ethylhexanoate; glyceryl tri-2-ethylhexanoate, glyceryl trioctanoate, glyceryl triisostearate;
Glyceryl tricoconut oil fatty acid, glyceryl di-paramethoxycinnamate-mono-2-ethylhexanoate, glyceryl monocottonseed oil, glyceryl monoerucate, glyceryl sesquioleate, glyceryl monooleate, glyceryl monostearate, hydrogenated rosin Glycerin esters such as glycerin ester and diglyceryl diisostearate; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, Sorbitan fatty acid esters such as diglycerol sorbitan penta-2-ethylhexylate and diglycerol sorbitan tetra-2-ethylhexylate;
【0017】α−α' −オレイン酸ピログルタミン酸グ
リセリン、モノステアリン酸グリセリンリンゴ酸等のグ
リセリン脂肪酸類;モノステアリン酸プロピレングリコ
ール等のプロピレングリコール脂肪酸エステル類;Glycerin fatty acids such as α-α′-glycol pyroglutamate oleate and glyceryl monostearate; propylene glycol fatty acid esters such as propylene glycol monostearate;
【0018】硬化ヒマシ油誘導体、グリセリンアルキル
エーテル、POEソルビタンモノオレエート、POEソ
ルビタンモノステアレート、POEソルビタンテトラオ
レエート等のPOEソルビタン脂肪酸エステル類;PO
Eソルビットモノラウレート、POEソルビットモノオ
レエート、POEソルビットペンタオレエート、POE
ソルビットモノステアレート等のPOEソルビット脂肪
酸エステル類;POEグリセリンモノステアレート、P
OEグリセリンモノイソステアレート、POEグリセリ
ントリイソステアレート等のPOEグリセリン脂肪酸エ
ステル類;POE sorbitan fatty acid esters such as hydrogenated castor oil derivative, glycerin alkyl ether, POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan tetraoleate; PO
E sorbit monolaurate, POE sorbit monooleate, POE sorbit pentaoleate, POE
POE sorbitol fatty acid esters such as sorbitol monostearate; POE glycerin monostearate, P
POE glycerin fatty acid esters such as OE glycerin monoisostearate and POE glycerin triisostearate;
【0019】POEモノオレエート、POEジステアレ
ート、POEモノジオレエート、ジステアリン酸エチレ
ングリコール等のPOE脂肪酸エステル類;POEラウ
リルエーテル、POEオレイルエーテル、POEステア
リルエーテル、POEベヘニルエーテル、POE−2−
オクチルドデシルエーテル、POEコレスタノールエー
テル等のPOEアルキルエーテル類;POE fatty acid esters such as POE monooleate, POE distearate, POE monodioleate, ethylene glycol distearate; POE lauryl ether, POE oleyl ether, POE stearyl ether, POE behenyl ether, POE-2-enyl
POE alkyl ethers such as octyldodecyl ether and POE cholestanol ether;
【0020】POEオクチルフェニルエーテル、POE
ノニルフェニルエーテル、POEジノニルフェニルエー
テル等のPOEアルキルフェニルエーテル類;プルロニ
ック等のプルロニック型類;ポリオキシエチレン・ポリ
オキシプロピレン(以下、POE・POPと略す)セチ
ルエーテル、POE・POP−2−デシルテトラデシル
エーテル、POE・POPモノブチルエーテル、POE
・POP水素添加ラノリン、POE・POPグリセリン
エーテル、POE・POPデカグリセリルエーテル等の
POE・POPアルキルエーテル類;POE octyl phenyl ether, POE
POE alkyl phenyl ethers such as nonyl phenyl ether and POE dinonyl phenyl ether; Pluronics such as Pluronic; polyoxyethylene / polyoxypropylene (hereinafter abbreviated as POE / POP) cetyl ether; POE / POP-2-decyl Tetradecyl ether, POE / POP monobutyl ether, POE
POE / POP alkyl ethers such as POP hydrogenated lanolin, POE / POP glycerin ether, POE / POP decaglyceryl ether;
【0021】テトロニック等のテトラPOE・テトラP
OPエチレンジアミン縮合物類;POEヒマシ油、PO
E硬化ヒマシ油、POE硬化ヒマシ油モノイソステアレ
ート、POE硬化ヒマシ油モノピログルタミン酸モノイ
ソステアリン酸ジエステル、POE硬化ヒマシ油マレイ
ン酸等のPOEヒマシ油硬化ヒマシ油誘導体;POEソ
ルビットミツロウ等のPOEミツロウ・ラノリン誘導
体;Tetra POE and Tetra P such as Tetronic
OP ethylenediamine condensates; POE castor oil, PO
POE castor oil-hardened castor oil derivatives such as E-hardened castor oil, POE-hardened castor oil monoisostearate, POE-hardened castor oil monopyroglutamic acid monoisostearate diester, POE-hardened castor oil-maleic acid; POE beeswax such as POE sorbitol beeswax; Lanolin derivatives;
【0022】POEプロピレングリコール脂肪酸エステ
ル、POEアルキルアミン、POE脂肪酸アミド、ショ
糖脂肪酸エステル、POEノニルフェニルホルムアルデ
ヒド縮合物;不均化ロジン及び/又は水素添加ロジンと
脂肪酸と多価アルコールとからなるエステル等などが挙
げられる。POE propylene glycol fatty acid ester, POE alkylamine, POE fatty acid amide, sucrose fatty acid ester, POE nonylphenylformaldehyde condensate; disproportionated rosin and / or hydrogenated rosin, ester composed of fatty acid and polyhydric alcohol, etc. And the like.
【0023】本発明油性毛髪化粧料においては、特に、
(B)成分である炭化水素油として、上記の液状ラノリ
ン、あるいは上記の不均化ロジン及び/又は水素添加ロ
ジンと脂肪酸と多価アルコールとからなるエステルを配
合すると、この油性毛髪化粧料の透明性を向上させるこ
とが可能であり、好ましい。In the oily hair cosmetic of the present invention,
When the above-mentioned liquid lanolin or the above-mentioned disproportionated rosin and / or hydrogenated rosin and an ester composed of a fatty acid and a polyhydric alcohol are blended as the hydrocarbon oil as the component (B), the transparency of the oily hair cosmetic is improved. It is possible to improve the property, which is preferable.
【0024】なお、本発明において不均化ロジンは、ロ
ジン中に含まれるアビエチン酸をデヒドロアビエチン酸
とジヒドロアビエチン酸とテトラヒドロアビエチン酸と
に不均化したもの、あるいは単離したものを意味する。In the present invention, the disproportionated rosin means abietic acid contained in rosin which is disproportionated into dehydroabietic acid, dihydroabietic acid and tetrahydroabietic acid, or is isolated.
【0025】本発明油性毛髪化粧料の(B)成分として
選択するのに好ましい、不均化ロジン及び/又は水素添
加ロジンと脂肪酸と多価アルコールとからなるエステル
としては、例えば、トリ(水素添加ロジン・イソステア
リン酸)グリセリル、ジ(水素添加ロジン・モノステア
リン酸)グリセリル、モノ不均化ロジンモノカプロン酸
エチレングリコール、モノ不均化ロジンモノカプリン酸
エチレングリコール、モノ水素添加ロジンモノミリスチ
ン酸エチレングリコール、モノ水素添加ロジンモノパル
ミチン酸エチレングリコール、モノ水素添加ロジンモノ
オレイン酸エチレングリコール、モノ水素添加ロジンモ
ノ−2−エチルブタン酸エチレングリコール、モノ水素
添加ロジンモノ−2−エチルヘキサン酸エチレングリコ
ール、モノ不均化ロジンモノオレイン酸トリエチレング
リコール、モノ水素添加ロジンモノ−2−エチルブタン
酸トリエチレングリコール、モノ水素添加ロジンモノエ
ルシン酸ポリエチレングリコール、Examples of the ester comprising a disproportionated rosin and / or a hydrogenated rosin, a fatty acid and a polyhydric alcohol which are preferably selected as the component (B) of the oily hair cosmetic of the present invention include tri (hydrogenated). Glyceryl rosin / isostearic acid, glyceryl di (hydrogenated rosin / monostearic acid), ethylene glycol mono-disproportionated rosin monocaproate, ethylene glycol mono-disproportionated rosin monocaprate, ethylene glycol mono-hydrogenated rosin monomyristate Mono-hydrogenated rosin ethylene glycol monopalmitate, mono-hydrogenated rosin mono-oleic acid ethylene glycol, mono-hydrogenated rosin mono-2-ethylbutanoate ethylene glycol, mono-hydrogenated rosin mono-2-ethyl hexanoate ethylene glycol, mono-disproportionation Jin monooleate triethylene glycol, mono-hydrogenated Rojinmono 2-ethylbutane acid triethylene glycol, mono hydrogenated rosin mono erucic acid polyethylene glycol,
【0026】モノ不均化ロジンモノ−2−エチルヘキサ
ン酸プロピレングリコール、モノ不均化ロジンモノオレ
イン酸グリセリル、モノ不均化ロジンモノオレイン酸モ
ノ−2−エチルヘキサン酸グリセリル、ジ水素添加ロジ
ンモノイソステアリン酸(メチル分岐)グリセリル、モ
ノテトラヒドロアビエチン酸モノイソステアリン酸モノ
−12−ヒドロキシステアリン酸グリセロール、モノデ
ヒドロアビエチン酸モノラウリン酸モノオレイン酸グリ
セリル、モノ水素添加ロジンモノエルシン酸ジグリセリ
ル、ジヒドロアビエチン酸ジリシノール酸ジグリセリ
ル、ジ不均化ロジン−モノ−ヘプチルウンデカン酸トリ
メチロールプロパン、ジ水素添加ロジンジイソステアリ
ン酸(メチル分岐)ペンタエリスリトール、ジ水素添加
ロジンジイソステアリン酸−モノ−2−デシルテトラデ
カン酸ジペンタエリスリトール、モノデヒドロアビエチ
ン酸−モノ9,10−ジヒドロキシステアリン酸ポリグ
リセリル等が挙げられる。Mono-proportionated rosin propylene glycol mono-2-ethylhexanoate, mono-proportionated rosin monoglycoleyl monooleate, glyceryl mono-proportionated rosin mono-2-ethylhexanoate, rosin monoisostearin dihydrogenated Glyceryl acid (methyl branch), monotetrahydroabietic acid monoisostearate glycerol mono-12-hydroxystearate, monodehydroabietic acid monolaurate glyceryl monooleate, monohydrogenated rosin monoerucinate diglyceryl, dihydroabietic acid diricinoleate Glyceryl, di-proportionated rosin-trimethylolpropane mono-heptylundecanoate, dihydrogenated rosin diisostearate (methyl branch) pentaerythritol, dihydrogenated rosin diisostea Phosphate - mono-2 decyltetradecanoate dipentaerythritol, mono dehydroabietic acid - mono-9,10-dihydroxy stearic acid polyglyceryl the like.
【0027】本発明油性毛髪化粧料において、(B)成
分である炭化水素油は、1種を単独で、あるいは2種以
上を組み合わせて用いることが可能であり、その配合量
は、好ましくは毛髪化粧料全体に対して1.0〜80.
0重量%、特に好ましくは同3.0〜70.0重量%で
ある。この配合量が、毛髪化粧料全体の1.0重量%未
満では、処方によってはシリコーン誘導体(後述する)
を、12−ヒドロキシステアリン酸と相溶させることが
できず好ましくなく、同80.0重量%を超えて配合し
ても、配合量に見合った感触面における効果の向上を期
待することが困難になり好ましくない。In the oily hair cosmetic composition of the present invention, the hydrocarbon oil as the component (B) can be used alone or in combination of two or more. 1.0 to 80 with respect to the whole cosmetic.
0% by weight, particularly preferably 3.0 to 70.0% by weight. If the amount is less than 1.0% by weight of the total hair cosmetic, the silicone derivative (described later) may be used depending on the formulation.
Cannot be compatible with 12-hydroxystearic acid, and it is difficult to expect an improvement in the effect on the touch surface in proportion to the blending amount even if the amount exceeds 80.0% by weight. It is not preferable.
【0028】また、本発明油性毛髪化粧料に配合される
(C)成分のシリコーン誘導体は特に限定されず、例え
ば、メチルポリシロキサン、オクタメチルトリシロキサ
ン、デカメチルテトラシロキサン、高重合メチルポリシ
ロキサン等のジメチルシリコーンオイル;オクタメチル
シクロテトラシロキサン、デカメチルシクロペンタシロ
キサン、メチルシクロポリシロキサン等の環状ジメチル
シリコーンオイル;メチルハイドロジェンポリシロキサ
ン、テトラヒドロテトラメチルシクロテトラシロキサン
等のメチルハイドロジェンシリコーンオイル;ポリオキ
シエチレン・メチルポリシロキサン共重合体、ポリ(オ
キシエチレン・オキシプロピレン)メチルポリシロキサ
ン共重合体等のポリエーテル変性シリコーンオイル;メ
チルフェニルポリシロキサン等のメチルフェニルシリコ
ーンオイル;ステアロキシメチルポリシロキサン等のス
テアロキシ変性シリコーン;シリコーン樹脂、エポキシ
変性シリコーン、フッ素変性シリコーン、アルコール変
性シリコーン、アルキル変性シリコーン、アルコキシ変
性シリコーン等が挙げられる。The silicone derivative of the component (C) blended in the oily hair cosmetic of the present invention is not particularly limited, and examples thereof include methylpolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, and highly polymerized methylpolysiloxane. Dimethyl silicone oil; cyclic dimethyl silicone oil such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and methylcyclopolysiloxane; methyl hydrogen silicone oil such as methylhydrogenpolysiloxane and tetrahydrotetramethylcyclotetrasiloxane; polyoxy Polyether-modified silicone oil such as ethylene / methyl polysiloxane copolymer and poly (oxyethylene / oxypropylene) methyl polysiloxane copolymer; methyl phenyl poly Methylphenyl silicone oil such as Rokisan; stearoxypolyethylene stearoxy-modified silicones such as methyl polysiloxane; silicone resins, epoxy-modified silicone, fluorine-modified silicones, alcohol-modified silicones, alkyl-modified silicone, and alkoxy-modified silicones.
【0029】これらのシリコーン誘導体は、常法によっ
て製造したものはもとより、市販のものを使用すること
も可能であり、例えば、メチルフェニルポリシロキサン
として「シリコーンKF56」(信越化学工業(株) 社
製)、環状シリコーン(デカメチルシクロペンタシロキ
サン)として「シリコーンKF995」(信越化学工業
(株) 社製)、さらにメチルハイドロジェンポリシロキ
サンとして「SH1107C」(東レ・ダウコーニング
(株)社製)等が例示される。As these silicone derivatives, not only those manufactured by a conventional method but also those commercially available can be used. For example, "Silicone KF56" (manufactured by Shin-Etsu Chemical Co., Ltd.) as methylphenylpolysiloxane ), "Silicone KF995" (manufactured by Shin-Etsu Chemical Co., Ltd.) as a cyclic silicone (decamethylcyclopentasiloxane), and "SH1107C" (manufactured by Dow Corning Toray) as a methylhydrogenpolysiloxane. Is exemplified.
【0030】本発明油性毛髪化粧料においては、特に、
(C)成分であるシリコーン誘導体として、上記のメチ
ルフェニルシリコーンオイルを配合すると、この油性毛
髪化粧料の透明性を向上させることが可能であり、好ま
しい。In the oily hair cosmetic of the present invention,
It is preferable to blend the methylphenyl silicone oil described above as the silicone derivative as the component (C) because the transparency of the oily hair cosmetic can be improved.
【0031】本発明油性毛髪化粧料において、(C)成
分であるシリコーン誘導体は、1種を単独で、あるいは
2種以上を組み合わせて配合することが可能であり、そ
の配合量は、好ましくは、毛髪化粧料全体に対して1.
0〜60.0重量%、特に好ましくは同3.0〜50.
0重量%である。シリコーン誘導体の配合量が、毛髪化
粧料全体に対して1.0重量%未満では、塗布時の使用
感や、あるいは毛髪のツヤといった仕上がりの面で、本
発明において期待される効果が発揮され難く好ましくな
く、同60.0重量%を超えて配合した場合、処方によ
っては、12−ヒドロキシステアリン酸あるいは炭化水
素油の層と相溶することができない場合があり、好まし
くない。In the oily hair cosmetic composition of the present invention, the silicone derivative as the component (C) may be used alone or in combination of two or more. 1. For the entire hair cosmetic composition.
0 to 60.0% by weight, particularly preferably 3.0 to 50.
0% by weight. If the amount of the silicone derivative is less than 1.0% by weight based on the total weight of the hair cosmetic, the effects expected in the present invention are less likely to be exerted in terms of the feeling during application and the finish such as gloss of hair. If it is not preferred, if it exceeds 60.0% by weight, it may not be compatible with the layer of 12-hydroxystearic acid or hydrocarbon oil depending on the formulation, which is not preferred.
【0032】このようにして、(A)成分である12−
ヒドロキシステアリン酸、(B)成分である炭化水素
油、及び(C)成分であるシリコーン誘導体を組み合わ
せて配合した、本発明油性毛髪化粧料は、使用感が良好
で、櫛通り性も良く、毛髪になめらかな感触を付与し、
かつ良好な整髪力を保持させるとともに、毛髪に対して
優れた光沢を与えることができる油性毛髪化粧料であ
る。Thus, the component (A), 12-
The oily hair cosmetic composition of the present invention, which is obtained by combining hydroxystearic acid, a hydrocarbon oil as the component (B), and a silicone derivative as the component (C), has a good feeling in use, has good combability, and has a good hair quality. Gives a smooth feel,
It is an oily hair cosmetic that can maintain good hair styling power and impart excellent gloss to hair.
【0033】本発明油性毛髪化粧料には、上記必須成分
に加えて、本発明の効果を損なわない範囲内において、
化粧料に一般に使用される色素、パール剤、香料、保湿
剤、防腐剤、酸化防止剤、紫外線吸収剤、樹脂、高分
子、界面活性剤、顔料、薬剤、アルコール、油剤、ワッ
クス、粉体、溶剤等を適宜配合することができる。The oily hair cosmetic composition of the present invention may further comprise, in addition to the above essential components, within the range not impairing the effects of the present invention.
Dyes, pearls, fragrances, humectants, preservatives, antioxidants, ultraviolet absorbers, resins, polymers, surfactants, pigments, drugs, alcohol, oils, waxes, powders commonly used in cosmetics A solvent or the like can be appropriately blended.
【0034】また、本発明油性毛髪化粧料においては、
クリーム状、エマルジョン状、ゲル状、固形状等、種々
の剤形を選択可能であり、本発明油性毛髪化粧料を、ヘ
アクリーム、ヘア乳液、ヘアジェル、ヘアワックス、ヘ
アスティク等とすることが可能である。これらのいずれ
の剤形、形態の本発明油性毛髪化粧料も、選択する剤
形、形態に応じた常法を用いることにより、所望する剤
形や形態の本発明油性毛髪化粧料を得ることができる。In the oily hair cosmetic of the present invention,
Various dosage forms such as cream, emulsion, gel, and solid can be selected, and the oily hair cosmetic composition of the present invention can be a hair cream, a hair emulsion, a hair gel, a hair wax, a hair stick, and the like. is there. Any of these dosage forms and forms of the oil-based hair cosmetic composition of the present invention can obtain a desired dosage form and form of the oil-based hair cosmetic composition of the present invention by using a conventional method according to the selected dosage form and form. it can.
【0035】[0035]
【実施例】以下、本発明を、実施例を用いて、さらに具
体的に説明するが、これらの実施例により、本発明の技
術的範囲が限定解釈されるべきものではない。なお、配
合量は、特に断わらない限り、その成分を配合する対象
全体に対する重量%で表示する。EXAMPLES Hereinafter, the present invention will be described more specifically with reference to Examples, but the technical scope of the present invention should not be limited by these Examples. Unless otherwise specified, the amount of compounding is expressed in terms of% by weight based on the entire object to which the component is compounded.
【0036】以下、本発明品の処方例(実施例1〜4)
と、比較品の処方例(比較例1〜5)を示し、これらの
処方例の油性毛髪化粧料について、本発明において発揮
されるべき効果が認められるか否かを評価した(評価方
法と評価結果については、後述する)。Hereinafter, the formulation examples of the product of the present invention (Examples 1 to 4)
And Comparative Formulation Examples (Comparative Examples 1 to 5). The oily hair cosmetics of these Formulation Examples were evaluated to determine whether the effects to be exhibited in the present invention were observed (evaluation method and evaluation). The results will be described later).
【0037】 〔実施例1〕 ヘアスティック 配合成分 配合量(重量%) (1)12−ヒドロキシステアリン酸 15.0 (2)流動パラフィン 39.599 (3)液状ラノリン 25.0 (4)メチルフェニルポリシロキサン 15.0 [商品名:シリコーンKF56,信越化学工業(株)社製] (5)イソノナン酸イソノニル 5.0 (6)香料 0.1 (7)緑色3号 0.001 (8)酸化防止剤 0.3Example 1 Hair Stick Ingredients Amount (wt%) (1) 12-hydroxystearic acid 15.0 (2) liquid paraffin 39.599 (3) liquid lanolin 25.0 (4) methylphenyl Polysiloxane 15.0 [Product name: Silicone KF56, manufactured by Shin-Etsu Chemical Co., Ltd.] (5) Isononyl isononanoate 5.0 (6) Fragrance 0.1 (7) Green No. 3 0.001 (8) Oxidation Inhibitor 0.3
【0038】<製法>(1)〜(5)を95℃で混合撹
拌し、均一になった後に、70℃まで冷却し、(6)〜
(8)を添加し、スティック用金型に充填し、冷却する
ことにより、透明性のある硬度40.0のヘアスティッ
クを得た。<Production Method> (1) to (5) were mixed and stirred at 95 ° C., and after the mixture became uniform, cooled to 70 ° C.
(8) was added, the mixture was filled in a stick mold, and cooled to obtain a transparent hair stick having a hardness of 40.0.
【0039】 〔比較例1〕 ヘアスティック(シリコーン誘導体を抜去) 配合成分 配合量(重量%) (1)12−ヒドロキシステアリン酸 15.0 (2)流動パラフィン 44.599 (3)液状ラノリン 30.0 (4)イソノナン酸イソノニル 10.0 (5)香料 0.1 (6)緑色3号 0.001 (7)酸化防止剤 0.3Comparative Example 1 Hair Stick (with Silicone Derivative Removed) Blending Component Blending Amount (% by weight) (1) 12-hydroxystearic acid 15.0 (2) Liquid paraffin 44.599 (3) Liquid lanolin 30. 0 (4) Isononyl isononanoate 10.0 (5) Fragrance 0.1 (6) Green No. 3 0.001 (7) Antioxidant 0.3
【0040】<製法>(1)〜(4)を95℃で混合撹
拌し、均一になったところで70℃まで冷却し、(5)
〜(7)を添加し、均一に混合した。次いで、この混合
物をスティック用金型に充填し、透明性のある、硬度3
5.0のヘアスティックを得た。<Production method> (1) to (4) were mixed and stirred at 95 ° C, and cooled to 70 ° C when the mixture became uniform.
To (7) were added and mixed uniformly. The mixture is then filled into a stick mold and a transparent, hardness 3
5.0 hair sticks were obtained.
【0041】 〔比較例2〕 ヘアスティック(炭化水素油を抜去) 配合成分 配合量(重量%) (1)12−ヒドロキシステアリン酸 15.0 (2)メチルフェニルシロキサン 45.0 〔商品名:シリコーンKF56,信越化学工業(株)社製〕 (3)香料 0.1 (4)緑色3号 0.001 (5)酸化防止剤 0.3[Comparative Example 2] Hair stick (remove hydrocarbon oil) compounding component compounding amount (% by weight) (1) 12-hydroxystearic acid 15.0 (2) methylphenylsiloxane 45.0 [trade name: silicone KF56, manufactured by Shin-Etsu Chemical Co., Ltd.) (3) Fragrance 0.1 (4) Green No. 3 0.001 (5) Antioxidant 0.3
【0042】<製法>(1)(2)を95℃で混合攪拌
し、均一になった後に、70℃まで冷却し、(3)〜
(5)を添加し、スティック用金型に充填し、冷却する
ことにより、透明性のある、硬度45.0のヘアスティ
ックを得た。<Production Method> (1) and (2) were mixed and stirred at 95 ° C., and after they became uniform, cooled to 70 ° C.
(5) was added, the mixture was filled in a stick mold, and cooled to obtain a transparent hair stick having a hardness of 45.0.
【0043】 〔実施例2〕 ヘアワックス 配合成分 配合量(重量%) (1)12−ヒドロキシステアリン酸 8.0 (2)軽質流動イソパラフィン 20.0 (3)カルナバロウ 3.0 (4)キャンデリラロウ 3.0 (5)ジメチルポリシロキサン(6mPa・s) 13.0 (6)ジメチルポリシロキサン(100mPa・s) 5.0 (7)パルミチン酸オクチル 11.0 (8)オクチルメトキシシンナメート 5.0 (9)イソステアリン酸−2−ヘキシルデシル 5.0 (10)流動パラフィン 24.5 (11)香料 0.5 (12)1,3−ブチレングリコール 2.0[Example 2] Hair wax compounding component compounding amount (% by weight) (1) 12-hydroxystearic acid 8.0 (2) light liquid isoparaffin 20.0 (3) carnauba wax 3.0 (4) candelilla Wax 3.0 (5) Dimethyl polysiloxane (6 mPa · s) 13.0 (6) Dimethyl polysiloxane (100 mPa · s) 5.0 (7) Octyl palmitate 11.0 (8) Octyl methoxycinnamate 0 (9) 2-hexyldecyl isostearate 5.0 (10) Liquid paraffin 24.5 (11) Fragrance 0.5 (12) 1,3-butylene glycol 2.0
【0044】<製法>(1)〜(12)を95℃で混合
撹拌し、オンレーターで冷却し、容器に充填することに
より、硬度15のヘアワックスを得た。<Production Method> (1) to (12) were mixed and stirred at 95 ° C., cooled with an onlator, and filled in a container to obtain a hair wax having a hardness of 15.
【0045】 〔比較例3〕 ヘアワックス(12−ヒドロキシステアリン酸を抜去) 配合成分 配合量(重量%) (1)軽質流動イソパラフィン 20.0 (2)カルナバロウ 7.0 (3)キャンデリラロウ 7.0 (4)ジメチルポリシロキサン(6mPa・s) 13.0 (5)ジメチルポリシロキサン(100mPa・s) 5.0 (6)パルミチン酸オクチル 11.0 (7)オクチルメトキシシンナメート 5.0 (8)イソステアリン酸−2−ヘキシルデシル 5.0 (9)流動パラフィン 24.5 (10)香料 0.5 (11)1,3−ブチレングリコール 2.0[Comparative Example 3] Hair wax (12-hydroxystearic acid was removed) Compounding ingredients (% by weight) (1) Light liquid isoparaffin 20.0 (2) Carnauba wax 7.0 (3) Candelilla wax 7 0.0 (4) Dimethyl polysiloxane (6 mPa · s) 13.0 (5) Dimethyl polysiloxane (100 mPa · s) 5.0 (6) Octyl palmitate 11.0 (7) Octyl methoxycinnamate 5.0 ( 8) 2-hexyldecyl isostearate 5.0 (9) Liquid paraffin 24.5 (10) Fragrance 0.5 (11) 1,3-butylene glycol 2.0
【0046】<製法>(1)〜(11)を95℃で混合
撹拌し、オンレーターで冷却し、容器に充填することに
より、硬度10のヘアワックスを得た。<Production Method> (1) to (11) were mixed and stirred at 95 ° C., cooled with an onlator, and filled in a container to obtain a hair wax having a hardness of 10.
【0047】 〔実施例3〕 ヘアクリーム 配合成分 配合量(重量%) (1)12−ヒドロキシステアリン酸 3.0 (2)ポリオキシエチレングリセリルトリステアレート 3.0 [ 商品名:エマレックスGWS−310,日本エマルジョン(株)社製] (3)デカメチルシクロペンタシロキサン 30.0 [ 商品名:シリコーンKF995,信越化学(株)社製] (4)イオン交換水 10.0 (5)ホホバ油 10.0 (6)アジピン酸ジイソブチル 10.0 (7)スクワラン 20.0 (8)液状ラノリン 9.8 (9)2−ヒドロキシ−メトキシベンゾフェノン 4.0 (10)香料 0.2Example 3 Hair Cream Ingredients Amount (Weight%) (1) 12-hydroxystearic acid 3.0 (2) Polyoxyethylene glyceryl tristearate 3.0 [Product name: Emarex GWS- 310, manufactured by Nippon Emulsion Co., Ltd.] (3) Decamethylcyclopentasiloxane 30.0 [Product name: Silicone KF995, manufactured by Shin-Etsu Chemical Co., Ltd.] (4) Deionized water 10.0 (5) Jojoba oil 10.0 (6) diisobutyl adipate 10.0 (7) squalane 20.0 (8) liquid lanolin 9.8 (9) 2-hydroxy-methoxybenzophenone 4.0 (10) perfume 0.2
【0048】<製法>(2)、(3)を70℃で混合撹
拌し、次いで、(4)を添加し、ホモミキサーで乳化
し、乳化組成物を得る。(1)、(5)〜(10)を9
5℃で混合撹拌し、均一になったところで、70℃まで
冷却する。次いで、この混合物に先の乳化組成物を添加
し、混合撹拌しながら、常温まで冷却し、粘度3500
0mPa・sのヘアクリームを得た。<Production Method> (2) and (3) are mixed and stirred at 70 ° C., and then (4) is added and emulsified with a homomixer to obtain an emulsified composition. (1), (5) to (10) are 9
Mix and stir at 5 ° C, and when uniform, cool to 70 ° C. Next, the above emulsified composition was added to this mixture, and the mixture was cooled to room temperature while mixing and stirring to obtain a mixture having a viscosity of 3500.
A hair cream of 0 mPa · s was obtained.
【0049】 〔実施例4〕 透明ヘアスティック 配合成分 配合量(重量%) (1)12−ヒドロキシステアリン酸 10.0 (2)トリ(水素添加ロジン・イソステアリン酸)グリセリル 39.99 (3)液状ラノリン 20.0 (4)メチルフェニルポリシロキサン 30.0 〔シリコーンKF56,信越化学工業(株)社製] (5)香料 0.01Example 4 Transparent Hair Stick Ingredients Ingredients (% by weight) (1) 12-hydroxystearic acid 10.0 (2) tri (hydrogenated rosin / isostearic acid) glyceryl 39.99 (3) liquid Lanolin 20.0 (4) Methylphenyl polysiloxane 30.0 [Silicone KF56, manufactured by Shin-Etsu Chemical Co., Ltd.] (5) Fragrance 0.01
【0050】<製法>(1)〜(4)を95℃で混合撹
拌し、均一になった後に、70℃まで冷却し、(5)を
添加し、スティック用金型に充填し、冷却して、透明性
のある硬度45.0のヘアスティックを得た。<Production Method> (1) to (4) were mixed and stirred at 95 ° C., and after they became uniform, cooled to 70 ° C., (5) was added, and the mixture was filled in a stick mold and cooled. Thus, a transparent hair stick having a hardness of 45.0 was obtained.
【0051】 〔比較例4〕 ヘアスティック(シリコーン誘導体非配合) 配合成分 配合量(重量%) (1)12−ヒドロキシステアリン酸 10.0 (2)水素添加ロジンのグリセリンエステル 43.7 (3)モノオレイン酸グリセリル 40.0 (4)1,3−ブチレングリコール 2.0 (5)緑色3号 0.1 (6)香料 0.1 (7)酸化防止剤 0.1 (8)ジグリセリルジイソステアレート 4.0[0051] Comparative Example 4 Hair Stick (silicone derivative nonformulated) Ingredients Amount (wt%) (1) 12-hydroxystearic acid 10.0 (2) glycerol esters of hydrogenated rosin 43.7 (3) Glyceryl monooleate 40.0 (4) 1,3-butylene glycol 2.0 (5) Green No. 3 0.1 (6) Fragrance 0.1 (7) Antioxidant 0.1 (8) Diglyceryl di Isostearate 4.0
【0052】<製法>(1)〜(4)、(8)を95℃
で混合撹拌し、均一になったところで70℃まで冷却
し、(5)〜(7)を添加し、均一に混合した。次い
で、この混合物をスティック用金型に充填し、硬度40
のヘアスティックを得た。<Production method> (1) to (4), (8) at 95 ° C.
When the mixture became uniform, the mixture was cooled to 70 ° C., and (5) to (7) were added and mixed uniformly. Next, this mixture was filled into a stick mold, and the hardness was set to 40.
Got a hair stick.
【0053】 〔比較例5〕 ヘアワックス(12−ヒドロキシステアリン酸非配合) 配合成分 配合量(重量%) (1)キャンデリラロウ 5.0 (2)パラフィンワックス 15.0 (3)ステアリン酸 2.0 (4)ポリオキシエチレン(10モル)オレイルエーテル 3.0 (5)ステアリルアルコール 0.1 (6)流動パラフィン 7.0 (7)スクワラン 8.0 (8)メチルポリシロキサン 5.0 〔シリコーンKF96A−6 信越化学工業(株)社製〕 (9)ポリビニルアルコール 0.2 (10)1,3−ブチレングリコール 5.0 (11)水酸化ナトリウム 0.2 (12)メチルパラベン 0.1 (13)イオン交換水 49.5 (14)香料 0.1[Comparative Example 5] Hair wax (12-hydroxystearic acid non-blended) blended component blended amount (% by weight) (1) Candelilla wax 5.0 (2) Paraffin wax 15.0 (3) Stearic acid 2 0.0 (4) polyoxyethylene (10 mol) oleyl ether 3.0 (5) stearyl alcohol 0.1 (6) liquid paraffin 7.0 (7) squalane 8.0 (8) methyl polysiloxane 5.0 [ Silicone KF96A-6 manufactured by Shin-Etsu Chemical Co., Ltd.) (9) Polyvinyl alcohol 0.2 (10) 1,3-butylene glycol 5.0 (11) Sodium hydroxide 0.2 (12) Methyl paraben 0.1 ( 13) Ion exchange water 49.5 (14) Fragrance 0.1
【0054】<製法>(1)〜(8)及び(13)を8
0〜90℃で撹拌溶解して油相部とし、(9)、(1
0)〜(12)を70〜80℃で撹拌溶解して水相部と
した。水相部に油相部を加えて乳化させた後、オンレー
ターで冷却し、容器に充填し、硬度15のヘアワックス
を得た。<Production method> (1) to (8) and (13)
The mixture was stirred and dissolved at 0 to 90 ° C. to form an oil phase, and (9), (1)
0) to (12) were stirred and dissolved at 70 to 80 ° C. to obtain an aqueous phase. After the oil phase was added to the water phase to emulsify, the mixture was cooled with an onlator and filled in a container to obtain a hair wax having a hardness of 15.
【0055】 〔比較例6〕 ヘアクリーム(12−ヒドロキシステアリン酸非配合) 配合成分 配合量(重量%) (1)カラギーナン 1.0 (2)ポリオキシエチレン硬化ヒマシ油(60EO) 1.0 (3)カルボキシビニルポリマー 0.6 [商品名:カーボポール940,BF.Goodrich社製] (4)ジメチルポリシロキサン(n=1000) 5.0 (5)トリエタノールアミン(pH=7.5に調整) 0.2 (6)グリセリン 2.0 (7)香料 0.1 (8)オクチルメトキシシンナメート 0.1 (9)エタノール 25.0 (10)イオン交換水 62.0 (11)ポリオキシエチレン(40)・ポリオキシプロピレン(5) 3.0 デカグリセリルエーテルComparative Example 6 Hair Cream (without 12-Hydroxystearic Acid) Blended Components (% by weight) (1) Carrageenan 1.0 (2) Polyoxyethylene hydrogenated castor oil (60EO) 1.0 ( 3) Carboxyvinyl polymer 0.6 [trade name: Carbopol 940, BF. Goodrich Co.) (4) Dimethylpolysiloxane (n = 1000) 5.0 (5) Triethanolamine (adjusted to pH = 7.5) 0.2 (6) Glycerin 2.0 (7) Fragrance 0.1 (8) ) Octyl methoxycinnamate 0.1 (9) Ethanol 25.0 (10) Deionized water 62.0 (11) Polyoxyethylene (40) / polyoxypropylene (5) 3.0 Decaglyceryl ether
【0056】<製法>(6)に(2)、(4)を加えて
乳化する(乳化パーツ)。(10)に(1)、(3)を
加えて均一に溶解した後、(5)、(7)、(8)、
(9)、(11)を加えて得た混合物に乳化パーツを混
合し、粘度35000mPa・sのヘアクリームを得
た。<Production method> (2) and (4) are added to (6) and emulsified (emulsified parts). After adding (1) and (3) to (10) and dissolving uniformly, (5), (7), (8),
The emulsified parts were mixed with the mixture obtained by adding (9) and (11) to obtain a hair cream having a viscosity of 35,000 mPa · s.
【0057】なお、本発明油性毛髪化粧料の必須成分の
一つである、炭化水素油を抜去した処方例は、処方から
炭化水素油を抜去することにより、他の必須成分であ
る、12−ヒドロキシステアリン酸とシリコーン誘導体
が、均一に相溶しなくなる。そのため、比較例として挙
げることは困難であった。In addition, in the formulation example in which the hydrocarbon oil is removed, which is one of the essential components of the oily hair cosmetic of the present invention, the other essential component is obtained by removing the hydrocarbon oil from the formulation. Hydroxystearic acid and the silicone derivative are not homogeneously compatible. Therefore, it was difficult to give it as a comparative example.
【0058】以上、実施例1〜4で得られたものと、比
較例1〜6で得られたものについて、「塗布時の手のべ
たつき感」、「手ぐしの通りやすさ」、「なめらか
さ」、「整髪力」、「つや」について評価した。評価方
法を以下に示す。As described above, the results obtained in Examples 1 to 4 and the results obtained in Comparative Examples 1 to 6 were evaluated for "stickiness of hand at the time of application", "easiness of hand gesture", and "smoothness". , "Hair styling" and "gloss" were evaluated. The evaluation method is described below.
【0059】(1)手のべたつき感 20名の被験者において、各人が手のひらに試料1gを
とり、30秒間手でこすった後、手のべたつき感を官能
評価した。評価基準は、以下の通りである。 ◎:非常に良好 手のべたつきがないと答えた被験者が18人以上 ○:良好 手のべたつきがないと答えた被験者が8〜17人 △:やや悪い 手のべたつきがないと答えた被験者が5〜8人 ×:悪い 手のべたつきがないと答えた被験者が4人以下(1) Hand Stickiness In 20 subjects, each person took 1 g of a sample on the palm and rubbed it with his / her hand for 30 seconds. The evaluation criteria are as follows. ◎: Very good 18 or more subjects answered that there was no stickiness. :: 8 to 17 subjects who answered that there was no stickiness. :: 5 subjects who answered that there was no stickiness. Up to 8 ×: Bad No more than 4 subjects answered that there was no stickiness
【0060】(2)手ぐしの通りやすさ 20名の被験者各々の、毛髪ストランド(4g )に試料
1g を塗布し、くしで形を整え、その直後及び6時間後
に手ぐしの通りやすさを、各人が評価した。評価基準
は、以下の通りである。 ◎:非常に良好 手ぐしが通りやすいと答えた被験者が18人以上 ○:良好 手ぐしが通りやすいと答えた被験者が8〜17人 △:やや悪い 手ぐしが通りやすいと答えた被験者が5〜8人 ×:悪い 手ぐしが通りやすいと答えた被験者が4人以下(2) Ease of passing through the hand A 1 g sample was applied to a hair strand (4 g) of each of 20 subjects, and the shape was adjusted with a comb. , Each person rated. The evaluation criteria are as follows. ◎: Very good 18 or more subjects answered that it was easy to pass through. ○: 8 to 17 subjects who answered that it was easy to pass through. △: 5 or less subjects answered that it was easy to pass through. Up to 8 ×: Less than 4 subjects answered that it was easy to pass
【0061】(3)なめらかさ 20名の被験者各々の、上記毛髪ストランド(4g )の
なめらかさを、塗布直後及び6時間後に、各人が評価し
た。評価基準は、以下の通りである。 ◎:非常に良好 なめらかであると答えた被験者が18人以上 ○:良好 なめらかであると答えた被験者が8〜17人 △:やや悪い なめらかであると答えた被験者が5〜8人 ×:悪い なめらかであると答えた被験者が4人以下(3) Smoothness The smoothness of the hair strand (4 g) of each of the 20 subjects was evaluated immediately after application and 6 hours after the application. The evaluation criteria are as follows. ◎: 18 or more subjects answered that they were very smooth ○: 8 to 17 subjects who answered that they were smooth △: Somewhat 5 to 8 subjects who answered that they were smooth ×: Poor No more than 4 subjects said they were smooth
【0062】(4)整髪力 20名の被験者各々の毛髪ストランド(4g )に、試料
2g を塗布し、くしで形を整える。次いで、そのストラ
ンドに、第1図で示すように、ドライヤー1で1分間送
風(熱風)を行い、ストランド2の広がり具合を、目視
により評価した。評価基準は、以下の通りである。 ○:広がっていない △:やや広がっている ×:広がっている(4) Hair Styling A 2 g sample was applied to each hair strand (4 g) of each of 20 subjects, and the hair was shaped with a comb. Next, as shown in FIG. 1, the strand was blown (hot air) for 1 minute by a dryer 1 to visually evaluate the spread of the strand 2. The evaluation criteria are as follows. ○: not spread △: slightly spread ×: spread
【0063】(5)毛髪へのつやの付与効果 各試料1g を、長さ15cm、500〜600本の毛髪束
に塗布し、40℃の温水300mL中で、振盪すすぎ(1
00cycle)を2回繰り返した後、この毛髪束を乾
燥させる。次いで、この毛髪束から任意に10本の毛髪
を選び、変角光度計GP−IR[ (株)村上色彩研究所
製] で入射された光に対する毛髪の反射光分布を測定
し、毛髪の光沢度(つや)を次の式により求めた。(5) Effect of Applying Gloss to Hair 1 g of each sample is applied to a bundle of 500 to 600 hairs each having a length of 15 cm and shaken and rinsed in 300 mL of 40 ° C. warm water (1).
00 cycle) is repeated twice, and the hair bundle is dried. Next, ten hairs were arbitrarily selected from the hair bundle, and the reflected light distribution of the hair with respect to the incident light was measured by a goniophotometer GP-IR [manufactured by Murakami Color Research Laboratory Co., Ltd.], and the gloss of the hair was measured. The degree (gloss) was determined by the following equation.
【0064】G=s/d(G:光沢度、s:正反射光
量、d:拡散反射光量)G = s / d (G: glossiness, s: regular reflection light amount, d: diffuse reflection light amount)
【0065】以上の方法で求められた光沢度Gにより各
試料の毛髪へのつや付与効果を以下のように評価した。The gloss imparting effect of each sample to the hair was evaluated as follows based on the gloss G obtained by the above method.
【0066】 [0066]
【0067】以上の評価結果を第1表に示す。Table 1 shows the evaluation results.
【表1】 [Table 1]
【0068】第1表の結果から明らかなように、比較例
1,4のように、処方からシリコーン誘導体を欠いた場
合には、滑らかさに欠け、比較例2のように、処方から
炭化水素油を欠いた場合には、手のべたつきを伴い、か
つ、毛髪へのつや付与効果に劣っていた。さらに、比較
例3のように、処方から12−ヒドロキシステアリン酸
を欠いた場合には、出来上がったヘアスティックの硬度
が低すぎ、製品としては使いにくいものであった。ま
た、比較例5,6のようなヘアワックス、ヘアクリーム
として調製した場合には、手にべたつきが感じられるも
のになった。As is clear from the results shown in Table 1, when the silicone derivative was omitted from the formulation as in Comparative Examples 1 and 4, the smoothness was lacked, and as in Comparative Example 2, the hydrocarbon was not included in the formulation. When the oil was lacking, hand stickiness was accompanied and the effect of imparting gloss to hair was poor. Furthermore, when 12-hydroxystearic acid was missing from the formulation as in Comparative Example 3, the hardness of the resulting hair stick was too low, making it difficult to use as a product. When prepared as a hair wax or a hair cream as in Comparative Examples 5 and 6, stickiness was felt in the hands.
【0069】しかしながら、12−ヒドロキシステアリ
ン酸とシリコーン誘導体と炭化水素油を組み合わせた、
本発明油性化粧料は、毛髪に対し優れた光沢を与え、な
めらかな感触を付与しながら、かつ、良好な整髪力を保
持させると共に、毛髪に対して優れた光沢を与えること
ができた。However, a combination of 12-hydroxystearic acid, a silicone derivative and a hydrocarbon oil,
The oil-based cosmetic of the present invention can impart excellent gloss to hair, impart a smooth feel, maintain good hair styling power, and impart excellent gloss to hair.
【0070】[0070]
【発明の効果】本発明油性毛髪化粧料は、使用感が良好
で、櫛通り性も良く、毛髪になめらかな感触を付与し、
かつ良好な整髪力を保持させるとともに、毛髪に対して
優れた光沢を与えることができるEFFECT OF THE INVENTION The oily hair cosmetic composition of the present invention has a good feeling in use and good combability, and imparts a smooth feel to hair,
In addition to maintaining good hair styling power, it can give excellent gloss to hair
【図1】本発明に関する整髪力試験における、毛髪スト
ランドと、これに送風するためのドライヤーの位置関係
を示した図面である。FIG. 1 is a drawing showing a positional relationship between a hair strand and a dryer for blowing air to the hair strand in a hair styling test according to the present invention.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 難波 富幸 神奈川県横浜市港北区新羽町1050番地 株 式会社資生堂第1リサーチセンター内 Fターム(参考) 4C083 AA122 AC011 AC012 AC022 AC072 AC102 AC111 AC112 AC122 AC182 AC241 AC242 AC342 AC352 AC422 AC432 AC472 AC542 AC792 AD052 AD092 AD151 AD152 AD172 AD352 AD511 AD512 AD531 CC31 CC32 DD01 DD11 DD21 DD31 EE06 EE07 FF05 FF06 ────────────────────────────────────────────────── ─── Continued on the front page (72) Inventor Tomiyuki Namba 1050 Nippa-cho, Kohoku-ku, Yokohama-shi, Kanagawa F-term in Shiseido First Research Center Co., Ltd. 4C083 AA122 AC011 AC012 AC022 AC072 AC102 AC111 AC112 AC122 AC182 AC241 AC242 AC342 AC352 AC422 AC432 AC472 AC542 AC792 AD052 AD092 AD151 AD152 AD172 AD352 AD511 AD512 AD531 CC31 CC32 DD01 DD11 DD21 DD31 EE06 EE07 FF05 FF06
Claims (4)
12−ヒドロキシステアリン酸の配合量が1.0〜7
0.0重量%、(B)成分の炭化水素油の配合量が1.
0〜80.0重量%、(C)成分のシリコーン誘導体の
配合量が1.0〜60.0重量%である請求項1記載の
油性毛髪化粧料。2. The amount of component (A), 12-hydroxystearic acid, in the total amount of the hair cosmetic composition is from 1.0 to 7%.
0.0% by weight, the compounding amount of the hydrocarbon oil (B) is 1.
The oily hair cosmetic according to claim 1, wherein the amount of the silicone derivative (C) is 1.0 to 60.0% by weight.
並びに不均化ロジン及び/又は水素添加ロジンと脂肪酸
と多価アルコールとからなるエステルから選ばれるもの
である請求項1又は2記載の油性毛髪化粧料。3. The hydrocarbon oil according to claim 1, wherein the hydrocarbon oil (B) is selected from liquid lanolin and disproportionated rosin and / or an ester comprising a hydrogenated rosin, a fatty acid and a polyhydric alcohol. Oily hair cosmetics.
フェニルシリコーンオイルである請求項1ないし3のい
ずれかの請求項記載の油性毛髪化粧料。4. The oily hair cosmetic according to claim 1, wherein the silicone derivative (C) is methylphenylsilicone oil.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP10314556A JP2000143454A (en) | 1998-11-05 | 1998-11-05 | Oily hair cosmetic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10314556A JP2000143454A (en) | 1998-11-05 | 1998-11-05 | Oily hair cosmetic |
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Publication Number | Publication Date |
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JP2000143454A true JP2000143454A (en) | 2000-05-23 |
Family
ID=18054718
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10314556A Pending JP2000143454A (en) | 1998-11-05 | 1998-11-05 | Oily hair cosmetic |
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---|---|---|---|---|
JP2002154937A (en) * | 2000-10-04 | 2002-05-28 | Wella Ag | Hair wax product comprising wax, non-volatile oil and volatile hydrophobic substance |
JP2005213252A (en) * | 2004-01-28 | 2005-08-11 | Wella Ag | Hair wax product comprising silicone wax, non-silicone containing wax, and oil |
JP2008143869A (en) * | 2006-12-12 | 2008-06-26 | Kao Corp | Hair cosmetics |
JP2009143847A (en) * | 2007-12-14 | 2009-07-02 | Shiseido Co Ltd | Wax composition |
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1998
- 1998-11-05 JP JP10314556A patent/JP2000143454A/en active Pending
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JP2002154937A (en) * | 2000-10-04 | 2002-05-28 | Wella Ag | Hair wax product comprising wax, non-volatile oil and volatile hydrophobic substance |
JP2005213252A (en) * | 2004-01-28 | 2005-08-11 | Wella Ag | Hair wax product comprising silicone wax, non-silicone containing wax, and oil |
JP2008143869A (en) * | 2006-12-12 | 2008-06-26 | Kao Corp | Hair cosmetics |
JP2009143847A (en) * | 2007-12-14 | 2009-07-02 | Shiseido Co Ltd | Wax composition |
KR101053641B1 (en) * | 2008-07-31 | 2011-08-02 | 주식회사 엘지생활건강 | Hair styling wax composition |
JPWO2016158011A1 (en) * | 2015-03-27 | 2017-09-14 | 株式会社マンダム | Oily composition for hair |
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JPWO2016158012A1 (en) * | 2015-03-27 | 2017-09-14 | 株式会社マンダム | Oily composition for hair |
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